Electromagnetic induction for mapping textural contrasts of mine tailing deposits

Mine tailings present an important legacy of past and present ore-extraction activities in the Desert Southwest. Inactive mine tailings have no immediate economic role in current mining operations, yet from an environmental point of view it is important that such deposits are stabilized to prevent mass movement, wind or water erosion, leaching of chemicals such as acid mine drainage, and to reduce visual blight. In the presented study, we assess the potential for inferring textural properties of mine tailing deposits with electromagnetic induction (EMI) mapping as a means of informing efforts to establish vegetation at mine waste sites. EMI measurements of apparent electrical conductivity (EC_a) and tailing samples were collected at a mine waste site in Southern Arizona, USA and used to test empirical and theoretical relationships between EC_a and physical and mineralogical properties using linear and Gaussian process regression. Sensitivity analyses of a semi-theoretical and a regression model of EC_a as a function of tailing properties indicated that volumetric clay fraction in the top 60 cm was a primary influence on bulk electrical conductivity along with water content, conductivity of the soil water and the presence of conductive minerals hematite and pyrite. At this site, latitude and longitude were better predictors of clay content than EC_a, and while it was possible to obtain information about the spatial distribution of tailing texture using EMI, simple Kriging of texture data was a more powerful textural mapping technique. We conclude that EMI is a useful tool for mapping tailing texture at waste deposit sites, but due to physical and chemical heterogeneity of tailing deposits, it is necessary to collect more in situ samples than are needed for agricultural applications.     

Inversion of multi-frequency electromagnetic induction data for 3D characterization of hydraulic conductivity

Electromagnetic induction (EMI) instruments provide rapid, noninvasive, and spatially dense data for characterization of soil and groundwater properties. Data from multi-frequency EMI tools can be inverted to provide quantitative electrical conductivity estimates as a function of depth. In this study, multi-frequency EMI data collected across an abandoned uranium mill site near Naturita, Colorado, USA, are inverted to produce vertical distribution of electrical conductivity (EC) across the site. The relation between measured apparent electrical conductivity (EC_a) and hydraulic conductivity (K) is weak (correlation coefficient of 0.20), whereas the correlation between the depth dependent EC obtained from the inversions, and K is sufficiently strong to be used for hydrologic estimation (correlation coefficient of ? 0.62). Depth-specific EC values were correlated with co-located K measurements to develop a site-specific ln(EC)–ln(K) relation. This petrophysical relation was applied to produce a spatially detailed map of K across the study area. A synthetic example based on EC_a values at the site was used to assess model resolution and correlation loss given variations in depth and/or measurement error. Results from synthetic modeling indicate that optimum correlation with K occurs at ~ 0.5 m followed by a gradual correlation loss of 90% at 2.3 m. These results are consistent with an analysis of depth of investigation (DOI) given the range of frequencies, transmitter–receiver separation, and measurement errors for the field data. DOIs were estimated at 2.0 ± 0.5 m depending on the soil conductivities. A 4-layer model, with varying thicknesses, was used to invert the EC_a to maximize available information within the aquifer region for improved correlations with K. Results show improved correlation between K and the corresponding inverted EC at similar depths, underscoring the importance of inversion in using multi-frequency EMI data for hydrologic estimation.     

Field‐Scale Relationships Among Soil Properties and Shallow Groundwater Quality

It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near‐water‐table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100‐m grid on a 64‐ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product‐moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (EC_a) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca‐ and Mg‐HCO₃ type water and was associated with topographic high areas with lower EC_a and net groundwater recharge. Small topographic depressions were areas of higher EC_a (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short‐term depression‐focused recharge events. At this site, groundwater quality and soil EC_a were related to surface topography. High‐resolution topography and EC_a measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field‐scale and to delineate areas where the shallow groundwater is most susceptible to contamination.     

Space-time mapping of soil salinity using probabilistic bayesian maximum entropy

The mapping of saline soils is the first task before any reclamation effort. Reclamation is based on the knowledge of soil salinity in space and how it evolves with time. Soil salinity is traditionally determined by soil sampling and laboratory analysis. Recently, it became possible to complement these hard data with soft secondary data made available using field sensors like electrode probes. In this study, we had two data sets. The first includes measurements of field salinity (EC_a) at 413 locations and 19 time instants. The second, which is a subset of the first (13 to 20 locations), contains, in addition to EC_a, salinity determined in the laboratory (EC_2.5). Based on a procedure of cross-validation, we compared the prediction performance in the space-time domain of 3 methods: kriging using either only hard data (HK) or hard and mid interval soft data (HMIK), and Bayesian maximum entropy (BME) using probabilistic soft data. We found that BME was less biased, more accurate and giving estimates, which were better correlated with the observed values than the two kriging techniques. In addition, BME allowed one to delineate with better detail saline from non-saline areas.     

Geophysical study of the Peinan Archaeological Site,Taiwan

The Peinan archaeological site is the most intact Neolithic village with slate coffin burial complexes in Taiwan. However, the area that potentially contains significant ancient remains is covered by dense vegetation. No reliable data show the distribution of the ancient village, and no geophysical investigation has been performed at this site. To evaluate various geophysical methods under the geological setting and surface condition of the site, the physical properties of the remains were measured and four geophysical methods involving magnetic, electromagnetic (EM), electrical resistivity tomography (ERT), and ground-penetrating radar (GPR) were tested along three parallel profiles. The results imply that the EM and magnetic methods are much cost-effective and suitable for investigating the entire area. GPR and ERT methods can provide high resolution subsurface image, which are much suitable for subsequently detail investigation.The EM and magnetic surveys were thus conducted over the entire Peinan Cultural Park to understand the distribution of the ancient building remains at the Peinan site. The results of this study were verified by subsequent excavations, which indicate that the EM survey was successful in delineating the majority of the ancient village because the basements of building are highly resistive in comparison to the background sediment. The results of this investigation suggest that the ancient village was broadly distributed over the eastern part of the Peinan Culture Park and extended to the southeast.     

FIELD RESULTS WITH DOWNWARD CONTINUATION TECHNIQUE IN INDUCED POLARIZATION PROFILING USING POINT ELECTRODES1

The method of downward continuation is well known to those working in gravity, magnetic, SP and low-frequency electromagnetic exploration. It is demonstrated that the method of continuation can also be usefully employed in the interpretation of induced polarization gradient profiling using point electrodes to determine target depth. The apparent resistance R_a and chargeability M_a measurements obtained with point electrode excitation of the ground have been used to compute the values of (R_a)_l and (M_a)_l that would be obtained with a linear array. Continuation of the apparent polarizability profile thus obtained with the linear array gives a value for the depth of the target which agrees closely with that obtained by the continuation of the SP profile. On the other hand, continuation of the profile of the secondary transient signal (V_S)_L alone, yields a depth of the target which is in agreement with the borehole information. However, it is seen that the secondary transient voltage profiling response splits into two anomalies which fall on either side of the SP and/or (M_a)_l anomaly centre, and does not coincide with that of the latter.     

Soil water content and salinity determination using different dielectric methods in saline gypsiferous soil / Détermination de la teneur en eau et de la salinité de sols salins gypseux à l'aide de différentes méthodes diélectriques

Abstract

Measurements of dielectric permittivity and electrical conductivity were taken in a saline gypsiferous soil collected from southern Tunisia. Both time domain reflectometry (TDR) and the new WET sensor based on frequency domain reflectometry (FDR) were used. Seven different moistening solutions were used with electrical conductivities of 0.0053–14 dS m^?1. Different models for describing the observed relationships between dielectric permittivity (K _a ) and water content (θ), and bulk electrical conductivity (EC _a ) and pore water electrical conductivity (EC _p ) were tested and evaluated. The commonly used K _a –θ models by Topp et al. (1980) and Ledieu et al. (1986) cannot be recommended for the WET sensor. With these models, the RMSE and the mean relative error of the predicted θ were about 0.04 m³ m^?3 and 19% for TDR and 0.08 m³ m^?3 and 54% for WET sensor measurements, respectively. Using the Hilhorst (2000) model for EC _p predictions, the RMSE was 1.16 dS m^?1 and 4.15 dS m^?1 using TDR and the WET sensor, respectively. The WET sensor could give similar accuracy to TDR if calibrated values of the soil parameter were used instead of standard values.     

A new tool for hillslope hydrologists: spatially distributed groundwater level and soilwater content measured using electromagnetic induction

New methods for obtaining and quantifying spatially distributed subsurface moisture are a high research priority in process hydrology. We use simple linear regression analyses to compare terrain electrical conductivity measurements (EC) derived from multiple electromagnetic induction (EMI) frequencies to a distributed grid of water‐table depth and soil‐moisture measurements in a highly instrumented 50 by 50 m hillslope in Putnam County, New York. Two null hypotheses were tested: H0₍₁₎, there is no relationship between water table depth and EC; H0₍₂₎, there is no relationship between soil moisture levels and EC. We reject both these hypotheses. Regression analysis indicates that EC measurements from the low frequency EM31 meter with a vertical dipole orientation could explain over 80% of the variation in water‐table depth across the test hillslope. Despite zeroing and sensitivity problems encountered with the high frequency EM38, EC measurements could explain over 70% of the gravimetrically determined soil‐moisture variance. The use of simple moisture retrieval algorithms, which combined EC measurements from the EM31 and EM38 meters in both their vertical and horizontal orientations, helped increase the r² coefficients slightly. This first hillslope hydrological analysis of EMI technology in this way suggests that it may be a promising method for the collection of a large number of distributed soilwater and groundwater depth measurements with a reasonable degree of accuracy. Copyright © 2003 John Wiley & Sons, Ltd.     

基于微焦点CT与数据约束模型的古代家猪牙齿显微结构研究

本文对一例考古发掘出土的古代家猪下颌骨及牙齿进行了微焦点CT成像,通过加置滤波片有效减弱了线束硬化对CT图像的影响。基于数据约束模型（DCM）对样品三维结构进行了定量计算,获取了包含小于CT图像体元尺寸在内的样品跨尺度结构信息。对样品中孔隙及高吸收组分的联通特性进行了跨尺度计算,得到这两种组分的三维团簇分布。与常见的图像阈值分割法相比,DCM模型有效减弱了部分体积效应对图像分析的影响。本文研究结果为考古样品的内部形态测量、结构分析提供了数据基础,为考古样品的数字建模存档提供一种新的方法。      

On temporal and spatial distribution of seismic apparent stresses in Yunnan area

Introduction In recent years the study of the digital seismology has made great progress due to the wide use of the broadband digital records. And many fine results of the focal theory have obtained. The focal theory mainly studies the physical process of the seismic fracture and production of the seismic wave, as well as its traveling process. One of the great progresses is to simulate the fracture process in the active fault. Especially a new concept of the fracture mechanics has been intro…     

A New Soil Sampling Design in Coastal Saline Region Using EM38 and VQT Method

Spatial sampling design based on the variability and distribution of soil properties is an important issue with the progress in precision agriculture and soil ecology. Electromagnetic induction (type EM38) and variance quad‐tree (VQT) method were both applied to optimize the sampling scheme of soil salinity in a coastal reclamation field in north Jiangsu Province, China. Apparent soil electrical conductivity (EC_a) measured with EM38 was used as an ancillary variable and the spatial distribution of EC_a was used as priori information. The process and result of VQT algorithm analysis was illustrated and the obtained sampling strategy was validated using observed soil salinity. Then the spatial precision and sampling efficiency were evaluated. The result indicated that the spatial distribution of soil salinity produced with the VQT scheme was quite similar to that produced with total sampling sites, while sampling quantity of the former was reduced to approximately 1/2 of the latter. The spatial precision of VQT scheme was considerably higher than that of traditional grid method with respect to the same sampling number, and fewer samples were required for VQT scheme to obtain the same precision level. A 17.3% increase in sampling efficiency was achieved by VQT over grid method at the precision level of 90%. The VQT method was proved to be more efficient and economical because it can sample intensively or sparsely according to variation status in local areas. The associated application of EM38 and VQT method provides efficient tools and theoretical basis for saving sampling cost and improving sampling efficiency in coastal saline region and enriching soil ecology.     

Toxicity-directed Fractionation of Tannery Wastewater Using Solid-phase Extraction and Luminescence Inhibition in Microtiter Plates

A four-step solid-phase extraction (SPE) method is presented for toxicity-directed fractionation of industrial wastewater. This fractionation procedure serves as a key step for identifying unknown organic toxicants in complex samples. Toxicity was determined as luminescence inhibition of Vibrio fischeri using microtiter plates. This method was compared to standard tests in glass cuvettes using both 37 standard chemicals and 24 wastewater fractions with EC₅₀ values covering five orders of magnitude. Results of both methods correlated well. 22 tannery wastewater samples were sequentially extracted using C₁₈e and polystyrene-divinylbenzene phases in combination with pH-changes. Final solid-phase filtrates showed low inhibition, so toxicity of inorganics could be neglected. Using 1/EC₅₀ values, the SPE eluates showed clearly different toxicity patterns. Even in eluates of the fourth extraction step, high toxic effects could be observed. In several cases, luminescence inhibition was increasing at the anaerobic treatment step compared to the corresponding untreated samples. After aerobic treatment, toxicity of most wastewater fractions was greatly diminished. HPLC/DAD analyses of the wastewater fractions showed a fair separation concerning compound polarity. However, the samples were still too complex to identify single compounds responsible for the detected toxicity. Therefore, a further clean-up step accompanied with toxicity testing is needed.     

Estimating water fluxes in the critical zone using water stable isotope approaches in the Groundnut and Ferlo basins of Senegal

Sustainable water management in semi-arid agriculture practices requires quantitative knowledge of water fluxes within the soil-vegetation-atmosphere system. Therefore, we used stable-isotope approaches to evaluate evaporation (E_a), transpiration (T_a), and groundwater recharge (R) at sites in Senegal's Groundnut basin and Ferlo Valley pasture region during the pre-monsoon, monsoon, and post-monsoon seasons of 2021. The approaches were based upon (i) the isothermal evaporation model (for quantifying E_a); (ii) water and isotope mass balances (to partition E_a and T_a for groundnut and pasture); and (iii) the piston displacement method (for estimating R). E_a losses derived from the isothermal evaporation model corresponded primarily to Stage II evaporation, and ranged from 0.02 to 0.09 mm d⁻¹ in the Groundnut basin, versus 0.02–0.11 mm d⁻¹ in Ferlo. At the groundnut site, E_a rates ranged from 0.01 to 0.69 mm d⁻¹; T_a was in the range 0.55–2.29 mm d⁻¹; and the T_a/ET_a ratio was 74%–90%. At the pasture site, the ranges were 0.02–0.39 mm d⁻¹ for E_a; 0.9–1.69 mm d⁻¹ for T_a; and 62–90% for T_a/ET_a. The ET_a value derived for the groundnut site via the isotope approach was similar to those from eddy covariance measurements, and also to the results from the previous validated HYDRUS-1D model. However, the HYDRUS-1D model gave a lower T_a/ET_a ratio (23.2%). The computed groundwater recharge for the groundnut site amounted to less than 2% of the local annual precipitation. Recommendations are made regarding protocols for preventing changes to isotopic compositions of water in samples that are collected in remote arid regions, but must be analysed days later. The article ends with suggestions for studies to follow up on evidence that local aquifers are being recharged via preferential pathways.     

Magnetic study of archaeological structures in La Campana,Colima, western Mesoamerica

Results of a magnetic survey of the archaeological site at La Campana in the Colima area of western Mesoamerica are reported. The site is located in the northern suburbs of the city of Colima over a terrain characterized by volcanic debris avalanche deposits. The study area of about 12,600 m² is divided into two sections corresponding to (1) the main archaeological site and to (2) a potential extension north of it. The magnetic survey shows the presence of three large dipolar anomalies oriented N–S or NNE–SSW occurring over small hills some 2 to 4 m high. The archaeological excavations have uncovered three large structures made mainly of rounded volcanic boulders built on large platforms. The southern structure consists of a pyramid (25×25 m² at its base) and an adjacent structure (at least 30×15 m²). The central structure is a pyramid (20×20 m²) with stair-like accesses on either side. The northern structure is a large complex extending over an area at least 40×30 m². A detailed survey in the open plaza area, using the vertical gradient method, revealed an elongated shallow linear feature, which turned out to be part of a channel network constructed with flat volcanic slabs. Inverted conical openings that end in a small well are connected to the channel network, which was apparently designed to collect water from rain and distribute it to the surrounding structures. The magnetic survey also shows the occurrence of a dipolar anomaly over a small topographic elevation that may likely correspond to another large pyramid. North of it, there is a series of elongated anomalies similar in shape and amplitude to those associated with the hydrological network. The archaeological remains extend over an area considerably larger than the one excavated in the archaeological study. The characteristics and size of the pyramidal structures, the plazas and channel network, and the apparent overall extension of the archaeological site strongly suggests that La Campana constituted a major urban and ceremonial center in westernmost Mesoamerica.     

High resolution 3D ERT to help GPR data interpretation for researching archaeological items in a geologically complex subsurface

Muro Leccese (Lecce) contains one the most important Messapian archaeological sites in southern Italy.The archaeological interest of the site arises from the discovery of the remains of Messapian walls, tombs, roads, etc. (4th–2nd centuries BC) in the neighbourhood. The archaeological remains were found at about 0.3 m depth.At present the site belongs to the municipality, which intends to build a new sewer network through it. The risk of destroying potentially interesting ancient archaeological structures during the works prompted an archaeological survey of the area. The relatively large dimensions of the area (almost 10,000 m²), together with time and cost constraints, made it necessary to use geophysical investigations as a faster means to ascertain the presence of archaeological items. Since the most important targets were expected to be located at a soil depth of about 0.3 m, a ground-penetrating radar (GPR) survey was carried out in an area located near the archaeological excavations. Unfortunately the geological complexity did not allow an easy interpretation of the GPR data.Therefore a 3D electrical resistivity tomography (ERT) scan was conducted in order to resolve these interpretation problems.A three-way comparison of the results of the dense ERT measurements parallel to the x axis, the results of the measurements parallel to the y axis and the combined results was performed.Subsequently the synthetic model approach was used to provide a better characterization of the resistivity anomalies visible on the ERT field data.The 3D inversion results clearly illustrate the capability to resolve in view of quality 3D structures of archaeological interest. According to the presented data the inversion models along one direction (x or y) seems to be adequate in reconstructing the subsurface structures.Naturally field data produce good quality reconstructions of the archaeological features only if the x-line and y-line measurements are considered together. Despite the increased computational time required by the 3D acquisition and 3D inversion schemes, good quality results can be produced.     

Testing the application of post IR IRSL dating to Iron- and Viking-age ceramics and heated stones from Denmark

In this study we test, for the first time, the potential of an elevated temperature post-IR IR (pIRIR₂₉₀) SAR protocol for the dating of young heated artefacts. Seven heated stones and seven potshards were collected from three different archaeological sites in Denmark: one site from the early Pre-Roman Iron Age 200 BC to AD 100, and two from the Viking period between AD 800 and 1200.We first derive quartz OSL ages for these samples, to support the archaeological age control. The luminescence characteristics of the pIRIR₂₉₀ signal are then investigated; in particular the dose recovery ratios are shown to be close to unity. The performance of the feldspar pIRIR₂₉₀ protocol is then examined by comparing the pIRIR₂₉₀ ages with those based on the quartz OSL signal; the average ratio of pIRIR₂₉₀ to OSL ages is 1.14 ± 0.05 (n = 14) and there is some suggestion that the possible overestimation of the feldspar ages compared to quartz is only of significance for the heated stone samples. Nevertheless, there is no indication of incomplete heating of the stones; the ratios of D_e derived from the IR₅₀ and pIRIR₂₉₀ signals are independent of sample type, and consistent with complete resetting by heating. Comparison with the archaeological age control is not able to identify whether quartz or feldspar provides the most reliable dating signal.     

The earthquake of Carnuntum in the fourth century a.d. – archaeological results, seismologic scenario and seismotectonic implications for the Vienna Basin fault, Austria

Excavations in the former Roman provincial capital of Pannonia Superior, Carnuntum, 40 km east of Vienna revealed damaged masonry structures from many parts of the ancient settlements. A compilation of structurally damaged buildings has formerly been given by Kandler (Acta Archaeol Acad Sci Hung, 41:313–336, 1989), who related damage to an earthquake in the middle of the fourth century a.d. This paper reviews and supplements these data, and discusses the significance of the style of damage. It is concluded that seismic damage is the only likely interpretation for the damaging mechanism. Although archaeological age dating for the individual collapsed buildings only constrains the timing of their destruction to a few decades around 350 a.d., we assume a single damaging event. In spite of the restrictions on damage assessment by the nature of the archaeological data, it is possible to give a reasonable appraisal of macroseismic intensity. The tentative seismological interpretation of damage leads to an intensity estimate of about nine of the European macroseismic scale (EMS-1998). Comparison with macroseismic data of modern earthquakes in the region, which show a rapid decrease of intensity with distance form the epicentre, indicate a near-by seismic source unless exceptionally high epicentral intensities are assumed for the fourth century event. The most likely source is an active sinistral strike-slip fault (Lassee Fault) passing about 8 km NW of the archaeological site. The fault belongs to Vienna Basin fault system with about 2 mm sinistral movement per year. The system is characterized by fault segmentation and distinct seismicity along the different segments. Moderate seismicity during the last centuries at the southern segments (e.g., Schwadorf 1927, I ₀=8) strongly contrasts from the Lassee fault segment with Carnuntum as the only known severe earthquake. The earthquake of Carnuntum provides evidence for the overall seismic style of deformation along this segment, which previously has not been regarded seismically active. Also, the fourth century earthquake is the strongest event known from the Vienna Basin fault so far.     

Response of a Freshwater Ostracod (Cypris subglobosa SOWERBY) Exposed to Copper at Different pH Levels

Short-term tests of the acute toxicity of Cu²⁺ (from copper sulphate) to a freshwater ostracod, Cypris subglobosa SOWERBY were carried out at five different pH values from 5.5 to 8.5. The toxicity of copper abruptly decreased with an increase in pH of the Cu-containing medium. The 48 h EC₅₀ value of Cu increased from 0.35 ppm at pH =5.5… 5.1 ppm at pH =8.5. The per cent survival, median period of immobilization (ET₅₀), slope functions and the 95 per cent confidence limits were determined at each pH level. The direct correlation between EC₅₀ value and pH indicated that the acute toxicity of Cu decreased as the pH increased from 5.5… 8.5.