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1.
Linear domains of deformed alkaline rocks and carbonatites have recently been identified as representing sites of ancient suture zones. In peninsular India, the western margin of the Proterozoic Eastern Ghats Belt (EGB) is characterized by a series of alkaline plutons that are aligned close to the contact with the Archaean Craton. Most of the complexes were deformed and metamorphosed during a subsequent orogenic event. Unlike other plutons in the belt, the alkaline complex at Koraput reportedly escaped deformation and granulite facies metamorphism forming an anomalous entity within the zone. Multiply-deformed country rocks hosting this complex underwent syn-D1CR granulite facies metamorphism followed by D2CR thrusting, with pervasive shearing along a NE-SW trending foliation. A second granulite facies event followed localized D3CR shearing. Within the Koraput Complex, strain partitioning was responsible for preserving igneous textures in the gabbroic core, but aligned magmatic amphibole needles and plagioclase laths occasionally define a S1AC fabric. Along the margins, S1AC is rotated parallel to a NE-trending, east-dipping S2AC fabric in the gabbro, fringing syenodiorite and nepheline syenite bands. Locally, D3AC shearing follows D2AC deformation; S2AC and S3AC parallel S2CR and S3CR in the country rocks. High-grade metamorphism represented by recrystallization of amphibole and plagioclase, and breakdown of amphibole and biotite to garnet, pyroxene and K-feldspar in the complex follows D3AC. Unlike earlier reports, therefore, the Koraput body is also deformed and metamorphosed. The aligned alkaline complexes in the EGB probably represent deformed alkaline rocks and carbonatites formed by rifting related to an earlier episode of continental break-up that were deformed during subsequent juxtaposition of the EGB with the Archaean Craton. This supports the contention that the western margin of the EGB and its contact with the Archaean Craton is a suture zone related to the Indo-Antarctica collision event.  相似文献   

2.
An assemblage of predominantly metasedimentary rocks in the Eastern Ghats Province, India, underwent granulite facies metamorphism and deformation in early Neoproterozoic times, and was subsequently intruded by the Koraput alkaline complex. The intrusion was earlier believed to be syn- to late tectonic. The gabbroic core of the complex hosts nepheline-bearing syenitic dykes and veins. Following emplacement, magmatic amphibole within the syenites, and early orthopyroxene in feldspathic gneisses within the country rocks were retrogressed to biotite during pervasive solid-state deformation. Subsequent prograde metamorphism resulted in the formation of anhydrous assemblages at the expense of relict magmatic amphibole within the syenites, and metamorphic biotite in both the complex and the country rocks. Reactions reconstructed from textural observations indicate breakdown of biotite and amphibole to garnet + clinopyroxene ± orthopyroxene-bearing assemblages. Schreinemakers’ analysis on the relevant mineral associations suggests that heating was followed by loading of the region. This indicates thermal rejuvenation of the complex and the host granulites during an intracrustal orogeny that post-dates emplacement and cooling of the pluton. Available ages suggest that this event occurred in the mid-Neoproterozoic, and is probably unrelated to the amalgamation of the granulite belt with the Archaean Bastar/Dharwar craton.  相似文献   

3.
The Kunavaram alkaline complex is a NE-SW trending elongate body located along a major lineament, the Sileru Shear Zone (SSZ) that is regarded as a Proterozoic suture related to Indo-Antarctica collision. The complex is hosted within migmatitic quartzofeldspathic gneisses, mafic granulites retrogressed to amphibolites, and quartzites. The structural evolution of the country rocks and the alkaline complex are similar. The first phase of deformation, D1, produces a pervasive segregation banding (S1) in all rock units within and outside the complex. A second deformation phase D2 isoclinally folded S1 along subvertical axial planes with shallow plunging axes. F2 isoclinal folds are ubiquitous in the country rocks and the eastern extremity of the complex. In the interior of the alkaline body, D2 strain decreases and S1 is commonly subhorizontal. While amphibolite to granulite facies conditions prevailed during deformation, post-D2 annealing textures testify to persisting high grade conditions. In the west, a NNE-SSW trending dextral shear zone with strike-slip sense (D3) truncates the complex. Within this shear zone, quartzofeldspathic country rocks are plastically deformed, while hornblende-K-feldspar assemblages of the complex are retrogressed to biotite and plagioclase. Warping related to D3 shears also resulted in fold interference patterns on the subhorizontal S1 foliation in low D2 strain domains. Based on its steep dip, north-easterly trend, and non-coaxial nature with dextral strike-slip sense, the D3 shear zone can be correlated with the SSZ. Since this shear zone, i.e., the SSZ, is not associated with primary igneous fabrics and resulted in solid state deformation of the complex, it cannot be considered as a conduit for alkaline magmatism, but is probably responsible for the post-tectonic disposition of the pluton.  相似文献   

4.
The Koraput Alkaline Complex in the high-grade Eastern Ghats Belt, India, is synkinematically emplaced in a pull-apart structure and far from the Bastar cratonic margin. The suite comprises four distinct members, namely, mafic syenite, felsic syenite, nepheline syenite and perthite syenite. Fe-rich orthopyroxene rims on olivine in mafic syenite indicate iron-enrichment in the early stage of differentiation. With plagioclase of andesine composition it could be described as alkali-norite, the plutonic equivalent of hawiite. Felsic syenite with both alkali-feldspars and plagioclase of oligoclase composition could be described as two-feldspar syenite, the plutonic equivalent of mugearite. Albitic rims on nepheline indicates subsolvus reaction. Chemical trends in amphiboles and plagioclase feldspars, progressively more ferroan and more sodic respectively, are strong indications of mineral fractionation in the Koraput suite. Chemical trends in the variation diagrams are compatible with feldspar fractionation in the Koraput suite. A weak Fe-enrichment trend in the early stage of differentiation, as observed in the AFM diagram, is compatible with that of the alkali-basalt series. Nb anomalies, both positive and negative, are indicative of crustal contamination as expected in synkinematic plutons. In terms of Gondwana assembly and break up, the alkaline complexes are supposed to represent rift-related magmatism along the continental margin. In spite of petrological evidence of the magmatic character of the Koraput Complex, anorogenic setting is contra-indicated by mesoscopic and microscopic fabrics, more akin to synkinematic intrusion during F 2 folding in the host country rocks. The Proterozoic alkaline complexes in the Eastern Ghats Belt, could alternatively trace the path of moving Gondwana continent over mantle plumes.  相似文献   

5.
The Koraput Alkaline Complex (KAC) lies on the NE-SW trending Sileru Shear Zone (SSZ) separating the Proterozoic Eastern Ghats Province from the Archaean Indian craton. The core of the KAC is made of hornblende gabbro, which is rimmed by a band of nepheline syenite in the east and syenodiorite in the west. The timing of magmatism with respect to the SSZ is disputed. The KAC was deformed during emplacement, and a magmatic foliation related to the syn-emplacement deformation, D 1 , is present in the gabbroic core. The dominant D 2 -related field fabric strikes NESW and is penetrative in parts of the gabbro and marginal lithologies. E-W trending D 3 shear zones cut across the complex. Distinct textural domains resulted from strain partitioning during deformation. Parts of the complex with magmatic textures constitute Domain-1, while D 2 and D 3 fabric zones comprise Domains-2 and 3 respectively. Temperatures in the KAC initially decreased following D 1 , but increased through D 2 and D 3 . Anisotropy of magnetic susceptibility (AMS) studies show that the magnetic fabric generally follows S 1 in Domain-1. While the magnetic fabric in Domain-2 is dominantly parallel to S 2 , some of it parallels S 1 . The latter is a relict D 1 fabric that is recognized from AMS analysis but is obliterated in the field, which confirms that the KAC pre-dates the SSZ. The response of magnetic fabrics to temperature and implications of the study for Indo-Antarctica amalgamation are discussed.  相似文献   

6.
Stability of the assemblage sapphirine + quartz in Mg–Al-rich granulites implies ultrahigh temperature (UHT) condition of metamorphism but their direct contact is rarely preserved in natural rocks. The present study shows contrasting textural relations between sapphirine and quartz in different parts of the same occurrence of a Mg–Al-rich granulite, Eastern Ghats Belt, India. Textural data suggest stabilization of the assemblage sapphirine + quartz with orthopyroxene and cordierite during the metamorphic peak. Thermometric estimates yield temperature exceeding 950 °C for the stability of this assemblage. Most of such sapphirine grains (Spr1) are texturally separated from quartz and cordierite grains by double corona of sillimanite + orthopyroxene that results due to isobaric cooling during the post-peak stage. Sapphirine (Spr2) also forms a symplectic intergrowth with quartz and orthopyroxene at the fringe of coarse orthopyroxene. This textural feature can be explained by the breakdown of (Fe, Mg)-Tschermak components of orthopyroxene during the same isobaric cooling episode from UHT peak condition. The preservation of grain contact of this intergrown sapphirine and quartz can be attributed to a problem in reaction kinetics. In the other mode, sapphirine (Spr3) occurs with quartz with a thin skin of cordierite near a quartz vein. Such texture could result from isothermal decompression of the cooled crust. Alternatively and more possibly, cordierite could form from ingress of CO2–H2O rich fluid during terminal stage of cooling. Finally, sapphirine (Spr4) and quartz show direct contact close to the quartz vein. Direct contact of such sapphirine and quartz represents textural disequilibrium as this particular quartz is introduced as a vein much later than the peak metamorphism but prior to the major foliation-forming deformation. Coarse sapphirine and vein quartz, therefore, accidentally came in contact with each other and persisted metastably. Therefore, though coexistence of sapphirine and quartz is considered to be a strong evidence for ultrahigh temperature condition, care should be taken to decipher their stable coexistence. Different types of textural relations involving this mineral pair could originate in a single rock, probably in different stages of its metamorphic history.  相似文献   

7.
Textural relations, thermobarometry and petrogenetic grid considerations in the syn-tectonic granitoid massif and the enveloping metasedimentary gneisses at Salur are consistent with a counter-clockwise PT t path for the rocks. The low-P/high-T prograde sector is documented by the pre- to syn-D1 cordierite±orthopyroxene±garnet±spinel–bearing metatexite leucosomes in metapelites. Heating and loading of the rocks (syn- to post-D1) resulted in the formation of garnet+orthopyroxene± cordierite-bearing diatexites, and decomposition of cordierite in metatexite leucosomes to orthopyroxene+sillimanite+biotite+quartz symplectites. Near-peak temperature, 850 °C at 8.0 kbar, was reached syn- to post-D2. Post-peak cooling resulted in the stabilization of coronal grossular and anorthite+calcite symplectites at the expense of scapolite+wollastonite+calcite assemblages in calc-silicate gneisses, and the resetting of cation exchange temperatures at 700–750 °C. Near-isothermal decompression at c. 700–750 °C is manifested by the decomposition of garnet porphyroblasts in the granitoid gneisses to plagioclase+orthopyroxene/ilmenite/biotite two-phase coronas and restabilization of cordierite at garnet margins in metapelites. Subsequent low-P, near-isobaric cooling led to the overprinting of granulite facies assemblages by muscovite+calcite assemblages, and further resetting of cation exchange thermometers to lower temperatures c. 600 °C. The tectonothermal evolution of the Salur gneiss complex vis-a-vis the Eastern Ghats Belt is therefore consistent with high degrees of lower crustal melting, followed by prograde heating of the cover rocks due to magma invasion synchronous with crustal compression, and finally thermal relaxation over a protracted period punctuated by tectonic/erosional denudation of the thickened crust.  相似文献   

8.
The massif-type anorthosite complex at Bolangir in the northern part of the Eastern Ghats belt occurs in a milieu of predominantly supracrustal granulite-grade rocks. The massif is separated from the host gneisses by coarse-grained garnetiferous granitoid gneisses which are interpreted as coeval crustallyderived melts. Melanocratic ferrodiorite rocks occur at the immediate contact with the anorthosite massif which they intrude in cross-cutting dikes and sheets. The emplacement age of the anorthosite diapir and the associated igneous suites is deemed to be pre-D2. Recrystallization of the igneous assemblages of the ferrodiorite suite (750–800°C, 7–8kbar, ) during a period of near-isobaric cooling from the igneous crystallization stage to the regionalP-T regime led to extensive development of coronitic garnet at the interface of plagioclase phenocrysts with the mafic matrix assemblage (opx + fay + cpx + ilm ± amph, bio). Abundant accessory phases are zircon, apatite and thorite. The mafic phases have extremely ferrous compositions (XFe gar: 0.93-0.87, fay: 0.90-0.87, opx: 0.80-0.60, cpx: 0.70-0.47, amph: 0.81-0.71) reflecting the low Mg-number (16-8) of the rocks. Compared to worldwide occurrences of similar rocks, the Bolangir ferrodiorites (SiO2 36–58 wt.%, FeO*: 39-10 wt.%) are characterized by exceptionally high concentrations of HFSE and REE (TiO2: 4.8-1.0 wt.%, P2O5: 1.7-0.5 wt.%, Zr: 5900-1300 ppm, Y: 240-80 ppm, La: 540-100 ppm, Ce: 1100-200 ppm, Yb: 22-10 ppm, Th: 195-65 ppm). Well defined linear variation trends for major and trace elements reflect progressive plagioclase accumulation towards the felsic members of the suite. The ferrodiorites are interpreted to represent residual liquids of anorthosite crystallization which after segregation and extraction from the ascending diapir became enriched in HFSE and REE through selective assimilation of accessory phases (zircon, monazite, apatite) from crustal felsic melts. Ferromonzodioritic rock presumably formed through hybridization between the ferrodiorite and overlying felsic melts.  相似文献   

9.
A suite of spinel–cordierite granulites from Viziangram, Eastern Ghats Belt, India preserve mineral assemblages and reaction textures indicative of peak metamorphic conditions of >1000 °C, >8<10 kbar, followed successively by near isobaric cooling (down to 750–800 °C), near isothermal decompression (to 4–5 kbar), and late hydration. P–T conditions of each stage are evaluated through a combination of petrogenetic grid approach and thermobarometry. Sapphirine is developed in sillimanite‐bearing acid pegmatite veins that intruded the spinel–cordierite granulite close to peak metamorphic conditions, and also in the host rock in immediate contact with the pegmatite. Both sillimanite and sapphirine in the pegmatite are considered to be magmatic phases. Field observations and textural characteristics suggest that Al‐metasomatism of the spinel–cordierite granulite due to the intrusion of pegmatite was responsible for sapphirine formation in the spinel granulite.  相似文献   

10.
High‐MgAl rocks occur as xenoliths (up to 2 m in diameter) in mafic granulites at a newly discovered locality near Anakapalle. Following an early phase of deformation, ultrahigh‐temperature (UHT) metamorphism and near‐isothermal decompression, the rocks were intruded in a lit‐par‐lit manner by felsic melts (charnockite), which caused local‐scale metasomatism. A subsequent deformation produced isoclinal folds and the distinct gneissic foliation of the charnockite still at granulite facies conditions. The sequence of multiphase reaction textures in the high‐MgAl xenoliths reflects the changes of physico‐chemical conditions during the polyphase evolution of the terrane; UHT metamorphism (stage 1, > 1000°C, c. 10 kbar) is documented by relics of extremely coarse grained domains with the assemblage orthopyroxene (opx)1 + garnet (grt)1 + sapphirine (spr)1 + spinel (spl)1 + rutile (rt). A subsequent phase of near‐isothermal decompression in the order of 1–2 kbar (stage 2) resulted in extensive replacement of grt1 and opx1 megacrysts by lamellar (opx2 + spr2) symplectites. The intrusion of felsic melt (stage 3) led to the development of a narrow metasomatic black wall reaction zone (bt + sil + plg3 + opx2,3 + rt) at the immediate contact of the xenoliths and in melt infiltration zones to the partial replacement of (opx2 + spr2) symplectites by biotite and sillimanite and/or plg3, mainly at the expense of orthopyroxene, with concomitant coarsening of the intergrowth texture. The subsequent deformation (stage 4) further modified the symplectite textures through polygonization, recrystallization and grain‐size coarsening. The deformation was followed by a period of cooling and decompression (stage 5, c. 800°C, 4–7 kbar) as indicated by local growth of late garnet (grt5) at the expense of (opx + spr + plg) domains at static conditions. Recently published isotope data suggest that the multistage evolution of the high‐MgAl granulites at Anakapalle followed a discontinuous P–T trajectory that may be related to heating of the crust through magmatic accretion culminating in deep‐crustal UHT metamorphism at 1.4 Ga (stage 1), fast uplift of the UHT granulites into mid‐crustal levels as a consequence of extensional tectonics (stage 2), emplacement of felsic magmas in the Grenvillian (at c. 1 Ga, stage 3) resulting in reheating of the crust to high–T conditions followed by a phase of compressional tectonics (stage 4) and a period of cooling to the stable geotherm (stage 5) still in the Grenvillian.  相似文献   

11.
Abstract Three types of mineral associations are described from calc-silicate granulites from the Eastern Ghats, India, where geothermobarometry in associated rocks suggests extremely high P–T conditions of metamorphism ( c . 9 ± 1 kbar, 950° C). These mineral associations are: (i) calcite + quartz + scapolite + plagioclase, (ii) calcite + scapolite + wollastonite + porphyroblastic garnet + coronal garnet and (iii) calcite + quartz + wollastonite + scapolite + porphyroblastic garnet + coronal garnet, all coexisting with K-feldspar, titanite and clinopyroxene. The first two associations evolved through nearly isobaric cooling retrograde paths, whereas the third evolved through a nearly isothermal decompression path followed by an isobaric cooling retrograde path. Textural and compositional characteristics suggest the following mineral reactions in the calc-silicate granulites: calcite + quartz = wollastonite + CO2, calcite + plagioclase = scapolite, calcite + scapolite + wollastonite = porphyroblastic garnet ± quartz + CO2, CaTs + wollastonite = coronal garnet (association ii) and wollastonite + scapolite = coronal garnet (association iii) + quartz + CO2. Andradite content in garnet was buffered by the redox equilibria wollastonite + hedenbergite + O2= andradite + quartz (association iii) and wollastonite + andradite + CaTs + scapolite = hedenbergite + calcite + grossular + O2 (association ii). The contrasting mineral parageneses have been ascribed to interplay of variables such as X CO2, f O2, f HCl in the fluid, bulk Na content and the nature of the retrograde P–T–X CO2 paths through which the rocks evolved.  相似文献   

12.
High Mg-Al spinel-sapphirine granulites, orthopyroxene-bearing quartzofeldspathic granulites, two pyroxene-bearing mafic granulites and metapelitic gneisses are exposed around Paderu, Eastern Ghats Belt. Geothermobarometry in orthopyroxene-bearing quartzofeldspathic granulites and mafic granulites indicate near isobaric cooling through 90°C from ca. 720°C to 630°C, at 8.0 kbar. However, signatures of ultrahigh temperature metamorphism are recorded from the mineralogy and reaction textures in the high Mg-Al granulites. Mineral reactions deduced in this work, when combined with others described by Lalet al (1987) from the same area and plotted in an appropriate petrogenetic grid in the system FMASO indicate an ACW path comprising a high dT/dP prograde arm reaching Pmax − Tmax = 9.5 kbar, ∼ 1000°C, followed by near-isobaric cooling down to 9 kbar, 900°C and subsequent decompressive reworking.  相似文献   

13.
The boundary between the Archean cratons and the Eastern Ghats Belt in peninsular India represents a rifted Mesoproterozoic continental margin which was overprinted by a Pan-African collisional event associated with the westward thrusting of the Eastern Ghats granulites over the cratonic foreland. The contact zone contains a number of deformed and metamorphosed nepheline syenite complexes of rift-related geochemical affinities. In addition to the nepheline-bearing rocks, metamorphosed quartz-bearing monzosyenitic bodies can also be identified along the suture in the region between the Godavari-Pranhita graben and the Prakasam Igneous Province. One such occurrence at Jojuru near Kondapalle is geochemically comparable to the nepheline syenites and furnishes a weighted mean concordant U–Th–Pb SHRIMP zircon age of 1263 ± 23 Ma (2σ), which provides a lower age bracket for the rift-related magmatic activity. The original igneous mineral assemblage in the monzosyenite was partially replaced by the formation of coronitic garnet during the Pan-African metamorphism of the rocks. PT estimates of garnet corona formation at the interface between clinopyroxene–orthopyroxene–ilmenite clusters and plagioclase indicate mid to upper amphibolite facies condition (5.5–7.0 kbar and 600–700 °C) during the thrust induced deformation and metamorphism associated with the Pan-African collisional tectonics.  相似文献   

14.
T.R.K. Chetty   《Gondwana Research》2010,18(4):565-582
New data from structural mapping and tectonic evaluation in the northern parts of the Eastern Ghats Mobile Belt (EGMB-north) involving the interpretation of satellite images, field traverses, critical outcrop mapping and kinematic studies of macro- as well as microstructures of the shear zone rocks together with the geometry and disposition of Gondwana basins led to, for the first time, the elucidation of post-Grenvillian structural architecture of the terrane. This helps in assessing the sequence of successive tectonothermal events that were responsible for the origin and progressive evolution of the Permo-Carboniferous coal bearing sediments along the Mahanadi rift that forms significant in the reconstruction models of east Gondwana.The composite terrane of high-grade metamorphic rocks (EGMB-north), strikes E–W in contrast to the regional NE–SW trend of the EGMB. The structural architecture obtained from this study is controlled by the boundary shear zones and associated link shear zones. The dextral kinematic displacements along the Northern Boundary Shear Zone (NBSZ) as well as the Mahanadi Shear Zone (MSZ) and Koraput–Sonapur–Rairakhol Shear Zone (KSRSZ) were derived from multi-scale field based structural observations. A N–S structural cross-section presents a crustal-scale ‘flower structure’ across the composite terrane exposing different domains displaying distinctive internal structures with widely varying different geological evolution history and strain partitioning, separated by crustal-scale shear zones. Deep seismic imaging and gravity signatures support ‘flower structure’ model. The pervasive first formed gneissic fabrics were continuously reworked and partitioned into a series of E–W, crustal-scale shear zones.The Neoproterozoic regional dextral transpressional tectonics along the shear zones and their repeated reactivation could be responsible for initiation and successive evolution of Gondwana basins and different episodes of sedimentation. Available geochronological data shows that the structural architecture presented here is post-Grenvillian, which has been repeatedly reactivated through long-lived transpressional tectonics. The composite terrane is characterized by all the typical features of an oblique convergent orogen with transpressional kinematics in the middle to lower crust. The kinematic changes from transpression to transtensional stresses were found to be associated with global geodynamics related to the transformation from Rodinia to Gondwana configuration.  相似文献   

15.
The alkaline complex of Koraput, Orissa, India, is one of several bodies in the high-grade Eastern Ghats belt, but this one is an integral part of the high-grade belt and remote from the western boundary against the Bastar craton. The Koraput complex forms a lozenge-shaped intrusion into the metapelitic granulites and is bounded by shear zones. The combined effect of movement along these shear zones, is a northeasterly elongated sygmoidal cavity with maximum width along the northwesterly trending Reidel shear. Thus the Koraput alkaline complex can be considered to have been emplaced in a pull-apart structure, developed in the granulitic country rocks. Moreover, in view of the fact that the western margin of the high-grade Eastern Ghats belt bears clear evidence of collisional features, rather than that of rifting or break-up, the rift-valley model for the alkaline magmatism in this high-grade belt appears untenable.  相似文献   

16.
A suite of metapelites, charnockites, calc-silicate rocks, quartzo-feldspathic gneisses and mafic granulites is exposed at Garbham, a part of the Eastern Ghats granulite belt of India. Reaction textures and mineral compositional data have been used to determine the P–T–X evolutionary history of the granulites. In metapelites and charnockites, dehydration melting reactions involving biotite produced quartzofeldspathic segregations during peak metamorphism. However, migration of melt from the site of generation was limited. Subsequent to peak metamorphism at c . 860° C and 8 kbar, the complex evolved through nearly isothermal decompression to 530–650° C and 4–5 kbar. During this phase, coronal garnet grew in the calc-silicates, while garnet in the presence of quartz broke down in charnockite and mafic granulite. Fluid activities during metamorphism were internally buffered in different lithologies in the presence of a melt phase. The P–T path of the granulites at Garbham contrasts sharply with the other parts of the Eastern Ghats granulite belt where the rocks show dominantly near-isobaric cooling subsequent to peak metamorphism.  相似文献   

17.
18.
In the Vizianagaram area (E 83°29.442′; N 18°5.418′) of the Eastern Ghats Belt, India, a suite of graphite‐bearing calc‐silicate granulites, veined by syenitic rocks, developed wollastonite‐rich veins at 6–7 kbar and > 850 °C. During subsequent near‐isobaric cooling wollastonite was replaced by calcite + quartz and a graphic intergrowth of fluorite + quartz ± clinopyroxene. Titanite with variable Al and F contents is present throughout the rock. Combining the compositional variation of titanite and recent experimental data, it is demonstrated that the mineral assemblage, the composition of coexisting fluids and the mobility of Al exert a far greater control on the composition of titanite than pressure, temperature or the whole rock composition. Thermodynamically computed isothermal–isobaric logfO2– logfCO2 and logfF2– logfO2 grids in the systems Ca–Fe–Si–O–F (CISOF; calcite‐free) and Ca–Fe–Si–O–F–C–H (CISOFV; calcite‐present) demonstrate the influence of bulk rock and fluid compositions on the stability of the fluorite‐bearing assemblages in diverse geological environments and resolve the problem of the stability of titanite in fayalite + fluorite‐bearing rocks in the Adirondacks. The mineralogy of the studied rocks and the topological constraints tightly fix the logfO2, logfF2 and logfCO2 at ?15.8, ?30.6 and 4.1, respectively, at 6.5 kbar and c. 730 °C. Because of the similarity in the P–T conditions, the compositions of pore fluids in the fluorite‐bearing assemblages of the Adirondacks and the Eastern Ghats Belt have been compared.  相似文献   

19.
The time‐scales and P–T conditions recorded by granulite facies metamorphic rocks permit inferences about the geodynamic regime in which they formed. Two compositionally heterogeneous cordierite–spinel‐bearing granulites from Vizianagaram, Eastern Ghats Province (EGP), India, were investigated to provide P–T–time constraints using petrography, phase equilibrium modelling, U–Pb geochronology, the rare earth element composition of zircon and monazite, and Ti‐in‐zircon thermometry. These ultrahigh temperature (UHT) granulites preserve discrete compositional layering in which different inferred peak assemblages are developed, including layers bearing garnet–sillimanite–spinel, and others bearing orthopyroxene–sillimanite–spinel. These mineral associations cannot be reproduced by phase equilibrium modelling of whole‐rock compositions, indicating that the samples became domainal on a scale less than that of a thin section, even at UHT conditions. Calculation of the P–T stability fields for six compositional domains within which the main rock‐forming minerals are considered to have attained equilibrium suggests peak metamorphic conditions of ~6.8–8.3 kbar at ~1,000°C. In most of these domains, the subsequent evolution resulted in the growth of cordierite and final crystallization of melt at an elevated (residual) H2O‐undersaturated solidus, consistent with <1 kbar of decompression. Concordant U–Pb ages obtained by SHRIMP from zircon (spread 1,050–800 Ma) and monazite (spread 950–800 Ma) demonstrate that crystallization of these minerals occurred during an interval of c. 250 Ma. By combining LA‐ICP‐MS U–Pb zircon ages with Ti‐in‐zircon temperatures from the same analysis sites, we show that the crust may have remained above 900°C for a minimum of c. 120 Ma between c. 1,000 and c. 880 Ma. Overall, the results suggest that, in the interval 1,050 to 800 Ma, the evolution of the Vizianagaram granulites culminated with UHT conditions from c. 1,000 Ma to c. 880 Ma, associated with minor decompression, before further zircon crystallization at c. 880–800 Ma during cooling to the solidus. However, these rocks are adjacent to the Paderu–Anantagiri–Salur crustal block to the NW that experienced counterclockwise P–T–t paths, and records similar UHT peak metamorphic conditions (7–8 kbar, ~950°C) followed by near‐isobaric cooling, and has a similar chronology during the Neoproterozoic. The limited decompression inferred at Vizianagaram may be explained by partial exhumation due to thrusting of this crustal block over the adjacent Paderu–Anantagiri–Salur crustal block. The residual granulites in both blocks have high concentrations of heat‐producing elements and likely remained hot at mid‐crustal depths throughout a period of relative tectonic quiescence in the interval 800–550 Ma. During the Cambrian Period, the EGP was located in the hinterland of the Denman–Pinjarra–Prydz orogen. A later concordant population of zircon dated at 511 ± 6 Ma records crystallization at temperatures of ~810°C. This age may record a low‐degree of melting due to limited influx of fluid into hot, weak crust in response to convergence of the Crohn craton with a composite orogenic hinterland comprising the Rayner terrane, EGP, and cratonic India.  相似文献   

20.
A suite of high-Mg–Al granulites from Sunkarametta, Eastern Ghats Belt, India, shows contrasting prograde assemblages of extremely aluminous orthopyroxene+cordierite+sapphirine and similarly aluminous orthopyroxene+Ti-rich spinel in closely associated domains. Textural and compositional characteristics indicate that both were derived from prograde dehydration–melting of biotite–plagioclase–quartz-bearing protoliths. The former assemblage was stabilized at relatively more magnesian bulk composition. Geothermobarometric data and petrogenetic grid considerations place 'peak' metamorphic conditions at c. 950 °C and 9 kbar. Subsequent to peak metamorphism, the rocks cooled to c . 700–750 °C, with slight lowering of pressure, and the retrograde reactions also involved melt–solid interaction. The inferred P – T  trajectory is one of heating–cooling at lower crustal (25–30 km) depths.  相似文献   

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