Quartz OSL dating of late Holocene beach ridges from the Magdalen Islands (Quebec,Canada)

Quartz optically stimulated luminescence (OSL) dating has been applied to sandy beach ridge systems from the Magdalen Islands in the center of the Gulf of St. Lawrence (Quebec, Canada) to provide the first chronological framework for these features. Nineteen beach ridges (22 samples) from four different sites throughout the archipelago were investigated. At one of the sites, samples were taken at 9 m and 7.5 m depth using a vibracore. The quartz is dominated by the fast OSL component and a single-aliquot regenerative-dose (SAR) protocol was used to measure the equivalent doses; a low preheat (180°C/10 s) was chosen to avoid the influence of thermal transfer. The average dose recovery ratio of all samples is 1.02 ± 0.02 (n = 130) suggesting that the SAR protocol works satisfactorily on this material. The OSL ages are internally consistent and supported by independent age control (radiocarbon). The OSL ages indicate that the ridges were built between 2.6 ± 0.2 ka and 0.40 ± 0.10 ka, i.e. during a period of sea level rise. This rise eroded adjacent sandstone cliffs, which contributed a significant sediment supply to the littoral drift and beaches. Some low-lying coasts in the archipelago are still prograding, despite a relative sea level increase of ∼1.6 mm/a over the last 600 years. The late Holocene ages obtained in this study indicate that these processes have been active for at least the past two thousand years. This study demonstrates for the first time that OSL dating using quartz has great potential in this area, and is an appropriate method for establishing precise chronologies for coastal sediments in this region of the Gulf of St. Lawrence.     

Multi-method pIRIR dating of sedimentary sequences at the southern edge of the Gurbantunggut Desert,NW China and its palaeoenvironmental implications

The Gurbantunggut Desert is the second-largest desert in China, located in the westerly-dominated region of north-western China. Previous understanding of palaeoclimate of this desert was mostly based on lake and loess records from the Junggar Basin and Tian Shan Mountains, whilst direct dating of sedimentary records from the desert was very limited. This study applies high-resolution post-infrared infrared stimulated luminescence (pIRIR) dating to three sedimentary profiles at the southern edge of the Gurbantunggut Desert, which contain aeolian sand and water-lain sediments, recording palaeoenvironmental changes at the desert margin since the Last Glacial Maximum (LGM). Different pIRIR dating procedures were applied for samples with different ages. For Holocene-aged samples, a single-aliquot regenerative-dose (SAR) pIRIR procedure based on a three-stepped pIRIR measurement at 110 °C, 140 °C and 170 °C was used, and a standard growth curve (SGC) procedure yields an equivalent dose (D_e) similar to that of the full-SAR procedure; thus, is applicable for accelerating D_e measurement. For samples much older than the Holocene, a multi-aliquot regenerative-dose (MAR) pIRIR procedure based on a three-stepped pIRIR measurement at 150 °C, 200 °C and 250 °C was found to be the optimal dating procedure, because a SAR procedure would yield underestimated ages due to uncorrected initial sensitivity change. pIRIR dating results of the investigated profiles reveal a substantial sand accumulation during the LGM, an intensification of aeolian deposition at ∼12 ka and a wetter depositional environment at ∼10–8 ka. A rapid fluvial deposition is dated at ∼20–19 ka, corresponding to the deglaciation period. The sedimentary records from the desert margin show some correlation with lake and loess records in the same region and suggest a complex response of the desert environment to different climatic factors.     

Holocene climate changes in westerly-dominated areas of central Asia: Evidence from optical dating of two loess sections in Tianshan Mountain,China

Optical dating was applied to two loess-paleosol sections (Lujiaowan and Shuixigou) from the northern piedmont of Tianshan Mountain, Xinjiang province, China. The two sections are over 200 km apart and have a similar depositional sequence, which consists of two paleosol layers embedded by one loess layer. Two difficulties were met in optical dating. First, because the sections are located on the slope of the mountain, it was found that some cliff debris, with coarse grains (>200 μm), were mixed with the eolian sediments by rainfall, especially in the paleosol layers. Second, the optically stimulated luminescence (OSL) signals of quartz grains from the deposits were too dim to obtain a reliable equivalent dose (D_e). The 63–90 μm K-feldspar grains were separated to decrease the debris portion, and they yielded bright infrared stimulated luminescence (IRSL) signals. A multiple-elevated-temperature post-IR IRSL (MET-pIRIR) procedure was applied to determine D_e. Comparing the optical dating ages of the two sections, the Lujiaowan (LJW) and Shuixigou (SXG) sections recorded almost the same depositional process during the Holocene. The ages of the two loess layers (2.44–3.38 ka at LJW; 2.47–4.36 ka at SXG) suggested that one drought event happened widely in this westerly dominated area. The same drought event 2.5–3.5 ka ago also happened in the Chinese Loess Plateau (CLP), where the summer monsoon dominated. However, the paleosol development period (6.6–4 ka) in the study area was distinguished from the monsoon dominated area (8–4 ka), which suggests an arid early Holocene in the westerly area.     

Optical dating of aeolian and fluvial sediments in north Tian Shan range,China: Luminescence characteristics and methodological aspects

Loess and fluvial sand are important materials for dating river terraces and alluvial fans. This study focuses on the methodological aspects of dating loess and fluvial deposits from the northern flank of the Tian Shan range, China, using sand-sized quartz and potassium (K) feldspar. Luminescence characteristics of quartz and K-feldspar were studied for searching suitable dating procedures. Our results indicate that 1) most quartz aliquots were contaminated by feldspar, and were dated using a post-infrared optically stimulated luminescence (post-IR OSL) procedure. A Fast ratio acceptance threshold of 15 can be applied to select these aliquots with post-IR OSL signals dominated by quartz OSL; 2) the multi-elevated-temperature post-IR IR stimulated luminescence (MET-pIRIR) procedures are applicable for K-feldspar. A test dose of ∼30% of the natural dose is appropriate for dating of older (>10 ka) samples. An Age (T, t) plateau test can be used to evaluate the dating results; 3) for the loess samples, both quartz and K-feldspar were well bleached and are suitable for dating. Dating using K-feldspar is preferred for its higher efficiency; 4) for the fluvial sand samples, only the quartz grains were fully bleached. Single-aliquot dating of quartz gives reliable ages.     

ESR and OSL dating of fossil-bearing deposits from Naracoorte Cave Complex palaeontological sites,south Australia

Little work has been undertaken on combined dating of sedimentary quartz grains using electron spin resonance (ESR) and optically stimulated luminescence (OSL) techniques in Australia. This study aims to assess the suitability of a combined ESR and OSL dating approach for establishing improved chronologies of Middle-Late Pleistocene deposits within the Naracoorte Cave Complex (NCC), South Australia. Here, we apply ESR and OSL dating in tandem to a series of samples collected from three different NCC sites: Whale Bone, Specimen and Alexandra cave. ESR quartz dating focuses on the multi-centre (MC) approach, which involves comparative evaluations of Al and Ti centre signals, while paired luminescence dating focuses on single-grain OSL analysis and includes examination of multi-grain averaging effects. The comparative ESR-OSL dating results exhibit broad agreement for deposits spanning 50–150 thousand years, with either the Ti–H or Al centre ages overlapping with paired OSL ages at 2σ in nearly all cases. MC ESR evaluations (Al v Ti–Li v Ti–H age assessments) indicate incomplete resetting of the bleachable Al centre signal for a small number of samples. Two-thirds of samples exhibit Ti–Li ages that are significantly older than corresponding Al centre ages, which is unexpected from a bleaching kinetics perspective and may indicate a broader reliability issue for Ti–Li palaeodose evaluation with these particular samples. Our findings: (i) support the applicability of both palaeodosimetric dating methods in this depositional setting; (ii) highlight the merits of applying combined ESR-OSL analyses in tandem, and; (iii) provide one of the first reliable evaluations of quartz ESR MC dating for samples with natural dose ranges as low as only a few tens of Gy. These results show that the Whale Bone, Specimen and Alexandra cave sites are temporally related and can be used to derive multi-site reconstructions of faunal assemblages and palaeoenvironmental history.     

Luminescence dating of Holocene sediment cores from a wave-dominated and mountainous river delta in central Vietnam

Sediments of river deltas provide valuable records of past coastal environments. Optically-stimulated luminescence (OSL) dating has become an alternative to radiocarbon dating for constraining the sediment chronology in large deltas that allow for sufficient sunlight bleaching of sediments during the fluvial transport. However, its applicability to smaller deltas with mountainous riverine systems has not been confirmed yet. To check this, we examine multiple signals from two Holocene sediment cores in the wave-dominated Thu Bon River delta in central Vietnam. Two cores were collected, respectively, 3.9 km and 1.2 km inland from the present shoreline and both show a >-25-m thick succession of coarsening-upward mud to sand deposits. Coarse grains (180–250 μm in diameter) of quartz and K-feldspar, and fine grains (4–11 μm in diameter) of quartz and polymineral were extracted from the upper and lower parts of the cores for multi-grain measurements of quartz OSL, and of feldspar infrared-stimulated luminescence (IRSL) at 50 °C (IR₅₀) and post-IR IRSL at 175 °C (pIRIR₁₇₅) to determine burial ages. In addition, facies analysis and radiocarbon dating were conducted. The landward core consists of transgressive to early regressive estuarine and prodelta facies, which is overlain by a sandy beach-shoreface facies. The seaward core consists of a relatively simple shallowing-upward succession from muddy prodelta facies to sandy beach-shoreface facies. All luminescence ages except for pIRIR₁₇₅ of fine grains are mostly consistent with the radiocarbon ages. Instead, pIRIR₁₇₅ ages of fine grains are significantly overestimated with variable offsets. OSL and IR₅₀ of fine grains provide reasonable age estimates, as these grains were likely well bleached during the transport even along a short and steep mountainous river. Consistent age estimates of all signals from sand indicate that sand was well-bleached in the beach and shoreface owing to the frequent sediment reworking by waves and currents. These results support the hypothesis that luminescence dating is applicable to Holocene wave-dominated deltas and reiterate that comparing different luminescence signals is an effective way to check reliability of the age estimates in environments where the sunlight bleaching is not ensured.     

OSL and radiocarbon dating of a core from the Bohai Sea in China and implication for Late Quaternary transgression pattern

The Bohai Sea is a semi-enclosed continental shelf sea in northern China. Three transgression layers have been identified from the Late Quaternary strata in the western Bohai Sea and the coastal regions, which provide critical information on Late Quaternary sea-level fluctuations and landscape development. The three transgression layers were previously assigned to Marine Isotope Stage (MIS) 1 (transgression 1, T1), MIS 3 (T2) and MIS 5 (T3), respectively, mainly based on ¹⁴C dating. However, this chronological framework aroused an enigma that the regional sea level in MIS 3 was even higher than that of MIS 5, conflicting with the context of global sea-level pattern. In order to clarify this issue, here quartz optically stimulated luminescence (OSL) dating (four samples) was used to constrain the T2 chronology of borehole TJC-1 from the western Bohai Sea. Radiocarbon samples (eight) of peaty sediments were also measured for reference and comparison. All the four OSL samples showed saturation ages of >80 ka, suggesting that the T2 layer should have formed at least in MIS 5, instead of in MIS 3. Radiocarbon ages in T2 should have been severely underestimated, with a saturation age range of 22–30 cal ka BP, similar to all the previous published radiocarbon ages. The renewed OSL chronological framework for Late Quaternary transgressions in the western Bohai Sea is in better compliance with the history of global sea-level change.     

毛乌素沙地东南缘全新世湖相地层石英和钾长石释光测年对比

采集来自毛乌素沙地东南缘巴图湾、大沟湾和三岔河等3处典型湖相地层出露点的3个样品,分别提取石英和钾长石矿物组分,采用小片技术(样品直径2 mm)进行释光年代测试,并将两种矿物年代结果进行对比研究.应用单片再生剂量(SAR)流程测试了石英样品的等效剂量(预热温度选为260℃).剂量恢复实验和光释光特性显示,SAR流程测试条件选择合适,样品沉积前光释光信号晒退完全,说明石英年代结果可靠.另外,应用两步红外激发(激发温度分别为50℃和150℃)的单片再生剂量流程(post-infrared infrared-stimulated luminescence,简写为p IRIR流程)测试钾长石样品的等效剂量,剂量恢复实验和释光特性等各项检验均符合要求,剩余剂量在-0.2~0.026 Gy之间,可忽略不计.钾长石的p IRIR150信号异常衰减速率为0.55~1.71(%/decade),因造成的误差较小,故无需对年代结果进行校正.3处湖相地层的石英年代分别为11.3±0.9、6.5±0.6、2.7±0.2 ka BP,钾长石p IRIR150年代分别为10.0±0.7、6.9±0.5、2.4±0.2 ka BP,两者在误差范围内一致,说明毛乌素沙地东南缘的全新世湖相沉积物适合用钾长石p IRIR150流程进行释光测年.本研究为毛乌素沙地部分样品因石英信号较弱而无法测年问题提供了解决办法,也为该区域全新世,尤其是历史时期(近2000年)以来的环境变化研究提供了年代学支撑.     

Comparison between luminescence and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia

Dust depositions are critical archives for understanding interior aridification and westerly climatic changes in Central Asia. Accurate and reliable dating of loess is very important for interpreting and correlating environmental records. There remains a disparity between luminescence ages and radiocarbon dating of late Quaternary loess from the Ili Basin in Central Asia. In this study, we establish a closely spaced quartz optically stimulated luminescence (OSL) chronology for the 20.5-m-thick Nilka loess section in the Ili Basin. Based on OSL ages, two intervals of higher mass accumulation rate occurred at 49–43 ka and 24–14 ka. We further compare these OSL ages with 23 accelerator mass spectrometry (AMS) ¹⁴C ages of bulk organic matter. The results indicate that the OSL and radiocarbon ages agree well for ages younger than ca. 25 ¹⁴C cal ka BP. However, beyond 30 cal ka BP, there is no consistent increase in AMS ¹⁴C age with depth, while the OSL ages continue to increase. These differences confirm the observation that the AMS ¹⁴C ages obtained using conventional acid–base–acid (ABA) pretreatment are severely underestimated in other terrestrial deposits in Central Asia, which could be due to 2–4% modern carbon contamination. However, OSL dating is applicable for constructing an accurate chronology beyond 30 cal ka BP. We suggest caution when interpreting paleoenvironmental changes based on radiocarbon ages older than 25 cal ka BP.     

Chronology of the Upper Pleistocene loess sequence of Havrincourt (France) and associated Palaeolithic occupations: A Bayesian approach from pedostratigraphy,OSL, radiocarbon,TL and ESR/U-series data

In connection with the future Seine-North Europe Canal (Seine-Scheldt), a large-scale rescue archaeological survey was conducted at Havrincourt (northern France) between 2008 and 2011. The discovery of several levels of Palaeolithic flint artefacts embedded in a relatively thick loess sequence (ca 6–7 m) preserved on a gentle slope facing North-East, resulted in a 6000 m² excavation. This opened the opportunity for a detailed pedosedimentary and interdisciplinary geochronological survey (¹⁴C, optically stimulated luminescence, thermoluminescence, ESR/U-series) that has allowed us date the sequence reliably. On the basis of these results we propose this sequence as a new pedostratigraphic and archaeological reference sequence for northern France. We present here the optical dating of the sequence performed on fine (4–11 μm) quartz grains extracted from 17 samples. The luminescence characteristics of these extracts indicate that the single-aliquot regenerative dose optically stimulated luminescence (SAR-OSL) procedure that was applied is well suited. A consistent set of optical ages was obtained for the loess deposited up to around 70 ka ago. Independent age control (pedostratigraphy, ¹⁴C, ESR/U-series dates) allowed us to apply a Bayesian approach to build a chronometric model. This in turn enabled a regional chronostratigraphic framework to be built, to constrain the correlations with neighboring regions (northern France and Belgium) and to calculate a precise age for the four Palaeolithic levels discovered, including a unique occupation related to the early Upper Palaeolithic which was previously unknown in the area.     

Quartz OSL and TL dating of pottery,burnt clay,and sediment from Beicun archaeological site,China

This study focuses on characterizing the thermoluminescence (TL) and optically stimulated luminescence (OSL) of quartz in burnt clay, pottery, and the sediments unearthed from a Neolithic site, the Beicun site of the Liangzhu culture. It shows that the initial OSL signals (within 0.8 s) of most burnt clay and pottery sherds are not dominated by the fast component. Results of a heating simulation experiment of sediment quartz show that annealing at temperatures exceeding 600–800 °C decreased the proportion of the fast component in the initial signal slightly. In addition, the proportion of the medium component in the later signal (0.8–5 s) increased significantly, resulting in a decrease in the Fast Ratio value. Therefore, high annealing temperature may be an important reason for the slow decay rate of OSL signals of the burnt clay and pottery samples. The D_e(t) plot shows that most of the samples have thermally stable OSL component signals, which have no significant effect on the final OSL ages. The single-aliquot regenerative-dose (SAR) protocol was used to determine the OSL and TL ages for chunk burnt clay and pottery sherds. The high-precision age of the last archaeological heating event, such as sacrifice, burning, or domestic firing, can be obtained by determining the TL and OSL ages of a homogeneous chunk of burnt clay. The OSL results are consistent with the ¹⁴C age of carbon chips extracted from burnt clay. The age of the Beicun site is finally determined to be approximately 5000–5300 BP (BP represents before 2020), belonging to the early period of the Liangzhu culture.     

OSL chronology of a sedimentary sequence from the inner-shelf of the East China Sea and its implication on post-glacial deposition history

Sedimentary records from the inner-shelf of the East China Sea (ECS) are unique for the reconstruction of post-glacial palaeoclimate and sea-level changes. So far, the chronology of sediment succession from this region has mainly been based on radiocarbon dating, which might be problematic due to reworked deposition or old carbon contamination. In this study we tested the applicability of optically stimulated luminescence (OSL) dating to a drilling core (ECS-DZ1) taken from the northern ESC. A total of 20 OSL samples and two radiocarbon samples were collected from the upper 58 m of this core. The results indicate the likely sufficient reset of OSL signal of fine-grained (4–11 μm) quartz before burial, and thus reliable chronology for the studied core sediments. For one sample, however, the extracted coarse-grained (100–200 μm) quartz overestimated the deposition age significantly, presumably resulting from partial bleaching prior to deposition. The fine-grained quartz ages are generally consistent with the stratigraphical order, and the reliability of these OSL ages are further validated by two selective robust ¹⁴C dates. The chronological framework of core ECS-DZ1 reveals striking sedimentation-rate changes. By comparison with other chronostratigraphical records, we infer that post-glacial deposition history (since ∼15 ka) of the study site is likely related to regional sea-level rise and delta-estuary environment evolution, as well as strengthened human activities and/or coastal currents.