Nucleogenic noble gas components in the Cape York iron meteorite

We report data on neutron capture products of the secondary cosmic ray component, the inferred proton and neutron fluences, and the identification of double beta decay of ⁸²Se in heavily shielded samples of the Cape York iron meteorite. One purpose of this study is to develop a new chronometer for cosmic ray exposure, based on the nuclides ¹²⁹I (16 My half-life) and ¹²⁹Xe from low energy cosmic ray reactions on Te. The abundance ratio of these two nuclides permits the determination of an (effective) exposure age of 93 ± 16 My, which represents the first exposure age datum of Cape York. The very small concentrations of spallogenic ³⁸Ar = 6.5 × 10⁻¹⁰ cm³ STP/g in the metal and troilite (per g Fe) document the heavily shielded locations of our sample. An excess of ¹²⁹Xe in the troilite is shown to be entirely due to the decay of cosmic-ray-produced ¹²⁹I. On the other hand, an inclusion in the troilite reveals the presence of ¹²⁹Xe from extinct ¹²⁹I and documents its ~4.5 Gy formation age. Mono-isotopic excess of ⁸²Kr is identified as due to ββ-decay of ⁸²Se with an inferred half-life of 1.0 × 10¹⁰ y. This represents the first ββ-decay product observed in a meteorite.     

A dendritic solidification model to explain Ge-Ni variations in iron meteorite chemical groups

Segregation during solidification is responsible for the secondary fractionation of trace elements in iron meteorite chemical groups. This study examines the consequences of dendritic segregation on the Ge-Ni fractionation in iron meteorite chemical groups. Solidification experiments and computer simulations of the dendritic solidification process indicate that the effect of P on the partitioning behavior of Ge and the effect of solid state diffusion on segregation are both important in understanding the observed Ge-Ni correlations. The Ge-Ni concentration trends predicted by the dendritic solidification model agree well with the observed variations.     

A 5 million year record of compositional variations in mantle sources to magmatism on Santiago, southern Cape Verde archipelago

High-precision Pb isotope data and Sr–Nd–Hf isotope data are presented together with major and trace element data for samples spanning the 4.6 Ma history of volcanism at Santiago, in the southern Cape Verde islands. Pb isotope data confirm the positive Δ8/4 signature of the southern islands indicating that the north–south compositional heterogeneity in the Cape Verde archipelago has persisted for at least 4.6 Ma. The Santiago volcanics show distinct compositional differences between the old, intermediate and young volcanics, and suggest greater involvement of an enriched mantle (EM1)-like source over time. Isotopic variations in the Santiago volcanics indicate convergence towards a homogeneous EM1-like end-member and distinct temporal variations in the FOZO-like end-member. Santiago and Santo Antão (a northern island, Holm et al. 2006), show a simultaneous decrease in ²⁰⁸Pb/²⁰⁴Pb of the high ²⁰⁶Pb/²⁰⁴Pb FOZO-like source with time. Such systematic archipelago-wide variations in the FOZO-like component suggest that this component is more likely to be present as a coherent package of recycled ocean crust rather than as multiple small heterogeneities dispersed in the upwelling mantle. The temporal variations in ²⁰⁸Pb/²⁰⁴Pb reflect minor lateral variations in Th/U of this recycled ocean crust package entering the melting zone beneath the islands. The location of the EM1-like component is more equivocal. A shallow lithospheric location is possible, but this would require a coincidence between spatial compositional variations in the lithosphere (EM1 is spatially restricted to the southern islands) and flow lines in the upwelling mantle revealed by seismic anisotropy. Therefore, we favour a deeper asthenospheric mantle source for the EM1-like source.     

Nedagolla,a remelted iron meteorite

The Nedagolla meteorite was recognized by Axon to be a rare example of an iron which has been preterrestrially reheated to the point of melting. The dendrite secondary arms are spaced 200 μm apart, implying that Nedagolla solidified and cooled at ~0·02°C/sec. The presence of (Fe, Cr)_1-xS inclusions precipitated during cooling in the interdendritic regions and evidence of solute redistribution of Ni, Cr, Co, Si and P are consistent with this cooling rate. Such a rate indicates that Nedagolla cooled very near the surface of its parent ‘body’. Secondary microstructural features including the presence of isothermal taenite and minute phosphide precipitates, which have formed from the dissolution of primary phosphide material, indicate a later reheating to about 750°C for a period of several hours.     

The isotopic composition of silver and lead in two iron meteorites: Cape York and Grant

Silver in the metal phases of Cape York (IIIA) and Grant (IIIB) has been determined after an extensive surface cleaning process. The ${}^{107}\text{Ag}{}^{109}\text{Ag}$ was found to be enriched over that found in terrestrial Ag by ~7%. to 19%., demonstrating the presence of excess ¹⁰⁷Ag (¹⁰⁷Ag¹) in this class of meteorites. An effort was made to find schreibersite with a distinctive ¹⁰⁸Pd/¹⁰⁹Ag ratio in order to establish a three-point isochron, but the results are not markedly different from those obtained for the bulk metal. The Ag isotopic ratio of sulfides from the same meteorites were nearly normal in composition. These results demonstrate correlations of ${}^{107}\text{Ag}{}^{109}\text{Ag}$ with ${}^{108}\text{Pd}{}^{109}\text{Ag}$ between coexisting phases of two iron meteorites that are associated with planetary differentiation processes. The ratios ${}^{107}\text{Ag}{}^1{}^{108}\text{Pd}$ were found to be 1.7 × 10^?5 and 1.2 × 10^?5 for Cape York and Grant, respectively. These observations are in support of the widespread presence of ¹⁰⁷Pd in the early solar system. The difference in isotopic composition between metal and sulfide phases demonstrates that silver diffusion was small (over 6.5 × 10⁶ y) indicating a cooling rate much greater than 150°C/my for meteorites which have been attributed to small planetary cores. Uranium determinations were carried out on the metal phases and concentrations of ~ $\text{1 × 10}{}^{12}$ g U/g and 2 × 10^?10g U/g were found for Cape York and Grant, respectively. The Pb in these meteorites was determined using the improved cleaning procedures and chemical separations with low blank levels. The results confirm the presence of variable proportions of radiogenic Pb in both the metal and sulfide phases of iron meteorites. No simple explanation for the presence of radiogenic lead is apparent; while terrestrial contamination may appear to be the obvious explanation, it is possible that this effect could result from relatively recent metamorphism in the meteorite parent body.     

Mineralogy of silicate inclusions in the Elga IIE iron meteorite

The petrography, mineral modal data and major and trace element compositions of 15 silicate inclusions in the Elga iron meteorite (chemical group IIE) show that these inclusions represent chemically homogeneous zoned objects with highly variable structures, reflecting the sequence of crystallization of a silicate melt during cooling of the metal host. The outer zones of inclusions at the interface with their metal host have a relatively medium-grained hypocrystalline texture formed mainly by Cr-diopside and merrillite crystals embedded in high-silica glass, whereas the central zones have a fine-grained hypocrystalline texture. Merrillite appears first on the liquidus in the outer zones of the silicate inclusions. Na and REE concentrations in merrillite from the outer zones of inclusions suggest that it may have crystallized as α-merrillite in the temperature range of 1300–1700°С. Merrillite tends to preferentially accumulate Eu without Sr. Therefore, strongly fractionated REE patterns are not associated with prolonged differentiation of the silicate melt source but depend on crystallization conditions of Н-chondrite droplets in a metallic matrix. The systematic decrease in Mg# with increasing Fe/Mn in bronzite may indicate partial reduction of iron during crystallization of the inclusion melt. The modal and bulk compositions of silicate inclusions in the Elga meteorite, as well as the chemical composition of phases are consistent with the model equilibrium crystallization of a melt, corresponding to 25% partial melting of H-chondrite, and the crystallizing liquidus phase, merrillite, and subsequent quenching at about 1090°С. Despite a high alkali content of the average weighted bulk inclusion composition, La/Hf and Rb/Th fall within the field of H chondrites, suggesting their common source. Our results reveal that silicate inclusions in the Elga (IIE) iron meteorite originated by mixing of two impact melts, ordinary chondrite and Ni-rich iron with а IIE composition, which were produced by impact event under near-surface conditions on a partially differentiated parent asteroid.     

Chondrules in the Murray CM2 meteorite and compositional differences between CM-CO and ordinary chondrite chondrules

Bulk compositions were determined by broad-beam electron microprobe analysis for thirteen of the least aqueously altered chondrules in Murray (CM2). These and literature data reveal compositional differences between CM-CO and ordinary chondrite (OC) chondrules:

• 1.(a) CO chondrules are richer in refractory lithophiles and poorer in Cr, Mn and volatile lithophiles than OC chondrules; much lower refractory lithophile abundances in CM chondrules resulted from aqueous alteration,
• 2.(b) in CM-CO chondrites, abundances of refractory lithophiles are higher in nonporphyritic than porphyritic chondrules, whereas in H-L-LL3 chondrites the converse is true,
• 3.(c) Cr ranges are greater and Cr and Mn correlate more strongly in chondrules in CM-CO than in H-L-LL3 chondrites.

We find evidence for two important lithophile precursor components of CM-CO chondrite chondrules:

• 1.(1) pyroxene- and refractory-rich, FeO-poor;
• 2.(2) olivine-rich, refractory and FeO-poor.

The occurrence of a few FeO-rich chondrules attests to a third component similar to matrix: olivine- and FeO-rich, refractories not characterized. The first two components differ from those inferred for OC chondrules, consistent with formation at different locations. The pyroxene- and refractory-rich, FeO-poor lithophile precursor component probably formed by an incomplete evaporation of presolar silicates that brought these materials into the enstatite stability field.     

Native silicon and iron silicides in the Dhofar 280 lunar meteorite

The Dhofar 280 lunar highland meteorite is the first one in which native silicon was identified in association with iron silicides. This association is surrounded by silicate material enriched in Si, Na, K, and S and occurs within an impact-melt matrix. Compared to the meteorite matrix, the objects with native Si and the silicate material around them show high Al-normalized concentrations of volatile elements and/or elements with low sensitivity to oxygen but are not any significantly enriched in refractory lithophile elements. Some lithophile elements (V, U, Sm, Eu, and Yb) seem to be contained in reduced forms, and this predetermines REE proportions atypical of lunar rocks and a very low Th/U ratio. The admixture of siderophile elements (Ni, Co, Ge, and Sb) suggests that the Si-bearing objects were contaminated with meteorite material and were produced by the impact reworking of lunar rocks. The high concentrations of volatile elements suggest that the genesis of these objects could be related to the condensation of silicate vapor generated during meteorite impacts. The reduction of silicon and other elements could take place in an impact vapor cloud, with the subsequent condensation of these elements together with volatile components. On the other hand, condensates of silicate vapor could be reduced by impact reworking of impact breccias. Impact-induced vaporization and condensation seem not to play any significant role in forming the composition of the lunar crust, but the contents of the products of such processes can be locally relatively high. The greatest amounts of silicate vapor were generated during significant impact events. For example, more than 70% of the total mass of lunar material evaporated in the course of impact events should have resulted from the collision of the Moon with a cosmic body that produced the Moon??s largest South Pole-Aitken basin.     

Isotopic measurements in the Cape York Peninsula area,North Qeensland

K‐Ar and Rb‐Sr isotopic measurements have been made on the north‐south belt of igneous and metamorphic rocks from the Peninsula Ridge and Yambo Inlier of Cape York Peninsula. Four periods of Palaeozoic igneous activity appear to have been denned. These are (⁸⁷’Rb^λ = 1.39 X 10^–11y–1) about 415 m.y., about 400 m.y., 385–390 m.y., and 255–280 m.y., with the youngest dates to the north and northeast. The largest volume of magma, the Kintore Adamellite was emplaced during the 285–390 m.y. period. Initial ⁸⁷Sr/⁸⁶Sr ratios range from 0.715 (a granodiorite) through 0.72–0.74 (muscovite adamellite) to 0.76 (leuco‐adamellite), which suggests a high component of old crustal material in the latter types.

The host metamorphics grade from greenschist facies in the west to almandine‐amphibolite facies in the centre and south. Limited direct data suggest that the greenschists are older than 1400 m.y. This is supported by intrusive dolerite dating greater than 1800 m.y. Rocks possibly 2000 m.y. old are thus adjacent to the Australian northeast coast and place drastic limitations on the possibility of continual continental growth to the east.

Rb/Sr measurements on minerals of the almandine amphibolite rocks record the major Kintore event. Total rock measurements have high uncertainties but give only slightly older figures. Initial ⁸⁷Sr/⁸⁶Sr ratios of these apparent total rock isochrons are high, 0.735–0.745. Gross isotopic redistribution must have occurred during the Palaeozoic metamorphism.

The Rb/Sr isotopic and geochemical relationships suggest that some of the granitic rocks have been derived from the equivalent of the present greenschist facies suite, and that the almandine amphibolite facies was, in part, remetamorphosed during the Palaeozoic and is possibly partly residual after metamorphic segregation.

The region has been examined from the plate tectonic point of view and shows that many of the requirements of a cordilleran‐type mountain belt of Dewey & Bird (1970) existed during the mid‐upper Palaeozoic. The Palmerville Fault and the Hodgkinson Basin are key units in this interpretation.

Dolerite, possibly 2000 m.y. old, could be contemporaneous with voluminous dolerites of similar age from the Kimberley region (Australia) and of Venezuela and Guyana. They may be a useful continental breakup indicator, as are the Gondwana dolerites.     

A search for primordial atmospheric-like argon in an iron meteorite

He and Ar were extracted from the Weekeroo Station octahedrite in six heating steps. The Ar isotopic ratios were searched for any indication of an indigenous component with atmospheric-like values. Negative results were obtained.     

Analytical electron microscopy study of the plessite structure in the Carlton iron meteorite

In order to gain a better understanding of the formation of plessite in iron meteorites, various electron optical techniques were employed to study the range of plessite structures observed in the Carlton fine octahedrite. Compositional and structural studies of twins in clear taenite and the cloudy zone were made. Transmission electron microscopy studies of martensitic and duplex α + γ plessite regions show the presence of γ-taenite rods, 10–200 nm wide, in an α-kamacite matrix. Scanning transmission electron microscope X-ray analyses showed Ni contents in the y rods of $\text{≥43}\text{wt}\text{\%}$ and Ni contents in the a matrix of 3 wt% Ni. The reaction path involves the decomposition of $\text{α}{}_2$ martensite into $\text{α + γ}$ and these reactions occur below 200°C and possibly below 100°C. Apparently the formation of plessite is intimately related to the formation of martensite and the further decomposition of martensite during the cooling history of the meteorite. It is quite probable that the martensite decomposition reaction has occurred in a large number of iron meteorites and is responsible for many of the observed plessite structures.     

The compositional classification of some Chinese iron meteorites

Based on structural observations and the concentrations of Cr, Co, Ni, Cu, Ga, Ge, As, Sb, Re, Ir, and Au by neutron-activation analysis we have classified 14 Chinese iron meteorites. Thirteen are members of the large groups IAB, IIICD, IIIAB and IVA. Leshan is an ungrouped iron meteorite that falls within the IIE field on some element-Ni diagrams, but is distinctly outside this field on plots of Cu, W, and Ir vs. Ni; it is very similar in composition to Techado, another ungrouped iron. The high Cu content of Leshan in consistent with other evidence indicating that Cu is a valuable parameter for classifying iron meteorites. IIICD Dongling appears not to be a new meteorite, but to be paired with Nantan; Dongling was recovered about 50 km from the location of the Nantan shower. In view of the fact that Yongning is highly oxidized, we assign it to group IAB but cannot rule out IIICD. IVA-An Longchang has many characteristics of IVA irons, but has been remelted, probably in a terrestrial setting. Five irons belong to group IVA, a remarkably large number. Three are identical in composition, and we suspect that the two from Hubei, Guanghua and Huangling, are paired. Thus this set of 14 irons includes 12 independent falls.     

Neutron capture records of mesosiderites and an iron meteorite

The Sm and Gd isotopic compositions of silicates from six mesosiderites (Dalgaranga, Estherville, Morristown, Northwest Africa (NWA) 1242, NWA 2932, and Vaca Muerta) and one iron meteorite (Udei Station) were determined to elucidate the cosmic-ray exposure records. All seven samples showed significant ¹⁵⁰Sm/¹⁴⁹Sm and ¹⁵⁸Gd/¹⁵⁷Gd isotopic shifts from neutron capture reactions corresponding to neutron fluences of (1.3-21.8) × 10¹⁵ n cm⁻². In particular, Vaca Muerta showed a significantly higher neutron fluences than the other six samples. The parameter for the degree of neutron thermalization (ε_Sm/ε_Gd) also showed a significant difference between Vaca Muerta (0.76) and the other samples (0.93-1.20). These results suggest a two-stage irradiation of the Vaca Muerta silicates in the parent body (>50 Ma) before formation of the mesosiderite and during its transit to Earth (138 Ma). This is consistent with the ⁸¹Kr-Kr cosmic-ray exposure age data of a Vaca Muerta pebble from a previous noble gas isotopic study.     

Transmission electron microscopy on iron monosulfide varieties from the Suizhou meteorite

Transmission electron microscopy on the iron monosulfide (FeS) varieties from the Suizhou meteorite (Hubei, China) reveals the intergrowth of primary hexagonal 2C troilite and minor monoclinic 4C pyrrhotite (SG: F2/d) phases as nanometer-scale domain microstructure. In addition, anti-phase domain boundaries are found to present in the 2C troilite superstructure with the displacement vector 1/4[001]_2C, which is expected to form during the translational symmetry breaking during cooling from higher symmetry, high-temperature modification of the NiAs-type (SG: P6₃/mmc) structure. Furthermore, 60° rotation twinning about the pseudo-hexagonal c-axis is observed in the 4C pyrrhotite superstructure, which may result from rotation symmetry reduction induced by the ordered arrangements of metal vacancies through solid-state transformation during further cooling. All the above microstructural characteristics are discussed with consideration to the thermal metamorphism history experienced by the Suizhou meteorite.     

Regional and local variations in the composition of the wolframite series from SW Japan and possible factors controlling compositional variations

The regional and local variations in the composition of the wolframite series associated with the ilmeniteseries and magnetite-series granitoids in the Inner Zone of SW Japan were investigated using X-ray diffraction and microprobe analyses. It is concluded that the variation in Mn/Fe ratios in the source materials (granitic magmas in most cases) is the dominant factor controlling the regional variation in the wolframite compositions, while, as exemplified by the Kaneuchi mine, Kyoto Prefecture, the wallrock chemistry and pH of ore fluids are responsible for the local variation within a single vein system. Within a fresh euhedral crystal from the mine, only slight compositional variation of less than 3 mole% MnWO₄ is found in the form of oscillatory zoning. This study, combined with the fluid inclusion research, indicates that the wolframite compositions (Mn/Fe ratios) cannot be used as a geothermometer.     

Effect of the depositional environment on the compositional variations among the phosphorite deposits in Egypt

Late Cretaceous economic phosphorites from the Red Sea, Nile Valley, and Abu Tartur areas, Egypt, show distinct variations in the lithology of associated sediments, mineralogy of nonphosphatic constituents, and distributions of major and trace elements. In the Red Sea area, the phosphorite beds are intercalated with laminated black shales, and the nonphosphatic constituents are detrital quartz and calcite, ankerite, and pyrite cements. In the Nile Valley, the phosphorite beds are intercalated with chert, marl, and sandstone and the nonphosphatic constituents are detrital quartz and calcite and chalcedony cements. In the Abu Tartur Plateau, the phosphorite beds are intercalated with laminated black shales, and the nonphosphatic constituents are detrital quartz and ankerite and pyrite cements. The phosphorites studied also show distinct variations in major- and trace-element concentrations. The Abu Tartur phosphorites have higher contents of TiO₂, Al₂O₃, Fe₂O₃, K₂O, Co, Nb, Pb, Sr, Th, Y, and Zr and lower SiO₂, Ba, and U contents as compared to those in the Red Sea and Nile Valley areas. The positive correlations between Al₂O₃ and TiO₂, K₂O, Nb, Y, and Zr suggest the detrital origin of these constituents.Similarity in the phosphatic constituents, which were derived from outside the depositional sites, and variations in the lithology of associated sediments and the mineralogy and geochemistry of the nonphosphatic constituents, which reflect the conditions at the depositional sites, suggest that the variations in the depositional environment of the phosphorites are the potential controlling factor of the compositional variations among these phosphorites. The abundance of black shales in the Red Sea and Abu Tartur areas, as well as the occurrence of ankerite and pyrite as cementing materials for the phosphatic constituents, might reflect reducing conditions in these areas, while the abundance of siliciclastic sediments and calcite and chalcedony cements suggests oxidizing conditions in the Nile Valley. The reducing conditions in the Red Sea and Abu Tartur areas were probably developed within the pre-existing depressions in a shelf environment. These depressions might have formed as a result of a change in the movements of the North Atlantic, Eurasian, and African Plates during the late Santonian, which led to transgressive inversion of rifts along northern Egypt and consequent folding in the continental interior. The higher contents of detrital components in the Abu Tartur phosphorites compared to the Red Sea and Nile Valley areas suggest more detrital inputs during the deposition of the phosphorites in Abu Tartur. The products of the diagenesis and weathering of these deposits also reflect the variations in the depositional conditions.     

Terpenoid composition and origin of amber from the Cape York Peninsula,Australia

The terpenoid composition of fossil resin from the Cape York Peninsula, Australia has been analysed by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to determine its origin. The pyrolysis products were dominated by cadalene-based C₁₅ bicyclic sesquiterpenoids including some C₃₀–C₃₁ bicadinanes and bicadinenes typical of Class II resin derived from angiosperm plants of Dipterocarpaceae. This observation contrasts with the Araucariaceae (Agathis sp.) source previously suggested for the resin based on Fourier transform infrared (FTIR) analyses. Dipterocarpaceae are not known in Australian vegetation but grow abundantly in Southeast Asia including New Guinea, indicating that the geological origin of the amber is not the Australian mainland but could be traced to Southeast Asia.     

Evolution of drainage patterns on Cape York Peninsula,northeast Queensland

Drainage patterns along passive continental margins are often hypothesised to be the result of drainage disruption following highland uplift and downwarping of the highland flank. Several studies of stream catchments throughout southeast Australia have demonstrated that the opposite tends to be the case in this region because the field evidence favours stream and continental drainage‐divide stability. While significant advances have been made towards understanding this phenomenon in the southeastern corner of the continent, little is known of the evolution of streams and highlands in northeast Australia. Our study examines palaeochannels and fluvial sedimentary units close to the continental drainage divide in six stream catchments along the length of Cape York Peninsula. The results show that four of the catchments (Barron‐Mitchell and Stewart‐Holroyd) have experienced continental divide and drainage stability, whereas the Pascoe‐Wenlock system appears to have experienced westward migration of the continental drainage divide and diversion of the Pascoe River. River diversion here is likely to be a result of the raising of base‐level and flooding of stream channels during the Cretaceous marine transgression and subsequent stream incision by the Pascoe River along structural weaknesses in the underlying strata, following cessation of marine conditions.     

Seismological evidence for compositional variations at the base of the mantle transition zone under Japan Islands

Temperature and water content anomalies just above the 660-km discontinuity under the Japan Islands are estimated from seismological observations. Two sets of seismological observations of P-wave velocity perturbations and depth variations of the 660-km discontinuity are used, which are (1) long-wavelength (~ 500 km) variations from seismic tomography based on a grid parameterization and waveform analysis of ScS reverberations and (2) moderate-wavelength (~ 150 km) variations from seismic tomography with a block parameterization and receiver-function analysis. To estimate temperature and water content anomalies, partial derivatives of velocity and depth variations with respect to temperature and water content determined by mineral physics studies are used. Under Southwest Japan, low temperature and high water-content anomalies are obtained from both sets of seismological observations, which have already been found by a previous study. Under Northeast Japan, however, there are discrepancies between the results estimated from the two data sets, possibly due to the different resolution scales. This discrepancy is dismissed when examining distributions of the temperature and water content anomalies. These anomalies can be grouped into two geographical locations, one group under Southwest Japan, the other under Northeast Japan. The two groups are clearly separated and exhibit common features in both sets of the seismological observations. The grouping is interpreted by a compositional difference between the subducting Pacific slab under Southwest Japan and a normal mantle under Northeast Japan.