Experimental paleotemperature equation for planktonic foraminifera

Small live individuals of Globigerinoides sacculifer which were cultured in the laboratory reached maturity and produced garnets. Fifty to ninety percent of their skeleton weight was deposited under controlled water temperature (14° to 30°C) and water isotopic composition, and a correction was made to account for the isotopic composition of the original skeleton using control groups.Comparison of. the actual growth temperatures with the calculated temperature based on paleotemperature equations for inorganic CaCO₃ indicate that the foraminifera precipitate their CaCO₃ in isotopic equilibrium. Comparison with equations developed for biogenic calcite give a similarly good fit. Linear regression with Craig's (1965) equation yields: $\text{t = ?0.07 + 1.01}\text{t}\text{?}\text{(r= 0.95)}$ where t is the actual growth temperature and $\text{t}\text{?}$ Is the calculated paleotemperature. The intercept and the slope of this linear equation show that the familiar paleotemperature equation developed originally for mollusca carbonate, is equally applicable for the planktonic foraminifer G. sacculifer.Second order regression of the culture temperature and the delta difference (δ¹⁸Oc ? δ¹⁸Ow) yield a correlation coefficient of r = 0.95: $\text{t}\text{?}\text{= 17.0 ? 4.52(δ}{}^{18}\text{Oc ? δ}{}^{18}\text{Ow) + 0.03(δ}{}^{18}\text{Oc ? δ}{}^{18}\text{Ow)}{}^2$$\text{t}\text{?}\text{, δ}{}^{18}\text{Oc}$ and δ¹⁸Ow are the estimated temperature, the isotopic composition of the shell carbonate and the sea water respectively.A possible cause for nonequilibnum isotopic compositions reported earlier for living planktonic foraminifera is the improper combustion of the organic matter.     

陆相断陷盆地的构造层序地层分析

海洋浮游有孔虫中的硼同位素能够反映海水酸碱度的变化,从而为重建大气二氧化碳浓度的变化提供了一种新的手段,有望提供目前极地冰心记录所无法企及的百万年甚至千万年时间尺度上的大气二氧化碳浓度的变化。最近,海洋浮游有孔虫硼同位素的研究在实验分析技术(负热电离质谱法)、实验室偏差、同位素分馏系数、海水硼同位素长期变化以及各种次要因素等方面都取得了长足的进步,尤其是全蒸发负热电离质谱法的建立使硼同位素分析的样品需求量降到纳克级以下。不过,尽管海洋浮游有孔虫中的硼同位素作为大气二氧化碳浓度的替代指标很具有潜力,但还需要进行更加深入地研究。     

Jurassic planktonic foraminifera from the United Kingdom

Unequivocal planktonic foraminifera have been discovered in Oxfordian strata from Dorset and Scotland. These assemblages are, in part, coeval with previously reported occurrences of planktonic taxa in the Oxfordian of Normandy and Seine Maritime (France). Three species are now reported from the United Kingdom for the first time: Globuligerina oxfordiana ( Grigelis, 1958 ), Haeuslerina helvetojurassica ( Haeusler, 1881 ) and Compactogerina sp. cf. C. stellapolaris ( Grigelis, 1977 ). There appears to be a close relationship between the distribution of these planktonic taxa in the UK and a marked sea-level highstand.     

Glacial-interglacial changes in the surface water characteristics of the Andaman Sea: Evidence from stable isotopic ratios of planktonic foraminifera

Stable carbon and oxygen isotopic analyses of the planktonic foraminifera (Globigerinoides ruber) from a deep sea sediment core (GC-1) in the Andaman Sea show high glacial-to-Holocene δ¹⁸O amplitude of 2.1%o which is consistent with previously published records from this marginal basin and suggest increased salinity and/or decreased temperature in the glacial surface waters of this region. A pulse of¹⁸O enrichment during the last deglaciation can be attributed to a Younger Dryas cooling event and/or to a sudden decrease of fresh water influx from the Irrawady and Salween rivers into the Andaman Sea. High δ¹³C values observed during the isotopic stages 2 and 4 are probably due to the enhanced productivity during glacial times in the Andaman Sea.     

Entrainment of planktonic foraminifera: effect of bulk density

Depositional hydrodynamics have been studied using settling rate distributions of Norwegian deep sea sediments (between Jan Mayen Island and the Vøring Plateau), together with Shields’ critical shear stress velocities. Planktonic foraminifera are the dominant sand sized component of these sediments. The bulk density of the foraminifera was calculated from their settling velocity, sieve size and shape. Density decreases from 2·39 g cm^?3 at 0·05 mm diameter to 1·37 g cm^?3 at 0·35 mm diameter. These density and size data were used to construct a threshold sediment movement curve. From the similarity in their Shield's critical shear-stress velocities and the observed correlation of foraminifera size with decreasing percentage of fine fraction, it is concluded that the two components, the sand size foraminifera and the quartz and carbonate silt, are transport-equivalent.     

Dating the Penninic Ocean subduction: new data from planktonic foraminifera

The Penninic Ocean was a side tract of the Central Atlantic Oceanic System intercalated between the European and the Austroalpine plates. Its closure started in the Early Cretaceous, as subduction of the oceanic crust beyond the Austroalpine plate. The sedimentary change on the Austroalpine shelf from pelagic carbonates into deep-water siliciclastics correlated with the denudation of the accretionary wedge resulting from that subduction. Within the Bajuvaric Unit of the Upper Austroalpine, this transition is reflected by the lithostratigraphic boundary between the older Schrambach and the younger Tannheim Formation. This boundary is well exposed in a newly discovered site at Sittendorf, southwest of Vienna. This new outcrop yields an extraordinarily rich planktonic foraminifera assemblage characterized by typical Aptian species belonging to Blowiella, Globigerinelloides, Hedbergella, Leupoldina, and Praehedbergella. A detailed biostratigraphic analysis based on thin-section investigations precisely dated the lithostratigraphic boundary within the lower part of the early Aptian Leupoldina cabri Acme Zone, having an approximate age of 123 Ma. Along with the biostratigraphic analyses, the gamma-log outcrop measurement was a powerful tool in interpreting the stratigraphy and the tectonic setting in the outcrop, which intersects one smaller-scale isoclinal fold.     

西太平洋782A钻孔新生代的有孔虫

大洋钻探工程” 1 2 5航次的 782 A钻孔位于西太平洋菲律宾海东北部 ,井深 4 76.8m。基底为安山岩 ,上覆盖层为中始新统—更新统的沉积层 ,其中保存有低丰度的有孔虫。自下而上可划分出 8个浮游有孔虫带。由于出现 Catapsydrax dissimilis,C.stainforthi为 N5 、N6 带的带化石 ,表明本钻孔存在早中新世的地层。同时由于缺失浮游有孔虫带 P1 5 — P1 6 下部 ,N3上部—N4,N7—N1 1 带的带化石 ,说明在中始新世与晚始新世之间、晚渐新世与早中新世之间、早中新世与中中新世之间存在 3个沉积间断。钻孔中的有孔虫标志本区当时处于温暖亚热带环境。根据不同时期温度的变化 ,可划分出 5个阶段 ,包括 3个偏暖时期和 2个温凉时期。     

Re-evaluation of the phylogeny of Early Cretaceous planktonic foraminifera (Praehedbergellidae)

Tunisia, Ukraine, Russia, the North Sea area and elsewhere have yielded knowledge that the Early Cretaceous planktonic foraminifera are predominantly members of the Praehedbergellidae. The taxonomy and phylogeny of this family have been revised and refined. New generic and specific taxa have been proposed, new phylogenetic lineages have been described, and many type specimens have been imaged by scanning electron microscopy for the first time.Gorbachikella(Hauterivian–Early Aptian) gave rise toPraehedbergella(Late Hauterivian–Late Aptian), evolvingBlefuscuiana,Lilliputianella, and the planospiralBlowiellain the Barremian. The last gave rise toGlobigerinelloidesin the Aptian, from which the macroperforateAlanlordella(and its descendantPlanomalina) evolved in the Albian.Blowiellawas ancestral to taxa with radially elongated chambers (Claviblowiella, Leupoldina, Schackoina).     

Diversity of recent planktonic foraminifera in the southern Indian Ocean and Late Pleistocene paleotemperatures

Planktonic foraminiferal assemblages have been examined in 25 trigger core top samples and 51 piston core top samples collected between latitudes 28° S and 55° S and longitudes 79° E and 120° E from the southern Indian Ocean during cruises of the U.S.N.S. Eltanin. Samples taken from water depths exceeding 4000 m and/or showing evidence of calcium carbonate dissolution were eliminated from further analysis. The final piston core data set consists of 34 samples; the trigger core data set containing 21 samples. A close relationship exists between changes in the planktonic foraminiferal assemblages in the surface sediments and surface water temperatures. Species diversity values were computed for each of the core top assemblages using the Shannon-Wiener Index and the Brillouin Index, each of which takes into consideration the number of species and the proportionment of individuals among the species. The Shannon and Brillouin diversity values for all samples are positively correlated (correlation coefficient (r) = +.999). Regression analysis of latitude versus Shannon diversity values in the trigger core samples clearly shows a decrease in diversity with increasing latitude (r = ?.979). Furthermore, a strong correlation (r = +.977) exists between decreasing species diversity (Shannon) and decreasing average summer-winter temperature of the overlying surface waters. A paleotemperature equation derived from the relationship of diversity in trigger core samples and surface water temperature was used to generate paleotemperature curves for five trigger cores and a 6 m piston core of Late Pleistocene age, located beneath the present position of the Subtropical Convergence. A 7–8° C temperature range is suggested between the interglacial and glacial episodes in this Late Pleistocene sequence, and probably reflects latitudinal shifts of the Subtropical Convergence and Australasian Front during the Late Pleistocene.     

现代浮游有孔虫对南海西南部上升流的响应

现代夏季风系统导致了南海西南部（越南岸外）上升流的发育,但浮游有孔虫对夏季上升流的响应如何尚缺乏实测资料,这不利于准确地利用有孔虫来重建古上升流的活动进而反演过去夏季风的强度变化。本研究利用2014年4月14日至11月1日布放于南海西南部夏季上升流区的时间序列沉积物捕获器材料,详细鉴定并定量统计了其所含浮游有孔虫类型。通过分析样品中浮游有孔虫各属种的通量和百分含量变化,结合区域气候环境资料,探讨南海西南部夏季上升流区浮游有孔虫对夏季风的响应,为古上升流与夏季风研究提供现代依据。研究结果表明初级生产力是控制上升流区浮游有孔虫通量变化的首要因素,喜营养种在上升流发育期增多而寡营养种含量下降。因此高表层生产力指示种,如Neogloboquadrina dutertrei可能是追溯南海西南部夏季上升流变化最可靠的指标。

     

南海西部浮游有孔虫含量与水深关系定量研究

南海西部4°～18°N,1085～115°E海域表层沉积物中有孔虫定量分析表明,从陆架至深海盆区,随着水深增加,底栖有孔虫丰度总体呈下降趋势;而浮游有孔虫在上陆坡区水深200～2 000 m处最丰富,向浅水和深水方向,其丰度均下降,浮游有孔虫百分含量（P）与水深（D）有明显的相关关系。但在陆架区和陆坡－深海盆区,两者关系完全不同：在陆架区随水深增加浮游有孔虫百分含量明显增大,而在陆坡－深海盆区,两者呈负相关关系。经定量拟合水深小于200 m的陆架区,浮游有孔虫含量与水深满足关系式：lnD＝0.021P＋3.208;而在水深大于200 m的陆坡－深海盆区,两者满足D＝－5263P＋52 105.2。这主要是由于陆架区随水深增加,浮游有孔虫增加,但水深大于200 m后,碳酸盐的溶解起主要作用,浮游有孔虫比底栖有孔虫更易于溶解,造成其含量随水深增加而下降。     

Radiolaria,planktonic foraminifera,and stratigraphy of Turonian-lower Coniacian in the Biyuk-Karasu section,Crimea

The first data on the distribution of Radiolaria and planktonic Foraminifera in the section at Biyuk-Karasu River in central part of the Crimean Mountains, are presented. Based on the study of radiolarian findings, the upper Cretaceous deposits of Biyuk-Karasu section are subdivided into the following biostratigraphic units: Alievium superbum-Phaseliforma turovi (middle Turonian), Dactylodiscus longispinus-Patulibracchium (?) quadroastrum (upper Turonian), and Orbiculiforma quadrata-Patellula sp. B (Turonian-Coniacian boundary deposits). The stratigraphic interval of Alievium superbum-Phaseliforma turovi has been previously characterized by the complex of Alievium superbum-Phaseliforma sp. A (middle Turonian, Mt. Chuku section, SW of the Crimean Mountains, and middle Turonian, Mt. Ak, central part of the Crimean Mountains). Based on the study of Foraminifera findings, the following biostratigraphic subdivisions were identified: Whiteinella paradubia (lower-lower part of the middle Turonian), Marginotruncana pseudolinneiana (uppermost middle Turonian), and Marginotruncana coronata (upper Turonian). The complex of beds with Marginotruncana pseudolinneiana and Marginotruncana coronata are comparable to the deposits of zones of same name in the Crimean-Caucasian region.     

A critical evaluation of calcium isotope ratios in tests of planktonic foraminifers

We critically evaluate the applicability of Ca-isotope ratios in planktonic foraminifers as proxy for past sea surface temperatures (SST) and isotope composition of paleo-seawater (δ⁴⁴Ca_sw) reconstructions. Previous studies have shown discrepancies regarding the temperature sensitivity of Ca isotope fractionation in foraminifers of more than one order of magnitude. We present new data from the planktonic foraminifer species Orbulina universa, Globigerinoides sacculifer and Neogloboquadrina pachyderma (sinistral) from culture experiments, multinet deployments and coretop samples. Specimens of G. sacculifer cultured at low salinities (33-34.5) show predominantly no major temperature dependent Ca isotope fractionation, in contrast to previous individuals cultured at higher salinities of 34.5-36. The new data of O. universa are consistent with previously published results, revealing a small but significant temperature sensitivity. Calcium isotope fractionation in tests of N. pachyderma shows a significant variation with temperature, which is not uniform over the total investigated temperature range (−1.6 °C to +10 °C), possibly reflecting the influence of additional controlling factors besides temperature. Controlled dissolution experiments in the laboratory indicate that the Ca-isotope composition of G. sacculifer and N. pachyderma is relatively insensitive to partial dissolution of their tests.Calcium isotope ratios in the planktonic foraminifers G. sacculifer and N. pachyderma (s) reveal a complex Ca isotope fractionation behaviour, which is not yet fully understood. Additional validation studies are crucial to enhance the basic understanding of the calcium isotope systematics in planktic foraminifer shells, and the potential for applying Ca-isotope ratios as proxies for seawater temperature and the oceanic Ca budget.     

Early Eocene planktonic and benthic foraminifera from the Khangiran formation (northeast of Iran)

The Kopet-Dagh sedimentary basin is located in northeast of Iran and southeast of Turkmenistan in the Middle East. The Khangiran formation represents the last marine deposition in the Kopet-Dagh sedimentary basin. The early Eocene planktonic and benthic foraminifera from the Khangiran formation which belongs to the lower 376 m thickness of this formation are identified and biostratigraphically evaluated. Due to rarity of Morozovella species, planktonic foraminiferal zonation was difficult to determine in this formation. The determination of upper part of the late Paleocene for the lower 124 m of this formation is according to the lowest occurrence of Acarinina sibaiyaensis species. From E₅ to near middle of E₇ biozone, increasing trend of Acarinina frequency and a peak in Morozovella species and decreasing trend of frequency of Subbotina and Pseudohastigerina species indicate the warm and oligotrophic condition of the seawater during sedimentation of the studied interval. Toward the Ypresian-Lutetian boundary, the increasing trend of Pseudohastigerina and Subbotina species and decreasing in frequency of Acarinina species suggest the low-oxygen level, eutrophic and intermediate condition of the seawater. In this formation, the high abundance of the epifaunal taxa such as Anomalinoides spp., Cibicidoides spp., Gyroidinoides spp., and Lenticulina spp. from the base (late Paleocene sediments) up to E₆ biozone reflects oligotrophic and oxic shallow water conditions. The occurrence of several peaks in abundance of Bulimina and Uvigerina species at the Ypresian/Lutetian boundary suggests eutrophic condition. These paleoecological conditions could be correlated with fluctuations in the numbers of the planktonic foraminifera.     

Benthonic and planktonic foraminifera in relation to the Early Holocene stagnation in the Ionian Basin, Central Mediterranean

The distribution patterns of benthonic and planktonic foraminifera in cores from the Ionian Basin, central Mediterranean, were investigated in relation to the deposition of sapropel S-1. The sapropel is a dark organic-rich sediment deposited under anoxic conditions during the last marine stagnation in the Early Holocene. The major divisions between both benthonic and planktonic faunas correspond to changes in the core lithology and coincide with the transitions between pre-sapropel, sapropel/'oxidized layer' and post-sapropel sediments. The faunal evidence shows that the oxidized layer belongs to the sapropel sequence. The planktonic faunas have the same species composition as in the sapropel sediment and the high density of planktonic species continues into the oxidized layer. The oxidized layer is devoid of a benthonic fauna or contains a 'sapropel-associated' fauna composed of infaunal species with an affinity to high supply of organic material material and low oxygen. High depletion in the heavy oxygen isotope in the oxidized layer substantiates the faunal evidence. A peak in abundance of the planktonic species Globorotalia inflata at the top of the oxidized layer marks the time when turnover of the water masses ended the stagnation phase and sapropel sedimentation in the Ionian Basin at about 6000 BP. The distribution of the benthonic and planktonic foraminifera shows that the sapropel in the central part of the Ionian Basin was originally almost twice as thick as it is today. When oxygen returned to the deep sediments the top of the sapropel was oxidized to 4–7 cm below its original surface. Only the lower part of the sapropel is preserved. The remainder is now a red laminated layer, the 'oxidized layer'.     

New data on the trace metal composition of the planktonic foraminifera microfossils of the Atlantic Ocean

This paper reports new data on the trace metal composition of planktonic foraminifer shells from surface sediments and cores (fraction >0.1 mm) in the central part of the Atlantic Ocean. This investigation has made it possible to identify a considerable accumulation of trace elements from water due to calcite entering into the crystal lattice under biomineralization and adsorption on the shell surface and pores, despite the fact that the shells are depleted in trace elements relative to pelagic clays. The trace element content in planktonic foraminifer microfossils is characterized by temporal variability, which is the most pronounced in long cores (Holocene–Upper Pleistocene) and reflects the sedimentation paleoenvironment in the ocean.     

Comparison of two potential strategies of planktonic foraminifera for house building: Mg or H removal?

Marine organisms must possess strategies enabling them to initiate calcite precipitation despite the unfavorable conditions for inorganic precipitation in surface seawater. These strategies are poorly understood. Here we compare two potential strategies of marine calcifyers to manipulate seawater chemistry in order to initiate calcite precipitation: Removal of Mg²⁺ and H⁺ ions from seawater solutions. An experimental setup was used to monitor the onset of inorganic precipitation on seed crystals as a function of the Mg²⁺ concentration and pH in artificial seawater. We focused on precipitation rates typical for biogenic calcification in planktonic foraminifera (∼10⁻³ mol m⁻² h⁻¹) and time scales typical for the initiation of calcification in these organisms (minutes to hours). We find that the carbonate ion concentration has to increase by a factor of ∼13 when [Mg²⁺] increases from 0 to 53 mmol kg⁻¹ in order to maintain a typical biogenic precipitation rate. Model calculations for the energy requirement for various scenarios of Mg²⁺ and H⁺ removal including Ca²⁺ exchange and CO₂ diffusion are presented. We conclude that the more cost-effective strategy to initiate calcite precipitation in foraminifera is H⁺ removal, rather than Mg²⁺ removal.     

Model for kinetic effects on calcium isotope fractionation (δCa) in inorganic aragonite and cultured planktonic foraminifera

The calcium isotope ratios (δ⁴⁴Ca = [(⁴⁴Ca/⁴⁰Ca)_sample/(⁴⁴Ca/⁴⁰Ca)_standard −1] · 1000) of Orbulina universa and of inorganically precipitated aragonite are positively correlated to temperature. The slopes of 0.019 and 0.015‰ °C⁻¹, respectively, are a factor of 13 and 16 times smaller than the previously determined fractionation from a second foraminifera, Globigerinoides sacculifer, having a slope of about 0.24‰ °C⁻¹. The observation that δ⁴⁴Ca is positively correlated to temperature is opposite in sign to the oxygen isotopic fractionation (δ¹⁸O) in calcium carbonate (CaCO₃). These observations are explained by a model which considers that Ca²⁺-ions forming ionic bonds are affected by kinetic fractionation only, whereas covalently bound atoms like oxygen are affected by kinetic and equilibrium fractionation. From thermodynamic consideration of kinetic isotope fractionation, it can be shown that the slope of the enrichment factor α(T) is mass-dependent. However, for O. universa and the inorganic precipitates, the calculated mass of about 520 ± 60 and 640 ± 70 amu (atomic mass units) is not compatible with the expected ion mass for ⁴⁰Ca and ⁴⁴Ca. To reconcile this discrepancy, we propose that Ca diffusion and δ⁴⁴Ca isotope fractionation at liquid/solid transitions involves Ca²⁺-aquocomplexes (Ca[H₂O]_n²⁺ · mH₂O) rather than pure Ca²⁺-ion diffusion. From our measurements we calculate that such a hypothesized Ca²⁺-aquocomplex correlates to a hydration number of up to 25 water molecules (490 amu). For O. universa we propose that their biologically mediated Ca isotope fractionation resembles fractionation during inorganic precipitation of CaCO₃ in seawater. To explain the different Ca isotope fractionation in O. universa and in G. sacculifer, we suggest that the latter species actively dehydrates the Ca²⁺-aquocomplex before calcification takes place. The very different temperature response of Ca isotopes in the two species suggests that the use of δ⁴⁴Ca as a temperature proxy will require careful study of species effects.     

Trace/minor element:calcium ratios in cultured benthic foraminifera. Part II: Ontogenetic variation

Ontogenetic (developmental stage) measurements of Mg/Ca and Sr/Ca were made on the benthic foraminifer Bulimina aculeata, which were cultured under controlled physicochemical conditions of temperature, pH, alkalinity, salinity, and trace- and minor-element concentrations. We utilized two methods of ontogenetic sampling—whole specimens progressively increasing in length and laser microdissection of a single specimen with subsequent analysis of dissected portions. A novel high-resolution laser-microdissection (HRLM) method allowed for precise (10 μm) cuts of the foraminiferal tests (shells) along the geometrically complex sutures distinguishing individual chambers. This new microdissection method limited sample loss and cross-contamination between foraminiferal chambers. Little or no variation in D_Sr was observed at different foraminiferal developmental stages. Conversely, D_Mg was enriched during a mid-developmental stage of whole-specimen samples (150-225 μm D_Mg = 1.6 × 10⁻³) compared to earlier and later stages (<150 μm, >225 μm D_Mg = 8.3 × 10⁻⁴). Further analysis of HRLM ontogenetic samples showed a larger, age-dependent D_Mg signature variation. This increase in shell Mg/Ca may contribute substantially to the measured inter-individual variability in Mg/Ca temperature prediction for cultured B. aculeata. Due to relatively large Mg/Ca inter- and intra-individual variability, measuring similar-size foraminiferal samples may improve the precision of paleotemperature prediction. Additionally, partial dissolution of the highest ontogenetically Mg-enriched calcite (D_Mg = 1.3 × 10⁻²-1.6 × 10⁻²) may occur in undersaturated bottom-water environments or during reductive cleaning procedures. Thus, the calcite phases remaining after partial dissolution by either natural or laboratory cleaning processes may not accurately represent the calcification environment.     

Effects of seawater carbonate ion concentration and temperature on shell U, Mg, and Sr in cultured planktonic foraminifera

We investigate the sensitivity of U/Ca, Mg/Ca, and Sr/Ca to changes in seawater [CO₃²⁻] and temperature in calcite produced by the two planktonic foraminifera species, Orbulina universa and Globigerina bulloides, in laboratory culture experiments. Our results demonstrate that at constant temperature, U/Ca in O. universa decreases by 25 ± 7% per 100 μmol [CO₃²⁻] kg⁻¹, as seawater [CO₃²⁻] increases from 110 to 470 μmol kg⁻¹. Results from G. bulloides suggest a similar relationship, but U/Ca is consistently offset by ∼+40% at the same environmental [CO₃²⁻]. In O. universa, U/Ca is insensitive to temperature between 15°C and 25°C. Applying the O. universa relationship to three U/Ca records from a related species, Globigerinoides sacculifer, we estimate that Caribbean and tropical Atlantic [CO₃²⁻] was 110 ± 70 μmol kg⁻¹ and 80 ± 40 μmol kg⁻¹ higher, respectively, during the last glacial period relative to the Holocene. This result is consistent with estimates of the glacial-interglacial change in surface water [CO₃²⁻] based on both modeling and on boron isotope pH estimates. In settings where the addition of U by diagenetic processes is not a factor, down-core records of foraminiferal U/Ca have potential to provide information about changes in the ocean’s carbonate concentration.Below ambient pH (pH < 8.2), Mg/Ca decreased by 7 ± 5% (O. universa) to 16 ± 6% (G. bulloides) per 0.1 unit increase in pH. Above ambient pH, the change in Mg/Ca was not significant for either species. This result suggests that Mg/Ca-based paleotemperature estimates for the Quaternary, during which surface-ocean pH has been at or above modern levels, have not been biased by variations in surface-water pH. Sr/Ca increased linearly by 1.6 ± 0.4% per 0.1 unit increase in pH. Shell Mg/Ca increased exponentially with temperature in O. universa, where Mg/Ca = 0.85 exp (0.096*T), whereas the change in Sr/Ca with temperature was within the reproducibility of replicate measurements.