Influences of catchment characteristics on nitrogen concentration in largely forested streams during the base flow period

Based on measured stream nitrogen concentrations at outlets of 12 small sub‐areas (1·3–54·7 km²) in a largely forested catchment during the base flow period, we investigated the influences of discharges and different catchment characteristics on stream nitrogen concentration. Our field surveys were carried out during the 11‐month's period from April 2001 to February 2002 and the correlations between nitrogen concentrations and catchment characteristics were studied. The results showed that the vegetation cover was strongly correlated to total nitrogen (TN) and nitrate + nitrite ? nitrogen (NO_x‐N) concentrations. That is, the TN and NO_x‐N concentrations had positive correlations with mean normalized difference vegetation cover index (NDVI) of each sub‐area during dormant seasons (mean NDVI < 0 · 70) and had negative correlations during the growing season (mean NDVI ≥ 0 . 70). The significance of catchment characteristics to TN and NO_x‐N concentrations was ranked as vegetation cover > soil > topography > land use, and the best models can account for 55–64% of the variance of TN and NO_x‐N concentrations. Copyright © 2006 John Wiley & Sons, Ltd.     

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.     

Evaluating the impacts of climate change and switchgrass production on a semiarid basin

Climate and land use changes greatly modify hydrologic regimes. In this paper, we modelled the impacts of biofuel cultivation in the US Great Plains on a 1061‐km² watershed using the Soil and Water Assessment Tool (SWAT) hydrologic model. The model was calibrated to monthly discharges spanning 2002–2010 and for the winter, spring, and summer seasons. SWAT was then run for a climate‐change‐only scenario using downscaled precipitation and a projected temperature for 16 general circulation model (GCM) runs associated with the Intergovernmental Panel on Climate Change Special Report on Emission Scenarios A2 scenario spanning 2040–2050. SWAT was also run on a climate change plus land use change scenario in which Alamo switchgrass (Panicum virgatum L.) replaced native range grasses, winter wheat, and rye (89% of the basin). For the climate‐change‐only scenario, the GCMs agreed on a monthly temperature increase of 1–2 °C by the 2042–2050 period, but they disagreed on the direction of change in precipitation. For this scenario, decreases in surface runoff during all three seasons and increases in spring and summer evapotranspiration (eT) were driven predominantly by precipitation. Increased summer temperatures also significantly contributed to changes in eT. With the addition of switchgrass, changes in surface runoff are amplified during the winter and summer, and changes in eT are amplified during all three seasons. Depending on the GCM utilized, either climate change or land use change (switchgrass cultivation) was the dominant driver of change in surface runoff while switchgrass cultivation was the major driver of changes in eT. Copyright © 2014 John Wiley & Sons, Ltd.     

Fluxes of inorganic carbon from two forested catchments in the Appalachian mountains

This study uses long‐term records of stream chemistry, discharge and air temperature from two neighbouring forested catchments in the southern Appalachians in order to calculate production of dissolved CO₂ and dissolved inorganic carbon (DIC). One of the pair of catchments was clear‐felled during the period of the study. The study shows that: (1) areal production rates of both dissolved CO₂ and DIC are similar between the two catchments even during and immediately after the period of clear‐felling; (2) flux of total inorganic carbon (dissolved CO₂+ DIC) rises dramatically in response to a catchment‐wide acidification event; (3) DIC and dissolved CO₂ are dominantly released on the old water portion of the discharge and concentrations peak in the early autumn when flows in the study catchments are at their lowest; (4) total fluvial carbon flux from the clear‐felled catchment is 11·6 t km⁻² year⁻¹ and for the control catchment is 11·4 t km⁻² year⁻¹. The total inorganic carbon flux represents 69% of the total fluvial carbon flux. The method presented in the study provides a useful way of estimating inorganic carbon flux from a catchment without detailed gas monitoring. The time series of dissolved CO₂ at emergence to the stream can also be a proxy for the soil flux of CO₂. Copyright © 2005 John Wiley & Sons, Ltd.     

Modelling the trends of vehicle-emitted pollutants in Salalah,Sultanate of Oman,over a 10-year period

From 2004 to 2014, a significant increase in the number of vehicles in Salalah, Oman, has been observed and is related to the fact that the city has become a more popular tourist destination. Due to this rise in the number of vehicles, traffic jams have become a serious problem in Salalah. Therefore, this study aims to assess carbon monoxide (CO), nitrogen oxides (NO_x), and carbon dioxide (CO₂) from 2004 to 2014 for the Salalah region using the CALPUFF modelling system. Although the number of vehicles gradually increased in the area, the pollutant concentration levels fluctuated. CALPUFF results illustrated that CO levels were within the allowable concentrations assigned by the U.S. Environmental Protection Agency (EPA) standards, but NO_x and CO₂ concentrations were higher than the criterion limits set by the EPA and the Ontario Ministry of the Environment and Climate Change’s emission standards. Since Salalah is a coastal city, wind blowing toward the land from the sea significantly affects the dispersion of pollutants. Additionally, most of the maximum concentrations of the three pollutants were located near the centers of the streets. Replacing roundabouts with flyovers might significantly reduce traffic jams and vehicle-emitted pollutants in Salalah.     

Sensitivity of streamflow simulation in the Delaware River Basin to forecasted land‐cover change for 2030 and 2060

In order to simulate the potential effect of forecasted land‐cover change on streamflow and water availability, there has to be confidence that the hydrologic model used is sensitive to small changes in land cover (<10%) and that this land‐cover change exceeds the inherent uncertainty in forecasted conditions. To investigate this, a 26‐year streamflow record was simulated for 33 basins (54–928 km²) in the Delaware River Basin using three dates of land cover: the 2011 National Land‐Cover Dataset (Homer, Fry, & Barnes, 2012 ), 2030 land‐cover conditions representing median values from 101 equally‐likely forecasts, and 2060 land‐cover conditions corresponding to the same iterations used to represent 2030. Streamflow was simulated using a process‐based hydrologic model that includes both pervious and impervious methods as parameterized by three land‐cover‐based hydrologic response units (HRUs)—forested, agricultural, and developed land. Small, but significant differences in streamflow magnitude, variability, and seasonality were seen among the three time periods—2011, 2030, and 2060. Temporal differences were discernible from the range of conditions simulated with 101 equally likely forecasts for 2030. Development was co‐located with the most frequent landscape components, as characterized by topographic wetness index, resulting in a change in hydrology for each HRU, highlighting that knowing the location of disturbance is key to understanding potential streamflow changes. These results show that streamflow simulation using regional calibration that incorporates land‐cover‐based HRUs can be sensitive to relatively small changes in land‐cover and that temporal trends resulting from land‐cover change can be isolated in order to evaluate other changes that might affect water resources.     

A mass‐balance approach to estimate in‐stream processes in a large river

A mass‐balance approach was used to estimate in‐stream processes related to inorganic nitrogen species (NH₄⁺, NO₂^? and NO₃^?) in a large river characterized by highly variable hydrological conditions, the Garonne River (south‐west France). Studies were conducted in two consecutive reaches of 30 km located downstream of the Toulouse agglomeration (population 760 000, seventh order), impacted by modification of discharge regime and high nitrogen concentrations. The mass‐balance was calculated by two methods: the first is based on a variable residence time (VRT) simulated by a one‐dimensional (1‐D) hydraulic model; the second is a based on a calculation using constant residence time (CRT) evaluated according to hydrographic peaks. In the context of the study, removal of dissolved inorganic nitrogen (DIN) for a reach of 30 km is underestimated by 11% with the CRT method. In sub‐reaches, the discrepancy between the two methods led to a 50% overestimation of DIN removal in the upper reach (13 km) and a 43% underestimation in the lower reach (17 km) using the CRT method. The study highlights the importance of residence time determination when using modelling approaches in the assessment of whole stream processes in short‐duration mass‐balance for a large river under variable hydrological conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

Sources and variability of CO2 in a prealpine stream gravel bar

Gravel bars (GBs) contribute to carbon dioxide (CO₂) emissions from stream corridors, with CO₂ concentrations and emissions dependent on prevailing hydraulic, biochemical, and physicochemical conditions. We investigated CO₂ concentrations and fluxes across a GB in a prealpine stream over three different discharge‐temperature conditions. By combining field data with a reactive transport groundwater model, we were able to differentiate the most relevant hydrological and biogeochemical processes contributing to CO₂ dynamics. GB CO₂ concentrations showed significant spatial and temporal variability and were highest under the lowest flow and highest temperature conditions. Further, observed GB surface CO₂ evasion fluxes, measured CO₂ concentrations, and modelled aerobic respiration were highest at the tail of the GB over all conditions. Modelled CO₂ transport via streamwater downwelling contributed the largest fraction of the measured GB CO₂ concentrations (31% to 48%). This contribution increased its relative share at higher discharges as a result of a decrease in other sources. Also, it decreased from the GB head to tail across all discharge‐temperature conditions. Aerobic respiration accounted for 17% to 36% of measured surface CO₂ concentrations. Zoobenthic respiration was estimated to contribute between 4% and 8%, and direct groundwater CO₂ inputs 1% to 23%. Unexplained residuals accounted for 6% to 37% of the observed CO₂ concentrations at the GB surface. Overall, we highlight the dynamic role of subsurface aerobic respiration as a driver of spatial and temporal variability of CO₂ concentrations and evasion fluxes from a GB. As hydrological regimes in prealpine streams are predicted to change following climatic change, we propose that warming temperatures combined with extended periods of low flow will lead to increased CO₂ release via enhanced aerobic respiration in newly exposed GBs in prealpine stream corridors.     

Effects of land cover change on flood peak discharges and runoff volumes: model estimates for the Nyando River Basin,Kenya

The impacts of historical land cover changes witnessed between 1973 and 2000 on the hydrologic response of the Nyando River Basin were investigated. The land cover changes were obtained through consistent classifications of selected Landsat satellite images. Their effects on runoff peak discharges and volumes were subsequently assessed using selected hydrologic models for runoff generation and routing available within the HEC‐HMS. Physically based parameters of the models were estimated from the land cover change maps together with a digital elevation model and soil datasets of the basin. Observed storm events for the simulation were selected and their interpolated spatial distributions obtained using the univariate ordinary Kriging procedure. The simulated flows from the 14 sub‐catchments were routed downstream afterwards to obtain the accrued effects in the entire river basin. Model results obtained generally revealed significant and varying increases in the runoff peak discharges and volumes within the basin. In the upstream sub‐catchments with higher rates of deforestation, increases between 30 and 47% were observed in the peak discharge. In the entire basin, however, the flood peak discharges and volumes increased by at least 16 and 10% respectively during the entire study period. The study successfully outlined the hydrological consequences of the eminent land cover changes and hence the need for sustainable land use and catchment management strategies. Copyright © 2010 John Wiley & Sons, Ltd.     

Factors controlling nitrogen and dissolved organic carbon exports across timescales in two watersheds with different land uses

Investigating factors controlling the temporal patterns of nitrogen (N) and dissolved organic carbon (DOC) exports on the basis of a comparative study of different land uses is beneficial for managing water resources, especially in agricultural watersheds. We focused our research on an agricultural watershed (AW) and a forested watershed (FW) located in the Shibetsu watershed of eastern Hokkaido, Japan, to investigate the temporal patterns of N and DOC exports and factors controlling those patterns at different timescales (inter‐annual, seasonal, and hydrological event scales). Results showed that the annual patterns of N and DOC exports significantly varied over time and were probably controlled by climate. Higher discharge volumes in 2003, a wet year, showed higher N and DOC loadings in both watersheds. However, this process was also regulated by land use associated with N inputs. Higher concentrations and loadings were shown in the agricultural watershed. At the seasonal scale, N and DOC exports in the AW and the FW were more likely controlled by sources associated with land use. The Total N (TN) and Nitrate‐N (NO₃^?‐N) had higher concentrations during snowmelt season in the AW, which may be attributed to manure application in late autumn or early winter in the agricultural watershed. Concentrations of TN, NO₃^?‐N, dissolved organic nitrogen (DON), and DOC showed higher values during the summer rainy season in the FW, related to higher litter decomposition during summer and autumn and the fertilizer application in the agricultural area during summer. Higher DOC concentrations and loadings were observed during the rainy season in the AW, which is probably attributed to higher DOC production related to temperature and microbial activity during summer and autumn in grasslands. Correlations between discharge and concentrations differed during different periods or in different watersheds, suggesting that weather discharge can adequately represent the fact that N export depends on N concentrations, discharge level, and other factors. The differing correlations between N/DOC concentrations and the Si concentration indicated that the N/DOC exports might occur along different flow paths during different periods. During baseflow, the high NO₃^?‐N exports were probably derived from deep groundwater and might have percolated from uplands during hydrological events. During hydrological events, NO₃^?‐N exports may occur along near‐surface flow paths and in deep groundwater, whereas DOC exports could be related to near‐surface flow paths. At the event scale, the relationships between discharge and concentrations of N and DOC were regulated by antecedent soil moisture (shallow groundwater condition) in each watershed. These results indicated that factors controlling N and DOC exports varied at different timescales in the Shibetsu area and that better management of manure application during winter in agricultural lands is urgently needed to control water pollution in streams. Copyright © 2013 John Wiley & Sons, Ltd.     

Variability and trends in the annual snow‐cover cycle in Northern Hemisphere land areas, 1972–2000

This study investigated variability and trends in the annual snow‐cover cycle in regions covering high‐latitude and high‐elevation land areas in the Northern Hemisphere. The annual snow‐cover cycle was examined with respect to the week of the last‐observed snow cover in spring (WLS), the week of the first‐observed snow cover in autumn (WFS), and the duration of the snow‐free period (DSF). The analysis used a 29‐year time‐series (1972–2000) of weekly, visible‐band satellite observations of Northern Hemisphere snow cover from NOAA with corrections applied by D. Robinson of Rutgers University Climate Laboratory. Substantial interannual variability was observed in WLS, WFS and DSF (standard deviations of 0·8–1·1, 0·7–0·9 and 1·0–1·4 weeks, respectively), which is related directly to interannual variability in snow‐cover area in the regions and time periods of snow‐cover transition. Over the nearly three‐decade study period, WLS shifted earlier by 3–5 days/decade as determined by linear regression analysis. The observed shifts in the annual snow‐cover cycle underlie a significant trend toward a longer annual snow‐free period. The DSF increased by 5–6 days/decade over the study period, primarily as a result of earlier snow cover disappearance in spring. The observed trends are consistent with reported trends in the timing and length of the active growing season as determined from satellite observations of vegetation greenness and the atmospheric CO₂ record. Copyright © 2002 John Wiley & Sons, Ltd.     

Spatio‐temporal patterns of nutrient concentrations and export in a north‐eastern European lowland catchment

In 2002–2004 we undertook six sampling campaigns during representative hydrological stages in a 901 km² Estonian lowland catchment to quantify the spatial and seasonal variability of in‐stream dissolved inorganic nitrogen (DIN) and dissolved reactive phosphorus (DRP) concentrations and to identify the influence of land cover and landscape structure. Using a synoptic approach we mapped concentrations in all stream orders. Using linear regression, the relations between the share of agricultural land and log‐transformed in‐stream concentrations were explored. Both the share of agricultural land in the entire ‘area of influence’ upstream from a sampling location, as well as the share in a 150‐m buffer around the stream were used as linear regression input variables. Log‐transformed DIN and DRP concentration variability was highest for lower order streams, while it averaged out in higher order streams during all seasons. Between‐season variation in export can mainly be attributed to discharge variation. In extremely dry periods, there are no significant relations between land cover/structure and in‐stream ln(DIN) concentrations and only weak relations for ln(DRP) concentrations. In other seasons, the share of agricultural land in the upstream area can explain concentrations in higher order streams better than in lower order streams. The prediction of ln(DIN) concentrations in lower order streams can be improved by using the share of agricultural land in a 150‐m buffer as an input variable. This indicates that hydrological connectivity must be taken into account for lower order streams, while land cover shares are enough to explain concentrations for higher order streams. Copyright © 2009 John Wiley & Sons, Ltd.     

Contemporary rates of chemical denudation and atmospheric CO2 sequestration in glacier basins: an Arctic perspective

This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO₂ drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq⁺ m⁻² a⁻¹ for Svalbard (range: 160–560 Σmeq⁺ m⁻² a⁻¹), which lies within the global range of 94–4200 Σmeq⁺ m⁻² a⁻¹ for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq⁺ m⁻² a⁻¹. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO₂ drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO₂ drawdown lies in the range 110–3000 kg C km⁻² a⁻¹, whilst the range is 110–13000 kg C km⁻² a⁻¹ for the northern hemisphere glacial data set. Transient CO₂ drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO₂ drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.     

Impacts of climate variability on water quality with best management practices in sub‐tropical climate of USA

Efficiency of non‐point source pollution control methods may be altered in future climate. This study investigated climate change impacts on sediment and nutrient transport, and efficiency of best management practices (BMPs), in the Upper Pearl River Watershed (UPRW) in Mississippi. The Soil and Water Assessment Tool was applied to the UPRW using observed flow, sediment and nutrient data. Water quality samples were collected at three US geological survey gauging stations. The model was successfully calibrated and validated for daily time steps (Nash Sutcliffe efficiency and coefficient of determination – R² up to 0.7) using manual and automatic (sequential uncertainty fitting version 2) methods from February 2010 to May 2011. Future weather scenarios were simulated using the LARS‐WG model, a stochastic weather generator, with Community Climate System Model, global climate model, which was developed by the National Center for Atmospheric Research in the USA. On the basis of the Special Report on Emissions Scenarios A1B, A2 and B1 of the Intergovernmental Panel on Climate Change, climate change scenarios were simulated for the mid (2046–2065) and late (2080–2099) century. Effectiveness of four BMPs (Riparian buffer, stream fencing, sub‐surface manure applications and vegetative filter strips) on reducing sediment and nutrient were evaluated in current and future climate conditions. Results show that sediment, nitrogen and phosphorus loadings will be increased up to a maximum of 26.3%, 7.3% and 14.3%, respectively, in future climate conditions. Furthermore, the effectiveness of BMPs on sediment removal will be reduced in future climate conditions, and the efficiency of nitrogen removal will be increased, whereas phosphorus removal efficiency will remain unchanged. Copyright © 2013 John Wiley & Sons, Ltd.     

Mesoscalic estimation of nitrogen discharge via drainage systems

A complex approach has been developed for estimating mesoscalic nitrogen discharges via drainage systems using spatial information about land use, drainage areas, nitrogen balances and soil and site characteristics. Determining the total drainage area involves certain difficulties for larger areas, as on the one hand, the available databases are incomplete, and on the other hand the localisation and digitalisation of large subsurface drainage areas is a very time-consuming process. Knowledge of the history and causes of drainage systems in landscapes is required. To solve this problem a method has been developed to calculate the drainage areas for large catchments. In order to obtain a complete data set of subsurface drainage areas, representative areas were selected to enable the proportion of subsurface drainage area to be determined for various soil and site characteristics. These proportions were extrapolated to the entire area and the approach tested in the Mulde River Catchment Area in Germany.The rate of drained arable land is about 25.2% of the total area, which can be broken down into grassland (19.0%) and arable land (27.4%). The results differ for sandy soils with up to 8% drained areas and 57.8% for stagnant soils. This shows that the proportion of drained land is highly dependent on the nature of the soil in the catchment area, which has profound implications for approaches to nitrogen modelling.Average nitrogen discharge for the whole catchment area via drainage water was 33 kg ha⁻¹ yr⁻¹ in the 1980s and 10 kg ha⁻¹ yr⁻¹ in the 1990s. The nitrogen discharge varies from one soil type to another: in regions with sandy substrate (11,900 ha) discharge was 34 kg ha⁻¹ yr⁻¹ in the 1980s (14 kg ha⁻¹ yr⁻¹ in the 1990s), while in areas with loess lessivé soils (89,200 ha) it was about 26 kg ha⁻¹ yr⁻¹ in the 1980s (9 kg ha⁻¹ yr⁻¹ in the 1990s). The reduction can be explained by the complete change in farming strategy since the demise of the former German Democratic Republic (GDR).The approach shown is well suited to future model approaches on a regional scale. By creating and integrating new data sets derived from modern GIS operations the approach reduces the uncertainty of water and nitrogen modelling. This gives us a better understanding of nitrogen discharges into surface and groundwater and temporal discharge dynamics. The discharge data are highly valuable to predict environmental protection measurements for streams, lakes, coastal waters and groundwaters.     

香港一富营养河港内的底泥耗氧和营养盐释放

Tolo Harbour has received massive discharges of municipal sewage, agricultural wastes and cottage industrial effluents, via three river systems, in the past two decades before the mid Eighties. The Harbour is almost land locked and poorly flushed. The soft sediment acted as a sink for nutrients and organic pollutants. After a decade of efforts in establishing and enforcing water pollution control legislations and upgrading wastewater treatment facilities, the sediments have turned into sources of nutrients and exert a measurable oxygen demand upon the overlying waters. In vitro measurements showed that the sediments oxygen demand (SOD) was between 17.6 and 54.3 mgo₂ · m^-2 · h^-1. The maximum rates of release of ortho-phosphate phosphorus and ammonia nitrogen were 15.0 and 206.0 mg · m^-2 · h^-1, respectively.     

Impact of Hurricane Irene and Tropical Storm Lee on riparian zone hydrology and biogeochemistry

Although riparian zones are well known to reduce nitrogen (N) and phosphorus (P) runoff to streams, they also have the potential to affect greenhouse gas (CO₂, N₂O, and CH₄) fluxes to the atmosphere. Following large storms, soil biogeochemical conditions often become more reduced, especially in oxbow depressions and side channels, which can lead to hot moments of greenhouse gas production. Here, we investigate the impact of the remnants of Hurricane Irene and Tropical Storm Lee on riparian zone hydrology (water table: WT), and biogeochemistry (oxidation‐reduction potential [ORP], dissolved oxygen [DO], NO₃^?, PO₄^3?, CO₂, N₂O, CH₄). Results indicate that large storms have the potential to reset WT levels for weeks to months. Overbank flooding at our site following Irene and Lee led to the infiltration of well‐oxygenated water at depth (higher DO and ORP) while promoting the development of anoxic conditions within soil aggregates near the soil surface (increased N₂O and CH₄ fluxes). A short‐term increase in CO₂ emission was observed following Irene at our site where aerobic respiration was water‐limited. Over a 2‐year period, an oxbow depression exhibited higher WT, higher N₂O and CH₄ fluxes (hot moment), higher CO₂ fluxes (seasonal), and lower NO₃^? concentrations (seasonal) than the rest of the riparian zone. However, neither Irene, nor Lee, nor the oxbow depression significantly impacted PO₄^3?. Dissolved organic carbon, ORP, and DO data illustrate the time‐lag (>20 years) between the creation of an oxbow depression and the development of reducing conditions despite clear differences in riparian zone and oxbow WT dynamics.     

Seasonal δ13CDIC sourcing and geochemical flux in telogenetic epikarst of south-central Kentucky

Telogenetic epikarst carbon sourcing and transport processes and their associated hydrogeochemical responses are complex and dynamic. Carbon dioxide (CO₂) transport rates in the epikarst zone are often driven by hydrogeochemical responses, which influence carbonate dissolution and conduit formation. This study examines the influence of land use on carbon sourcing and carbonate dissolution kinetics through a comparative analysis of separate, but similar, epikarst systems in south-central Kentucky. The use of high-resolution hydrogeochemical data from multiple data loggers and isotope analysis from collected water samples reflects the processes within these epikarst aquifers, which are estimated to contribute significantly to bedrock dissolution. Results indicate that, in an agricultural setting, long-term variability and dissolution is governed by seasonal production of CO₂ . In a more urbanized, shallower epikarst system, land cover may affect CO₂ transport between the soil and underlying bedrock. This concentration of CO₂ potentially contributes to ongoing dissolution and conduit development, irrespective of seasonality. The observed responses in telogenetic epikarst systems seem to be more similar to eogenetic settings, which is suggested to be driven by CO₂ transport occurring independent of high matrix porosity. The results of this study indicate site-specific responses with respect to both geochemical and δ¹³C_DIC changes on a seasonal scale, despite regional geologic similarities. The results indicate that further comparative analyses between rural and urban landscapes in other karst settings is needed to delineate the impact of land use and seasonality on dissolution and carbon sourcing during karst formation processes. © 2019 John Wiley & Sons, Ltd.     

Modelling the effects of land‐use change on water and salt delivery from a catchment affected by dryland salinity in south‐east Australia

A comprehensive framework for the assessment of water and salt balance for large catchments affected by dryland salinity is applied to the Boorowa River catchment (1550 km²), located in south‐eastern Australia. The framework comprised two models, each focusing on a different aspect and operating on a different scale. A quasi‐physical semi‐distributed model CATSALT was used to estimate runoff and salt fluxes from different source areas within the catchment. The effects of land use, climate, topography, soils and geology are included. A groundwater model FLOWTUBE was used to estimate the long‐term effects of land‐use change on groundwater discharge. Unlike conventional salinity studies that focus on groundwater alone, this study makes use of a new approach to explore surface and groundwater interactions with salt stores and the stream. Land‐use change scenarios based on increased perennial pasture and tree‐cover content of the vegetation, aimed at high leakage and saline discharge areas, are investigated. Likely downstream impacts of the reduction in flow and salt export are estimated. The water balance model was able to simulate both the daily observed stream flow and salt load at the catchment outlet for high and low flow conditions satisfactorily. Mean leakage rate of about 23·2 mm year^?1 under current land use for the Boorowa catchment was estimated. The corresponding mean runoff and salt export from the catchment were 89 382 ML year^?1 and 38 938 t year^?1, respectively. Investigation of various land‐use change scenarios indicates that changing annual pastures and cropping areas to perennial pastures is not likely to result in substantial improvement of water quality in the Boorowa River. A land‐use change of about 20% tree‐cover, specifically targeting high recharge and the saline discharge areas, would be needed to decrease stream salinity by 150 µS cm^?1 from its current level. Stream salinity reductions of about 20 µS cm^?1 in the main Lachlan River downstream of the confluence of the Boorowa River is predicted. The FLOWTUBE modelling within the Boorowa River catchment indicated that discharge areas under increased recharge conditions could re‐equilibrate in around 20 years for the catchment, and around 15 years for individual hillslopes. Copyright © 2004 John Wiley & Sons, Ltd.     

Spatial patterns of suspended sediment yields in a humid tropical watershed in Costa Rica

An Erratum has been published for this article in Hydrological Processes 16(5) 2002, 1130–1131. Humid tropical regions are often characterized by extreme variability of fluvial processes. The Rio Terraba drains the largest river basin, covering 4767 km², in Costa Rica. Mean annual rainfall is 3139±419_sd mm and mean annual discharge is 2168±492_sd mm (1971–88). Loss of forest cover, high rainfall erosivity and geomorphologic instability all have led to considerable degradation of soil and water resources at local to basin scales. Parametric and non‐parametric statistical methods were used to estimate sediment yields. In the Terraba basin, sediment yields per unit area increase from the headwaters to the basin mouth, and the trend is generally robust towards choice of methods (parametric and LOESS) used. This is in contrast to a general view that deposition typically exceeds sediment delivery with increase in basin size. The specific sediment yield increases from 112±11·4_sd t km^?2 year^?1 (at 317·9 km² on a major headwater tributary) to 404±141·7_sd t km^?2 year^?1 (at 4766·7 km²) at the basin mouth (1971–92). The analyses of relationships between sediment yields and basin parameters for the Terraba sub‐basins and for a total of 29 basins all over Costa Rica indicate a strong land use effect related to intensive agriculture besides hydro‐climatology. The best explanation for the observed pattern in the Terraba basin is a combined spatial pattern of land use and rainfall erosivity. These were integrated in a soil erosion index that is related to the observed patterns of sediment yield. Estimated sediment delivery ratios increase with basin area. Intensive agriculture in lower‐lying alluvial fans exposed to highly erosive rainfall contributes a large part of the sediment load. The higher elevation regions, although steep in slope, largely remain under forest, pasture, or tree‐crops. High rainfall erosivity (>7400 MJ mm ha^?1 h^?1 year ^?1) is associated with land uses that provide inadequate soil protection. It is also associated with steep, unstable slopes near the basin mouth. Improvements in land use and soil management in the lower‐lying regions exposed to highly erosive rainfall are recommended, and are especially important to basins in which sediment delivery ratio increases downstream with increasing basin area. Copyright © 2001 John Wiley & Sons, Ltd.