重庆洪官渡铝土矿床镓元素地球化学特征及其成矿环境探讨

重庆洪官渡铝土矿床伴生Ga含量普遍超过了工业综合利用指标。Ga与Cr、TiO2呈强正相关,与V呈中等程度的正相关,与Al2O3、Fe2O3不相关。根据Sr/Ba、u/Th、Ga/Al等地球化学指标值特征,判断该铝土矿床的含矿岩系属海陆交互沉积,但以陆相沉积为主;同时,洪官渡铝土矿床是在以淡水作用为主的弱酸性氧化环境的中形成。     

长白山天池老虎洞期火山活动地质特征及成因意义

长白山天池火山老虎洞期火山活动发生在更新世晚期白头山组碱性粗面岩喷发之后,火山活动的产物主要为玄武岩质火山碎屑岩和少量玄武岩质或粗面岩质熔岩;老虎洞组火山岩的稀土元素地球化学特征介于早期玄武岩和气象站组碱流岩两者之间,将二者有机地联系在一起,使整个天池火山岩的演化趋势更加清晰。老虎洞组火山岩的存在充分证明了天池火山的粗面岩类与该区早期的大量玄武岩具有成因联系。长白山天池火山活动的成因并非简单地用西太平洋板块的俯冲作用所能解释的。     

鄂西北碱性火山岩型铌矿床榍石矿物学及对铌富集机理的指示

位于南秦岭武当地区的天宝铌矿床是我国典型的碱性火山岩型铌矿床,但其岩浆成因、演化及成矿机理等方面的研究十分薄弱.天宝碱性火山岩主要分为粗面质岩石和碱性玄武岩两大类,两者在空间上紧密共生.在详细的岩(矿)相学及榍石显微结构研究的基础上,利用LA-ICP-MS分析技术对天宝粗面质火山岩中的榍石进行原位U-Pb定年,并利用E...     

滇东北会泽地区发现铝土质泥岩铜矿

最新研究显示,位于云南会泽县的大黑山层状铜矿的矿化分布于上二叠统峨眉山玄武岩顶部间断面(假整合面)之上的宣威组底部,明显受铝土质泥岩层位的控制.对矿床地质特征的研究及与国内典型砂岩铜矿的对比显示,该矿床在成矿背景、赋矿围岩岩性和成矿地质特征上,有别于中国南方川滇地区的砂岩/页岩铜矿,是一种新的铜矿类型.根据赋矿围岩和沉积层控等宏观地质特征,暂定为"铝土质泥岩铜矿".     

Petrology and petrogenesis of a tertiary bimodal dolerite-peralkaline/subalkaline trachyte/rhyolite dyke association from Lundy,Bristol Channel,UK

The island of Lundy forms the southernmost igneous complex of the British Tertiary Volcanic Province (BTVP) and consists of granite (≈ 90%) emplaced into deformed Devonian sedimentary rocks (Pilton Shale) and associated with a swarm of dykes of dolerite/basalt, minor trachyte and rhyolite composition. The dolerites are of varied olivine basalt composition and are associated with peralkaline trachyte and subalkaline/peralkaline rhyolite with alkali feldspar and quartz ± alkali amphibole ± pyroxene mineralogy. The dyke swarm is therefore an anorogenic bimodal dolerite/basalt–trachyte/rhyolite BTVP association. Although the dyke association is bimodal in major element terms between dolerite/basalt and minor trachyte/rhyolite, the mineralogy and trace element geochemistry indicate that the dykes may be regarded as a cogenetic dolerite—peralkaline trachyte/rhyolite association with minor subalkaline rhyolites. Sr and Nd isotope data indicate derivation of these magmas from a similar BTVP mantle source (with or without minor contamination by Pilton Shale, or possibly Lundy granite). The petrogenesis of the Lundy dyke association is therefore interpreted in terms of extensive fractional crystallization of basaltic magma in a magma chamber of complex geometry below the (exposed) Lundy granite. Fractional crystallization of a representative dolerite magma (olivine ± clinopyroxene ± plagioclase) yields trachyte magma from which the crystallization of alkali feldspar (anorthoclase) ± plagioclase (oligoclase) + Fe–Ti oxide + apatite results in peralkaline rhyolite. Rarer subalkaline rhyolites result from fractionation from a similar dolerite source which did not achieve a peralkaline composition so allowing the crystallization and fractionation of zircon. The basalt–(minor trachyte)/rhyolite bimodality reflects rapid crystallization of basalt magma to trachyte (and rhyolite) over a relatively small temperature interval (mass fraction of melt, F = ≈ 0.15). The rapid high level emplacement of basalt, trachyte and rhyolite dyke magmas is likely to have been associated with the development of a substantial composite bimodal basalt–(minor trachytel)/rhyolite volcano above the BTVP Lundy granite in the Bristol Channel.     

四川攀枝花二叠纪双峰式火山岩地球化学特征及其地质意义

攀枝花二叠纪火山岩发育有玄武岩和粗面岩的基性和碱性两个端元,区域上明显缺失中间过渡类型。玄武岩SiO_2含量处于45.65%~49.32%范围内,粗面岩SiO_2含量介于64.39%~69.17%之间,构成经典的"双峰式"火山岩特征组合。两者均具有富Na、贫K、轻稀土富集、轻重稀土明显分馏的特征。特征微量元素Nb/Ta、Th/Ta、Th/U比值变化相对较小,玄武岩分别为15.16、2.70和4.13,粗面岩分别为15.40、2.55和4.12,显示两者具有相似的地球化学属性。微量元素特征显示,除了Ti和Y等少数高场强元素不协调以外,玄武岩与粗面岩绝大多数微量元素变化规律相似,且Rb、Ce、Y、Nb、Hf、Ta等元素与洋岛玄武岩(OIB)特征一致,说明它们具有地幔柱构造系统下的岩浆属性,岩浆源于石榴石二辉橄榄岩岩石圈地幔的部分熔融。结合前人资料,攀枝花二叠纪双峰式火山岩的厘定,不仅暗示了岩浆形成于拉张的裂谷构造环境,也为西南地区二叠纪峨眉山大火成岩地幔柱成因提供支撑。     

赣东北地区早白垩世火山岩的岩石学及岩石化学特征

岩石学及岩石化学特征表明，赣东北地区早白垩世火山岩及次火山岩主要有：玄武岩、伊丁石化橄榄玄武岩、橄榄玄武粗安岩、粗面玄武岩、安粗岩、粗面英安岩、粗面岩、流纹岩、凝灰岩及花岗斑岩等，可划分为高钾钙碱性、橄榄安粗岩和碱性玄武岩3个系列。高钾钙碱性系列富Si、K，贫Mg、Fe、Ca、Al；橄榄安粗岩系列和碱性玄武岩系列富碱，尤其富K，富Al、Ti，贫Si。相比之下，橄榄安粗岩系列比碱性玄武岩系列更富K、Al、Ti、Si。本区复杂的火山岩很可能是晚中生代时期古太平洋巨大板块中Faralong、Izanagi、Kula等板块相对亚洲大陆走滑和斜向俯冲及在大陆内产生的NE－NNE向平移剪切－伸展拉张的结果。     

Characterization of bauxite deposits from Kachchh Area,Gujarat

The bauxites deposits of Kachchh area in Gujarat are investigated to characterize them based on mineralogical and petrographic studies. The major bauxitic mineral in these occurrences is gibbsite, with minor concentration of boehmite and diaspore. Apart from the bauxitic minerals, the other associate minerals are kaolin, calcite, alunite and the iron ore minerals such as hematite and goethite and titanium rich anatase. The iron ore minerals (hematite and goethite) are 10-50microns in size and are disseminated throughout the oolitic and pisolitic bauxitic minerals. At places the goethite exhibits colloform texture. The preservation of basaltic texture in some of the samples indicate that the insitu nature of these bauxites, which are formed by the alteration of calcic plagioclase from the parent basalt. Although, the basalt occurs as the main parent rock for these bauxites, the presence of calcite in some of the samples represent the possibility of having a limestone parent rock at least in some of the bauxite occurrences.     

重庆银矿垭口铝土矿床镓地球化学特征及成矿环境研究

通过对重庆银矿垭口铝土矿床的研究,发现该矿床中镓含量普遍超过了工业综合利用的最低指标,在含矿岩系中均有分布,且镓和Al₂O₃呈弱的正相关关系。通过Sr与Ba比值推断,矿床以陆相沉积为主,沉积过程中有海水的介入;样品Rb/K值小于标准海洋沉积值（0.006）,属半咸水海陆过渡带沉积~淡水沉积;U/Th比值和V/Cr比值分别在0.1~0.73和0.5~2.04之间,由此可以判别含矿岩系属于典型氧化环境;对Ni/Co比值的计算发现含矿岩系可能在沉积过程中受到了海水的改造;Ga/Al比值变化范围主要在0.53～1.74,成矿介质酸碱度的变化幅度较小;从含矿岩系矿物组合中含黄铁矿、高岭石等矿物可以推断介质为酸性的可能性较大。稀土元素球粒陨石标准化分布模式表明,轻稀土富集,重稀土亏损,据样品统计,δCe<0.95为负异常的4个样品分布在探槽工程底部,0.95<δCe<1.05为正常的样品个数为3,其余19个为正异常,Eu显示为负异常;总体水介质应以淡水为主、基本处于氧化环境、弱酸性介质。因此该矿床是以陆相沉积、淡水作用为主的海陆交互环境。     

贵州务川大竹园铝土矿床伴生镓富集规律及沉积环境特征

通过对贵州务川大竹园铝土矿床的研究,发现矿床中伴生镓的含量普遍超过了工业综合利用的最低指标。Ga在含铝岩系中均有不同程度的分布,Ga与TiO₂、Cr、Zr、Sn呈中等正相关关系,说明Ga可能赋存于含TiO₂、Cr、Zr、Sn的矿物中; Ga与Al₂O₃呈弱正相关关系,说明Ga可能以类质同象的形式存在于Al的化合物中。Sr/Ba=1.09~19.69>1,表明铝土矿形成于海相沉积环境; Th/U=1.72~12.31,表明铝土矿可能风化作用不彻底; Ga/Al=0.45~1.84,表明成矿介质酸碱度的变化幅度较小。从含矿岩系矿物组合中含黄铁矿、高岭石等矿物可以推断介质为酸性的可能性较大; 稀土元素(rare earth element, REE)球粒陨石标准化分布曲线向右倾斜,轻稀土元素(LREE)富集,重稀土元素(HREE)亏损,δCe显示为弱正异常,Ce/Ce^*=1.17~10.17>1,表明铝土矿形成于富氧的沉积环境,δEu显示为负异常,进一步表明成矿是以氧化环境为主。综合分析认为大竹园铝土矿床形成于以海相沉积作用为主的富氧的沉积环境。     

Al speciation in tropical podzols of the upper Amazon Basin: A solid-state Al MAS and MQMAS NMR study

In the upper Amazon Basin, aluminum previously accumulated in lateritic formations is massively remobilised in soils by podzolization and exported in waters. We have investigated the speciation of aluminum in the clay-size fractions of eight horizons of waterlogged podzols lying in a depression of a plateau. The horizons illustrate the main steps involved in the podzolization of laterites. They belong to eluviated topsoil A horizons and illuviated subsoil Bhs, Bh and 2BCs horizons of weakly and better-expressed podzols located at the margin and centre of the depression. For the first time, aluminum speciation is quantitatively assessed in soils by spectroscopic methods, namely FTIR, ²⁷Al magic angle spinning (MAS) and multiple-quantum magic angle spinning (MQMAS), nuclear magnetic resonance (NMR). The results thus obtained are compared to chemical extraction data.Solid-state ²⁷Al MAS NMR spectra enable to distinguish Al bound to organic compounds from that incorporated in secondary mineral phases detected by FTIR. MQMAS experiments additionally show that both chemical shifts and quadrupolar constants are distributed for Al nuclei linked with organic compounds. Similar amounts of chelated Al are obtained from NMR spectra and chemical extractions. The study enables to highlight three major steps in the fate of aluminum. (i) Aluminum is first released by mineral weathering, feeds complexing sites of organic matter and accumulates in subsurface Bhs horizons of weakly expressed podzols (acidocomplexolysis). (ii) Complexes of aluminum with organic matter (Al-OM) then migrate downwards in sandy horizons of better-expressed podzols and accumulate at depth in less permeable 2BCs horizons. (iii) The minor amounts of aluminum present in the 2BCs horizon of the downslope podzol show that aluminum is eventually exported towards the river network, either complexed with organic matter or as Al³⁺ ions after desorption from organic compounds, due to decreasing pH or biodegradation of organic ligands. The direct spectroscopic determination of Al-speciation during the formation of podzolic soils opens new perspectives to trace metal loads in the rivers of the upper Amazon Basin.     

南方红土形成过程及其稀土元素地球化学

南方不同红土的化学蚀变指数(CIA),硅铝系数 、铝铁系数 硅铁铝系数 反映红土的形成经历了脱钙、脱碱基和初级脱硅富铝富铁3个主要的 风化阶段;稀土在前两个阶段中主要发生淋失,而在后一阶段中富集,其配分曲线具Eu亏损的轻稀土显著富集型特征。红土中稀土元素的赋存状态以晶格相为主,主要与基岩密切有关,而其它赋存状态则与红土化过程紧密相连。红土中可溶态稀土含量的高低是风化作用强度的有效指标。     

广东三水盆地始新世火山岩地球化学特征

广东三水盆地的演化伴随着强烈的火山活动.为研究三水盆地各类岩石之间的演化关系, 对在盆地内的玄武岩、粗面岩和流纹岩样品进行常量、微量元素地球化学分析.对样品的地球化学投图表明: 玄武岩样品表现为轻稀土富集的板内玄武岩稀土配分模式, 而其微量元素也具有Nb、Ti富集、Sr弱亏损的特征, 由部分熔融产生;粗面岩与流纹岩样品稀土与微量元素配分模式相似, 两类岩石均经历以斜长石为主的分离结晶过程.华南陆缘在始新世早期处于与红海相似的大陆裂谷环境, 喷发来源于深部软流圈地幔的岩浆, 但在42 Ma之后, 火山活动因区域挤压作用而停止.其后的南海扩张可能是两种作用的叠加影响的结果.      

焙烧-湿法预脱硅工艺处理高硫低铝硅比铝土矿石的试验研究及效果——以贵州务川大竹园铝土矿区矿石为例

DS1试样主要化学成分为Al2O3 64.31%,SiO2 8.92%,A/S 7.11,TS 0.30%;该试样经焙烧-湿法预脱硅处理后,A/S由7.11提高到26.37,Al2O3由63.41%升高到78.53%,TS从0.30%降低到0.11%;焙砂在温度280℃,时间60 min,配料比αk 1.45,碱浓度为220 g/l,石灰添加量4%的最佳溶出条件下,Al2O3的绝对溶出率为95.52%,相对溶出率99.59%;Ga的溶出率91.63%,溶出物在1100℃下锻烧2 h,可获得Al2O3>99%,其他各项指标均优于YS/T274-1998AO-1行业标准的氧化铝产品。     

欧北-大湾地区火山岩储层成因机制的研究

从分布、成分组成、形成机制等几个方面探讨了辽河油田东部凹陷中段最主要的火山岩储层－－粗面岩的成因机制，并对其成为该区良好储层的原因进行了探讨，通过对比说明了另一类火山岩－－玄武岩不含油的原因，并建立了成因模式，最后得出结论：粗面岩呈喷发状态产出，由于其硅质含量高，流动性小，容易在构造高部位形成巨厚的火山岩锥或火山岩钏，从而造成其大部分在水上，结晶较好且储层物性极佳，同时因其裂缝发育，这些因素结合起来使其成为良好的会层。从供油方式来看，其成藏方式属于侧生式，而从生储盖组合方式来看，其属于自生、自储、自盖式成藏组合。同时给出了其成藏模式。     

Karst bauxite deposits in the Zagros Mountain Belt,Iran

More than 190 occurrences of bauxitic–lateritic deposits were investigated in seven areas within the Zagros Simply Folded Mountain Belt in southwestern of Iran. The bauxitic horizons are situated in eroded major NW–SE trending anticlines and occur in karst cavities near or at the boundary between the Sarvak and Ilam Formations. Uplift in the Cenomanian–Turanian period had exposed the Sarvak limestone to karst weathering and, during a period of unconformity, layers of ferruginous–argillaceous limestone debris developed and accumulated on its surface. The ferruginous–argillaceous debris was partly converted to bauxite. Folding and faulting in Oligocene–Miocene time, with ensuing erosion, exposed the bauxitic horizons on the limbs and cores of anticlines. The karst bauxite deposits are probably of authigenic origin, as evidenced by their lithologic associations, textural and mineralogy.     

新疆卡拉麦里姜巴斯套组火山岩地球化学特征与构造意义

通过对新疆卡拉麦里姜巴斯套组火山岩野外地质特征、岩石学和高精度同位素年代学的研究,发现姜巴斯套组火山岩具典型双峰式组合,岩石类型包括玄武岩-酸性火山碎屑岩-玄武粗面安山岩;得到玄武粗面安山岩LA-ICP-MS锆石U-Pb年龄为（319.8±2）Ma（加权均方偏差值为3）,表明姜巴斯套组火山岩形成于早石炭世谢尔普霍夫阶。对火山岩地球化学特征的研究表明,姜巴斯套组火山岩钙碱性系列、高钾钙碱性系列和钾玄岩系列岩石兼而有之,岩石的稀土元素配分曲线均为轻稀土元素富集型,无明显Eu异常,玄武岩和玄武粗面安山岩具有K正异常和Sr负异常,酸性火山碎屑岩表现出Nb、Ta和Ti显著亏损。总体来说,姜巴斯套组火山岩富集大离子亲石元素,相对亏损高场强元素。玄武岩和玄武粗面安山岩表现出大陆裂谷（大陆板内拉张区域）岩石特征;酸性火山碎屑岩表现出岛弧或者活动大陆边缘岩石属性。总之,姜巴斯套组火山岩形成于卡拉麦里洋盆闭合碰撞造山后的拉张伸展环境,卡拉麦里地区在早石炭世末期就进入了碰撞后的陆内伸展拉伸阶段。     

Mineralogical and geochemical evolution of the Bidgol bauxite deposit,Zagros Mountain Belt,Iran: Implications for ore genesis,rare earth elements fractionation and parental affinity

The present study focuses on the Late Cretaceous Bidgol bauxite deposit in the Zagros Simply Fold Belt, SW Iran. The orebody is located in the eroded major NW–SE trending Koh-e-Hosseyn anticline and hosted as discontinuous stratified layers and lenses within the upper member of the Cenomanian–Turonian Sarvak Formation. Detailed mineralogical analysis reveals that diaspore, hematite, goethite, anatase, clinochlore, chamosite, and calcite are the major mineral components accompanied by minor amounts of detrital and REE-bearing minerals such as rutile, zircon and parisite. The ore texture suggest that the bauxite material has an authigenic origin but in some parts it has been transported short distances from a primary in situ environment and redeposited in karstic depressions. The spheroidal pisolites of the Bidgol bauxite formed under conditions of low water activity, favouring the formation of large diaspore cores and a single dry-to-wet climatic fluctuation. The mass change calculations relative to the immobile element Ti show that elements such as Si, Fe, Mg, K, Na and Sr are leached out of the weathered system; Al, Ni, Zr, Ga, Cr and Ba are concentrated in the residual system; and Hf, Ta, Co, Rb, Cs, Be, and U are relatively immobile during the bauxitisation processes. The Nb, Th, Y, V, Sc, Sn and ΣREE are relatively immobile in the initial stage of bauxitisation processes in the bauxite ores, but were slightly mobile at the later stage of bauxitisation. Geochemical data reveal progressive enrichment of the REE and intense LREE/HREE fractionation toward the lower parts of the bauxite profile. Cerium behaves differently from the other REEs (especially LREE) and show positive anomalies in the upper horizons that gradually become negative in the deeper parts of the profile. The distribution and fractionation of trace elements and REEs during the bauxitisation process in the Bidgol deposit are mainly controlled by the presence of REE-bearing minerals, fluctuations in soil solution pH, REE ionization potential and the presence of bicarbonates or organic matter. Geochemical analyses confirm a protolith contribution from the bedrock argillaceous limestone and suggest that the source material for the Bidgol bauxite was provided from a siliciclastic material derived from a continental margin. The mid-Turonian uplift led to the formation of karstic topography, rubbly breccia and a layer of ferruginous–argillaceous debris that was affected by lateritic weathering under humid tropical climate. Subsequently, mobile elements are removed from the profiles, while Al, Fe and Ti are enriched, resulting in the formation of the pristine bauxite materials. When the platform subsided into the water again, the pristine bauxitic materials were partly converted to bauxite. During the exposure of bauxite orebodies on the limbs and crests of anticlines and subsequent eroding and accumulation in the karstic depressions during folding and faulting in Oligocene–Miocene, important factors such as intensity of the weathering, drainage and floating flow may have improved the qualities of the bauxite ores.     

Cenozoic intra-plate magmatism in the Darfur volcanic province: mantle source, phonolite-trachyte genesis and relation to other volcanic provinces in NE Africa

Chemical and Sr, Nd and Pb isotopic compositions of Late Cenozoic to Quaternary small-volume phonolite, trachyte and related mafic rocks from the Darfur volcanic province/NW-Sudan have been investigated. Isotope signatures indicate variable but minor crustal contributions. Some phonolitic and trachytic rocks show the same isotopic composition as their primitive mantle-derived parents, and no crustal contributions are visible in the trace element patterns of these samples. The magmatic evolution of the evolved rocks is dominated by crystal fractionation. The Si-undersaturated strongly alkaline phonolite and the Si-saturated mildly alkaline trachyte can be modelled by fractionation of basanite and basalt, respectively. The suite of basanite–basalt–phonolite–trachyte with characteristic isotope signatures from the Darfur volcanic province fits the compositional features of other Cenozoic intra-plate magmatism scattered in North and Central Africa (e.g., Tibesti, Maghreb, Cameroon line), which evolved on a lithosphere that was reworked or formed during the Neoproterozoic.     

广西平果沉积型铝土矿Ga的分布特征与沉积环境关联性探讨

广西平果上二叠统合山组沉积型铝土矿储量大,并以伴生稀散元素Ga为特色。从主量成分和微量元素角度研究平果铝土矿的地球化学特征、形成环境及其与Ga的相互关联性,对综合回收利用和提升矿床经济价值有重要帮助。通过对整个研究区内均匀采集的18件不同类型的矿石及铝土岩样品进行金属Ga和常量、微量元素测试,经统计学方法计算和相关性图解分析,发现样品中Ga平均含量已达到工业品位（0.002×10-2）。但在不同类型矿石中的富集程度不同:豆鲕粒状铝土矿>致密块状铝土矿>铝土岩。而且Ga含量与Al₂O₃含量呈显著正低相关性;与SiO₂含量呈显著负相关关系;与V含量呈显著正低相关关系;与稀土元素相关性不强,无明显规律性。通过对那豆沉积型铝土矿床古地理环境和不同类型样品Sr/Ba比值、Ga的富集、LREE/HREE比值分析发现:区内沉积型铝土矿主成矿期为较稳定、酸性、潮湿的滨海至浅海相环境;而且从二叠纪合山组早期的滨海相氧化环境逐步过渡到二叠纪合山组后期的浅海相还原环境。矿石类型则由早期的紫红色致密块状矿化变化为青灰色至灰黑色鲕粒状矿化。