关于日本主张以“中间线”划分东海的几点思考

日本新任首相安倍晋三于2006年10月8日访华。他就任后第一次出访就到中国,说明很重视与中国和亚洲的外交关系,旨在改变小泉时代留下的政治后遗症——中日关系冷淡,日本亚洲外交危机。安倍访华期间中日发表联合公报,其内容包括坚持东海磋商,加快共同开发步伐,寻求双方都能接受的方案等。安倍访华标志着中日紧张关系开始缓和,但并不等于中日东海问题就此迎刃而解。中日东海问题是长期形成的,错综复杂的,不可能通过一两次首脑访问就能解决根本问题,充其量只能起到遏制势头恶化的作用。以笔者之见,在东海问题上日方仍然掌握着主动权,海上保安厅出动武装舰船和飞机始终控制着我国固有领土——钓鱼岛及其周边海域。至今没有任何迹象表明日本政府要收回授权民间企业在东海试开采的成命,强行试钻的可能性依然存在。中日双方虽然就东海共同开发达成继续进行磋商的一致意见,但从发展趋势分析最终仍有利日方。     

Piezoelectric Energy Analysis on Diverse Buoy Coupling with Hydrodynamic Parameters

This paper mainly describes the influence factors of the captured energy power by huge wave energy harvesters, in which the vertical motion of buoy can transform ocean’s potential energy into piezoelectric energy power by undulating waves. Firstly, related environmental coefficients are analyzed by means of the incident wave theory. Besides, the geometric structural parameters are also analyzed and compared under optimal environmental coefficients with semi-analytical solutions. Thirdly, the numerical results also show the impact trend of hydrodynamic parameters and geometric volume on motion, voltage and power with qualitative agreement. The numerical simulation confirms that the improved structure parameters could markedly deliver sufficient power under the same conditions with long-time stability.     

一株印度洋深海食烷茵(Alcanivorax sp.P40)的烷烃羟化酶基因的克隆

以印度洋深层海水,用柴油和石油作为混合碳源经富集培养、分离获得一株具有很强的柴油降解能力的茵株P40.茵株P40革兰氏染色阴性,接触酶和氧化酶为阳性,能还原硝酸盐,不能还原亚硝酸盐.16S rDNA Blastn 结果表明其与 Alcanivorax dieselolei B-5T(柴油食烷茵)及 A.dieselolei NO1A具有最高相似性,均为99.8%.茵株P40的gyrB序列与 A.dieselolei NO1A同源性也高达99.2%.而与A.dieselolei B-5T只有86.9%.此外,从茵株P40中克隆到两个烷烃羟化酶alkB基因片断,分别命名为P40-alkB1和P40-alkB2.其中P40-alkBl与报道的 A.dieselolei B-5T 中的 alkB 同源性较高,达96.3%,而与同为深海来源的茵株NO1A的alkB的同源性更是达100%,P40-alkB2则与A.borkumensis SK2T(泊库岛食烷茵)的alkB1同源性最高,但仅为65%.     

China Ocean Engineering Contents of Volume 28, 2014

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世界海洋日暨全国海洋宣传日 主场活动在大连隆重举行

6月8日,2011年世界海洋日暨全国海洋宣传日主场活动在辽宁省大连市隆重开幕,今年活动的主题是辛亥百年,海洋振兴。全国人大常委会副委员长周铁农出席庆祝大会并宣布2011世界海洋日暨全国海洋宣传日活动开幕。国家     

保障渔民合法权益是深化海洋管理工作面临的重要课题

舟山是我国唯一以群岛设立的地级市,区域总面积2.22万km2,其中海域面积2万hm2余,“港、景、渔”等海洋资源十分丰富,是名副其实的海洋大市。     

GPU-Based DEM Simulations of Global Ice Resistance on Ship Hull During Navigation in Level Ice

The ice resistance on a ship hull affects the safety of the hull structure and the ship maneuvering performance in icecovered regions.In this paper,the discrete element method(DEM)is adopted to simulate the interaction between level ice and ship hull.The level ice is modeled with 3D bonded spherical elements considering the buoyancy and drag force of the water.The parallel bonding approach and the de-bonding criterion are adopted to model the freezing and breakage of level ice.The ship hull is constructed with rigid triangle elements.To improve computational efficiency,the GPU-based parallel computational algorithm was developed for the DEM simulations.During the interaction between the ship hull and level ice,the ice cover is broken into small blocks when the interparticle stress approaches the bonding strength.The global ice resistance on the hull is calculated through the contacts between ice elements and hull elements during the navigation process.The influences of the ice thickness and navigation speed on the dynamic ice force are analyzed considering the breakage mechanism of ice cover.The Lindqvist and Riska formulas for the determination of ice resistance on ship hull are employed to validate the DEM simulation.The comparison of results of DEM,Lindqvist,and Riska formula show that the DEM result is between those the Lindqvist formula and Riska formula.Therefore the proposed DEM is an effective approach to determine the ice resistance on the ship hull.This work can be aided in the hull structure design and the navigation operation in ice-covered fields.     

Experimental Studies on Sloshing Mitigation Using Dual Perforated Floating Plates in A Rectangular Tank

The performance of dual perforated floating plates in a rectangular tank is investigated based on the model tests under different external excitations for different filling rates.It is found that dual perforated floating plates in the tank can remarkably mitigate violent resonant sloshing responses compared with the clean tank,especially when the external excitation frequency is in the vicinity of the first-order resonant frequency.Next,the parametric studies based on different filling rates and external excitation amplitudes are performed for the first-order resonant frequencies.The presence of dual perforated floating plates seldom shifts the sloshing natural frequencies.Further,dual perforated floating plates change the sloshing modes from the standing-wave mode in the clean tank to the Utube mode,which can arise from the sloshing reduction to some extent.     

国务院副总理曾培炎在“国际极地年中国行动”启动仪式上的致词

很高兴前来参加“国际极地年中国行动”启动仪式。国际极地年是全球范围的科学家共同策划、联合开展的大规模极地科学考察     

Study on copper complexing ligand concentrations in several China''s coastal waters

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows： Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer （SSL） in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complex- ing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China＇s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.     

中国近岸部分海域海水中金属络合配位体浓度的研究

采用阳极溶出伏安法对黄河口、青岛近海、大亚湾和南海海域海水中的金属络合配位体的浓度进行了测定,同时探讨了其分布规律与相关参量的关系.结果发现:南海海域海水中的金属络合配体的浓度稍高于其他3个海域,且都明显高于大洋水的浓度;在微表层存在富集现象;在垂直分布上表层最大,然后随深度增加而降低,在底层有较大值;各海域配位体的性质呈复杂性;铜的络合配位体浓度大于镉和铅;总的来说与世界其他海域的分布规律是一致的.同时发现铜络合配位体浓度与BOD(生化需氧量)、COD(化学需氧量)、DOC(溶解有机碳)及黏度存在显著的正相关性.     

大亚湾水体中溶解的碳水化合物

根据1985年10月至1986年8月对大亚湾进行的环境调查,本文报道海水中溶解的碳水化合物(DCHO)的调查结果,讨论了该海区DCHO的分布特征及季节性变化。对DCHO和叶绿素a、磷酸盐、溶解氧、颗粒有机碳、温度以及盐度之间进行了相关分析,综合探讨了影响D-CHO含量变化的因素。结果表明,浮游植物在大亚湾水体中DCHO的浓度调节方面起着主要的作用。     

中国黄、渤海海水中溶解镉的形态研究

黄、渤海是我国重要的海洋经济渔业开发区域,海水中痕量金属的含量及其存在形态会对海洋环境、海洋渔业产生重要影响。随着近年我国痕量金属采集与分析测试技术的发展,数据的准确性有了新的提升。2016-06—07采集黄、渤海40个站位的海水样品,测定其溶解态金属Cd的总浓度,并应用电化学方法(阳极溶出伏安法)分析Cd存在形态。结果表明,渤海海水中的总溶解态Cd浓度是南黄海海水中的2~3倍,这可能与渤海海水停留时间较长,水深较浅,周边较多河流输入有关。20%~92%以上的溶解态Cd是以有机络合物形态存在,以自由离子态存在的Cd浓度不超过100 pmol/L,低于Cd对浮游生物的毒性阈值。渤海比黄海的金属配体浓度高出2倍以上,高值出现在黄河口周围海域,表明黄河水携带较多有机配体输入。推测我国近海有机配体来源可能包括陆源输入、沉积物再悬浮的解析过程以及藻类分泌。研究还表明,黄、渤海海水中溶解态Cd的有机配体络合常数较其他海域的稍高,这与我国近海废、污水排放的有机络合配体类型有关。     

浙江西沪港重金属铜的配位容量和形态分析

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.     

Organic complexation and its control of the dissolved concentrations of copper and zinc in the Scheldt estuary

Cathodic stripping voltammetry (CSV) is used to determine total (after UV-irradiation) and labile dissolved metal concentrations as well as complexing ligand concentrations in samples from the river Scheldt estuary. It was found that even at high added concentrations of catechol (1 m for copper and 0·4 m for iron) and of APDC (1 m for zinc) only part of the dissolved metal was labile (5–58% for copper, 34–69% for zinc, 10–38% for iron); this discrepancy could be explained by the low solubility of iron which is largely present as colloidal material, and by competition for dissolved copper and zinc by organic complexing ligands. Ligand concentrations varied between 28 and 206 n for copper and between 22 and 220 n for zinc; part of the copper complexing ligands could be sub-divided into strong complexing sites with concentrations between 23 and 121 n and weaker sites with concentrations between 44 and 131 n . Values for conditional stability constants varied between (logK′ values) 13·0 and 14·8 for strong and between 11·5 and 12·1 for weaker copper complexing ligands, whereas for zinc the values were between 8·6 and 10·6. The average products of ligand concentrations and conditional stability constants (a-coefficients) were 6 × 10² for zinc and 6 × 10⁶ for copper.The dissolved zinc concentration was found to co-vary with the zinc complexing ligand concentration throughout the estuary. It is argued that the zinc concentration is regulated, in this estuary at least, by interactions with dissolved organic complexing ligands. A similar relationship was apparent between the dissolved copper and the strong copper complexing ligand concentration. The total copper complexing ligand concentrations were much greater than the dissolved copper concentrations, suggesting that only strongly complexed copper is kept in solution.These results provide evidence for the first time that interactions of copper and zinc with dissolved organic complexing ligands determine the geochemical pathway of these metals.     

C18 Sep-Pak Extractable Dissolved Organic Copper Related to Hydrochemistry in the North-west Mediterranean

Extractable organic copper using C18 Sep-Pak cartridges was investigated in seawater after laboratory experiment showed that the (C18 Sep-Pak) cartridges were reliable, in open and coastal waters with normal levels of dissolved organic carbon, for the separation of a specific fraction of organo-copper complexes.Given that the Sep-Pak cartridges retain the hydrophobic fraction of the dissolved organic matter, this extraction technique was applied for studying the characteristics of this particular hydrophobic dissolved organic copper fraction (hDOCu) in the north-western Mediterranean waters. Surface distribution of hDOC is influenced by organic matter input from the river Rhone and its estuary as well as the physical processes affecting the primary productivity such as coastal upwelling. By correlating hDOCu concentrations with total dissolved copper and other hydrochemical data such as salinity and dissolved organic carbon, it was possible to examine the behaviour of hDOCu in the water masses of different sources and ages.Marine organic matter has been shown to have high complexing capacity. Productive superficial and intermediate waters as well as deep waters showed relatively high and comparable complexing capacity indicating that old organic matter may have strong complexing sites.     

乳山湾外低氧海域沉积物中有机碳、氮、磷及其形态特征分析

根据2009年8月在乳山湾及其毗邻海域的综合调查,分析了该海域表层沉积物中有机碳、氮、磷含量及其组成形态的变化,初步探讨了影响底质理化参数变化的原因及对乳山湾外近岸底层低氧形成的影响.结果表明,乳山湾外近海为粉砂质岸滩,以细颗粒为主;底质中有机碳含量介于0.49％ ～0.93％,平均值为0.69％;总氮含量介于382～1020 mg/kg,平均值为671 mg/kg;可溶性总氮含量介于23.0 ～ 60.0 mg/kg,平均值为44.0mg/kg,其中可溶性有机氮和氨氮分别占可溶性总氮的58.8％和38.8％;总磷含量介于138～769 mg/kg,平均值为356 mg/kg,有机磷是占有绝对优势的磷形态(62.5％).研究区域沉积物中总氮和湾内相当,有机碳、总磷含量普遍低于乳山湾内,但均明显高于南黄海区域,且呈还原性状态.调查区域内沉积物中相对较高的有机碳、氮、磷可能是在潮流作用下乳山湾与外海的物质交换所致,其耗氧过程是导致底层溶解氧亏损的重要原因,值得进一步关注.     

黄、东海春季海水胞外酶活性水平分布特征研究

海水胞外酶活性可以指示有机物的分布特征以及微生物的营养状况。我们测定了2017年3月25日至4月15日黄海和东海44个大面站以及2018年4月28日至29日胶州湾湾口附近海域10个站位表层海水中的8种胞外酶活性并研究了其分布特征。2017年春季黄、东海表层海水中碱性磷酸酶和脂肪酶活性较高,高值区出现在苏北沿岸和南黄海中部,碱性磷酸酶与磷酸盐浓度之间呈正相关。其余6种酶(肽酶、几丁质酶、纤维素酶、α-D-葡萄糖苷酶、β-D-半乳糖苷酶、木糖苷酶)活性高值区出现在长江口以东的外海,东海的β-D-半乳糖苷酶、木糖苷酶平均酶活性显著高于黄海。8种酶活性平均值排列顺序由大到小为:碱性磷酸酶、脂肪酶、肽酶、几丁质酶、α-D-葡萄糖苷酶、β-D-半乳糖苷酶、纤维素酶、木糖苷酶,其中α-D-葡萄糖苷酶和β-D-半乳糖苷酶的活性基本一致。2018年春季胶州湾附近海域海水中碱性磷酸酶、脂肪酶、木糖苷酶活性分布为近岸高于远岸,几丁质酶活性为近岸低于远岸。8种酶活性平均值排列顺序由大到小为:碱性磷酸酶、脂肪酶、肽酶、木糖苷酶、α-D-葡萄糖苷酶、β-D-半乳糖苷酶、几丁质酶、纤维素酶,其中几丁质酶和纤维素酶的活性基本一致。黄海的碱性磷酸酶和脂肪酶平均酶活性均显著高于东海和胶州湾附近海域。糖类水解酶(几丁质酶、纤维素酶、α-D-葡萄糖苷酶、β-D-半乳糖苷酶、木糖苷酶)平均酶活性在黄海最低。本文的结果对于理解中国近海海水有机碳的分布、浮游植物及异养细菌对有机碳的降解具有重要意义。     

Copper, lead and cadmium in coastal waters of the western North Sea

Cadmium, lead and copper have been determined in both dissolved and particulate phases for 130 surface-water samples from the coastal zone of Scotland and England in the western North Sea. The concentrations reported are, in general, lower than those published previously for the same area.The distribution of total metal concentration between the dissolved and particulate phases varies for the three elements. The lead distribution is dominated by its associations with particulate material while cadmium shows the reverse behaviour, existing almost totally in the dissolved phase. Copper is intermediate in behaviour, with the dissolved phase generally being dominant.An inverse relationship between salinity and dissolved copper concentration suggests a freshwater origin for this element. It is suggested that sedimentary and/or anthropogenic sources affect dissolved copper concentrations in coastal waters. The dissolved lead distribution reveals plumes of contaminated coastal water. The lead distribution is, however, dominated by associations with particulate material and sediments which produce a sharp concentration gradient close to the coast. The Humber estuary is identified as a significant source of cadmium to the North Sea.