Crustal recycling through intraplate magmatism: Evidence from the Trans-North China Orogen

The North China Craton (NCC) preserves the history of crustal growth and craton formation during the early Precambrian followed by extensive lithospheric thinning and craton destruction in the Mesozoic. Here we present evidence for magma mixing and mingling associated with the Mesozoic tectonic processes from the Central NCC, along the Trans-North China Orogen, a paleo suture along which the Eastern and Western Blocks were amalgamated at end of Paleoproterozoic. Our investigations focus on two granitoids – the Chiwawu and the Mapeng plutons. Typical signatures for the interaction of mafic and felsic magmas are observed in these plutons such as: (1) the presence of diorite enclaves; (2) flow structures; (3) schlierens; (4) varying degrees of hybridization; and (5) macro-, and micro-textures. Porphyritic feldspar crystals show numerous mineral inclusions as well as rapakivi and anti-rapakivi textures. We present bulk chemistry, zircon U–Pb geochronology and REE data, and Lu–Hf isotopes on the granitoids, diorite enclaves, and surrounding basement rocks to constrain the timing of intraplate magmatism and processes of interaction between felsic and mafic magmas. Our LA-ICP-MS zircon U–Pb data show that the pophyritic granodiorite was emplaced at 129.7 ± 1.0 Ma. The diorite enclaves within this granodiorite show identical ages (128.2 ± 1.5 Ma). The basement TTG (tonalite–trondhjemite–granodiorite) gneisses formed at ca. 2.5 Ga coinciding with the major period of crustal accretion in the NCC. The 1.85 Ga age from zircons in the gabbro with positive Hf isotope signature may be related to mantle magmatism during post-collisional extension following the assembly of the Western and Eastern Blocks of the NCC along the Trans-North China Orogen. Our Hf isotope data indicate that the Neoarchean–Paleoproterozoic basement rocks were derived from complex sources of both juvenile magmas and reworked ancient crust, whereas the magma source for the Mesozoic units are dominantly reworked basement rocks. Our study provides a window to intraplate magmatism triggered by mantle upwelling beneath a paleosuture in the North China Craton.     

Constraints on the paleogeographic evolution of the North China Craton during the Late Triassic–Jurassic

This paper reports U–Pb–Hf isotopes of detrital zircons from Late Triassic–Jurassic sediments in the Ordos, Ningwu, and Jiyuan basins in the western-central North China Craton (NCC), with the aim of constraining the paleogeographic evolution of the NCC during the Late Triassic–Jurassic. The early Late Triassic samples have three groups of detrital zircons (238–363 Ma, 1.5–2.1 Ga, and 2.2–2.6 Ga), while the latest Late Triassic and Jurassic samples contain four groups of detrital zircons (154–397 Ma, 414–511 Ma, 1.6–2.0 Ga, and 2.2–2.6 Ga). The Precambrian zircons in the Late Triassic–Jurassic samples were sourced from the basement rocks and pre-Late Triassic sediments in the NCC. But the initial source for the 238–363 Ma zircons in the early Late Triassic samples is the Yinshan–Yanshan Orogenic Belt (YYOB), consistent with their negative zircon ε_Hf(t) values (−24 to −2). For the latest Late Triassic and Jurassic samples, the initial source for the 414–511 Ma zircons with ε_Hf(t) values of −18 to +9 is the Northern Qinling Orogen (NQO), and that for the 154–397 Ma zircons with ε_Hf(t) values of −25 to +12 is the YYOB and the southeastern Central Asian Orogenic Belt (CAOB). In combination with previous data of late Paleozoic–Early Triassic sediments in the western-central NCC and Permian–Jurassic sediments in the eastern NCC, this study reveals two shifts in detrital source from the late Paleozoic to Jurassic. In the Late Permian–Early Triassic, the western-central NCC received detritus from the YYOB, southeastern CAOB and NQO. However, in the early Late Triassic, detritus from the CAOB and NQO were sparse in basins located in the western-central NCC, especially in the Yan’an area of the Ordos Basin. We interpret such a shift of detrital source as result of the uplift of the eastern NCC in the Late Triassic. In the latest Late Triassic–Jurassic, the southeastern CAOB and the NQO restarted to be source regions for basins in the western-central NCC, as well as for basins in the eastern NCC. The second shift in detrital source suggests elevation of the orogens surrounding the NCC and subsidence of the eastern NCC in the Jurassic, arguing against the presence of a paleo-plateau in the eastern NCC at that time. It would be subsidence rather than elevation of the eastern NCC in the Jurassic, due to roll-back of the subducted paleo-Pacific plate and consequent upwelling of asthenospheric mantle.     

Multiple Mesozoic porphyry-skarn Cu (Mo–W) systems in Yidun Terrane,east Tethys: Constraints from zircon U–Pb and molybdenite Re–Os geochronology

Porphyry Cu ± Mo ± Au deposits typically formed in volcanoplutonic arcs above subduction zones. However, there is increasing evidence for the occurrence of porphyry deposits related to magmas generated after the underplating arc has ceased. Post-subduction lithospheric thickening, lithospheric extension, or mantle lithosphere delamination could trigger the remelting of subduction-modified arc lithosphere and lead to the formation of post-subduction porphyry deposits. The NNW-trending Yidun Terrane, located in the eastern Tethys, experienced subduction of Garze–Litang oceanic plate (a branch of the Paleotethys) in the Late Triassic and witnessed two mineralization events respectively associated with the ca. 215 Ma arc-related intermediate–felsic porphyries and the 88–79 Ma mildly-alkaline granitic porphyries. It is, therefore, an ideal place to investigate the genetic linkage between the subduction-related porphyry deposits and post-subduction porphyry deposits. Our new in situ zircon U–Pb dating of the two granitic intrusions (biotite granite, 213.4 ± 0.9 Ma; monzogranite porphyry, 86.0 ± 0.4 Ma) in the Xiuwacu district, the molybdenite Re–Os age (84.7 ± 0.6 Ma) of the mineralization, and previously published geochronological data, together show the spatially overlapping distribution of the multiple Mesozoic porphyry systems in the Late Triassic Yidun arc system. Furthermore, the arc-like elemental signatures and the mixed Sr–Nd–Hf isotopic signatures of the Late Cretaceous ore-related porphyries (i.e., originating from a mixed components between the ∼215 Ma juvenile arc crust and the Mesoproterozoic mafic lower crust) indicate a genetic linkage between the Late Triassic and Late Cretaceous porphyry systems. This suggests that the remelting of underplated arc-related mafic rocks formed during the subduction of the Garze–Litang Ocean could be responsible for the mixing between the mantle-derived components and the Mesoproterozoic lower crustal materials, when post-subduction transtension occurred in the Late Cretaceous. The formation of the Late Cretaceous porphyry–skarn Cu–Mo–W deposits could most likely be related to the remelting of Late Triassic residual sulfide-bearing Cu-rich cumulates in the subduction-modified lower crust that triggered by the Late Cretaceous transtension.     

Lithospheric structure of the North China Craton: Integrated gravity,geoid and topography data

The lithospheric structure of ancient cratons provides important constraints on models relating to tectonic evolution and mantle dynamics. Here we present the 3D lithospheric structure of the North China Craton (NCC) from a joint inversion of gravity, geoid and topography data. The NCC records a prolonged history of Archean and Paleoproterozoic accretion of crustal blocks through subduction and collision building the cratonic architecture, which was subsequently differentially destroyed during Mesozoic through extensive magmatism. The thermal structure obtained in our study is considered to define the lithosphere-asthenosphere boundary (LAB) of the NCC, and reflects the density variations within the mantle lithosphere. Employing the Moho depths from deep seismic sounding profiles for the inversion, and based on repeated computations using different parameters, we estimate the Moho depth, LAB depth and average crustal density of the craton. The Moho depth varies from 28 to 50 km and the LAB depth varies from 105 to 205 km. The LAB and Moho show concordant thinning from West to East of the NCC. The average crustal density is 2870 kg m^− 3 in the western part of the NCC, higher than that in the eastern part (2750 kg m^− 3). The results of joint inversion in our study yielded LAB depth and lithospheric thinning features similar to those estimated from thermal and seismic studies, although our results show different depth and variations in the thickness. The lithosphere gently thins from 145 to 105 km in the eastern NCC, where as the thinning is much less pronounced in the western NCC with average depth of about 175 km. The joint inversion results in this study provide another perspective on the lithospheric structure from the density properties and corresponding geophysical responses in an ancient craton.     

Inhomogeneous lithospheric thinning in the central North China Craton: Zircon U–Pb and S–He–Ar isotopic record from magmatism and metallogeny in the Taihang Mountains

The large scale Mesozoic magmatism and related metallogeny in the Taihang Mountains (TM) provide important clues for the lithospheric thinning of the North China Craton (NCC). Among the ore deposits, the vein gold mineralization of Shihu in the Fuping region and the skarn ore deposit of Xishimen in the Wu'an region represent typical Mesozoic metallogeny in the TM. In the Shihu gold mine, the Mapeng batholith is dominantly composed of monzogranite and granodiorite, whereas, the Wu'an pluton in the Xishimen iron mine mainly comprises monzonite and diorite. Here we present zircon LA–ICP-MS U–Pb data from 8 samples which reveal the timing of magmatism in the TM as ca. 130 Ma, which is contemporaneous with the large-scale metallogeny in the margins of the NCC. The δ³⁴S values recorded in the sulfide minerals from the Shihu gold deposit and the Xishimen skarn iron deposit show a range of 2.2‰–5.0‰, and 11.6‰–18.7‰, respectively. Helium isotopic compositions of fluid inclusions in pyrite from the Shihu gold deposit vary from 0.12 to 1.98 Ra (where Ra is the ³He/⁴He ratio of air = 1.39 × 10^? 6), with calculated mantle helium values of 1.4%–25%, whereas, those of the Xishimen skarn iron deposit range from 0.06 to 0.19 Ra, with calculated mantle helium of 0.7%–2.2%. The S–He–Ar isotopic data suggest a lower crustal origin for the ore-forming components, with variable inputs of mantle source. The large population of inherited zircons in our samples, with ²⁰⁷Pb/²⁰⁶Pb ages ranging between 2500 Ma and 1800 Ma, also supports crustal participation. Our data reveal that the Shihu gold deposit witnessed greater mantle input than the Xishimen skarn iron deposit, suggesting that the continental lithosphere is markedly thinner under the Fuping region than that under the Wu'an region. Our interpretation is also supported by published data from two ultra-broadband high-precision magnetotelluric sounding profiles across the TM region showing a variation in the lithosphere thickness from 155 km to 70 km while moving from the south (Wu'an region) to the north (Fuping region). Our study suggests that inhomogeneous lithospheric thinning in the central NCC occurred at least as early as ca. 130 Ma ago.     

柴北缘西段晚古生代牛鼻子梁高镁闪长岩成因机制及地球动力学过程

牛鼻子梁地区首次发现的高镁闪长岩对于探讨柴北缘地区岩石圈地幔演化历史具有重要意义.为确定该类岩石成因及地球动力学过程,对其开展矿物学、岩石主-微量元素分析、锆石U-Pb定年和Hf同位素分析工作.岩石地球化学特征显示,岩石均为钙碱性岩石,具有富Mg（Mg#=62~72）、Cr、Ni、LREE（LREE/HREE=2.84~4.61）值、低FeOT/MgO（0.70~1.12）比值特征,属于高镁闪长岩;所有样品均表现出富集大离子亲石元素（Rb、Ba、Th、U、K）和LREE,而相对亏损高场强元素Nb、Ta、Ti、P和HREE,与典型的"赞岐岩"地球化学特征一致;锆石U-Pb同位素年代学研究表明岩石形成时代为388 Ma,为中泥盆世岩浆作用的产物.锆石Hf同位素特征显示岩石ε_Hf（t）均为正值（4.4~11.6）,表明岩浆起源于亏损地幔.结合区域构造演化过程认为,牛鼻子梁高镁闪长岩是由早古生代（540~520 Ma）消减带流体交代地幔楔后的富集地幔经历晚古生代（400~388 Ma）岩石圈伸展作用部分熔融的产物.      

内蒙古金厂沟梁地区晚三叠世脉岩地球化学特征及成岩动力学背景

金厂沟梁位于张家口-赤峰-朝阳金矿集区东端, 区内发育大量规模不等的脉岩, 岩性以闪长岩、闪长玢岩为主.对其进行了锆石U-Pb年龄、主微量元素及Sr-Nd同位素分析.脉岩锆石LA-ICP-MS U-Pb年龄值可分为三组: 2 458~2 524 Ma、253±6 Ma(MSWD=3.0)及228±1 Ma(MSWD=0.26).2.5 Ga锆石反映成岩过程中有古老地壳物质参与, 253 Ma锆石可能与古亚洲洋闭合时的岩浆事件有关, 228 Ma则为脉岩的形成年龄.脉岩SiO₂(51.22%~68.48%)、MgO(1.35%~8.13%)含量变化较大, 且具有高Na₂O+K₂O、Al₂O₃及低的TiO₂、P₂O₅含量等特征.岩石LREE及LILE富集, HFSE亏损.脉岩(87Sr/86Sr)_i比值较为一致(0.704 95~0.705 92), 而ε_Nd(t)(-0.2~-9.5)及T_2DM(1.02~1.77 Ga)值变化范围较大.主微量元素及同位素研究结果表明: 部分熔融的岩石圈地幔熔体底侵到壳幔边界, 诱发古老地壳物质的部分熔融, 随后发生的幔源熔体与壳源熔体的混合是脉岩最可能的源区过程.主微量元素构造判别图解指示岩石形成于陆弧向板内演化的构造环境; 结合区域上同时代脉岩群、碱性岩带及A2型花岗岩的侵位, 认为晚三叠世华北板块北缘已完成与蒙古弧地体的碰撞并进入造山后伸展阶段.      

Late Mesozoic magmatism in the Jiaodong Peninsula,East China:Implications for crust-mantle interactions and lithospheric thinning of the eastern North China Craton

A section from the Linglong gold deposit on the northwestern Jiaodong Peninsula,East China,containing Late Mesozoic magmatic rocks from mafic and intermediate dikes and felsic intrusions,was chosen to investigate the lithospheric evolution of the eastern North China Craton(NCC).Zircon U-Pb data showed that low-Mg adakitic monzogranites and granodiorite intrusions were emplaced during the Late Jurassic(～145 Ma) and late Early Cretaceous(112-107 Ma),respectively;high-Mg adakitic diorite and mafic dikes were also emplaced during the Early Cretaceous at～139 Ma and ～118 Ma,and 125-145 Ma and 115-120 Ma,respectively.The geochemical data,including whole-rock major and trace element compositions and Sr-Nd-Pb isotopes,imply that the mafic dikes originated from the partial melting of a lithospheric mantle metasomatised through hydrous fluids from a subducted oceanic slab.Low-Mg adakitic monzogranites and granodiorite intrusions originated from the partial melting of the thickened lower crust of the NCC,while high-Mg adakitic diorite dikes originated from the mixing of mafic and felsic melts.Late Mesozoic magmatism showed that lithosphere-derived melts showed a similar source depth and that crust-derived felsic melts originated from the continuously thickened lower crust of the Jiaodong Peninsula from the Late Jurassic to Early Cretaceous.We infer that the lower crust of the eastern NCC was thickened through compression and subduction of the Palaeo-Pacific plate beneath the NCC during the Middle Jurassic.Slab rollback of the plate from ～160 Ma resulted in lithospheric thinning and accompanied Late Mesozoic magmatism.     

A review of the geodynamic setting of large-scale Late Mesozoic gold mineralization in the North China Craton: an association with lithospheric thinning

Abundant gold deposits are distributed along the margins of the North China Craton (NCC). Occurring throughout the Precambrian basement and located in or proximal to Mesozoic granitoids, these deposits show a consistent spatial–temporal association with Late Jurassic–Early Cretaceous magmatism and are characterized by quartz lode or disseminated styles of mineralization with extensive alteration of wall rock. Their ages are mainly Early Cretaceous (130–110 Ma) and constrain a very short period of metallogenesis. Sr–Nd–Pb isotopic tracers of ores, minerals and associated rocks indicate that gold and associated metals mainly were derived from multi-sources, i.e., the wall rocks (Precambrian basement and Mesozoic granites) and associated mafic rocks.Previous studies, including high surface heat flow, uplift and later basin development, slow seismic wave speeds in the upper mantle, and a change in the character of mantle xenoliths sampled by Paleozoic to Cenozoic magmas, have been used to suggest that ancient, cratonic mantle lithosphere was removed from the base of the NCC some time after the Ordovician, and replaced by younger, less refractory lithospheric mantle. The geochemistry and isotopic compositions of the mafic rocks associated with gold mineralization (130–110 Ma) indicate that they were derived from an ancient enriched lithospheric mantle source; whereas, the mafic dikes and volcanic rocks younger than 110 Ma were derived from a relatively depleted mantle source, i.e., asthenospheric mantle. According to their age and sources, relation to magmatism and geodynamic framework, the gold deposits were formed during lithospheric thinning. The removal of lithospheric mantle and the upwelling of new asthenospheric mantle induced partial melting and dehydration of the lithospheric mantle and lower crust due to an increase of temperature. The fluids derived from the lower crust were mixed with magmatic and meteoric waters, and resulted in the deposition of gold and associated metals.     

Water contents of the Cenozoic lithospheric mantle beneath the western part of the North China Craton: Peridotite xenolith constraints

Nominally anhydrous phases (clinopyroxene (cpx), orthopyroxene (opx), and olivine (ol)) of peridotite xenoliths hosted by the Cenozoic basalts from Beishan (Hebei province), and Fansi (Shanxi province), Western part of the North China Craton (WNCC) have been investigated by Fourier transform infrared spectrometry (FTIR). The H₂O contents (wt.) of cpx, opx and ol are 30–255 ppm, 14–95 ppm and ~ 0 ppm, respectively. Although potential H-loss during xenolith ascent cannot be excluded for olivine, pyroxenes (cpx and opx) largely preserve the H₂O content of their mantle source inferred from (1) the homogenous H₂O content within single pyroxene grains, and (2) equilibrium H₂O partitioning between cpx and opx. Based on mineral modes and assuming a partition coefficient of 10 for H₂O between cpx and ol, the recalculated whole-rock H₂O contents range from 6 to 42 ppm. In combination with previously reported data for other two localities (Hannuoba and Yangyuan from Hebei province), the H₂O contents of cpx, opx and whole-rock of peridotite xenoliths (43 samples) hosted by the WNCC Cenozoic basalts range from 30 to 654 ppm, 14 to 225 ppm, and 6 to 262 ppm respectively. The H₂O contents of the Cenozoic lithospheric mantle represented by peridotite xenoliths fall in a similar range for both WNCC and the eastern part of the NCC (Xia et al., 2010, Journal of Geophysical Research). Clearly, the Cenozoic lithospheric mantle of the NCC is dominated by much lower water content compared to the MORB source (50–250 ppm). The low H₂O content is not caused by oxidation of the mantle domain, and likely results from mantle reheating, possibly due to an upwelling asthenospheric flow during the late Mesozoic–early Cenozoic lithospheric thinning of the NCC. If so, the present NCC lithospheric mantle mostly represents relict ancient lithospheric mantle. Some newly accreted and cooled asthenospheric mantle may exist in localities close to deep fault.     

辽东凤城地区早白垩世花岗岩的锆石U-Pb年龄、地球化学特征及地质意义

辽东凤城地区出露的大面积花岗岩一直是华北克拉通北缘岩石圈减薄的研究热点,但花岗岩的岩石年龄、成因及构造环境等方面的研究尚不够深入.以辽东凤城地区帽盔山二长花岗岩、蛟羊峪花岗闪长岩、清凉山二长花岗岩为研究对象,采用岩石学、岩石地球化学及LA-ICP-MS锆石U-Pb测年方法,讨论了花岗岩的岩石成因及构造意义.帽盔山二长花岗岩、蛟羊峪花岗闪长岩、清凉山二长花岗岩中锆石具有典型的岩浆振荡生长环带和较高的钍铀比（Th/U>0.4）,LA-ICP-MS锆石U-Pb年龄分别为127.2±0.6 Ma、122.9±1.1 Ma、129.0±0.8 Ma,均形成于早白垩世.岩石地球化学特征显示帽盔山二长花岗岩和清凉山二长花岗岩为高钾钙碱性A型花岗岩,具有富Si、富碱,贫Al、Fe、Ca、Mg的特征,Eu负异常较为明显;蛟羊峪花岗闪长岩为准铝质到过铝质岩石,微量元素富集Nd、Tb、La,亏损Sr、P、Ti.构造环境判别结果显示,上述3个花岗岩体均形成于伸展拉张的构造环境.以上研究表明,辽东凤城地区在早白垩世时期处于非造山的伸展环境,是华北克拉通岩石圈减薄和克拉通破坏作用的缩影.      

Mesozoic magmatism and metallogenesis associated with the destruction of the North China Craton: Evidence from U–Pb geochronology and stable isotope geochemistry of the Mujicun porphyry Cu–Mo deposit

The North China Craton (NCC) provides a classic example of lithospheric destruction and refertilization. The timing and duration of magmatism and related metallogenesis associated with the destruction process are pivotal to understanding the geodynamic controls. In this study, we present zircon U–Pb and Hf data, Re–Os ages, and He, Ar, Pb and S isotope data from the Mujicun porphyry Cu–Mo deposit in the northern Taihang Mountains within the Central Orogenic Belt of the NCC. We constrain the timing of magmatism as 144.1 ± 1.2 Ma from zircon U–Pb data on the diorite porphyry that hosts Cu–Mo mineralization. Another U–Pb age of 139.7 ± 1.4 Ma was obtained from an epidote skarn that is located in the contact zone between the porphyry and its wall rocks. These data and five Re–Os molybdenite ages that range from 142.7 ± 2.0 Ma to 138.5 ± 1.9 Ma suggest that magmatism and mineralization occurred in about five million year duration from ~ 143 Ma to ~ 138 Ma. The He, Ar, Pb and, Hf data suggest that magmatism involved recycled Neoarchean lower crustal components, with input of heat and volatiles from an upwelling mantle. The Mujicun porphyry and associated mineralization provide a typical example for magmatism and metallogeny associated with lithospheric thinning in the NCC.     

Late Paleozoic provenance shift in the south-central North China Craton: Implications for tectonic evolution and crustal growth

U–Pb geochronologic and Hf isotopic results of seven sandstones collected from Late Carboniferous through Early Triassic strata of the south-central part of the North China Craton record a dramatic provenance shift near the end of the Late Carboniferous. Detrital zircons from the Late Carboniferous sandstones are dominated by the Early Paleozoic components with positive ε_Hf(t) values, implying the existence of a significant volume of juvenile crust at this age in the source regions. Moreover, there are also three minor peaks at ca. 2.5 Ga, 1.87 Ga and 1.1–0.9 Ga. Based on our new data, in conjunction with existing zircon ages and Hf isotopic data in the North China Craton (NCC), Central China Orogenic Belt (CCOB) and Central Asian Orogenic Belt (CAOB), it can be concluded that Early Paleozoic and Neoproterozoic detritus in the south-central NCC were derived from the CCOB. Zircons with ages of 1.9–1.7 Ga were derived from the NCC. However, the oldest components can't be distinguished, possibly from either the NCC or the CCOB, or both. In contrast, detrital zircons from the Permian and Triassic sandstones are characterized by three major groups of U–Pb ages (2.6–2.4 Ga, 1.9–1.7 Ga and Late Paleozoic ages). Specially, most of the Late Paleozoic zircons show negative ε_Hf(t) values, similar to the igneous zircons from intrusive rocks of the Inner Mongolia Paleo-Uplift (IMPU), indicating that the Late Paleozoic detritus were derived from the northern part of the NCC. This provenance shift could be approximately constrained at the end of the Late Carboniferous and probably hints that tectonic uplift firstly occurred between the CCOB and the NCC as a result of the collision between the South and North Qinling microcontinental terranes, and then switched to the domain between the CAOB and the NCC. Additionally, on the basis of Lu–Hf isotopic data, we reveal the pre-Triassic crustal growth history for the NCC. In comparison among the three crustal growth curves obtained from modern river sands, our samples, and the Proterozoic sedimentary rocks, we realize that old components are apparently underestimated by zircons from the younger sedimentary rocks and modern river sands. Hence, cautions should be taken when using this method to investigate growth history of continental crust.     

Geochronology and geochemistry of early Mesozoic magmatism in the northeastern North China Craton: Implications for tectonic evolution

This paper reports geochronological, geochemical, zircon U–Pb and Hf–O isotopic data of the Late Triassic and Early Jurassic intrusive rocks in the northeastern North China Craton (NCC), with the aim of reconstructing the tectonic evolution and constraining the spatial–temporal extent of multiple tectonic regimes during the early Mesozoic. Zircon U–Pb ages indicate that the early Mesozoic magmatism in the northeastern NCC can be subdivided into two stages: Late Triassic (221–219 Ma) and Early Jurassic (180–177 Ma). Late Triassic magmatism produced mainly granodiorite and monzogranite, which occur as a NE–SW-trending belt parallel to the Sulu–Jingji Belt. Geochemically, they are classified as high-K calc-alkaline and metaluminous to weakly peraluminous granitoids, and are enriched in large-ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depleted in high-field-strength elements (HFSEs; e.g., Nb, Ta, Ti, and P) and heavy rare earth elements (HREEs), indicating an affinity to adakite. Combined with their ε_Hf(t) values (−17.9 to −3.2) and two-stage model ages (2387–1459 Ma), we conclude that the Late Triassic granitoid magma in the northeastern NCC was derived from partial melting of the thickened lower crust of the NCC and was related to deep subduction and collision between the NCC and the Yangtze Craton (YC). The Early Jurassic magmatism is composed mainly of monzogranites, which are classified as metaluminous, high-K calc-alkaline, and I-type granite. Their ε_Hf(t) values and two-stage model ages are −16.7 to −4.2 and 2282–1491 Ma, respectively. Compared with the Late Triassic granitoids, the Early Jurassic granitoids have relatively high HREE contents, similar to calc-alkaline igneous rocks in an active continental margin setting. These Early Jurassic granitoids, together with the coeval calc-alkaline volcanic rocks and gabbro–diorite–granodiorite association in the northeastern (NE) Asian continental margin, comprise a NNE–SSW-trending belt parallel to the NE Asian continental margin, indicative of the onset of Paleo-Pacific Plate subduction beneath Eurasia.     

Rapid cooling of the Yanshan Belt,northern China: Constraints from 40Ar/39Ar thermochronology and implications for cratonic lithospheric thinning

The Yanshan Orogenic Belt is located in the northern part of the North China Craton (NCC), which lost ∼120 km of lithospheric mantle during Phanerozoic tectonic reactivation. Mesozoic magmatism in the Yanshan fold-and-thrust belt began at 195–185 Ma (Early Jurassic), with most of the granitic plutons being Cretaceous in age (138–113 Ma). Along with this magmatism, multi-phase deformational structures, including multiple generations of folds, thrust and reverse faults, extensional faults, and strike-slip faults are present in this belt. Previous investigations have mostly focused on geochemical and isotopic studies of these magmatic rocks, but not on the thermal history of the Mesozoic plutons. We have applied ⁴⁰Ar/³⁹Ar thermochronology to biotites and K-feldspars from several Lower Cretaceous granitic plutons to decipher the cooling and uplift history of the Yanshan region. The biotite ⁴⁰Ar/³⁹Ar ages of these plutons range from 107 to 123 Ma, indicating that they cooled through about 350 °C at that time. All the K-feldspar step-heating results modeled using multiple diffusion domain theory yield similarly rapid cooling trends, although beginning at different times. Two rapid cooling phases have been identified at ca. 120–105 and 100–90 Ma. The first phase of rapid cooling occurred synchronously with widespread extensional deformation characterized by the formation of metamorphic core complexes, A-type magmatism, large-scale normal faults, and the development of half-graben basins. This suggests rapid exhumation took place in an extensional regime and was a shallow-crustal-level response to lithospheric thinning of the NCC. The second phase of rapid cooling was probably related to the regional uplift and unroofing of the Yanshan Belt, which is consistent with the lack of Upper Cretaceous sediments in most of the Yanshan region.     

Paleoproterozoic bimodal post-collisional magmatism in the southwestern Amazonian Craton,Mato Grosso,Brazil: Geochemistry and isotopic evidence

This paper discusses geological and geochemical aspects of a Paleoproterozoic volcano-plutonic association that crops out in southwestern Amazonian Craton, Mato Grosso, Brazil. The study area was divided into undeformed and deformed domains, based on structural and geochronology studies. The undeformed domain is composed mainly of felsic explosive and effusive flows. Inter-layered mafic flows of basalts and sedimentary rocks are also present. The deformed domain is mainly composed of titanite and hornblende-bearing monzogranite to syenogranite and biotite monzogranite, while granodiorite is less common. U–Pb single zircon analyses yielded ages of 1.8–1.75 Ga in granites and felsic volcanic rocks for both domains. Basalts from the undeformed domain are phaneritic, fine-grained, and are often hydrothermally altered. They show tholeiitic affinity and are LREE enriched. Their trace element composition resembles those of within-plate associations. The ε_Nd (t = 1.75 Ga) for all these rocks are positive, ranging from 0.12 to 1.49, which reflect a juvenile source. The felsic volcanism comprises subalkaline rocks with high K contents and is divided into two groups: crystal enriched ignimbrites and effusive rhyolites. REE patterns of effusive rocks show negative-Eu anomalies and are smooth in the ignimbrites. Trace element patterns similar to those of the effusive rocks and ignimbrites are found in magmatic rocks derived from sources affected by subduction-related metasomatism. Hornblende and biotite granites occur in the deformed felsic plutonic domain. These rocks show evidence of low-temperature metamorphism and deformation, and in some places, of hydrothermal alteration. The LREE/Nb (or Ta) ratios of these rocks are consistent with those observed in granites of post-collisional settings. The ε_Nd (t = 1.75 Ga) values are slightly negative on average, with few positive values (?1.41 to +2.96). These data are interpreted as indicative of a magmatism produced during a post-collisional event from mixed sources: a metasomatised mantle and a Paleoproterozoic continental crust. An intracontinental shearing with age of 1.7–1.66 Ga created the Teles Pires–Juruena lineament which partially controlled this magmatism.     

Petrology,geochemistry and geochronology of the magmatic suite from the Jianzha Complex,central China: Petrogenesis and geodynamic implications

The intermediate–mafic–ultramafic rocks in the Jianzha Complex (JZC) at the northern margin of the West Qinling Orogenic Belt have been interpreted to be a part of an ophiolite suite. In this study, we present new geochronological, petrological, geochemical and Sr–Nd–Hf isotopic data and provide a different interpretation. The JZC is composed of dunite, wehrlite, olivine clinopyroxenite, olivine gabbro, gabbro, and pyroxene diorite. The suite shows characteristics of Alaskan-type complexes, including (1) the low CaO concentrations in olivine; (2) evidence of crystal accumulation; (3) high calcic composition of clinopyroxene; and (4) negative correlation between FeO^tot and Cr₂O₃ of spinels. Hornblende and phlogopite are ubiquitous in the wehrlites, but minor orthopyroxene is also present. Hornblende and biotite are abundant late crystallized phases in the gabbros and diorites. The two pyroxene-bearing diorite samples from JZC yield zircon U–Pb ages of 245.7 ± 1.3 Ma and 241.8 ± 1.3 Ma. The mafic and ultramafic rocks display slightly enriched LREE patterns. The wehrlites display moderate to weak negative Eu anomalies (0.74–0.94), whereas the olivine gabbros and gabbros have pronounced positive Eu anomalies. Diorites show slight LREE enrichment, with (La/Yb)_N ratios ranging from 4.42 to 7.79, and moderate to weak negative Eu anomalies (Eu/Eu¹ = 0.64–0.86). The mafic and ultramafic rocks from this suite are characterized by negative Nb–Ta–Zr anomalies as well as positive Pb anomalies. Diorites show pronounced negative Ba, Nb–Ta and Ti spikes, and typical Th–U, K and Pb peaks. Combined with petrographic observations and chemical variations, we suggest that the magmatism was dominantly controlled by fractional crystallization and crystal accumulation, with limited crustal contamination. The arc-affinity signature and weekly negative to moderately positive ε_Nd(t) values (−2.3 to 1.2) suggest that these rocks may have been generated by partial melting of the juvenile sub-continental lithospheric mantle that was metasomatized previously by slab-derived fluids. The lithologies in the JZC are related in space and time and originated from a common parental magma. Geochemical modeling suggests that their primitive parental magma had a basaltic composition. The ultramafic rocks were generated through olivine accumulation, and variable degrees of fractional crystallization with minor crustal contamination produced the diorites. The data presented here suggest that the subduction in West Qinling did not cease before the early stage of the Middle Triassic (∼242 Ma), a back-arc developed in the northern part of West Qinling during this period, and the JZC formed within the incipient back-arc.     

Petrology and geochemistry of peridotite xenoliths from the Lianshan region: Nature and evolution of lithospheric mantle beneath the lower Yangtze block

Lithospheric thinning beneath the North China Craton is widely recognized, but whether the Yangtze block has undergone the same process is a controversial issue. Based on a detailed petrographic study, a suite of xenoliths from the Lianshan Cenozoic basalts have been analyzed for the compositions of minerals and whole rocks, and their Sr–Nd isotopes to probe the nature and evolution of the subcontinental lithospheric mantle beneath the lower Yangtze block. The Lianshan xenoliths can be subdivided into two Types: the main Type 1 xenoliths (9–15% clinopyroxene and olivine-Mg# < 90) and minor Type 2 peridotites (1.8–6.2% clinopyroxene and olivine-Mg# > 90). Type 1 peridotites are characterized by low MgO, high levels of basaltic components (i.e., Al₂O₃, CaO and TiO₂), LREE-depleted patterns in clinopyroxenes and whole rocks, and relatively high ¹⁴³Nd/¹⁴⁴Nd (0.513219–0.513331) and low ⁸⁶Sr/⁸⁷Sr (0.702279–0.702789). These features suggest that Type 1 peridotites represent fragments of the newly accreted fertile lithospheric mantle that have undergone ~ 1% of fractional partial melting and later weak silicate–melt metasomatism, similar to Phanerozoic lithospheric mantle beneath the eastern North China Craton. Type 2 peridotites may be shallow relics of the older lithospheric mantle depleted in basaltic components, with LREE-enriched and HREE-depleted patterns, relatively low ¹⁴³Nd/¹⁴⁴Nd (0.512499–0.512956) and high ⁸⁶Sr/⁸⁷Sr (0.703275–0.703997), which can be produced by 9–14% partial melting and subsequent carbonatite–melt metasomatism. Neither type shows a correlation between equilibration temperatures and Mg# in olivine, indicating that the lithospheric mantle is not compositionally stratified, but both types coexist at similar depths. This coexistence suggests that the residual refractory lithospheric mantle (i.e., Type 2 peridotites) may be irregularly eroded by upwelling asthenosphere materials along weak zones and eventually replaced to create a new and fertile lithosphere mantle (i.e., Type 1 xenoliths) as the asthenosphere cooled. Therefore, the subcontinental lithospheric mantle beneath the lower Yangtze block shared a common evolutional dynamic environment with that beneath the eastern North China Craton during late Mesozoic–Cenozoic time.     

Os-isotope constraints on the dynamics of orogenic mantle: The case of the Central Balkans

We used Os isotopic systematics to assess the geochemical relationship between the lithospheric mantle beneath the Balkans (Mediterranean), ophiolitic peridotites and lavas derived from the lithospheric mantle. In our holistic approach we studied samples of Tertiary post-collisional ultrapotassic lavas sourced within the lithospheric mantle, placer Pt alloys from Vardar ophiolites, peridotites from nearby Othris ophiolites, as well as four mantle xenoliths representative for the composition of the local mantle lithosphere. Our ultimate aim was to monitor lithospheric mantle evolution under the Balkan part of the Alpine-Himalayan belt. The observations made on Os isotope and highly siderophile element (HSE) distributions were complemented with major and trace element data from whole rocks as well as minerals of representative samples. Our starting hypothesis was that the parts of the lithospheric mantle under the Balkans originated by accretion and transformation of oceanic lithosphere similar to ophiolites that crop out at the surface.Both ophiolitic peridotites and lithospheric mantle of the Balkan sector of Alpine-Himalayan belt indicate a presence of a highly depleted mantle component. In the ophiolites and the mantle xenoliths, this component is fingerprinted by the low clinopyroxene (Cpx) contents, low Al₂O₃ in major mantle minerals, together with a high Cr content in cogenetic Cr-spinel. Lithospheric mantle-derived ultrapotassic melts have high-Fo olivine and Cr-rich spinel that also indicate an ultra-depleted component in their mantle source. Further resemblance is seen in the Os isotopic variation observed in ophiolites and in the Serbian lithospheric mantle. In both mantle types we observed an unusual increase of Os abundances with increase in radiogenic Os that we interpreted as fluid-induced enrichment of a depleted Proterozoic/Archaean precursor. The enriched component had suprachondritic Os isotopic composition and its ultimate source is attributed to the subducting oceanic slab. On the other hand, a source–melt kinship is established between heterogeneously metasomatised lithospheric mantle and lamproitic lavas through a complex vein + wall rock melting relationship, in which the phlogopite-bearing pyroxenitic metasomes with high ¹⁸⁷Re/¹⁸⁸Os and extremely radiogenic ¹⁸⁷Os/¹⁸⁸Os > 0.3 are produced by recycling of a component ultimately derived from the continental crust.We tentatively propose a two-stage process connecting lithospheric mantle with ophiolites and lamproites in a geologically reasonable scenario: i) ancient depleted mantle “rafts” representing fragments of lithospheric mantle “recycled” within the convecting mantle during the early stages of the opening of the Tethys ocean and further refertilized, were enriched by a component with suprachondritic Os isotopic compositions in a supra-subduction oceanic environment, probably during subduction initiation that induced ophiolite emplacement in Jurassic times. Fluid-induced partial melts or fluids derived from oceanic crust enriched these peridotites in radiogenic Os; ii) the second stage represents recycling of the melange material that hosts above mantle blocks, but also a continental crust-derived terrigenous component accreted to the mantle wedge, that will later react with each other, producing heterogeneously distributed metasomes; final activation of these metasomes in Tertiary connects the veined lithospheric mantle and lamproites by vein + wall rock partial melting to generate lamproitic melts. Our data are permissive of the view that the part of the lithospheric mantle under the Balkans was formed in an oceanic environment.     

Chronology and tectonic implications of Neoproterozoic blocks in the South Qinling Orogenic Belt,Central China

The Qinling Orogenic Belt (QOB) located between the North China Craton (NCC) and the Yangtze Craton (YZC) is composed of the North Qinling Belt (NQB), the South Qinling Belt (SQB) and the northern margin of the YZC. Detailed geological and geochronological investigations have revealed distinct Neoproterozoic blocks of various scales in the middle and western segments of the SQB, including the Madao block (MDB), Mihunzhen intrusion (MHI), Zhenggou block (ZGB), and Lengshuigou block (LSB) which constitute an east-west trending Neoproterozoic uplift zone of the basement continental blocks. These blocks are mainly composed of four lithological groups. Group #1 consists mainly of diorites in the LSB, the zircons from which yield a weighted mean ²⁰⁶Pb/ ²³⁸U age of ca. 941 Ma. Group #2 is chiefly composed of hornblende gabbros and diorites in the MHI and LSB, which were formed at ca. 885 Ma. Group #3 comprises massive diorites, quartz diorite, tonalites, granodiorites, and monzogranites in the MDB, MHI, ZGB and LSB, which were emplaced during ca. 785–740 Ma. Group #4 is composed of hornblende gabbros with an emplacement age of ca. 667 Ma in the ZGB.Detailed whole-rock geochemical and zircon Hf isotopic studies reveal the following: (1) The diorites of Group #1 were produced by partial melting of depleted mantle which was enriched by slab-derived melts, with the parental magmas contaminated by crustal materials. (2) The gabbros of Group #2 were derived from the partial melting of depleted mantle enriched by slab-derived melts and the diorites are the fractional crystallization products of the gabbroic magmas. (3) Group #3 which can be further sub-divided based on lithological assemblages and zircon Hf isotopic features into two subgroups, one representing massive diorites, quartz diorite, tonalites, granodiorites, and monzogranites (DTGMs) and the other composed of gneissic quartz diorites and granodiorites. Among these, the DTGMs were derived through magma mixing between melts derived from the depleted mantle wedge altered by slab-derived fluids and melts from juvenile sources, which subsequently underwent amphibole-dominated fractionation, whereas the gneissic granitoids formed through partial melting of thickened lower crust contaminated by depleted mantle melts. (4) The gabbros of Group #4 originated from a depleted lithospheric mantle that was enriched by slab-derived melts and fluids with contribution of asthenospheric mantle-derived materials. In conjunction with data from previous studies on the Neoproterozoic blocks in the SQB and basement blocks in the northern margin of the YZC, our new geological, geochronological and geochemical data suggest a large Neoproterozoic uplift zone in the SQB, which was destructed by Paleozoic to Mesozoic magmatism and deformation. The Neoproterozoic uplift zone of the SQB might have been separated from the northern margin of the YZC during the formation of the Mianlue Ocean, and might have evolved under an active continental margin setting and subsequent continental rift setting accompanied by significant crustal growth. The magmatism also resulted in the formation of important Neoproterozoic ore deposits and supplied the material sources for some of the major Mesozoic ore deposits.