Meteoric 10Be speciation in subglacial sediments of East Antarctica

A sequential chemical extraction procedure was developed and tested to investigate the utility of meteoric ¹⁰Be as a tracer for authigenic mineral formation beneath the East Antarctic Ice Sheet. Subglacial meltwater is widely available under the Antarctic Ice Sheet and dissolved gases within it have the potential to drive chemical weathering processes in the subglacial environment. Meteoric ¹⁰Be is a cosmogenic nuclide with a half-life of 1.39·10⁶ years that is incorporated into glacier ice, therefore its abundance in the subglacial environment in Antarctica is meltwater dependent. It is known to adsorb to fine-grained particles in aqueous solution, precipitate with amorphous oxides/hydroxides, and/or be incorporated into authigenic clay minerals during chemical weathering. The presence of ¹⁰Be in chemical weathering products derived from beneath the ice therefore indicates chemical weathering processes in the subglacial environment. Freshly emerging subglacial sediments from the Mt. Achernar blue ice moraine were subject to chemical extractions where these weathering phases were isolated and ¹⁰Be concentrations therein quantified. Optimization of the phase isolation was developed by examining the effects of each extraction on the sample mineralogy and chemical composition. Experiments on ¹⁰Be desorption revealed that pH 3.2–3.5 was optimal for the extraction of adsorbed ¹⁰Be. Vigorous disaggregation of the samples before grain size separations and acid extractions is crucial due to the incorporation of the nuclide in clay minerals and its preferential absorption to clay-sized particles. ¹⁰Be concentrations of 2–22·10⁷ atoms·g⁻¹ measured in oxides and clay minerals in freshly emerging sediments strongly indicate subglacial chemical weathering in the catchment of the Mt. Achernar moraine. Based on total ¹⁰Be sample concentrations, local basal melt rates, and ¹⁰Be ice concentrations, sediment-meltwater contact in the subglacial environment is on the order of thousands of years per gram of underlying fine sediment. Strong correlation (R = 0.97) between ¹⁰Be and smectite abundance in the sediments supports authigenic clay formation in the subglacial environment. This suggests meteoric ¹⁰Be is a useful tool to characterize subglacial geochemical weathering processes under the Antarctic Ice Sheet.     

A simple model for reconstructing geomagnetic field intensity with <Superscript>10</Superscript>Be production rate and its application in Loess studies

A simple model for reconstructing the paleomagnetic field intensity with ¹⁰Be production rate was used for the first time in Loess ¹⁰Be studies of Luochuan profile. Using the LGM (Last Glacial Maxmium) method, the climatic effects and geomagnetic modulation effects on loess ¹⁰Be was separated and in turn the 80 ka geomagnetic excursion sequence reconstructed, of which the globally remarkable geomagnetic excursion events such as the Laschamp (42 ka), Mono Lake (32 ka) during the Last Glacial period were revealed and the paleo-geomagnetic intensity curve from Loess ¹⁰Be over the past 80 ka was quantitatively reconstructed. The reconstructed paleo-intensity fits well with the paleo-intensity curves (SINT200 and NAPIS75), which indicates the significance of global criterion of the ¹⁰Be paleo-intensity curve and the future direction of loess ¹⁰Be tracing studies. Results show the irregular variability of the East Asian monsoon precipitation in Loess Plateau is the main cause that has resulted in the ambiguity of the geomagnetic modulation of the ¹⁰Be record in the loess, and the intrinsic source component of the loess ¹⁰Be and inherited fraction of magnetic susceptibility (SUS) are characterized by the “quasi-homogeneous distribution” manner. Supported by the Key Innovation Project of the Chinese Academy of Sciences (Grant No. KZCX2-YW-118), the National Natural Science Foundation of China (Grant Nos: 40531003, 40121303, 40523002) and State Key Laboratory of Loess and Quaternary Geology in the Institute of Earth Environment of Chinese Academy of Sciences (Grant No. SKLLQG0712)     

Effects of long soil surface residence times on apparent cosmogenic nuclide denudation rates and burial ages in the Cradle of Humankind,South Africa

In situ cosmogenic nuclides are an important tool for quantifying landscape evolution and dating fossil-bearing deposits in the Cradle of Humankind (CoH), South Africa. This technique mainly employs cosmogenic 10-Beryllium (¹⁰Be) in river sediments to estimate denudation rates and the ratio of 26-Aluminium (²⁶Al) to ¹⁰Be (²⁶Al/¹⁰Be), to constrain ages of sediment burial. Here, we use ¹⁰Be and ²⁶Al concentrations in bedrock and soil above the Rising Star Cave (the discovery site of Homo naledi) to constrain the denudation rate and the exposure history of soil on the surface. Apparent ¹⁰Be-derived denudation rates obtained from pebble- to cobble-sized clasts and coarse-sand in soil (on average 3.59 ± 0.27 m/Ma and 3.05 ± 0.25 m/Ma, respectively) are 2-3 times lower than the bedrock denudation rates (on average 9.46 ± 0.68 m/Ma). In addition, soil samples yield an average ²⁶Al/¹⁰Be ratio (5.12 ± 0.27) that is significantly lower than the surface production ratio of 6.75, which suggests complex exposure histories. These results are consistent with prolonged surface residence of up to 1.5 Ma in vertically mixed soils that are up to 3 m thick. We conclude that the ¹⁰Be concentrations accumulated in soils during the long near-surface residence times can potentially cause underestimation of single-nuclide (¹⁰Be) catchment-wide denudation rates in the CoH. Further, burial ages of cave sediment samples that consist of an amalgamation of sand-size quartz grains could be overestimated if a pre-burial ²⁶Al/¹⁰Be ratio calculated from the surface production is assumed. © 2019 John Wiley & Sons, Ltd.     

Clean quartz matters for cosmogenic nuclide analyses: An exploration of the importance of sample purity using the CRONUS-N reference material

Reference materials are key for assessing inter-laboratory variability and measurement quality, and for placing analytical uncertainty bounds on sample analyses. Here, we investigate four years of data resulting from repeated processing of the CRONUS-N reference material for cosmogenic ¹⁰Be and ²⁶Al analyses. At University of Vermont, we prepared a CRONUS-N aliquot with most of our sample batches from 2013 to 2017; these reference material samples were then distributed to four different accelerator mass spectrometry facilities, yielding 73 ¹⁰Be analyses and 58 ²⁶Al analyses. We determine CRONUS-N ¹⁰Be concentrations of (2.26 ± 0.14) x 10⁵ atoms g⁻¹ (n = 73, mean, 1 SD) and ²⁶Al concentrations of (1.00 ± 0.08) x 10⁶ atoms g⁻¹ (n = 58, mean, 1 SD). We find a reproducibility of 6.3% for ¹⁰Be and 7.7% for ²⁶Al (relative standard deviations). We also document highly variable ²⁷Al and Mg concentrations and a ¹⁰Be dispersion twice as large as the mean AMS analytic uncertainty. Analyses of the CRONUS-N material with and without density separation demonstrate that non-quartz minerals are present in the material and have a large impact on measured concentrations of ²⁷Al, ¹⁰Be, and impurities; these non-quartz minerals represent only a very small portion of the total mass (0.6–0.8%) but have a disproportionally large effect on the resulting data. Our results highlight the importance of completely removing all non-quartz mineral phases from samples prior to Be/Al extraction for the determination of in situ cosmogenic ¹⁰Be and ²⁶Al concentrations.     

Grain size-dependent 10Be concentrations in alluvial stream sediment of the Huasco Valley,a semi-arid Andes region

Terrestrial cosmogenic nuclide concentrations in sediment are used to quantify mean denudation rates in catchments. This article explores the differences between the ¹⁰Be concentration in fine (sand) and in coarse (1–3 or 5–10 cm pebbles) river sediment. Sand and pebbles were sampled at four locations in the Huasco Valley, in the arid Chilean Andes. Sand has ¹⁰Be concentrations between 4.8 and 8.3·10⁵ at g⁻¹, while pebbles have smaller concentrations between 2.2 and 3.3·10⁵ at g⁻¹. It appears that the different concentrations, systematically measured between sand and pebbles, are the result of different denudation rates, linked with the geomorphologic processes that originated them. We propose that the ¹⁰Be concentrations in sand are determined by the mean denudation rate of all of the geomorphologic processes taking place in the catchment, including debris flow processes as well as slower processes such as hill slope diffusion. In contrast, the concentrations in pebbles are probably related to debris flows occurring in steep slopes. The mean denudation rates calculated in the catchment are between 30 and 50 m/Myr, while the denudation rates associated with debris flow are between 59 and 81 m/Myr. These denudation rates are consistent with those calculated using different methods, such as measuring eroded volumes.     

Meteoric 10Be concentrations from saprolite and till in northern Sweden: Implications for glacial erosion and age

We examine ¹⁰Be concentration in two pit profiles in the Parkajoki area at ∼67°N on the northern Fennoscandian shield in northern Sweden. Due to repeated cover by cold-based, non-erosive ice sheets, the area retains many relict non-glacial features, including tors and saprolites. In the examined pit profiles, gruss-type saprolite developed from weathering of intermediate igneous rocks is overlain unconformably by Weichselian till.Our results show that ¹⁰Be concentrations found in the till greatly exceed the levels of ¹⁰Be that can have accumulated since deglaciation at ∼11 ka and are comparable to those reported from Pliocene and Early Pleistocene tills in North America. Old tills with grussified boulders at depth were excavated in the Parkajoki area and correlations with neighbouring parts of Finland indicate a Middle Pleistocene or older age. Evidence from pit excavations and geochemistry shows that the underlying saprolites have been truncated by glacial erosion and that previously weathered material has been incorporated into the till sequence. Hence, ¹⁰Be inventories in the tills are dominated by material recycled from Middle Pleistocene or older soils, near-surface sediments and saprolite, and cannot be used to date the periods of till deposition. The retention of relict ¹⁰Be in the tills nonetheless confirms minimal glacial erosion.Concentrations of meteoric ¹⁰Be in the saprolites are lower than any reported saprolite concentrations measured in other settings. Uncertainty in the pre-glaciation ¹⁰Be concentrations in the saprolites makes age determinations difficult. One possibility is that that the saprolite had higher ¹⁰Be concentrations in the past but that saprolite formation ended after glaciation and burial by till and that the ¹⁰Be has substantially decayed. Modelling of the meteoric ¹⁰Be depth profiles in this case suggests that the saprolites in the Parkajoki area were formed at a minimum of 2 Ma. Erosion of the saprolite allows an older age of up to ∼5 Ma, with up to 250 cm of material removed and incorporated into later tills. A second possibility is that concentrations of meteoric ¹⁰Be in the saprolite were originally lower, with formation of the saprolite in a period or periods of ice- and permafrost-free conditions before 0.8 Ma.     

Discordance between cosmogenic nuclide concentrations in amalgamated sands and individual fluvial pebbles in an arid zone catchment

Based on cosmogenic ¹⁰Be and ²⁶Al analyses in 15 individual detrital quartz pebbles (16–21 mm) and cosmogenic ¹⁰Be in amalgamated medium sand (0.25–0.50 mm), all collected from the outlet of the upper Gaub River catchment in Namibia, quartz pebbles yield a substantially lower average denudation rate than those yielded by the amalgamated sand sample. ¹⁰Be and ²⁶Al concentrations in the 15 individual pebbles span nearly two orders of magnitude (0.22 ± 0.01 to 20.74 ± 0.52 × 10^{6 10}Be atoms g⁻¹ and 1.35 ± 0.09 to 72.76 ± 2.04 × 10^{6 26}Al atoms g⁻¹, respectively) and yield average denudation rates of ∼0.7 m Myr⁻¹ (¹⁰Be) and ∼0.9 m Myr⁻¹ (²⁶Al). In contrast, the amalgamated sand yields an average ¹⁰Be concentration of 0.77 ± 0.03 × 10⁶ atoms g⁻¹, and an associated mean denudation rate of 9.6 ± 1.1 m Myr⁻¹, an order of magnitude greater than the rates obtained for the amalgamated pebbles. The inconsistency between the ¹⁰Be and ²⁶Al in the pebbles and the ¹⁰Be in the amalgamated sand is likely due to the combined effect of differential sediment sourcing and longer sediment transport times for the pebbles compared to the sand-sized grains. The amalgamated sands leaving the catchment are an aggregate of grains originating from all quartz-bearing rocks in all parts of the catchment. Thus, the cosmogenic nuclide inventories of these sands record the overall average lowering rate of the landscape. The pebbles originate from quartz vein outcrops throughout the catchment, and the episodic erosion of the latter means that the pebbles will have higher nuclide inventories than the surrounding bedrock and soil, and therefore also higher than the amalgamated sand grains. The order-of-magnitude grain size bias observed in the Gaub has important implications for using cosmogenic nuclide abundances in depositional surfaces because in arid environments, akin to our study catchment, pebble-sized clasts yield substantially underestimated palaeo-denudation rates. Our results highlight the importance of carefully considering geomorphology and grain size when interpreting cosmogenic nuclide data in depositional surfaces.     

In situ cosmogenic 10Be production-rate calibration from the Southern Alps,New Zealand

We present a ¹⁰Be production-rate calibration derived from an early Holocene debris-flow deposit at about 1000 m above sea level in the central Southern Alps, New Zealand, in the mid-latitude Southern Hemisphere. Ten radiocarbon ages on macrofossils from a soil horizon buried by the deposit date the deposit to 9690 ± 50 calendar years before AD2008. Surface ¹⁰Be concentrations of seven large boulders partially embedded in the stable surface of the deposit are tightly distributed, yielding a standard deviation of ～2%. Conversion of the ¹⁰Be measurements to sea level/high-latitude values using each of five standard scaling methods indicates ¹⁰Be production rates of 3.84 ± 0.08, 3.87 ± 0.08, 3.83 ± 0.08, 4.15 ± 0.09, and 3.74 ± 0.08 atoms g^?1 a^?1, relative to the ‘07KNSTD’ ¹⁰Be AMS standard, and including only the local time-integrated production-rate uncertainties. When including a sea level high-latitude scaling uncertainty the overall error is ～2.5% (1σ) for each rate. To test the regional applicability of this production-rate calibration, we measured ¹⁰Be concentrations in a set of nearby moraines deposited before 18 060 ± 200 years before AD2008. The ¹⁰Be ages are only consistent with minimum-limiting ¹⁴C age data when calculated using the new production rates. This also suggests that terrestrial in situ cosmogenic-nuclide production did not change significantly from Last Glacial Maximum to Holocene time in New Zealand. Our production rates agree well with those of a recent calibration study from northeastern North America, but are 12–14% lower than other commonly adopted values. The production-rate values presented here can be used elsewhere in New Zealand for rock surfaces exposed during or since the last glacial period.     

Differences in 10Be concentrations between river sand,gravel and pebbles along the western side of the central Andes

Cosmogenic nuclides in river sediment have been used to quantify catchment-mean erosion rates. Nevertheless, variable differences in ¹⁰Be concentrations according to grain size have been reported. We analyzed these differences in eleven catchments on the western side of the Andes, covering contrasting climates and slopes. The data include eight sand (0.5–1 mm) and gravel (1–3 cm) pairs and twelve sand (0.5–1 mm) and pebble (5–10 cm) pairs. The difference observed in three pairs can be explained by a difference in the provenance of the sand and coarser sediment. The other sand–pebble pairs show a lower ¹⁰Be concentration in the pebbles, except for one pair that shows similar concentrations. Two sand–gravel pairs show a lower ¹⁰Be concentration in the gravel and the other five pairs show a higher ¹⁰Be concentration in the gravel. Differences in climate do not reveal a particular influence on the ¹⁰Be concentration between pairs. The analysis supports a model where pebbles and gravel are mainly derived from catchment areas that are eroding at a faster rate. The five gravel samples with high ¹⁰Be concentrations probably contain gravel that were derived from the abrasion of cobbles exhumed at high elevations. In order to validate this model, further work should test if pebbles are preferentially exhumed from high erosion rate areas, and if the difference between pebbles with high ¹⁰Be concentrations and sand decreases when the erosion rate tends to be homogeneous within a catchment.     

Climate controls on coupled processes of chemical weathering,bioturbation, and sediment transport across hillslopes

Most hillslope studies examining the interplay between climate and earth surface processes tend to be biased towards eroding parts of landscapes. This limitation makes it difficult to assess how entire upland landscapes, which are mosaics of eroding and depositional areas, evolve physio‐chemically as a function of climate. Here we combine new soil geochemical data and published ¹⁰Be‐derived soil production rates to estimate variations in chemical weathering across two eroding‐to‐depositional hillslopes spanning a climate gradient in southeastern Australia. At the warmer and wetter Nunnock River (NR) site, rates of total soil (–3 to –14 g m^‐2 yr^‐1; negative sign indicates mass loss) and saprolite (–18 to –32 g m^‐2 yr^‐1) chemical weathering are uniform across the hillslope transect. Alternatively, the drier hillslope at Frog's Hollow (FH) is characterized by contrasting weathering patterns in eroding soils (–30 to –53 g m^‐2 yr^‐1) vs. depositional soils (+91 g m^‐2 yr^‐1; positive sign indicates mass addition). This difference partly reflects mineral grain size sorting as a result of upslope bioturbation coupled with water‐driven soil erosion, as well as greater vegetative productivity in moister depositional soils. Both of these processes are magnified in the drier climate. The data reveal the importance of linking the erosion–deposition continuum in hillslope weathering studies in order to fully capture the coupled roles of biota and erosion in driving the physical and chemical evolution of hillslopes. Our findings also highlight the potential limitations of applying current weathering models to landscapes where particle‐sorting erosion processes are active. Copyright © 2018 John Wiley & Sons, Ltd.     

Dating chert (diagenetic silica) using in-situ produced 10Be: Possible complications revealed through a comparison with 36Cl applied to coexisting limestone

This paper highlights potential complications that may arise while using in situ produced ¹⁰Be to date exposure or burial events using diagenetic silica (chert). The initiation and evolution of large gravitational collapses in sedimentary rocks were constrained using cosmic ray exposure dating. Because these collapses occurred in a stratigraphic level composed of chert (diagenetic silica) concretions interbedded in limestone layers, their development was studied by performing in situ-produced ³⁶Cl and ¹⁰Be concentration measurements in both the limestone and coexisting diagenetic silica (chert), respectively. Following the routinely used decontamination and preparation protocols for ¹⁰Be produced in diagenetic silica, large discrepancies were observed with exposure ages determined by ³⁶Cl within carbonate for samples originating from the same scarp. While ³⁶Cl exposure ages were clustered as expected for a unique single gravitational event, ¹⁰Be exposure ages were scattered along the same studied scarps. To determine the origin of such a bias, petrological investigations were carried out for chert (diagenetic silica). Thin sections highlighted a complex mineralogical texture characterized by remnant silicified ooids showing calcitic cores, calcite inclusions and a dominant amorphous hydrated silica (grain > 20 μm). To decipher and characterize the potential origins of the excess measured ¹⁰Be within diagenetic silica, all samples were first reprocessed following the routine decontamination protocol (HCL–H₂SiF₆ leachings and three partial HF dissolutions) but starting from three different grain size fractions (GS1: 1000–500, GS2: 500–250 and GS3: 250–50 μm). The resulting concentrations clearly showed a decreasing ¹⁰Be content as a function of the grain size, but still yielded ¹⁰Be exposure ages significantly higher than ³⁶Cl counterparts. Because potential adsorption of ¹⁰Be at the surface of amorphous silica grains was suspected, partial dissolution steps following by a leaching step in hydroxylamine were investigated. Finally, it seems that an additional leaching in KOH allowed removal of the amorphous silica phase and the measured ¹⁰Be concentrations yielded ¹⁰Be exposure ages agreeing within uncertainties with the ³⁶Cl ones. This work suggests that measuring in situ produced ¹⁰Be within chert (amongst other types of diagenetic silica, e.g. flint, hornstone, jasper, etc.) containing amorphous silica requires caution.     

Holocene dust accumulation and the formation of polycyclic cinnamon soils (luvisols) in the Chinese Loess Plateau

Chinese loess–palaeosol sequences are well known for their records of monsoonal climatic variations. However, the modern processes of dust accumulation and soil formation remain poorly understood. A high‐resolution investigation on modern soils, including the measurement of magnetic susceptibility, particle‐size distribution, total Fe, total organic carbon, CaCO₃ content, and optical stimulated luminescence (OSL) dating was carried out on the Zhouyuan loess tableland in the southern Loess Plateau. The results indicate that modern cinnamon soils (luvisols) have developed on contemporarily accumulated aeolian dust during the Holocene. The aeolian loess accumulated during the Younger Dryas was identi?ed in the top part of the Malan Loess that underlay the modern soil by OSL dating and proxy climatic data. It indicates that the Malan Loess accumulated during the last glaciation (marine isotope stages 2–4) does not serve as the parent material for the modern soils. Pedogenesis of the soils started with the increased precipitation and soil moisture that have occurred on the loess tableland since the early Holocene. Precipitation‐driven pedogenesis and organic activities are responsible for the leaching of CaCO₃, decomposition of mineral dust and the production of clay and ferromagnetic minerals. Drier intervals have interrupted soil formation several times, and therefore pro?les with multiple soils have been developed at many sites on the loess tableland. At places where soil erosion was relatively strong, either a single soil or welded soils are preserved in the Holocene pro?les. This does not necessarily mean, however, that modern soils over the plateau have been developed without interruption under a constantly warmer, moister climate. This is signi?cant for understanding the surface processes and climatic variation during the formation of the numerous palaeosols over the Loess Plateau in the Quaternary. Copyright © 2003 John Wiley & Sons, Ltd.     

Dating carbonate rocks with in-situ produced cosmogenic Be: Why it often fails

Surface exposure dating of carbonate rocks using cosmogenic ¹⁰Be is problematic. We have performed step-wise leaching of calcite-rich samples in order to investigate the reasons for this. Results on different grain size fractions clearly indicate the source of atmospheric ¹⁰Be is clay. We demonstrate that partial-leaching procedures, which result in moderate pH levels will not release ¹⁰Be (in-situ produced or atmospheric) due to the instant re-absorption on grain surfaces. By contrast, under strongly acidic conditions, all absorbed ¹⁰Be is leached from aluminosilicates giving abnormally high ¹⁰Be concentrations and consequently exposure ages that are too old. Dating is only possible if samples do not contain any clay minerals or if they can be removed prior to carbonate dissolution.     

CRONUS-Earth calibration samples from the Huancané II moraines,Quelccaya Ice Cap,Peru

The Huancané II moraines deposited by the Quelccaya Ice Cap in southern Peru were selected by the CRONUS-Earth Project as a primary site for evaluating cosmogenic-nuclide scaling methods and for calibrating production rates. The CRONUS-Earth Project is an effort to improve the state of the art for applications of cosmogenic nuclides to earth-surface chronology and processes. The Huancané II moraines are situated in the southern Peruvian Andes at about 4850 m and ∼13.9°S, 70.9°W. They are favorable for cosmogenic-nuclide calibration because of their low-latitude and high-elevation setting, because their age is very well constrained to 12.3 ± 0.1 ka by 34 radiocarbon ages on peat bracketing the moraines, and because boulder coverage by snow or soil is thought to be very unlikely. However, boulder-surface erosion by granular disintegration is observed and a ∼4% correction was applied to measured concentrations to compensate. Samples from 10 boulders were analyzed for ¹⁰Be, ²⁶Al, and ³⁶Cl. Interlaboratory bias at the ∼5% level was the largest contributor to variability of the ¹⁰Be samples, which were prepared by three laboratories (the other two nuclides were only prepared by one laboratory). Other than this issue, variability for all three nuclides was very low, with standard deviations of the analyses only slightly larger than the analytical uncertainties. The site production rates (corrected for topographic shielding, erosion, and radionuclide decay) at the mean site elevation of 4857 m were 45.5 ± 1.6 atoms ¹⁰Be (g quartz)⁻¹ yr⁻¹, 303 ± 15 atoms ²⁶Al (g quartz)⁻¹ yr⁻¹, and 1690 ± 100 atoms ³⁶Cl (g K)⁻¹ yr⁻¹. The nuclide data from this site, along with data from other primary sites, were used to calibrate the production rates of these three nuclides using seven global scaling methods. The traditional Lal formulation and the new Lifton-Sato-Dunai calibrations yield average ages for the Huancané samples that are in excellent-to-good agreement with the radiocarbon age control (within 0.7% for ¹⁰Be and ³⁶Cl and 6% for ²⁶Al). However, all of the neutron-monitor-based methods yielded ages that were too young by about 20%. The nuclide production ratios at this site are 6.74 ± 0.34 for ²⁶Al/¹⁰Be in quartz and 37.8 ± 2.3 (atoms ³⁶Cl (g K)⁻¹) (atom ¹⁰Be (g SiO₂)⁻¹)⁻¹ for ³⁶Cl/¹⁰Be, in sanidine and quartz, respectively.     

A locally calibrated,late glacial 10Be production rate from a low-latitude,high-altitude site in the Peruvian Andes

Well-dated records of tropical glacier fluctuations are essential for developing hypotheses and testing proposed mechanisms for past climate changes. Since organic material for radiocarbon dating is typically scarce in low-latitude, high-altitude environments, surface exposure-age dating, based on the measurement of in situ produced cosmogenic nuclides, provides much of the chronologic information on tropical glacier moraines. Here, we present a locally calibrated ¹⁰Be production rate for a low-latitude, high-altitude site near Quelccaya Ice Cap (∼13.95°S, 70.89°W, 4857 m asl) in the southeastern Peruvian Andes. Using an independent age (12.35 +0.2, −0.02 ka) of the late glacial Huancané IIa moraines based on thirty-four bracketing radiocarbon ages and twelve ¹⁰Be concentrations of boulders on the moraines, we determine a local production rate of 43.28 ± 2.69 atoms gram⁻¹ year⁻¹ (at g⁻¹ yr⁻¹). Reference ¹⁰Be production rates (i.e., production rates by neutron spallation appropriate for sea-level, high-latitude sites) range from 3.97 ± 0.09 to 3.78 ± 0.09 at g⁻¹ yr⁻¹, determined using scaling after Lal (1991) and Stone (2000) and depending on our assumed boulder surface erosion rate. Since our boulder surface erosion rate estimate is a minimum value, these reference production rates are also minimum values. A secondary control site on the Huancané IIIb moraines suggests that the ¹⁰Be production rates are at least as low as, or possibly lower than, those derived from the Huancané IIa moraines. These sea-level, high-latitude production rates are at least 11–15% lower than values derived using the traditional global calibration dataset, and they are also lower than those derived from the late glacial Breque moraine in the Cordillera Blanca of Peru. However, our sea-level, high-latitude production rates agree well with recently published, locally calibrated production rates from the Arctic, New Zealand, and Patagonia. The production rates presented here should be used to calculate ¹⁰Be exposure ages in low-latitude, high-altitude locations, particularly in the tropical Andes, and should improve the ability to compare the results of studies using ¹⁰Be exposure-age dating with other chronological data.     

Tracing environmental change in southern Patagonia using beryllium isotopes,Laguna Potrok Aike,Argentina

We have examined the relationship between beryllium isotopes and the hydrological record of Laguna Potrok Aike, a maar lake in southern Argentina for the past 16,000 cal BP. Our study shows that sedimentary ¹⁰Be and ⁹Be records of Laguna Potrok Aike are associated with the hydrological balance, when compared to other proxies such as Ca, Ti and total inorganic carbon (TIC). During drier periods, the level of ⁹Be is decreased. ¹⁰Be follows this trend from 16,000 to 8000 cal BP, for younger samples, the concentration of ¹⁰Be increases at about 5000 cal BP and in recent times, but is otherwise relatively constant. At 13,000 cal BP total beryllium (⁹Be) was relatively low, but the ¹⁰Be/⁹Be ratio was the highest for the entire record studied. Our study shows that beryllium isotopes can be used for tracing climatic signals associated with lake level changes, i.e., dry or wet conditions at Laguna Potrok Aike.     

The critical role of climate and saprolite weathering in landscape evolution

Landscapes evolve in response to external forces, such as tectonics and climate, that influence surface processes of erosion and weathering. Internal feedbacks between erosion and weathering also play an integral role in regulating the landscapes response. Our understanding of these internal and external feedbacks is limited to a handful of field‐based studies, only a few of which have explicitly examined saprolite weathering. Here, we report rates of erosion and weathering in saprolite and soil to quantify how climate influences denudation, by focusing on an elevation transect in the western Sierra Nevada Mountains, California. We use an adapted mass balance approach and couple soil‐production rates from the cosmogenic radionuclide (CRN) ¹⁰Be with zirconium concentrations in rock, saprolite and soil. Our approach includes deep saprolite weathering and suggests that previous studies may have underestimated denudation rates across similar landscapes. Along the studied climate gradient, chemical weathering rates peak at middle elevations (1200–2000 m), averaging 112·3 ± 9·7 t km^–2 y^–1 compared to high and low elevation sites (46·8 ± 5·2 t km^?2 y^?1). Measured weathering rates follow similar patterns with climate as those of predicted silica fluxes, modeled using an Arrhenius temperature relationship and a linear relationship between flux and precipitation. Furthermore, chemical weathering and erosion are tightly correlated across our sites, and physical erosion rates increase with both saprolite weathering rates and intensity. Unexpectedly, saprolite and soil weathering intensities are inversely related, such that more weathered saprolites are overlain by weakly weathered soils. These data quantify exciting links between climate, weathering and erosion, and together suggest that climate controls chemical weathering via temperature and moisture control on chemical reaction rates. Our results also suggest that saprolite weathering reduces bedrock coherence, leading to faster rates of soil transport that, in turn, decrease material residence times in the soil column and limit soil weathering. Copyright © 2009 John Wiley & Sons, Ltd.     

Paired 10Be sampling of polished bedrock and erratic boulders to improve dating of glacial landforms: an example from the Western Alps

Cosmogenic nuclide dating of glacial landforms may lead to ambiguous results for ice retreat histories. The persistence of significant cosmogenic concentrations inherited from previous exposure may increase the apparent exposure ages for polished bedrocks affected by limited erosion under ice and for erratic boulders transported by glaciers and previously exposed in high-altitude rock walls. In contrast, transient burying by moraines, sediments and snow decreases the apparent exposure age. We propose a new sampling strategy, applied to four sites distributed in the Arc and Arve valleys in the Western Alps, to better constrain the factors that can bias exposure ages associated with glacial processes. We used the terrestrial cosmogenic nuclide ¹⁰Be (TCN) to estimate the exposure time from paired sampling of depth profiles in polished bedrock and on overlying erratic boulders. For a given sampling site, the exposure ages for both the polished bedrock and boulder are expected to be the same. However, in six cases out of seven, boulders had significantly higher ¹⁰Be surface concentrations than those of the associated polished surfaces. In present and past glacial processes, the ¹⁰Be distribution with depth for boulders and bedrocks implies the presence of an inheritance concentration of ¹⁰Be. Our study suggests that ¹⁰Be concentrations in erratic boulders and in polished bedrocks provide maximum and minimum exposure ages of the glacial retreat, respectively. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

A high-resolution magnetic susceptibility study of a loess/palaeosol couplet at Baoji,China

Summary Magnetic susceptibility, and its frequency dependence, are reported for 288 individual samples spanning the 8.3 m — thick S3 palaeosol/L4 loess couplet at an important site in the Chinese Loess Plateau. The resulting profile demonstrates that there is a very close link between magnetic properties and soil development: soil and loess sub-divisions recognised visually in the field are clearly reflected in both the bulk susceptibility data and in its frequency dependence. As found at all Chinese sites, the distribution of susceptibilities is bi-modal, one peak representing loess (median=0.74×10⁻⁶m³/kg), the other representing palaeosol (median=2.99×10⁻⁶m³/kg). This is the basis of the climatic proxy information. The Baoji section is the site of one of the most detailed grain-size analyses available anywhere (Ding et al., 1994), and we find a strong correlation between the resulting profile and the susceptibility data reported here. Frequency-dependence of susceptibility exhibits slight differences between the loess and palaeosol populations which we interpret as reflecting reduced transport distances during glacial intervals when the Siberian High causes stronger winds and expands southwards.     

10Be accumulation in a soil chronosequence

We have measured the concentration of the cosmogenic isotope¹⁰Be in soil samples from various horizons at six sites, including three independently dated Rappahannock River terraces and a previously undated Piedmont soil to which we have assigned an age. All of the incident¹⁰Be can be accounted for in one of these soils and a second is within a factor of two. In three soils, whose concentrations vary widely with depth, a significant fraction of the incident¹⁰Be cannot be accounted for. Incomplete sampling, and enhanced Be mobility caused by organic components, are the probable reasons for the low inventory of Be from these three soils. Overall, the data from these six sites indicate that¹⁰Be accumulation could be used to assign ages to soils if Be is not mobilized and lost from the soil profile.