Transient ocean warming and shifts in carbon reservoirs during the early Danian

A long-standing question in Paleogene climate concerns the frequency and mechanism of transient greenhouse gas-driven climate shifts (hyperthermals). The discovery of the greenhouse gas-driven Paleocene–Eocene Thermal Maximum (PETM; ～ 55 Ma) has spawned a search for analogous events in other parts of the Paleogene record. On the basis of high-resolution bulk sediment and foraminiferal stable isotope analyses performed on three lower Danian sections of the Atlantic Ocean, we report the discovery of a possible greenhouse gas-driven climatic event in the earliest Paleogene. This event – that we term the Dan-C2 event – is characterized by a conspicuous double negative excursion in δ¹³C and δ¹⁸O, associated with a double spike in increased clay content and decreased carbonate content. This suggests a double period of transient greenhouse gas-driven warming and dissolution of carbonates on the seafloor analogous to the PETM in the early Paleocene at ～ 65.2 Ma. However, the shape of the two negative carbon isotope excursions that make up the Dan-C2 event is different from the PETM carbon isotope profile. In the Dan-C2 event, these excursions are fairly symmetrical and each persisted for about ～ 40 ky and are separated by a short plateau that brings the combined duration to ～ 100 ky, suggesting a possible orbital control on the event. Because of the absence of a long recovery phase, we interpret the Dan-C2 event to have been associated with a redistribution of carbon that was already in the biosphere. The Dan-C2 event and other early Paleogene hyperthermals such as the short-lived early Eocene ELMO event may reflect amplification of a regular cycle in the size and productivity of the marine biosphere and the balance between burial of organic and carbonate carbon.     

High-resolution upper Pliocene to Pleistocene calcareous nannofossil biostratigraphy in Ocean Drilling Program Hole 1146A in the South China Sea

We established a high-resolution calcareous nannofossil biostratigraphy for the late Pliocene–Pleistocene by analyzing a 242 m-thick, continuous sedimentary succession from Ocean Drilling Program Site 1146, Hole A, in the South China Sea (SCS). A total of 14 calcareous nannofossil datums were detected in the SCS succession. They are, in descending order: first occurrence (FO) of Emiliania huxleyi, last occurrence (LO) of Pseudoemiliania lacunosa, LO of Reticulofenestra asanoi, FO of Gephyrocapsa parallela, FO of R. asanoi, LO of large Gephyrocapsa spp., FO of large G. spp., FO of Gephyrocapsa oceanica, FO of Gephyrocapsa caribbeanica, LO of Calcidiscus macintyrei, LO of Discoaster brouweri, LO of Discoaster pentaradiatus, LO of Discoaster surculus, and LO of Discoaster tamalis. The FO of E. huxleyi was not precisely detected due to poor preservation and dissolution of nannofossils in the underlying strata. We refined the previous calcareous nannofossil biostratigraphy in the SCS by identifying Gephyrocapsa species and four evolutionary extinction events of the genus Discoaster. The proposed calcareous nannofossil biostratigraphy correlates with those reported in other terrestrial and marine areas/sites and global benthic foraminiferal δ¹⁸O records. The age–depth curves based on nannofossil biostratigraphy indicate a significant increase in the sedimentation rates at the LO of R. asanoi (0.91–0.85 Ma). The timing of this increase corresponds to reef expansion in the Ryukyu Islands linked to a stepwise increase in Kuroshio Current intensity. This timing is broadly coeval with a sea surface temperature increase of ∼2 °C in the northwestern Pacific due to expansion of the Western Pacific Warm Pool towards the north and south subtropical regions. This can be explained by increased weathering and erosion of terrestrial areas in glacial periods and increased rainfall causing higher sediment transport in interglacial periods, which were both linked to Middle Pleistocene Transition-related climatic changes.     

Sedimentary and geochemical evidence of Eocene climate change in the Xining Basin,northeastern Tibetan Plateau

The northeastern Tibetan Plateau began to grow during the Eocene and it is important to understand the climatic history of Asia during this period of so-called ‘doubthouse' conditions. However, despite major advances in the last few decades,the evolutionary history and possible mechanisms of Eocene climate change in the northeastern Tibetan Plateau remain unclear.The Xining Basin in the northeastern Tibetan Plateau contains a continuous sequence of Early to Late Eocene non-marine sediments which provides the opportunity to resolve long-term climate changes during this period. In this study, we report the results of analyses of lithofacies, sediment color and geochemistry of bulk samples collected from the Xijigou section of the Xining Basin. An abrupt lithofacies change between the Early(~52–40 Ma) and Late Eocene(~40–34 Ma) indicates a change in the depositional environment from a shallow lake to a playa lake in response to a significant climatic shift. During ~52–40 Ma,higher values of sediment redness(a*), redness/lightness(a*/L*) and higher modified Chemical Index of Weathering(CIW′)indicate a relatively warm and humid climate, while from ~40–34 Ma the lower values of a*, a*/L*and lower CIW′ imply subhumid to semi-arid climatic conditions. The paleoclimatic records indicate a long-term(~52–34 Ma) trend of decreasing chemical weathering, consistent with global climate change. An abrupt sharp excursion of the proxy records during ~42–40 Ma suggests a relatively brief warm interval, corresponding to the Middle Eocene Climatic Optimum(MECO). We suggest that global cooling substantially reduced humidity in inner Asia, resulting in sub-humid to semi-arid climatic conditions after 40 Ma in the Xining Basin, which may have been responsible for the long-term trend of decreasing chemical weathering during the Eocene.     

Peraluminous igneous rocks as an indicator of thermogenic methane release from the North Atlantic Volcanic Province at the time of the Paleocene–Eocene Thermal Maximum (PETM)

Unusual cordierite-bearing peraluminous dacites, produced by melting of organic-rich sediments by intrusion of basaltic magma, are found within the North Atlantic Volcanic Province (NAVP). Calculations suggest that formation of the dacites, radiometric dated at 55.9?±?0.3 Ma and possibly widespread, could have released an average of ～4,500 Gt (range from 3,000 to 6,000 Gt) of carbon as methane, with a δ¹³C of about ?35‰. Published model results suggest that such a methane release could explain the negative δ¹³C excursion in the oceans and atmosphere, the extreme global warming, and the marked dissolution of carbonates in the deep oceans that accompanied the concurrent Paleocene–Eocene Thermal Maximum (PETM). Outgassing from melting of sediments and formation of dacites, possibly in conjunction with methane produced in contact metamorphic aureoles and by methane hydrate release, provides a novel way of explaining the PETM and its timing.     

Carbonate deposits on submerged seamounts in the northwestern Pacific Ocean

Abstract   The lithology of shallow-water carbonates collected from 19 sites on 16 seamounts in six areas of the northwestern Pacific Ocean using the Deep-sea Boring Machine System are described. The areas include the Amami Plateau, Daito Ridge, Oki-Daito Ridge, Urdaneta Plateau, Kyushu-Palau Ridge and Ogasawara Plateau. Chronological constraint is provided by calcareous nannofossil biostratigraphy, planktonic foraminiferal biostratigraphy, larger foraminiferal biostratigraphy and strontium (Sr) isotope stratigraphy. Large amounts of shallow-water carbonates accumulated on the seamounts during the Oligocene, a relatively cool period, whereas limited carbonate deposits formed during the Early Miocene, a relatively warm period. This might indicate that deposition of shallow-water carbonates on seamounts in the northwestern Pacific Ocean was not necessarily controlled by climatic conditions, but was related to volcanism and tectonics that served as foundations for reef/carbonate-platform formation. Remarkable differences in biotic composition exist between Cretaceous and Cenozoic shallow-water carbonates. Late Cretaceous shallow-water carbonates are distinguished by the occurrence of rudists, solenoporacean algae and microencrusters. Middle Eocene to Early Oligocene shallow-water carbonates are dominated by Halimeda or nummulitid and discocyclinid larger foraminifers. Scleractinian corals became common from the Oligocene onward. Nongeniculate coralline algae and larger foraminifers were common to abundant throughout the Eocene to the Pleistocene. The replacement of major carbonate producers in the shallow-water carbonate factory during post-Cretaceous time is in accordance with previous studies and is considered to reflect a shift in seawater chemistry.     

Tectonic significance of Eocene and Cretaceous radiolaria from South Andaman Island, northeast Indian Ocean

Abstract Eocene (Middle) and Cretaceous (Campanian) radiolarian faunas from the basement rocks of the southern part of South Andaman Island in the northeastern Indian Ocean affirm the sedimentological hiatus that encompassed part of the Paleocene to Early Eocene ages in these islands, and its extension northward to Indoburma region and south to the outer islands of the Sunda Arc.     

Magnetostratigraphic correlation of the Oxfordian–Kimmeridgian boundary

A magnetic polarity pattern for Boreal and Sub-Boreal ammonite zones of the Upper Oxfordian to Lower Kimmeridgian was established and confirmed in four British sections, including the proposed Global Boundary Stratotype Section and Point (GSSP) on the Isle of Skye (Scotland) to define the base of the international Kimmeridgian Stage. A coeval pattern for Sub-Mediterranean ammonite zones was compiled from seven sections in Poland, one German section and multi-section composites from France and Spain. The mean paleopole for the European Craton (excluding Spain) at the Oxfordian–Kimmeridgian boundary is 74.2°N, 181.3°E (Α₉₅ = 3.8°). The common magnetic polarity scale enables inter-correlation of ammonite subzones among these three faunal provinces and to the marine magnetic-anomaly M-Sequence. The proposed GSSP at the base of the Pictonia baylei Zone is near the base of an extended interval dominated by reversed polarity, which is interpreted to be Chron M26r. This GSSP level projects to the lower to middle part of the Epipeltoceras bimammatum Subzone, which is the middle subzone of this E. bimammatum Zone in the Sub-Mediterranean standard zonation. In contrast, the traditional placement of the Oxfordian–Kimmeridgian boundary in that Sub-Mediterranean standard zonation (base of Sutneria platynota Zone) is at the base of Chron M25r, or nearly 1 million years younger.     

New age data from the Lesnaya Group: A key to understanding the timing of arc-continent collision, Kamchatka, Russia

Abstract The Lesnaya Group is part of a thick, poorly dated turbidite assemblage that sits in the footwall of a regionally extensive collision zone in which the Cretaceous–Paleocene Olutorsky island arc terrane was obducted onto continental margin basin strata. Nannoplankton from 18 samples from the upper part of the Lesnaya Group yield Paleocene through Middle Eocene assemblages. Detrital zircons from nine sandstone samples have a young population of fission-track ages that range from 43.7 ± 3.4 to 55.5 ± 3.5 Ma (uppermost Paleocene to Middle Eocene). The deformed footwall rocks of the Lesnaya Group and the overlying thrusts of the Olutorsky arc terrane, are unconformably overlain by neoautochthonous deposits which are Lutetian (lower Middle Eocene) and younger. Together, these new data indicate that thrusting, which is inferred to have been driven by collision of the Cretaceous–Paleocene island arc with north-eastern Asia, took place in the mid-Lutetian, at about 45 Ma.     

Episodic Cenozoic volcanism and tectonism in the Andes of Peru

Radiometric and geologic information indicate a complex history of Cenozoic volcanism and tectonism in the central Andes. K-Ar ages on silicic pyroclastic rocks demonstrate major volcanic activity in central and southern Peru, northern Chile, and adjacent areas during the Early and Middle Miocene, and provide additional evidence for volcanism during the Late Eocene. A provisional outline of tectonic and volcanic events in the Peruvian Andes during the Cenozoic includes: one or more pulses of igneous activity and intense deformation during the Paleocene and Eocene; a period of quiescence, lasting most of Oligocene time; reinception of tectonism and volcanism at the beginning of the Miocene; and a major pulse of deformation in the Middle Miocene accompanied and followed through the Pliocene by intense volcanism and plutonism. Reinception of igneous activity and tectonism at about the Oligocene-Miocene boundary, a feature recognized in other circum-Pacific regions, may reflect an increase in the rate of rotation of the Pacific plate relative to fixed or quasifixed mantle coordinates. Middle Miocene tectonism and latest Tertiary volcanism correlates with and probably is genetically related to the beginning of very rapid spreading at the East Pacific Rise.     

Calcareous nannofossil biostratigraphic study of forearc basin sediments: Lower to Upper Cretaceous Budden Canyon Formation (Great Valley Group), northern California,USA

The results of a calcareous nannofossil biostratigraphic investigation of the North Fork Cottonwood Creek section of the Budden Canyon Formation (BCF; Hauterivian–Turonian) in northern California are summarized using the Boreal – cosmopolitan Boreal Nannofossil Biostratigraphy (BC) – Upper Cretaceous Nannofossil Biostratigraphy (UC) nannofossil zonal schemes of Bown et al. and Burnett et al. Sixteen intervals, ranging from the BC15 to UC8 zones, were established in the section. Combined biostratigraphic and magnetostratigraphic studies suggest a Hauterivian to mid‐Turonian age for the studied sequence. The Hauterivian–Barremian, Barremian–Aptian, Aptian–Albian, Albian–Cenomanian, and Cenomanian–Turonian stage boundaries were delineated near the top of the Ogo Member, below the Huling Sandstone Member, within the upper Chickabally Member, in the upper portion of the Bald Hills Member and within the Gas Point Member, respectively. Unconformities probably exist at the base of the Huling Sandstone Member and the upper part of the upper Chickabally Member. The nannofossil assemblage in the North Fork Cottonwood Creek suggests that the study area was under the influence of cold‐water conditions during the Barremian to Lower Aptian interval, shifting to tropical/warm‐water conditions during the Albian to Turonian interval as a result of the mid‐Cretaceous global warming. Although oceanic anoxic events have not yet been reported in the BCF, preliminary total organic carbon, along with nannofossil data, suggest the presence of the global Cenomanian–Turonian boundary oceanic anoxic event 2.     

Middle Miocene to Pleistocene magneto-biostratigraphy of ODP Sites 1150 and 1151, northwest Pacific: Sedimentation rate and updated regional geological timescale

Abstract Shipboard and shore‐based investigation on siliceous and calcareous microfossil biostratigraphy, magneto‐stratigraphy and tephrostratigraphy identified numerous datum events from the sedimentary sequences of Sites 1150 and 1151 drilled on the forearc basin of northern Japan by the Ocean Drilling Program Leg 186. Some 83 datum events were selected to construct new age–depth models for the sites. Based on the reliable magneto‐stratigraphy from the Pleistocene to the Upper Miocene, which were correlated to the standard geomagnetic polarity timescale, and on excellent records of diatom and radiolarian biostratigraphy throughout the sequences, the shipboard age model was revised. Major revisions referred to stratigraphic position of the Miocene–Pliocene boundary that has been shifted more than 200 m downward in each sequence. The age–depth relations of the forearc sites represent drastic changes in the sedimentation rate—extremely high (40 cm/k.y. on average) in the Early Pliocene and low (less than 2 cm/k.y. on average) in the Middle Miocene—and several hiatuses exist throughout the sequence. The drastic changes can be related mostly to changes in diatom sedimentation and the tectonics of the Japanese Island Arc. Local ages for some foraminiferal, calcareous nannofossil and radiolarian bioevents are estimated from the age–depth models at each site. These newly calibrated bioevents and biozones as well as established diatom biostratigraphy are incorporated into the updated magneto‐biochronologic timescale, which will contribute to an improvement in biochronologic accuracy of Neogene sediments in northern Japan and adjacent areas.     

Rapid evolution of the Eocene accretionary complex (Hyuga Group) of the Shimanto terrane in southeastern Kyushu, southwestern Japan

Abstract   Detailed geologic examination of the Eocene accretionary complex (Hyuga Group) of the Shimanto terrane in southeastern Kyushu revealed that the oceanic plate was composed of Paleocene to Lower Eocene mudstone and siliceous mudstone, lower Middle Eocene red mudstone, and mid-Middle Eocene trench-fill turbidite with siltstone breccia, successively overlying the pre-Eocene oceanic plate. This oceanic plate sequence was overlain by Upper Eocene siltstone. Deposition of the lower Middle Eocene red mudstone was accompanied by basalt flows and it is interbedded with continental felsic tuff, which indicates that the basalt and red mudstone were deposited near the trench just before accretion. The Hyuga Group has very similar geological structure to that of the chert–clastic complexes found in the Jurassic accretionary complexes in Japan: that is, a decollement fault formed in the middle of an oceanic plate sequence, and an imbricate structure formed only in the upper part of the sequence. Thus, it appears that the Hyuga Group was formed by the same accretionary process as the Jurassic accretionary complexes. No accretion occurred before the Middle Eocene, and the rapid accretion of the Hyuga Group was commenced by the supply of coarse terrigenous sediments in the mid-Middle Eocene, when the direction of movement of the Pacific Plate changed. The pre-Eocene oceanic basement and lower Middle Eocene volcanic activity suggest that the oceanic plate partly preserved in the Hyuga Group was very similar to the northern part of the present West Philippine Sea Plate.     

Linkage of deep sea rapid acidification process and extinction of benthic foraminifera in the deep sea at the Paleocene/Eocene transition

Ocean Drilling Program Leg 199 Site 1220 provides a continuous sedimentary section across the Paleocene/Eocene (P/E) transition in the carbonate‐bearing sediments on 56–57 Ma oceanic crust. The large negative δ¹³C shift in seawater is likely due to the disintegration of methane hydrate, which is expected to be rapidly changed to carbon dioxide in the atmosphere and well‐oxygenated seawater, leading to a reduction in deep‐sea pH. A pH decrease was very likely responsible for the emergence of agglutinated foraminiferal fauna as calcareous fauna was eliminated by acidification at the P/E transition at Site 1220. The absence of the more resistant calcareous benthic foraminifera and the presence of the planktonic foraminifera at Site 1220 is interesting and unique, which indicates that calcareous benthic foraminifera suffered greatly from living on the seafloor. Box model calculation demonstrates that, assuming the same mean alkalinity as today, pCO₂ must increase from 280 ppm to about 410 ppm for the calcite undersaturation in the deep ocean and for the oversaturation in the surface ocean during the P/E transition. The calculated increased pCO₂ coincides with paleo‐botanical evidence. The current global emission rate (～7.3 peta (10¹⁵) gC/y) of anthropogenic carbon input is approximately 30 times of the estimate at the P/E transition. The results at the P/E transition give an implication that the deep sea benthic fauna will be threatened in future in combination with ocean acidification, increased sea surface temperature and more stratified surface water.     

Evolution and global correlation for strontium isotopic composition of marine Triassic from Huaying Mountains,eastern Sichuan,China

Strontium isotope stratigraphy (SIS) has progressively become an efficient chemostratigraphic tool in the research and correlation of global geological events, such as global sea level fluctuations, orogeny, and paleoclimatic and paleoenvironmental changes. In this paper, 87Sr/86Sr ratios of the Triassic marine carbonate rock samples from Huaying Mountains, eastern Sichuan are measured, and the corre-sponding Sr-isotopic curve is constructed, based on the fundamental principle of strontium isotope stratigraphy, analysis of rock fabric, luminescent intensity, chemical composition and representative evaluation for the coeval seawater information. The 87Sr/86Sr ratios show a rapid rise from 0.70721 near the Permian-Triassic transition to 0.70830 at the end of Early Triassic, and then they decline rapidly to 0.70787 in the early Middle Triassic. These data are generally coincident with 87Sr/86Sr ratios of coeval seawater from previous papers, and the curve is also similar to other previous curves. This indicates that the global geological events are the most important controlling factors to the strontium isotope evolution of the global seawater in the Early and Middle Triassic.     

The relationship between the growth process of the ferromanganese crusts in the pacific seamount and Cenozoic ocean evolvement

Base on the Os isotope stratigraphy together with the empirical growth rate models using Co concentrations, the growth ages of the ferromanganese crusts MHD79 and MP3D10 distributed in the seamount of Pacific are confirmed. Through the contrast and research on the previous achievements including ODP Leg 144 and the crusts CD29-2, N5E-06 and N1–15 of the seamount of the Central Pacific, the uniform five growth and growth hiatus periods of them are found, and closely related to the Cenozoic ocean evolvement process. In the Paleocene Carbon Isotope Maximum (PCIM), the rise of the global ocean productivity promoted the growth of the seamount crust; the first growth hiatus (I) of the ferromanganese crust finished. In the Paleocene-Eocene Thermal Maximum (PETM), though the vertical exchange of seawater was weakened, the strong terrestrial chemical weathering led to the input of a great amount of the terrigenous nutrients, which made the bioproductivity rise, so there were no crust hiatuses. During 52–50 Ma, the Early Eocene Optimum Climate (EECO), the two poles were warm, the latitudinal temperature gradient was small, the wind-driven sea circulation and upwelling activity were weak, the terrestrial weathering was also weakened, the open ocean bioproductivity decreased, and the ferromanganese crust had growth hiatus again (II). From early Middle Eocene-Late Eocene, Oligocene, it was a long-term gradually cooling process, the strengthening of the sea circulation and upwelling led to a rise of bioproductivity, and increase of the content of the hydrogenous element Fe, Mn and Co and the biogenous element Cu, Zn, so that was the most favorable stage for the growth of ferromanganese crust (growth periods III and IV) in the studied area. The hiatus III corresponded with the Eocene- Oligocene boundary, is inferred to relate with the global climate transformation, celestial body impact event in the Eocene-Oligocene transition. From the early to the middle Miocene, a large-scale growth hiatus (hiatus period IV) of the ferromanganese crust in the studied area is inferred to relate with temporary warm up climate and ephemeral withdrawal of Antarctic bottom water in the early Miocene. After that, the Antarctic ice sheets extended, the bottom water circumfluence strengthened, the ocean fertility increased, and the once interrupted crust continued to grow in the late Miocene (growth period V). Supported by China Ocean Mineral Resources Research and Development Association “10th Five Year” Topic (Grant No. DY105-01-04-14)     

Magnetostratigraphy of Plio–Pleistocene fossiliferous cave sediments in the Bubing Basin,southern China

Our understanding of the chronological sequence of Pleistocene land mammal faunas (including hominids) preserved in caves and fissures in the karstic terrain of subtropical southern China has been greatly impeded by the discontinuous nature of the strata yielding the fossils. A contributory issue is the lack of suitable elements for numerical dating, especially for the Early Pleistocene cave sediments. Here we present new magnetostratigraphic dating results for five cave sedimentary sequences in the Bubing Basin, Guangxi Zhuang Autonomous Region, which contain the typical Pleistocene Gigantopithecus fauna and Ailuropoda–Stegodon fauna of southern China. The five karstic caves are situated at elevations ranging from 252 m to 191 m above sea level. The integrated dating results reveal that the five cave sedimentary sequences span an age range from the late Gauss normal Chron to the early Brunhes normal Chron. The faunas are assigned to >2.6 Ma (Mohui–houshan Cave), 1.95–1.78 Ma (Mohui Cave), 0.99–0.78 Ma (Baolai Cave) and ∼0.7 Ma (Upper Wuyun and Ganxian Caves). Furthermore, by combining our new magnetostratigraphy work with previously published magnetostratigraphic, U–series and electron spin resonance dating results, a chronological sequence of the Plio–Pleistocene mammalian faunas from cave sites in southern China has been established. The chronological sequence contributes to an improved understanding of the evolutionary processes of Plio–Pleistocene land mammals, as well as of early humans in subtropical southern China.     

Triassic mid-oceanic sedimentation in Panthalassa Ocean: Sambosan accretionary complex, Japan

Abstract   The Sambosan accretionary complex of southwest Japan was formed during the uppermost Jurassic to lowermost Cretaceous and consists of basaltic rocks, carbonates and siliceous rocks. The Sambosan oceanic rocks were grouped into four stratigraphic successions: (i) Middle Upper Triassic basaltic rock; (ii) Upper Triassic shallow-water limestone; (iii) limestone breccia; and (iv) Middle Middle Triassic to lower Upper Jurassic siliceous rock successions. The basaltic rocks have a geochemical affinity with oceanic island basalt of a normal hotspot origin. The shallow-water limestone, limestone breccia, and siliceous rock successions are interpreted to be sediments on the seamount-top, upper seamount-flank and surrounding ocean floor, respectively. Deposition of the radiolarian chert of the siliceous rock succession took place on the ocean floor in Late Anisian and continued until Middle Jurassic. Oceanic island basalt was erupted to form a seamount by an intraplate volcanism in Late Carnian. Late Triassic shallow-water carbonate sedimentation occurred at the top of this seamount. Accumulation of the radiolarian chert was temporally replaced by Late Carnian to Early Norian deep-water pelagic carbonate sedimentation. Biotic association and lithologic properties of the pelagic carbonates suggest that an enormous production and accumulation of calcareous planktonic biotas occurred in an open-ocean realm of the Panthalassa Ocean in Late Carnian through Early Norian. Upper Norian ribbon chert of the siliceous rock succession contains thin beds of limestone breccia displaced from the shallow-water buildup resting upon the seamount. The shallow-water limestone and siliceous rock successions are nearly coeval with one another and are laterally linked by displaced carbonates in the siliceous rock succession.     

Ar/Ar geochronology of the West Greenland Tertiary volcanic province

Paleocene volcanic rocks in West Greenland and Baffin Island were among the first products of the Iceland mantle plume, forming part of a larger igneous province that is now submerged beneath the northern Labrador Sea. A ⁴⁰Ar/³⁹Ar dating study shows that volcanism commenced in West Greenland between 60.9 and 61.3 Ma and that 80% of the Paleocene lava pile was erupted in 1 million years or less (weighted mean age of 60.5±0.4 Ma). Minimum estimates of magma production rates (1.3×10⁻⁴ km³ year⁻¹ km⁻¹) are similar to the present Iceland rift, except for the uppermost part of the Paleocene volcanic succession where the rate decreases to <0.7×10⁻⁴ km³ year⁻¹ km⁻¹ (rift). The timing of onset of volcanism in West Greenland coincides with the opening of the northern Labrador Sea and is also strikingly similar to the age of the oldest Tertiary volcanic rocks from offshore SE Greenland and the British–Irish province. This is interpreted as manifesting the impact and rapid (>1 m/year) lateral spreading of the Iceland plume head at the base of the Greenland lithosphere at 62 Ma. We suggest that the arrival, or at least a major increase in the flux, of the Iceland mantle plume beneath Greenland was a contributing factor in the initiation of seafloor spreading in the northern Labrador Sea. Our study has also revealed a previously unrecognised Early Eocene volcanic episode in West Greenland. This magmatism may be related to movement on the transform Ungava Fault System which transferred drifting from the Labrador Sea to Baffin Bay. A regional change in plate kinematics at 55 Ma, associated with the opening of the North Atlantic, would have caused net extension along parts of this fault. This would have resulted in decompression and partial melting of the underlying asthenosphere. The source of the melts for the Eocene magmatism may have been remnants of still anomalously hot Iceland plume mantle which were left stranded beneath the West Greenland lithosphere in the Early Paleocene.     

C-isotope stratigraphy and paleoenvironmental changes across OAE2 (mid-Cretaceous) from shallow-water platform carbonates of southern Mexico

The stratigraphic and geochemical record of the mid-Cretaceous (Cenomanian–Turonian) Oceanic Anoxic Event 2 (OAE2) has been studied in numerous Tethyan and proto-Atlantic hemi-pelagic/pelagic successions, but little data comes from nearshore carbonate successions from the proto-Pacific region. Here we present the results of a combined stratigraphic and δ¹³C study of C–T platform carbonates from southern Mexico, which were deposited within the proto-Pacific. Two scales of sedimentary cyclicity are recognized. High-frequency peritidal and subtidal cycles (0.4–8 m) display little evidence of cycle-capping subaerial exposure and are not correlative between sections; these relationships suggest that the amplitudes of high-frequency sea-level changes were minimal during the peak mid-Cretaceous greenhouse. Longer-term transgressive-regressive sequences (18–40⁺ m) are correlated between sections, and using δ¹³C trends, can be correlated with sequences developed in northern Europe and India.The Mexican successions were sampled at a high resolution (~ 10 ky) for stable isotopes (inorganic, organic carbon and oxygen), total organic carbon, insoluble residues, and trace metals. The δ¹³C_carb curve matches global trends (including 6 distinct isotopic stages) permitting identification of OAE2 despite the lack of characteristic anoxic facies. Using the δ¹³C_carb trends, we tie the previously identified ammonite, planktonic foram, and nannofossil biostratigraphy from England and the Western Interior seaway of Colorado into the Mexican sections. The initiation of OAE2, defined by an abrupt positive 3–4‰ δ¹³C shift, coincides with a long-term sea-level rise, though the sedimentary expression of the deepening is no greater than that observed for any of the other sea-level events across the studied interval. OAE2 termination (transition from gradually decreasing to background δ¹³C values) is not associated with a particular sea-level trend. Stratigraphic changes in insoluble residues (proxy for continental sediment discharge) across OAE2 are not correlative between sections and do not show consistent systematic relationships with δ¹³C or sea-level variations, therefore do not support the hypothesis that OAE2 was associated with increased continental-derived nutrient influx. Two peaks in trace metal concentrations coincide with the abrupt increase in δ¹³C ratios (onset of OAE2) and during the transition from elevated-to-decreasing δ¹³C values (near the C–T stage boundary). These trends are similar to those recorded in coeval deposits of the Western Interior seaway, and are consistent with the hypothesis that OAE2 development was related to the release of reduced metals during the short-lived (< 1 My) Caribbean oceanic plateau basalt eruption. In this scenario, oxidation of the metals depleted the existing low dissolved-O₂ concentrations and thermally-buoyant plumes of seawater enriched in biolimiting elements mixed with surface waters, stimulated primary productivity, and further reduced O₂ concentrations leading to widespread anoxia and a large positive δ¹³C shift.     

Geologic age of the lower Josoji Formation,Shimane Peninsula,Southwest Honshu,Japan: Implications for an abrupt change to deep-water during the earlier opening stage of the Japan Sea

The lower part of the Josoji Formation, Shimane Peninsula, contains clues for figuring out changes in deep-water characteristics during the opening of the Japan Sea. The foraminiferal assemblage includes early to middle Miocene biostratigraphic index taxa such as planktonic foraminiferal Globorotalia zealandica and Globorotaloides suteri. The occurrence of these two species, together with the absence of praeorbulinids, suggests that the lower part of the Josoji Formation is assigned to the top of planktonic foraminiferal Zone N7/M4 (16.39 Ma). The benthic foraminiferal assemblage, which is characterized by Cyclammina cancellata and Martinottiella communis, clearly suggests that the lower Josoji Formation was deposited at bathyal depths, and that it developed in association with the abrupt appearance of deep-sea calcareous forms. Such bathyal taxa are the main constituents of the Spirosigmoilinella compressa–Globobulimina auriculata Zone of the Josoji Formation and also of the Gyrodina–Gyroidinoides Zone at Ocean Drilling Program Site 797 in the Japan Sea. The base of these benthic foraminiferal zones can be correlated with the base of the nannofossil Sphenolithus heteromorphus Base Zone (= CNM6/CN3); thus, its estimated age is 17.65 Ma. This biostratigraphic information suggests that the lower Josoji Formation was deposited from shortly before 17.65–16.39 Ma in upper limit age. Evidence that fresh to brackish and shallow-water basins formed in the rifting interval of 20–18 Ma in the Japan Sea borderland suggests that the abrupt appearance of deep-sea calcareous foraminifera occurred about 1 my earlier in this area than in other sedimentary basins and suggests that a significant paleoceanographic change occurred in the proto-Japan Sea at 17.65 Ma.