Potential of establishing a ‘global standardised growth curve’ (gSGC) for optical dating of quartz from sediments

We report investigations of the optically stimulated luminescence (OSL) signals of sedimentary quartz from different regions of Asia, Africa, Europe and North America using a single-aliquot regenerative-dose (SAR) procedure. We show that variations in the shape of dose response curves (DRCs), or growth curves, of the test dose sensitivity-corrected OSL signals among single aliquots composed of multiple grains can be greatly reduced by normalising the DRCs using one of the regenerative dose OSL signals. We refer to this regenerative-dose normalisation procedure as ‘re-normalisation’. We find a common re-normalised DRC extends to doses of ∼250 Gy for samples that differ significantly in terms of geological provenance, sedimentary context and depositional age. This feature permits the development of a ‘global standardised growth curve’ (gSGC) for OSL signals from single aliquots of quartz. The equivalent dose (D_e) of an aliquot can be estimated from the natural signal, one regenerative dose signal and their corresponding test dose signals. For the variety of samples investigated, we find that D_e estimates obtained from the gSGC are consistent with those obtained using full SAR procedures for doses of up to ∼250 Gy. Use of the gSGC for single aliquots would greatly reduce the time required to estimate the D_e values of older samples and for a large number of aliquots.     

Testing the use of quartz ‘micro-hole’ photon-simulated luminescence for dating sediments from the central Lomonosov Ridge,Arctic Ocean

In the Arctic Ocean, direct dating methods are needed as an alternative to the radiocarbon (¹⁴C) method and to various indirect approaches for a longer stratigraphy. In past attempts to develop a luminescence sediment dating, the use of fine-silt (4–11 μm) mixture of quartz and feldspar grains from core tops has often produced large age overestimates by several ka. A recent application of micro-focused laser (‘micro-hole’) photon-stimulated luminescence (PSL) to medium-silt to fine-sand quartz grains (11–105 μm) from the core tops at the Alaska margin has been usefully accurate. To extend this approach to the central Arctic Ocean and to a larger grain size range, we applied micro-hole PSL dating to >11 μm quartz grains from core tops (0.5–2 cm horizon) from two sites on the central Lomonosov Ridge. We obtain a burial age estimate of ca. 2 ka for 11–62 μm grains at a multicore site 18 MC within a perched intra-ridge basin, in accord with ¹⁴C ages obtained on foraminifers. At nearby site 19 MC on the erosive ridge top, the micro-hole PSL dating of >90 μm quartz grains produces a burial age estimate of ∼ca. 25 ka, in accord with a foraminiferal ¹⁴C age of ca. 26 ka. However, the 11–90 μm grains from the same sample produce a much younger burial age estimate of ca. 9 ka. Thus, these two size fractions of quartz grains record different burial times and different deposition agents (icebergs vs. sea ice), providing insight into past sedimentary processes. Overall, our results confirm an earlier conclusion from micro-hole PSL dating study at the Alaska margin that medium to coarse silt fractions of quartz grains (11–90 μm or at least 62 μm) is the preferred material for direct dating of the last daylight exposure of detrital sediment in the Arctic Ocean.     

Luminescence properties and optically (post-IR blue-light) stimulated luminescence dating of limnic sediments from northern Lake Malawi – Chances and limitations

Affected by the shifting Intertropical Convergence Zone, Lake Malawi holds an outstanding limnic sediment archive storing palaeo-environmental information of a climatically highly responsive landscape in the East African Rift Valley. Reliable chronological data are essential to interpret the lake-bottom sediments and optically stimulated luminescence (OSL) dating is an important method to build up the chronology. We report on material-property studies and OSL-dating results for polymineral fine grains extracted from piston cores obtained from the northern basin of Lake Malawi during the 1998 campaign of the International Decade of the East African Lakes (IDEAL). OSL-dating is based on a post-IR blue (pIRB) light stimulation single aliquot regeneration (SAR) protocol. Our results support earlier publications demonstrating the general applicability of OSL-dating on Lake Malawi sediments of Holocene and late Pleistocene age. However, the study also shows that dose rate estimations imply major challenges which need to be investigated in more detail to improve future OSL-dating results.     

Annual growth rings in a sample of Paraná pine (Araucaria angustifolia): Toward improving the 14C calibration curve for the Southern Hemisphere

This work reports the first high-precision ¹⁴C-AMS dating of holocellulose from a Brazilian subtropical species for the period 1927–1997, with the goal to identify suitable Southern American tree species that will serve as benchmarks for improving the calibration of the ¹⁴C time-scale for the Southern Hemisphere (SH). The tree rings analyzed here came from a single tree of Paraná pine (Araucaria angustifolia) growing at 22°50′S, 46°04′W (Camanducaia, Minas Gerais, Brazil). A slight depletion of atmospheric ¹⁴C after 1927 AD was observed, due to the Suess effect. Our ¹⁴C results also showed the rise and rapid decrease of atmospheric ¹⁴C concentrations associated with the detonation of nuclear weapons during the late 50s, and its subsequent uptake by other large C sinks. Current ¹⁴C data can be used for the study of the global carbon cycle, forensic sciences applications, and the determination of the age and growth rate of tropical trees without annual ring patterns. The remarkable overall agreement of our tree-ring/¹⁴C data with the SH Zone 1–2 compilation dataset shows this subtropical tree species' potential to refine the ¹⁴C calibration curve.     

OSL dating of fine and coarse quartz from a Palaeolithic sequence on the Bistrița Valley (Northeastern Romania)

Previous works focused on optically stimulated luminescence dating of quartz extracted from Romanian and Serbian loess reported significant discrepancies between ages obtained on fine (4–11 μm) and coarse (63–90 μm) quartz. The present study is directed at expanding these investigations. The SAR-OSL and double SAR-OSL protocols are applied on quartz of different grain sizes belonging to 9 samples extracted from a newly identified archaeological site at Bistricioara-Lutărie III on the Bistrița Valley (NE Romania). Radiocarbon ages are also obtained for the 3 uppermost cultural layers hosted in the loess-like deposit.Discrepant ages are obtained between fine (4–11 μm) and coarse (63–90 and 90–200 μm, respectively) quartz for equivalent doses higher than ∼80–100 Gy. However, a very good agreement is achieved for the youngest sample, with an age of ∼8 ka (with a D_e of 38 Gy for fine and 35 Gy for coarse grains, respectively). The comparison with independent control provided by radiocarbon dating suggests better agreement of ages calculated for coarse quartz. Our results are once again proof that concerns should be raised regarding the reliability of the equivalent doses obtained on quartz samples for which the laboratory dose response cannot be fitted by a single saturating exponential function. Further systematic investigations are required regarding the very different saturation characteristics of fine and coarse grained quartz.     

High-resolution optical dating of Late Holocene storm surge deposits – a showcase from Schokland (Noordoostpolder,the Netherlands)

Storm surges have a major impact on land use and human habitation in coastal regions. Our knowledge of this impact can be improved by correlating long-term historical storm records with sedimentary evidence of storm surges, but so far few studies have applied such an approach. Here we apply, for the first time, state-of-the-art optically stimulating luminescence (OSL) methods to obtain high-resolution age information on a sequence of Late Holocene storm surge deposits. By combining this chronological framework of storm surges with other reconstruction methods, we investigate the storm surge impact on the former island Schokland, located in a former inlet of the North Sea (central Netherlands).During the Late Holocene, Schokland transformed from a peat area that gradually inundated (~800 CE) via an island in a marginal marine environment (~1600 CE) to a land-locked island in the reclaimed Province of Flevoland (1942 CE). These transitions are recorded in the sediment archive of the island, consisting of silty clay with sandy intervals deposited during storm surges. A series of ten quartz OSL ages, obtained using best-practice methods to deal with incomplete resetting of the OSL signal and dose rate heterogeneity, reveal two periods of storm surge deposition, around 1600 CE and between 1742 and 1822 CE. Historical sources indicate that major storm surges hit Schokland during these periods. Laboratory analyses (thermogravimetry, grain-size, foraminifera, bivalves and ostracods) corroborates the existence of the two sets of storm surge deposits within the clay sequence. Our study sets a benchmark for obtaining robust depositional age constraints from storm surge sediments, and demonstrates the great potential of modern OSL methods to contribute to improved assessment of storm surge risk. © 2018 John Wiley & Sons, Ltd.     

Seismic signals in geothermal areas of active volcanism: a case study from ‘La Fossa’, Vulcano (Italy)

Since the last eruption (1888–1890) volcanism at Vulcano, Aeolian Archipelago, southern Tyrrhenian Sea, has taken the form of persistent fumarolic activity. The gas-vapour phases of the geothermal systems are mainly discharged within two restricted areas about 1 km apart from each other, in the northern part of the island. These areas are La Fossa crater, and the beach fumaroles of the Baia di Levante. Fluids released at the two main fumarolic fields display quite different chemical and temperature characteristics, implying different origins. The local seismicity essentially takes the form of discrete shocks of shallow origin (depth1 km) at La Fossa, usually with energy < 10¹³ ergs. They are thought to be related to the uprise of pressurized hot gases and vapours discharged at the crater fumaroles. The present investigation points to the existence of two principal categories of seismic events (called M-shocks and N-shocks). These are short events (normally < 10 s). M-type shocks are thought to be due to resonance vibrations within the interior of the volcano, probably driven by the excitation of shock-waves within cavities deeply affected by deposition and alteration of self-sealant hydrothermal minerals. N-type events display features that resemble those of volcano-tectonic earthquakes, but have no recognizable S-phases. Here they are tentatively attributed to microfracturing of rocks which have been extensively hydrothermally altered. Results of the present study permit a preliminary conceptual model of the local shallow seismic processes in the framework of geochemical modelling of fumarolic activity and geological inferences from geothermal drilling.     

‘Detachment’ of icefield outlet glaciers: catastrophic thinning and retreat of the Columbia Glacier (Canada)

We present an investigation of changes taking place on the Columbia Glacier, a lake-terminating outlet of the Columbia Icefield in the Canadian Rockies. The Columbia Icefield is the largest, and one of the most important, ice bodies in the Canadian Rockies. Like other ice masses, it stores water as snow and ice during the winter and releases it during warmer summer months, sustaining river flows and the ecosystems that rely on them. However, the Columbia Glacier and Icefield is shrinking. We use Landsat and Sentinel-2 imagery to show that the Columbia Glacier has retreated increasingly rapidly in recent years, and suggest that this looks set to continue. Importantly, we identify a previously undocumented process that appears to be playing an important role in the retreat of this glacier. This process involves the ‘detachment’ of the glacier tongue from its accumulation area in the Columbia Icefield. This process is important because the tongue is cut off from the accumulation area and there is no replenishment of ice that melts in the glacier's ablation area by flow from upglacier. As a consequence, for a given rate of ablation, the ice in the tongue will disappear much faster than it would if the local mass loss by melting/calving was partly offset by mass input by glacier flow. Such a change would alter the relationship between rates of surface melting and rates of glacier frontal retreat. We provide evidence that detachment has already occurred elsewhere on the Columbia Icefield and that it is likely to affect other outlet glaciers in the future. Modelling studies forecast this detachment activity, which ultimately results in a smaller ‘perched’ icefield without active outlets. © 2019 John Wiley & Sons, Ltd.     

Impact of space energetic particles on the Earth’s atmosphere (a review)

The state of the Earth??s upper atmosphere is formed with the participation of impacts by energetic particles, such as galactic cosmic rays, protons of solar proton events, and precipitation of relativistic electrons. Changes in the neutral composition and the thermal and dynamical regime of the upper atmosphere during periods of disturbances caused by the influence of energetic particles are considered.     

Gravitational potential of the Earth’s crust as a promising energy proxy for seismic hazard assessment (by the example of southeastern Kazakhstan)

The gravitational potential energy of the Earth’s crust in southeastern Kazakhstan relative to the subcrustal level is assessed. Neotectonic geological-geophysical control of variations in the gravitational potential is demonstrated. The seismic parameters are shown to be correlated with the gravitational potential energy and boundaries separating the layers of the Earth’s crust.     

Intercalibration of the Servicio Nacional de Geología y Minería (SERNAGEOMIN), Chile and WiscAr 40Ar/39Ar laboratories for Quaternary dating

Accurate and precise dating of Quaternary lavas and pyroclastic flow or fall deposits is essential for understanding the evolution of active volcanoes and providing context for future eruptions and hazard assessment. The ⁴⁰Ar/³⁹Ar method is commonly employed to date these volcanic materials, however, dating young (<150 ka) K₂O-poor materials can be challenging owing to low radiogenic ⁴⁰Ar* contents that can be difficult to distinguish from trapped atmospheric argon. To address this challenge, a collaborative intercalibration exercise involving the University of Wisconsin-Madison WiscAr Laboratory and the ⁴⁰Ar/³⁹Ar Laboratory of the Servicio Nacional de Geología y Minería (SERNAGEOMIN), Chile was conducted on a common set of samples with the aim of refining our methods and optimizing precision and accuracy of age determinations. Groundmass and plagioclase samples were analyzed on a 5-collector Noblesse ion counting mass spectrometer in the WiscAr lab, whereas measurements in the SERNAGEOMIN lab were performed using an ARGUS VI spectrometer equipped with faraday detectors and one compact discrete dynode electron multiplier. Samples for the intercalibration were collected jointly from three Andean Southern Volcanic Zone volcanoes to evaluate the capability of each laboratory to date different materials. Samples from lava flows with 1.0–3.2 wt % K₂O from Planchon-Peteroa volcanic complex and with <1.0 wt % K₂O from Calbuco Volcano that are the focus of ongoing geological studies were measured in both laboratories. Single crystals of plagioclase (0.6–1.0 wt% K₂O) were measured from the voluminous Diamante (Pudahuel) ignimbrite sourced from the Diamante Caldera. Multiple rounds of experiments were conducted including co-irradiation of samples at Oregon State University, as well as irradiations using the CCHEN reactor in Chile to investigate differences in neutron fluence parameters. As a result, SERNAGEOMIN has modified long-used protocols for the CCHEN reactor so that Quaternary samples may be irradiated for periods of time most appropriate for their age. Although less precise than plateau ages, the isochron ages generated in the two laboratories agree at 2σ for each sample. Six of six co-irradiated samples from Planchon-Peteroa yield plateau ages that also show inter-lab agreement at 2σ. The low K₂O lavas from Calbuco proved more challenging with only three out of five plateau ages in agreement between labs. SERNAGEOMIN blanks were higher and more variable in Calbuco experiments, thus, differences in the variability of the measured ³⁶Ar blanks between the two laboratories may explain the discrepancy in plateau ages. Analysis of single plagioclase crystals from the Diamante Ignimbrite show excellent agreement between labs for both weighted mean apparent ages and isochron ages. We favor an isochron age for the ignimbrite of 132.4 ± 2.2 ka, however, discrepancies in results between samples from three different outcrops present an interesting geochronologic problem that warrants further study. Overall, the consistency of the results between labs is promising. These new precise age determinations significantly improve our understanding of the temporal evolution of these active volcanoes.     

Construction of Intensity–Duration–Frequency (IDF) curves for precipitation at Lubumbashi,Congo, under the hypothesis of inadequate data

Abstract

Intensity–Duration–Frequency (IDF) curves for precipitation constitute a probabilistic tool and have proven useful in water resources management. In particular, IDF curves for precipitation enable questions on the extreme character of precipitation to be answered. The construction of IDF curves for precipitation is difficult or impossible in tropical areas due to the lack of long-term extreme precipitation data. A technique is proposed to overcome this shortcoming by combining limited high-frequency information on rainfall extremes with long-term daily rainfall information. It may be regarded as an extension of Koutsoyiannis' approach. Using this technique, IDF curves for precipitation are produced for Lubumbashi in Congo.

Citation Van de Vyver, H. & Demarée, G. R. (2010) Construction of Intensity–Duration–Frequency (IDF) curves for precipitation at Lubumbashi, Congo, under the hypothesis of inadequate data. Hydrol. Sci. J. 55(4), 555–564.     

Comment on “Thermoluminescence and optically stimulated luminescence signals from volcanic ash: History of volcanism in Barren Island,Andaman Sea” by D. Banerjee (Quaternary Geochronology)

Banerjee, D. [2009. Thermoluminescence and optically stimulated luminescence signals from volcanic ash: History of volcanism in Barren Island, Andaman Sea, Quaternary Geochronology, doi:10.1016/j.quageo.2009.01.011] aimed at determining the history of volcanism and evolution of Barren Island by dating a single ash sample using thermoluminescence and optically stimulated luminescence signals. An attempt to date the volcanic episodes and decipher the history of the volcano with just one sample, the stratigraphic position of which is not known (or at least specified in the paper), does not make any sense, at least in the context of history of volcanism on Barren Island. The title of the paper is a misnomer, as it does not in fact address the reconstruction of the history of volcanism on the Barren Island, but discusses the methods and problem of age underestimation using this technique instead.     

Monitoring Systems for Local Historical Natural–Technical Systems (HNTS) as a Basis for Measures for Long-Term Preservation of Cultural Objects

Examples of the development of monitoring systems are considered for the case of local historical natural–technical systems of various classification levels. The authors’ scheme of classification of local HNTSs is given. The classification is aimed to systematize the diverse data on various HNTSs to form a single interrelated system basing on common principal features. Monitoring systems of local HNTSs of the Borodino Battlefield, Old Ryazan City, and Rostov Kremlin are used as examples to demonstrate their relevancy for solving problems of the complex of protection measures.