长白山区二道白河流域早更新世玄武质熔岩的成因

采用岩石化学和同位素分析方法,研究了二道白河流域早更新世玄武质熔岩的成因。玄武质熔岩由钠质拉斑玄武岩和钾质粗面玄武岩、玄武质粗面安山岩组成。它们的REE分配形式比较相近,表明它们来自共同的源区。Sr、Nd、Pb同位素示踪表明,二道白河流域早更新世玄武质熔岩岩浆源区接近于似原始地幔。它们的Mg#=100Mg O/(Mg O+Fe O)低于中国东部新生代玄武岩原始岩浆的Mg#(60~68),Ni(27.76×10-6~200.6×10-6)低于原始地幔,Rb/Sr(0.05~0.09)、Ba/Rb(15.64~264)高于原始地幔,说明这些岩石不是源自原始地幔。玄武质熔岩的DI变化于42~67,具有高Ca、高Sr、Eu正异常,微量元素图解显示玄武岩保留部分熔融趋势,粗面玄武岩、玄武质粗安岩具有结晶分异趋势,岩浆上升过程中发生了不同程度的地壳混染作用。玄武质熔岩的Nb/Ta之比为14.8~15.8,与勘察加半岛深俯冲带火山类似。Nb/Ta-(Na2O-K2O)关系图解显示研究区玄武质岩浆的形成与俯冲板片的部分熔融有关。     

中国东部富钾埃达克岩成因的实验约束

Adakite在地球化学上具明显特征的火山岩和深成花岗岩类岩石，见于洋内岛孤环境和大陆孤，如安底斯孤。在洋内岛孤，由热的消减的大洋岩石圈熔融形成（叫做“板片熔融”），而在大陆孤，熔融曾发生在构造或岩浆加厚的下地壳底（叫做“下地壳熔融”）。在这两种产状环境中，adakite的鲜明地球化学特征被认为是起因子，一种不同程度含水的变质基性原岩在足够深度上的部分熔融，这里的足够深度是指可使石榴子石在残余结晶组合（即石榴角闪石和/或榴辉石的残余）中保持稳定的深度。“原始”或“母”adakite熔体一旦形成，便可能在其向上运移和侵位上地壳期间受到同化作用（或是地幔，或是大陆物质）和结晶分异作用的改造。中国东部晚中生代（早中白垩世，160-110Ma）的adakite,与见于同一地区和其它地方的钠质adakite相比，通常富含钾(K2O)和其它大离子亲石元素（如Ba,Th,U），有较低的Na2O/K2O比值（-1.0-1.1）,类似于玄武岩在石榴角闪岩-榴辉岩相含水熔融实验中所产生adakite熔体，要么是由洋壳板片熔融所形成，要么是由不同成分的玄武质下地壳原岩部分熔融所形成。尽管有些成分差异，它们的总体化学特征仍然可将中国东部的富钾花岗岩类岩石定均adakite。我们把这些富钾的adakite的独特化学行特征，归因于成分来源的特殊性，或adakite母岩浆遭受了同化混染和结晶分异(AFC)作用的改造。虽然中国东部与消减带环境明显不同这一点表明，那里的adakite可由板块底部侵位的（岩浆加厚的）镁铁质下地壳部分熔融所形成，但燕山运动期间中国东部存在“平坦”俯冲的地球动力学环境是可能被排除的。     

新疆北部的两类埃达克岩

新疆北部有两类埃达克岩，一是俯冲型，形成于早、中泥盆世-早石炭世晚期（≥320Ma），包括了埃达克岩、富Nb玄武岩、高（富）Mg安山岩。第二类埃达克岩是底侵型，形成于中晚二叠世（≤280Ma）。第一类埃达克岩分布于西天山的阿拉套山、博罗科努山，中天山的骆驼沟和巴仑台，东天山的土屋-延东，阿尔泰山陆缘南富蕴-青河南，准噶尔盆地中部陆梁，克拉玛依等地。在阿尔泰陆缘南，苦橄岩与埃达克岩、富Nb玄武岩和高（富）Mg安山岩密切组合。第二类埃达克岩分布于西天山的阿吾拉勒山和东天山的三岔口，未发现富Nb玄武岩和高（富）Mg安山岩组合。俯冲型埃达克岩、富Nb玄武岩和高（富）Mg安山岩的高Sr低Y、Yb、富Eu及高εNd（t）（＋1．5～＋10．0），低（^87Sr／^86Sr）；（〈0．7070）的同位素组成，均一致表明其源区物质为洋壳板片，部分为地幔楔、弧前棱柱，产于岛弧环境；而底侵型埃达克岩源于底侵的幔源玄武质物质，形成于后造山环境。两类埃达克岩及其组合岩石的地质及地球化学特点，展示了中亚型造山在本区晚古生代陆壳增生作用的多样性：在增生构造过程上，有洋壳板片的斜俯冲、俯冲板片的撕裂、板片窗、俯冲剥蚀及玄武质物质的底侵作用等；在增生方向上，有洋壳板片的侧向斜俯冲，也有玄武质物质垂向上底侵于壳-幔边界；在增生物质上，有洋壳板片、地幔楔、受地幔楔混染的洋壳板片熔体，弧前棱柱、地幔楔受板片熔体交代后形成熔体及底侵的幔源玄武质物质。与两类埃达克岩有关，尤其是第一类埃达克岩及其组合岩石，在本区广泛发育了Cu、Au成矿作用，其中部分达到大型-超大型规模。因此．对埃达克岩及其组合岩石的识别及相关Cu、Au成矿作用的找矿勘探应予以足够重视。     

新疆北部晚古生代埃达克岩、富铌玄武岩组合：古亚洲洋板块南向俯冲的证据

地球化学研究结果表明，新疆北部富蕴县境内的晚古生代下泥盆统托让格库都克组的安山质岩石具有与埃达克岩非常相似的地球化学特征，它们具有较高的Al2O3，Na2O和Sr含量以及Sr/Y比值；明显亏损重稀土和Y，它们的MORB标准化微量元素蛛网图表现为明显的Nb，Ta负异常和Sr正异常，同时强烈亏损高场强元素。与埃达克岩共生的玄武岩的地球化学特征则与富铌玄武岩一致，表现为Si过饱和及富Na的特征，同时具有较高的Nb，TiO2和P2O5含量，并富集高场强元素。由于埃达克岩和富铌玄武岩的形成均与板块俯冲有关，因此，它们的存在表明，古亚洲洋在早-中泥盆世向南(哈萨克斯坦-准噶尔板块)发生了一次洋壳俯冲作用。     

扎河坝蛇绿混杂岩内富铌玄武(安山)岩的地球化学特征及其地质意义

在新疆北部东准噶尔的扎河坝蛇绿混杂岩中发现的富铌玄武（安山）岩,其SiO₂含量介于46.71%~57.65%,TiO₂含量为1.00%~1.76%,与太古代绿岩带内富铌玄武（安山）岩相似,Na₂O含量为3.86%~6.64%,P₂O₅为0.34%~0.82%,明显高于太古代绿岩带富铌玄武（安山）岩。扎河坝富铌玄武岩铌含量介于7.22×10^-6~21.91×10^-6之间,大于7×10^-6,与典型的富铌玄武岩相同。该岩石轻重稀土元素分馏较明显,其分布模式为无明显铕至弱负铕异常的右倾曲线。尽管铌的绝对含量较高,但由于钍和轻稀土元素更加富集,在微量元素蛛网图中扎河坝富铌玄武（安山）岩仍表现为铌的明显亏损,同时高场强元素Zr、Hf及Ti也表现出一定程度的亏损。微量元素地球化学特征显示,扎河坝蛇绿混杂岩内富铌玄武（安山）岩形成于古亚洲洋的洋内弧,它是被埃达克质岩浆交代的地幔楔橄榄岩部分熔融的产物,同时大洋沉积物及俯冲板块释放的流体对成岩作用也有一定的贡献。富铌玄武（安山）岩作为弧前增生楔定位在扎河坝蛇绿混杂岩体内,与早前报道的超高压变质岩共存表明,该蛇绿混杂岩体至少记录了两次性质不同的古亚洲洋洋壳俯冲,这更进一步证实新疆北部晚古生代新增陆壳是古亚洲洋多次俯冲作用的产物。     

北祁连走廊南山西水地区加里东期大野口埃达克质闪长玢岩的成因及其地质意义

北祁连走廊南山北坡西水地区的加里东期大野口岩体中闪长玢岩地球化学的研究表明,该套岩石的SiO_256%,Al_2O_315%,Na_2OK_2O,富集大离子亲石元素和轻稀土元素,具正Eu异常,富集Sr元素、亏损重稀土元素Yb和Y,具有较高的Sr/Y值,表现出明显的埃达克岩的地球化学性质。结合岩体产出的时空位置,认为大野口岩体形成于奥陶纪与板块俯冲作用相关的俯冲洋壳部分熔融和壳幔岩浆混合作用。     

柴北缘东段奥陶纪埃达克岩-富Nb玄武岩:对大陆深俯冲之前大洋俯冲及地壳增生的启示

在柴北缘东段识别出早古生代埃达克岩-富Nb玄武岩的火山岩组合。埃达克岩富Na₂O、贫K₂O,K₂O/Na₂O比值介于0.14~0.43之间;高Sr（614×10^-6~1043×10^-6）,但亏损Y（3.26×10^-6~14.1×10^-6）和Yb（0.33×10^-6~1.46×10^-6）,具有高的Sr/Y比值（44~282）;富集Sr、Ba等大离子亲石元素,亏损Nb、Ta、Ti等高场强元素及Cr、Ni、Co、V等相容元素。富Nb玄武岩富Na₂O、贫K₂O、高TiO₂,其Nb含量较高,介于16.9×10^-6~17.9×10^-6之间,具有高的Nb/Ta、Nb/U、（Nb/La）_N比值,同时富集高场强元素。埃达克岩锆石U-Pb定年得到453±4Ma和457±4Ma的结晶年龄。锆石ε_Hf（t）范围较大,介于3.40~13.23之间,对应的二阶段模式年龄t_DM2介于1059~566Ma之间,显示以新生物质为主的特征。综合研究表明柴北缘东段埃达克岩可能为岛弧环境下俯冲的南祁连大洋板片部分熔融的产物。板片来源的埃达克质熔体交代或与上覆地幔楔橄榄岩反应,导致被交代的地幔橄榄岩部分熔融而形成富Nb玄武质岩浆。柴北缘东段埃达克岩-富Nb玄武岩火山岩组合的厘定表明南祁连洋可能直到~455Ma之前并未完全闭合,同时表明俯冲大洋板片的部分熔融可能是柴北缘早古生代地壳增生的一种重要方式。     

天山北部石炭纪埃达克岩-高镁安山岩-富Nb岛弧玄武质岩：对中亚造山带显生宙地壳增生与铜金成矿的意义

新疆天山北部地区存在有石炭纪的埃达克岩-高镁安山岩-富Nb玄武质岩组合，并且其中许多岩石与铜（金）矿床伴生（如达巴特、阿希、土屋-延东、赤湖，等等）。埃达克岩富钠、高Sr但亏损Y与Yb，无明显Eu-正Eu异常以及正Sr异常与Nb、Ti亏损。高镁安山（闪长）岩是本次研究首次报道的，这些岩石无明显Eu-正Eu异常以及Nb、Ti亏损，普遍具有高的MgO和Cr、Ni含量，其中阿希金矿区一些样品类似于日本西南新生代Setouchi弧火山岩带中的赞岐岩类。富Nb玄武质岩富钠贫钾，具有微弱负．正Ba、Nb和Ti异常以及高的Nb／La比值，不同于大多数正常岛弧玄武岩。天山北部地区石炭纪埃达克岩具有高的8Nd（t）（＋3．4-＋9．0）和低的（^87Sr／^86Sr）i（0．7032—0．7043）。富Nb玄武质岩具有变化的εNd（t）（＋3．6-＋11．6）和（^87Sr／^86Sr）；（0．7007—0．7067）。我们的研究表明，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合可能是“埃达克岩交代的岛弧岩浆岩系列”。埃达克岩最有可能由石炭纪北天山洋的年轻洋壳在俯冲过程中熔融形成。另外，俯冲板片产生的熔体以及所释放的少量流体在上升过程中可能交代地幔楔橄榄岩或与其发生反应：一方面，触发地幔楔橄榄岩发生熔融形成富Nb岛弧玄武质岩；另一方面，地幔组分迅速进入到板片熔体中，导致其地幔组分增加，乃至形成高镁安山岩。因此，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合表明：（1）天山北部地区石炭纪可能为岛弧环境而非裂谷环境；（2）天山地区石炭纪的地壳生长可能以侧向增生为主；（3）除了亏损地幔之外，俯冲洋壳的熔融可能也在地壳的生长中发挥了重要的作用；（4）俯冲板片产生的埃达克质岩浆具有高的氧逸度，而其与地幔楔橄榄岩的强烈相互作用将导致地幔中的金属硫化物分解，成矿金属元素进入到岩浆中。这可能是新疆北部铜金矿化与一些埃达克岩、高镁安山（闪长）岩或富Nb岛弧玄武质岩密切共生的基本原因。     

五大连池等地钾质碱性玄武岩、幔源包体的微量元素特征及成因信息

黑龙江省五大连池、科洛、二克山火山岩的成因,是一个重要而又复杂的问题.作者根据岩相学、地球化学、模式计算等一系列工作,认为这组钾质玄武岩是含金云母的尖晶石二辉橄榄岩低度局部熔融的产物。岩浆在上升过程中,经历了结晶分异和同化混染,从而形成一套具成因联系的新生代大陆板内钾质碱性玄武岩。本文试从微量元素方面对此结论提供证据,并显示钾质熔岩及幔源包体的微量元素特征,由此说明地幔交代作用在钾质系列岩浆形成过程中的重要性。     

大陆板内玄武岩数据挖掘:成分多样性及在判别图中的表现

通常认为,大陆溢流玄武岩(CFB)、裂谷玄武岩(CRB)、板内玄武岩(WPB)均产于板内构造环境,其地球化学特征与OIB类似,源于富集的下地幔,与地幔柱的活动有关。本文利用GEOROC数据库对全球CFB、CRB和WPB数据进行挖掘,发现上述三类玄武岩判别图投图几乎落入了全部的构造环境域,有些甚至主要落入MORB和IAB区,而不是落入WPB区。结果表明原先的玄武岩判别图的判别功能值得商榷,尤其对大陆玄武岩来说,许多判别图都存在问题。全体CFB、CRB和WPB的地球化学成分变化巨大,暗示其源区具有强烈的不均一性:部分CFB、CRB和WPB来自富集的地幔柱,仍然具有经典的OIB的特征;部分来自MORB的源区,与MORB的再循环作用有关;部分来自岛弧岩石圈之下的亏损地幔源区,以强烈亏损Nb-Ta为特征,类似岛弧玄武岩的地球化学特征。许多地区的大陆玄武岩可分为低钛和高钛两类,低钛玄武岩大多是亏损或强烈亏损的,而高钛玄武岩通常是富集型的。本文的研究表明,富集型大陆玄武岩可能来自富集的下地幔,而亏损的和强烈亏损的玄武岩可能来自具有MORB或岛弧特征的软流圈地幔。进一步指出,源区性质可能是大陆玄武岩多样性的主控因素,其次为部分熔融程度、熔融深度、结晶分离、陆壳混染以及AFC过程。     

海南岛北部晚新生代玄武岩成分演化及成因讨论

板内玄武岩通常具有复杂的成分组成和成因过程。海南岛北部（简称“琼北”）自渐新世始逐渐发育了大量板内玄武岩,岩性跨度大,从石英拉斑玄武岩到橄榄拉斑玄武岩,再到碱性橄榄玄武岩和碧玄岩均有分布。对琼北晚新生代玄武岩虽已开展了广泛的研究,但“琼北晚新生代玄武岩的成分随时间演化规律”这一问题却未引起足够的关注。本文从晚更新世道堂组橄榄玄武岩入手,对其开展了细致的岩石学、矿物学和主微量及Sr- Nd- Pb同位素地球化学的研究;并结合文献中琼北其他时代（组）玄武岩的数据,阐述了琼北晚新生代玄武岩成分随时间演化的规律并对其成因进行了探讨。研究发现,自中—上新世到更新世再到全新世,琼北晚新生代玄武岩呈现从碱性玄武岩过渡到拉斑玄武岩再突变到碱性—强碱性系列的演化规律;中—上新世到更新世这一时期的碱性玄武岩和拉斑玄武岩可能形成于石榴子石二辉橄榄岩由低到高程度的部分熔融作用,而全新世碱性岩则更可能形成于石榴子石辉石岩的部分熔融。琼北晚新生代玄武岩的Sr- Nd- Pb同位素组成揭示其源区地幔以PREMA端元为主,但经历了来自古老陆壳的沉积物不同程度的改造作用。采用“海南地幔柱”模型可以较好地解释琼北晚新生代玄武岩的复杂组成和成因。     

黄岩海山链俯冲与吕宋岛斑岩铜金成矿

菲律宾吕宋岛上约5Ma以来的斑岩铜金矿床主要集中在北部的Baguio和Mankayan地区,它们在时空上与黄岩海山链密切相关。1907~2013年间的地震数据表明,在吕宋岛中部(16°N)附近存在地震稀疏带。吕宋岛上的斑岩铜金矿床分布在该地震稀疏带的两侧。收集到的相应时期埃达克岩的Sr/Y-(La/Yb)N、Sr/Y-Y和La/Yb-Yb图解表明,这些埃达克岩几乎都是洋壳部分熔融形成的。与吕宋岛北部侵入型埃达克岩相比,位于16°N附近的埃达克岩具有更高的Sr含量,这可能与南海古扩张脊俯冲撕裂形成的板片窗有关。斜长石是辉长岩的主要矿物之一,因此,撕裂的洋壳边缘的辉长岩层部分熔融,形成具有更高Sr含量的埃达克质岩浆。而位于吕宋岛南部Bataan弧中的埃达克质火山岩,可能是在南海古扩张脊俯冲之前形成的。根据已发表的斑岩铜金矿床数据,Mankayan地区的成矿年龄在约3.5~1.4Ma,Baguio地区的成矿年龄在约3.1~0.5Ma之间,有从北向南变年轻的趋势,这与黄岩海山链沿马尼拉海沟向南迁移一致。此外,吕宋岛北部Mt.Cagua到Baguio之间存在一个延伸了220km的第四纪火山活动的空隙,该区域大部分火山已经在中新世停止活动。这可能是黄岩海山链的俯冲使得俯冲倾角逐渐变缓、挤压加强而导致的。同时期的斑岩铜矿床正好分布在这一火山空隙中,是俯冲洋壳部分熔融的产物。     

Triassic Nb-enriched basalts, magnesian andesites, and adakites of the Qiangtang terrane (Central Tibet): evidence for metasomatism by slab-derived melts in the mantle wedge

New chronological, geochemical, and isotopic data are reported for Triassic (219–236 Ma) adakite-magnesian andesite-Nb-enriched basaltic rock associations from the Tuotuohe area, central Qiangtang terrane. The adakites and magnesian andesites are characterized by high Sr/Y (25–45), La/Yb (14–42) and Na₂O/K₂O (12–49) ratios, high Al₂O₃ (15.34–18.28 wt%) and moderate to high Sr concentrations (220–498 ppm) and ε_ND (t) (+0.86 to +1.21) values. Low enrichments of Th, Rb relative to Nb, and subequal normalized Nb and La contents, and enrichments of light rare earth elements combine to distinguish a group of Nb-enriched basaltic rocks (NEBs). They have positive ε_ND (t) (+2.57 to +5.16) values. Positive correlations between Th, La and Nb and an absence of negative Nb anomalies on mantle normalized plots indicate the NEBs are products of a mantle source metasomatized by a slab melt rather than by hydrous fluids. A continuous compositional variation between adakites and magnesian andesites confirms slab melt interaction with mantle peridotite. The spatial association of the NEBs with adakites and magnesian andesites define an “adakitic metasomatic volcanic series” recognized in many demonstrably subduction-related environments (e.g., Mindanao arc, Philippines; Kamchatka arc, Russia; and southern Baja California arc, Mexico). The age of the Touhuohe suite, and its correlation with Triassic NEB to the north indicates that volcanism derived from subduction-modified mantle was abundant prior to 220 Ma in the central Qiangtang terrane.     

Origin of high field strength element enrichment in volcanic arcs: Geochemical evidence from the Sulu Arc, southern Philippines

Lavas from the Sulu Arc, southern Philippines, exhibit an enrichment in high field strength elements (HFSE) that represents a departure from the typical volcanic arc geochemical signature. It has been postulated that this relative enrichment arises from metasomatism of mantle wedge peridotites by melts derived from the subducting oceanic lithosphere, through formation of amphibole which subsequently breaks down and enriches the mantle source of parental arc magmas in HFSE. Divergent chemical and isotopic characteristics between Sulu Arc HFSE-enriched lavas and the Sulu Sea crust being subducted—the presumed source of slab-derived melts—render it unlikely, however, that HFSE enrichment arises from the influence of such melts. New geochemical data suggest that the varying degrees of HFSE enrichment in Sulu Arc lavas are instead the result of variable amounts of mixing between enriched and depleted mantle end-components—the sources of South China Sea intraplate lavas and Sulu seafloor basalts, respectively—within a compositionally heterogeneous mantle wedge.     

Isotope geochemistry of Jeongok basalts,northernmost South Korea: Implications for the enriched mantle end-member component

South Korea separates two mantle source domains for Late Cenozoic intraplate volcanism in East Asia: depleted mid-ocean-ridge basalt (MORB) mantle-enriched mantle type 1 (DMM-EM1) in the north and DMM-EM2 in the south. We determined geochemical compositions, including Sr, Nd, Pb, and Hf isotopes for the Jeongok trachybasalts (∼0.51 to 0.15 Ma K–Ar ages) from northernmost South Korea, to better constrain the origin and distribution of the enriched mantle components. The Jeongok basalts exhibit light rare earth element (LREE)-enriched patterns ([La/Yb]_N = 9.2–11.6). The (La/Yb)_N ratios are lower than that of typical oceanic island basalt (OIB). On a primitive mantle-normalized incompatible element plot, the Jeongok samples show OIB-like enrichment in highly incompatible elements. However, they are depleted in moderately incompatible elements (e.g., La, Nd, Zr, Hf, etc.) compared with the OIB and exhibit positive anomalies in K and Pb. These anomalies are also prime characteristics of the Wudalianchi basalts, extreme EM1 end-member volcanics in northeast China. We have compared the geochemistry of the Jeongok basalts with those of available Late Cenozoic intraplate volcanic rocks from East Asia (from north to south, Wudalianchi, Mt. Baekdu and Baengnyeong for DMM-EM1, and Jeju for DMM-EM2). The mantle source for the Jeongok volcanics contains an EM1 component. The contribution of the EM1 component to East Asian volcanism increases toward the north, from Baengnyeong through Jeongok to Mt. Baekdu and finally to Wudalianchi. Modeling of trace element data suggests that the Jeongok basalts may have been generated by mixing of a Wudalianchi-like melt (EM1 end-member) and a melt that originated from a depleted mantle source, with some addition of the lithospheric mantle beneath the Jeongok area. In Nd–Hf isotope space, the most enriched EM1-component-bearing Jeongok sample shows elevation of ¹⁷⁶Hf/¹⁷⁷Hf at a given ¹⁴³Nd/¹⁴⁴Nd compared with OIB. Recycled pelagic sediments may explain the EM1-end-member component of northeastern Asian volcanism, possibly from the mantle transition zone.     

Multiple ophiolite generation preserved in the northern Philippines and the growth of an island arc complex

Although all oceanic arcs grow through the addition of subduction-generated magmas, the geology of the northern Philippines demonstrates that a major contribution to arc crustal growth can come from repeated, episodic, intra-arc, back-arc, and/or fore-arc oceanic crust generation with subsequent preservation of the basic–ultrabasic units in the arc complex. At least five episodes of oceanic crust generation are represented in the northern Philippines by preserved ophiolitic sequences and recent intra-arc seafloor spreading. Each episode is distinct in age as confirmed by modern dating techniques, with the ages ranging from pre(?)-Jurassic to Quaternary. Although the Philippines is widely regarded as an amalgamation of allochthonous terranes, a review of the available data shows that there is currently no compelling evidence that these ophiolites are of exotic origin and that they have been tectonically accreted to the Philippine arc complex. Rather, the evidence suggests that most—and possibly all—of the ophiolites were generated as back-arc, fore-arc, or intra-arc crust within the Philippine arc complex. Hence, there is a close spatial association of several ophiolitic terranes of diverse ages spanning 150 Myr that formed as part of the arc complex. Such an association may have arisen from episodic generation of oceanic crust during periods of local extension in a suprasubduction zone setting, which has experienced changing and possibly overlapping subduction from the east and west sides (in the current reference frame). Disruption of the ophiolitic basement terranes has been, and continues to be, effected primarily by wrench faulting. This style of arc growth has implications for the paleotectonic interpretation of ancient ophiolite-arc terranes in continents and the petrologic evolution of island arcs.     

Early Cretaceous high-Mg adakites associated with Cu-Au mineralization in the Cebu Island,Central Philippines: Implication for partial melting of the paleo-Pacific Plate

Early Cretaceous arc volcanic rocks, diorite intrusions and an associated large porphyry deposit occur in the Cebu Island, Central Philippines. In this paper, we studied the diorite porphyries associated with Cu-Au mineralization in the Kansi region, where Early Cretaceous arc volcanic rocks are widely distributed. Zircon U-Pb age reveals that the diorites were formed at ca. 110 Ma, close to the formation age of Lutopan diorites in the famous Atlas porphyry Cu-Au deposit (109–101 Ma), and younger than those of the arc volcanics in this region (126–118 Ma). The Kansi diorites and Lutopan diorites are both calc-alkaline high-Mg adakites with high Sr/Y ratios. Their major elements define similar variation trends in Harker diagrams, suggesting that they were probably generated from a uniform source but experienced different degree of partial melting or fractional crystallization. The Kansi diorites are characterized by LREE enrichment, HREE depletion, no Eu negative anomaly, with enrichment of Pb, Sr, Zr and Hf and depletion of Nb, Ta, and Ti. They are probably generated by the partial melting of subducted oceanic crust, followed by a certain degree of mantle interaction and crustal contamination. The highly depleted Sr-Nd-Pb-Hf isotopes of the Kansi diorites are close to the Amami Plateau basalt and tonalite, indicating the dominance of a Pacific-type MORB in the source. The Cu-Au mineralization-related Kansi diorites are characterized by high oxygen fugacities more than ΔFMQ +2, indicating quite a good potential for porphyry Cu-Au mineralization in the region. Finally, in our tectonic model, the successive generation of arc volcanic rocks and adakites in the Cebu Island are responses to the subduction and rollback of the paleo-Pacific Plate to the proto-Philippine Sea Plate (PSP) in the Early Cretaceous.     

新疆吐哈盆地南缘铜矿带含矿斑岩的地球化学及形成环境

吐哈盆地南缘斑岩铜矿带位于中亚造山带东天山的中段。研究表明该铜矿带含矿斑岩的形成时代可分早石炭世和晚石炭世-早二叠世两期,前者以土屋-延东含矿斜长花岗斑岩为例,形成于与洋壳俯冲有关的岛弧环境,后者以赤湖和三岔口斜长花岗斑岩为例,形成于同碰撞造山的中-晚期。主量、微量元素和Sr—Nd同位素地球化学数据表明,吐哈盆地南缘铜矿带大多数斑岩具有钙碱性和岛弧花岗岩的特征,初始锶比值一般小于0．7046,εNd（t）值为5．3—7．6,反映成岩物质的深源性;进一步可将斑岩划分为埃达克岩和非埃达克岩,其中延东-土屋和三岔口含矿斑岩具有埃达克岩的特征,而赤湖、灵龙、卡拉塔格和垅西矿化斑岩和成矿后斑岩不具埃迭克岩特征。埃迭克岩成因有两种：土屋-延东埃迭克岩为洋壳板片熔融成因,三岔口埃达克岩为加厚下地壳的熔融成因。土屋-延东洋壳熔融埃达克岩的确定,进一步肯定了晚古生代石炭纪吐哈盆地南缘的岛弧环境。研究表明侵位于中亚造山带晚古生代岛弧环境和洋壳熔融成因的埃达克岩最有利于形成大型斑岩铜矿。