Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.     

Correlations of three-component ground motions from the 23 June 2010 Val-des-Bois, Québec, earthquake

In this paper, we investigate the characteristics of three-component ground motions recorded during the $M_\text{w}\,5.2$ Val-des-Bois (Québec) earthquake, which occurred on the 23 June 2010. The earthquake is the largest recorded event in eastern Canada within the last decade. The records analyzed were provided by a strong motion monitoring network, comprising accelerometers located at sites with different soil conditions. The two orthogonal horizontal components and one vertical component at each recording station are uncorrelated to determine their principal directions, and the results obtained are used to characterize intensity ratios between the three uncorrelated components. A new hodograph representation is proposed to highlight the correlation between accelerations and displacement trajectories along various time increments at each recording station. The principal components are discussed in light of seismographic data, local site conditions, and trajectories. Time–frequency analyses of the uncorrelated records are also conducted to compare the distribution of spectral amplitudes and frequency content along the three principal components during the shaking. The results of this work shed more light on the characteristics of three-component ground motions from an important Eastern North America earthquake, and could be used to calibrate simulated multicomponent ground motions in this region.     

Paleomagnetic dating of the Cenjiawan Paleolithic site in the Nihewan Basin, northern China

It draws much attention of scientists how early hu- mans occupy and adapt to the rigorous climate and environment at high northern latitudes in East Asia after they stepped out of Africa, passed West Asia and finally arrived in East Asia[1-4]. Reliable age determi- nations of Paleolithic sites from northeastern Asia not only help to find out the earliest occupation of early humans in this region, but also relate to the founda- tion of the overall framework of human origin and migration[1-8]…     

OSL dating of individual quartz ‘supergrains’ from the Ancient Middle Palaeolithic site of Cuesta de la Bajada,Spain

Dose saturation represents a fundamental limitation for obtaining finite optically stimulated luminescence (OSL) quartz ages over Middle Pleistocene timescales. Single-grain OSL studies typically reveal significant intra- and inter-sample variability in quartz dose saturation properties at the individual grain level. This enhanced variability may offer the potential to obtain extended-range chronologies exceeding the traditional upper age limits of multiple-grain OSL dating. However, there have been relatively few detailed assessments of single-grain OSL properties over high dose ranges. In this study we investigate extended-range single-grain OSL dating potential at Cuesta de la Bajada, one of the most important Ancient Middle Palaeolithic sites in the Iberian Peninsula. The quartz samples from this site exhibit exceptional dose saturation properties and contain significant populations of individual ‘supergrains’ with bright OSL signals, very high characteristic saturation dose (D₀) limits of 200 to >600 Gy, and dose-response curves that closely conform to single saturating exponential functions. Assessments of OSL signal composition and the ability to successfully recover a known laboratory dose of 470 Gy support the potential for obtaining high equivalent dose (D_e) values with reasonable fitting uncertainties. A series of novel sensitivity tests are used to assess potential biases in supergrain D_e estimation over high dose ranges related to (i) thermally transferred signal contributions, (ii) choice of dose-response curve fitting function, and (iii) insufficient dose saturation properties of individual grains. The single-grain D_e values obtained using the standard quality assurance criteria and novel sensitivity tests are consistent at 2σ, and are in agreement with quartz Ti-centre ages obtained on two of three paired electron spin resonance (ESR) samples collected from Cuesta de la Bajada. These comparisons support the suitability of our single-grain OSL results and suggest there may be good potential for using quartz supergrains to establish extended-range chronologies at some Middle Pleistocene sites. Comparisons with other single-grain OSL studies across the Iberian central plains suggest that favourable dose saturation properties may be influenced by regional-scale geological controls. The importance of undertaking single-grain OSL dating at Cuesta de la Bajada is also demonstrated by the results of synthetic aliquot experiments, which reveal multiple-grain age offsets of 60–170 ka when unsuitable grain types are inadvertently included in the final age calculations. The single-grain OSL results indicate that the main archaeological horizon at Cuesta de la Bajada (unit CB3) accumulated between 264 ± 22 and 293 ± 24 ka. These ages are consistent with the chronologies of other key early Middle Palaeolithic sites in the region (Ambrona AS6 and Gran Dolina TD10) and indicate that the Ancient Middle Palaeolithic techno-complex likely spread across Iberia from at least Marine Isotope Stage 9 onwards.     

A nested multivariate copula approach to hydrometeorological simulations of spring floods: the case of the Richelieu River (Québec,Canada) record flood

Floods have potentially devastating consequences on populations, industries and environmental systems. They often result from a combination of effects from meteorological, physiographic and anthropogenic natures. The analysis of flood hazards under a multivariate perspective is primordial to evaluate several of the combined factors. This study analyzes spring flood-causing mechanisms in terms of the occurrence, frequency, duration and intensity of precipitation as well as temperature events and their combinations previous to and during floods using frequency analysis as well as a proposed multivariate copula approach along with hydrometeorological indices. This research was initiated over the Richelieu River watershed (Quebec, Canada), with a particular emphasis on the 2011 spring flood, constituting one of the most damaging events over the last century for this region. Although some work has already been conducted to determine certain causes of this record flood, the use of multivariate statistical analysis of hydrologic and meteorological events has not yet been explored. This study proposes a multivariate flood risk model based on fully nested Archimedean Frank and Clayton copulas in a hydrometeorological context. Several combinations of the 2011 Richelieu River flood-causing meteorological factors are determined by estimating joint and conditional return periods with the application of the proposed model in a trivariate case. The effects of the frequency of daily frost/thaw episodes in winter, the cumulative total precipitation fallen between the months of November and March and the 90th percentile of rainfall in spring on peak flow and flood duration are quantified, as these combined factors represent relevant drivers of this 2011 Richelieu River record flood. Multiple plausible and physically founded flood-causing scenarios are also analyzed to quantify various risks of inundation.     

LA-ICP-MS zircon U-Pb dating from granitoids in southern basement of Songliao basin:Constraints on ages of the basin basement

Seven LA-ICP-MS zircon U-Pb datings from granitoids in the southern basement of the Songliao basin were done in order to constrain the ages of the basin basement. The cathodoluminescence (CL) images of the zircons from seven granitoids indicate that they are euhedral-subhedral ones with striped ab-sorption and obvious oscillatory zoning rims. The dating results show that a weighted mean 206Pb/238U age is 236±3 Ma for quartz diorite (sample No.T6-1) located in the western slope of the basin,that weighted mean 206Pb/238U ages are 319±1 Ma (2126 m) and 361±2 Ma (1994 m) for diorite (sample No.YC1-1) and granite (sample No.YC1-2) located in northern part of southeastern uplift of the basin,respectively,and that weighted mean 206Pb/238U ages are 161±5 Ma,165±2 Ma,165±1 Ma and 161±4 Ma for samples Q2-1,SN121,SN122,and SN72 granitoids located in southern part of southeastern uplift of the basin,respectively. The statistical results of ages suggest that the middle Jurassic granitoids con-stitute the main part of basement granitoids,and that the Hercynian and Indo-Sino magmatisms also occur in the basin basement. It is implied that the Songliao basin should be a rift one formed in the intracontinent or active continental margin settings in the late Mesozoic after the Middle Jurassic orogeny took place.     

Flood events and flood risk assessment in relation to climate and land-use changes: Saint-François River,southern Québec,Canada

Abstract

In the current context of climatic variability, it is important to quantify the impact on the environment. This study deals with an analysis of climatic data and land-use changes in terms of the impacts on flood recurrence based on multisource data. The study area covers the mouth of the Saint-François River (southern Québec, Canada), where spring floods and ice jams are a recurring problem. The flood frequency analysis shows an increase in flooding over recent decades, attributable to an increase in winter temperatures that has the effect of causing ice jams earlier in the year. Regarding land-use changes, a small decrease in agricultural surface areas is observed, from 53% to 39%, along with increases in forest and urban surface areas from 27% to 38% (forest) and 3% to 5% (urban) between 1928 and 2005. In a context of continuing climate warming, more pronounced inter-annual variations are to be expected along with a higher incidence of flooding.

Editor Z.W. Kundzewicz

Citation Ouellet, C., Saint-Laurent, D. and Normand, F., 2012. Flood events and flood risk assessment in relation to climate and land-use changes: Saint-François River, southern Québec, Canada. Hydrological Sciences Journal, 57 (2), 313–325.     

Hydroclimatic variability and relation with flood events (Southern Québec, Canada)

In the context of global warming, some climatic models predict an increase in flooding in some regions of the world. It is therefore important to better define the high-risk areas and to limit the use of these areas by riverside communities as much as possible. The study deals with the historical and chronological reconstruction of flood events (from 1865 to 2005) in the southern Quebec basins, and compare with the hydroclimatic data (streamflow, temperature, precipitation) over the past century. Different statistic tests are used on hydroclimatic series and flood events to detect the trend observed. We note an important variability of hydrometric data series and the chronological flood events shows a significant trend in increased flooding in the last 100 years.     

Selective chemical degradation of kerogen from Nenjiang Formation of the southern Songliao Basin

A sequential selective chemical degradation has been performed on the kerogen from the Nenjiang Formation of the southern Songliao Basin by using a series of mild chemical degradations (alkaline hydrolysis, cleavage of ether-bonds and sulfur-bonds, and ruthenium tetroxide (RuO4) oxidation). Subsequently, the GC-MS analyses are carried out on different degradation products. The results show that chemical degradations can release a great number of GC/MS-determinable biomarkers from insoluble kerogen, such as, alkaline hydrolysis products mainly comprise n-alkanes, fatty acids and alkanols; thiophene compounds are predominantly ether-bound to kerogen matrix; the products from the cleavage of sulfur-sulfur and sulfur-carbon bonds in the kerogen include fatty acids, alkanols and some n-alkanes with high carbon numbers; RuO4 oxidation products are predominantly monocarboxylic acids and α,ω-dicarboxylic acids. The distributions of main degradation products indicate that organic matter in this kerogen is predominantly derived from algae and bacteria, and that small amounts of high plant-derived organic matter are possibly combined into kerogen matrix at the late stage by sulfur bonds and other means. This study will provide an important approach for further discussing sources of organic matter in source rocks and their depositional paleoenvironments.     

Twelve years of ground-tilt measurements on the Soufriere of St. Vincent, 1977–1989

Five ground-tilt stations were established on the flanks of the Soufriere of St. Vincent; two in 1977, two in 1980, and one in 1983. Four of these stations have survived; two consist of lines oriented radially to the volcano, and the other two consist of cross-shaped arrays. Collectively, this network showed that the volcano inflated gradually before the eruption of 1979 and then deflated rapidly during the eruption and for about a year after it had ended. The volcano then reinflated during much of 1981 and inflated only slightly, if at all, during the 7-year period 1982–1989. The measured amount of ground tilt from 1977 to 1989 was relatively small; the maximum recorded change of radial tilt at a station 6.5 km from the summit of the volcano totaled about 20 rad. Local seismicity correlates well with measured ground deformation: numerous earthquakes accompanied the 1979–1981 deflation/inflation cycle; relatively few earthquakes occurred during the 1982–1989 period of little or no ground deformation. In the hope that the experience we have gained might be of use to others who are considering a program of ground-tilt monitoring on volcanoes elsewhere in the humid tropics, we describe many practical aspects of our program that have evolved over the years. For example: (1) stainless steel bench marks cemented into solid bedrock appear to be stable for at least 12 years, (2) bench marks can be located in concrete-filled drums where bedrock is absent, (3) bench marks should be concealed to protect them from vandalism, (4) care must be exercised where sight lines graze the ground (<0.5 m), and (5) automatic levels are preferable because of their efficiency of operation, especially with inexperienced personnel.     

Comparative dating of a Bison-bearing late-Pleistocene deposit,Térapa,Sonora, Mexico

A recently discovered Bison-bearing fossil locality at Térapa, Sonora, Mexico, had previously been dated to 440 ± 130 ka using whole rock ⁴⁰Ar/³⁹Ar on a basalt flow that impounds the deposit. This age is considerably older than the accepted age of about 240–160 ka for the migration of Bison into greater North America. The Térapa deposit also contains a mixture of fossils from extralimital or extinct tropical animals and temperate animals. Constraining the age of the deposit is critical to interpret the paleontologic and paleoclimatologic implications of this unique Sonoran fossil locality. Three additional geochronological methods have been applied to this deposit (infrared stimulated luminescence (IRSL), amino acid racemization (AAR), and radiocarbon) and the data from the original ⁴⁰Ar/³⁹Ar age were revisited. The IRSL data suggest that the impounding basalt flow and the sediments that abut it were emplaced 43 ka ago and that the oldest sediments were deposited shortly after. Two radiocarbon ages suggest the fossiliferous sediments were emplaced by 42 ka. Effective diagenetic temperatures inferred from the AAR results, combined with AAR data from a similar-age deposit in southern Arizona, are in accordance with the 40–43 ka age estimates. For the AAR results to corroborate the ⁴⁰Ar/³⁹Ar age, the effective diagenetic temperature for the area would need to be approximately 3 °C, which is unrealistically low for northern Mexico. The new geochronological results suggest the Térapa deposit and fossils are 40–43 ka old. The anomalously old ⁴⁰Ar/³⁹Ar age for the impounding basalt is probably the result of low ⁴⁰Ar* concentrations and inherited ⁴⁰Ar.     

Re-Os (ICP-MS) dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

The Jinchuan Ni-Cu-PGE deposit is the largest nickel sulfide deposit in China and the third largest in the world[1]. It is also the largest platinum deposit in China and contains about 60% platinum reserve of China[2]. The Jinchuan intrusion covers only an area of 1.34 km2, but 47.8% of its volume is the orebody. That makes Jinchuan a typical “large ore deposit in a small intrusion”. A number of research works has been car-ried out towards the Jinchuan deposit. Different ore-forming mo…     

What compensates the topography of southern Norway? Insights from thermo-isostatic modeling

The origin of the high topography of the Norwegian Mountains is currently much debated. Several geophysical studies show that the uppermost mantle below southern Norway has anomalously low velocities as compared to other parts of the Baltic Shield. This study aims to shed lights on the structure of the lithospheric mantle below southern Norway by adapting and further refining a method based on isostatic and thermal equilibrium to compute temperature, temperature-related density and synthetic S-wave velocity in stable continental domains. The one-dimensional steady-state heat equation is used with topographic, Moho depth, crustal density and surface heat flow data. A condition of local isostasy is assumed and geoid undulations are used to constrain the range of possible lithosphere models.Results derived from this method suggest a thickening of the thermal lithosphere below southern Norway from west to east. The western part is found to have higher temperatures, lower densities and lower synthetic S-wave velocities than the eastern part, compatible with results from a recent P-wave travel time residual study. Comparison of the synthetic shear-velocity profiles beneath southwestern Norway with velocity profiles inverted from Rayleigh wave dispersion data suggests that the higher temperatures associated with a thinner lithosphere can explain parts of the seismic low-velocity anomaly.The inferred lithospheric structure is sensitive to uncertainties in the crustal input model, but the main features remain undisturbed by changes in the input data. The results show that the lithosphere of southwestern Norway can be in local isostatic equilibrium, if it is thinner and warmer than the lithosphere of eastern Norway. The present-day high topography may therefore be partially sustained by lower densities in the mantle lithosphere.     

Analyse fréquentielle régionale des précipitations journalières maximales annuelles au Québec,Canada / Regional frequency analysis of annual maximum daily precipitation in Quebec,Canada

Abstract

Abstract A complete regional analysis of daily precipitations is carried out in the southern half of the province of Quebec, Canada. The first step of the regional estimation procedure consists of delineating the homogeneous regions within the area of study and testing for homogeneity within each region. The delineation of homogeneous regions is based on using L-moment ratios. A simulation-based testing of statistical homogeneity allows one to verify the inter-site variability. The second step of the procedure deals with the identification of the regional distribution and the estimation of its parameters. The General Extreme Value (GEV) distribution was identified as an appropriate parent distribution. This distribution has already been recommended by several previous research studies for regional frequency analysis of precipitation extremes. The parameters of the GEV distribution are estimated based on the computation of the regional L-CV, L-C_S and the mean of annual maximal daily precipitations. The third step consists of the estimation of precipitation quantiles corresponding to various return periods. The final procedure allows for the estimation of these quantiles at sites where no precipitation information is available. The use of a jack-knife resampling procedure with data from the province of Quebec allows one to demonstrate the robustness and efficiency of the regional estimation procedure. Values of the root mean square error were below 10% for a return period of 20 years, and 20% for a return period of 100 years.     

Changes in the spectral and chemical properties of a water mass passing through extensive macrophyte beds in a large fluvial lake (Lake Saint-Pierre, Québec, Canada)

Large fluvial lakes, as part of river corridors, are recognized as spatially heterogeneous ecosystems. Due to their shallowness, the littoral zone of these lakes occupies a large proportion of their surface and is extensively covered by macrophytes that are known to affect their physical, chemical and biological environments in various ways. This study documents the small-scale (5 km) bio-optical variations associated with the longitudinal passage of a water mass through macrophyte beds during their maximal growth season. The utilization of a 2D hydrodynamic model allowed us to establish hydrological connectivity between stations within the beds, and thus to identify longitudinal heterogeneity along the macrophyte beds. Significant changes in the inherent properties of the water were observed along the upstream-downstream gradient. Due to their effects on hydrodynamics, macrophytes were responsible for a decrease in particles and dissolved organic carbon (DOC) resulting in an increasing penetration depth of ultraviolet (UV) and photosynthetically active radiation (PAR). Along the transect, chromophoric dissolved organic matter (CDOM) decreased more rapidly than DOC resulting in a decrease of the CDOM to DOC ratio. The observed changes in the DOC pool may be explained by the constant input of non-chromophoric DOC from macrophyte leachates and exudation within the bed and/or the photochemical and microbial degradation of CDOM. The implication of such small-scale heterogeneity on Lake Saint-Pierre productivity is discussed.     

Testing the use of quartz ‘micro-hole’ photon-simulated luminescence for dating sediments from the central Lomonosov Ridge,Arctic Ocean

In the Arctic Ocean, direct dating methods are needed as an alternative to the radiocarbon (¹⁴C) method and to various indirect approaches for a longer stratigraphy. In past attempts to develop a luminescence sediment dating, the use of fine-silt (4–11 μm) mixture of quartz and feldspar grains from core tops has often produced large age overestimates by several ka. A recent application of micro-focused laser (‘micro-hole’) photon-stimulated luminescence (PSL) to medium-silt to fine-sand quartz grains (11–105 μm) from the core tops at the Alaska margin has been usefully accurate. To extend this approach to the central Arctic Ocean and to a larger grain size range, we applied micro-hole PSL dating to >11 μm quartz grains from core tops (0.5–2 cm horizon) from two sites on the central Lomonosov Ridge. We obtain a burial age estimate of ca. 2 ka for 11–62 μm grains at a multicore site 18 MC within a perched intra-ridge basin, in accord with ¹⁴C ages obtained on foraminifers. At nearby site 19 MC on the erosive ridge top, the micro-hole PSL dating of >90 μm quartz grains produces a burial age estimate of ∼ca. 25 ka, in accord with a foraminiferal ¹⁴C age of ca. 26 ka. However, the 11–90 μm grains from the same sample produce a much younger burial age estimate of ca. 9 ka. Thus, these two size fractions of quartz grains record different burial times and different deposition agents (icebergs vs. sea ice), providing insight into past sedimentary processes. Overall, our results confirm an earlier conclusion from micro-hole PSL dating study at the Alaska margin that medium to coarse silt fractions of quartz grains (11–90 μm or at least 62 μm) is the preferred material for direct dating of the last daylight exposure of detrital sediment in the Arctic Ocean.     

Effect of deposit alterations on the dating of herbivorous teeth from Arago cave by the ESR–U-series method

Geochemical alteration processes in archaeological sites may affect the environmental dose rate during the burial history and cause inaccuracy in age determination by palaeodosimetric dating methods, such as luminescence or ESR. In Arago Cave (Tautavel, France), the original composition of the sandy aeolian sediments of palaeoanthropological level G, where the Homo heidelbergensis Arago XXI skull was found, has been modified by both carbonation and phosphatization processes. Eight fossil teeth were collected from different geochemically affected parts of level G and analyzed by the ESR–U-series method. All the teeth are presumably contemporaneous. The results show that the samples from the phosphated area agree within error with those from the carbonated area. Surprisingly, the samples from the non-altered area show ages 100–150 ka younger. This difference is mainly due to the remarkable changes in the gamma dose rate over time. The measured in situ dose rate accounts for more than 50% of the total dose rate for all the samples. We observed that the samples' equivalent dose (D_E) were generally 20% lower in the non-altered area than in the carbonated and phosphated ones. These results show the crucial effect of the geochemical processes affecting the age calculation by ESR–U-series method in comparison with independent chronological data.     

A zooarchaeological study of bone assemblages from the Ma’anshan Paleolithic site

Ten thousands of bone fragments were recovered from the Ma’anshan Paleolithic site, of which 4358 pieces can be identified to skeletal elements or species. In this research, the bone assemblages are quantified based on elements of MNI, MNE, and MAU. Then bone surface modifications and skeletal element profiles of the bone assemblages are studied to understand shlepping behaviors and reveal the technique of disarticulating and defleshing the animals’ bodies, etc. Based on the analyses of bone assemblages and the comparative study with the ethnoarchaeological as well as experimental data, it is assumed that later hominids at the site made fuller use of the game animals than the earlier hominids. Incorporating the lines of evidence from chronological dating, paleoenvironment, and polished bone tools between the two cultural layers, here we propose three hypotheses suggesting that the changes of environment, the migrations of the hominids from the North, or the demographic pulses may cause such a behavioral difference. However, it is yet to be determined which hypothesis can better explain the changes.