Enhancement of OI 630.0 nm emission at mid-latitudes during an intense magnetic storm

All-sky camera (ASC), Global Positioning System (GPS), and ionosonde measurements were used to investigate the upper atmospheric variations at mid-latitude during the strong geomagnetic storm on October 29–31, 2003. An arc-shaped 630.0 nm emission was observed in the northern sky on all-sky images taken at Mt. Bohyun (36.2°N, 128.9°E, GMLAT=29°N) in Korea during 17:48–8:58 UT in the main phase of the geomagnetic storm on October 29. The NmF₂ and hmF₂ from the ionosonde show strong disturbances at that time. The vertical profiles of electron densities, calculated by the ionospheric tomographic method using ground-based GPS slant total electron contents measurements, show the largest value at ∼440 km height at 18:30 UT on October 29 when the enhancements of OI 630.0 nm emission were observed. The arc-shaped red emission observed during the main phase of the magnetic storm is likely a low-latitude red aurora due to its short duration of ∼1 h. The result implies that the plasmapause was at L=1.4–1.6 during the geomagnetic storm. The fact that the arc did not follow a constant L-value appears to suggest that neutral precipitation and a traveling ionospheric disturbance could also be the cause of the arc.     

Influence of nitrate and dissolved organic carbon loading on the interaction of Microcystis aeruginosa and heterotrophic bacteria from hyper-eutrophic lake (Taihu Lake,China)

To investigate the interaction between cyanobacteria and heterotrophic bacteria under gradients of glucose and nitrate, a cyanobacterial strain of Microcystis aeruginosa was grown in microcosms with and without a freshwater bacterial mixture, which was collected from Lake Taihu. Concentrations of glucose (1350, 975, 600, 300, 150, and 37.5 μmol C L⁻¹) and nitrate (150, 300, and 9000 μmol N L⁻¹) were used in a range of combinations giving 9 different treatments of glucose:nitrate. In the microcosm without the bacterial mixture, M. aeruginosa abundance gradually increased with days in all treatments. However, M. aeruginosa had much lower density in some treatments with the bacterial mixture. The difference in M. aeruginosa growth could be explained by competition with bacteria in the cultures in which these were added. The abundance of M. aeruginosa and bacteria when grown together was nearly equal and the number of the bacterial species was highest in the treatment with 300 μmol C L⁻¹ and 150 μmol N L⁻¹. Our results suggest that at this glucose:nitrate ratio M. aeruginosa and the bacterial mixture maintain a balance, and bacteria maintain diversity. In conclusion, we propose that dissolved organic carbon and nitrate availability fundamentally affects the structure as well as stoichiometry of pelagic associations.     

Whistlers observed at low-latitude ground-based VLF facility in Fiji

The propagation features of nighttime whistlers to low-latitude station, Suva (−18.2°, 178.3°, geomag. lat. −22.1°, geomag. long. 253.5°, L=1.15), Fiji, from preliminary observations made during the period from September 2003–2005, are reported. The observations of ELF–VLF signals commenced in September 2003 using the VLF set-up of World Wide Lightning Location Network at our station. The whistlers were observed during the severe magnetic storm of 20–22 November 2003 and moderate magnetic storm of 17–19 July 2005. A whistler with dispersion D=12.7 s^1/2 occurred on 22 November at 00:11 h LT. On 20 July at 01:00 h LT, a short whistler with dispersion D=20.9 s^1/2 and two whistler events having two-component whistlers with D=15.8, 16.7 s^1/2 and 16.7, 17.3 s^1/2 were observed. Non-ducted pro-longitudinal mode of the whistler propagation supported by negative latitudinal electron density gradients in the ionosphere that are enhanced by magnetic storms, seems most likely mode of propagation for the whistlers with dispersion of 12.7–17.3 s^1/2 to this low-latitude station.     

Ground-based Pc5 ULF wave power: Solar wind speed and MLT dependence

Using over 20 years of ground-based magnetometer data from the CANOPUS/CARISMA magnetometer array, we present a statistical characterisation of Pc5 ultra-low frequency (ULF) power in the 2–10 mHz band as a function of magnetic local time (MLT), L-shell, and solar wind speed. We examine the power across L-shells between 4.2 and 7.9, using data from the PINA, ISLL, GILL and FCHU stations, and demonstrate that there is a significant MLT dependence in both the H- and D-component median 2–10 mHz power during both fast (>500 km/s) and slow (<500 km/s) solar wind speeds. The H-component power consistently dominates over D-component power at all MLTs and during both fast and slow solar wind. At the higher-L stations (L>5.4), there are strong MLT power peaks in the morning and midnight local time sectors; the morning sector dominating midnight during fast solar wind events. At lower L-shells, there is no evidence of the midnight peak and the 2–10 mHz power is more symmetric with respect to MLT except during the fastest solar wind speeds. There is little evidence in the ground-based power of a localised MLT peak in ULF power at dusk, except at the lowest L-shell station, predominantly in the H-component. The median 2–10 mHz power increases with an approximate power law dependence on solar wind speed, at all local times across the L-shell domain studied in both components. The H-component power peaks at the latitude of the GILL station, with significantly lower power at both higher and lower L-shells. Conversely, the D-component power increases monotonically. We believe that this is evidence for 2–10 mHz power accumulating at auroral latitudes in field line resonances. Finally, we discuss how such ULF wave power characterisation might be used to derive empirical radiation belt radial diffusion coefficients based on, and driven by, the solar wind speed dependence of ULF wave power.     

Patterns of significant seismic quiescence on the Mexican Pacific coast

Many authors have proposed that the study of seismicity rates is an appropriate technique for evaluating how close a seismic gap may be to rupture. We designed an algorithm for identification of patterns of significant seismic quiescence by using the definition of seismic quiescence proposed by Schreider (1990). This algorithm shows the area of quiescence where an earthquake of great magnitude may probably occur. We have applied our algorithm to the earthquake catalog on the Mexican Pacific coast located between 14 and 21 degrees of North latitude and 94 and 106 degrees West longitude; with depths less than or equal to 60 km and magnitude greater than or equal to 4.3, which occurred from January, 1965 until December, 2014. We have found significant patterns of seismic quietude before the earthquakes of Oaxaca (November 1978, M_w = 7.8), Petatlán (March 1979, M_w = 7.6), Michoacán (September 1985, M_w = 8.0, and M_w = 7.6) and Colima (October 1995, M_w = 8.0). Fortunately, in this century earthquakes of great magnitude have not occurred in Mexico. However, we have identified well-defined seismic quiescences in the Guerrero seismic-gap, which are apparently correlated with the occurrence of silent earthquakes in 2002, 2006 and 2010 recently discovered by GPS technology.     

Effects of tributyltin at concentrations below ambient levels in seawater on Caprella danilevskii (Crustacea: Amphipoda: Caprellidae)

Hatched juveniles of Caprella danilevskii (Crustacea: Amphipoda) were exposed to one of two concentrations of tributyltin (TBT) (1.1 and 10.7 ng TBT L⁻¹) for 49 d at 20 °C. These concentrations are near or below ambient levels in seawater. In both treatments and control, the survival rate was 100% at maturation, and >85% at the end of the experiments. Females reached maturation at 20 (median) to 21.5 d at instar VII, and repeated spawning 4–5 times during the experiment. The total number of juveniles per female decreased significantly from 39.5 in the control to 24.5 and 17.5 in 1.1 ng L⁻¹ and 10.7 ng L⁻¹ treatments, respectively. An earlier study reported that as the TBT concentration in seawater increased from a 0–10 ng L⁻¹ regime to a 10–20 ng L⁻¹ regime, the number of stations where Caprella spp. could be collected decreased along the coast of the Seto Inland Sea, of Japan. Thus, the present study indicates the possibility that the extremely low concentration of TBT measured in Japanese waters after 2000 lead to a reduction in reproductive success of Caprella spp.     

Toxicities of antifouling biocide Irgarol 1051 and its major degraded product to marine primary producers

Irgarol 1051 (2-methythiol-4-tert-butylamino-6-cyclopropylamino-s-triazine) is an algaecide commonly used in antifouling paints. It undergoes photodegradation which yields M1 (2-methylthio-4-tert-butylamino-6-amino-s-triazine) as its major and most stable degradant. Elevated levels of both Irgarol and M1 have been detected in coastal waters worldwide; however, ecotoxicity effects of M1 to various marine autotrophs such as cyanobacteria are still largely unknown. This study firstly examined and compared the 96 h toxicities of Irgarol and M1 to the cyanobacterium Chroococcus minor and two marine diatom species, Skeletonema costatum and Thalassiosira pseudonana. Our results suggested that Irgarol was consistently more toxic to all of the three species than M1 (96 h EC50 values: C. minor, 7.71 μg L⁻¹ Irgarol vs. >200 μg L⁻¹ M1; S. costatum, 0.29 μg L⁻¹ Irgarol vs. 11.32 μg L⁻¹ M1; and T. pseudonana, 0.41 μg L⁻¹ Irgarol vs. 16.50 μg L⁻¹ M1). Secondly, we conducted a meta-analysis of currently available data on toxicities of Irgarol and M1 to both freshwater and marine primary producers based on species sensitivity distributions (SSDs). Interestingly, freshwater autotrophs are more sensitive to Irgarol than their marine counterparts. For marine autotrophs, microalgae are generally more sensitive to Irgarol than macroalgae and cyanobacteria. With very limited available data on M1 (i.e. five species), M1 might be less toxic than Irgarol; nonetheless this finding warrants further confirmation with additional data on other autotrophic species.     

Temporal and spatial variations of seismicity scaling behavior in Southern México

R/S analysis is used in this work to investigate the fractal correlations in terms of the Hurst exponent for the 1998–2011 seismicity data in Southern Mexico. This region is the most seismically active area in Mexico, where epicenters for severe earthquakes (e.g., September 19, 1985, M_w = 8.1) causing extensive damage in highly populated areas have been located. By only considering the seismic events that meet the Gutenberg–Ritcher law completeness requirement (b = 0.97, M_GR = 3.6), we found time clustering for scales of about 100 and 135 events. In both cases, a cyclic behavior with dominant spectral components at about one cycle per year is revealed. It is argued that such a one-year cycle could be related to tidal effects in the Pacific coast. Interestingly, it is also found that high-magnitude events (M_w ≥ 6.0) are more likely to occur under increased interevent correlations with Hurst exponent values H > 0.65. This suggests that major earthquakes can occur when the tectonic stress accumulates in preferential directions. In contrast, the high-magnitude seismic risk is reduced when stresses are uniformly distributed in the tectonic shell. Such cointegration between correlations (i.e., Hurst exponent) and macroseismicity is confirmed for spatial variations of the Hurst exponent. In this way, we found that, using the Hurst exponent standpoint, the former presumed Michoacan and the Guerrero seismic gaps are the riskiest seismic zones. To test this empirical finding, two Southern Mexico local regions with large earthquakes were considered. These are the Atoyac de Alvarez, Guerrero (M_w = 6.3), and Union Hidalgo, Oaxaca (M_w = 6.6), events. In addition, we used the Loma Prieta, California, earthquake (October 17, 1989, M_w = 6.9) to show that the high-magnitude earthquakes in the San Andreas Fault region can also be linked to the increments of determinism (quantified in terms of the Hurst exponent) displayed by the stochastic dynamics of the interevent period time series. The results revealed that the analysis of seismic activity by means of R/S analysis could provide further insights in the advent of major earthquakes.     

Relation of PC index to the geomagnetic storm Dst variation

Relationships between the polar cap magnetic activity index PC and the magnetic storm Dst index have been studied for the magnetic storms with duration more 12 h and peak value Dst<?30 nT and, observed in 1998–2002 and 2004–2005. Along with PC index the geoeffective interplanetary electric field Em was also examined. It has been found that all examined storms, lying in range from ?30 to ?373 nT, started when the PC index and, correspondingly, the Em field firmly exceeded the threshold >2 mV/m. In particular, the “anomalous” magnetic storm on January 21–22, 2005 occurring under conditions of northward IMF B_Z (Du et al., 2008) is usual phenomena fitted well with the threshold restriction owing to the large IMF By component input. The maximal storm depression (the peak value of Dst) is linearly related to the quantities Em and PC, averaged for the time interval from the storm beginning to the storm maximum. The correlation between Dst and PC is more steady and larger than correlation between Dst and Em, the latter being dependent on Em value (effect of “Dst saturation”). The moment of the firm descent of the Em and PC quantities below the threshold level ～2 mV/m is indicative of the depression damping and transition to the recovery phase. The results are consistent with the similar peculiarities revealed for substorms development (Troshichev and Janzhura, 2009) and support the conclusion that the PC index is a reliable proxy characterizing the solar wind energy having been entered into the magnetosphere.     

A similarity approach to determine response times to steady-state saturation in landscapes

Relationships describing response times for landscape saturation and subsurface flow for idealised hillslopes after a change in water balance are derived in terms of similarity parameters given by their topographic, soil and climatic attributes. The study was carried out under a set of specific assumptions.The work quantitatively describes effects of each of these attributes on travel time. For example, divergent hillslopes can exhibit travel times that are double those of convergent hillslopes, and concave slopes tend to have lower travel times than planar or convex slopes. It is shown that the hillslope travel time T is dependent on hillslope length L, hydraulic conductivity K and slope S such that T = f(L/KS, B, CR, Δq/smd) and if saturation does not occur in the lower reaches of a hillslope, this can be simplified to T = f(L/KS, B). Here, Δq is change in net external flux and smd is soil moisture deficit; CR and B are the convergence ratio and profile factor respectively. The relative importance of these attributes on response time is discussed.It is shown that subsurface flow hydrographs of simple hillslopes of different scale, derived numerically, can be collapsed into a single curve by normalising them by means of a form of response time, the time constant.Results from the analytical derivation were compared with numerical analysis with good agreement. The theory was applied to a natural catchment using observed data from a bushfire event. Comparison of analytically calculated response time with observed response time for the event showed a large discrepancy. The reason is discussed.     

Nonlinear geodynamics of the Baikal rift system: An evolution scenario with triple equilibrium bifurcation

This is an attempt to analyze the current lithospheric stress pattern in the Baikal rift in terms of nonlinear dynamics as an open self-organizing system in order to gain more insights into the general laws of regional seismicity. According to the suggested approach, the stress pattern inferred from seismic moments of 70,000 M_LH ≥ 2.0 events that occurred in the region between 1968 and 1994 is presented as a phase portrait in the phase spaces of the seismic moments. The obtained phase portrait of the system evolution fits well a scenario with triple equilibrium bifurcation where stress bifurcations account for the frequency of M > 5.5 earthquakes. Extrapolation of the results into the nearest future indicates probability of such a bifurcation (a catastrophe of stress), i.e., there is growing risk that M ≈ 7 events may happen in the region within a few years.     

Coda-Q and its lapse time dependence analysis in the interaction zone of the Dinarides,the Alps and the Pannonian basin

The single backscattering model was used to estimate total attenuation of coda waves (Q_c) of local earthquakes recorded on eight seismological stations in the complex area of the western continental Croatia. We estimated Q₀ and n, parameters of the frequency dependent coda-Q using the relation Q_c = Q₀fⁿ. Lapse time dependence of these parameters was studied using a constant 30 s long time window that was slid along the coda of seismograms. Obtained Q_c were distributed into classes according to their lapse time, t_L. For t_L = 20–50 s we estimated Q₀ = 45–184 and n = 0.49–0.94, and for t_L = 60–100 s we obtained Q₀ = 119–316 and n = 0.37–0.82. There is a tendency of decrease of parameter n with increasing Q₀, and vice versa. The rates of change of both Q₀ and n seem to decrease for lapse times larger than 50–80 s, indicating an alteration in rock properties controlling coda attenuation at depths of about 100–160 km. A very good correlation was found between the frequency dependence parameter n and the Moho depths for lapse times of 50, 60 and 70 s.     

Neotectonics of the Dinarides–Pannonian Basin transition and possible earthquake sources in the Banja Luka epicentral area

This study provides evidence for post-5 Ma shortening in the transition area between the Dinarides fold-and-thrust belt and the Pannonian Basin and reviews possible earthquake sources for the Banja Luka epicentral area (northern Bosnia and Herzegovina) where the strongest instrumentally recorded earthquake (M_L 6.4) occurred on 27 October 1969. Geological, geomorphological and reflection seismic data provide evidence for a contractional reactivation of Late Palaeogene to Middle Miocene normal faults at slip rates below 0.1 mm/a. This reactivation postdates deposition of the youngest sediments in the Pannonian Basin of Pontian age (c. 5 Ma). Fault plane solutions for the main 1969 Banja Luka earthquake (M_L 6.4) and its largest foreshock (M_L 6.0) indicate reverse faulting along ESE–WNW-striking nodal planes and generally N–S trending pressure axes. The spatial distribution of epicentres and focal depths, analyses of the macroseismic field and fault-plane solutions for several smaller events suggest on-going shortening in the internal Dinarides. Seismic deformation of the upper crust is also associated with strike-slip faults, likely related to the NE–SW trending, sinistral Banja Luka fault. Possibly, this fault transfers contraction between adjacent segments of the Dinarides thrust system. The study area represents the seismically most active region of the Dinarides apart from the Adriatic Sea coast and the bend zone around Zagreb. We propose that on-going thrusting in the internal Dinarides thrust system takes up a portion of the current Adria–Europe convergence.     

Magnetic properties of synthetic six-line ferrihydrite nanoparticles

Three synthetic samples of six-line ferrihydrite (Fh5.4, Fh4.1, and Fh3.0), with average particle sizes of 5.4, 4.1, and 3.0 nm (respectively), have been studied by low-temperature magnetic techniques, Mössbauer spectroscopy, transmission electron microscopy, and X-ray absorption spectroscopy. Magnetic data indicate that these nanoparticles are not only antiferromagnetic, but that they also possess a ferromagnetic-like moment due to the presence of uncompensated spins. Both magnetic and Mössbauer data indicate that nanoparticles of six-line ferrihydrite are superparamagnetic at room temperature, with a low-temperature transition between blocked and unblocked magnetic states dependent on average particle size. In particular, low-field magnetic susceptibility data display a peak in amplitude at 45 K (Fh3.0), 55 K (Fh4.1), and 80 K (Fh5.4). Low-temperature induced magnetization data, acquired in magnetic fields up to 5 T, also display clearly a superparamagnetic behavior. These data were tentatively modeled as the sum of two contributions: a linear term due to the antiferromagnetic susceptibility and a nonlinear term due to the uncompensated spins. Model estimates of the magnetization carried by the uncompensated spins (M_nc) show a decrease in M_nc with increasing temperature. Extrapolation of M_nc values down to zero provided an estimate of the Néel temperature for six-line ferrihydrite on the order of 500 K.     

Time-Domain Moment Tensors for shallow (h ≤ 40 km) earthquakes in the broader Aegean Sea for the years 2006 and 2007: The database of the Aristotle University of Thessaloniki

We present a catalog of moment tensor (MT) solutions and moment magnitudes, M_w, for 119 shallow (h ≤ 40 km) earthquakes in Greece and its surrounding lands (34°N–42°N, 19°E–30°E) for the years 2006 and 2007, computed with the 1D Time-Domain Moment Tensor inversion method (TDMT_INV code of Dreger, 2003). Magnitudes range from 3.2 ≤ M_w ≤ 5.7. Green's functions (GF) have been pre-computed to build a library, for a number of velocity profiles applicable to the broader Aegean Sea region, to be used in the inversion of observed broad band waveforms (10–50 s). All MT solutions are the outcome of a long series of tests of different reported source locations and hypocenter depths. Quality factors have been assigned to each MT solution based on the number of stations used in the inversion and the goodness of fit between observed and synthetic waveforms. In general, the focal mechanisms are compatible with previous knowledge on the seismotectonics of the Aegean area. The new data provide evidence for strike-slip faulting along NW–SE trending structures at the lower part of Axios basin, close to the heavily industrialized, and presently subsiding, region of the city of Thessaloniki. Normal faulting along E–W trending planes is observed at the Strimon basin, and in Orfanou Gulf in northern Greece. A sequence of events in the east Aegean Sea close to the coastline with western Anatolia sheds light on an active structure bounding the north coastline of Psara–Chios Islands about 20–25 km in length exhibiting right lateral strike-slip faulting.     

An evaluation of the toxicity and bioaccumulation of thallium in the coastal marine environment using the macroalga,Ulva lactuca

Thallium(I) has been added to cultures of the marine macroalga, Ulva lactuca, for a period of 48 h and the accumulation of the metal and its effects on the photochemical efficiency of photosystem II (PS II) measured. Thallium elicited a measurable toxic response above concentrations of 10 μg L⁻¹ in both coastal seawater (salinity 33) and estuarine water (salinity 20). The accumulation of Tl was defined by a linear relationship with aqueous Tl and accumulation factors of about 900 mL g⁻¹ in both media. Thallium accumulated by U. lactuca that was resistant to an EDTA extraction and, by operational definition, internalised, exceeded 90% in both cases. Accumulation and toxicity of Tl in the presence of a ∼10⁵-fold excess of its biogeochemical analogue, potassium, suggests that Tl has a high intrinsic phytotoxicity and that its mode of action involves permeation of the cell membrane as Tl⁺ through NaCl–KCl co-transporter sites rather than (or in addition to) transport through K⁺ ion channels.     

The effect of Hurricane Lili on the distribution of organic matter along the inner Louisiana shelf (Gulf of Mexico,USA)

On October 3, 2002 Hurricane Lili made landfall on a previously studied region of the inner Louisiana shelf as a Category 2 storm with winds over 160 km/h. A week after the hurricane, major impacts of the storm were not evident in the water column except for the lower than expected inshore salinities (∼12 psu) for this time of year, which was characterized by low river discharge. Turbidity profiles were typical of those measured during previous investigations with suspended sediment concentrations >75 mg/L at inshore stations and <50 mg/L in surface waters and offshore. The implication is that the sediments resuspended during the hurricane settled soon after the storm passage. Water column particulate organic carbon (POC) concentrations ranged from 0.1 to over 2.0 mg/L, with the highest concentrations measured near the seabed and in the inshore portions of the study area. Suspended particles were characterized by low organic matter content (%POC of 0.5–2 wt%), low chlorophyll:POC ratios (Chl:POC<4 mg/g) and moderately elevated POC:particulate nitrogen ratios (POC:PN of 10–14 mol/mol), all suggesting their source was locally resuspended seabed sediment rather than from algal biomass or land-derived vascular plant detritus.Post hurricane sediment deposition throughout the study area resulted in a storm layer that ranged from <0.5 to 20 cm in thickness. In most locations sediment accumulation ranged from 3 to 10 cm. The storm deposits were generally composed of silty clays with a coarser, somewhat sandy 1–2 cm basal layer. Surface sediments from the storm layer were characterized by relatively high mineral surface areas (SA of 30–50 m²/g) and elevated OC contents (%OC of 1.0–2.0%). The dispersal of fine sediments following the hurricane resulted in marked changes in the SA and %OC values of surface sediments from offshore locations, which prior to the storm contained coarser, organic-poor particles (SA of 5–15 m²/g and %OC of 0.2–0.6%). The OC:SA and OC:N ratios of storm layer sediments ranged from 0.4 to 0.6 mg OC/m² and from 10 to 12 mol/mol, respectively, and were comparable to those measured in surface sediments prior to the hurricane. Such similarities in the composition of the organic matter reinforce the idea that the source of the storm deposits was the finer fraction of resuspended seabed sediments, with little evidence for inputs from local land-derived sources or autochthonous algal production. Overall, the magnitude of sediment and organic matter deposition on the seabed after the storm greatly exceeded the annual inputs from the Atchafalaya River and coastal primary production. The combined effects of hurricane-driven erosion and post-storm deposition represent a major perturbation to the benthic community of the region, which is already subject to these types of disturbances due to the combined effects of peaks in river discharge and the passage of storm fronts.     

Importance of reversible attachment in predicting E. coli transport in saturated aquifers from column experiments

Drinking water wells indiscriminatingly placed adjacent to fecal contaminated surface water represents a significant but difficult to quantify health risk. Here we seek to understand mechanisms that limit the contamination extent by scaling up bacterial transport results from the laboratory to the field in a well constrained setting. Three pulses of Escherichia coli originating during the early monsoon from a freshly excavated pond receiving latrine effluent in Bangladesh were monitored in 6 wells and modeled with a two-dimensional (2-D) flow and transport model conditioned with measured hydraulic heads. The modeling was performed assuming three different modes of interaction of E. coli with aquifer sands: (1) irreversible attachment only (best-fit k_i = 7.6 day⁻¹); (2) reversible attachment only (k_a = 10.5 and k_d = 0.2 day⁻¹); and (3) a combination of reversible and irreversible modes of attachment (k_a = 60, k_d = 7.6, k_i = 5.2 day⁻¹). Only the third approach adequately reproduced the observed temporal and spatial distribution of E. coli, including a 4-log₁₀ lateral removal distance of ∼9 m. In saturated column experiments, carried out using aquifer sand from the field site, a combination of reversible and irreversible attachment was also required to reproduce the observed breakthrough curves and E. coli retention profiles within the laboratory columns. Applying the laboratory-measured kinetic parameters to the 2-D calibrated flow model of the field site underestimates the observed 4-log₁₀ lateral removal distance by less than a factor of two. This is promising for predicting field scale transport from laboratory experiments.     

Response of the radiation belt electron flux to the solar wind velocity: Parameterization by radial distance and energy

The solar wind velocity is the primary driver of the electron flux variability in Earth's radiation belts. The response of the logarithmic flux (“log-flux”) to this driver has been determined at the geosynchronous orbit and at a fixed energy [Baker, D.N., McPherron, R.L., Cayton, T.E., Klebesadel, R.W., 1990. Linear prediction filter analysis of relativistic electron properties at 6.6 RE. Journal of Geophysical Research 95(A9), 15,133–15,140) and as a function of L shell and fixed energy [Vassiliadis, D., Klimas, A.J., Kanekal, S.G., Baker, D.N., Weigel, R.S., 2002. Long-term average, solar-cycle, and seasonal response of magnetospheric energetic electrons to the solar wind speed. Journal of Geophysical Research 107, doi:10.1029/2001JA000506). In this paper we generalize the response model as a function of particle energy (0.8–6.4 MeV) using POLAR HIST measurements. All three response peaks identified earlier figure prominently in the high-altitude POLAR measurements. The positive response around the geosynchronous orbit is peak P₁ (τ=2±1 d; L=5.8±0.5; E=0.8–6.4 MeV), associated with high-speed, low-density streams and the ULF wave activity they produce. Deeper in the magnetosphere, the response is dominated by a positive peak P₀ (0±1 d; 2.9±0.5R_E; 0.8–1.1 MeV), of a shorter duration and producing lower-energy electrons. The P₀ response occurs during the passage of geoeffective structures containing high IMF and high-density parts, such as ICMEs and other mass ejecta. Finally, the negative peak V₁ (0±0.5 d; 5.7±0.5R_E; 0.8–6.4 MeV) is associated with the “D_st effect” or the quasiadiabatic transport produced by ring-current intensifications. As energies increase, the P₁ and V₁ peaks appear at lower L, while the D_st effect becomes more pronounced in the region L<3. The P₀ effectively disappears for E>1.6 MeV because of low statistics, although it is evident in individual events. The continuity of the response across radial and energy scales supports the earlier hypothesis that each of the three modes corresponds to a qualitatively different type of large-scale electron acceleration and transport.     

Embryotoxic and genotoxic effects of heavy metals and pesticides on early life stages of Pacific oyster (Crassostrea gigas)

This study evaluated embryotoxicity and genotoxicity of two dissolved metals copper and cadmium (Cu and Cd) and two pesticides (metolachlor and irgarol) occurring in Arcachon Bay (SW France) in Pacific oyster (Crassostrea gigas) larvae and investigated the relationship between those two endpoints. Embryotoxicity was measured by calculating the percentage of abnormal D-shaped larvae and genotoxicity was evaluated with DNA strand breaks using the comet assay. After 24 h exposure, significant increases of the percentage of abnormal D-larvae and the DNA strand breaks were observed from 0.1 μg L⁻¹ for Cu, 10 μg L⁻¹ for Cd and 0.01 μg L⁻¹ for both irgarol and metolachlor in comparison with the controls. A strong positive relationship between embryotoxicity and genotoxicity was recorded for Cu, Cd and metolachlor. The current study suggests that copper, irgarol and metolachlor can induce larval abnormalities and DNA damage in a population of exposed oysters at environmentally relevant concentrations.