Low temperature (LT) combustion of sediments does not necessarily provide accurate radiocarbon ages for site chronology

Radiocarbon dating of soils and sediments is notoriously problematic for the purposes of dating a specific event due to their heterogeneous mix of multiple organic fractions, each of which may have a different radiocarbon age. Numerous studies have failed to agree on which sedimentary fraction or radiocarbon pre-treatment method, if any, provides the closest agreement between the age of a sedimentary fraction and that of associated plant macrofossils or charcoal. We tested the stepped-combustion method of McGeehin et al. (2001), as well as standard radiocarbon humin and humic extraction techniques, using samples from a chronologically well-constrained perennially-frozen site at Quartz Creek, Yukon Territory, Canada. The ages in closest agreement with associated radiocarbon-dated plant macrofossils and with the overlying Dawson tephra were given by the humic and humin fractions, but even these were still older than the macrofossil ages by up to 4195 ± 260 radiocarbon years. The low temperature (LT) humin method recommended by McGeehin et al. (2001) yielded ages older than the macrofossils by up to nearly 4425 ± 240 radiocarbon years. These fractions, while still providing information on the mobility and potential residence times of carbon in soils and sediments, should not be relied upon to provide consistently accurate site chronologies.     

Identifying a reliable target fraction for radiocarbon dating sedimentary records from lakes

Lake basins that experience rapid rates of deposition act as high-resolution environmental archives because they produce sedimentary records that have centennial or even decadal resolution. However, identifying target fractions for radiocarbon dating of lake sediments remains problematic because reworked organic material from fluvial catchments can produce anomalously old radiocarbon ages. This study determines the extent to which reworked material from catchment soils impacts radiocarbon dates on pollen and other organic concentrates by comparing radiocarbon dates produced by these techniques against a chronostratigraphic marker in cores from Lake Mapourika, New Zealand. Pollen preferentially preserved and reworked from catchment soils was identified using soil palynology. A technique was then developed to remove reworked pollen types from pollen concentrates extracted from lake sediment. Identification and removal of reworked pollen from pollen concentrates produced ages that were consistently closer to the age of the chronostratigraphic horizon than other organic concentrates. However, these dates were still between 736 and 366 calendar years older than expected. The only organic fractions that reliably reproduced the age of the chronostratigraphic horizon were terrestrial leaf macrofossils, although terrestrial leaf macrofossils isolated from megaturbidite deposits, which are formed by high-energy depositional events, also provided anomalously old ages. The results indicate that leaf material extracted from hemipelagite, which accumulates gradually, is likely to be the only organic fraction to produce reliable chronology in lakes where a component of sedimentation is driven by the fluvial system. The results also demonstrate the importance of conducting a detailed investigation of physical sedimentology before selecting material for radiocarbon dating lake sediments.     

Holocene moist period recorded by the chronostratigraphy of a lake sedimentary sequence from Lake Tangra Yumco on the south Tibetan Plateau

Palaeolimnological studies together with geomorphological investigations of exposed lacustrine sections on the Tibetan Plateau provided valuable palaeoclimate records. Radiocarbon dating is the most commonly used method for establishing chronologies of lake sediments. However, ¹⁴C dating of such sediments could be problematic due to the lack of organic matter or a reservoir effect, which commonly appears in radiocarbon ages of lacustrine sediments from the Tibetan Plateau. OSL dating is an alternative for dating the lake sediments and also provides the opportunity to independently test radiocarbon chronologies. The current study tries to compare OSL and ¹⁴C dating results in order to evaluate the reservoir effect of ¹⁴C dating, and then based on quartz OSL dating and stratigraphic analysis, to construct the chronostratigraphy of a lacustrine sedimentary sequence (TYC section), an offshore profile from Tangra Yumco lake on the southern Tibetan Plateau. Results suggest that: (1) it is possible to obtain robust OSL age estimates for these lake sediments and the OSL ages of the three samples range from ca. 7.6 ka to ca. 2.3 ka; (2) The discrepancy between the OSL and ¹⁴C ages is ca. 4–5 ka, which possibly results from the age overestimate of ¹⁴C dating due to a reservoir effect in the studied lake; (3) the chronostratigraphy of TYC section and sedimentological environmental analysis show a large lake with a lake level distinctively above the present during ca. 7.6–2.7 ka indicating a wet mid-Holocene in the study area.     

Reliable radiocarbon dating of fossil pollen grains: It is truly possible

Radiocarbon dating of fossil pollen concentrates has the potential to reduce limitations for sample selection in chronological studies of sedimentary archives. The recent development of the technology for rapidly preparing highly purified fossil pollen concentrates using a cell sorter makes it realistic to turn this dream into reality. Before utilizing pollen as a material for dating with confidence, however, it is necessary to understand the factors that may affect the result of the measurements, and to establish criteria to assess the reliability of the radiocarbon ages produced. In this study, peat soils which are commercially available in large quantities, and are hence used as our laboratory standard, as well as the varved lacustrine sediments from Lake Suigetsu, which has one of the best terrestrial radiocarbon stratigraphies in the world, were used to assess the accuracy of radiocarbon ages of pollen concentrates and to establish an appropriate protocol for sample preparation. A pollen-rich fraction prepared by a recently proposed combined method of physio-chemical pre-treatment and cell sorter (Yamada et al. 2021) was submitted to a range of different posterior treatments and radiocarbon measurement. The results were also compared with SEM (Scanning Electron Microscoic) and Fourier Transform Infrared Spectroscopic observations. It was discovered that the sample prepared by the initial pre-treatment and cell sorter were not sufficiently pure and did not yield radiocarbon ages that were consistent with the terrestrial leaf fossils. Instead, the Acid-Base-Acid treatment with ultrafiltration following on from the cell sorter step proved to be highly effective in the removal of contaminants and improve the measured ages. The comparison with Suigetsu's terrestrial radiocarbon dataset also indicated that accuracy could be improved through closer assessment using the pollen taxa composition, carbon content (%C), and stable isotope ratios (δ¹³C) of the pollen concentrates. The age-depth models established by the radiocarbon dating of fossil pollen grains extracted from the Suigetsu sediments agree very well with that of plant macrofossils, and even improve the precision of the combined model. As long as handling was appropriate, the pollen concentrates prepared by the cell sorter provide reliable radiocarbon ages and the method can significantly contribute to Quaternary sciences in the future.     

Improving age-depth models of fluvio-lacustrine deposits using sedimentary proxies for accumulation rates

Lacustrine fills, including those of oxbow lakes in river floodplains, often hold valuable sedimentary and biological proxy records of palaeo-environmental change. Precise dating of accumulated sediments at levels throughout these records is crucial for interpretation and correlation of (proxy) data existing within the fills. Typically, dates are gathered from multiple sampled levels and their results are combined in age-depth models to estimate the ages of events identified between the datings. In this paper, a method of age-depth modelling is presented that varies the vertical accumulation rate of the lake fill based on continuous sedimentary data. In between Bayesian calibrated radiocarbon dates, this produces a modified non-linear age-depth relation based on sedimentology rather than linear or spline interpolation.The method is showcased on a core of an infilled palaeomeander at the floodplain edge of the river Rhine near Rheinberg (Germany). The sequence spans from ∼4.7 to 2.9 ka cal BP and consists of 5.5 m of laminated lacustrine, organo-clastic mud, covered by ∼1 m of peaty clay. Four radiocarbon dates provide direct dating control, mapping and dating in the wider surroundings provide additional control. The laminated, organo-clastic facies of the oxbow fill contains a record of nearby fluvial-geomorphological activity, including meander reconfiguration events and passage of rare large floods, recognized as fluctuations in coarseness and amount of allochthonous clastic sediment input. Continuous along-core sampling and measurement of loss-on-ignition (LOI) provided a fast way of expressing the variation in clastic sedimentation influx from the nearby river versus autochthonous organic deposition derived from biogenic production in the lake itself. This low-cost sedimentary proxy data feeds into the age-depth modelling. The sedimentology-modelled age-depth relation (re)produces the distinct lithological boundaries in the fill as marked changes in sedimentation rate. Especially the organo-clastic muddy facies subdivides in centennial intervals of relative faster and slower accumulation. For such intervals, sedimentation rates are produced that deviate 10–20% from that in simpler stepped linear age-models. For irregularly laminated muddy intervals of the oxbow fill – from which meaningful sampling for radiocarbon dating is more difficult than from peaty or slowly accumulating organic lake sediments – supplementing spotty radiocarbon sampling with continuous sedimentary proxy data creates more realistic age-depth modelling results.     

Refining late Quaternary plunge pool chronologies in Australia's monsoonal 'Top End'

Plunge pool deposits from Australia's 'Top End' are considered as important archives of past monsoonal activity in the region. The available chronology of these deposits was so far based on thermoluminescence (TL) dating and indicated maximum flood magnitudes during the Last Glacial Maximum in contrast with more arid conditions as deduced from other archives of the region. This study revisits plunge pool deposits at Wangi Falls by applying multiple and single-grain Optically Stimulated Luminescence (OSL) dating of quartz and high-resolution gamma spectrometry, supported by radiocarbon dating of organic material. The aim is to reappraise the existing chronology and investigate if the deposits are affected by partial bleaching, post-depositional mixing and/or problems related to annual dose determination. The latter seems to have a minor impact on the ages at most. Equivalent Dose (D_e) distributions are broad, in particular for single grains, but apparently not result from partial bleaching or post-depositional mixing. Rather, microdosimetry caused by radiation hotspots in the sediment and zircon inclusions in the quartz grains is considered problematic for these sediments. The results presented here imply that the previous TL chronology overestimated the real deposition age of the sediments.     

Optically stimulated luminescence and radiocarbon dating of sediments from Lop Nur (Lop Nor), China

Lop Nur is a playa lake occupying the lowest part of the Tarim Basin, northwestern China, and is now a desolate and barren region. In the past decades, the ages of the lacustrine sediments from the lake were determined mainly by radiocarbon dating on bulk sediment. In this study, both optically stimulated luminescence (OSL) and radiocarbon methods were used to date the sediments from a pit in the central part of the lake. The OSL ages obtained for ten samples range from 0.5 to 9.4 ka, and are in stratigraphic order except for one sample. The ¹⁴C ages obtained for twenty-two bulk sediment samples range from 5.8 to 30.2 cal ka BP with erratic distribution. Based on the comparison of ¹⁴C with OSL ages and their age-depth models, we argue that the OSL ages are relatively reliable. The disequilibria in the U decay chain for some samples are deduced from the comparison of the NAA and TSAC results. We suggest that the OSL dating technique should preferably be applied to the playa sediments from Lop Nur, but the disequilibria in the U decay chain should be considered in evaluating dose rates. Additionally, radiocarbon reservoir effects in lakes in western China are reviewed.     

Testing less-conventional methods to date a late-pleistocene to Holocene eruption: Radiocarbon dating of paleosols and 36Cl exposure ages at Pelado volcano,Sierra Chichinautzin,Central Mexico

Despite their significance for estimating hazards and forecasting future activity, dating young volcanic deposits and landforms (<50,000 yrs old) remains a challenge due to the limitations inherent to the different isotopic chronometers used. The Trans-Mexican Volcanic Belt is one of the most active and populated continental arcs worldwide, yet its temporal pattern of activity is poorly constrained. Such deficiency is particularly problematic for the Sierra Chichinautzin Volcanic Field (SCVF) that is located at the doorstep of Mexico City and Cuernavaca and is hence a major source of risk for these cities. Existing ages for this area derive mostly from either radiocarbon on charcoal, which is rare and may be contaminated, or ⁴⁰Ar/³⁹Ar on rock matrix, which is poorly precise for this time period and rock type. Here, we focus on the Pelado monogenetic volcano, which is located in the central part of the SCVF and erupted both explosively and effusively, producing a large lava shield and a widespread tephra blanket. This unique eruptive event was previously dated at ∼12 calibrated (cal) kyrs BP, using radiocarbon dating on charcoal from deposits related to the eruption. To test alternative dating approaches and confirm the age of this significant eruption, we applied two less conventional techniques, radiocarbon dating of bulk paleosol samples collected below the complete tephra sequence at nine sites around the shield, and in-situ ³⁶Cl exposure dating of two samples of an aphyric lava from the base of the shield. Radiocarbon paleosol ages span a continuous time interval from 13.2 to 20.2 cal kyrs BP (2σ), except for one anomalously young sample. This wide age spread, along with the low organic contents of the paleosols, may be due to erosive conditions, related to the sloping topography of the sampling sites and the cool and relatively dry climate of the Younger Dryas (11.7–12.9 ka), during which the Pelado eruption probably occurred. The two ³⁶Cl-dated lava samples have consistent ages at 1σ analytical errors of 15.5 ± 1.4 ka and 13.2 ± 1.2 ka, respectively, yielding an average age of 14.3 ± 1.6 ka for this lava flow. The high full uncertainty in ³⁶Cl ages (24%) is due to high rock Cl content. We conclude that paleosol radiocarbon dating is useful if numerous samples are analyzed and climatic and relief conditions at the time of the eruption and at the sites of tephra deposition are considered. The ³⁶Cl dating technique is an alternative method to date volcanic eruptions, as it gave consistent results, but in the specific case of Pelado volcano, the high Cl content in the analyzed rocks increases the age uncertainties.     

The minimum extraction technique: A new sampling methodology for optically stimulated luminescence dating of museum ceramics

This paper introduces a novel optically stimulated luminescence (OSL) sampling protocol, referred to as the minimum extraction technique (MET), which assists in the OSL dating of museum ceramics. Here we outline how to extract a sample using this technique, as well as offering a discussion on the preparation protocols used for the method, and the calculation of the internal and external dose rates. A major benefit of MET is the minute sample size required, resulting in minimal damage to the museum object.MET permits OSL dating of material which would otherwise be usually off-limits for conventional OSL dating, for example, those housed in museum collections. In particular, MET can be used on objects which originate from regions where scientific analysis is currently not permitted on archaeological material, often owing to heritage laws.     

Developments in optically stimulated luminescence age control for geoarchaeological sediments and hearths in western New South Wales,Australia

Research conducted by the Western New South Wales Archaeology Program (WNSWAP) provides the opportunity to assess the reliability of optically stimulated luminescence (OSL) dating of late Pleistocene and Holocene fluvial sediments and burnt stone samples from arid zone geoarchaeological contexts. A large number of radiocarbon age determinations of charcoal preserved in heat retainer hearths provides independent chronological control at these contexts. We describe a rapid OSL methodology for dating burnt hearth stones to complement previously applied radiocarbon methods, which we have tested using 37 samples from hearths with radiocarbon determinations. We propose a geoarchaeological model in which these hearths were constructed by people whose activity took place on an archaeological surface, formed by the earlier deposition of fluvial sediments. Here we demonstrate the veracity of this model by dating sediments lying stratigraphically below the hearths, and use the radiocarbon age control and chronological consistency to assess the accuracy and reliability of both small aliquot and single grain single aliquot regenerative-dose (SAR) OSL dating. While small aliquot age estimates are in most cases in agreement with independent control, the single grain determinations using a finite mixture model (FMM) appear to provide improved chronological resolution. Using single grains, we note some problems in the application of the FMM and in the dating of young samples in the range of 1–100 years. As many samples may have resided close to the surface since deposition, we have developed a mathematical function to describe gamma and cosmic dose rate contributions at burial depths down to 40 cm. These OSL age estimates allow us to reject the model of intensification of human activity as responsible for the observed pattern of archaeological radiocarbon determinations in this part of the Australian arid zone.     

Radiocarbon wiggle-match dating of proglacial lake sediments – Implications for the 8.2 ka event

The problem of insufficient age-control limits the utilisation of the 8.2 ka BP event for modelling freshwater forcing in climate change studies. High-resolution radiocarbon dates, magnetic susceptibility and lithostratigraphic evidence from a lake sediment core from Nedre Hervavatnet located at Sygnefjell in western Norway provide a record of the early Holocene. We use the method of radiocarbon wiggle-match dating of the lake sediments using the non-linear relationship between the ¹⁴C calibration curve and the consecutive accumulation order of the sample series in order to build a high-resolution age-model. The timing and duration of Holocene environmental changes is estimated using 38 AMS radiocarbon dates on terrestrial macrofossils, insects and chironomids covering the time period from 9750 to 1180 cal BP. Chironomids, Salix and Betula leaves produce the most consistent results. Sedimentological and physical properties of the core suggest that three meltwater events with high sedimentation rates are superimposed on a long-term trend with glacier retreat between 9750 and 8000 cal BP. The lake sediment sequence of Nedre Hervavatnet demonstrates the following: only a reliable high-resolution geochronology based on carefully selected terrestrial macrofossils allows the reconstruction of a more refined and complex environmental change history before and during the 8.2 ka event.     

OSL chronology of a sedimentary sequence from the inner-shelf of the East China Sea and its implication on post-glacial deposition history

Sedimentary records from the inner-shelf of the East China Sea (ECS) are unique for the reconstruction of post-glacial palaeoclimate and sea-level changes. So far, the chronology of sediment succession from this region has mainly been based on radiocarbon dating, which might be problematic due to reworked deposition or old carbon contamination. In this study we tested the applicability of optically stimulated luminescence (OSL) dating to a drilling core (ECS-DZ1) taken from the northern ESC. A total of 20 OSL samples and two radiocarbon samples were collected from the upper 58 m of this core. The results indicate the likely sufficient reset of OSL signal of fine-grained (4–11 μm) quartz before burial, and thus reliable chronology for the studied core sediments. For one sample, however, the extracted coarse-grained (100–200 μm) quartz overestimated the deposition age significantly, presumably resulting from partial bleaching prior to deposition. The fine-grained quartz ages are generally consistent with the stratigraphical order, and the reliability of these OSL ages are further validated by two selective robust ¹⁴C dates. The chronological framework of core ECS-DZ1 reveals striking sedimentation-rate changes. By comparison with other chronostratigraphical records, we infer that post-glacial deposition history (since ∼15 ka) of the study site is likely related to regional sea-level rise and delta-estuary environment evolution, as well as strengthened human activities and/or coastal currents.     

Compound-specific radiocarbon dating of Ross Sea sediments: A prospect for constructing chronologies in high-latitude oceanic sediments

We present an overview of the problems relating to the development of sedimentary chronologies for Antarctic margin sediments, and review the recent application of compound-specific radiocarbon dating methods for resolving them. Radiocarbon dating of solvent-extractable, short-chain (C₁₄, C₁₆, and C₁₈) fatty acids isolated from surface sediments of the Ross Sea, Antarctica, revealed their ages to be consistent with that of the modern dissolved inorganic carbon (DIC) reservoir age (pre-bomb, Δ¹⁴C≈−150‰; post-bomb, Δ¹⁴C≈−100‰) in this region. This contrasts sharply with the radiocarbon ages of bulk organic matter in the corresponding sediments are substantially older (Δ¹⁴C=−298‰ to −712‰). Furthermore, the radiocarbon ages of these fatty acids progressively increase with the core depth. These results clearly show a utility of the compound-specific radiocarbon dating for developing sediment chronologies in the Antarctic margin sediments. This approach is potentially applicable to Arctic Ocean, as well as other areas of Southern Ocean where similar interferences by fossil or pre-aged carbon inputs have hindered the progress in the development of late Quaternary paleoceanographic records.     

Testing the use of range-finder OSL dating to inform field sampling and laboratory processing strategies

A newly developed range-finder luminescence dating method is applied to samples from the eastern Punjab region of Pakistan. Overbank sediments from this area are the subject of an ongoing project into the demise of the Harappan civilization about 4.2 ka and the range-finder technique was used to ascertain whether samples from three pits are from this part of the Holocene. Luminescence measurements of raw sample gave a signal dominated by feldspars, even when using a [post-IR] optically stimulated luminescence (OSL) signal. Following etching in hydrofluoric acid samples gave OSL signals characteristic of quartz and these were used to calculate the equivalent dose. The total dose rate was estimated from beta counting. Eight range-finder OSL ages extend from 4000 to 6600 years ago and are consistent with two radiocarbon ages from the same pits demonstrating that these sediments do straddle the period of interest for this project. The range-finder approach provides a rapid means of informing future field sampling campaigns.     

Exploring the dating of “dirty” speleothems and cave sinters using radiocarbon dating of preserved organic matter

Speleothems and other carbonate deposits such as tufa containing high proportions of detrital material can be difficult to chemically date due to detrital thorium levels causing a high level of error in conventional U-Th disequilibrium dating. Here we investigate the use of an alternative technique centring on radiocarbon dating of organic matter preserved within the detrital fraction. Non-acid soluble humic, particulate and detritally absorbed organic matter was recovered from eight samples from a flowstone sinter formed within a roman aqueduct at Trento in Italy with a maximum age of 100 CE (1850 cal yr BP), and two repeat samples from a dripstone formed within the 20th Century on a wire fence at Lilly-Pilly Cave, Buchan Caves Reserve in Victoria, Australia. In the aqueduct samples the median calibrated ¹⁴C ages ranged from 2232 to 2889 cal yr BP, with 95.4% probability age range in the youngest and oldest samples of 2153–2337 and 2342–3449 cal yr BP respectively. The median age of the more modern dripstone was 336 cal yr BP, with a 95.4% probability age range of 148–486 cal yr BP. These results provide very approximate ball-park estimates of the age of the sample, but are consistently too old when compared to the known maximum ages of formation. It is hypothesised that this offset is due to a combination of the nature of the organic carbon transported from the source organic matter pools, and reworking of both modern and old organic carbon by in situ microbial communities.     

Comparison between luminescence and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia

Dust depositions are critical archives for understanding interior aridification and westerly climatic changes in Central Asia. Accurate and reliable dating of loess is very important for interpreting and correlating environmental records. There remains a disparity between luminescence ages and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia. In this study, we establish a closely spaced quartz optically stimulated luminescence (OSL) chronology for the 20.5-m-thick Nilka loess section in the Ili Basin. Based on OSL ages, two intervals of higher mass accumulation rate occurred at 49–43 ka and 24–14 ka. We further compare these OSL ages with 23 accelerator mass spectrometry (AMS) ¹⁴C ages of bulk organic matter. The results indicate that the OSL and radiocarbon ages agree well for ages younger than ca. 25 ¹⁴C cal ka BP. However, beyond 30 cal ka BP, there is no consistent increase in AMS ¹⁴C age with depth, while the OSL ages continue to increase. These differences confirm the observation that the AMS ¹⁴C ages obtained using conventional acid–base–acid (ABA) pretreatment are severely underestimated in other terrestrial deposits in Central Asia, which could be due to 2–4% modern carbon contamination. However, OSL dating is applicable for constructing an accurate chronology beyond 30 cal ka BP. We suggest caution when interpreting paleoenvironmental changes based on radiocarbon ages older than 25 cal ka BP.     

Using the N/C ratio to correct bulk radiocarbon ages from lake sediments: Insights from Chilean Patagonia

The offset between AMS radiocarbon ages obtained on bulk lake sediments and the true age of deposition was evaluated at four sites in Northern Chilean Patagonia. Our results show that the bulk radiocarbon ages are systematically older by 300 to 1100 years. In this region free of carbonate and carbonaceous rocks, we argue that this difference results from variable inputs of terrestrial organic carbon from the Holocene soils that cover the lake watersheds. For the four studied lakes, the age offset is clearly related to the fraction of terrestrial carbon preserved in the lake sediments, which was estimated using the N/C ratio of the bulk organic matter. We propose that N/C measurements can be used to significantly improve chronologies based on radiocarbon dating of bulk lake sediments.     

Assessment of oxygen plasma ashing as a pre-treatment for radiocarbon dating

This study investigates the potential of low-temperature oxygen plasma ashing as a technique for decontaminating charcoal and wood samples prior to radiocarbon dating. Plasma ashing is demonstrated to be rapid, controllable and surface-specific. Different organic materials clearly ash at different rates, however, the ability of plasma ashing to selectively ash different organic components is limited in heterogeneous sample matrices. This is because oxidation is confined to the immediate sample surface. Comparison of radiocarbon dates obtained from identical aliquots of contaminated ancient charcoal pre-treated by acid–base–acid (ABA), acid–base-oxidation-stepped combustion (ABOx-SC) and plasma ashing suggests that the technique performs as well as the ABA pre-treatment but does not remove as much contamination as the ABOx-SC technique. Plasma ashing may be particularly useful in cases where sample size is limiting.     

Luminescence dating of the last earthquake of the Sabzevar thrust fault, NE Iran

Iran is one of the world's most tectonically active regions, yet dating past earthquakes for neotectonic studies has been limited. One of the main reasons for this is that organic material suitable for radiocarbon dating of deformed sediments is rare. We investigate the use of infrared stimulated luminescence (IRSL) from coarse-grained feldspars to date colluvial deposits associated with the Sabzevar thrust fault in northeastern Iran. The single-aliquot regenerative (SAR) dose measurement procedure was used for this study. The current study investigates monitoring and correcting for sensitivity changes, recovering a known laboratory dose and equivalent dose estimation using three SAR IRSL methods. It is shown that SAR has recovered a given laboratory dose using a range of preheat temperatures but D_e determination of natural samples requires its own preheat plateaus for two of these SAR methods. The SAR IRSL method provided an age of 1.7±0.3 ka for colluvium, predating the last earthquake event on the Sabzevar fault. This result suggests that this fault is likely to be responsible for an earthquake that destroyed Sabzevar city in AD 1052.     

A radiocarbon chronology for Sanamere Lagoon,Cape York Peninsula,using multiple organic fractions

The selection and pre-treatment of reliable organic fractions for radiocarbon age determination is fundamental to the development of accurate chronologies. Sampling from tropical lakes is particularly challenging given the adverse preservation conditions and diagenesis in these environments. Our research is the first to examine and quantify the differences between radiocarbon ages from different carbon fractions and pretreatment protocols from tropical lake sediments. Six different organic fractions (bulk organics, pollen concentrate, cellulose, stable polycyclic aromatic carbon (SPAC), macrocharcoal >250 μm and microcharcoal >63 μm) were compared at six different depths along a 1.72 m long core extracted from Sanamere Lagoon, Cape York Peninsula, northern Australia. Acid-base-acid (ABA), modified ABA (30% hydrogen peroxide + ABA), 2chlorOx (a novel cellulose pre-treatment method) and hydrogen pyrolysis (hypy) were used to pre-treat the organic fractions. The oldest date is ∼31,300 calibrated years before present (cal yr BP) and the youngest is ∼2800 cal yr BP, spanning ∼28,500 years. The smallest offset between the minimum and the maximum age for different fractions and across pretreatment methods at a given depth was found to be 832 years (between SPAC and pollen) and the largest ∼16,750 years (between pollen concentrate and SPAC). The SPAC fractions pre-treated with hypy yielded older ages compared to all other fractions in most cases, while bulk organics yielded consistently younger ages. The magnitude and consistency of the offsets and the physical and chemical properties of the tested organic fractions suggest that SPAC is the most reliable fraction to date in tropical lake sediments and that hypy successfully removes exogenous carbon contamination.