海南岛全新世海滩岩的胶结作用与成岩环境的关系

我国海南岛及南海诸岛沿岸,广泛发育海滩岩。1980年我队赴海南岛考察现代沉积时,对海滩岩的分布、岩性特征及其与周围环境的关系进行了观察和采样。样品采自崖县鹿回头三亚湾水尾岭海蚀崖、西洲岛、小东海、东瑁岛、西瑁岛、天涯海角,乐东县莺歌海,文昌县渔业等地(图1)。有关的地质、地貌及岩性特征等,已有许多描述,对海滩岩的岩石学及成岩作用也有许多研究。本文侧重探讨海滩岩的胶结作用及与成岩环境的关系。     

A study on the adsorption of chromium on laterite from Guizhou Province,China

The adsorption behaviors of Cr(VI) on laterite from Guizhou Province were studied in this paper, and the adsorption mechanism was discussed as well. Results showed that different mineral compositions in the laterite would cause differences in the capacity of laterite to absorb Cr(VI). Gibbsite, iron oxide minerals and non-crystalloids are the main contributors to enhancing the capacity of laterite to absorb Cr(VI). The pH of the solution is an important factor affecting the adsorption of Cr(VI) on laterite. Acidic environment (pH=2–5) is favorable to the adsorption of Cr(VI). The amount of adsorbed Cr(VI) decreases with increasing pH of the solution. With increasing initial concentrations of Cr(VI), the amount of adsorbed Cr(VI) increases first, and then decreases. The optimal adsorption concentration of Cr(VI) on laterite is 250 μg/mL. The adsorption of Cr(VI) on laterite is a rapid process, about 80% Cr(VI) will be adsorbed within 2 hours. And the adsorption of Cr(VI) on kaolinite is a slow process.     

辽宁盘岭矿集区花岗岩锆石SHRIMP U-Pb年龄、Hf同位素组成及地质意义

辽宁盘岭矿集区产出在辽吉裂谷中段的草河口—草河城—黑峪一带,是一处典型的古元古代沉积盆地和多金属矿集区。矿区内发育有早白垩世的北大砬子岩体和古元古代高丽墩台岩体,与本区的矿化作用密切相关。北大砬子岩体锆石SHRIMP U-Pb年龄加权平均值为(123.9±2.2)Ma,高丽墩台岩体锆石SHRIMP U-Pb年龄加权平均值为(1 872±13)Ma。北大砬子岩体εHf(0)为负值,εHf(t)为负值(-16.86~-10.95),说明北大砬子岩体形成时壳源物质成分占主导地位,单阶段Hf模式年龄(TDM)平均为1 339 Ma,两阶段Hf模式年龄(TDMC)平均为2 043 Ma;高丽墩台岩体εHf(0)为负值,εHf(t)为正值(0.29~4.64),说明高丽墩台岩体形成时壳源物质成分占主导地位,并有地幔物质混染,单阶段Hf模式年龄(TDM)平均为2 171 Ma,两阶段Hf模式年龄(TDMC)平均为2 355 Ma。结合岩石地球化学特征得出:北大砬子岩体具有高钾钙碱性岩浆岩特征,为较高分异的过铝质I型花岗岩,是底侵岩浆提供热动力使下地壳物质部分熔融的产物,属于晚中生代大陆边缘岩浆弧环境,其与进入早白垩世古太平洋板块俯冲作用密切相关,岩浆活动直接影响盘岭矿集区内一期铜、铅、锌、钼等矿化作用;高丽墩台岩体具有低钾(拉斑)岩浆岩特征,为较高分异的过铝质I型花岗岩,是热的玄武质熔体加热下地壳使之熔融的产物,且可能有地幔物质贡献,岩体侵入诱发的一系列断裂(包括层间断裂)控制着矿集区内矿脉及岩脉的空间分布。     

二连盆地赛汉塔拉凹陷腾二段低熟油地球化学特征和油源对比

赛汉塔拉凹陷位于二连盆地腾格尔坳陷西部,是二连盆地低熟油分布区.采用有机地球化学和生物标志物分析方法,对赛汉塔拉凹陷下白垩统腾二段低熟原油和油砂样品进行了地球化学特征和油源对比研究.赛汉塔拉凹陷腾二段低熟油具有饱和烃含量相对较低、非烃和沥青质含量相对较高的族组成特征,正构烷烃分布以前峰型为主,主峰碳为C21或C23,P...     

广西中部泥盆系的多金属-重晶石矿床和热水沉积作用

广西中部的来宾-武宣-象州地区是泥盆系象州型的典型地区,又发育较多的铜、铅、锌多金属脉状矿床和层状-脉状重晶石矿床。过去工作主要是对单个矿区或矿带作评价,而对各矿种间的关系,对区域中成矿作用的联系讨论较少。本文研究了该区泥盆系中的多金属矿与重晶石砂的时空关系和地球化学特征,认为是由统一的上泥盆世热水对流体系形成的热水沉积矿床。不同的矿种,矿体的不同产状由对流体系的特点和地质环境的差异所决定。     

Metamorphism of the Crystalline Basement of Central Chile

The metamorphic basement of the Cordillera de la Costa, in CentralChile, consists mainly of slate, meta-sandstone, phyllite, andmica schist but contains small quantities of greenschist. Thegreater part of the basement is comprised in the Curepto series,and is characterized by dynamo-metamorphism whose intensityincreases westward. East of this is the smaller Nirivilo series,characterized by contact metamorphism whose intensity increaseseastward toward a granodiorite batholith. At the northern endof the metamorphic belt lies the Pichilemu series, in whichthe metamorphism is dynamo-thermal and increases in intensityto the east. The rocks in the first two areas are divisibleinto zones that trend north-north-east, essentially parallelto the margin of the batholith and to the Pacific coast; butin the Pichilemu area the zoning trends north-west. In the Cureptoseries three zones were distinguished; these are, in order fromeast to west: (1) a muscovite-chlorite(-albite) slate zone,(2) a muscovite-biotite(-albite) phyllite zone, and (3) a muscovite-chlorite-albite(±garnet) schist zone. The rocks in all three zones belongto the greenschist facies; the chlorite in the third zone isbelieved to be a product of H metasomatism. In the much narrowerNirivilo area no zones were mapped, but the following eastwardsuccession of critical assemblages was recognized: (1) muscovite-biotite-chlorite-albite;(2) muscovite-biotite-chlorite-andalusite-albite; (3) biotite-muscovite-andalusite-oligoclase;(4) biotite(± muscovite)-andalusite-sillimanite (or cordierite).The muscovite in the rocks that have undergone highgrade metamorphismis largely of metasomatic origin. Part of the sillimanite hasbeen formed at the expense of biotite and andalusite. In mostof the Nirivilo area the most strongly metamorphosed rocks areof the hornblende-hornfels facies, but small parts of that areamay contain rocks of the pyroxene-hornfels facies. The Pichilemuarea comprises the following zones and subzones: (1) a biotitezone, which includes (a) a muscovite-chlorite-biotite-albitesubzone and (b) a muscovite-biotite-albite subzone; (2) a garnet-oligoclasezone; (3) a staurolite-andalusite zone; (4) a muscovite-sillimanitezone; and (5) a sillimanite-orthoclase zone which includes (a)a sillimanite-orthoclase subzone and (b) a sillimanite-orthoclase-cordierite-almandinesubzone. Some thermal metamorphism is superimposed on the regionalmetamorphism. The facies grade from the greenschist to the granuliteor intermediate between the granulite and the amphibolite facies.The three series represent different pressure conditions: theNirivilo series corresponds to a low-pressure (contact) type,Pichilemu represents a low-pressure intermediate, dynamo-thermaltype, and Curepto is a dynamothermal, high-pressure intermediatetype series. The Curepto area was affected first, the Pichilemuarea next, and the Nirivilo area last. The metamorphism in allthree series is thought to have occurred during a single tectoniccycle within Late Paleozoic time, but it was probably interruptedby periods of erosional unloading. The width of the contactaureole is thought to have been determined by the irregularexpansion of the batholith. The analogy between the metamorphicseries of the Cordillera de la Costa and Miyashiro's circum-Pacificpaired belts is briefly discussed.     

基于成分数据分析和能谱-面积分形模型的鄂西黄陵背斜化探异常识别

鄂西黄陵背斜地区虽已发现众多矿点,但是矿床规模较小,找矿潜力不明。由于区内植被茂盛、覆盖严重,致使地质异常信息被削弱或掩盖,对进一步找矿工作造成了严重干扰。本次研究使用成分数据分析和能谱-面积（S-A）分形模型识别与金矿化相关的异常,结果表明：（1）等距对数比（ILR）变换后的主成分分析结果相比对数（Log）变换更能够反应元素的共生组合规律,第一主成分（PC1）元素组合为Au-Cu-Ag,且Au元素占有最大的载荷,与金矿密切相关,PC1元素组合异常的分布模式与矿点的分布更加吻合;（2） S-A方法抑制了黄陵背斜区域水系沉积物的背景模式,增强了异常模式;（3）根据地质特征和以往勘查工作情况,圈定了三处找矿远景区,为该地区金矿下一步勘查工作提供了重要依据。     

大贵州滩二叠系—三叠系界线附近锶同位素组成特征

位于贵州南部的“大贵州滩”上,二叠系—三叠系界线附近地层为一套连续的发育完整的碳酸盐岩。二叠系顶部主要为厚层生物屑泥粒灰岩,而三叠系底部则主要为钙质微生物骨架灰岩及厚层粒泥灰岩。穿过二叠系—三叠系界线的取样累计厚度81m,二叠系和三叠系大致各占一半的厚度,共取样品91件,n(87Sr)/n(86Sr)值变化在0.707269～0.707409之间,平均为0.707327,低于现代海水的锶同位素比值的平均值（0.7090737）。锶同位素比值变化曲线表明从晚二叠世末期到早三叠世初期,同位素比值虽小幅度的起伏波动频繁,但总体上没有明显变化,三叠系底部的平均值（0.707330）略高于二叠系顶部的平均值（0.707323）。大贵州滩晚二叠世末至早三叠世初锶同位素组成的总体演化趋势与扬子台地及世界其它地方同时期的锶同位素组成的演化趋势（呈急剧的上升）不同,造成这种状况的原因可能是在全球事件控制的大背景下,由于大贵州滩特殊的环境条件,陆源物质对其影响小,导致了壳源锶对锶同位素组成的制约作用减弱,因而锶同位素组成未发生明显变化。     

我国首次发现的锌—砷黝铜矿

锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322,粉末衍射强线是2.98,1.82,1.56。     

Origin of the difference in the distribution behavior of tellurium and selenium in a soil-water system

The distribution behavior of tellurium (Te) between soil and water in a synthetic soil-water system was studied coupled with the speciation of Te both in soil and water phases by using X-ray absorption fine structure (XAFS) spectroscopy and a high-performance liquid chromatography connected to an ICP-MS (HPLC-ICP-MS), respectively. The results were compared with a similar data set for Se, which was simultaneously obtained in this study. The oxidation states and host phases of Te and Se in the soil samples were given by XAFS, while the oxidation states in water were given by HPLC-ICP-MS. It was found that both Te and Se in soil are mainly associated with Fe(III) hydroxides under oxic conditions. From the EXAFS analyses, the outer-sphere complex is important for the Se(VI) sorbed on Fe(III) hydroxides in soils, while Se(IV), Te(IV), and Te(VI) form inner-sphere complexes. Under reducing condition, it was found that Te(0) and Se(0) species were formed and that Se was more readily reduced to Se(0) than Te, as is predicted from their Eh-pH diagrams. The reduction process from hexavalent to zerovalent species was different between Se and Te, that is, the direct reduction from Se(VI) to Se(0) was observed for Se, while Te was reduced stepwise from Te(VI) to Te(0) via Te(IV). In terms of the distribution between soil and water, Se distribution to water was much higher than that of Te under wide redox conditions. For Se, selenate is the predominant species in water even under reducing condition due to the much higher solubility of Se(VI) than Se(IV). Furthermore, a much smaller distribution of Te in water was primarily due to the larger affinities of Te(IV) and Te(VI) to Fe(III) hydroxides than Se(VI), which originates from the formation of the inner-sphere complexes of Te(IV) and Te(VI) to Fe(III) hydroxides.     

攀枝花大田地区前震旦纪斜长角闪岩地球化学特征及构造意义

对攀枝花大田地区斜长角闪岩进行了系统的主微量地球化学特征、锆石LA-ICP-MS U-Pb年代学以及Lu-Hf同位素特征研究.结果表明:斜长角闪岩的SiO₂含量为47.88%~50.05%,原岩为亚碱性-碱性玄武岩.斜长角闪岩稀土总量(ΣREE)较高,稀土元素配分模式为轻稀土富集的右倾型,与洋岛玄武岩相似.微量元素原始地幔标准化蛛网图为"隆起"型,与板内玄武岩特征类似.Zr/Nb、Hf/Th等比值均表明其与板内玄武岩类似,而与岛弧玄武岩具有明显的差异.锆石U-Pb定年结果表明岩浆结晶年龄为816.0~833.6 Ma,同期岩浆结晶锆石的ε_Hf(t)值在-6.8~+3.8之间,其岩浆源区为与OIB类似的富集地幔源区且受到了地壳物质的混染.综合上述资料,认为其形成于Rodinia超级地幔柱活动导致的大陆裂谷环境.      

对于氟碳钡铈矿（Cordylite—Ce）成分与结构的质疑

本文讨论了氟碳钡铈矿的成分和结构问题。发现氟碳钡铈矿的成分、密度、折射率三者间的一致性参数很差,晶体结构与光性和空间群相矛盾,单个大阳离子的平均占有体积远大于同类矿物的平均占有体积,它的晶体结构与同类矿物不可类比。由于受当时条件的限制,在以往有关氟碳钡铈矿的成分和结构的资料中存在着一些明显的错误,有必要对其进行重新定义。其结构化学式应改为:(Na_(1-x),Ca_(0·5x))BaCe_2(CO_3)_4F。     

锌水绿矾在自然界发现和研究

锌水绿矾产于陕西省南部红土石黄铁矿矿床氧化带。集合体呈钟乳状或皮壳状，单晶为短柱状和不规则粒状，极易溶于水。颜色为黄绿色或翠绿色。主要化学成分：ZnO16．35％，FeO8．86％，SO328．30％，H2O44．33％。分子式为（Zn，Fe）SO4·7H2O。主要X射线粉晶谱线是：0．4880（100），0．2739（80），0．5439（30），0．3225（30）和0．2476（30）um。它的化学成分和粉晶数据均与水绿矾（FeSO47H2O）或人工合成的锌水绿矾相似。     

新疆喀拉通克Y1含矿岩体的岩石化学特征及其与成矿的关系

喀拉通克Ｙ１含矿岩体岩石类型属铁质基性岩类，岩体为单式岩体，具富镁、铁、碱、低钙贫铝的特点。组成岩体的各岩相是同一母岩浆结晶分异的产物。原始岩浆为来自上地幔的拉斑玄武岩浆。岩体锶初始比值约为０．７０３３，形成时代约为２９１Ｍａ。在岩浆结晶分异作用下，氧化物组分的变化使硫化物熔浆与硅酸盐熔浆发生分离，并在重力作用下聚积形成铜镍硫化物富矿。     

膨润土负载纳米铁去除地下水中六价铬研究

随着人民生活水平的提高和城市化进程的加快,有机污染物及重金属高强度场地污染对人类健康、生态环境及社会安全构成了严重威胁。地下水中的重金属Cr(Ⅵ)污染逐渐受到重视,纳米零价铁可以有效地将六价铬还原成三价铬,使其沉淀固定下来,从而将污染源区的污染物消减固定,防止其向周围扩散。然而由于纳米铁颗粒微小,易被氧化,极易团聚,自身活性受到限制,因此,纳米铁的分散性、稳定性、良好活性研究至关重要。采用低成本环境友好型粘土矿膨润土作为负载材料制备膨润土负载纳米铁（B-NZVI）,批实验和柱实验研究B NZVI去除模拟地下水中Cr(Ⅵ)。结果表明：(1)自制的膨润土负载纳米铁个体呈球形,呈分散状负载于膨润土;(2)相同铁含量的B-NZVI处理Cr(Ⅵ)的效率远大于纳米铁,还原反应符合伪一级反应动力学模型,表观速率常数K随着B NZVI初始浓度的减小而减小;(3)B NZVI在石英砂柱中基本无迁移,适用于点源污染,Cr(Ⅵ)穿透曲线为B-NZVI的实际应用提供了理论和实验基础。     

岩石矿物数据处理微型计算机软件系统研制

微型计算机是国际上近年来迅速发展起来的一个重要分支,它具有价廉、方便、体积小、多效能等优点,正在向各个领域普及。在岩石学、矿物学研究领域中,随着科学技术的发展和研究工作的深入,能获得的数据越来越多,数据处理量也越来越大。有的数据处理特别繁琐,要花费大量时间,比如标准矿物分子计算法,有的是手算无法进行的,如三斜晶系的晶胞参数修正。1983年,作者利用美国Cromemco Ⅱ微型计算机,研制成功岩石矿物数据处理微型计算机软件系统(PM-C2系统),这个系统包括岩石化学、矿物分子式、温度压力、晶胞参数修正等程序。     

Accurate determination of Fe(II) concentrations in the presence of a very high soluble Fe(III) background

Analytical methods used for determining dissolved Fe(II) often yield inaccurate results in the presence of high Fe(III) concentrations. Accurate analysis of Fe(II) in solution when it is less than 1% of the total dissolved Fe concentration (Fe_T) is sometimes required in both geochemical and environmental studies. For example, such analysis is imperative for obtaining the ratio Fe(II)/Fe(III) in rocks, soils and sediments, for determining the kinetic constants of Fe(II) oxidation in chemical or biochemical systems operating at low pH, and is also important in environmental engineering projects, e.g. for proper control of the regeneration step (oxidation of Fe(II) into Fe(III)) applied in ferric-based gas desulphurization processes. In this work a method capable of yielding accurate Fe(II) concentrations at Fe(II) to Fe_T ratios as low as 0.05% is presented. The method is based on a pretreatment procedure designed to separate Fe(II) species from Fe(III) species in solution without changing the original Fe(II) concentration. Once separated, a modified phenanthroline method is used to determine the Fe(II) concentration, in the virtual absence of Fe(III) species. The pretreatment procedure consists of pH elevation to pH 4.2–4.65 using NaHCO₃ under N₂(g) environment, followed by filtration of the solid ferric oxides formed, and subsequent acidification of the Fe(II)-containing filtrate. Accuracy of Fe(II) analyses obtained for samples (Fe(II)/Fe_T ratios between 2% and 0.05%) to which the described pretreatment was applied was >95%. Elevating pH to above 4.65 during pretreatment was shown to result in a higher error in Fe(II) determination, likely resulting from adsorption of Fe(II) species and their removal from solution with the ferric oxide precipitate.     

浙江遂昌治岭头金矿床黄铁矿的化学成分标型研究

对遂昌治岭头金矿床 3个矿段 (东矿段、中矿段、西矿段 )的黄铁矿进行了化学成分标型特征的研究。指出黄铁矿中铁、硫主元素的含量 ,钴、镍含量及比值 ,硒、碲含量及比值均为本矿床的成因系沉积后经热液叠加提供了比较可靠的依据。黄铁矿中的 w( Cu) /w( Zn)、w ( Ag) /w ( Zn)、w ( Pb) /w ( Zn)值为本矿床提供了成矿信息 ,认为西矿段见矿部位矿体向下延伸要大于中矿段 ,指出了进一步找矿的前景。     

广西柳桥深水相二叠系/三叠系界线剖面有机碳同位素地层学对比研究及事件响应

研究了广西柳桥地区东攀剖面有机碳同位素的组成,并和浙江煤山剖面进行了对比。结果表明东攀剖面在1δ3Corg变化趋势上,既具有全球PTB剖面普遍存在的共性,又具有其独特性。在东攀剖面一个显著的1δ3Corg负漂移出现在事件界线(EB)之上和二叠系/三叠系界线(PTB)之下,这与煤山剖面具有相似性。显著的1δ3Corg负漂移指示了P/T之交生物绝灭后海水表层水原始生产率的降低以及大气和海水中CO2含量的增加,并得到放射虫绝灭事件、火山事件和海退事件的响应。煤山剖面1δ3Corg负漂移从第27层就开始向13C富集的方向恢复,而东攀剖面1δ3Corg在下Induan阶仍持续亏损,表明东攀剖面早三叠世的生物复苏明显滞后于煤山剖面的。