Magnetostratigraphy of Plio–Pleistocene fossiliferous cave sediments in the Bubing Basin,southern China

Our understanding of the chronological sequence of Pleistocene land mammal faunas (including hominids) preserved in caves and fissures in the karstic terrain of subtropical southern China has been greatly impeded by the discontinuous nature of the strata yielding the fossils. A contributory issue is the lack of suitable elements for numerical dating, especially for the Early Pleistocene cave sediments. Here we present new magnetostratigraphic dating results for five cave sedimentary sequences in the Bubing Basin, Guangxi Zhuang Autonomous Region, which contain the typical Pleistocene Gigantopithecus fauna and Ailuropoda–Stegodon fauna of southern China. The five karstic caves are situated at elevations ranging from 252 m to 191 m above sea level. The integrated dating results reveal that the five cave sedimentary sequences span an age range from the late Gauss normal Chron to the early Brunhes normal Chron. The faunas are assigned to >2.6 Ma (Mohui–houshan Cave), 1.95–1.78 Ma (Mohui Cave), 0.99–0.78 Ma (Baolai Cave) and ∼0.7 Ma (Upper Wuyun and Ganxian Caves). Furthermore, by combining our new magnetostratigraphy work with previously published magnetostratigraphic, U–series and electron spin resonance dating results, a chronological sequence of the Plio–Pleistocene mammalian faunas from cave sites in southern China has been established. The chronological sequence contributes to an improved understanding of the evolutionary processes of Plio–Pleistocene land mammals, as well as of early humans in subtropical southern China.     

230Th/U chronology of a paleolithic site at Xinglong Cave in the three-Gorge region of south China

Xinglong Cave, containing four human teeth, numerous mammalian fossils, stone artifacts and a Stegodon tusk with intentional and seemingly grouped engravings, is one of the most significant archaic Homo sapiens sites in south China, located 95 km south of Fengjie County, in Chongqing. In an attempt to constrain the age of the human relics, calcitic flowstone deposits with a significant detrital component were dated by U–Th methods using a leachate scheme. Total sample digestion MC-ICPMS dating was used to assess the reliability of the leachate technique. Six calcite samples from horizons beneath and above the fossil-bearing layer were dated. We obtained ages of 130 ± 9.1, 124 ± 11, 135 ± 12 and 127 ± 11 ka for the flowstones above the fossil layer with a weighted mean of 128.9 ± 5.2 ka. Two flowstone samples gave MC-ICPMS dates between 128.3 ± 3.3 and 152.4 ± 25.3 ka with an assumed detrital component to correct for the initial ²³⁰Th, which are consistent with results obtained using the L/L regression data from layer U-4 within uncertainty. All errors herein quoted at the 2σ level. Ages determined for the flowstone underlying the fossil-bearing layer were 221 ± 29 to 189 ± 19 ka with a weighted mean age of 199 ± 16 ka. These results are stratigraphically consistent within error limits and show that the cave was occupied by Fengjie Man within the time range of ∼200 to ∼130 ka. These new U-series ages of flowstones in association with human teeth and an engraved stegodon tusk at the Xinglong Cave site provide valuable geochronologic information for the study of the origin of modern humans in East Asia and earliest human art.     

Optical dating of flowstone and silty carbonate-rich sediments from Panxian Dadong Cave,Guizhou, southwestern China

Panxian Dadong Cave located in the western Guizhou is a very important Paleolithic site in China. At this site bone and stone artifacts, human teeth and mammalian fossils (known as Ailuropoda-Stegodon fauna) were found, and the site was previously dated to 120–300 ka using ESR/uranium-series methods. In this study, we successfully extracted fine quartz grains from flowstone and silty carbonate-rich sediments in the excavated area. The quartz extracts displayed excellent luminescence properties, and satisfied the SAR (single-aliquot regenerative dose method) acceptance criteria. The sensitivity-corrected OSL signals are not saturated at a dose up to about 1400 Gy. The cultural unit was OSL dated to 190–300 ka, corresponding to MISs 7–8. The flowstone deposits overlying the cultural unit were determined to be 13–190 ka and the silty carbonate-rich sediments underlying the cultural unit to be 300–360 ka. The optical ages are in general agreement with the coupled ESR/U-series and U-series ages.     

Applying a Bayesian approach for refining the chronostratigraphy of the Yumidong site in the Three Gorges region,central China

Yumidong (Corn Cave) is a newly discovered Paleolithic site in the Three Gorges region of central China. Numerous Paleolithic artifacts have been excavated from the sedimentary deposits of the cave in association with faunal remains attributed to the Middle-Late Pleistocene Ailuropoda-Stegodon fauna of southern China. To establish the chronology of the sedimentary sequence (>5 m thick), ¹⁴C dating was applied to bone and charcoal samples (n = 6); the U-series method was used to date in situ precipitated speleothems (n = 12), transported speleothem samples (n = 6) and 18 subsamples of a fossil tooth; and the coupled ESR/U-series method was used to date fossil teeth (n = 6). The derived dates were combined using a hierarchical Bayesian approach to generate a unified chronostratigraphy for the Yumidong sequence. In our Bayesian analyses, the ¹⁴C and coupled ESR/U-series dates were considered to provide direct age estimates for the target layers, while the U-series dates of the in situ precipitated speleothems and fossil tooth were used as minimum age constraints and those of the transported speleothem fragments as maximum age constraints. The Bayesian analyses provided robust time intervals for the archeological layers: L2-Upper (14–23 ka), L2-Lower (27–63 ka), L3 (106–171 ka), L4 (140–192 ka), L10 (157–229 ka), L11 (181–256 ka), and L12 (214–274 ka) with a probability of 95%, allowing the establishment of a ∼300 ka long geological and archeological history for the Yumidong site and placing it as a reference site for Paleolithic cultural evolution in the Three Gorges region from the late Middle Pleistocene to Late Pleistocene.     

ESR chronology of the fluvial sequence of Cueva del Silo (Sierra de Atapuerca,Spain)

The Cueva del Silo is part of the lower karst level of the Cueva Mayor-Cueva del Silo karst system (Sierra de Atapuerca, Burgos, Spain), whose evolution has preserved an impressive archeo-paleoanthropological sequence since the Early Pleistocene. Cueva del Silo is remarkable for the presence of fluvial deposits that record the entry of the Arlanzón River water in the cave system, providing a key sequence to investigate the fluvio-karstic relationships that give rise to this endokarst system. In order to provide a chronological framework to these fluvial deposits, six sediment samples were dated by Electron Spin Resonance and 16 samples by paleomagnetism, collected from two outcrops: Galería de las Arenas and Sala del Caos. Our results provide maximum mean age of around 1600 ka and a minimum age of 916 ± 136 ka for the deposits in Sala del Caos. The younger date from Sala del Caos might represent the last fluvial input from Arlanzón River in the lower karst level. In contrast, ESR ages estimates of 1268 ± 133 ka and 1262 ± 108 ka were obtained for Galería de las Arenas sequence, which could indicate re-sedimentation processes from the intermediate karst level where similar ages were published. The annual dose might be wrongly assessed due to the re-sedimentation processes inside the karst, hence, ESR ages for these facies should be treated with extreme caution.     

Chronology of Early to Mid-Pleistocene sediments in the northern North Sea: New evidence from amino acid and strontium isotope analyses

Sediments deposited during glacial-interglacial cycles through the Early to Mid-Pleistocene in the North Sea are chronologically poorly constrained. To contribute to the chronology of these units, amino acid racemization (AAR) and strontium (Sr) isotope analyses have been performed on samples from four shallow borings and one oil well along a transect in the northern North Sea. D/L Asp (aspartic acid) values obtained through reverse-phase liquid chromatography in the benthic foraminiferal species Elphidium excavatum is focused on because of consistent results and a good stratigraphic distribution of this benthic species. For the Early Pleistocene, an age model for the well 16/1–8, from the central part of the northern North Sea based on Sr ages allows for dating of the prograding wedges filling the pre-Quaternary central basin. A regional calibration curve for the racemization of Asp in Elphidium excavatum is developed using published ages of radiocarbon-dated samples and samples associated with the previously identified Bruhnes/Matuyama (B/M) paleomagnetic boundary and a Sr age from this study. Based on all the available geochronological evidence, samples were assigned to marine oxygen isotope stages (MIS) with uncertainties on the order of 10–70 ka.Sr ages suggest a hiatus of <2 million years (Ma) possibly due to non-deposition or low sedimentation between the Utsira Formation (Pliocene) and the Early Pleistocene. An increase in sedimentation rates around 1.5 ± 0.07 Ma (∼MIS 51) may partly be due to sediment supply from rivers from the south-east and partly due to the extension of ice sheet around 1.36 ± 0.07 Ma from the Norwegian coast to the central North Sea. A possible basin-wide glaciation occurred around 1.1 Ma (∼ MIS 32) (upper regional unconformity/top of unit Q4 in this study), resulting in erosion and regional unconformity. Two interglacials in the Norwegian Channel have been dated: the Radøy Interglacial to 1.07 ± 0.01 Ma (possibly MIS 31, the ‘super interglacial’), and the Norwegian Trench Interglacial to 0.50 ± 0.02 Ma (possibly MIS 13). A massive till unit identified at the same stratigraphic level in all shallow borings may partly represent an extensive MIS 12 glaciation. This study shows that the combined use of amino acid racemization data and Sr isotope chronology can refine the chronological ambiguities of Quaternary North Sea sediments related partly to the impact of glacial processes.     

Cosmogenic isotope burial dating of fluvial sediments from the Lower Rhine Embayment,Germany

Cosmogenic isotope burial dating, using ¹⁰Be and ²⁶Al, was applied to Plio–Pleistocene fluvial successions from the Lower Rhine Embayment, Germany. The approach consists of three principal steps: (1) measurement of cosmogenic nuclides in depth profiles, (2) modelling of hypothetical nuclide concentrations based on a first-order conceptualisation of the geological context and the principal succession of depositions and subsequent erosional and burial phases, and (3) using parameter estimation to identify values for the a priori unknown model parameters (burial age, initial nuclide concentrations, terrace erosion rates) that result in minimal disagreement between hypothetical and measured nuclide concentrations.The Late Pliocene Kieseloolite Formation was dated to 3650 ± 1490 ka and the Early Pleistocene Waalre Formation to 900 ± 280 ka. The unconformably overlying Upper Terrace Formation revealed ages of 740 ± 210 ka and 750 ± 250 ka for the two different sites. These findings are in good agreement with independent age control derived by bio-, magneto-, and litho-stratigraphy. Furthermore, identifiability and uncertainty analysis reveal a relationship between burial depth and sensitivity of isotope concentrations to burial age and erosion rate. Our results indicate that using shallower buried samples would enable a considerably more robust estimation of the burial age and the terrace erosion rate. Uncertainties arose mainly from nuclide measurements, and not from the uncertainties derived from modelling or insufficient knowledge of nuclide production and decay properties.     

Radiometric dating of Meipu hominin site in China by coupled ESR/U-series and cosmogenic 26Al/10Be burial dating methods

The Three Gorges and Western Hubei area in the geographic central part of China was a potential migration corridor for early hominin and mammals linking South and North China during the Pleistocene period. Some key early hominin sites are known in this region where limestone cave and fissure sites are numerous but difficult to date as beyond the dating range of OSL and mass spectrometry U-series method. Here, we report radiometric dating study for such a hominin site, Meipu (Hubei Province), by coupled ESR and U-series dating of nine fossil teeth and cosmogenic ²⁶Al/¹⁰Be burial dating of one quartz sediment. The burial age calculated by simple burial model (573 ± 266 ka) gives a minimum age constraint of the sediment. The fossil dating provided two main age groups at 541 ± 48 ka and 849 ± 39 ka, the older age group is in agreement with the U-series age (>630 ka) of the flowstone overlying the fossil layer and the paleomagnetic data which placed the Brunhes-Matuyama boundary in the fossil layer. The reason of this age difference is probably caused by the U-content discrepancy in the enamel of the dated fossil samples. This study exhibits the limitation of ESR/U-series fossil dating and the importance of using multiple dating approach when it is possible in order to identify the problematic ages.     

Laser-ablation ICP-MS zircon U-Pb ages for key Pliocene-Pleistocene tephra beds in unglaciated Yukon and Alaska

Tephrochronology is one of the most effective ways to correlate and date Quaternary deposits across large distances. However, it can be challenging to obtain direct ages on tephra beds when they are beyond the limit of radiocarbon dating, do not contain mineral phases suitable for ⁴⁰K-⁴⁰Ar (or ⁴⁰Ar/³⁹Ar) dating, or suitable glass shards for fission-track dating are not available. Zircon U-Pb dating by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging technique for dating young (<1 Ma) tephra. Here, we demonstrate that LA-ICP-MS zircon U-Pb dating can produce reliable ages for key tephra beds found in Yukon and Alaska. We assessed five different techniques for calculating tephra maximum depositional ages from zircon U-Pb ages for eight tephra beds. Our preferred zircon U-Pb ages (reported with 2σ uncertainties), based on a Bayesian model for calculating maximum depositional ages, are broadly consistent with previously established chronology constructed from stratigraphy, paleomagnetism, and/or glass fission track and ⁴⁰Ar/³⁹Ar ages: Biederman tephra (178 ± 17 ka), HP tephra (680 ± 47 ka), Gold Run tephra (688 ± 44 ka), Flat Creek tephra (708 ± 43 ka), PA tephra (1.92 ± 0.06 Ma), Quartz Creek tephra (2.62 ± 0.08 Ma), Lost Chicken tephra (3.14 ± 0.07 Ma), and GI tephra (542 ± 64 ka). We also present newly revised glass fission-track and ⁴⁰Ar/³⁹Ar ages recalculated from previous determinations using updated ages for the Moldavite tektite and Fish Canyon Tuff standards, and updated K decay constants. For Pleistocene age zircon crystals, corrections for ²³⁰Th disequilibrium and common-Pb are significant and must be treated with caution. Similarly, apparent tephra ages are sensitive to the choice of method used to calculate a maximum depositional age from the assemblage of individual crystallization ages. This study demonstrates that LA-ICP-MS zircon U-Pb dating can be successfully applied to numerous Pliocene-Pleistocene Alaskan-Yukon tephra, providing confidence in applying this method to other stratigraphically important tephra in the region.     

Ages of Liangshan Paleolithic sites in Hanzhong Basin,central China

Thermally transferred optically stimulated luminescence (TT-OSL) dating extends the age range beyond current limits of OSL dating in Chinese loess. In this study, we use a single-aliquot regenerative-dose procedure for TT-OSL protocol to date Yaochangwan and Hejialiang localities of loess-covered Liangshan Paleolithic sites in Hanzhong Basin, which is an important area for the study of Paleolithic industries during the middle Pleistocene in central China. The results suggest that buried culture layer at the Hejialiang locality is correlated with the last interglacial paleosol S1 in Chinese Loess Plateau, it is dated at 86.3 ± 6.4 ka. The Yaochangwan locality spans from approximate 600–100 ka and correlates with S5–S1 in the typical Chinese loess–paleosol sequences, respectively. These ages suggest that hominins already occupied the Hanzhong Basin since approximately 600 ka ago.     

Challenges in constraining pluvial events and hominin activity: Examples of ESR dating molluscs from the Western Desert,Egypt

Receiving <0.1 mm/y of precipitation, Egypt’s hyperarid Western Desert, today lacks naturally occurring surface water. Artesian spring deposits, tufa deposited by springs and carbonate-rich silty lacustrine sediment attest that oases in the Western Desert had surface water during the Pleistocene. Paleolithic artefacts, fossil ungulate teeth, and snails occurring within the Pleistocene deposits and dotting the surface record times when higher rainfall and/or groundwater tables during pluvial events allowed surface water to exist in wetlands, small ponds and lakes, enabling hominin habitation. Archaeological finds ranging from Early to Later Stone Age (ESA–LSA) occur in gravel lags, within sedimentary deposits, and on the older geomorphic surfaces. Near Kharga, large tufa deposits ranging from a few hectares to more than 10 km² in area, such as Matana and Medauwara, dot the edge of the Libyan Plateau. Molluscs were dated using standard ESR protocols. To test for reworked fossils, multiple samples from a single sample were dated independently. In some units at Medauwara, multiple gastropod populations from different times have been preserved, while others appear to only preserve a single population. To see the effects of the cosmic dose rate on ESR ages, ages were calculated using zero cosmic dose rate, the full modern cosmic dose rate, and time-averaged cosmic and sedimentary dose rates. For gastropods from Matana, no significant difference in ESR ages resulted from different cosmic dose rate assumptions. Therefore, at Matana 2, the shells dated at 27.7 ± 1.9 assuming time-averaged external dose rates, while at Matana 3, they averaged 65.1 ± 4.1 ka, suggesting that water was present for hominin use at times during OIS 2 and 4.     

When were the walls of the Chauvet-Pont d'Arc Cave heated? A chronological approach by thermoluminescence

Direct chronological data of the ancient heating of calcitic walls at the Chauvet-Pont d'Arc Cave (Ardèche, France) were obtained at the Galerie des Mégacéros and at the Eboulis d'Entrée. Fragments of reddened limestone were extracted from the walls and were studied by thermoluminescence (TL). A novel measurement protocol of the equivalent dose (ED) was implemented and was optimized with respect to the nature of the material being dated (calcite), to the small quantities of sample available and to the relatively low heating of the rock surface in the past (close to 350 °C). The presence of a high level of free radon in the cave and ²¹⁰Pb in large excess in samples implied the development of a specific irradiation model allowing the evaluation of the mean annual dose over time, taking into account possible scenarios of radon and daughters migration from the bedrock. The following dating results were obtained (in ka before the present and associated total estimated standard deviation):- Galerie des Mégacéros, 36.9 ± 2.3 ka.- Eboulis d'Entrée, 34.3 ± 2.9 ka.These data are in agreement with the calibrated radiocarbon dates of the most ancient periods of human occupation in their respective areas. TL dates indicate that the fires which altered the walls were lighted during the first paleolithic human occupation period. Eventually, TL dating of the heated surface of the bedrock opens a new window on the chronology of human activities in the Chauvet-Pont d'Arc Cave and it makes an alternative contribution to the demonstration of the early chronology of its rock art.     

Direct U–Th dating of vertebrate fossils with minimum sampling destruction and application to museum specimens

Although vertebrate fossils are commonly abundant in museum palaeontological collections, they are only rarely accompanied by contextual data (e.g., stratigraphic and taphonomic information) that allow them to be placed independently into reliable temporal frameworks critical for testing significant evolutionary and extinction hypotheses. Moreover, where critical samples do exist in such collections, sampling for direct geochronological analyses becomes a significant concern, especially where such sampling is destructive in nature. Here we apply a direct fossil dating, micro-drilling sampling approach that minimises damage to and destruction of precious museum specimens. We carried out a systematic U–Th dating study (n = 28 ages) of an isolated museum specimen of the extinct Palorchestes azael (megafaunal ‘marsupial tapir’) originally collected in 1977 from Tea Tree Cave, Chillagoe, northeastern Australia. We obtained 21 U–Th ages and constructed ²³⁰Th-age profiles across three teeth exposed in cross-section, using micro-drilling and thermal ionisation mass spectrometry. Individual sample masses were as little as 0.18 mg (U concentration 33–82 ppm), meaning that the sampling resulted in only minimal destruction of the specimen. The results show no evidence of U leaching, suggesting that the dates represent reliable minimum ages. For independent age control, we also dated calcite that had encrusted the sample (thus, providing a minimum age; n = 6) and an older calcite clast that had been reworked into the surrounding breccia at the time of burial (thus, providing a maximum age; n = 1). U–Th ages of the teeth are older than the calcite overgrowths and younger than the reworked calcite, consistent with their demonstrable relative age relationships. Collectively, the results unequivocally bracket the age of the fossil between 199.1 ± 8.9 ka and 137.4 ± 1.1 ka (2σ), adding another rare datum to inform the timing and geographic distribution of last occurrences of the species. The benefits of our dating approach of museum fossil specimens are threefold: 1) it is minimally destructive even compared with laser-ablation method; 2) the use of U vs. apparent age approach allows direct testing for potential U leaching as occasionally seen in fossil dating; and 3) the combination of fossil and associated speleothem dating provides the most robust means of securely bracketing the age of fossils that lack firm stratigraphic control.     

ESR/U-series dating of Eemian human occupations of Northern France

Palaeolithic sites associated with the Eemian Interglacial (MIS 5e) are very rare in NW Europe, and especially in Northern France, where their preservation is restricted to very specific geological contexts, in association with carbonated tufa (Caours) or peat deposits (Waziers). In order to check the reliability of ESR/U-series method to date teeth recovered from archaeological levels in such specific geological environments, teeth were sampled on these two Middle Palaeolithic sites and systematic in situ dosimetry was performed using portable gamma spectrometer. The ESR/U-series ages obtained on the Caours site are very homogeneous allowing the calculation of a mean age equal to 125 ± 11 ka, in agreement with the geological age, mammal's association and other available geochronological data (U-series on tufa carbonate, TL on burnt flints, OSL on sediments), despite a relatively heterogeneous dosimetric environment (gamma dose rate ranging between ca 200–450 μGy/a). At Waziers, reducing (water logging) environment linked to the peat leads to very specific U-series data of the analysed teeth (U content lower than 0.1 ppm in all the dental tissues, evidence of leaching in some tissues), but the mean ESR/U-series age, 129 ± 4 ka, is also in agreement with the available geological and palaeoenvironmental data indicating that the dated teeth were associated with Late Glacial deposits prior to the climatic interglacial optimum. These two case studies then confirm the reliability of ESR/U-series method to date with good reliability and accuracy the archaeological levels linked to such relatively short climatic events (ca 10 ka).     

Refining the Quaternary Geomagnetic Instability Time Scale (GITS): Lava flow recordings of the Blake and Post-Blake excursions

The Blake excursion was among the first recognized with directional and intensity behavior known mainly from marine sediment and Chinese loess. Age estimates for the directional shifts in sediments are poorly constrained to about 118−100 ka, i.e., at the marine isotope stage (MIS) 5e/5d boundary. Moreover, sediments at Lac du Bouchet maar, France and along the Portuguese margin reveal what may be a "post-Blake" excursion at about 105−95 ka. The excursional directions are associated with a prominent paleointensity minimum between about 125 and 95 ka in global stacked records. Lava flow recordings of the Blake excursion(s) have, however, been questionable because precise ages required for correlation with these sediment records are lacking. To establish new, independent records of the Blake excursion, and link these into a larger Quaternary GITS, we have undertaken ⁴⁰Ar/³⁹Ar incremental heating and unspiked K-Ar experiments on groundmass from the transitionally magnetized Inzolfato flow on Lipari Island. We also obtained ⁴⁰Ar/³⁹Ar incremental heating results for a lava flow on Amsterdam Island originally thought to record the Mono Lake excursion and from the transitionally magnetized El Calderon basalt flow, New Mexico that was K-Ar dated by Champion et al. (1988) at 128 ± 66 ka.Unspiked K-Ar ages of four samples from the Inzolfato flow are 102.5 ± 4.7, 101.3 ± 3.3, 97.1 ± 2.6, and 96.8 ± 3.1 ka and thus indistinguishable from one another. ⁴⁰Ar/³⁹Ar results are more complex, with three samples yielding discordant age spectra. Based on incremental heating data obtained in both the UW-Madison and Gif-sur-Yvette ⁴⁰Ar/³⁹Ar laboratories, a fourth sample yields six concordant age plateaus and a weighted mean age of 105.2 ± 1.4 ka that we take as the best estimate of time since the flow erupted. Five ⁴⁰Ar/³⁹Ar incremental heating experiments on the Amsterdam Island lava yield a plateau age of 120 ± 12 ka, whereas ages from two sites in the Calderon flow are 112 ± 23 and 101 ± 14 ka, together giving a weighted mean of 104 ± 12 ka. The age of 120 ± 12 ka from Amsterdam Island, though imprecise, correlates with the Blake excursion. In contrast, the 104–105 ka age obtained from both Lipari and New Mexico indicates that these lavas record a younger period of dynamo instability, most probably associated with the post-Blake excursion. These radioisotopic ages are consistent with the astronomical ages of two paleointensity minima in the PISO-1500 global stack. Our findings indicate that the Blake and post-Blake excursions are both global features of past geodynamo behavior and support the hypothesis that Brunhes chron excursions are temporally clustered into two groups of at least a half-dozen each spanning over 220 to 30 ka and 720 to 520 ka.     

High-precision 40Ar/39Ar dating of pleistocene tuffs and temporal anchoring of the Matuyama-Brunhes boundary

High-precision ⁴⁰Ar/³⁹Ar ages for a series of proximal tuffs from the Toba super-volcano in Indonesia, and the Bishop Tuff and Lava Creek Tuff B in North America have been obtained. Core from Ocean Drilling Project Site 758 in the eastern equatorial Indian Ocean contains discrete tephra layers that we have geochemically correlated to the Young Toba Tuff (73.7 ± 0.3 ka), Middle Toba Tuff (502 ± 0.7 ka) and two eruptions (OTTA and OTTB) related to the Old Toba Tuff (792.4 ± 0.5 and 785.6 ± 0.7 ka, respectively) (⁴⁰Ar/³⁹Ar data reported as full external precision, 1 sigma). Within ODP 758 Termination IX is coincident with OTTB and hence this age tightly constrains the transition from Marine Isotope Stage 19–20 for the Indian Ocean. The core also preserves the location of the Australasian tektites, and the Matuyama-Brunhes boundary with Bayesian age-depth models used to determine the ages of these events, c. 786 and c. 784 ka, respectively. In North America, the Bishop Tuff (766.6 ± 0.4 ka) and Lava Creek Tuff B (627.0 ± 1.5 ka) have quantifiable stratigraphic relationships to the Matuyama-Brunhes boundary. Linear age-depth extrapolation, allowing for uncertainties associated with potential hiatuses in five different terrestrial sections, defines a geomagnetic reversal age of 789 ± 6 ka. Considering our data with respect to the previously published age data for the Matuyama-Brunhes boundary of Sagnotti et al. (2014), we suggest at the level of temporal resolution currently attainable using radioisotopic dating the last reversal of Earths geomagnetic field was isochronous. An overall Matuyama-Brunhes reversal age of 783.4 ± 0.6 ka is calculated, which allowing for inherent uncertainties in the astronomical dating approach, is indistinguishable from the LR04 stack age (780 ± 5 ka) for the geomagnetic boundary. Our high-precision age is 10 ± 2 ka older than the Matuyama-Brunhes boundary age of 773 ± 1 ka, as reported previously by Channell et al. (2010) for Atlantic Ocean records. As ODP 758 features in the LR04 marine stack, the high-precision ⁴⁰Ar/³⁹Ar ages determined here, as well as the Matuyama-Brunhes boundary age, can be used as temporally accurate and precise anchors for the Pleistocene time scale.     

A targeted drilling and dating campaign to identify Stone Age archaeological sites before excavation in west coast southern Africa

Here we present the results of a targeted drilling campaign that facilitated a geochronological study with coarse sampling resolution inside a new cave site, Simons Cave, on the west coast of southern Africa. A combination of radiocarbon (¹⁴C) dating and optically stimulated luminescence (OSL) dating was used as a range-finder. Results confirmed preservation of Holocene and late Pleistocene sediments up to 133 ± 35 ka, overlapping with the ages of Middle Stone Age (MSA) occupations of the broader west coast region. A subsequent, systematic test-excavation at the site then embarked on a second geochronological study with a higher sampling resolution. Ultimately, the comparative study confirmed the potential of Simons Cave as a new site for the exploration of hominin occupation through the later Pleistocene and Holocene, yet raised several issues concerning the direct comparability of information deriving from drilled sediment cores and actual archaeological excavation.     

New ESR/U-series dates of the lowest Acheuleo-Yabrudian levels of Qesem cave

Qesem cave is a Middle Pleistocene site located close to Tel Aviv, Israel, assigned to the Acheuleo-Yabrudian Cultural Complex (AYCC) of the Lower Palaeolithic. The site provides rich assemblages of knapped flint, animal remains and some human teeth making it of particular interest. Its location in the Levantine corridor confers a major interest to the understanding of human dynamics during the Middle Pleistocene.A series of 6 herbivorous teeth from the base of the 11 m archaeological sequence of AYCC Qesem Cave was analysed by combined ESR/U-series method; this complements previous dating series carried out on teeth and on heated flints on higher parts of the sequence (Mercier et al., 2013; Falguères et al., 2016) The teeth were measured according a regular protocol for which each tissue was analysed by inductively coupled plasma-quadrupole mass spectrometry (ICP-Q-MS) for U-series using a combination of a Thermo iCAP-RQ mass spectrometer coupled to a Cetac Aridus III desolvator system, and ESR analyses were implemented on enamel tissue. All these data were combined in order to yield modelled ages.The goal was to find out whether there was a time gap between the carbonates layers dated to 420 ka (Gopher et al., 2010) and archaeological layers of the AYCC found throughout the cave's sequence. The new results yield ages ranging between 220 and 430 ka confirming a great antiquity and a long duration of AYCC in the Levant.     

Optical dating of a hyperconcentrated flow deposit on a Yellow River terrace in Hukou,Shaanxi, China

A sand layer, interpreted as a hyperconcentrated flow deposit, was found interbedded between loess on a Yellow River terrace in Hukou, Shaanxi, China. The site is known as the Longwangchan Palaeolithic site. The deposits from the terrace were dated using optically stimulated luminescence (OSL). Two samples from the sand layer were dated to 30 ± 2 and 33 ± 3 ka using coarse-grained (CG) quartz, and to 82 ± 7 and 94 ± 5 ka using fine-grained (FG) quartz, respectively. The CG quartz OSL ages are believed to be reliable on the basis of the OSL ages of the bracketing loess samples. The overestimation of the FG quartz OSL ages of the sand samples is explained in terms of hyperconcentrated flow processes during sediment transport and deposition. The large difference between the CG and FG quartz OSL ages of the sand samples helps to better understand the formation of the hyperconcentrated flow deposit. The hyperconcentrated flow deposit in this study indicates an extreme river flood occurring at ～30 ka in this area. In addition, the stone artifacts found in the lower loess layer overlying the bedrock of the terrace were dated to ～47 ka.     

40Ar/39Ar constraints on some French landmark Late Pliocene to Early Pleistocene large mammalian paleofaunas: Paleoenvironmental and paleoecological implications

To improve the French Plio-Pleistocene biostratigraphy scheme based on mammal biozone boundaries or “Mammal Neogene/Quaternary Zones” (MNQ) we collected volcanic material that could be dated using the ⁴⁰Ar/³⁹Ar method in five exceptional mammalian paleofauna sites located in the Massif Central (France). We present ⁴⁰Ar/³⁹Ar ages that we obtained for Perrier-Les Etouaires, Roca-Neyra, Chilhac, Senèze and le Creux de Peyrolles. We show that the overall stratigraphic position of these sites based on faunal assemblages is valid from the relative point of view. However, we greatly improve both the accuracy and precision of the age of these mammalian paleofaunas. We obtained ⁴⁰Ar/³⁹Ar ages varying between 2.78 ± 0.01 Ma (1σ external) for Les Etouaires (Lower MNQ 16b) and 1.47 ± 0.01 Ma for the Creux de Peyrolles site (MNQ 19). Based on these new dates we estimate the duration of several biozones including MNQ 16b, 17a and 17b. We suggest that the first Late Villafranchian biozone (MNQ 18) starts as early as the Reunion subchron or just after. The first occurrence of Equus stenonis in Roca-Neyra (i.e. 2.60 ± 0.02 Ma) is close to or synchronous with the Gauss–Matuyama transition (i.e. 2.59 Ma) and the Pliocene/Pleistocene boundary. The chronological framework we build shows the very rapid increase of the large grazers community in French faunal assemblages at the beginning of MNQ 17 (i.e. 2.6 to 2.4 Ma). This rapid faunal turnover is probably associated with a general decrease of woodland habitat in the Massif Central contemporaneous with the onset of the Northern Hemisphere glaciations. The faunal assemblages in France, Spain, and Italy covering the period between 2.1 and 2.0 Ma suggest that favorable conditions for early hominin settlement (mainly savannah prairies, grassland with open forest patches) existed in southwestern Europe at least 200 ka before the first traces of Homo in Eurasia. This period also shows the arrival of taxa originating in Asia and Africa, suggesting dispersal events within southwestern Europe well before the Olduvai subchron and with no indication (as yet) of Homo as a “fellow traveler”.