不纯碳酸盐岩的变质作用

不纯碳酸盐岩中的矿物共生组合与变质时的总压和二氧化碳分压密切相关。总压增高促使透闪石、透辉石和橄榄石等矿物生成温度增高。变质过程中岩石中流体成分的变化有两种极端情况,即渗滤作用和缓冲作用。渗滤作用下变质反应,变质矿物界线和变质矿物特征等均与缓冲作用下有所差异,以此可以区别它们。湖北宿松群和河北红旗营子群不纯大理岩是在渗滤作用下变质的。山西五台群板峪口组不纯大理岩是在缓冲加渗滤作用下变质的。     

On the Occurrence and Metamorphism of Late Palaeozoic Extrusive Rocks of Taofu,Sikang

Introduction. General Geology. Metamorphosed Submarine Pyroclastic Rocks of Tiehkuangshan. Rocks of the Taofu Volcanic Series of Waerhkou and Matzukou. Concluding Remarks.     

Oxygen and Carbon Isotope Studies of Contact Metamorphism of Carbonate Rocks

O¹⁸/O¹⁶ and C¹²/C¹³ ratios have been determined for carbonaterocks and coexisting minerals from two contact metamorphic aureolesat Birch Creek, California and Marble Canyon, Texas. The peliticmetasediments and granitic intrusions of the Birth Creek localitywere also analyzed for their O¹⁸/¹⁶ and D/H ratios. Oxygen andcarbon isotope fractionations in coexisting dolomite and calciteare interrelated but show no obvious correlation with sampledistance from the intrusive contact. Small-scale oxygen isotopicexchange effects between rock units are observed within a fewfeet of the intrusive-country rock contacts and the marble-schistcontacts at Birch Creek. Oxygen isotopic temperatures obtainedfrom quartz—biotite fractionations in the biotite schistsof Birch Creek show a systematic decrease with increasing distanceaway from the intrusive contact; the isotopic contact temperatureis calculated to be 535–45°C. Low O¹⁸/¹⁶ and C¹³/¹²ratiosof the contact metamorphic marbles generally correlate wellwith presence of calc-silicate minerals, indicating that theCO₂ liberated during metamorphic decarbonation reactions isenriched in both O¹⁸and C¹² relative to the carbonates. Materialbalance calculations indicate that the liberated CO₂ is about5 per mille richer in O¹⁸ and about 6 per mille richer in C¹³than coexisting calcite.     

福建武夷山脉中段五台——吕梁期变质作用与变质岩

闽赣交界武夷山脉中段里心－－付坊地区,奠基于古岛弧的天井坪组和上坪超单元,五台－吕梁期发生中压区域动力热流变质作用。角闪岩相变质岩主要为片岩、变粒岩夹长石石英岩及斜长角闪岩,其次片麻状石英闪长岩、英云闪长岩等。角闪岩相变质后续有重熔型混合岩化。五台－－吕梁期变质尾声及叠加区域动力变质作用。该区变质作用自始至终,由于４个世代不同样式叠加,形成绚丽的构造景观。     

Osumilite-bearing Granulites in the Eastern Grenville Province, Eastern Labrador, Canada: Mineral Parageneses and Metamorphic Conditions

Osumilite-bearing metasedimentary gneiss occurs in the contactaureole of the Sand Hill Big Pond gabbronorite complex of Labradorianage in eastern Grenville Province, eastern Labrador, Canada.The osumilite (Os) occurs in association with cordierite (Cd),orthopyroxene (Opx), sillimanite (Sil), sapphirine (Sa), spinel(Sp), K-feldspar (Kf), plagioclase (PI), phlogopite (Ph), hematite(Hm),magnetite (Mt), corundum (Co), and quartz (Q) in zones adjacentto the gabbronorite intrusion. The osumilite-in isogard is delineatedat a distance of 1-3km from the intrusive contact. The osumiliteis characterized by enhanced Mg/(Mg + Fe) ratios (0.89-0.92)and relatively high K₂O contents (4. 13-4.78 wt. % ) The compositionalvariation of the osumilite is best understood by the substitutions(Mg+Fe+Mn)+St=2A1 and (K+Na)+(Mg +Fe+Mn)=Al+vacancy. Symplectiticintergrowth of Opx-Cd-Kf-Q, which partly of completely replacedosumilite, is ubiquitously present. The stable osumilite-bearingassemblages (all with Hm, Mt, and P1) deduced from petrographicfeatures and from the phase relations in the KMAS system areOs-Sa-Cd, Os-Cd-Sil-Q, Os-Cd-Kf-Q, Os-Cd-Opx-Q, and Os-Opx-Kf-Q.The saphirine-bearing assemblages are restricted to silica-deficient(quartz-absent) zones of the gnesis, which include Sa-Os-Cd,Sa-Sil-Cd, Sa-Opx-Sp, Sa-Sp-Cd, and Sa-Sp-Co. Orthopyroxenecoronas mantling phologite reflect the breakdown reaction Ph+ Q= Opx+Kf+vapor under extremely low water activity in thevapour. Petrogenetic grids in MAS, KMAS, and KMAS-H₂O-CO₂appropriateto the mineral assemblages in the metasedimentary gneisses suggestthat the changes of the mineral assemblages in the area studiedreflect dehydration reactions Ph+Sil+Q=Cd+Kf+V and Ph+Q=Opx+Kf+V, and osumilite and sapphirine-forming reactions Opx+Cd+Kf+Q=Os,Cd+Kf+Q=Os+Sil+, Opx+Sil+Kf=Os+Sa, and Opx+Sil =Sa+ Cd. Relativelyhigh Mg/(Mg+Fe²⁺) (0. 64-0.88) in the whole-rock compositionand high oxygen fugacity (near hematite-magnetite buffer), togetherwith exceptionally high temperature ( 1000?C) and extremelylow water activity (0.2) at peak meta-morphic conditions mightstabilize the osumilite- and sapphirine-bearing assemblagesat middle or lower crustal levels. Relatively low water activityis probably caused by the relatively dry precursor, which hadbeen metamorphosed at upper amphibolite facies metamorphic conditionsbefore gabbronorite emplacement.     

Carbon and Oxygen Isotopic Compositions of Carbonates from Precambrian Apatite-Bearing Carbonate Rocks of the Aldan Shield

Geostructural setting, as well as mineral and isotopic compositions, of separate apatite deposits and occurrences in the Aldan Shield composed of Precambrian metasedimentary apatite–carbonate rocks are considered. In terms of carbon and oxygen isotopic compositions, they differ from other carbonate rocks of the Aldan Shield, including carbonatites and Ca–Mg metasomatites, and resemble Phanerozoic and Precambrian metasedimentary carbonates. They formed in oxidizing conditions. The contribution of evaporite processes at different stages of their formation is supported by the carbonate enrichment in ¹³C and the presence of sulfates. It was established that apatite–carbonate rocks represent the product of complex alternation of sedimentary processes at different values of salinity in the basins occasionally characterized by the decomposition of older sediments under subaerial conditions.     

辽宁阜新地区太古宙变质岩变质作用及其演化规律

辽宁阜新地区的"太古宙变质岩"是华北板块北缘太古代的最下部的地体,它由连续性很差的表壳岩、TTG岩石及其他深成侵入岩构成。基本岩石类型包括：角闪石岩、辉石岩、斜长角闪岩、麻粒岩、紫苏花岗岩、片麻岩及少量的磁铁石英岩。主要特征变质矿物由石榴子石（Gr）、斜方辉石（Opx）、单斜辉石（Cpx）、角闪石（Hb）、斜长石（Pl）和石英（Q）。岩相学研究确定了指示变质作用不同阶段的3个变质反应的存在,并且它们与推测的矿物相的转化关系吻合。结合地质温压的限定,笔者得出了该区太古宙末期的强烈的变质热事件的IBC型的PTt演化轨迹,即具有近等压冷却过程。并推测出此变质热事件形成于大量岩浆的板低垫托,同时伴有深部的地壳拉张作用的大地构造环境。     

Pressure--Temperature--Time Paths of Regional Metamorphism II. Their Inference and Interpretation using Mineral Assemblages in Metamorphic Rocks

A companion paper (England & Thompson, 1984a) investigatesthe pressure-temperature-time (PTt) paths followed by rocksundergoing burial metamorphism in continental thickening events.This paper discusses problems involved in inferring such pathsfrom the petrological data available in metamorphic rocks and—oncesuch paths are determined—how they may be interpretedin terms of the thermal budgets of metamorphism. Each of theprincipal facies series (glaucophane-jadeite, andalusite- sillimaniteand kyanite-sillimanite) may be encountered by rocks involvedin the thickening and erosion of continental crust in a regimeof average continental heat flow. The inference of a minimumthermal budget required for a given metamorphism depends stronglyon a knowledge of the PTt paths followed by rocks during themetamorphism. Discrimination between possible thermal regimesis greatly enhanced if portions of PTt paths, rather than singlePT points, are available, and additional constraint is possibleif these paths are supplemented by geochronological, structuraland heat flow data.     

On the Rocks and Metamorphism of Peyinchang Volcanic Series, Kaolan, Kansu

I. INTRODUCTIONIn July, 1946, while investigating the pyrite deposit ot Peyinchang, Kaolan,. Kansu [7], the writer noticed that the country rocks of the deposit, formerly recognized as a series of metamorphosed sedimentary rocks consisting mainly of phyllite, quartzite and schist by Mr. P. Chen [2], and Messrs. N. L. Liu, W. Y. Liang and T. C. Liu [4] who visited there in the years of 1940 and 1944 respectively, are far different in rock character as compared with the doubtless metamorphosed sedimentogenous rocks over-     

塔里木盆地深层碳酸盐岩中不同赋存形式芳烃化合物组成

通过对塔参1井深层（＞5 700 m）碳酸盐岩游离有机质（氯仿沥青“A”）和包裹有机质（氯仿沥青“C”）中芳烃化合物组成和成熟度参数对比研究发现,芳烃化合物组成中菲和二苯并噻吩系列化合物较为丰富,菲和〖JX-*9〗〖XCQQ.TIF;%80%80〗〖JX*9〗等系列化合物丰度随埋深增加而增大,而二苯并噻吩、苯并萘并噻吩和芴等系列化合物丰度表现出相反的规律,这反映出不同芳烃系列化合物在高过成熟阶段热稳定性的差异。同一样品两种赋存形式芳烃化合物组成和成熟度参数明显不同,芳烃化合物成熟度参数和烷基化程度都反映出包裹有机质成熟度低于游离有机质,说明包裹有机质的热演化作用受到了抑制。在高过成熟阶段仍有部分芳烃参数仍可以用来表征深层有机质热演化程度,这些参数包括:菲系列烷基化指标（C1 P /C4 P、C1 P /C3 P、 C2 P /C4 P 、C2 P /C3 P）、以及二苯并噻吩系列化合物中MDR、C1/C3 DBT、2,4/1,4 DMDBT和4,6/1,4 DMDBT参数;虽然DBT/P比值被认为指示沉积环境的有效参数,但塔参1井深层样品研究表明,该参数与热演化程度关系密切,为高过成熟度阶段较好的成熟度参数。      

长白山地区新生代火山岩及其幔源包体的矿物化学及矿物包裹体研究

长白山地区新生代火山岩主要为玄武岩类、粗面岩类和碱性流纹岩类。其中奶头山期碱性玄武岩中含有幔源的尖晶石二辉橄榄岩包体和辉石岩包体。幔源包体及不同期次火山岩的主要矿物是橄榄石、单斜辉石、斜方辉石、尖晶石、斜长石、碱性长石。不同寄主岩石中的矿物组成及其化学成分具有一定的变化，反映了岩浆分异演化的特征；矿物及火山熔岩中的包裹体成分及玻璃熔体结构的激光拉曼光谱分析结果表明，地下深处的岩浆含有较多的挥发分，岩浆上升过程中发生了强烈的出溶作用；岩浆由起源经分异演化上升到地壳浅部直至喷发，幔源的挥发分减少，而浅成或壳源的挥发分增多，特别是在岩浆喷发过程中，地下水或大气成分起了重要作用     

湖北蛇屋山金矿床含金碳酸盐岩风化成矿过程

为阐述含金碳酸盐岩的风化成土过程,以湖北蛇屋山红土型金矿床为例,系统开展了元素地球化学和矿物学研究.研究发现,从风化壳腐泥层→杂色粘土带,碱金属、FeO、MnO、有机碳(Morg)、稀土元素(REE)和高场强元素(HFSE)等元素,以及钾长石、斜长石和黄铁矿等矿物的含量逐渐降低.质量平衡计算表明,风化过程中Si、Fe、...     

青藏高原拉萨地体北部的前寒武纪变质作用及构造意义

青藏高原南部拉萨地体中分布的角闪岩相至麻粒岩相变质岩一直被认为是前寒武纪变质基底,但并没有获得可靠的年代学证据。本文运用原位锆石U-Pb定年方法,在拉萨地体北部那果地区的变质岩中获得了约720Ma的变质年龄,从而证明拉萨地体北部在新古元代经历了角闪岩相变质作用和近同期的岩浆作用。基于这一成果和在拉萨地体中、南部高级变质岩中陆续获得的中、新生代变质年龄,对拉萨地体变质作用的时、空变化及其成因进行了初步探讨。     

Research on Diageneses of Cambrian Shoal Facies Carbonate Rocks in the Xiadong Area, Hubei Province

With continuous outcrops, developed shoal fades rocks, complete types of diagenesis and changeable diagenetic environments, Cambrian strata are well developed in the Xiadong area, Yichang, Hubei Province. Under the combined influence of numerous diageneses, secondary pores can be formed, which result in better reservoir properties of the rock strata.The Cambrian rocks in this area consist of mainly carbonate rocks and secondarily detrital rocks. The carbonate rocks are dominated by grainstones including wormkalk, calcirudite-calcarenite, oolitic limestone and oncolitic limestone. Graded bedding and cross bedding are well developed in the strata, which indicates that the formation environment is of a high-energy shoal facies.In this area, there has developed a sequence of stable Cambrian platform carbonate deposition. The evolution trend is as follows: open sea shelf facies→intertidal low-energy restricted sea facies→Hntertidal high-energy shoal facies→coastal shoal facies→evaporite tidal-flat facies     

云南主要双峰式火山岩及相关矿产资源

云南双峰式火山岩时空分布较为广泛,贯穿云南及整个西南"三江"地区的地质发展演化过程,并伴有各具特色的矿产。本文基于前人的研究资料,总结了云南主要的双峰式火山岩的时空分布和相关矿产资源的情况,并讨论与双峰式火山岩有关的地质构造背景。总结出在地质历史演化过程中,云南主要分布有:(1)元古宙:滇中地区中元古代大红山群、河口群、东川群、昆阳群中的碱性火山岩及细碧-角斑岩类火山岩组合,新元古代与苏雄组同期的双峰式火山岩;(2)早寒武世梅树村期:扬子地台西缘玄武岩和凝灰岩等火山喷发记录;(3)中—晚志留世:滇西普洱大平掌铜多金属矿区大凹子组(S2+3d)细碧岩-石英角斑岩建造;(4)中—晚泥盆世:滇西北德钦羊拉里农组(D2+3l)碎屑岩夹双峰式火山岩+碳酸盐岩;(5)早三叠世:金沙江造山带攀天阁组(T1p)流纹岩+崔依比组(T1c)玄武岩(细碧岩或蚀变玄武岩)组成的"双峰式"火山岩,滇西洱源岩群双峰式火山岩;(6)中—晚三叠世:澜沧江造山带中南段忙怀组(T2m)流纹岩、流纹英安岩、流纹质火山碎屑岩、少量玄武岩和小定西组(T3x)玄武质火山碎屑岩以及芒汇河组(T3mh)玄武岩、流纹质火山碎屑岩组成的双峰式火山岩;(7)古近纪:剑川组(E2j)碱性玄武岩-粗面质火山角砾岩组合等7个阶段的双峰式火山岩,其地质构造背景各异,并伴有各具特色的矿产。这些双峰式火山岩可以作为制约云南及整个西南"三江"地区关键地质演化和成矿事件的标志性地质现象,是研究其地质构造背景和成矿作用的重要依据。     

新矿物——汉江石

新矿物汉江石的理想分子式为Ba2CaV23＋[（Si3AlO10）（OH）2]F（CO3）2。矿物呈黄绿色、深绿色,显微镜下呈浅绿色、淡绿色;单斜晶系,空间群为C2,a=0.52050（12）nm,b=0.9033（2）nm,c=3.2077（8）nm,β=93.49（8）°,V=1.5054（8）nm3,Z=4;二轴晶,正延性,负光性,一组完全解理,干涉色为三级绿,多色性明显,浅绿色-黄绿-深绿色;折射率α=1.615,β=1.655,γ=1.700（589 nm）,2Vobs=114°～115°,2Vcalc=88.8°;显微硬度平均值203 kg/mm2,相当于莫氏硬度4;实测密度平均3.69 g/cm3,计算密度3.78 g/cm3。X射线粉晶衍射的强谱线有1.5866 nm（7）（002）、0.5340 nm（91）（006）、0.4010 nm（10）（ī14）、0.3209 nm（23）（027）、0.2676 nm（100）（ī110）、0.2294 nm（29）（ī37）和0.2008 nm（11）（228）。汉江石的晶体结构由硅酸盐结构单元TOT（二八面体型）和碳酸盐结构单元Ba2Ca（CO3）2F交替组成,可能有3个多型,即1M型,2M型和3T型。     

苏南下三叠统青龙组碳酸盐岩的成岩作用和孔隙演化

苏南下三叠统青龙组碳酸盐岩中,由于沉积相(台地浅难相和深水斜坡-盆地相)的复杂性,导致了成岩作用和成岩环境的多样性。作者通过薄片观察,阴极发光和碳、氧同位素的分析以及孔隙度、渗透率的研究,对该地区胶结作用、白云石化作用、溶解作用等九种成岩作用进行了详细的讨论,并在此基础上建立了相应的成岩作用和孔隙演化的模式。     

赣东北高压变质岩的岩石类型、矿物组成与变质过程

赣东北高压变质岩包括含硬玉霓辉石钠长角闪片岩、含硬玉霓辉石石英钠长石岩、含霓辉石角闪石英钠长石岩、含霓辉石钠长角闪片岩、蓝透闪石石英钠长石岩、镁钠闪石石英钠长石岩等岩石类型，主要组成脏矿物为硬玉、霓辉石、镁钠闪石、蓝透闪石、镁角闪石、阳起石、石英、钠长石、金红石和榍石。研究表明，高压变质峰期后经历了近等温降压退变质过程。     

山东莱芜盆地碳酸盐岩热液溶蚀特征及水文地质意义

鲁中山区莱芜盆地在燕山期发生大规模岩浆侵入活动,岩浆岩体外围碳酸盐岩区分布有水源地、富水块段等岩溶发育富水区,且靠近岩体含水层多发生大理岩化。富含CO₂、H₂S等酸性成分的岩浆热液流体,能对碳酸盐岩产生明显的溶蚀作用。基于岩石样品化学组分分析、水文地质调查及数据统计分析、热液溶蚀地质点详细观测,构建热液溶蚀模式,对莱芜盆地及外围热液溶蚀特征及机理进行研究。结果表明:高温高压岩浆侵入使得接触带碳酸盐岩发生热液变质大理岩化;沿渗透性断裂、裂缝以及不整合面等运移的热液流体,对碳酸盐岩地层产生酸性热液溶蚀和混合溶蚀作用,形成不同规模溶蚀孔洞,构成地下水富集空间,为寻找城镇地下水后备水源地提供新方向。     

Fluid Evolution during HP and UHP Metamorphism in Dabie Shan, China: Constraints from Mineral Chemistry, Fluid Inclusions and Stable Isotopes

The Dabie Shan ultrahigh-pressure (UHP) metamorphic terraneis located in the eastern part of the east–west-strikingQinling–Dabie orogenic belt in China. A major mylonitizedcontact zone of 200–300 m width divides Dabie Shan intothe South Dabie Terrane (SDT) and the North Dabie Complex (NDC).Combined investigation of major and trace element geochemistry,fluid inclusions, and oxygen and hydrogen isotopes constrainsthe fluid history during the metamorphic evolution of the twometamorphic belts, which differ in their fluid and metamorphicevolution. Fluid inclusions in rocks from the SDT are mainlyaqueous with varying salinities, whereas those from the NDCare dominated by CO₂. Low