P–T evolution and tectonic significance of lawsonite-bearing schists from the eastern segment of the southwestern Tianshan,China

Robust quantification of pressure (P)–temperature (T) paths for subduction-related HP/UHP metamorphic rocks is fundamental in recognizing spatial changes in both the depth of detachment from the down-going plate and the thermal evolution of convergent margin sutures in orogenic belts. Although the Chinese southwestern (SW) Tianshan is a well-known example of an accretionary metamorphic belt in which HP/UHP metabasites occur in voluminous host metasedimentary schists, information about the P–T evolution of these rocks in the eastern segment is limited, precluding a full understanding of the development of the belt as a whole. In this study at Kekesu in the eastern segment of the SW Tianshan, we use microstructural evidence and phase equilibrium modelling to quantify the peak and retrograde P–T conditions from two lawsonite-bearing micaschists and an enclosed garnet–epidote blueschist; for two of the samples we also constrain the late prograde P–T path. In the two micaschist samples, relics of prograde lawsonite are preserved in quartz inclusions in garnet, whereas in the metabasite, polymineralic aggregates included in garnet are interpreted as pseudomorphs after lawsonite. For garnet micaschist TK21, which is mainly composed of garnet, phengite/paragonite, albite, chlorite, quartz and relict lawsonite, with accessary rutile, titanite and ilmenite, the maximum P–T conditions for the peak stage are 18.0–19.0 kbar at 480–485°C. During initial exhumation, the retrograde P–T path passed through metamorphic conditions of 15.0–17.0 kbar at 460–500°C. For garnet–glaucophane micaschist TK33, which is mainly composed of garnet, glaucophane, phengite/paragonite, albite, chlorite, quartz, relict lawsonite and minor epidote, with accessary titanite, apatite, ilmenite and zircon, the maximum P conditions for the peak stage are >24.0 kbar at 400–500°C. During exhumation, the P–T path passed through metamorphic conditions of 17.5–18.5 kbar at 485–495°C and 14.0–17.5 kbar at 460–500°C. For garnet–epidote blueschist TK37, which is mainly composed of garnet, glaucophane, epidote, phengite, chlorite, albite and quartz, with accessary titanite, apatite, ilmenite, zircon and calcite, the prograde evolution passed through metamorphic conditions of ~20.0 kbar at ~445°C to P_max conditions of ~21.5 kbar at 450–460°C and T_max conditions of 19.5–21.0 kbar at 490–520°C. During exhumation, the rock passed through metamorphic conditions of 17.5–19.0 kbar at 475–500°C, before recording P–T conditions of <17.5 kbar at <500°C. These results demonstrate that maximum recorded pressures for individual samples vary by as much as 6 kbar in the eastern segment of the SW Tianshan, which may suggest exhumation from different depths in the subduction channel. Furthermore, the three samples record similar P–T paths from ~17.0 to 15.0 kbar, which suggests they were juxtaposed at a similar depth along the subduction interface. We compare our new results with published information from eclogites in the same area before considering the wider implications of these data for the orogenic development of the belt as a whole.     

P–T evolution of meta-peridotite in the Penjwin ophiolite, northeastern Iraq

The Penjwin meta-peridotite rock represents one of the five main metamorphosed ultramafic bodies in Kurdistan region, Northwest Zagros Thrust Zone. It underwent at least two successively low-retrograde metamorphic events with one progressive one which all modified the original mineralogy and texture of primary dunite and harzburgite. The primary upper mantle mineral assemblage olivine?+?orthopyroxene?+?chromian spinel is replaced by olivine?+?tremolite–actiolite?+?anthopylite?+?talc?+?ferichromite?+?Cr-chlorite assemblage of amphibolite facies. The further retrograde metamorphic amphibolite facies assemblage is replaced by lizardite–chrysotile?+?Cr-chlorite?+?syn-serpentinization Cr-magnetite of lower greenschist facies. Later at the main Zagros thrust fault, low greenschist facies underwent progressive metamorphism due to the local effect of shear stress as a result of the exhumation and obduction of Penjwin ophiolite suite over Merga Red bed series during Tertiary. Lizardite–chrysotile transformed to antigorite and producing antigorite?+?carbonate?+?syn-serpentinization Cr-magnetite?+?Cr-chlorite assemblage of upper greenschist facies. Chromian spinel is concentrically zoned as a result of multi-stages retrogressive metamorphic events, in which the Cr # (Cr/(Cr?+?Al)) increases from core to rim (0.5 to 1). Three zones can be identified from core to rim: The core is primary Al-rich and mantled by ferrichromite of amphibolite facies. The most outer zone of chromian spinel grains is represented by syn-serpentinization Cr-magnetite of greenschist facies.     

Syn-tectonic sedimentary evolution of the Miocene Çatallar Basin,southwestern Turkey

The Çatallar Basin is one of the Miocene basins located in the southern part of the Bey Da?lar? Massif (SW Turkey). This basin has been reinvestigated and new stratigraphic and sedimentological data are now presented. The Çatallar Basin lies in paraconformity on the Bey Da?lar? carbonate platform of Late Cretaceous to Palaeogene age. It consists of an impersistent, shallow-marine carbonate base (Karabay?r formation, Late Oligocene to Early Burdigalian) followed by an onlapping detrital sequence including the Akçay and Ba?beleni formations (Langhian to Serravallian). The Akçay formation mainly contains turbidites in which several debris-flows and olistostromes are intercalated. The lowest debris flows derive from the local carbonate platforms of Cretaceous and Palaeogene age. Higher, the debris flows and olistostromes contain large carbonate blocks deriving from nearby sources (Bey Da?lar? platform carbonates), whereas the accompanying pebbles originate from the allochthonous ophiolitic units located farther to the north (Lycian Nappes) or to the east (Antalya Nappes). The origin of these ophiolitic detritus is a matter of debate. The new data obtained in this study favour a northern origin.     

Petrology and P–T history of the Wutai amphibolites: implications for tectonic evolution of the Wutai Complex,China

The Wutai Complex represents the best preserved granite-greenstone terrane in the North China Craton. The complex comprises a sequence of metamorphosed ultramafic to felsic volcanic rocks, variably deformed granitoid rocks, along with lesser amounts of siliciclastic and carbonate rocks and banded iron formations. Petrological evidence from the Wutai amphibolites indicates four metamorphic evolutionary stages. The M₁ assemblage is composed of plagioclase+quartz+actinolite+chlorite+epidote+biotite+rutile, preserved as mineral inclusions in garnet porphyroblasts. The metamorphic conditions for this assemblage cannot be quantitatively estimated. The M₂ stage is represented by garnet porphyroblasts in a matrix of quartz, plagioclase, amphibole, biotite, rutile and ilmenite. P–T conditions for this assemblage have been estimated using the program Tweequ at 10–12 kbar and 600–650°C. The M₃ assemblage is shown by amphibole+plagioclase±ilmenite symplectic coronas around embayed garnets and yields P–T conditions of 6.0–7.0 kbar and 600–650°C. M₄ is represented by chlorite and epidote rimming garnet, chlorite rimming amphibole and epidote replacing plagioclase under greenschist-facies conditions of 400–500°C and relatively lower pressures. Taken together, the qualitative P–T estimates from M₁ and M₄ and the quantitative P–T estimates from M₂ and M₃ define a clockwise P–T path for the Wutai amphibolites.The estimated P–T path from the four stages suggests that the Wutai Complex underwent initial burial and crustal thickening (M₁+M₂), subsequent isothermal exhumation (M₃), and finally cooling and retrogression (M₄). This tectonothermal path, along with those of the Fuping and Hengshan complexes, which bound the southeast and northwest margins, respectively, of the Wutai Complex, is considered to record the early Paleoproterozoic collision between the eastern and western segments of the North China craton.     

Multiple P–T–d–t paths reveal the evolution of the final Nuna assembly in northeast Australia

The final assembly of the Mesoproterozoic supercontinent Nuna was marked by the collision of Laurentia and Australia at 1.60 Ga, which is recorded in the Georgetown Inlier of NE Australia. Here, we decipher the metamorphic evolution of this final Nuna collisional event using petrostructural analysis, major and trace element compositions of key minerals, thermodynamic modelling, and multi-method geochronology. The Georgetown Inlier is characterised by deformed and metamorphosed 1.70–1.62 Ga sedimentary and mafic rocks, which were intruded by c. 1.56 Ga old S-type granites. Garnet Lu–Hf and monazite U–Pb isotopic analyses distinguish two major metamorphic events (M1 at c. 1.60 Ga and M2 at c. 1.55 Ga), which allows at least two composite fabrics to be identified at the regional scale—c. 1.60 Ga S1 (consisting in fabrics S1a and S1b) and c. 1.55 Ga S2 (including fabrics S2a and S2b). Also, three tectono-metamorphic domains are distinguished: (a) the western domain, with S1 defined by low-P (LP) greenschist facies assemblages; (b) the central domain, where S1 fabric is preserved as medium-P (MP) amphibolite facies relicts, and locally as inclusion trails in garnet wrapped by the regionally dominant low-P amphibolite facies S2 fabric; and (c) the eastern domain dominated by upper amphibolite to granulite facies S2 foliation. In the central domain, 1.60 Ga MP–medium-T (MT) metamorphism (M1) developed within the staurolite–garnet stability field, with conditions ranging from 530–550°C at 6–7 kbar (garnet cores) to 620–650°C at 8–9 kbar (garnet rims), and it is associated with S1 fabric. The onset of 1.55 Ga LP–high-T (HT) metamorphism (M2) is marked by replacement of staurolite by andalusite (M2a/D2a), which was subsequently pseudomorphed by sillimanite (M2b/D2b) where granite and migmatite are abundant. P–T conditions ranged from 600 to 680°C and 4–6 kbar for the M2b sillimanite stage. 1.60 Ga garnet relicts within the S2 foliation highlight the progressive obliteration of the S1 fabric by regional S2 in the central zone during peak M2 metamorphism. In the eastern migmatitic complex, partial melting of paragneiss and amphibolite occurred syn- to post- S2, at 730–770°C and 6–8 kbar, and at 750–790°C and 6 kbar, respectively. The pressure–temperature–deformation–time paths reconstructed for the Georgetown Inlier suggest a c. 1.60 Ga M1/D1 event recorded under greenschist facies conditions in the western domain and under medium-P and medium-T conditions in the central domain. This event was followed by the regional 1.56–1.54 Ga low-P and high-T phase (M2/D2), extensively recorded in the central and eastern domains. Decompression between these two metamorphic events is ascribed to an episode of exhumation. The two-stage evolution supports the previous hypothesis that the Georgetown Inlier preserves continental collisional and subsequent thermal perturbation associated with granite emplacement.     

P–T history of garnet-websterites in the Sharyzhalgai complex,southwestern margin of Siberian craton: evidence for Paleoproterozoic high-pressure metamorphism

The Saramta massif in the Paleoproterozoic Sharyzhalgai complex, the southwestern margin of the Siberian craton, is mainly composed of spinel-peridotites with garnet-websterites; it is enclosed within granitic gneisses and migmatites with mafic intercalations of granulite-facies grade. The garnet-websterites occur as lenses or layers intercalated within spinel-harzburgite and spinel-lherzolite. They consist mainly of clinopyroxene (Cpx), garnet (Grt), and orthopyroxene (Opx): Grt often includes Cpx, Opx, and pargasite (Prg). Opx also occurs as kelyphite with plagioclase (Pl), spinel, olivine, Prg, and biotite. Relationships between textures and chemical compositions of these minerals suggest the following P–T stages: stage 1 (pre-peak), 0.9–1.5 GPa at 640–780 °C; stage 2 (peak), 2.3–3.0 GPa at 920–1030 °C as the minimum estimate; and stage 3 (post-peak), 750–830 °C at 0.5–0.9 GPa. Finally, the garnet-websterites are veined with lower amphibolite- to greenschist-facies minerals (stage 4).These results suggests that the Saramta massif was carried to depths of c. 100 km by subduction, and metamorphosed under eclogite-facies conditions in the Paleoproterozoic, despite the commonly held view that high geothermal gradients in those times would have prevented such deep subduction. Paleoproterozoic plate subduction at the southwestern margin of the Siberian craton might have caused subduction-zone magmatism and mantle metasomatism similar to those in the Phanerozoic.     

Variscan P–T deformation paths from the southwestern Aiguilles Rouges massif (External massif, western Alps) and their implication for its tectonic evolution

Petrological and structural investigations in metapelites and amphibolites were undertaken to unravel the Variscan tectonic and metamorphic evolution of the southwestern Aiguilles Rouges massif. The geometry of planar and linear structures indicates a transpressive deformation regime with a change from predominantly subhorizontal to subvertical movements during its evolution. In metapelite samples from gneiss areas, garnet zonation trends have been correlated with chemical variations in plagioclase and biotite by microstructural observations. Applied conventional cation-exchange and net-transfer geothermobarometers yielded anti-clockwise P–T-deformation paths. Clockwise P–T-deformation paths resulted from (Na, Ca)-amphibole zonations of amphibolite samples from a different lithotectonic unit. Notable differences in P–T conditions and the general shape of P–T paths for the gneisses and amphibolites indicate that the units do not represent a continuous metamorphic zonation and underwent no common tectono-metamorphic evolution throughout the entire deformation. The combination of P–T-deformation paths and structural investigations revealed first-stage thrust tectonics followed by a transpressive deformation which was responsible for the uplift of the southwestern Aiguilles Rouges massif.     

Metamorphic evolution of the Maud Belt: P–T–t path for high-grade gneisses in Gjelsvikfjella,Dronning Maud Land,East Antarctica

A metamorphic petrological study, in conjunction with recent precise geochronometric data, revealed a complex P–T–t path for high-grade gneisses in a hitherto poorly understood sector of the Mesoproterozoic Maud Belt in East Antarctica. The Maud Belt is an extensive high-grade, polydeformed, metamorphic belt, which records two significant tectono-thermal episodes, once towards the end of the Mesoproterozoic and again towards the late Neoproterozoic/Cambrian. In contrast to previous models, most of the metamorphic mineral assemblages are related to a Pan-African tectono-thermal overprint, with only very few relics of late Mesoproterozoic granulite-facies mineral assemblages (M₁) left in strain-protected domains. Petrological and mineral chemical evidence indicates a clockwise P–T–t path for the Pan-African orogeny. Peak metamorphic (M_2b) conditions recorded by most rocks in the area (T = 709–785 °C and P = 7.0–9.5 kbar) during the Pan-African orogeny were attained subsequent to decompression from probably eclogite-facies metamorphic conditions (M_2a).The new data acquired in this study, together with recent geochronological and geochemical data, permit the development of a geodynamic model for the Maud Belt that involves volcanic arc formation during the late Mesoproterozoic followed by extension at 1100 Ma and subsequent high-grade tectono-thermal reworking once during continent–continent collision at the end of the Mesoproterozoic (M₁; 1090–1030 Ma) and again during the Pan-African orogeny (M_2a, M_2b) between 565 and 530 Ma. Post-peak metamorphic K-metasomatism under amphibolite-facies conditions (M_2c) followed and is ascribed to post-orogenic bimodal magmatism between 500 and 480 Ma.     

P–T composition and evolution of paleofluids in the Paleoproterozoic Mag Hill IOCG system,Contact Lake belt,Northwest Territories,Canada

The Echo Bay stratovolcano complex and Contact Lake Belt of the Great Bear Magmatic Zone, Northwest Territories, host a series of coalescing Paleoproterozoic hydrothermal systems that affected an area of several hundred square kilometers. They were caused by intrusion of synvolcanic diorite–monzodioritic plutons into andesitic host rocks, producing several characteristic hydrothermal assemblages. They include early and proximal albite, magnetite–actinolite–apatite, and potassic (K-feldspar) alteration, followed by more distal hematite, phyllic (quartz–sericite–pyrite), and propylitic (chlorite–epidote–carbonate±sericite±albite±quartz) alteration, and finally by late-stage polymetallic epithermal veins. These alteration types are characteristic of iron oxide copper–gold deposits, however, with distal and lower-temperature assemblages similar to porphyry Cu systems. Magnetite–actinolite–apatite alteration formed from high temperature (up to 560 °C) fluids with average salinity of 12.8 wt% NaCl equivalent. The prograde propylitic and phyllic alteration stages are associated with fluids with temperatures varying from 80 to 430 °C and a wide salinity range (0.5–45.6 wt% NaCl equivalent). Similarly, wide fluid temperature (104–450 °C) and salinity (4.2–46.1 wt% NaCl equivalent) ranges are recorded for the phyllic alteration. This was followed by Cu–Ag–U–Zn–Co–Pb sulfarsenide mineralization in late-stage epithermal veins formed at shallow depths and temperatures from 270 °C to as low as 105 °C. The polymetallic veins precipitated from high salinity (mean 30 wt% NaCl equivalent) dense fluids (1.14 g/cm³) with a vapor pressure of 3.8 bars, typical of epithermal conditions. Fluid inclusion evidence indicates that mixed fluids with evolving physicochemical properties were responsible for the formation of the alteration assemblages and mineralization at Mag Hill. An early high temperature, moderate salinity, and magmatic fluid was subsequently modified variably by boiling, mixing with cooler low-salinity meteoric water, and simple cooling. The evidence is consistent with emplacement of the source plutons and stocks into an epithermal environment within ~1 km of surface. This generated near-surface high-temperature alteration in a dynamic hydrothermal system that collapsed (telescoped) resulting in widespread evidence of boiling and epithermal mineralization superimposed on earlier stages of alteration.     

P–T–t evolution of the Cycladic Blueschist Unit in Western Anatolia/Turkey: Geodynamic implications for the Aegean region

Eclogite and blueschist facies rocks occurring as a tectonic unit between the underlying Menderes Massif (MM) and the overlying Afyon Zone/Lycian Nappes and the Bornova Flysch Zone in western Anatolia represent the eastward continuation of the Cycladic Blueschist Unit (CBU) in Turkey. This high-P unit is attributed to the closure of the Pindos Ocean and consists of (a) a Triassic to Upper Cretaceous coherent series derived from passive continental margin sediments and (b) the tectonically overlying Upper Cretaceous Selçuk mélange with eclogite blocks embedded in a pelitic epidote-blueschist matrix. The coherent series has experienced epidote-blueschist facies metamorphism (490 ± 25°C/11.5 ± 1.5 kbar; 38 km depth). ⁴⁰Ar/³⁹Ar white mica and ²⁰⁶Pb/²³⁸U monazite dating of quartz metaconglomerate from coherent series yielded middle Eocene ages of 44 ± 0.3 and 40.1 ± 3.1 Ma for epidote-blueschist facies metamorphism, respectively. The epidote-blueschist facies metamorphism of the matrix of the Selçuk mélange culminates at 520 ± 15°C/13 ± 1.5 kbar, 43 km depth, and is dated at 57.5 ± 0.3–54.5 ± 0.1 Ma (⁴⁰Ar/³⁹Ar phengite). Eclogite facies metamorphism of the blocks (570 ± 30°C/18 ± 2 kbar, 60 km depth) is early Eocene and dated at 56.2 ± 1.5 Ma by ²⁰⁶Pb/²³⁸U zircon. Eclogites experienced a nearly isothermal retrogression (490 ± 40°C/~6 to 7 kbar) during their incorporation into the Selçuk mélange. The retrograde overprints of the coherent series (410 ± 15°C/7 ± 1.5 kbar from Dilek Peninsula and 485 ± 33°C/~6 to 7 kbar from Selçuk–Tire area) and the Selçuk mélange (510 ± 15°C/6 ± 1 kbar) are dated at 35.8 ± 0.5–34.3 ± 0.1 Ma by ⁴⁰Ar/³⁹Ar white mica and 31.6 ± 6.6 Ma by ²⁰⁶Pb/²³⁸U allanite dating methods, respectively. Regional geological constrains reveal that the contact between the MM and the CBU originally formed a lithosphere-scale transform fault zone. ⁴⁰Ar/³⁹Ar white mica age from the contact indicates that the CBU and the MM were tectonically juxtaposed under greenschist facies conditions during late Eocene, 35.1 ± 0.3 Ma.     

The Guarguaraz Complex and the Neoproterozoic–Cambrian evolution of southwestern Gondwana: Geochemical signatures and geochronological constraints

The Guarguaraz Complex, in western Argentina, comprises a metasedimentary assemblage, associated with mafic sills and ultramafic bodies intruded by basaltic dikes, which are interpreted as Ordovician dismembered ophiolites. Two kinds of dikes are recognized, a group associated with the metasediments and the other ophiolite-related. Both have N-MORB signatures, with ε_Nd between +3.5 and +8.2, indicating a depleted source, and Grenville model ages between 0.99 and 1.62 Ga. A whole-rock Sm–Nd isochron yielded an age of 655 ± 76 Ma for these mafic rocks, which is compatible with cianobacteria and acritarchae recognized in the clastic metasedimentary platform sequences, that indicate a Neoproterozoic (Vendian)–Cambrian age of deposition.The Guarguaraz metasedimentary–ophiolitic complex represents, therefore, a remnant of an oceanic basin developed to the west of the Grenville-aged Cuyania terrane during the Neoproterozoic. The southernmost extension of these metasedimentary sequences in Cordón del Portillo might represent part of this platform and not fragments of the Chilenia terrane. An extensional event related to the fragmentation of Rodinia is represented by the mafic and ultramafic rocks. The Devonian docking of Chilenia emplaced remnants of ocean floor and slices of the Cuyania terrane (Las Yaretas Gneisses) in tectonic contact with the Neoproterozoic metasediments, marking the Devonian western border of Gondwana.     

P–T paths and modeling the evolution of metapelitic mineral assemblages in the MnNCKFMASH system: A case of Northern Ladoga area

Phase equilibria in medium-grade metapelites of the Northern Ladoga area are calculated with the pseudosection method and Theriak/Domono software on the basis of zoning in garnets. It is shown that garnet in the staurolite-bearing parageneses crystallized at 520–600°C against the background of a pressure release from 7.0 to 3.5–4.0 kbar. The evolution of the mineral composition of rocks in the course of porphyroblast formation is discussed, placing special emphasis on the comparative analysis of P–T paths of garnet growth under decompression conditions.     

Cadomian volcanosedimentary complexes across the Ediacaran–Cambrian transition of the Eastern Pyrenees,southwestern Europe

International Journal of Earth Sciences - The volcanism hosted by the Ediacaran–Terreneuvian Canaveilles Group of the Eastern Pyrenees displays two distinct geochemical affinities: (1)...     

Tectonic evolution of the southwestern margin of Pangea and its global implications: Evidence from the mid Permian–Triassic magmatism along the Chilean-Argentine border

The tectonic evolution of the southwestern margin of Pangea supercontinent is represented by the extensive late Paleozoic–Triassic magmatism along the southwestern margin of South America, including the Chilean Frontal Andes batholiths as part of the Choiyoi province. Several models have proposed cessation of subduction as the reason behind the vast amounts of felsic magmatism and apparent lack of typical arc magmas. Here, new U-Pb in zircon ages, and geochemical and isotope analyses (Rb-Sr, Sm-Nd, Re-Os) indicate that mid Permian–Triassic granitic magmatism originated in a subduction-related extensional setting (slab rollback). Subduction and anatexis of lower continental crust were the main magma-generation mechanisms, the latter caused by asthenospheric upwelling, decompression and subsequent accumulation of underplated basalts. A comparison with coeval igneous units along the Chilean-Argentine border allows extension of this model from at least 21° to 40°S. The key elements triggering slab rollback are low subduction plate velocities and convergence rates, which can be attributed to the assembly of Pangea supercontinent (mid Permian–Triassic). Therefore, subduction of the oceanic plate beneath South America has been a continuous process from early Paleozoic times onwards—rather than having a period without subduction before the onset of the Andean cycle as previous models have invoked. New geochronological constraints indicate that the peak of the voluminous crustal-derived magmatism and related explosive volcanism (Choiyoi province) was contemporaneous with the emplacement of the Emeishan and Siberian Traps LIPs, potentially conditioning the Earth system for the environmental collapse and biotic crises related to those LIPs. The observed tectonic changes, magmatism and related environmental implications could potentially be linked to the assembly of Pangea supercontinent.