A high-resolution tephrostratigraphy from Quoyloo Meadow,Orkney, Scotland: Implications for the tephrostratigraphy of NW Europe during the Last Glacial-Interglacial Transition

Macro- and crypto-tephra layers deposited in European climate archives during the Last Glacial-Interglacial Transition (LGIT ca. 16–8 ka) have become increasingly important as a means to robustly correlate palaeoclimate records, and to test the spatial and temporal synchronicity of climatic transitions. However, correlations between climate archives are currently limited by the number of tephra-linkages that can be made. This disparity in the observed distributions of tephras may lie with methodological limitations relating to the resolution of cryptotephra refinement within palaeoclimate records. Here we present new data from Quoyloo Meadow, Orkney Mainland, Scotland, where nine tephra horizons and ten chemically distinct tephra populations have been identified and correlated to known eruptions during the LGIT. Three of the tephras; the Hässeldalen, Hovsdalur and the Fosen are characterised and placed into a reliable tephrostratigraphy for the first time in the British Isles. The detection of new tephra layers in this case is thought to reflect modifications to the sampling approach applied here. The resulting tephrostratigraphy is used to produce an age model with centennial-scale precision, providing new age estimates for three poorly dated tephras. The chronology rivals the output of more traditionally dated radiocarbon chronologies, and illustrates the potential for tephra to develop robust age-depth models for carbonate sequences.     

Last glacial period cryptotephra deposits in an eastern North Atlantic marine sequence: Exploring linkages to the Greenland ice-cores

The establishment of a tephra framework for the Greenland ice-cores spanning the last glacial period, particularly between 25 and 45 ka b2k, provides strong potential for precisely correlating other palaeoclimatic records to these key archives. Tephra-based synchronisation allows the relative timing of past climatic changes recorded within different depositional environments and potential causal mechanisms to be assessed. Recent studies of North Atlantic marine records have demonstrated the potential of tracing cryptotephra horizons in these sequences and the development of protocols now allows a careful assessment of the isochronous nature of such horizons. Here we report on tephrochronological investigations of a marine sequence retrieved from the Goban Spur, Eastern North Atlantic, covering ∼25–60 ka b2k. Density and magnetic separation techniques and an assessment of potential transport and depositional mechanisms have identified three previously unknown isochronous tephra horizons along with deposits of the widespread North Atlantic Ash Zone II and Faroe Marine Ash Zone III. Correlations between the new horizons and the Greenland ice-core tephra framework are explored and despite no tie-lines being identified the key roles that high-resolution climatostratigraphy and shard-specific trace element analysis can play within the assessment of correlations is demonstrated. The previously unknown horizons are new additions to the overall North Atlantic tephra framework for the last glacial period and could be key horizons for future correlations.     

A second tephra isochron for the Younger Dryas period in northern Europe: The Abernethy Tephra

Visible and non-visible (cryptotephra) volcanic ash layers are increasingly being used to underpin the chronology and high-precision correlation of sequences dating to the last glacial–interglacial transition (LGIT). As the number of sediment records analysed for tephra content rises, and methodological developments permit the detection, extraction and chemical analysis of increasingly scantily represented glass shard concentrations, greater complexity in shard count profiles is revealed. Here we present new evidence from sites in Scotland, and review published evidence from sites elsewhere in NW Europe, that indicate complexity in the eruptive history of Katla volcano during the mid-Younger Dryas and Early Holocene. We propose evidence for a previously-overlooked tephra isochron, here named the Abernethy Tephra, which is consistently found to lie close to the Younger Dryas/Holocene transition. It has a major-element chemical composition indistinguishable from that of the Vedde Ash, which was erupted from the Katla volcano at 12,121 ± 114 cal a BP. The new data suggest that Katla may have erupted again between 11,720–11,230 cal a BP and the subsequent ash fall increases the potential to assess environmental response to Holocene warming across north and west Europe.     

A high-resolution Lateglacial–Early Holocene tephrostratigraphy from southernmost Sweden with comments on the Borrobol–Penifiler tephra complex

We present results from a cryptotephra investigation performed at a high resolution (0.5 cm) on sediments from Körslättamossen in southernmost Sweden. Six peak concentration levels were detected and extracted for geochemical analysis by electron probe microanalyser. Five of these levels were successfully analysed and we propose correlations to the Hässeldalen Tephra, the Vedde Ash, and the Laacher See Tephra (adding new analysis results for the first geochemically confirmed finding of the latter in Sweden), as well as an undetermined Borrobol-type tephra. The tephra identifications were combined with radiocarbon dated macrofossils in order to create an age model for the sampled sediments based on Bayesian methods. Stratigraphical and chronological results were found to concur with a previous study of the site and our results form the basis for discussion concerning the issues surrounding Lateglacial Borrobol-type tephras, of which we suggest further review in order to unlock these tephras’ full potential for Quaternary studies.     

The potential of cryptotephra and OSL dating for refining the chronology of open-air archaeological windblown sand sites: A case study from Mirkowice 33, northwest Poland

The discovery of a cryptotephra (nonvisible volcanic horizon) in a windblown sand archaeological site in Poland highlights how luminescence and tephrostratigraphy may combine to better refine the chronology of such sites. In this study we identify a cryptotephra horizon which on the basis of major and minor element geochemistry and an OSL age of 2.3 ± 0.1 ka is correlated to the Glen Garry tephra. The different methodological strengths of OSL and tephrostratigraphy may be harnessed to counter the limitations of a single approach to produce a more secure chronology. Although in this study the tephra deposition event is shown to post-date the archaeological activity, the methodological approach is clearly demonstrated. Further investigations will reveal if cryptotephra layers are commonly preserved in such environmental settings. If this is so then future applications of this approach may prove to be more widely applicable.     

Advances and limitations in establishing a contiguous high-resolution atmospheric radiocarbon record derived from subfossil kauri tree rings for the interval 60–27 cal kyr BP

Radiocarbon dating is the most widely applied and reliable dating technique for providing chronological control during Marine Isotope Stage 3 (MIS3; ∼60–27 cal kyr BP). Past variations in the atmospheric concentration of radiocarbon mean a calibration curve is required. IntCal20 and SHCal20 calibration curves covering MIS3 are presently largely based on non-atmospheric records which, in combination with larger radiocarbon (¹⁴C) dating uncertainties, results in significant smoothing and reduced resolution in calibration curve structure. Floating tree ring radiocarbon chronologies that are wiggle-matched to other palaeo records (particularly to Hulu Cave speleothems) have the potential to provide detailed structure to the MIS3 portion of extant calibration curves. New Zealand subfossil kauri (Agathis australis) trees are long-lived and are useful for constructing temporally-floating MIS3 atmospheric radiocarbon datasets. This paper presents extant and emerging data from several important Northland subfossil kauri locations (Omaha, Babylon Coast, Bream Bay, Kai Iwi Lakes, Mangawhai). We show the span of seven floating MIS3 kauri sequences (individual trees and chronologies) from which sequential radiocarbon series covering a total of 7556 years is now in development (representing 23% of the period 60–27 cal kyr BP). We also report radiocarbon dates for an additional 34 ancient kauri from MIS3 that can provide additional coverage. After these floating subfossil wood sequences have been produced, close to 40% of MIS3 (12,420 years) will be covered by contiguous subfossil kauri radiocarbon measurements. Based on our findings, we discuss the prospects and limitations for obtaining a highly resolved and precise atmospheric radiocarbon calibration curve comprehensively covering MIS3 using subfossil kauri.     

Testing the ABOx-SC method: Dating known-age charcoals associated with the Campanian Ignimbrite

Over the past decade several studies have shown the improvements to radiocarbon chronologies that arise when Acid Base Oxidation-Stepped Combustion (ABOx-SC, Bird et al., 1999) pretreatment methods are applied to the dating of charcoal thought to be >30 ka BP. However, few studies have examined whether the use of ABOx-SC produces dates that are not only older, but accurate on known-age charcoal samples that could not be decontaminated using the routine Acid–Base–Acid (ABA) pretreatment protocol. In this study we date 9 charcoal fragments found below the Campanian Ignimbrite (CI) tephra layer, dated by ⁴⁰Ar/³⁹Ar to 39,230 ± 45 years (De Vivo et al., 2001, Rolandi et al., 2003), from three Palaeolithic sites. When treated with the ABOx-SC pretreatment protocol, the radiocarbon dates provide an accurate terminus post quem for the CI. In contrast, the ABA protocol consistently underestimates the age of the tephra. These results serve as a warning against the use of consistency as an indicator for reliability, demonstrate that the routine ABA method is not sufficient to decontaminate charcoal samples from sites of Palaeolithic age, and show that ABOx-SC produces not only older, but accurate age estimates.     

Clarifying the distal to proximal tephrochronology of the Millennium (B–Tm) eruption,Changbaishan Volcano,northeast China

Tephra dispersed during the Millennium eruption (ME), Changbaishan Volcano, NE China provides one of the key stratigraphic links between Asia and Greenland for the synchronization of palaeoenvironmental records. However, controversy surrounds proximal-distal tephra correlations because (a) the proposed proximal correlatives of the distal ME tephra (i.e. B–Tm) lack an unequivocal chronostratigraphic context, and (b) the ME tephra deposits have not been chemically characterized for a full spectrum of element using grain-specific techniques. Here we present grain-specific glass chemistry, including for the first time, single grain trace element data, for a composite proximal sequence and a distal tephra from Lake Kushu, northern Japan (ca. 1100 km away from Changbaishan). We demonstrate a robust proximal-distal correlation and that the Kushu tephra is chemically associated with the ME/B–Tm. We propose that three of the proximal pyroclastic fall units were erupted as part of the ME. The radiocarbon chronology of the Kushu sedimentary record has been utilised to generate a Bayesian age-depth model, providing an age for the Kushu tephra which is consistent with high resolution ages determined for the eruption and therefore supports our geochemical correlation. Two further Bayesian age-depth models were independently constructed each incorporating one of two ice-core derived ages for the B–Tm tephra, providing Bayesian modelled ages of 933–949 and 944–947 cal AD (95.4%) for the Kushu tephra. The high resolution ice-core tephra ages imported into the deposition models help test and ultimately constrain the radiocarbon chronology in this interval of the Lake Kushu sedimentary record. The observed geochemical diversity between proximal and distal ME tephra deposits clearly evidences the interaction of two compositionally distinct magma batches during this caldera forming eruption.     

The last 40 ka tephrostratigraphic record of Lake Ohrid,Albania and Macedonia: a very distal archive for ash dispersal from Italian volcanoes

A 1075 cm long core (Lz1120) was recovered in the south-eastern part of the Lake Ohrid (Republics of Macedonia and Albania) and sampled for identification of tephra layers. Magnetic susceptibility investigations show rather high magnetic values throughout the core, with peaks unrelated to the occurrence of tephra layers but instead to the relative abundance of detrital magnetic minerals in the sediment. Naked-eye inspection of the core allowed us to identify of two tephra layers, at 896–897 cm and 1070–1075 cm. Laboratory inspection of the grain-size fraction > 125 μm allowed for the identification of a third cryptotephra at 310–315 cm. Major element analyses on glass shards of the tephra layers at 896–897 cm and 1070–1075 cm show a trachytic composition, and indicate a correlation with the regionally dispersed Y-3 and Y-5 tephra layers, dated at ca 30 and 39 cal ka BP. The cryptotephra at 310–315 cm has a mugearitic–benmoreitic composition, and was correlated with the FL eruption of Mt. Etna, dated at 3370 ± 70 cal yr BP. These ages are in agreement with five ¹⁴C AMS measurements carried out on plant remains and macrofossils from the lake sediments at different depths along the core.     

Low temperature (LT) combustion of sediments does not necessarily provide accurate radiocarbon ages for site chronology

Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies.     

Bayesian estimates of marine radiocarbon reservoir effect in northern Iberia during the Early and Middle Holocene

Reconstructing the past variability of marine radiocarbon reservoir effects (MRE) is crucial for generating reliable chronologies for marine species and their consumers. We investigated the temporal MRE variability at the Early-to Mid-Holocene site of El Mazo (Asturias, northern Spain) by using a combination of new and previously published radiocarbon measurements on marine and terrestrial samples. The El Mazo site is characterized by overall well-defined archaeological layers of unknown occupation length with the predominant presence of two mollusc species (Patella vulgata Linnaeus, 1758 and topshell Phorcus lineatus [da Costa, 1778]) which were analysed for radiocarbon measurements. We employed the recently released IntCal20 calibration curve for the northern hemisphere and Bayesian modelling to reconstruct the site's chronology and temporal variability in MREs according to mollusc species. Obtained radiocarbon modelling results, although the estimate precision is not high, reveal a temporal variability in MREs that can be interpreted in view of known past climatic and environmental events such as the 8.2 ka event. The results also revealed differences in MREs according to mollusc species, which need to be taken into account in future chronological modelling. Overall, our results provide reference MRE values for the study of chronologies in northern Iberia during the Early-to Mid-Holocene. In this respect, a non-conservative ΔR reference for local marine samples dating earlier than c. 8.1 ka cal BP is −238 ± 28 ¹⁴C years.     

Clinopyroxene and Fe-Ti oxides for correlating the ash from Changbaishan Millennium eruption

Volcanic glass compositions and tephra layer age are critical for anchoring their sources and correlating among different sites; however, such work may be imprecise when the tephra has varied compositions. The ash from Changbaishan Millennium eruption (940s AD), a widely distributed tephra layer, has been detected in the far-east areas of Russia, the Korean Peninsula, Japan, and in Greenland ice cores. There are some debates on the presence of this tephra from sedimentary archives to the west of Changbaishan volcano, such as lake and peat sediments in the Longgang volcanic field. In this paper, major element compositions for clinopyroxene and Fe-Ti oxides were performed on proximal tephra from Changbaishan and the Millennium eruption ash record in Lake Sihailongwan. Clinopyroxene and Fe-Ti oxides microlites from Sihailongwan show augite- ferroaugite and titanmagnetite compositions, similar to those from dark pumice in Changbaishan proximal tephra, but different from the light grey pumice, which has ferrohedenbergite and ilmenite microlite compositions. This result implies that the tephra recorded in Sihailongwan was mainly from the trachytic eruptive phase of the Millennium eruption, and the rhyolitic eruptive phase made a relatively small contribution to this area. Analyzing clinopyroxene and Fe-Ti oxides microlites is a new method for correlating tephra layers from Changbaishan Millennium eruption.     

TEPHRA RECORD FROM QUANYANG PEAT OF THE CHANGBAISHAN MILLENNIUM ERUPTION

Tephra, usually produced by explosive eruptions, is deposited rapidly, hence, it can serve as a distinctive and widespread synchronous marker horizon correlating terrestrial, marine and ice core records. The tephra from Changbaishan Millennium eruption, a widely distributed tephra, is an important marker bed across the Japan Sea, Japan Islands and even in the Greenland ice cores 9000km away from volcanic vent. In this study, a discrete tephra was identified in the Quanyang peat~45km northeast to the Changbaishan volcano. Radiocarbon ¹⁴ C dating on the plant remains constrains an age of 886-1013calAD(95.4%)to the tephra layer, which can correspond to the Millennium eruption of Changbaishan in time. In addition, there was no similar volcanic eruption in the surrounding areas except Changbaishan at the same time. This tephra shows rhyolitic glass shards major element compositions similar to those rhyolitic tephra from Millennium eruption. This study illustrates that tephra from Millennium eruption has been transported to Quanyang peat~45km northwest to the Changbaishan volcano. Additionally, the diameter of the pumice lapilli is up to 0.3cm, implying that the tephra must be transported more distal away from Quanyang peat and formed a widely distributed isochronic layer. Glass geochemistry of the Quanyang tephra, different from the distal tephra recorded at Sihailongwan, Japan, and Greenland ice, shows a close affinity to the pyroclastic flow deposits of the Millennium eruption while not from fall deposits. This may indicate that distribution of the Millennium eruption of Changbaishanin in different directions may be controlled by different stages of eruption. This layer with well-defined annual results can be used to optimize the chronological framework of the corresponding sedimentary environment, thus facilitating more accurate discussion of corresponding environmental changes, which can achieve the contrast of the ancient climate records in the whole Northeast China-Japan and arctic regions.     

Regional beryllium-10 production rate calibration for late-glacial northeastern North America

The major uncertainty in relating cosmogenic-nuclide exposure ages to ages measured by other dating methods comes from extrapolating nuclide production rates measured at globally scattered calibration sites to the sites of unknown age that are to be dated. This uncertainty can be reduced by locating production rate calibration sites that are similar in location and age to the sites to be dated. We use this strategy to reconcile exposure age and radiocarbon deglaciation chronologies for northeastern North America by compiling ¹⁰Be production rate calibration measurements from independently dated late-glacial and early Holocene ice-marginal landforms in this region. ¹⁰Be production rates measured at these sites are 6–12% lower than predicted by the commonly accepted global ¹⁰Be calibration data set used with any published production rate scaling scheme. In addition, the regional calibration data set shows significantly less internal scatter than the global calibration data set. Thus, this calibration data set can be used to improve both the precision and accuracy of exposure dating of regional late-glacial events. For example, if the global calibration data set is used to calculate exposure ages, the exposure-age deglaciation chronology for central New England is inconsistent with the deglaciation chronology inferred from radiocarbon dating and varve stratigraphy. We show that using the regional data set instead makes the exposure age and radiocarbon chronologies consistent. This increases confidence in correlating exposure ages of ice-marginal landforms in northeastern North America with glacial and climate events dated by other means.     

The first tephra evidence for a Late Glacial explosive volcanic eruption in the Arxan-Chaihe volcanic field (ACVF), northeast China

A 5 mm thick tephra layer has been identified in the lacustrine sediments of Moon Lake in the Arxan-Chaihe volcanic field (ACVF) in Greater Khingan Mountains (NE China). The visible tephra layer is clearly revealed as a distinct peak in magnetic susceptibility measurements. The tephra layer consists mainly of brown vesicular glass shards and minor amounts of plagioclase, olivine and clinopyroxene. Major and minor element analysis has been carried out on the glass shards and plagioclase minerals. Glass shards show low concentrations of K₂O, similar to the eruptive products derived from post-Miocene volcanoes of the ACVF. The plagioclase phenocrysts in both lava and tephra from ACVF, and in the tephra recorded in Moon Lake are labradorites. During the Late Pleistocene to Holocene, there were also extensive explosive eruptions in the nearby Nuominhe volcanic field (NVF). Volcanic rocks from the ACVF are easily distinguished from those derived from the NVF, having distinctly different K₂O concentrations. This compositional variation is likely the result of different magmatic processes operating in the ACVF and NVF. Radiocarbon dating on organic materials from the lacustrine sediments dates the tephra layer to ca. 14,200 cal yrs BP, which implies that it was generated by a previously unknown Late Pleistocene explosive eruption in the ACVF. These results, for the first time, give a direct tephra record in this area, and suggest that identification of further tephra and/or cryptotephra in local sedimentary basins such as crater lakes of scoria cones and maars will be significant for dating the Late Pleistocene to Holocene volcanic eruptions and will help to establish a detailed record of the volcanic activity in the ACVF. The newly discovered tephra layer also provides a dated tephrochronological marker layer, which will in future studies provide a means to synchronise local sedimentary records of the climatically variable Late Glacial.     

Improved age estimates for Holocene Ko-g and Ma-f~j tephras in northern Japan using Bayesian statistical modelling

The Ko-g and Ma-f~j tephras are two key isochronous marker layers in northern Japan, which are from the largest Plinian eruptions of Komagatake volcano (VEI = 5) and Mashu caldera (VEI = 6), respectively. Despite extensive radiocarbon studies associated with the two tephras, individual calibrated results show considerable variations and thus accurate ages of these important eruptions remain controversial. Bayesian statistical approaches to calibrating radiocarbon determinations have proven successful in increasing accuracy and sometimes precision for dating tephras, which is achieved through the incorporation of additional stratigraphic information and the combination of evidence from multiple records. Here we use Bayesian approaches to analyse the proximal and distal information associated with the two tephra markers. Through establishing phase and deposition models, we have taken into account all of the currently available stratigraphic and chronological information. The cross-referencing of phase models with the deposition model allows the refinement of eruption ages and the deposition model itself. Using this we are able to provide the most robust current age estimates for the two tephra layers. The Ko-g and Ma-f~j tephras are hereby dated to 6657-6505 (95.4%; 6586±40, μ±σ) cal yr BP, and 7670-7395 (95.4%; 7532±72, μ±σ) cal yr BP, respectively. These updated age determinations underpin the reported East Asian Holocene tephrostratigraphic framework, and allow sites where the tephra layers are present to be dated more precisely and accurately. Our results encourage further applications of Bayesian modelling techniques in the volcanically active East Asian region.     

The Campanian Ignimbrite and Codola tephra layers: Two temporal/stratigraphic markers for the Early Upper Palaeolithic in southern Italy and eastern Europe

Tephra layers from archaeological sites in southern Italy and eastern Europe stratigraphically associated with cultural levels containing Early Upper Palaeolithic industry were analysed. The results confirm the occurrence of the Campanian Ignimbrite tephra (CI; ca. 40 cal ka BP) at Castelcivita Cave (southern Italy), Temnata Cave (Bulgaria) and in the Kostenki–Borshchevo area of the Russian Plain. This tephra, originated from the largest eruption of the Phlegrean Field caldera, represents the widest volcanic deposit and one of the most important temporal/stratigraphic markers of western Eurasia. At Paglicci Cave and lesser sites in the Apulia region we recognise a chemically and texturally different tephra, which lithologically, chronologically and chemically matches the physical and chemical characteristics of the Plinian eruption of Codola; a poorly known Late Pleistocene explosive event from the Neapolitan volcanoes, likely Somma–Vesuvius. For this latter, we propose a preliminary age estimate of ca. 33 cal ka BP and a correlation to the widespread C-10 marine tephra of the central Mediterranean. The stratigraphic position of both CI and Codola tephra layers at Castelcivita and Paglicci help date the first and the last documented appearance of Early Upper Palaeolithic industries of southern Italy to ca. 41–40 and 33 cal ka BP, respectively, or between two interstadial oscillations of the Monticchio pollen record – to which the CI and Codola tephras are physically correlated – corresponding to the Greenland interstadials 10–9 and 5. In eastern Europe, the stratigraphic and chronometric data seem to indicate an earlier appearance of the Early Upper Palaeolithic industries, which would predate of two millennia at least the overlying CI tephra. The tephrostratigraphic correlation indicates that in both regions the innovations connected with the so-called Early Upper Palaeolithic – encompassing subsistence strategy and stone tool technology – appeared and evolved during one of the most unstable climatic phases of the Last Glacial period. On this basis, the marked environmental unpredictability characterising this time-span is seen as a potential ecological factor involved in the cultural changes observed.     

Single-grain optically stimulated luminescence dating of quartz temper from prehistoric Intermountain Ware ceramics,northwestern Wyoming,USA

This study applies single-grain optically stimulated luminescence (SG OSL) dating of quartz sand temper to Intermountain Ware ceramics recovered from four archaeological sites in northwestern Wyoming, USA. We show that SG OSL dating can strengthen and further refines existing archaeological site chronologies in certain settings. The SG OSL results are compared to multi-grain infrared stimulated luminescence (IRSL) dating of the polymineral (feldspar and quartz) silt fraction in the ceramic paste of the same sherds. Results from the two methods are statistically indistinguishable, although coarse-grained quartz SG OSL ages have consistently lower standard error terms due to higher relative sensitivity and avoidance of anomalous fading calculations. Moreover, the SG OSL results produced precision at two-sigma standard error greater than or equal to associated calibrated radiocarbon ages. SG OSL dating of quartz temper from Intermountain Ware ceramics provides more reliable site occupation timing than radiocarbon dating, which can be conditioned by incorporation of old wood and contamination from young soil carbon. This study highlights the importance of SG OSL dating on sherds from buried contexts when exposure to wildfires may have occurred, as ceramics recovered from the ground surface of one site after a high-intensity fire produced near-modern apparent ages, suggesting they were thermally reset during the fire. We suggest SG OSL should be applied to date similar ceramics with quartz temper to determine site age and bolster regional chronologies.     

Using the N/C ratio to correct bulk radiocarbon ages from lake sediments: Insights from Chilean Patagonia

The offset between AMS radiocarbon ages obtained on bulk lake sediments and the true age of deposition was evaluated at four sites in Northern Chilean Patagonia. Our results show that the bulk radiocarbon ages are systematically older by 300 to 1100 years. In this region free of carbonate and carbonaceous rocks, we argue that this difference results from variable inputs of terrestrial organic carbon from the Holocene soils that cover the lake watersheds. For the four studied lakes, the age offset is clearly related to the fraction of terrestrial carbon preserved in the lake sediments, which was estimated using the N/C ratio of the bulk organic matter. We propose that N/C measurements can be used to significantly improve chronologies based on radiocarbon dating of bulk lake sediments.     

Stratigraphic framework of Holocene volcaniclastic deposits, Akutan Volcano, east-central Aleutian Islands, Alaska

 Akutan Volcano is one of the most active volcanoes in the Aleutian arc, but until recently little was known about its history and eruptive character. Following a brief but sustained period of intense seismic activity in March 1996, the Alaska Volcano Observatory began investigating the geology of the volcano and evaluating potential volcanic hazards that could affect residents of Akutan Island. During these studies new information was obtained about the Holocene eruptive history of the volcano on the basis of stratigraphic studies of volcaniclastic deposits and radiocarbon dating of associated buried soils and peat. A black, scoria-bearing, lapilli tephra, informally named the "Akutan tephra," is up to 2 m thick and is found over most of the island, primarily east of the volcano summit. Six radiocarbon ages on the humic fraction of soil A-horizons beneath the tephra indicate that the Akutan tephra was erupted approximately 1611 years B.P. At several locations the Akutan tephra is within a conformable stratigraphic sequence of pyroclastic-flow and lahar deposits that are all part of the same eruptive sequence. The thickness, widespread distribution, and conformable stratigraphic association with overlying pyroclastic-flow and lahar deposits indicate that the Akutan tephra likely records a major eruption of Akutan Volcano that may have formed the present summit caldera. Noncohesive lahar and pyroclastic-flow deposits that predate the Akutan tephra occur in the major valleys that head on the volcano and are evidence for six to eight earlier Holocene eruptions. These eruptions were strombolian to subplinian events that generated limited amounts of tephra and small pyroclastic flows that extended only a few kilometers from the vent. The pyroclastic flows melted snow and ice on the volcano flanks and formed lahars that traveled several kilometers down broad, formerly glaciated valleys, reaching the coast as thin, watery, hyperconcentrated flows or water floods. Slightly cohesive lahars in Hot Springs valley and Long valley could have formed from minor flank collapses of hydrothermally altered volcanic bedrock. These lahars may be unrelated to eruptive activity. Received: 31 August 1998 / Accepted: 30 January 1999