New 40Ar/39Ar ages for selected young (<1 Ma) basalt flows of the Newer Volcanic Province,southeastern Australia

The Pliocene-Holocene Newer Volcanic Province (NVP) of southeastern Australia is an extensive, relatively well-preserved, intra-plate basaltic lava field containing more than 400 eruptive centres. This study reports new, high-precision ⁴⁰Ar/³⁹Ar ages for six young (300–600 ka) basalt flows from the NVP and is part of a broader initiative to constrain the extent, duration, episodicity and causation of NVP volcanism. Six fresh, holocrystalline alkali basalt flows were selected from the Warrnambool-Port Fairy area in the Western Plains sub-province for ⁴⁰Ar/³⁹Ar dating. These flows were chosen on the basis of pre-existing K-Ar age constraints, which, although variable, indicated eruption during a period of apparent relative volcanic quiescence (0.8–0.06 Ma).⁴⁰Ar/³⁹Ar ages were measured on multiple aliquots of whole rock basalt samples. Three separate flows from the Mount Rouse volcanic field yielded concordant ⁴⁰Ar/³⁹Ar age results, with a mean eruption age of 303 ± 13 ka (95% CI). An older weighted mean age of 382 ± 24 ka (2σ) was obtained for one sample from the central Rouse-Port Fairy Flow, suggesting extraneous argon contamination. Two basalt flows from the Mount Warrnambool volcano also yielded analogous results, with an average ⁴⁰Ar/³⁹Ar age of 542 ± 17 ka (95% CI). The results confirm volcanic activity during the interval of relative quiescence. Most previous K-Ar ages for these flows are generally older than the weighted mean ⁴⁰Ar/³⁹Ar ages, suggesting the presence of extraneous ⁴⁰Ar. This study demonstrates the suitability of the ⁴⁰Ar/³⁹Ar incremental-heating method to obtain precise eruption ages for young, holocrystalline alkali basalt samples in the NVP.     

40Ar/39Ar ages for the alkaline volcanism and the basement of Gorringe Bank,North Atlantic ocean

Gorringe Bank is situated on the Europe-Africa plate boundary at the eastern end of the Azores-Gibraltar fracture zone. It has two summits, Gettysburg Bank to the Southwest and Ormonde Bank to the northeast.We applied the⁴⁰Ar/³⁹Ar stepwise heating method to date six samples of the alkaline volcanic rocks, two gabbros from the Ormonde Bank and a dolerite from the Gettysburg Bank. The results that the alkaline volcanism lasted probably for less than 6 Ma(66-60 Ma).Although the nature of this volcanism precludes any subduction feature during its setting, the alkaline volcanism of Ormonde is probably linked to Upper Cretaceous/Eocene compressive tectonic events.The basement rocks of Gorringe Bank reveal distrubed⁴⁰Ar/³⁹Ar age spectra. One plagioclase and one biotite from a gabbro give evidence for a thermic event whose age is tentatively estimated at about 75 Ma, and related to a variation in the direction of the relative movement between Europe and Africa. The more probable age given by a plagioclase of another gabbro and by a dolerite (110 Ma) corresponds to tilting northeastward of the Gorringe massif.     

Ar/Ar geochronology of Neogene phreatomagmatic volcanism in the western Pannonian Basin,Hungary

Neogene alkaline basaltic volcanic fields in the western Pannonian Basin, Hungary, including the Bakony–Balaton Highland and the Little Hungarian Plain volcanic fields are the erosional remnants of clusters of small-volume, possibly monogenetic volcanoes. Moderately to strongly eroded maars, tuff rings, scoria cones, and associated lava flows span an age range of ca. 6 Myr as previously determined by the K/Ar method. High resolution ⁴⁰Ar/³⁹Ar plateau ages on 18 samples have been obtained to determine the age range for the western Pannonian Basin Neogene intracontinental volcanic province. The new ⁴⁰Ar/³⁹Ar age determinations confirm the previously obtained K/Ar ages in the sense that no systematic biases were found between the two data sets. However, our study also serves to illustrate the inherent advantages of the ⁴⁰Ar/³⁹Ar technique: greater analytical precision, and internal tests for reliability of the obtained results provide more stringent constraints on reconstructions of the magmatic evolution of the volcanic field. Periods of increased activity with multiple eruptions occurred at ca. 7.95 Ma, 4.10 Ma, 3.80 Ma and 3.00 Ma.     

Reconstruction of the volcanic history of the Tacámbaro-Puruarán area (Michoacán, México) reveals high frequency of Holocene monogenetic eruptions

The 690?km² Tacámbaro-Puruarán area located at the arc-front part of the Michoácan-Guanajuato volcanic field in the Trans-Mexican Volcanic Belt (TMVB) records a protracted history of volcanism that culminated with intense monogenetic activity in the Holocene. Geologic mapping, ⁴⁰Ar/³⁹Ar and ¹⁴C radiometric dating, and whole-rock chemical analyses of volcanic products provide insights to that history. Eocene volcanics (55–40?Ma) exposed at uplifted blocks are related to a magmatic arc that preceded the TMVB. Early TMVB products are represented by poorly exposed Pliocene silicic domes (5–2?Ma). Quaternary (<2?Ma) volcanoes (114 mapped) are mainly scoria cones with lavas (49 vol.%), viscous lava flows (22 vol.%), and lava shields (22 vol.%). Erupted products are dominantly either basaltic andesites (37 vol. %), or andesites (17 vol.%), or span across both compositions (28 vol.%). Basalts (9 vol.%), dacites (4 vol.%), shoshonites (2 vol.%), and other alkali-rich rocks (<3 vol.%) occur subordinately. Early-Pleistocene volcanism was bimodal (dacites and basalts) and voluminous while since 1?Ma small-volume eruptions of intermediate magmas have dominated. Higher rates of lithospheric extension in the Quaternary may have allowed a larger number of small, poorly evolved dikes to reach the surface during this period. Eruptive centers as old as 1.7?Ma are aligned in a NE direction parallel to both, basement faults and the direction of regional compressive stress, implying structural control on volcanic activity. Data suggest that volcanism was strongly pulsatory and fed by localized low-degree partial melting of mantle sources. In the Holocene, at least 13 eruptions occurred (average recurrence interval of 800?years). These produced ~3.8?km³ of basaltic andesitic to andesitic magma and included four eruptions dated at ~1,000; 4,000; 8,000; and 11,000?years bc (calibrated ¹⁴C ages). To date, this is one of the highest monogenetic eruption frequencies detected within such a small area in a subduction-related arc-setting. These anomalous rates of monogenetic activity in an area with thick crust (>30?km) may be related to high rates of magma production at depth and a favorable tectonic setting.     

The Early Andean Magmatic Province (EAMP): 40Ar/39Ar dating on Mesozoic volcanic and plutonic rocks from the Coastal Cordillera,northern Chile

The Early Andean Magmatic Province (EAMP), consists of about 150 000 km³ of volcanic and plutonic units in the Coastal Cordillera of northern Chile and southern Peru and represents a major magmatic Mesozoic event in the world, for which the precise age of the thick volcanic series was unknown.Thirty ⁴⁰Ar/³⁹Ar analyses were carried out on primary mineral phases of volcanic and plutonic rocks from northern Chile (18°30′–24°S). Reliable plateau and “mini plateau” ages were obtained on plagioclase, amphibole and biotite from volcanic and plutonic rocks, despite widespread strong alteration degree. In the Arica, Tocopilla and Antofagasta (700 km apart) regions, the ages obtained on lava flows constrain the volcanic activity between 164 and 150 Ma and no N–S migration of volcanism is observed. The uppermost lava flows of the volcanic sequence at the type locality of the La Negra Formation extruded at ca. 153–150 Ma, suggesting the end of the volcanic activity of the arc at that time. The oldest volcanic activity occurred probably at ca. 175–170 Ma in the Iquique area, although no plateau age could be obtained.The plutonic bodies of the same regions were dated between ca. 160 and 142 Ma, indicating that they were partly contemporaneous with the volcanic activity. At least one volcanic pulse around 160 Ma is evidenced over the entire investigated reach of the EAMP, according to the ages found in Arica, Tocopilla, Michilla and Mantos Blancos regions.The episodic emplacement of huge amounts of subduction related volcanism is observed throughout the whole Andean history and particularly during the Jurassic (southern Peru, northern Chile and southern Argentina). These events probably correspond to periodic extensional geodynamic episodes, as a consequence of particular subduction conditions, such as change of obliquity of the convergence, change in the subduction angle, slab roll back effect or lower convergence rate, that remain to be precisely defined.     

The timing and extent of the eruption of the Siberian Traps large igneous province: Implications for the end-Permian environmental crisis

We present new high-precision ⁴⁰Ar/³⁹Ar ages on feldspar and biotite separates to establish the age, duration and extent of the larger Siberian Traps volcanic province. Samples include basalts and gabbros from Noril'sk, the Lower Tunguska area on the Siberian craton, the Taimyr Peninsula, the Kuznetsk Basin, Vorkuta in the Polar Urals, and from Chelyabinsk in the southern Urals. Most of the ages, except for those from Chelyabinsk, are indistinguishable from those found at Noril'sk. Cessation of activity at Noril'sk is constrained by a ⁴⁰Ar/³⁹Ar age of 250.3 ± 1.1 Ma for the uppermost Kumginsky Suite.The new ⁴⁰Ar/³⁹Ar data confirm that the bulk of Siberian volcanism occurred at 250 Ma during a period of less than 2 Ma, extending over an area of up to 5 million km². The resolution of the data allows us to confidently conclude that the main stage of volcanism either immediately predates, or is synchronous with, the end-Permian mass extinction, further strengthening an association between volcanism and the end-Permian crisis. A sanidine age of 249.25 ± 0.14 Ma from Bed 28 tuff at the global section and stratotype at Meishan, China, allows us to bracket the P–Tr boundary to 0.58 ± 0.21 myr, and enables a direct comparison between the ⁴⁰Ar/³⁹Ar age of the Traps and the Permo–Triassic boundary section.Younger ages (243 Ma) obtained for basalts from Chelyabinsk indicate that volcanism in at least the southern part of the province continued into the Triassic.     

Holocene volcanic activity in Anjouan Island (Comoros archipelago) revealed by new Cassignol-Gillot groundmass K–Ar and 14C ages

The Comoros archipelago has attracted renewed attention since 2018 due to the submarine volcano growing east of the island of Mayotte and the associated ongoing seismic crisis. However, the origin of Comorian magmatism remains controversial, as it is either interpreted as related to a hotspot trail, to a fracture zone, or to a plate boundary. Lying in the central part of the archipelago, Anjouan is a key island to better understand the relationship between volcanism and geodynamics. Together with a careful selection of published whole-rock K–Ar ages, our new set of 13 groundmass K–Ar ages on lava flows and one radiocarbon age on a charcoal from a strombolian deposit, allow us to reassess the volcano-tectonic evolution of Anjouan Island. New groundmass K–Ar ages lie within the last 1 Ma, i.e. from 899 ± 14 to 11 ± 1 ka. They suggest that most of the subaerial volcanism in Anjouan is much younger than previously inferred, and occurred as pulses at 900–750 ka, perhaps 530 ka, 230–290 ka, and since 60 ka, with erosional periods in between. Among our new data, one ¹⁴C age of 7513–7089 yrs calBCE (9.3 ± 0.2 ka) and five K–Ar ages younger than 60 ka show that recent volcanism occurred in Anjouan. Moreover, the concentration of eruptive vents along a N150° alignment, parallel to the maximum horizontal stress, suggests a strong link between regional tectonics and volcanism. Considering the presence of active volcanoes on both the western and eastern extremities of the Comoros archipelago, our discovery of Holocene activity on Anjouan provides strong arguments against a chronological progression of volcanism along the archipelago, and therefore contradicts the hotspot hypothesis for the origin of volcanism.Finally, this study provides a robust geochronological timeframe of the different volcanic stages of Anjouan. It demonstrates that Anjouan is an active island and suggests that volcanism and tectonics can both resume at any time.     

Structure and evolution of the Rockeskyllerkopf Volcanic Complex, West Eifel Volcanic Field, Germany

The Rockeskyllerkopf Volcanic Complex (RVC) comprises three overlapping monogenetic volcanic centers: Southeast Lammersdorf (SEL), Mäuseberg (M) and Rockeskyllerkopf (RKK). Each volcanic center comprises proximal wall deposits with a well defined crater wall unconformity and crater fill deposits that partially to completely cover the outer crater wall. The SEL Center is a phreatomagmatic tuff ring composed of lithic rich tephra deposited by pyroclastic falls and surges. The second center, Mäuseberg, with its crater to the northwest of the SEL Center is predominantly magmatic. Topographic and outcrop patterns suggest that this center may have formed a series of overlapping scoria cones along a N–S trending fissure. The youngest center, RKK, which lies on a poorly developed palaeosol within the earlier Mäuseberg deposits, comprises a well developed proximal crater wall sequence. This sequence of magmatic, likely Strombolian, fall and grain avalanche deposits passes upward into a crater fill sequence that comprises variably welded bombs. The final eruptions in the center were massive lava flows that were ponded within the RKK crater. Ar–Ar age dating of reequilibrated fragments of phlogopite megacrysts in the SEL lavas indicates volcanic activity began at 474?±?39 ka. Literature K–Ar dates for the youngest lava flows in the RKK Center give ages of 360?±?60 to 470 ka. Our interpretation of the age data and the presence of the poorly developed palaeosol between the Mäuseberg and RKK centers indicates that volcanism in the RVC began around 470 ka with the eruption of the SEL and Mäuseberg centers followed a few thousand years later by the eruption of the RKK Center.     

Geology,geochronology and tectonic setting of late Cenozoic volcanism along the southwestern Gulf of Mexico: The Eastern Alkaline Province revisited

A NNW-trending belt of alkaline mafic volcanic fields parallels the Gulf of Mexico from the U.S. border southward to Veracruz state, in eastern Mexico. Previous studies grouped this volcanism into the so-called “Eastern Alkaline Province” (EAP) and suggested that it resulted from Gulf-parallel extensional faulting migrating from north to south from Oligocene to Present. On the basis of new geologic studies, forty-nine unspiked K–Ar and two ⁴⁰Ar–³⁹Ar ages, we propose a new geodynamic model for the volcanism along the southwestern Gulf of Mexico.We studied in detail four of the six recognized fields of mafic alkaline volcanism in Veracruz state: 1) The lavas flows of Tlanchinol area (7.3–5.7 Ma), 2) the Alamo monogenetic field and Sierra de Tantima (7.6–6.6 Ma), 3) the Poza Rica and Metlatoyuca lava flows (1.6–1.3 Ma) and 4) the Chiconquiaco–Palma Sola area (6.9–3.2 Ma). Other two mafic volcanic fields may represent the continuation of alkaline volcanism to the southeast: the Middle Miocene lavas at Anegada High, offshore port of Veracruz, and the Middle to Late Miocene volcanism at the Los Tuxtlas.The existence of major Neogene extensional faults parallel to the Gulf of Mexico (i.e., ∼N–S to NNW–SSE) proposed in previous works was not confirmed by our geological studies. Elongation of volcanic necks, vent alignment, and faults mapped by subsurface data trend dominantly NE to ENE and NW to NNW. These directions are parallel to transform and normal faults that formed during the Late Jurassic opening of the Gulf of Mexico. Ascent of mafic magmas was likely facilitated and controlled by the existence of these pre-existing basement structures.Coupled with previous studies, our data demonstrate the occurrence of three magmatic episodes in Veracruz: 1) A Middle Miocene (∼15–11 Ma) episode in southern Veracruz (Palma Sola, Anegada, and Los Tuxtlas); 2) A Late Miocene to Early Pliocene (∼7.5–3 Ma) pulse of mafic alkaline volcanism throughout the study region; and 3) A Late Pliocene to Quaternary transitional to calc–alkaline volcanism in southern Veracruz (Palma Sola, Los Tuxtlas). Whereas the first and third episodes may be considered part of the subduction-related Trans-Mexican Volcanic Belt, the second pulse of mafic alkaline volcanism has a more complex origin. The absence of significant extensional faulting precludes a rift origin. We favor a model in which a transient thermal anomaly and melting of the mantle was triggered by the tearing and detachment of part of the subducted slab.     

New data on the Late Cenozoic basaltic volcanism in Syria,applied to its origin

New data on geology and 21 K–Ar dates of the Late Oligocene–Quaternary basalts in Syria, combined with analysis of the new and previous data are used to reconstruct the volcanic history and relations between it and tectonic events. Volcanism began at the end of Oligocene (26–24 Ma) and was concentrated in the Late Oligocene–Early Miocene along a N-trending band, which stretches from the Jebel Arab (Harrat Ash Shaam) up to Kurd Dagh and southern Turkey. Activity waned in the Middle Miocene (17–12 Ma), but was resumed in the same band in the Tortonian and increased in the Messinian and Early Pliocene (6.3–4 Ma), when volcanism spread to the Shin Plateau and its coastal extension. After a brief hiatus ～ 4–3.5 Ma, volcanism became still more intensive and spread from the N-trending band to the east into the northern margin of the Mesopotamian Foredeep and to the west into the Dead Sea Transform zone. Additional eruptions continued into the Holocene.Volcanism lasted > 25 million years in the Jebel Arab Highland and > 15 million years in the Aleppo Plateau. The long duration of volcanism in the same parts of the moving Arabian plate and absence of records of one-way migration of the activity mean that the magmatic sources moved together with the plate, i.e., they were situated within the lithosphere mantle. Coincidence of the tectonic and volcanic stages of the Arabian plate development proves that volcanic activity depended on the geodynamic situation, caused by the plate motion. Situated within the lithosphere, magmatic sources within this transverse band were possibly caused by thermal and deforming influences of the asthenospheric lateral flow, moved laterally from the Ethiopia–Afar deep superplume.     

40Ar/39Ar constraints on the temporal evolution of Graciosa Island, Azores (Portugal)

Lava flows spanning the eruptive record of Graciosa Island (Azores archipelago) and a gabbro xenolith were dated by ⁴⁰Ar/³⁹Ar in order to constrain the Pleistocene and Holocene volcanic evolution of the island. The results range from 1.05 Ma to 3.9 ka, whereas prior published K–Ar and ¹⁴C ages range from 620 to 2 ka. The formation of the Serra das Fontes shield volcano started at minimum 1.05 Ma, and the magmatic system was active for ca. 600 ky, as suggested by the formation of the gabbro xenolith by magmatic differentiation. Evolved magmas making up the Serra das Fontes–Serra Branca composite volcano were generated at ca. 450 ka. After a period of ca. 110 ky of volcanic inactivity and erosion of volcanic edifices, volcanism was reactivated with the formation of the Vitória Unit NW platform. Later, the development of the Vulcão Central Unit started with the formation of monogenetic cones located to the south of the Serra das Fontes–Serra Branca–Vitória Unit. This volcanism became progressively more evolved and was concentrated in a main eruptive center, forming the Vulcão Central stratovolcano with an age older than 50 ka. The caldera related to this stratovolcano is older than 47 ka and was followed by effusion of basaltic magmas into the caldera, resulting in the formation of a lava lake, which ultimately spilled over the caldera rim at ca. 11 ka. The most recent eruptions on Graciosa formed two small pyroclastic cones within the caldera and the Pico do Timão cone within the Vitória Unit at ca 3.9 ka.     

New age constraints on the timing of volcanism and tectonism in the northern Main Ethiopian Rift–southern Afar transition zone (Ethiopia)

Forty new K-Ar and ⁴⁰Ar/³⁹Ar isotopic ages from the northern Main Ethiopian Rift (MER)–southern Afar transition zone provide insights into the volcano-tectonic evolution of this portion of the East African Rift system. The earliest evidence of volcanic activity in this region is manifest as 24–23 Ma pre-rift flood basalts. Transition zone flood basalt activity renewed at approximately 10 Ma, and preceded the initiation of modern rift margin development. Bimodal basalt–rhyolite volcanism in the southern Afar rift floor began at approximately 7 Ma and continued into Recent times. In contrast, post-subsidence volcanic activity in the northern MER is dominated by Mio-Pliocene silicic products from centers now covered by Quaternary volcanic and sedimentary lithologies. Unlike other parts of the MER, Mio-Pliocene silicic volcanism in the MER–Afar transition zone is closely associated with fissural basaltic products. The presence of Pliocene age ignimbrites on the plateaus bounding the northern MER, whose sources are found in the present rift, indicates that subsidence of this region was gradual, and that it attained its present physiography with steep escarpments only in the Plio-Pleistocene. Large 7–5 Ma silicic centers along the southern Afar and northeastern MER margins apparently formed along an E–W-oriented regional structural feature parallel to the already established southern escarpment of the Afar. The Addis Ababa rift embayment and the growth of 4.5–3 Ma silicic centers in the Addis Ababa area are attributed to the formation of a major cross-rift structure and its intersection with the same regional E–W structural trend. This study illustrates the episodic nature of rift development and volcanic activity in the MER–Afar transition zone, and the link between this activity and regional structural and tectonic features.     

Volcanism in the earliest stage of back-arc rifting in the Izu-Bonin arc revealed by laser-heating Ar/Ar dating

The back-arc region of the Izu-Bonin arc has complex bathymetric and structural features, which, due to repeated back-arc rifting and resumption of arc volcanism, have prevented us from understanding the volcano-tectonic history of the arc after 15 Ma. The laser-heating ⁴⁰Ar/³⁹Ar dating technique combined with high density sampling of volcanic rocks from the back-arc region of this arc successfully revealed the detailed temporal variation of volcanism related to the back-arc rifting. Based on the new ⁴⁰Ar/³⁹Ar dating results: (1) Back-arc rifting initiated at around 2.8 Ma in the middle part of the Izu-Bonin arc (30°30′N–32°30′N). Volcanism at the earliest stage of rifting is characterized by the basaltic volcanism from north–south-trending fissures and/or lines of vents. (2) Following this earliest stage of volcanism, at ca. 2.5 Ma, compositionally bimodal volcanism occurred and formed small cones in the wide area. This volcanism and rifting continued until about 1 Ma in the region west of the currently active rift zone. (3) After 1 Ma, active volcanism ceased in the area west of the currently active rift zone, and volcanism and rifting were confined to the currently active rift zone. The volcano-tectonic history of the back-arc region of the Izu-Bonin arc is an example of the earliest stage of back-arc rifting in the oceanic island arc. Age data on volcanics clearly indicate that volcanism changed its mode of activity, composition and locus along with a progress of rifting.     

The Llullaillaco volcano, northwest Argentina: construction by Pleistocene volcanism and destruction by sector collapse

Llullaillaco is one of a chain of Quaternary stratovolcanoes that defines the present Andean Central Volcanic Zone (CVZ), and marks the border between Chile and Argentina/Bolivia. The current edifice is constructed from a series of thick dacitic lava flows, forming the second tallest active volcano in the world (6739 m). K–Ar and new biotite laser ⁴⁰Ar/³⁹Ar step-heating dates indicate that the volcano was constructed during the Pleistocene (≤1.5 Ma), with a youngest date of 0.048±0.012 Ma being recorded for a fresh dacite flow that descends the southern flank. Additional ⁴⁰Ar/³⁹Ar measurements for andesitic and dacitic lava flows from the surrounding volcanic terrain yield dates of between 11.94±0.13 Ma and 5.48±0.07 Ma, corresponding to an extended period of Miocene volcanism which defines much of the landscape in this region. Major- and trace-element compositions of lavas from Llullaillaco are typical of Miocene–Pleistocene volcanic rocks from the western margin of the CVZ, and are related to relatively shallow-dipping subduction of the Nazca plate beneath northern Chile and Argentina.Oversteepening of the edifice by stacking of thick, viscous, dacitic lava flows resulted in collapse of its southeastern flank to form a large volcanic debris avalanche. Biotite ⁴⁰Ar/³⁹Ar dating of lava blocks from the avalanche deposit indicate that collapse occurred at or after 0.15 Ma, and may have been triggered by extrusion of a dacitic flow similar to the one dated at 0.048±0.012 Ma. The avalanche deposits are exceptionally well preserved due to the arid climate, and prominent levées, longitudinal ridges, and megablocks up to 20-m diameter are observed.The avalanche descended 2.8 km vertically, and bifurcated around an older volcano, Cerro Rosado, before debouching onto the salt flats of Salina de Llullaillaco. The north and south limbs of the avalanche traveled 25 and 23 km, respectively, and together cover an area of approximately 165 km². Estimates of deposit volume are hampered by a lack of thickness information except at the edges, but it is likely to be between 1 and 2 km³. Equivalent coefficients of friction of 0.11 and 0.12, and excess travel distances of 20.5 and 18.5 km, are calculated for the north and south limbs, respectively. The avalanche ascended 400 m where it broke against the western flank of Cerro Rosado, and a minimum flow velocity of 90 m s⁻¹ can be calculated at this point; lower velocities of 45 m s⁻¹ are calculated where distal toes ascend 200 m slopes.It is suggested that the remaining precipitous edifice has a high probability for further avalanche collapse in the event of renewed volcanism.     

Magmatic evolution of the Puyehue–Cordón Caulle Volcanic Complex (40° S), Southern Andean Volcanic Zone: From shield to unusual rhyolitic fissure volcanism

Magmas erupted from Quaternary volcanoes of Southern Andes between 37° and 46° S latitude are mainly basaltic to andesitic. However, PCCVC (40° S) shows a singular magmatic evolution due to the abnormal evacuation of rhyolites, especially in the last 100 ka. In addition, PCCVC is the result of juxtaposing products from the NW-trending alignment of Cordillera Nevada caldera, Cordón Caulle fissure volcano and the Puyehue stratocone. Using ⁴⁰Ar/³⁹Ar and ¹⁴C geochronology it can be established that they evolved since ca. 500 ka as coeval but separated vents with a first stage of shield volcanism, followed by repeated collapses that formed an internal NW-elongated graben. From ca. 100 ka, volcanic activity occurred in both a fissure system (Cordón Caulle) and a central volcano (Puyehue). Holocene explosive eruptions, mainly in the Puyehue crater, accompanied the dome growing along a NW-trending fissure system. Last historical eruptions were in 1921 and 1960 when NW fissures of Cordón Caulle fed rhyodacitic lava flows. In 1960, the fissure eruption was triggered by a remote Mw: 9.5 thrust earthquake.Cordillera Nevada caldera presents a reduced compositional range (52–63% SiO₂) and geochemical features of low-pressure magma mixing and assimilation. Instead, Cordón Caulle and Puyehue volcanoes have a wide silica range (48–71% SiO₂) and an outstanding affinity, which can be modelled with initial high-pressure fractional crystallization, moderate magma mixing and subsequent low-pressure fractional crystallization from a common parental source.The exceptional magmatic evolution and eruptive style of PCCVC in Southern Andes could be related with the physics of the plumbing system, which in turn can be controlled by external factors as the structure of the continental crust and the ongoing stress regime.     

Laser-ablation ICP-MS zircon U-Pb ages for key Pliocene-Pleistocene tephra beds in unglaciated Yukon and Alaska

Tephrochronology is one of the most effective ways to correlate and date Quaternary deposits across large distances. However, it can be challenging to obtain direct ages on tephra beds when they are beyond the limit of radiocarbon dating, do not contain mineral phases suitable for ⁴⁰K-⁴⁰Ar (or ⁴⁰Ar/³⁹Ar) dating, or suitable glass shards for fission-track dating are not available. Zircon U-Pb dating by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging technique for dating young (<1 Ma) tephra. Here, we demonstrate that LA-ICP-MS zircon U-Pb dating can produce reliable ages for key tephra beds found in Yukon and Alaska. We assessed five different techniques for calculating tephra maximum depositional ages from zircon U-Pb ages for eight tephra beds. Our preferred zircon U-Pb ages (reported with 2σ uncertainties), based on a Bayesian model for calculating maximum depositional ages, are broadly consistent with previously established chronology constructed from stratigraphy, paleomagnetism, and/or glass fission track and ⁴⁰Ar/³⁹Ar ages: Biederman tephra (178 ± 17 ka), HP tephra (680 ± 47 ka), Gold Run tephra (688 ± 44 ka), Flat Creek tephra (708 ± 43 ka), PA tephra (1.92 ± 0.06 Ma), Quartz Creek tephra (2.62 ± 0.08 Ma), Lost Chicken tephra (3.14 ± 0.07 Ma), and GI tephra (542 ± 64 ka). We also present newly revised glass fission-track and ⁴⁰Ar/³⁹Ar ages recalculated from previous determinations using updated ages for the Moldavite tektite and Fish Canyon Tuff standards, and updated K decay constants. For Pleistocene age zircon crystals, corrections for ²³⁰Th disequilibrium and common-Pb are significant and must be treated with caution. Similarly, apparent tephra ages are sensitive to the choice of method used to calculate a maximum depositional age from the assemblage of individual crystallization ages. This study demonstrates that LA-ICP-MS zircon U-Pb dating can be successfully applied to numerous Pliocene-Pleistocene Alaskan-Yukon tephra, providing confidence in applying this method to other stratigraphically important tephra in the region.     

Surface exposure dating of Holocene basalt flows and cinder cones in the Kula volcanic field (Western Turkey) using cosmogenic 3He and 10Be

The Kula volcanic field in Western Turkey comprises about 80 cinder cones and associated basaltic lava flows of Quaternary age. Based on geomorphological criteria and K-Ar dating, three eruption phases, β2–β4, were distinguished in previous studies. Human footprints in ash deposits document that the early inhabitants of Anatolia were affected by the volcanic eruptions, but the age of the footprints has been poorly constrained. Here we use ³He and ¹⁰Be exposure dating of olivine phenocrysts and quartz-bearing xenoliths to determine the age of the youngest lava flows and cinder cones. In the western part of the volcanic field, two basalt samples from a 15-km-long block lava flow yielded ³He ages of 1.5 ± 0.3 ka and 2.5 ± 0.4 ka, respectively, with the latter being in good agreement with a ¹⁰Be age of 2.4 ± 0.3 ka for an augen gneiss xenolith from the same flow. A few kilometers farther north, a metasedimentary xenolith from the top of the cinder cone Çakallar Tepe gave a ¹⁰Be age of 11.2 ± 1.1 ka, which dates the last eruption of this cone and also the human footprints in the related ash deposits. In the center of the volcanic field, a basalt sample and a metasedimentary xenolith from another cinder cone gave consistent ³He and ¹⁰Be ages of 2.6 ± 0.4 ka and 2.6 ± 0.3 ka, respectively. Two β4 lava flows in the central and eastern part of the volcanic province yielded ³He ages of 3.3 ± 0.4 ka and 0.9 ± 0.2 ka, respectively. Finally, a relatively well-preserved β3 flow gave a ³He age of ∼13 ka. Taken together, our results demonstrate that the penultimate eruption phase β3 in the Kula volcanic field continued until ∼11 ka, whereas the youngest phase β4 started less than four thousand years ago and may continue in the future.     

K/Ar dates of hydrothermal clays from core hole VC-2B, Valles caldera, New Mexico and their relation to alteration in a large hydrothermal system

Seventeen K/Ar dates were obtained on illitic clays within Valles caldera (1.13 Ma) to investigate the impact of hydrothermal alteration on Quaternary to Precambrian intracaldera and pre-caldera rocks in a large, long-lived hydrothermal system ( 1.0 Ma to present). Clay samples came from scientific core hole VC-2B (295°C at 1762 m) which was spudded in the Sulphur Springs thermal area and drilled into the boundary between the central resurgent dome and the western ring-fracture zone. Six illitic clays within Quaternary caldera-fill debris flow, tuffaceous sediment, and ash-flow tuff (48 to 587 m depth) yield ages from 0.35 to 1.09 Ma. Illite from Miocene pre-caldera sandstone (765 m) gives an age of 6.74 Ma. Two dates on illite from sandstones in Permian red beds (1008 and 1187 m) are 4.33 and 4.07 Ma, respectively. Surprisingly, three dates on illites from altered andesite pebbles within the red beds (1010–1014 m) are 0.95 to 1.06 Ma. Four illite dates on variably altered Precambrian quartz monzonite (1615–1762 m) range from 2.90 to 276 Ma.Post-Valles age illite is not correlated with alteration style (argillic to propylitic). Rather, post-Valles ages are uniformly obtained from illites in highly fractured, intensely altered, caldera-fill rocks and the Permian volcanic clasts. Generally, finer clay fractions from identical samples yield younger ages. Plots of ⁴⁰Ar/³⁶Ar versus ⁴⁰K/³⁶Ar and ⁴⁰Ar* versus ⁴⁰K for the illites in caldera-fill rocks lie close to a 1-Ma isochron. Most illite dates older than Valles caldera are difficult to interpret because they correspond to the ages of pre-Valles volcanic and hydrothermal episodes in the Jemez volcanic field ( 13 Ma). In addition, older dates may be caused by co-mingling of different illites during sample preparation, or by inherited argon or lost argon in illites from rocks with potentially complex hydrothermal histories. However, the range of ages obtained from illites in Permian sands and pebbles and from Precambrian crystalline rocks indicates that Valles hydrothermal activity is overwhelming illite produced by earlier geologic events.     

Volcanology and petrology of Mathews Tuya,northern British Columbia,Canada: glaciovolcanic constraints on interpretations of the 0.730 Ma Cordilleran paleoclimate

Petrological, volcanological and geochronological data collected at Mathews Tuya together provide constraints on paleoclimate conditions during formation of the edifice. The basaltic tuya was produced via Pleistocene glaciovolcanism in northern British Columbia, Canada, and is located within the Tuya volcanic field (59.195°N/130.434°W), which is part of the northern Cordilleran volcanic province (NCVP). The edifice comprises a variety of lithofacies, including columnar-jointed lava, pillow lava, massive dikes, and volcaniclastic rocks. Collectively these deposits record the transition from an explosive subaqueous to an effusive subaerial eruption environment dominated by Pleistocene ice. As is typical for tuyas, the volcaniclastic facies record multiple fragmentation processes including explosive, quench and mechanical fragmentation. All samples from Mathews Tuya are olivine-plagioclase porphyritic alkali olivine basalts. They are mineralogically and geochemically similar to nearby glaciovolcanic centers from the southeastern part of the Tuya volcanic field (e.g., Ash Mountain, South Tuya, Tuya Butte) as well as the dominant NCVP rock type. Crystallization scenarios calculated with MELTS account for variations between whole rock and glass compositions via low pressure fractionation. The presence of olivine microphenocrysts and the absence of pyroxene phenocrysts constrain initial crystallization pressures to less than 0.6 GPa. The eruption of Mathews Tuya occurred between 0.718 ± 0.054 Ma and 0.742 ± 0.081 Ma based on ⁴⁰Ar/³⁹Ar geochronology (weighted mean age of 0.730 Ma). The age determinations provide the first firm documentation for large (>700 m thick), pre-Fraser/Wisconsin glaciers in north-central British Columbia ~0.730 Ma, and correlate in age with glaciovolcanic deposits in Russia (e.g., Komatsu et al. Geomorph 88: 352-366, 2007) and with marine isotopic evidence for large global ice volumes ~0.730 Ma.     

Ar–Ar geochronology of Santo Antão, Cape Verde Islands

Santo Antão, the northernmost island of the Cape Verde Archipelago, consists entirely of silica-undersaturated volcanic products and minor intrusions. ⁴⁰Ar–³⁹Ar incremental heating experiments have been carried out on 24 samples that cover the entire exposed chronological sequence. The oldest lavas (7.57±0.56 Ma), representing an older volcanic basement, are exposed about 620 m above mean sea level. After an interval of quiescence of up to 4.3 Ma the volcanic activity resumed and continued at low eruption rates. The older basement is unconformably overlain by a ca. 810-m-thick lava sequence that spans an age range from 2.93±0.03 to 1.18±0.01 Ma. This sequence is cut by many dykes and sills. Simultaneous volcanic activity occurred in the northeastern, central and eastern part of the island. A phonolitic pumice deposit that forms a noteworthy feature over most of the island has an estimated age of 0.20 Ma. This predates volcanic activity that formed the highest point of the island (Tope de Coroa) which has an age of 0.17±0.02 Ma. The most recent eruption on the island formed nephelinitic lavas in the Porto Novo region at 0.09±0.03 Ma. The oldest volcanism exposed on Santo Antão, which took place about 7.6 Ma ago, was simultaneous with waning activity on Maio at the eastern end of the Cape Verde Archipelago.