Homogeneity of water content in obsidian from the coso volcanic field: Implications for obsidian hydration dating

Users of the obsidian hydration dating method have routinely assumed that artifacts which originate from the same geological flow will be of the same chemical composition and thus hydrate at the same rate under equivalent conditions of temperature and relative humidity. Recent laboratory experimentation into the hydration process has shown that the intrinsic water content of the glass is the dominant factor in establishing the rate of hydration. Water content determinations on a large suite of samples from numerous prehistoric quarries within the Coso volcanic field, California, indicated that water content values, and thus hydration rate, varied significantly on a within flow basis. It is recommended that water determinations be made on individual artifacts prior to obsidian hydration dating. © 1993 John Wiley & Sons, Inc.     

Distribution and sources of obsidian in the Rio Grande gravels of New Mexico

The obsidian in the gravels deposited by the Rio Grande in New Mexico has interested archaeologists of the region, particularly the use of these gravels by prehistoric populations and the implications for obsidian sourcing studies. Previous investigations of Rio Grande gravel obsidian have focused on obsidian in the archaeological record. This study focuses on the natural occurrence and distribution of obsidian in the gravels and the implications for archaeological investigations. Spatial sampling of the gravels clearly indicate that obsidian, as well as other chipped stone material, is not uniformly distributed across the landscape. Geochemical analysis of the obsidian in the gravels establishes the true source constituents for the obsidian present in the gravels. The main source area for obsidian in the Rio Grande gravels is the Jemez Mountains, although some obsidian comes from Grant's Ridge, Polvadera, and No Aqua sources. Sources south of Mount Taylor, such as Red Hill and Mule Creek, do not occur in the Rio Grande gravels of southern New Mexico. © 2000 John Wiley & Sons, Inc.     

The Coso volcanic field reexamined: Implications for obsidian sourcing and hydration dating research

Obsidian from the Coso locality, Inyo County, California, has long been regarded by archaeologists as a single “source.” However, studies by the U.S. Geological Survey have provided evidence of geochemical variability among flows within the volcanic field. to determine whether these geochemical distinctions could be applied productively to archaeological research, nondestructive x-ray fluorescence analyses were conducted on samples recently collected from 15 obsidian-bearing loci. the results of this research show that geochemically distinct varieties of artifact-quality obsidian can be recognized within the Coso volcanic field, and subsequent nondestructive x-ray fluorescence analyses of artifacts from two nearby archaeological sites document that different geochemical varieties of obsidian were used prehistorically to manufacture tools. Implications of these results for studies of prehistoric exchange and obsidian hydration dating are discussed.     

A note on the petrology of some lava types from East New Guinea

Quaternary and upper Tertiary lavas from the volcanic islands along the north coast of east New Guinea consist of pyroxene andesites, andesitic basalts, and basalts; many contain accessory olivine. The lavas of Mts Lamington, Yelia, and Victory, in southeast Papua and New Guinea, are rather more acid hornblende and lamprobolite andesites. Peralkaline obsidian and rhyolite occur at Fergusson and Dobu Islands, east of the Papuan mainland. Chemical analyses show that most of the lavas are of calc‐alkaline type, although some from Karkar and Long Islands appear to have tholeiitic tendencies.     

Las Cargas: Characterization and Prehistoric Use of a Southern Andean Obsidian Source

The importance of obsidian from the northern Patagonian source at Las Cargas is reflected in its early use (∼8000 years B.P.) and extensive geographic diffusion but is nonetheless surprising in light of the source's high altitude (located in the Andes Cordillera), which makes it both difficult to access under ideal conditions and inaccessible for much of the year. Prehistoric use of the Las Cargas source can inform us about mobility, subsistence choices, economics of stone consumption, trade, and territoriality. Here we present the results of various lines of evidence (surface survey, X‐ray fluorescence and instrumental neutron activation analyses, artifact morphometry, and obsidian hydration dating) used to characterize obsidian from Las Cargas and its prehistoric use during the Holocene. Results indicate that Las Cargas obsidian occurs at the source as blocks and nodules, which are chemically homogeneous and of variable quality. Use of the source was nearly continuous through time, and the primary knapping activities performed there were the production of blanks and preparation of cores.     

Obsidian provenancing and magmatic fractionation in central oregon

In many instances, geologically distinct obsidian flows located within even a relatively small geographic area can be uniquely identified by their chemical composition. This happens to be true for several obsidian sources from central Oregon. Internally each obsidian locality is chemically homogeneous, but the obsidian rocks from different collection sites exhibit chemical differences. Based on the geochemical variations and on K/ Ar dating of the end members of the chemical differentiation trend, these differences are related to the fractionation of a single Late Miocene magma chamber, dated at 6.5 Ma. By understanding the underlying causes of the chemical differences, constraints are disclosed that will govern the possible chemical variations of other, as yet unidentified but related obsidian flows. These can be useful for identifying the possible natural sources of obsidian artifacts which do not match known obsidian sources, and for suggesting possible geographic areas where these as yet undiscovered obsidian flows may be found. © 1993 John Wiley & Sons, Inc.     

SEM–EDS analysis of western Mediterranean obsidians: a new tool for Neolithic provenance studies

The contents of Na, Al, Si, K, Ca and Fe of 99 obsidians from the western Mediterranean islands of Lipari, Palmarola, Pantelleria and Sardinia were determined with the energy-dispersive spectrometer of a scanning electron microscope (SEM–EDS). The Na and in a lesser way other elements contents characterize any obsidian source-island. In Sardinia (80 samples), the four Monte Arci obsidian geochemical types can be discriminated from binary diagrams of element contents or by a discriminant analysis based on the six elements measured. It is concluded that SEM–EDS offers a new option for Neolithic obsidian provenance studies in this region. To cite this article: F.-X. Le Bourdonnec et al., C. R. Geoscience 338 (2006).     

Compressional and shear wave velocities of igneous rocks and volcanic glasses to 900° C and 20 kbar

Simultaneous measurements of compressional and shear wave velocities, V_p and V_s, in acidic and basic igneous rocks and volcanic glasses, were made up to 900°C and at 10–20 kbar.The effects of pressure and temperature on V_p and V_s in glasses and glassy rocks change at about 600°C, presumably the glass transition temperature. These effects are directly related to the silica content in the samples. and for obsidian are negative at room temperature and 245°C, but are positive at 655°C. The velocity—pressure relations for obsidian display an obvious hysteresis phenomena. for basalt glass is slightly negative, but is positive for usual substances at room temperature, and for obsidian and glassy andesite are positive up to about 600°C but are negative above that temperature. However, for basalt glass as well as other crystalline rocks, and are negative at all temperatures. Glass once heated above the glass transition temperature T_g under pressure P₁ retains the memory of pressure P₁ after it is cooled down below T_g and while subjected to another pressure P₂. An abrupt shift of the velocities correlating to pressure P₂ occurs when the glass is again heated to T_g. V_p−T and V_s−T relations for obsidian, glassy andesite, and basalt glass clearly exhibit this pressure memory.     

Morphological and geochemical analysis of the Laguna Blanca/Zapaleri obsidian source in the Atacama Puna

This paper describes a large obsidian deposit located along the southern banks of Laguna Blanca, on the eastern slope of the Jarellón volcanic caldera near the Chilean–Bolivian border. The obsidian at this site occurs in flows or sheets of deflated black or reddish to brown pebbles, redeposited on the shores of a lake. Blocks of obsidian are only found around the caldera rim. Here we analyze the shape of the obsidian pebbles and their geochemistry, comparing them with previously published data. The results indicate that the geochemical composition of the samples strongly matches previous analyses of obsidian from cultural contexts. This obsidian source was one of the most important sites of obsidian procurement since at least the Formative Period in the Atacama Puna region. © 2010 Wiley Periodicals, Inc.     

长白山地区黑曜岩地质特征及宝玉石特性研究

长白山位于华北地台东缘,是国内唯一的复合型火山.区内断裂构造发育,火山运动频繁,其独特的中心喷发方式,形成了独具特色的长白山黑曜岩.文章从长白山火山地质特征入手,通过对样品检测、分析研究,揭示了长白山黑曜岩产出特征、高温高压形成机理,及具有高能量、强吸附、弱电磁、富含微量元素的特性,得出了其为国内独有的宝玉石、养生保健石的结论.     

The Pachuca obsidian source,Hidalgo, Mexico: A geoarchaeological perspective

Sierra Las Navajas, known to archaeologists as “the Pachuca obsidian source,” has been a major source of obsidian to Mesoamerican societies for more than 3000 years, producing a fine green obsidian unique in Middle America. It was the primary source of the obsidian that formed the economic backbone of the major sociopolitical centers of Classic period Teotihuacán, epi‐Classic Toltec Tula, and Aztec Tenochtitlán. In this paper, the obsidian of Sierra Las Navajas is discussed in the following contexts: (1) geologically, because the extraordinary quality of the Pachuca obsidian, its ease of extraction, and its distinctive color and chemistry are a direct result of its geologic emplacement; (2) locally, as the different mining localities within Sierra Las Navajas reflect the varying needs of the cultures working them; and (3) globally, as the obsidians of Las Navajas were used in concert with obsidians from other sources, and were traded great distances across Mesoamerica. © 2004 Wiley Periodicals, Inc.     

Natural Obsidian Glass as an External Accuracy Reference Material in Laser Ablation‐Inductively Coupled Plasma‐Mass Spectrometry

Compared with solution ICP‐MS, LA‐ICP‐MS studies have thus far reported comparatively few external reference data for accuracy estimates of experiments. This is largely the result of a paucity of available reference materials of natural composition. Here, we report an evaluation of natural glass (obsidian) as an inexpensive and widely available external reference material. The homogeneity of over forty elements in six different obsidian samples was assessed by LA‐ICP‐MS. Accuracy was tested with two obsidian samples that were fully characterised by electron probe microanalysis and solution ICP‐MS. Laser ablation experiments were performed with a variety of ablation parameters (fluence, spot sizes, ablation repetition rates) and calibration approaches (natural vs. synthetic reference materials, and different internal standard elements) to determine the best practice for obsidian analysis. Furthermore, the samples were analysed using two different laser wavelengths (193 nm and 213 nm) to compare the effect of potential ablation‐related phenomena (e.g., fractionation). Our data indicate that ablation with fluences larger than 6 J cm^?2 and repetition rates of 5 or 10 Hz resulted in the most accurate results. Furthermore, synthetic NIST SRM 611 and 612 glasses worked better as reference materials compared with lower SiO₂ content reference materials (e.g., BHVO‐2G or GOR128‐G). The very similar SiO₂ content of the NIST SRM glasses and obsidian (i.e., matrix and compositional match) seems to be the first‐order control on the ablation behaviour and, hence, the accuracy of the data. The use of different internal standard elements for the quantification of the obsidian data showed that Si and Na yielded accurate results for most elements. Nevertheless, for the analysis of samples with high SiO₂ concentrations, it is recommended to use Si as the internal standard because it can be more precisely determined by electron probe microanalysis. At the scale of typical LA analyses, the six obsidian samples proved to be surprisingly homogenous. Analyses with a spot size of 80 μm resulted in relative standard deviations (% RSD) better than 8% for all but the most depleted elements (e.g., Sc, V, Ni, Cr, Cu, Cd) in these evolved glasses. The combined characteristics render obsidian a suitable, inexpensive and widely available, external quality‐control material in LA‐ICP‐MS analysis for many applications. Moreover, obsidian glass is suited for tuning purposes, and well‐characterised obsidian could even be used as a matrix‐matched reference material for a considerable number of elements in studies of samples with high SiO₂ contents.     

Low-temperature isotopic exchange in obsidian: Implications for diffusive mechanisms

While a great deal is known about the interaction between water and rhyolitic glasses and melts at temperatures above the glass transition, the nature of this interaction at lower temperatures is much more poorly understood. This paper presents the results of a series of isotopic exchange experiments aimed at further elucidating this process and determining the extent to which a point-by-point analysis of the D/H or ¹⁸O/¹⁸O isotopic composition across the hydrated rim on a geological or archaeological obsidian sample can be used as a paleoclimatic monitor. Experiments were performed by first hydrating the glass for 5 days in water of one isotopic composition, followed by 5 days in water of a second composition. Because waters of near end-member compositions were used (nearly pure ¹H₂¹⁶O, ¹H₂¹⁸O, and D₂¹⁶O), the relative migration of each species could be ascertained easily by depth-profiling using secondary ion mass spectrometry (SIMS). Results suggest that, during hydration, both the isotopic composition of the waters of hydration, as well as that of intrinsic water remaining from the initial formation of the glass vary dramatically, and a point-by-point analysis leading to paleoclimatic reconstruction is not feasible.     

Characterization of Iranian Obsidian Artifacts by PIXE and Multivariate Statistical Analysis

It had long been thought that obsidian found in Iranian sites originated from Anatolia and Armenia, but new research has challenged this assumption. In this study, 68 samples of obsidian obtained from an archaeological survey of Nader‐Tepe Aslanduz were analyzed by Proton Induced X‐ray Emission (PIXE). Nader‐Tepe Aslanduz is a tell site west of the city of Aslanduz in the Parsabad county of the Ardebil province in northern Iran. The site was inhabited from the first millennium B.C. to A.D. 17, and its history may extend back to the third or fourth millennium B.C. Our chemical composition results have been combined with obsidian composition data from Turkey and Armenia and subjected to Principal Component Analysis (PCA). This analysis shows that obsidian from each location can be grouped into distinctive classes—the obsidian from Nader‐Tepe Aslanduz is therefore probably derived from volcanic outcrops of the Sahand and Sabalan region. This study has been unable to assign a known source from Anatolia and Armenia for the obsidian of Nader‐Tepe Aslanduz.     

Subsource characterization: Obsidian utilization of subsources of the Coso volcanic field,Coso Junction,California, USA

Six chemical subsource groups were identified in the analysis of 84 obsidian samples collected from subsource locations at Coso volcanic field, California. In prehistoric times, Coso provided obsidian for artifacts found from San Francisco Bay to San Diego to Death Valley to the eastern Mojave Desert. Subsource groups were defined by instrumental neutron activation analysis (INAA) of 29 elements followed by cluster analysis, principal component analysis, and bivariate plotting. The new data are compared to previously published INAA and X‐ray fluorescence data. Characterization of 55 obsidian artifacts from archaeological sites located approximately 100 miles from Coso suggests preferential usage of specific subsources as a function of the directionality of travel. The results are consistent with a bimodal (resident and itinerant) model of procurement. This research illustrates the importance of accurate sourcing of obsidian artifacts when attempting to define subsource usage. © 2004 Wiley Periodicals, Inc.     

Concentration dependence of water diffusion in obsidian and dacitic melts at high-pressures

The diffusion of water in natural obsidian and model dacitic melts (Ab90Di8Wo2, mol %) has been studied at water vapor pressure up to 170 MPa, temperatures of 1200°C, H₂O contents in melts up to ～6 wt % using a high gas pressure apparatus equipped with a unique internal device. The experiments were carried out by a new low-gradient technique with application of diffusion hydration of a melt from fluid phase. The water solubility in the melts and its concentration along $C_{H_2 O} $ diffusion profiles were determined using IR microspectrometry by application of the modified Bouguer-Beer-Lambert equation. A structural-chemical model was proposed to calculate and predict the concentration dependence of molar absorption coefficients of the hydroxyl groups (OH^?) and water molecules (H₂O) in acid polymerized glasses (quenched melts) in the obsidian-dacite series. The water diffusion coefficients $D_{H_2 O} $ were obtained by the mathematical analysis of concentration profiles and the analytical solution of the second Fick diffusion law using the Boltzman-Matano method. It was shown experimentally that $D_{H_2 O} $ exponentially increases with a growth of water concentration in the obsidian and dacitic melts within the entire range of diffusion profiles. Based on the established quantitative correlation between $D_{H_2 O} $ and viscosity of such melts, a new method was developed to predict and calculate the concentration, temperature, and pressure dependences of $D_{H_2 O} $ in acid magmatic melts (obsidian, rhyolite, albite, granite, dacite) at crustal T, P parameters and water concentrations up to 6 wt %.     

Surface chemistry and dissolution kinetics of glassy rocks at 25°C

The weathering rates and mechanisms of three types of glassy rocks were investigated experimentally at 25 °C, pH 1.0 to 6.2, and reaction times as much as to 3 months. Changes in major element chemistry were monitored concurrently as a function of time in the aqueous solution and within the near surface region of the glass. Leach profiles, obtained by a HF leaching technique, displayed near-surface zones depleted in major cations. These zones increased in depth with increasing time and decreasing pH of reactions. Release rates into the aqueous solution were parabolic for Na and K and linear for Si and Al. A coupled weathering model, involving surface dissolution with concurrent diffusion of Na, K, and Al, produced a mass balance between the aqueous and glass phases. Steady state conditions are reached at pH 1.0 after approximately 3 weeks of reaction. Steady-state is not reached even after 3 months at pH 6.2.An interdiffusion model describes observed changes in Na diffusion profiles for perlite at pH 1.0. The calculated Na self-diffusion coefficient of 5 × 10^?19 cm²·s^?1 at 25°C approximates coefficients extrapolated from previously reported high temperature data for obsidian. The self-diffusion coefficient for H₃O⁺, 1.2 × 10^?20 cm²·s^?1, is similar to measured rates of water diffusion during hydration of obsidian to form perlite.     

Structural evolutions of an obsidian and its fused glass by shock-wave compression

Shock-recovery experiments for obsidian and its fused glass have been carried out with pressure up to 35 GPa. Structural evolution accompanying the shock compression was investigated using X-ray diffraction technique, Raman and infrared spectroscopy. The densities of obsidian and its fused glass increased with applied shock pressure up to 25 GPa. Densification reached a maximum of 4.7 and 3.6% for obsidian and its fused glass, respectively. The densification mechanism is attributed to reduction of the T–O–T angle, and changes in ring statistics in the structure. Density reduction observed at greater than 25 GPa of applied shock pressure is due to partial annealing of the high-density glass structures brought by high post-shock residual temperature. The density of fused glass is almost equal to its original value at 35 GPa while the shocked obsidian has a slightly lower value than its original value. Amorphization of crystallites present in the obsidian due to shock compression is probably the cause of the density decrease. The structural evolution observed in shock-compressed obsidian and its fused glass can be explained by densification resulting from average T–O–T angle reduction and increase of small rings, and subsequent structural relaxation by high post-shock temperature at applied shock compression above 25 GPa.     

长白山黑曜岩地质特征与成因浅析

长白山黑曜岩是火山活动的产物,除了具有长白山火山特有的喷出方式,与众不同的地质特征之外,还是长白山历史文化的重要物证.通过化学成分分析、物理性能测试,对长白山黑曜岩的特征、形成、分布及成因进行了初步分析,为了解长白山黑曜岩及今后开发利用提供了依据.     

Successive hydration and dehydration of high-P mafic granofels involving clinopyroxene–kyanite symplectites, Mt Daniel, Fiordland, New Zealand

Three texturally distinct symplectites occur in mafic granofels of the Arthur River Complex at MtDaniel, Fiordland, New Zealand. These include symplectic intergrowths of clinopyroxene and kyanite, described here for the first time. Pods of mafic granofels occur within the contact aureole of the Early Cretaceous Western Fiordland Orthogneiss batholith. The pods have cores formed entirely of garnet and clinopyroxene, and rims of pseudomorphous coarse‐grained symplectic intergrowths of hornblende and clinozoisite that reflect hydration at moderate to high‐P. These hornfelsic rocks are enveloped by a hornblende–clinozoisite gneissic foliation (S1). Narrow garnet reaction zones, in which hornblende and clinozoisite are replaced by garnet–clinopyroxene assemblages, developed adjacent to fractures and veins that cut S1. Fine‐grained symplectic intergrowths of (1) clinopyroxene and kyanite and (2) clinozoisite, quartz, kyanite and plagioclase form part of the garnet reaction zones and partially replace coarse‐grained S1 hornblende and clinozoisite. The development of the garnet reaction zones and symplectites was promoted by dehydration most probably following cooling of the contact aureole. Maps of oxide weight percent and cation proportions, calculated by performing matrix corrections on maps of X‐ray intensities, are used to study the microstructure of the symplectites.