Proterozoic rapakivi granites from the North Qaidam orogen,NW China: Implications for basement attribution

Voluminous Proterozoic (~ 1700 Ma) rapakivi granites occur in several cratons, especially in the northern hemisphere. Similar Proterozoic rapakivi granites have recently been recognized in the Paleozoic North Qaidam orogen, western segment of the China Central Orogenic System (CCOS). SHRIMP zircon U–Pb dating of these granites yielded ages of 1778 ± 17 and 1778 ± 12 Ma. These granites exhibit typical rapakivi textures. They are ferroan, alkalic to alkalic-calc, metaluminous to peraluminous and characterized by high Ga/Al ratios, Na₂O + K₂O and rare earth elements (apart from Eu) contents, but low MgO, CaO and Sr contents. These are typical A-type granite features. Whole-rock ε_Nd(t) values of the granites range from − 6.09 to − 5.74 with Nd model ages of 2762 to 2733 Ma, and their zircon ε_Hf(t) values are from − 8.3 to − 5.2 with two-stage Hf model ages of 2944 to 2800 Ma, suggesting that these rocks were derived from old continental crust. The ages, rapakivi texture and geochemical features suggest that these granites are very close to typical Proterozoic (~ 1700 Ma) rapakivi granites within the North China Craton (NCC) and belong to the group of Proterozoic rapakivi granites of the northern hemisphere. These indicate that part of the basement of the North Qaidam orogen in the western CCOS is similar to that of the NCC or was probably derived from it, and then became involved in the CCOS. This provides new data to solve the dispute on the basement origin in this orogen.     

Zircon U–Pb age,Hf isotopic compositions and geochemistry of the Silurian Fengdingshan I-type granite Pluton and Taoyuan mafic–felsic Complex at the southeastern margin of the Yangtze Block

This work presents an integrated study of zircon U–Pb ages and Hf isotope along with whole-rock geochemistry on Silurian Fengdingshan I-type granites and Taoyuan mafic–felsic intrusive Complex located at the southeastern margin of the Yangtze Block, filling in a gap in understanding of Paleozoic I-type granites and mafic-intermediate igneous rocks in the eastern South China Craton (SCC). The Fengdingshan granite and Taoyuan hornblende gabbro are dated at 436 ± 5 Ma and 409 ± 2 Ma, respectively. The Fengdingshan granites display characteristics of calc-alkaline I-type granite with high initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7093–0.7127, low εNd(t) values ranging from −5.6 to −5.4 and corresponding Nd model ages (T_2DM) of 1.6 Ga. Their zircon grains have εHf(t) values ranging from −2.7 to 2.6 and model ages of 951–1164 Ma. The Taoyuan mafic rocks exhibit typical arc-like geochemistry, with enrichment in Rb, Th, U and Pb and depletion in Nb, Ta. They have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7053–0.7058, εNd(t) values of 0.2–1.6 and corresponding T_2DM of 1.0–1.1 Ga. Their zircon grains have εHf(t) values ranging from 3.2 to 6.1 and model ages of 774–911 Ma. Diorite and granodiorite from the Taoyuan Complex have initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7065–0.7117, εNd(t) values from −5.7 to −1.9 and Nd model ages of 1.3–1.6 Ga. The petrographic and geochemical characteristics indicate that the Fengdingshan granites probably formed by reworking of Neoproterozoic basalts with very little of juvenile mantle-derived magma. The Taoyuan Complex formed by magma mixing and mingling, in which the mafic member originated from a metasomatized lithospheric mantle. Both the Fengdingshan and Taoyuan Plutons formed in a post-orogenic collapse stage in an intracontinental tectonic regime. Besides the Paleozoic Fengdingshan granites and Taoyuan hornblende gabbro, other Neoproterozoic and Indosinian igneous rocks located along the southeastern and western margin of the Yangtze Block also exhibit decoupled Nd–Hf isotopic systemics, which may be a fingerprint of a previous late Mesoproterozoic to early Neoproterozoic oceanic subduction.     

Gold-hosting high Ba-Sr granitoids in the Xincheng gold deposit,Jiaodong Peninsula,East China: Petrogenesis and tectonic setting

The Xincheng deposit is the only large gold deposit with a proven reserve of >200 t gold hosted by the Early Cretaceous granitoids in northwest Jiaodong Peninsula, East China. The granitoids hosting this ore deposit comprise an inner medium- to fine-grained quartz monzonite and an outer medium- to coarse-grained monzogranite with distinctive K-feldspar megacrysts. LA–ICP–MS zircon dating yields U–Pb ages of 128 ± 1 to 132 ± 1 Ma and 127 ± 2 to 129 ± 1 Ma, for the quartz monzonite and the monzogranite, respectively. The Early Cretaceous ages obtained in our study are comparable with the 126–130 Ma age range reported for the Guojialing granitic suite. The monzogranites, typical high Ba–Sr granites, possess high SiO₂ (70.89–73.35%), K₂O (3.85–4.32%), total alkalis (K₂O + Na₂O = 8.08–8.68%), Sr (634–888 ppm), Ba (1395–2111 ppm) and LREE (59.43–145.88), with low HREE and HFSE contents and insignificant Eu anomalies. The rocks display markedly high Sr/Y (114–297) and (La/Yb)_N (20–79) ratios. They have low MgO (0.23–0.62%), Cr (0.4–8.33 ppm) and Ni (0.47–2.92 ppm) contents. The typical high Ba–Sr signatures of the outer acidic monzogranites are also shared by the inner intermediate-acidic quartz monzonites, with a relatively higher abundance of these elements. The plagioclases in the quartz monzonites and monzogranites are oligoclase–andesine with An contents of 11.7–44.5%, and oligoclase with An contents of 12.9–29.3%, respectively, which both show the reverse zoning texture. The quartz monzonites have zircon ε_Hf(t) values of −21.3 to −13.9 (average −18.7), which are less negative and show larger variations than those of the monzogranites (ε_Hf(t) = −24.7 to −18.1, average −19.5). Detailed elemental, mineralogical and isotopic data suggest that the high Ba–Sr quartz monzonites and monzogranites were most likely generated by partial melting of the basement rocks of the Jiaobei terrane accompanied by crustal assimilation, with minor addition of the intermediate magma derived from the partial melting of juvenile mafic lower crust formed by the earlier underplating of mantle magma, and the quartz monzonites may represent the path of intermediate magma inputting into felsic magma. In combination with previous investigations, we suggest subduction of the paleo-Pacific slab beneath the North China Craton (NCC) and associated asthenosphere upwelling were most likely the mechanism associated with the generation of the high Ba–Sr granites.     

Phanerozoic amalgamation of the Alxa Block and North China Craton: Evidence from Paleozoic granitoids,U–Pb geochronology and Sr–Nd–Pb–Hf–O isotope geochemistry

The North China Craton (NCC) has been considered to be part of the supercontinent Columbia. The nature of the NCC western boundary, however, remains strongly disputed. A key question in this regard is whether or not the Alxa Block is a part of the NCC. It is located in the vicinity of the inferred boundary, and therefore could potentially resolve the issue of the NCC's relationship to the Columbia supercontinent. Some previous studies based on the Alxa Block's geological evolution and detrital zircon ages suggested that it is likely not a part of the NCC. The lack of evidence from key igneous rock units, however, requires further constraints on the tectonic affinity of the western NCC and Alxa Block and on the timing of their amalgamation.In this study, new zircon U–Pb age and Hf–O isotopes and whole-rock geochemical and Sr–Nd–Pb isotopic data for the Paleozoic granitoids in or near the eastern Alxa Block were used to constrain the petrogenesis of these rocks and the relationship between the Alxa Block and NCC. Secondary ion mass spectrometry (SIMS) U–Pb zircon dating indicates that the Bayanbulage, Hetun, Diebusige and South Diebusige granitoids were formed at ca. 423 Ma, 345 Ma, 345 Ma and 337 Ma, respectively. The Late Silurian (Bayanbulage) quartz diorites have variable SiO₂ (58.0–67.9 wt.%), and low Sr/Y (20–24) values, while the Early Carboniferous (Hetun, Diebusige and South Diebusige) monzogranites have high SiO₂ (71.5–76.7 wt.%) and Sr/Y (40–94) values. The Late Silurian quartz diorites display relatively homogeneous and high zircon δ¹⁸O (8.5–9.1‰) and ε_Hf(t) (− 8.6 to − 5.3) values, high whole-rock ε_Nd(t) values (− 9.2 to − 7.6) and highly radiogenic Pb isotopes (²⁰⁶Pb/²⁰⁴Pb = 18.13–18.25), whereas the Early Carboniferous monzogranites exhibit relatively low and variable zircon δ¹⁸O (5.7–7.2‰) and ε_Hf(t) (− 23.1 to − 7.4) values, low whole-rock initial ⁸⁷Sr/⁸⁶Sr (0.7043–0.7070) and ε_Nd(t) (− 19.1 to − 13.5) values and variable Pb isotopes (²⁰⁶Pb/²⁰⁴Pb = 16.06–18.22). The differences in whole rock Nd model ages and Pb isotope compositions of the Paleoproterozoic–Permian rocks in either side of the west fault of the Bayanwulashan–Diebusige complexes suggest that the Alxa Block is not a part of the NCC, and that the western boundary of the NCC is probably located on this fault. Furthermore, the linear distribution of the Early Paleozoic–Early Carboniferous granitoids, the high zircon δ¹⁸O values of the Late Silurian quartz diorites, the Early Devonian metamorphism and the foreland basin system formed during the collision between the Alxa Block and the NCC indicate that a Paleozoic cryptic suture zone likely existed in this area and records the amalgamation of the Alxa Block and North China Craton. Together with detrital zircon data, the initial collision was considered to have possibly occurred in Late Ordovician.     

Late Silurian–early Devonian adakitic granodiorite,A-type and I-type granites in NW Junggar,NW China: Partial melting of mafic lower crust and implications for slab roll-back

Late Silurian–early Devonian magmatism of the NW Junggar region in the Central Asian Orogenic Belt provides a critical geological record that is important for unraveling regional tectonic history and constraining geodynamic processes. In this study, we report results of Zircon U–Pb ages and systematic geochemical data for late Silurian–early Devonian largely granitic rocks in NW Junggar, aiming to constrain their emplacement ages, origin and geodynamic significance. The magmatism consists of a variety of mafic to felsic intrusions and volcanic rocks, e.g. adakitic granodiorite, K-feldspar granite, syenitic granite, gabbro and rhyrolite. U–Pb zircon ages suggest that the granitoids and gabbros were emplaced in the late Silurian–early Devonian (420–405 Ma). Adakitic granodiorites are calc-alkaline, characterized by high Sr (407–532 ppm), low Y (12.2–14.7 ppm), Yb (1.53–1.77 ppm), Cr (mostly < 8.00 ppm), Co (mostly < 11.0 ppm) and Ni (mostly < 4.10 ppm) and relatively high Sr/Y (31–42) ratios, analogous to those of modern adakites. K-feldspar granites and rhyolites are characterized by alkali- and Fe-enriched, with high Zr, Nb and Ga/Al ratios, geochemically similar to those of A-type granites. Syenitic granites show high alkaline (Na₂O + K₂O = 8.39–9.34 wt.%) contents, low Fe^# values (0.73–0.80) and are weakly peraluminous (A/CNK = 1.00–1.07). Gabbros are characterized by low MgO (6.86–7.15 wt.%), Mg^# (52–53), Cr (124–133 ppm) and Ni (84.7–86.6 ppm) contents. The geochemical characteristics of the gabbroic samples show affinity to both MORB- and arc-like sources. All granitoids have positive εNd(t) (+ 3.9 to + 6.9) and zircon εHf(t) (+ 9.8 to + 15.2) values and low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7035–0.7043), with young T_DM(Nd) (605–791 Ma) and T_DM(Hf) (425–773 Ma) ages, suggesting significant addition of juvenile material. The adakitic granodiorites probably resulted from partial melting of mafic lower crust, leaving an amphibolite and garnet residue. The K-feldspar granites, rhyolites and syenitic granites probably formed from partial melting of the Xiemisitai mid-lower crust, while the gabbroic intrusion was probably generated by interactions between asthenospheric and metasomatized lithospheric mantle. Voluminous plutons of various types (adakites, A-type granites, I-type granites, and gabbros) formed during 420–405 Ma, and their isotopic data suggest significant additions of juvenile material. We propose that a slab roll-back model can account for the 420–405 Ma magmatic “flare up” in NW Junggar as well as an extensional setting.     

Geochemistry and U–Pb zircon geochronology of the Alvand plutonic complex in Sanandaj–Sirjan Zone (Iran): New evidence for Jurassic magmatism

This paper presents geochemical, Sr–Nd isotopic, and U–Pb zircon geochronological data on the Alvand plutonic complex in Sanandaj–Sirjan zone (SSZ), Western Iran. The gabbroic rocks show a trend of a calc-alkaline magma suite and are characterized by low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7023–0.7037) and positive εNd(t) values (2.9–3.3), which suggest derivation from a moderately depleted mantle source. Geochemical features of the granites illustrate a high-K calc-alkaline magma series, whereas the leucocratic granitoids form part of a low-K series. Granites have intermediate ⁸⁷Sr/⁸⁶Sr ratios (0.707–0.719) and negative εNd_(t) values (−1.0 to −3.4), while leucocratic granitoids have higher initial ⁸⁷Sr/⁸⁶Sr ratio (0.713–0.714) and more negative εNd_(t) values (−3.5 to −4.5). Potential basement source lithologies for the granites are Proterozoic granites and orthogneisses, and those for the leucocratic granites are plagioclase-rich sources such as meta-arkoses or tonalites. The U–Pb dating results demonstrate that all granitoids were exclusively emplaced during the Jurassic instead of being Cretaceous or younger in age as suggested previously. The pluton was assembled incrementally over c. 10 Ma. Gabbros formed at 166.5 ± 1.8 Ma, granites between 163.9 ± 0.9 Ma and 161.7 ± 0.6 Ma, and leucocratic granitoids between 154.4 ± 1.3 and 153.3 ± 2.7 Ma. Granites and leucocratic granitoids show some A-type affinity. It is concluded that the Alvand plutonic complex was generated in a continental-arc-related extensional regime during subduction of Neo-Tethyan oceanic crust beneath the SSZ. The U/Pb zircon age data, recently corroborated by similar results in the central and southern SSZ, indicate that Jurassic granitoids are more areally extensive in this belt than previously thought.     

Growth and reworking of the early Precambrian continental crust in the North China Craton: Constraints from zircon Hf isotopes

We synthesize more than 2600 Hf isotope data on the Archean-Paleoproterozoic zircons from the North China Craton (NCC). Recalculation of the data based on single stage and two-stage Hf model ages of the Eastern Block of the NCC shows peak ages of 3902 ± 13 Ma and 3978 ± 18 Ma, respectively, and also small peaks at 3.5–4.0 Ga. The majority of zircon ε_Hf(t) values are positive, suggesting the possibility of the crust and the mantle differentiation at ca. 3.9–4.0 Ga in the Eastern Block of the NCC. Most magmatic zircons from the whole of NCC have their Hf model age range of 2.4–2.9 Ga, and the single stage model ages is cluster at 2698 ± 4 Ma, whereas the two-stage model ages concentrate at 2714 ± 5 Ma, implying that the protoliths were juvenile crustal rocks. The most prominent peak at 2.7 Ga indicates that this period marks the most important stage of the crust-mantle differentiation and crust formation of the NCC. The widespread 2.5 Ga rocks in the NCC and the absence of the 2.5 Ga peaks in Hf model ages are consistent with the partial melting and reworking of the juvenile rocks at 2.5 Ga. Furthermore, the 2.5–1.7 Ga zircon Hf isotope features are also related to the reworking of the crustal rocks. Our results from the integration of a large database suggest that the Eastern Block and the Trans-North China Orogen have undergone similar crust-mantle differentiation and magmatism, leading to the conclusion that the essential cratonization of the North China took place at the end of Neoarchean.     

Chronology and geochemistry of Mesozoic granitoids in the Bengbu area,central China: Constraints on the tectonic evolution of the eastern North China Craton

We performed zircon U–Pb dating and analyses of major and trace elements, and Sr–Nd–Pb isotopes for granitoids in the Bengbu area, central China, with the aim of constraining the magma sources and tectonic evolution of the eastern North China Craton (NCC). The analyzed zircons show typical fine-scale oscillatory zoning, indicating a magmatic origin. Zircon U–Pb dating reveals granitoids of two ages: Late Jurassic and Early Cretaceous (²⁰⁶Pb/²³⁸U ages of 160 Ma and 130–110 Ma, respectively). The Late Jurassic rocks (Jingshan intrusion) consist of biotite-syenogranite, whereas the Early Cretaceous rocks (Huaiguang, Xilushan, Nushan, and Caoshan intrusions) are granodiorite, syenogranite, and monzogranite. The Late Jurassic biotite-syenogranites and Early Cretaceous granitoids have the following common geochemical characteristics: SiO₂ = 70.35–74.56 wt.%, K₂O/Na₂O = 0.66–1.27 (mainly < 1.0), and A/CNK = 0.96–1.06, similar to I-type granite. The examined rocks are characterized by enrichment in light rare earth elements, large ion lithophile elements, and U; depletion in heavy rare earth elements, Nb, and Ta; and high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7081–0.7110) and low ε_Nd (t) values (? 14.40 to ? 22.77), indicating a crustal origin.The occurrence of Neoproterozoic magmatic zircons (850 Ma) and inherited early Mesozoic (208–228 Ma) metamorphic zircons within the Late Jurassic biotite-syenogranites, together with the occurrence of Neoproterozoic magmatic zircons (657 and 759 Ma) and inherited early Mesozoic (206–231 Ma) metamorphic zircons within the Early Cretaceous Nushan and Xilushan granitoids, suggests that the primary magmas were derived from partial melting of the Yangtze Craton (YC) basement. In contrast, the occurrence of Paleoproterozoic and Paleoarchean inherited zircons within the Huaiguang granitoids indicates that their primary magmas mainly originated from partial melting of the NCC basement. The occurrence of YC basement within the lower continental crust of the eastern NCC indicates that the YC was subducted to the northwest beneath the NCC, along the Tan-Lu fault zone, during the early Mesozoic.     

Episodic Mesozoic thickening and reworking of the North China Archean lower crust correlated to the fast-spreading Pacific plate

A central target in Earth sciences is to understand the processes controlling the stabilization and destruction of Archean continents. The North China craton (NCC) has in part lost its dense crustal root after the Mesozoic, and thus it is a key region to test models of crust–mantle differentiation and subsequent evolution of the continental crust. However, the timing and mechanisms responsible for its crustal thickening and reworking have been long debated. Here we report the Early Cretaceous Yinan (eastern NCC) adakitic granites, for which major/trace elemental models demonstrate that they are complementary to the analogy of the documented eclogitic relicts within the NCC. Based on their Late Archean inherited zircons, depleted mantle Nd model ages of ∼2.8 Ga, large negative ε_Nd(t) values (−36.7 to −25.3) and strongly radiogenic initial ⁸⁷Sr/⁸⁶Sr ratios (0.7178–0.7264), we suggest that the Yinan adakitic granites were potentially formed by the dehydration melting of a thickened Archean mica-bearing mafic lower crust during the Early Cretaceous (ca. 124 Ma), corresponding to a major period (117–132 Ma) of the NCC Mesozoic intrusive magmatism. Combined previous results, it is shown that the thickening and reworking of the North China Archean lower crust occurred largely as two short-lived episodes at 155–180 Ma and 117–132 Ma, rather than a gradual, secular event. These correlated temporally with the superfast-spreading Pacific plate during the Mesozoic. The synchroneity of these events suggests rapid plate motion of the Pacific plate driving the episodic NCC crustal thickening and reworking, resulting in dense eclogitic residues that became gravitationally unstable. The onset of lithospheric delamination occurred when upwelling asthenosphere heated the base of lower crust to form coeval felsic magmas with or without involvement of juvenile mantle material. Collectively, the circum-Pacific massive crustal production could be attributed to the unusually rapid motion of Pacific at 155–180 Ma and 117–132 Ma.     

Constraints on the paleogeographic evolution of the North China Craton during the Late Triassic–Jurassic

This paper reports U–Pb–Hf isotopes of detrital zircons from Late Triassic–Jurassic sediments in the Ordos, Ningwu, and Jiyuan basins in the western-central North China Craton (NCC), with the aim of constraining the paleogeographic evolution of the NCC during the Late Triassic–Jurassic. The early Late Triassic samples have three groups of detrital zircons (238–363 Ma, 1.5–2.1 Ga, and 2.2–2.6 Ga), while the latest Late Triassic and Jurassic samples contain four groups of detrital zircons (154–397 Ma, 414–511 Ma, 1.6–2.0 Ga, and 2.2–2.6 Ga). The Precambrian zircons in the Late Triassic–Jurassic samples were sourced from the basement rocks and pre-Late Triassic sediments in the NCC. But the initial source for the 238–363 Ma zircons in the early Late Triassic samples is the Yinshan–Yanshan Orogenic Belt (YYOB), consistent with their negative zircon ε_Hf(t) values (−24 to −2). For the latest Late Triassic and Jurassic samples, the initial source for the 414–511 Ma zircons with ε_Hf(t) values of −18 to +9 is the Northern Qinling Orogen (NQO), and that for the 154–397 Ma zircons with ε_Hf(t) values of −25 to +12 is the YYOB and the southeastern Central Asian Orogenic Belt (CAOB). In combination with previous data of late Paleozoic–Early Triassic sediments in the western-central NCC and Permian–Jurassic sediments in the eastern NCC, this study reveals two shifts in detrital source from the late Paleozoic to Jurassic. In the Late Permian–Early Triassic, the western-central NCC received detritus from the YYOB, southeastern CAOB and NQO. However, in the early Late Triassic, detritus from the CAOB and NQO were sparse in basins located in the western-central NCC, especially in the Yan’an area of the Ordos Basin. We interpret such a shift of detrital source as result of the uplift of the eastern NCC in the Late Triassic. In the latest Late Triassic–Jurassic, the southeastern CAOB and the NQO restarted to be source regions for basins in the western-central NCC, as well as for basins in the eastern NCC. The second shift in detrital source suggests elevation of the orogens surrounding the NCC and subsidence of the eastern NCC in the Jurassic, arguing against the presence of a paleo-plateau in the eastern NCC at that time. It would be subsidence rather than elevation of the eastern NCC in the Jurassic, due to roll-back of the subducted paleo-Pacific plate and consequent upwelling of asthenospheric mantle.     

Tectono-magmatic evolution of the Gaoligong belt,southeastern margin of the Tibetan plateau: Constraints from granitic gneisses and granitoid intrusions

The Gaoligong belt is located in the southeastern margin of the Tibetan plateau, and is bound by the Tengchong and Baoshan blocks. This paper presents new data from zircon geochronology, geochemistry, and whole-rock Sr–Nd–Pb–Hf isotopes to evaluate the tectonic evolution of the Gaoligong belt. The major rock types analysed in the present study are granitic gneiss, granodiorite, and granite. They are metaluminous to peraluminous and belong to high-K, calc-alkaline series. Laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS) analyses of zircons from nine granitic rocks yielded crystallization ages of 495–487 Ma, 121 Ma, 89 Ma, and 70–63 Ma. The granitoids can be subdivided into the following four groups. (1) Early Paleozoic granitic gneisses with high ε_Nd(t) and ε_Hf(t) values of − 1.06 to − 3.45 and − 1.16 to 2.09, and model ages of 1.16 Ga to 1.33 Ga and 1.47 Ga to 1.63 Ga, respectively. Their variable ⁸⁷Sr/⁸⁶Sr and Pb values resemble the characteristics of the Early Paleozoic Pinghe granite in the Baoshan block. Our data suggest that the rocks were derived from the break-off of the Proto-Tethyan oceanic slab between the outboard continent and the Baoshan block, which induced the partial melting of Mesoproterozoic pelitic sources mixed with depleted mantle materials. (2) Early Cretaceous granodiorites with low ε_Nd(t) and ε_Hf(t) values of − 8.92 and − 4.91 with Nd and Hf model ages of 1.41 Ga and 1.49 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.711992) and lower crustal Pb values, suggesting that they were derived from Mesoproterozoic amphibolites with tholeiitic signature, leaving behind granulite residue at the lower crust. (3) Early Late Cretaceous granites with low ε_Nd(t) and ε_Hf(t) values of − 9.58 and − 4.61 with Nd and Hf model ages of 1.43 Ga and 1.57 Ga, respectively. These rocks have high initial ⁸⁷Sr/⁸⁶Sr (0.713045) and lower crustal Pb isotopic values. These rocks were generated from the partial melting of Mesoproterozoic metapelitic sources resulting from the delamination of thickened lithosphere, following the closure of the Bangong–Nujiang Ocean and collision of the Lhasa–Qiangtang blocks. (4) Late Cretaceous to Paleogene granitic gneisses with low ε_Nd(t) and ε_Hf(t) values of − 4.41 to − 10 and − 5.95 to − 8.71, Nd model ages ranging from 1.08 Ga to 1.43 Ga, and Hf model ages from 1.53 Ga to 1.67 Ga, respectively. These rocks show high initial ⁸⁷Sr/⁸⁶Sr (0.713201 and 714662) and lower crustal Pb values. The data suggest that these rocks are likely related to the eastward subduction of the Neo-Tethyan Oceanic slab, which induced partial melting of Mesoproterozoic lower crustal metagreywacke. The results presented in this study from the Gaoligong belt offer important insights on the evolution of the Proto-Tethyan, Bangong–Nujiang, and Neo-Tethyan oceans in the southeastern margin of the Tibetan Plateau.     

Post-collisional potassic magmatism in the eastern Lhasa terrane,South Tibet: Products of partial melting of mélanges in a continental subduction channel

Post-collisional, potassic magmatic rocks widely distributed in the eastern Lhasa terrane provide significant information for comprehensive understanding of geodynamic processes of northward subduction of the Indian lithosphere and uplift of the Tibetan Plateau. A combined dataset of whole-rock major and trace elements, Sr–Nd–Pb isotopes, and in situ zircon U–Pb dating and Hf–O isotopic analyses are presented for the Yangying potassic volcanic rocks (YPVR) in the eastern part of the Lhasa terrane, South Tibet. These volcanic rocks consist of trachytes, which are characterized by high K₂O (5.46–9.30 wt.%), SiO₂ (61.34–68.62 wt.%) and Al₂O₃ (15.06–17.36 wt.%), and relatively low MgO (0.47–2.80 wt.%) and FeO_t (1.70–4.90 wt.%). Chondrite-normalized rare earth elements (REE) patterns display clearly negative Eu anomalies. Primitive mantle-normalized incompatible trace elements diagrams exhibit strong enrichment in large ion lithophile elements (LILE) relative to high field strength elements (HFSE) and display significantly negative Nb–Ta–Ti anomalies. Initial isotopic compositions indicate relatively radiogenic Sr [(⁸⁷Sr/⁸⁶Sr)_i = 0.711978–0.712090)] and unradiogenic Nd [(¹⁴³Nd/¹⁴⁴Nd)_i = 0.512121–0.512148]. Combined with their Pb isotopic compositions [(²⁰⁶Pb/²⁰⁴Pb)_i = 18.615–18.774, (²⁰⁷Pb/²⁰⁴Pb)_i = 15.708–15.793, (²⁰⁸Pb/²⁰⁴Pb)_i = 39.274–39.355)], these data are consistent with the involvement of component from subducted continental crustal sediment in their source region. The whole-rock Sr–Nd–Pb isotopic compositions exhibit linear trends between enriched mantle-derived mafic ultrapotassic magmas and relatively depleted crustal contaminants from the Lhasa terrane. The enrichment of the upper mantle below South Tibet is considered to result from the addition of components derived from subducted Indian continental crust to depleted MORB-source mantle during northward underthrusting of the Indian continental lithosphere beneath the Lhasa terrane since India–Asia collision at ~ 55 Ma. Secondary Ion Mass Spectrometry (SIMS) U–Pb zircon analyses yield the eruptive ages of 10.61 ± 0.10 Ma and 10.70 ± 0.18 Ma (weighted mean ages). Zircon Hf isotope compositions [Ɛ_Hf(t) = −4.79 to −0.17], combined with zircon O isotope ratios (5.51–7.22‰), imply an addition of crustal material in their petrogenesis. Clinopyroxene-liquid thermobarometer reveals pressure (2.5–4.1 kbar) and temperature (1029.4–1082.9 °C) of clinopyroxene crystallization, suggesting that depth of the magma chamber was 11.6–16.4 km. Energy-constrained assimilation and fractional crystallization (EC–AFC) model calculation indicates depth of assimilation and fractional crystallization in the region of 14.40–18.75 km underneath the Lhasa terrane, which is in consistent with depth of the magma chamber as suggested by clinopyroxene-liquid thermobarometer. Based on the whole-rock major and trace elements and Sr–Nd–Pb isotope compositions, combined with EC–AFC modeling simulations and zircon Hf–O isotope data, we propose that the YPVR resulted from assimilation and fractional crystallization (AFC) process of the K-rich mafic primitive magmas, which were caused by partial melting of the Indian continental subduction-induced mélange rocks.     

Shrimp U–Pb zircon geochronology,geochemistry, and Nd–Sr isotopic study of contrasting granites in the Emeishan large igneous province,SW China

The Cida A-type granitic stock (∼ 4 km²) and Ailanghe I-type granite batholith (∼ 100 km²) in the Pan-Xi (Panzhihua-Xichang) area, SW China, are two important examples of granites formed during an episode of magmatism associated with the Permian Emeishan mantle plume activity. This is a classic setting of plume-related, anorogenic magmatism exhibiting the typical association of mantle-derived mafic and alkaline rocks along with silicic units. SHRIMP zircon U–Pb data reveal that the Cida granitic pluton (261 ± 4 Ma) was emplaced shortly before the Ailanghe granites (251 ± 6 Ma). The Cida granitoids display mineralogical and geochemical characteristics of A-type granites including high FeO^⁎/MgO ratios, elevated high-field-strength elements (HFSE) contents and high Ga/Al ratios, which are much higher than those of the Ailanghe granites. All the granitic rocks show significant negative Eu anomalies and demonstrate the characteristic negative anomalies in Ba, Sr, and Ti in the spidergrams. It can be concluded that the Cida granitic rocks are highly fractionated A-type granitoids whereas the Ailanghe granitic rocks belong to highly evolved I-type granites.The Cida granitoids and enclaves have Nd and Sr isotopic initial ratios (ε_Nd(t) = − 0.25 to + 1.35 and (⁸⁷Sr/⁸⁶Sr)_i = 0.7023 to 0.7053) close to those of the associated mafic intrusions and Emeishan basalts, indicating the involvement of a major mantle plume component. The Ailanghe granites exhibit prominent negative Nb and Ta anomalies and weakly positive Pb anomalies in the spidergram and have nonradiogenic ε_Nd(t) ratios (− 6.34 to − 6.26) and high (⁸⁷Sr/⁸⁶Sr)_i values (0.7102 to 0.7111), which indicate a significant contribution from crustal material. These observations combined with geochemical modeling suggest that the Cida A-type granitoids were produced by extensive fractional crystallization from basaltic parental magmas. In contrast, the Ailanghe I-type granites most probably originated by partial melting of the mid-upper crustal, metasedimentary–metavolcanic rocks from the Paleo-Mesoproterozoic Huili group and newly underplated basaltic rocks.In the present study, it is proposed that petrogenetic distinctions between A-type and I-type granites may not be as clear-cut as previously supposed, and that many compositional and genetically different granites of the A- and I-types can be produced in the plume-related setting. Their ultimate nature depends more importantly on the type and proportion of mantle and crustal material involved and melting conditions. Significant melt production and possible underplating and/or intrusion into the lower crust, may play an important role in generating the juvenile mafic lower crust (average 20 km) in the central part of the Emeishan mantle plume.     

Origin of the Alxa Block,western China: New evidence from zircon U–Pb geochronology and Hf isotopes of the Longshoushan Complex

The NW–SE trending Longshoushan is in the southwestern margin of the Alxa Block, which was traditionally considered the westernmost part of the North China Craton (NCC). Precambrian crystalline basement exposed in the Longshoushan area was termed the “Longshoushan Complex”. This complex's formation and metamorphism are significant to understand the geotectonics and early Precambrian crustal evolution of the western NCC. In this study, field geology, petrology, and zircon U–Pb and Lu–Hf isotopes of representative orthogneisses and paragneisses in the Longshoushan Complex were investigated. U–Pb datings reveal three Paleoproterozoic magmatic episodes (ca. 2.33, ca. 2.17 and ca. 2.04 Ga) and two subsequent regional metamorphic events (ca. 1.95–1.90 Ga and ca. 1.85 Ga) for metamorphic granitic rocks in the Longshoushan Complex. U–Pb dating of the detrital magmatic zircons from two paragneisses yields concordant ²⁰⁷Pb/²⁰⁶Pb ages between 2.2 Ga and 2.0 Ga, and a small number of metamorphic zircon rims provide a ca. 1.95 Ga metamorphic age, suggesting that the depositional time of the protolith was between 2.0 and 1.95 Ga and that the sedimentary detritus was most likely derived from the granitic rocks in the Longshoushan Complex itself. Zircon Lu–Hf isotopic analyses indicate that nearly all magmatic zircons from ca. 2.0 Ga to ca. 2.17 Ga orthogneisses have positive εHf(t) values with two-stage Hf model ages (T_DMC) ranging from 2.45 to 2.65 Ga (peak at ca. 2.5 Ga), indicating that these Paleoproterozoic granitic rocks were derived from the reworking of the latest Neoarchean–early Paleoproterozoic juvenile crust. Detrital magmatic zircons from two paragneisses yield scattered ¹⁷⁶Hf/¹⁷⁷Hf ratios, εHf(t) and T_DMC values, further indicating that the sedimentary detritus was not only derived from these plutonic rocks but also from other unreported or denuded Paleoproterozoic igneous rocks. The ca. 2.15 Ga detrital magmatic zircons from one paragneiss have negative εHf(t) values with T_DMC ranging from 2.76 to 3.04 Ga, indicating another important crustal growth period in the Longshoushan region. These data indicate that the Longshoushan Complex experienced Neoarchean–Early Paleoproterozoic crustal growth, approximately ca. 2.3–2.0 Ga experienced multiphase magmatic events, and approximately ca. 1.95–1.90 Ga and ca. 1.85 Ga experienced high-grade metamorphic events. The sequence of tectonothermal events is notably similar to that of the main NCC. Together with the datasets from an adjacent area, we suggest that the western Alxa Block was most likely an integrated component of the NCC from the Neoarchean to the Paleoproterozoic.     

In situ zircon U–Pb and Hf–O isotopic results for ca. 73 Ma granite in Hainan Island: Implications for the termination of an Andean-type active continental margin in southeast China

We report in the paper integrated analyses of in situ zircon U–Pb ages, Hf–O isotopes, whole-rock geochemistry and Sr–Nd isotopes for the Longlou granite in northern Hainan Island, southeast China. SIMS zircon U–Pb dating results yield a crystallization age of ∼73 Ma for the Longlou granite, which is the youngest granite recognized in southeast China. The granite rocks are characterized by high SiO₂ and K₂O, weakly peraluminous (A/CNK = 1.04–1.10), depletion in Sr, Ba and high field strength elements (HFSE) and enrichment in LREE and large ion lithophile elements (LILE). Chemical variations of the granite are dominated by fractional crystallization of feldspar, biotite, Ti–Fe oxides and apatite. Their whole-rock initial ⁸⁷Sr/⁸⁶Sr ratios (0.7073–0.7107) and ε_Nd(t) (−4.6 to −6.6) and zircon ε_Hf(t) (−5.0 to 0.8) values are broadly consistent with those of the Late Mesozoic granites in southeast China coast. Zircon δ¹⁸O values of 6.9–8.3‰ suggest insignificant involvement of supracrustal materials in the granites. These granites are likely generated by partial melting of medium- to high-K basaltic rocks in an active continental margin related to subduction of the Pacific plate. The ca. 73 Ma Longlou granite is broadly coeval with the Campanian (ca. 80–70 Ma) granitoid rocks in southwest Japan and South Korea, indicating that they might be formed along a common Andean-type active continental margin of east–southeast Asia. Tectonic transition from the Andean-type to the West Pacific-type continental margin of southeast China likely took place at ca.70 Ma, rather than ca. 90–85 Ma as previously thought.     

Geochronological and geochemical constrains on petrogenesis of the Huangyangshan A-type granite from the East Junggar,Xinjiang, NW China

The Huangyangshan pluton occurs in the Kalamaili region which is situated in the central part of the Central Asian Orogenic Belt, East Junggar, Xinjiang (NW China). The granitoid rocks are composed of medium-grained biotite (richterite, arfvedsonite) alkali-feldspar granite, fine grained arfvedsonite alkali-feldspar granite and microgranular enclaves. The granites have a pronounced A-type affinity: they are metaluminous to weakly peraluminous and calc-alkaline to alkaline in composition with high concentrations of Na₂O + K₂O varying from 8.4 to 9.2 wt.%, high FeOt/MgO and 10,000 Ga/Al ratios, low abundances of CaO, MgO and TiO₂, enrichment in some LILEs (such as Rb and Th) and HFSEs (such as Zr, Y and REEs except Eu), depletion in Sr and Ba. Moreover, they display characteristic tetrad REE patterns and non-CHARAC trace element behavior, which is well demonstrated in highly differentiated rocks with strong hydrothermal interaction. The U–Pb zircon LA-ICP-MS ages of the host rocks and enclaves are 311 ± 5 Ma and 300 ± 6 Ma, respectively. The similar of these two ages suggests that host rocks and enclaves formed at a same time. Furthermore, the time span closely corresponds to known ages of post-collisional A-type granitoids of the Junggar terrane. Geochemical, geochronological and isotopic data (ε_Nd(T) in the range +5.2 to +6.6 and I_Sr mostly in the range 0.7031–0.7041) suggest that the Huangyangshan intrusions, and the enclaves are of mixed origin and are most probably formed by the interaction between the lower crust- and mantle-derived magmas in the Late Carboniferous post-collisional tectonic setting (A₂ type granite). The magma for the Huangyangshan granites was derived by partial melting of an enriched subcontinental lithospheric mantle (SCLM) that was modified by slab-derived components from an earlier subduction event, this melting resulted from heat supplied from the asthenosphere through an opening created during the break-off of an oceanic slab. This further proves the important contribution of the Late Paleozoic granitic magmatism in terms of vertical crustal growth in northern Xinjiang.     

Petrology,geochemistry and zircon U–Pb and Lu–Hf isotopes of the Cretaceous dykes in the central North China Craton: Implications for magma genesis and gold metallogeny

The Trans-North China Orogen (TNCO), a Paleoproterozoic suture that amalgamates the Western and Eastern Blocks of the North China Craton (NCC), witnessed extensive magmatism and metallogeny during Mesozoic, associated with intraplate tectonics and differential destruction of the cratonic lithosphere. Here we investigate a suite of porphyry dykes surrounding the Mapeng batholith in the Fuping Complex within the TNCO in relation to the Mesozoic gold and molybdenum mineralization. The major element chemistry of these dykes show a range of SiO₂ (57.92 to 69.47 wt.%), Na₂O (3.20 to 4.77 wt.%), K₂O (3.12 to 4.60 wt.%) and MgO (0.51 to 3.67 wt.%), together with high concentration of LREE and LILE, and relatively low contents of HREE and HFSE. The rocks display (La/Yb)_N = 13.53–48.11, negative Nb, Ta, Th, U and Zr anomalies, and distinctly positive Ba, K and Sm anomalies. The mineralogy and geochemistry of the porphyry dykes indicate the rocks to be high-K calc-alkaline, and I-type, with adakitic features similar to those of the adjacent Mapeng batholith. The source magma for these rocks was derived from a mixture of reworked ancient continent crust and juvenile mantle materials. The zircon U–Pb data from these rocks show ages in the range of 124 to 129 Ma, broadly coinciding with the emplacement age of the Mapeng intrusion. The inherited zircons of ca. 2.5, 2.0 and 1.8 Ga in the dykes represent capture from the basement rocks during melting. The zircon Lu–Hf isotopic compositions show negative ε_Hf(t) values varying from − 27.8 to − 11.3, with Hf depleted model ages (t_DM) ranging from 1228 Ma to 1918 Ma and Hf crustal model ages (t_DM^C) of 1905 Ma to 2938 Ma, suggesting that the Mesozoic magmatism and associated metallogeny involved substantial recycling of ancient basement rocks of the NCC. We present an integrated model to evaluate the genesis of the porphyry systems and their relation to mineralization. We envisage that these dykes probably acted as stoppers (impermeable barriers) that prevented the leakage and run-off of the ore-bearing fluids, and played a key role in concentrating the gold and molybdenum mineralization.     

The late- to postorogenic transition in the Apiaí domain,SE Brazil: Constraints from the petrogenesis of the Neoproterozoic Agudos Grandes Granite Batholith

A remarkable change in the typology of granite magmatism occurred during the late evolution of the Agudos Grandes Batholith (Apiaí domain, SE Brazil), marked by the appearance of A-type granites some 10–15 Myr after the last manifestations of the compressional period. The elemental and Sr–Nd isotope geochemistry of the approximately 600 Ma, “late-orogenic”, moderately peraluminous Piedade, Serra dos Lopes, and Pilar do Sul granites shows that the middle crust was heated to approximately 820–850 °C during the latest stages of the compressional period and generated large amounts of melt through biotite dehydration–melting of gneiss protoliths. These crustal magmas either formed independent intrusions or mixed in varied proportions with raising high-K calc-alkaline magmas, as suggested by continuous trends toward more mafic granites (65–70 wt% SiO₂), which have the geochemical signature of contaminated calc-alkaline magmas. The postorogenic granites occur as two subgroups with different age (∼585 and ∼565 Ma), both with the chemical fingerprints typical of A-type granites (low mg#, Ba, and Sr; high Zr, Hf, Nb, and Y), interpreted as a result of crustal melting at lower P, fO₂, and a(H₂O) and higher T (up to 870 °C, indicated by zircon saturation). Significant trace-element and radiogenic isotope contrasts (e.g., εNd_T = −16 vs. −11) show that the two postorogenic subgroups derived from different sources. A Sr–Nd isotope signature nearly identical to the “end-member” late-orogenic crustal melts suggests that the older postorogenic granites derived from a similar (but probably less fertile) source. The less negative εNd_T of the young subgroup is unmatched by known crustal sources in the Apiaí domain and may have resulted from either an infracrustal component or mobilization of an unexposed section with less crustal residence time.     

Petrology,geochemistry, and geochronology of Paleoproterozoic volcanic and granitic rocks (1.89–1.88 Ga) of the Pitinga Province,Amazonian Craton,Brazil

This paper presents geochemical, petrographic, and geochronological data on the Uatumã magmatism in the Pitinga Province, where it is represented by volcanic rocks from the Iricoumé Group and granitic rocks from the Mapuera Suite. The Iricoumé Group (1.89–1.88 Ga) is constituted of the Divisor Formation (intermediate volcanic rocks), Ouro Preto Formation (acid effusive rocks), and Paraiso Formation (acid crystal-rich ignimbrites, surge deposits, and basic rocks). The volcanic sequence is intruded by granitoids from the Mapuera Suite (1.88 Ga), mainly represented by monzogranites and syenogranites. Structural and field relations suggest that caldera complex collapse controlled the emplacement of volcanics and granitoids of the Mapuera Suite. Subsequent structure reactivations allowed the younger Madeira Suite (1.82–1.81 Ga) to be emplaced in the central portion of the caldera complex. The felsic Iricoumé magmatism is mainly composed of rhyolites, trachydacites and latites, with SiO₂ contents between 64 wt% and 80 wt%. The plutonic rocks from the Mapuera Suite present SiO₂ between 65 wt% and 77 wt%. Volcanic and granitic rocks present identical geochemical characteristics and that is attributed to their co-magmatic character. The felsic volcanic rocks and granites are metaluminous to slightly peraluminous and show affinity with silica-saturated alkaline series or with A-type magmas. They have Na₂O + K₂O between 6.6% and 10.4%, FeO^t/(FeO^t + MgO) varying between 0.76 and 0.99, Ga/Al ratios between 1.5 and 4.9, like typical A-type rocks; and plot in the within-plate or post-collisional fields in the (Nb + Y) vs. Rb diagram. The Nb/Y ratios indicate that these rocks are comparable to A2-type granites. This magmatism can be related to the (i) potassic alkaline series, with low Sr content in the felsic rocks explained by plagioclase fractionation at low pressure and high temperature or, alternatively, (ii) a bimodal association where magma had high crustal influence. The similarity of the Iricoumé felsic magmatism with A2-type granitoids and their high ETRL/Nb ratios suggest its relation with mantle sources previously modified by subduction, probably in a post-collision environment. Alternatively, this can be interpreted as bimodal within-plate magmatism with contamination by crustal melts. In this context, the extreme F, Nb and Zr enrichment of Madeira Suite could be explained by the presence of a thin crust which favored the presence and continuity of convective systems in the upper mantle.     

U–Pb zircon chronology,geochemistry and isotopes of the Changyi banded iron formation in the eastern Shandong Province: Constraints on BIF genesis and implications for Paleoproterozoic tectonic evolution of the North China Craton

The Changyi banded iron formation (BIF) in the eastern North China Craton (NCC) occurs within the Paleoproterozoic Fenzishan Group. The BIF shows alternating quartz-rich light and magnetite-rich dark bands with magnetite (15–65 vol.%), quartz (25–65 vol.%) and amphibole (15–30 vol.%) constituting the major minerals. Minor garnet, epidote, chlorite, calcite, biotite and pyrite occur locally. The BIF bands are interlayered with amphibolite, hornblende gneiss, biotite quartz schist, garnet biotite schist, biotite gneiss and leptynite, and are intruded by granites. LA-ICP-MS U–Pb dating on zircons separated from the BIF bands and the wallrocks constrains the depositional age as 2240–2193 Ma and metamorphic age as ~ 1864 Ma. The dominant composition of SiO₂ + Fe₂O₃^T (average value of 92.3 wt.%) of the BIF bands suggests their formation mainly through chemical precipitation. However, the widely varying contents of major elements such as Al₂O₃ (0.58–6.99 wt.%), MgO (1.00–3.86 wt.%), CaO (0.22–4.19 wt.%) and trace elements such as Rb (2.06–40.4 ppm), Sr (9.36–42.5 ppm), Zr (0.91–23.6 ppm), Hf (0.04–0.75 ppm), Cr (89.1–341 ppm), Co (2.94–30.4 ppm), and Ni (1.43–52.0 ppm) clearly indicate the incorporation of clastics, especially continental felsic clastics, as also confirmed by the presence of ancient detrital zircons in the BIF bands. When normalized against Post Archean Average Shale (PAAS), the seawater-like signatures of REE distribution patterns, such as LREE depletion, positive La and Y anomalies, and superchondritic Y/Ho ratios (average value of 36.3), support the deposition in seawater. Strong positive Eu anomalies (Eu/Eu*_PAAS = 1.14–2.86) also suggest the participation of hydrothermal fluids. In addition, the sympathetic correlation between Cr, Co and Ni as well as the Co + Ni + Cu vs. ∑ REE and the Al₂O₃ vs. SiO₂ relations further indicates that the iron and silica mainly originated from hydrothermal fluids. Combined with regional geological investigation and protolith restoration of the wallrocks, a continental rift environment is suggested for the Changyi BIF deposition. The appearance of negative Ce_PAAS anomalies might suggest the influence of the Great Oxidation Event at the time of deposition. The Changyi BIF witnessed the major Paleoproterozoic rifting–collision events in the NCC and their unique distribution in the NCC contrasts with other examples elsewhere in the world.