Energetics during eddy shedding in the Gulf of Mexico

Ocean Dynamics - Using the Estimating Circulation and Climate of the Ocean (ECCO) Phase II product, this study investigates the energetic characteristics during eddy shedding in the Gulf of Mexico....     

Natural gas seepage in the Gulf of Mexico

Hydrocarbon compositions and δ¹³C values for methane of fourteen natural seep gases and four underwater vents in the northwestern Gulf of Mexico are reported. The C₁/(C₂ + C₃) ratios of the seep gas samples ranged from 68 to greater than 1000, whereas δ_PDB¹³C values varied from ?39.9 to ?65.5‰. Compositions suggest that eleven of the natural gas seeps are produced by microbial degradation whereas the remaining three have a significant thermocatalytically produced component. Contradictions in the inferences drawn from molecular and isotopic compositions make strict interpretation of the origins of a few of the samples impossible.     

Coastal circulation and hydrography in the Gulf of Tehuantepec,Mexico, during winter

Winter observations of shelf and slope hydrography and currents in the inner Gulf of Tehuantepec are analysed from two field studies in 1989 and 1996 to specify the variability of near-shore conditions under varying wind stress. During the winter period frequent outbursts of ‘Norte’ winds over the central Gulf result in persistent alongshore inflows along both its eastern and western coasts. Wind-induced variability on time scales of several days strongly influences the shelf currents, but has greater effect on its western coast because of the generation and separation of anticyclonic eddies there. The steadier inflow (∼0.2 m s⁻¹) on the eastern shelf is evident in a strong down-bowing of shallow isosurfaces towards the coast within 100 km of shore, below a wedge of warmer, fresher and lighter water. This persistent entry of less saline (33.4–34.0), warmer water from the southeast clearly originates in buoyancy input by rivers along the Central American coast, but is augmented by a general shoreward tendency (0.2 m s⁻¹) in the southeastern Gulf. The resultant shallow tongue of anomalous water is generally swept offshore in the head of the Gulf and mixed away by the strong outflow and vertical overturning of the frequent ‘Norte’ events but during wind relaxations the warm, low-salinity coastal flow may briefly extend further west. In the head of the Gulf, flow is predominantly offshore (<0.2 m s⁻¹) as the alongshore component alternates eastward and westward in association with elevation or depression, respectively, of the pycnocline against the shore. More saline, open ocean water is introduced from the north-western side of the Gulf by the inflow along the west coast. During extended wind relaxations, the flow becomes predominantly eastward beyond the shelf while nearshore the coastally trapped buoyant inflow from the southeast penetrates across the entire head of the gulf at least as far as its western limit. On the basis of these and other recent observations, it seems that the accepted view of a broad, persistent Costa Rica Coastal Current (CRCC) is the result of averaging over many relatively sparse observations and that the instantaneous CRCC is a highly variable and convoluted flow around and between constantly changing eddies. The buoyancy-driven shelf current reported here forms a hitherto unrecognized, but major, component of this CRCC system.     

Brevetoxin abundance and composition during ECOHAB-Florida field monitoring cruises in the Gulf of Mexico

This project was undertaken to provide information about the composition and fate of brevetoxins in concert with the multidisciplinary study, ECOHAB-FL, of Karenia brevis blooms in the Gulf of Mexico. Brevetoxin composition was provided for water samples collected during and in the absence of K. brevis blooms from November 1998, through September 2002. The identity and concentration of the most abundant brevetoxins were determined using high performance liquid chromatography with ultraviolet diode array detection (HPLC-DAD). The analytical methods changed in 2002 to the use of a mass spectrometer for brevetoxin identification and quantitation. The most abundant brevetoxins observed during blooms were PbTx-1, -2 and -3. PbTx-2 was the most abundant toxin observed in viable bloom situations with an abundance of K. brevis cells. Starting with the 2000 cruises, a distinction was made between intra-cellular toxins (inside viable K. brevis cells) and extra-cellular brevetoxins (dissolved brevetoxins outside of the cell). An important observation was the change in composition of the major brevetoxins from intra-cellular to extra-cellular toxins. The most abundant intra-cellular toxin was PbTx-2, whereas the most abundant brevetoxin recovered from the extra-cellular (dissolved) fraction in the water was PbTx-3. The abundance of PbTx-3 relative to PbTx-2 generally increased as a bloom aged, indicating the conversion of PbTx-2 to -3 as cells lysed, and the persistence of PbTx-3 in the water after cell death.     

Authigenic carbonates in sediments from the Gulf of Mexico

The carbon isotopic composition of diagenetic dolomite and calcite in some sediments of the Gulf of Mexico varies between “normal-marine” (δ¹³C ca. 0‰) and −14.6‰ which suggests that biogenic CO₂ contributed to the carbonate formation. The δ¹³O values of dolomite and coexisting calcite are very similar but variable down-core.Dolomite and calcite precipitated early from pore water where SO₄²⁻ was not reduced. However, during (and after?) SO₄²⁻ reduction dolomite and calcite still formed and there are at least two generations of carbonate minerals present.     

Sea level variability in the Gulf of Mexico since 1900 and its link to the Yucatan Channel and the Florida Strait flows

The long-term variability of sea level and surface flows in the Gulf of Mexico (GOM) is studied using global monthly sea level reconstruction (RecSL) for 1900–2015. The study explored the long-term relation between the dynamics of the GOM and inflows/outflows through the Yucatan Channel (YC) and the Florida Straits (FS). The results show a century-long trend of increased mean velocity and variability in the Loop Current (LC); however, no significant upward trend was found in the YC and FS flows, only increased variability. Empirical orthogonal function (EOF) analysis of sea surface height found spatial patterns dominated by variations in the LC and temporal variations on time scales ranging from a few months to multidecadal. The time evolution of each EOF mode of sea level is correlated with the velocity of either the LC, the YC, or the FS or some combination of the different flows. The mean sea level difference between the GOM and the northwestern Caribbean Sea was found to be influenced by the North Atlantic Oscillation (NAO), with unusually high differences during the 1970s when the NAO index was low and the Atlantic Ocean circulation was weak. Extreme peaks in SL difference coincide with the extension of the LC and the seasonal eddy shedding pattern. The observed seasonal cycle in the extension area of the LC as obtained from 20 years of altimeter data is significantly correlated (R = 0.63; confidence level = 98%) with the seasonal YC flow obtained from 116 years of the RecSL data. However, the same LC extension record had lower correlation (R = 0.45; confidence level = 90%) with the observed YC transport obtained from direct moored measurements over ~ 5 years, indicating the need for much longer measurements, since the LC extension and the YC flow are strongly affected by interannual and decadal variations. The study demonstrates the usefulness of even a coarse-resolution reconstruction for studies of regional ocean variability and climate change over longer time scales than current direct observations allow.

     

Tide‐modulated hyperpycnal flows off the Huanghe (Yellow River) mouth,China

Few hyperpycnal flows have ever been observed in marine environments although they are believed to play a critical role in sediment dispersal within estuarine and deltaic depositional systems. The paper describes hyperpycnal flows observed in situ off the Huanghe (Yellow River) mouth, their relationship to tidal cycles, and the mechanisms that drive them. Simultaneous observations at six mooring stations during a cruise off the Huanghe mouth in the flood season of 1995 suggest that hyperpycnal flows observed at the river mouth are initiated by high concentrations of sediment input from river and modulated by tides. Hyperpycnal flows started near the end of ebb tides, when near‐bottom suspended sediment concentration (SSC) increased rapidly and salinity decreased drastically (an inverse salt wedge). The median grain size of suspended particles within the hyperpycnal layer increased, causing strong stratification of the suspended sediments in the water column. Towards the end of flood tides, the hyperpycnal flow attenuated due to frictions at the upper and lower boundaries of the flow and tidal mixing, which collapsed the stratification of the water column. Both sediment concentration and median grain size of suspended particles within the bottom layer significantly decreased. The coarser sediment particles were deposited and the hyperpycnal flows stopped. The intra‐tidal behaviors of hyperpycnal flows are closely associated with the variations of SSC, salinity, and stratification of the water column. As nearly 90% of riverine sediment is delivered to the sea during the flood seasons when hyperpycnal flows are active, hyperpycnal flows at the Huanghe mouth and the river's high sediment loads have caused rapid accretion of the Huanghe delta. Copyright © 2010 John Wiley & Sons, Ltd.     

Marine geophysics along the Gulf of Mexico and the Yucatan peninsula coastal area in Mexico

Marine geophysical studies were carried out along the coastal zone of Mexico in the Atlantic Ocean as part of CICAR and IDOE projects. An area of 200,000 km² was covered by two reconnaissance cruises and a more limited area by tracks for more detailed research. The 15,000 km of track lines include a collection of continuous seismic profiling, bathymetry, gravity and magnetic data.The analyses and correlation of results indicate some local structure features and their relationship to the Neo-volcanic zone and the salt dome belt in the Gulf of Mexico. On the Yucatan area the results show the interaction of continental and oceanic crust at the NW border of the Caribbean Plate.     

The late Wisconsin flood into the Gulf of Mexico

¹⁸O/¹⁶O and¹⁴C analysis of deep-sea cores from the Gulf of Mexico revealed a 2.4% isotopic anomaly between 12,000 and 11,000 years ago. This value, together with estimates of the oxygen isotopic composition of ice meltwater and rates of mixing within the Gulf of Mexico indicates that the average yearly discharge of the Mississippi River was between 100,000 and 230,000 m³/s (as compared to 57,000 m³/s for the peak flood of February 17, 1937), with probable yearly peak floods twice as large. Corresponding sea-level rise was between 1 and 2 m per century.     

Linking hypoxia to shrimp catch in the northern Gulf of Mexico

Wide spread and reoccurring hypoxia has been observed in the northern Gulf of Mexico since routine monitoring began in the 1980s. Although the potential ecological effects of hypoxia (habitat loss, mortalities) are well known, there is relatively little information linking hypoxia in the northern Gulf of Mexico to fisheries decline. Previous analyses have shown a negative relationship between hypoxic area and brown shrimp (Farfantepenaeus aztecus) catch for the Texas and Louisiana coasts combined from 1985 to 1997. Extending these analyses with data through 2004, we found that the correlation between hypoxic area and landings holds (r=-0.52), plus there was a significant negative relationship (r=-0.59) between hypoxia and shrimp landings for the Texas coast alone. We hypothesize that this pattern is not seen in the Louisiana fishery alone because of differences in fisheries practices (inshore vs. offshore) between Louisiana and Texas.     

Zooplankton and Karenia brevis in the Gulf of Mexico

Blooms of the toxic dinoflagellate Karenia brevis are common in the Gulf of Mexico, yet no in situ studies of zooplankton and K. brevis have been conducted there. Zooplankton abundance and taxonomic composition at non-bloom and K. brevis bloom stations within the Ecology of Harmful Algal Blooms (ECOHAB) study area were compared. At non-bloom stations, the most abundant species of zooplankton were Parvocalanus crassirostris, Oithona colcarva, and Paracalanus quasimodo at the 5-m isobath and P. quasimodo, O. colcarva, and Oikopleura dioica at the 25-m isobath. There was considerable overlap in dominance of zooplankton species between the 5 and 25-m isobaths, with nine species contributing to 90% of abundance at both isobaths. At stations within K. brevis blooms however, Acartia tonsa, Centropages velificatus, Temora turbinata, Evadne tergestina, O. colcarva, O. dioica, and P. crassirostris were dominant. Variations in abundance between non-bloom and bloom assemblages were evident, including the reduction in abundance of three key species within K. brevis blooms.     

Predicting summer hypoxia in the northern Gulf of Mexico: redux

We report on the evolution and accuracy of a model used to predict the mid-summer area of hypoxia (oxygen ≤2 mg l(-1)) in the northern Gulf of Mexico, use it to test for impacts from the Deepwater Horizon oil spill (2010), and estimate the N loading that would meet a management goal. The prediction since 2000 were 100%±6% (μ±1 SE) of the actual value. The predicted in 2010 was 99% of that actual value, suggesting that the net effect of the 2010 oil spill on the hypoxic zone size was negligible. A tropical storm, however, may have reduced the potential size of the hypoxic zone. Lowering the May nitrogen load to about 70,000 mton N nitrate+nitrite would bring the model's predicted hypoxic zone size down to the management goal of 5000 km(2) and restore hypoxic waters to normoxic conditions.     

Multiple equilibrium states of the Gulf of Mexico Loop Current

It has been established that idealized western boundary currents, which encounter a gap in their supporting boundary, will assume one of two dominant steady states: a loop current state and a gap leaping state, and that transitions between these states display hysteresis. However, a question of whether the idealized geometries considered to date apply to the Gulf of Mexico Loop Current (LC) remained. Here, the nonlinear potential vorticity advection-diffusions equations are solved, for Gulf of Mexico topography, using Newton’s method. We demonstrate that, in application to the LC in the Gulf of Mexico, the original conclusions do hold and additionally describe peculiarities of the more realistic steady states. The existence of our numerically calculated steady LC states in the actual Gulf of Mexico are supported through analysis of historical sea surface height data, and implications of our results for LC modeling and forecasting are discussed.