海南岛全新世海滩岩的胶结作用与成岩环境的关系

我国海南岛及南海诸岛沿岸,广泛发育海滩岩。1980年我队赴海南岛考察现代沉积时,对海滩岩的分布、岩性特征及其与周围环境的关系进行了观察和采样。样品采自崖县鹿回头三亚湾水尾岭海蚀崖、西洲岛、小东海、东瑁岛、西瑁岛、天涯海角,乐东县莺歌海,文昌县渔业等地(图1)。有关的地质、地貌及岩性特征等,已有许多描述,对海滩岩的岩石学及成岩作用也有许多研究。本文侧重探讨海滩岩的胶结作用及与成岩环境的关系。     

辽宁盘岭矿集区花岗岩锆石SHRIMP U-Pb年龄、Hf同位素组成及地质意义

辽宁盘岭矿集区产出在辽吉裂谷中段的草河口—草河城—黑峪一带,是一处典型的古元古代沉积盆地和多金属矿集区。矿区内发育有早白垩世的北大砬子岩体和古元古代高丽墩台岩体,与本区的矿化作用密切相关。北大砬子岩体锆石SHRIMP U-Pb年龄加权平均值为(123.9±2.2)Ma,高丽墩台岩体锆石SHRIMP U-Pb年龄加权平均值为(1 872±13)Ma。北大砬子岩体εHf(0)为负值,εHf(t)为负值(-16.86~-10.95),说明北大砬子岩体形成时壳源物质成分占主导地位,单阶段Hf模式年龄(TDM)平均为1 339 Ma,两阶段Hf模式年龄(TDMC)平均为2 043 Ma;高丽墩台岩体εHf(0)为负值,εHf(t)为正值(0.29~4.64),说明高丽墩台岩体形成时壳源物质成分占主导地位,并有地幔物质混染,单阶段Hf模式年龄(TDM)平均为2 171 Ma,两阶段Hf模式年龄(TDMC)平均为2 355 Ma。结合岩石地球化学特征得出:北大砬子岩体具有高钾钙碱性岩浆岩特征,为较高分异的过铝质I型花岗岩,是底侵岩浆提供热动力使下地壳物质部分熔融的产物,属于晚中生代大陆边缘岩浆弧环境,其与进入早白垩世古太平洋板块俯冲作用密切相关,岩浆活动直接影响盘岭矿集区内一期铜、铅、锌、钼等矿化作用;高丽墩台岩体具有低钾(拉斑)岩浆岩特征,为较高分异的过铝质I型花岗岩,是热的玄武质熔体加热下地壳使之熔融的产物,且可能有地幔物质贡献,岩体侵入诱发的一系列断裂(包括层间断裂)控制着矿集区内矿脉及岩脉的空间分布。     

A study on the adsorption of chromium on laterite from Guizhou Province,China

The adsorption behaviors of Cr(VI) on laterite from Guizhou Province were studied in this paper, and the adsorption mechanism was discussed as well. Results showed that different mineral compositions in the laterite would cause differences in the capacity of laterite to absorb Cr(VI). Gibbsite, iron oxide minerals and non-crystalloids are the main contributors to enhancing the capacity of laterite to absorb Cr(VI). The pH of the solution is an important factor affecting the adsorption of Cr(VI) on laterite. Acidic environment (pH=2–5) is favorable to the adsorption of Cr(VI). The amount of adsorbed Cr(VI) decreases with increasing pH of the solution. With increasing initial concentrations of Cr(VI), the amount of adsorbed Cr(VI) increases first, and then decreases. The optimal adsorption concentration of Cr(VI) on laterite is 250 μg/mL. The adsorption of Cr(VI) on laterite is a rapid process, about 80% Cr(VI) will be adsorbed within 2 hours. And the adsorption of Cr(VI) on kaolinite is a slow process.     

岩石矿物数据处理微型计算机软件系统研制

微型计算机是国际上近年来迅速发展起来的一个重要分支,它具有价廉、方便、体积小、多效能等优点,正在向各个领域普及。在岩石学、矿物学研究领域中,随着科学技术的发展和研究工作的深入,能获得的数据越来越多,数据处理量也越来越大。有的数据处理特别繁琐,要花费大量时间,比如标准矿物分子计算法,有的是手算无法进行的,如三斜晶系的晶胞参数修正。1983年,作者利用美国Cromemco Ⅱ微型计算机,研制成功岩石矿物数据处理微型计算机软件系统(PM-C2系统),这个系统包括岩石化学、矿物分子式、温度压力、晶胞参数修正等程序。     

二连盆地赛汉塔拉凹陷腾二段低熟油地球化学特征和油源对比

赛汉塔拉凹陷位于二连盆地腾格尔坳陷西部,是二连盆地低熟油分布区.采用有机地球化学和生物标志物分析方法,对赛汉塔拉凹陷下白垩统腾二段低熟原油和油砂样品进行了地球化学特征和油源对比研究.赛汉塔拉凹陷腾二段低熟油具有饱和烃含量相对较低、非烃和沥青质含量相对较高的族组成特征,正构烷烃分布以前峰型为主,主峰碳为C21或C23,P...     

广西中部泥盆系的多金属-重晶石矿床和热水沉积作用

广西中部的来宾-武宣-象州地区是泥盆系象州型的典型地区,又发育较多的铜、铅、锌多金属脉状矿床和层状-脉状重晶石矿床。过去工作主要是对单个矿区或矿带作评价,而对各矿种间的关系,对区域中成矿作用的联系讨论较少。本文研究了该区泥盆系中的多金属矿与重晶石砂的时空关系和地球化学特征,认为是由统一的上泥盆世热水对流体系形成的热水沉积矿床。不同的矿种,矿体的不同产状由对流体系的特点和地质环境的差异所决定。     

基于成分数据分析和能谱-面积分形模型的鄂西黄陵背斜化探异常识别

鄂西黄陵背斜地区虽已发现众多矿点,但是矿床规模较小,找矿潜力不明。由于区内植被茂盛、覆盖严重,致使地质异常信息被削弱或掩盖,对进一步找矿工作造成了严重干扰。本次研究使用成分数据分析和能谱-面积（S-A）分形模型识别与金矿化相关的异常,结果表明：（1）等距对数比（ILR）变换后的主成分分析结果相比对数（Log）变换更能够反应元素的共生组合规律,第一主成分（PC1）元素组合为Au-Cu-Ag,且Au元素占有最大的载荷,与金矿密切相关,PC1元素组合异常的分布模式与矿点的分布更加吻合;（2） S-A方法抑制了黄陵背斜区域水系沉积物的背景模式,增强了异常模式;（3）根据地质特征和以往勘查工作情况,圈定了三处找矿远景区,为该地区金矿下一步勘查工作提供了重要依据。     

中亚构造域多期叠加斑岩铜矿化:以阿尔泰东南缘哈腊苏铜矿床地质、地球化学和成岩成矿时代研究为例

新疆青河县新近发现哈腊苏铜矿床,正在进行的勘探证实具有大型铜储量前景。它位于阿尔泰东南缘,靠近额尔齐斯构造变形带。这个区域经历了古生代中期的洋-陆俯冲、古生代晚期的陆-陆碰撞以及其后的陆内活化等地质过程。铜成矿与哪种地质地质过程有关受人关注,矿床成因也存在斑岩型、热液脉型和火山岩型等不同认识。哈腊苏铜矿区主要出露中泥盆统基性火山岩(含苦橄岩)及侵入其中的不同时期含铜蚀变斑岩体,包括花岗闪长斑岩、斑状花岗岩、石英二长斑岩和石英闪长斑岩等,斑岩SiO_2质量分数为57.24%～65.45%,其中花岗闪长斑岩δ~(18)O_(V-SMOW)=7.9‰～8.6‰,ε_(Nd)(t)=7.3～8.5(接近于MORB值),(~(87)Sr/~(86)Sr)_t=0.70383～0.70410(接近原始地幔值),暗示岩浆起源于地幔或下地壳。矿区含铜蚀变斑岩全岩矿化(Cu 0.2%),矿体(Cu 0.3%以上)呈透镜状和不规则分枝脉状,产状与斑岩体相仿,95%以上矿体产于斑岩体内。围岩蚀变从矿体到斑岩再到基性火山岩围岩,发育钾长石黑云母化、黑云母绿泥石化、青磐岩化的分带,后期脉状线型钾长石化叠加于早期面状弥散型钾硅酸盐蚀变之上。没有次生硫化物富集现象,原生铜矿石出现细脉浸染型和脉状叠加型两种自然类型,前者以"黄铁矿+黄铜矿+辉钼矿"为典型金属矿物组合,后者呈在前者背景上的"石英+黄铁矿+黄铜矿"脉状叠加矿化。相对于前者,后者Cu、Au品位明显偏高(分别达到Cu 2.21%、Au 0.83 g/t)、微量和稀土元素总量降低,微量元素蛛网图和REE配分曲线更为平缓,Eu正异常更加显著。基性火山喷发、幔源岩浆侵入和多期矿化叠加是哈腊苏铜成矿的关键,早期斑岩型铜成矿基础上的后期构造热液矿化叠加显著。细脉浸染型铜矿石中共生黄铁矿-黄铜矿的硫同位素温度计指示斑岩型铜成矿温度为420～560℃。铜矿石硫化物δ~(34)S_(V-CDT)主体范围为-1‰～-4‰,矿石硫源自幔源斑岩体(有地层硫酸盐还原硫少量混入);黄铁矿~(206)Pb/~(204)Pb=18.052～18.461,~(207)Pb/~(204)Pb=15.501～15.606,~(208)Pb/~(204)Pb=37.813～39.335,与矿床所在区域喀拉通克岩浆Cu-Ni硫化物接近,成矿金属主体来自幔源斑岩;脉状矿化叠加型铜矿石中含铜硫化物石英脉晶出母液(δ~(18)O_(V-SMOW)=6.4‰～10.2‰,δD_(V-SMOW)=-89‰～-80‰)具有岩浆水的O、H同位素组成特点。通过成岩、成矿和热液蚀变的年代学研究获得:(1)含铜蚀变的斑状花岗岩(381.6±2.5)Ma和花岗闪长斑岩(371.8±9.6)Ma的U-Pb谐和年龄、细脉浸染型铜矿石中辉钼矿(376.9±2.2)Ma的Re-Os等时线年龄,是洋-陆俯冲期斑岩成岩成矿的年龄记录;(2)含铜蚀变石英二长斑岩(265.6±3.7)Ma的U-Pb谐和年龄和脉状叠加型铜矿石中钾长石(269.2±3.2)Ma的Ar-Ar坪年龄,是陆-陆碰撞晚期斑岩铜矿化蚀变的年龄记录;(3)含铜蚀变石英闪长斑岩(215.8±4.6)Ma的U-Pb谐和年龄和脉状叠加型铜矿石中钾长石(198.2±2.3)～(206.4±2.7)Ma的Ar-Ar坪年龄,是陆内构造岩浆活化期的年龄记录。多期构造-岩浆-热液矿化叠加作用是哈腊苏铜成矿的显著特征。该研究为认识中亚构造域斑岩铜矿床的多期叠加成矿作用特征积累了新资料。     

The Pleistocene history of Wales and the borderland

The Pleistocene rock-stratigraphic record is accorded more or less traditional time-stratigraphic interpretation which was held widely before application of an Irish developmental model in 1960. The following sequence of events are recognised: (1) Complete glaciation, of indeterminate age, which antedated the raised beach interglacial. (2) The raised beach episode which is shown to be the last (Ipswichian) interglacial. (3) The last (Devensian/Weichselian) glaciation, followed by possible readvance in northwest and northeast Wales; prior and subsequent to glaciation periglacial conditions obtained. It is shown that the Irish model, relying heavily as it does on the equation of rock and time stratigraphy, is inapplicable in Wales.     

Titanium,Ti, A New Mineral Species from Luobusha,Tibet, China

We describe the new mineral species titanium,ideally Ti,found in the podiform chromitites of the Luobusha ophiolite in Tibet,People’s Republic of China.The irregular crystals range from 0.1 to 0.6 mm in diameter and form an intergrowth with coesite and kyanite.Titanium is silver grey in colour,the luster is metallic,it is opaque,the streak is grayish black,and it is non-fluorescent.The mineral is malleable,has a rough to hackly fracture and has no apparent cleavage.The estimated Mohs hardness is 4,and the calculated density is 4.503 g/cm3.The composition is Ti 99.23-100.00 wt%.The mineral is hexagonal,space group P63 /mmc.Unit-cell parameters are a 2.950(2),c 4.686(1),V 35.32(5) 3,Z = 2.The five strongest powder diffraction lines [d in(hkl)(I/I0)] are: 2.569(010)(32),2.254(011)(100),1.730(012)(16),1.478(110)(21),and 0.9464(121)(8).The species and name were approved by the CNMNC(IMA 2010–044).     

Metamorphism of the Crystalline Basement of Central Chile

The metamorphic basement of the Cordillera de la Costa, in CentralChile, consists mainly of slate, meta-sandstone, phyllite, andmica schist but contains small quantities of greenschist. Thegreater part of the basement is comprised in the Curepto series,and is characterized by dynamo-metamorphism whose intensityincreases westward. East of this is the smaller Nirivilo series,characterized by contact metamorphism whose intensity increaseseastward toward a granodiorite batholith. At the northern endof the metamorphic belt lies the Pichilemu series, in whichthe metamorphism is dynamo-thermal and increases in intensityto the east. The rocks in the first two areas are divisibleinto zones that trend north-north-east, essentially parallelto the margin of the batholith and to the Pacific coast; butin the Pichilemu area the zoning trends north-west. In the Cureptoseries three zones were distinguished; these are, in order fromeast to west: (1) a muscovite-chlorite(-albite) slate zone,(2) a muscovite-biotite(-albite) phyllite zone, and (3) a muscovite-chlorite-albite(±garnet) schist zone. The rocks in all three zones belongto the greenschist facies; the chlorite in the third zone isbelieved to be a product of H metasomatism. In the much narrowerNirivilo area no zones were mapped, but the following eastwardsuccession of critical assemblages was recognized: (1) muscovite-biotite-chlorite-albite;(2) muscovite-biotite-chlorite-andalusite-albite; (3) biotite-muscovite-andalusite-oligoclase;(4) biotite(± muscovite)-andalusite-sillimanite (or cordierite).The muscovite in the rocks that have undergone highgrade metamorphismis largely of metasomatic origin. Part of the sillimanite hasbeen formed at the expense of biotite and andalusite. In mostof the Nirivilo area the most strongly metamorphosed rocks areof the hornblende-hornfels facies, but small parts of that areamay contain rocks of the pyroxene-hornfels facies. The Pichilemuarea comprises the following zones and subzones: (1) a biotitezone, which includes (a) a muscovite-chlorite-biotite-albitesubzone and (b) a muscovite-biotite-albite subzone; (2) a garnet-oligoclasezone; (3) a staurolite-andalusite zone; (4) a muscovite-sillimanitezone; and (5) a sillimanite-orthoclase zone which includes (a)a sillimanite-orthoclase subzone and (b) a sillimanite-orthoclase-cordierite-almandinesubzone. Some thermal metamorphism is superimposed on the regionalmetamorphism. The facies grade from the greenschist to the granuliteor intermediate between the granulite and the amphibolite facies.The three series represent different pressure conditions: theNirivilo series corresponds to a low-pressure (contact) type,Pichilemu represents a low-pressure intermediate, dynamo-thermaltype, and Curepto is a dynamothermal, high-pressure intermediatetype series. The Curepto area was affected first, the Pichilemuarea next, and the Nirivilo area last. The metamorphism in allthree series is thought to have occurred during a single tectoniccycle within Late Paleozoic time, but it was probably interruptedby periods of erosional unloading. The width of the contactaureole is thought to have been determined by the irregularexpansion of the batholith. The analogy between the metamorphicseries of the Cordillera de la Costa and Miyashiro's circum-Pacificpaired belts is briefly discussed.     

攀枝花大田地区前震旦纪斜长角闪岩地球化学特征及构造意义

对攀枝花大田地区斜长角闪岩进行了系统的主微量地球化学特征、锆石LA-ICP-MS U-Pb年代学以及Lu-Hf同位素特征研究.结果表明:斜长角闪岩的SiO₂含量为47.88%~50.05%,原岩为亚碱性-碱性玄武岩.斜长角闪岩稀土总量(ΣREE)较高,稀土元素配分模式为轻稀土富集的右倾型,与洋岛玄武岩相似.微量元素原始地幔标准化蛛网图为"隆起"型,与板内玄武岩特征类似.Zr/Nb、Hf/Th等比值均表明其与板内玄武岩类似,而与岛弧玄武岩具有明显的差异.锆石U-Pb定年结果表明岩浆结晶年龄为816.0~833.6 Ma,同期岩浆结晶锆石的ε_Hf(t)值在-6.8~+3.8之间,其岩浆源区为与OIB类似的富集地幔源区且受到了地壳物质的混染.综合上述资料,认为其形成于Rodinia超级地幔柱活动导致的大陆裂谷环境.      

我国首次发现的锌—砷黝铜矿

锌-砷黝铜矿产于内蒙的某一铅锌矽卡岩矿床中,呈它形粒状集合体,粒径0.2-0.5mm,铅灰色,硬度HvHN=339-388kg/mm2。反射色呈灰蓝色微带绿色。均质性。其成分经电子探针分析(平均值)为:S 25.94,As 10.70,Cu 39.67,Zn 7.36,Sb 9.81,Bi 5.81,Ag 0.18,Fe 0.37(%),化学式为:(Cu10.02Age03)10.05(Zn1.81Fe0.11)1.82(As2.29Sb1.29Bi0.45)4.03S18。X射线分析:晶胞参数a=10.322,粉末衍射强线是2.98,1.82,1.56。     

对于氟碳钡铈矿（Cordylite—Ce）成分与结构的质疑

本文讨论了氟碳钡铈矿的成分和结构问题。发现氟碳钡铈矿的成分、密度、折射率三者间的一致性参数很差,晶体结构与光性和空间群相矛盾,单个大阳离子的平均占有体积远大于同类矿物的平均占有体积,它的晶体结构与同类矿物不可类比。由于受当时条件的限制,在以往有关氟碳钡铈矿的成分和结构的资料中存在着一些明显的错误,有必要对其进行重新定义。其结构化学式应改为:(Na_(1-x),Ca_(0·5x))BaCe_2(CO_3)_4F。     

Sequential solvent extraction for the modes of occurrence of selenium in coals of different ranks from the Huaibei Coalfield, China

Forms of selenium in bituminous coal, anthracite, and cokeite (natural coke) from Huaibei Coalfield, Anhui, China, have been determined by sequential solvent extraction. The selenium content in bulk samples is 4.0, 2.4, and 2.0 μg/g in bituminous coal, anthracite, and cokeite, respectively. The six forms of selenium determined by six-step solvent extraction are water-leachable, ion-exchangeable, organic matter-associated, carbonate-associated, silicate-associated, and sulfide-associated. The predominant forms of selenium in bituminous coal are organic matter-associated (39.0%), sulfide-associated (21.1%), and silicate bound (31.8%); these three forms account for 92% of the total. The organic matter bound-selenium decrease dramatically from bituminous coal (39.0%) to anthracite (11.6%) and to cokeite (0%), indicating that organic matter bound selenium is converted to other forms during metamorphism of the coal, most likely sulfide-form. The sulfide-associated form increased remarkably from bituminous coal (21.1%) to anthracite (50.4%) and cokeite (54.5%), indicating the formation of selenium sulfide, possibly in pyrite during the transformation of bituminous coal to anthracite and cokeite. The silicate-associated selenium in bituminous coal (31.8%) is much higher than that in anthracite (16.4%) and cokeite (15.8%), indicating that silicate-associated selenium is partly converted to sulfide during metamorphism.     

大贵州滩二叠系—三叠系界线附近锶同位素组成特征

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本文通过详细岩石学及地球化学研究,探讨了塔里木盆地丘里塔格群(寒武至奥陶系)白云岩的成因。研究表明藻纹层白云岩、微晶白云岩及颗粒白云岩中的颗粒为近地表准同生白云化的产物。结晶白云岩(细晶以上)及颗粒白云岩中的中粗晶白云岩胶结物是深埋藏成岩环境的产物。并对埋藏白云化的镁离子来源及搬运机理进行了探讨。     

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锌水绿矾产于陕西省南部红土石黄铁矿矿床氧化带。集合体呈钟乳状或皮壳状，单晶为短柱状和不规则粒状，极易溶于水。颜色为黄绿色或翠绿色。主要化学成分：ZnO16．35％，FeO8．86％，SO328．30％，H2O44．33％。分子式为（Zn，Fe）SO4·7H2O。主要X射线粉晶谱线是：0．4880（100），0．2739（80），0．5439（30），0．3225（30）和0．2476（30）um。它的化学成分和粉晶数据均与水绿矾（FeSO47H2O）或人工合成的锌水绿矾相似。     

新疆喀拉通克Y1含矿岩体的岩石化学特征及其与成矿的关系

喀拉通克Ｙ１含矿岩体岩石类型属铁质基性岩类，岩体为单式岩体，具富镁、铁、碱、低钙贫铝的特点。组成岩体的各岩相是同一母岩浆结晶分异的产物。原始岩浆为来自上地幔的拉斑玄武岩浆。岩体锶初始比值约为０．７０３３，形成时代约为２９１Ｍａ。在岩浆结晶分异作用下，氧化物组分的变化使硫化物熔浆与硅酸盐熔浆发生分离，并在重力作用下聚积形成铜镍硫化物富矿。     

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受洪水补给来源和阿尔泰山山势影响,阿勒泰地区洪水发生时间比新疆其他以高山永久积雪和冰川融水补给为主的河流偏早。因此,从认识洪水特性、预防洪水灾害角度出发,对阿勒泰地区洪水发生机制、时空分布和变化特点进行分析研究是很有必要的。利用阿勒泰地区各主要河流1960~2011年历年洪峰、冬季和汛期降水、气温和700hPa高空温度资料,对洪水发生机制、时空分布和变化特点进行分析。结果表明:(1)本区洪水类型有融雪型洪水、融雪与降水混合型洪水和暴雨型洪水;(2)洪水与冬季积雪和汛期气温、降雨有关;(3)汛期过程相对短,主汛期发生时间以5月下旬至6月中旬期为主;(4)洪水挟沙能力强,汛期含沙量占年含沙量近90%;(5)暴雨洪水多发生于阿勒泰地区的中东部区域河流上;(6)全区洪水具有同步性,洪水年际变化相对小。