Comparative growth of juvenile white sturgeon and striped bass: Effects of temperature and hypoxia

The influences of temperature and environmental hypoxia on the growth rates of two California anadromous fishes, white sturgeon (Acipenser transmontanus) and striped bass (Morone saxatilis) were examined. Fish (0.5–0.6 g initial weight) were fedad libitum rations ofArtemia in flow-through aquaria regulated for temperature (15, 20, and 25°C) and oxygen tension (130 and 90 torr P_{o 2}). Growth of sturgeon was significantly greater at 20 °C compared with 15 °C, but there was no difference between 20 and 25 °C. Striped bass growth increased with each 5° increment of temeprature elevation to 3.2% body weight per d at 25 °C, the fastest growth rate measured. The temperature of maximum growth reflected the temperature of the native estuarine rearing area. Environmental hypoxia (90 torr P_{o 2}) reduced growth of sturgeon within each temperature level, whereas striped bass growth was reduced by hypoxia only at the upper two temperatures. Sturgeon were much more active in the growth chambers than striped bass. Sturgeon activity increased with each 5 °C temperature increase under normoxia and hypoxia, except at 25 °C (hypoxia) where activity was insignificantly different from that at 20 °C (hypoxia).     

Comparison of the magnetic properties of glass from Luna 20 with similar properties of glass from the Apollo missions

Magnetic susceptibility measurements have been made on four glass spherules and fragments from the Luna 20 fines; two at 300°K and two from 300°K to 4°K. From these data the magnetic susceptibility extrapolated to infinite field, the magnetization at low fields and also the saturation magnetization at high fields, the Curie constant, the Weiss temperature, and the temperature-independent susceptibility were determined. Using a model previously proposed for the Apollo specimens, the Curie constant of the antiferromagnetic inclusions and a zero field splitting parameter were calculated for the same specimens. The data show the relatively low concentration of iron in all forms in these specimens. In addition, the Weiss temperature is lower than that measured for the Apollo specimens, and can be attributed almost entirely to the ligand field distortion about the Fe²⁺ ions in the glassy phase. The data further suggest that the Luna 20 specimens cooled more slowly than those of the Apollo missions, and that some of the antiferromagnetic inclusions in the glass may have crystallized from the glass during cooling.     

Raman scattering and lattice vibrations of Ni2SiO4 spinel at elevated temperature

Raman spectra of Ni₂SiO₄ spinel (O _h ⁷ Z=8) have been measured in the temperature range from 20 to 600 °C and the Raman active vibrations (A _1g +E _g +3F _2g ) have been assigned. A calculation of the optically active lattice vibrations of this spinel has been made, assuming a potential function which combines general valence and short range force constants. The values of the force constants at 20 and 500 °C have been calculated from the vibrational frequencies of the observed Raman spectra and infrared (IR) spectral data. The Ni spinel at 20 °C has a prominently small Si-O bond stretching force constant of K(SiO)=2.356 ～ 2.680 md/Å and a large Ni-O bond stretching constant of K(NiO)=0.843 ～ 1.062 md/Å and these force constants at 500 °C decrease to K(SiO)=2.327 ～ 2.494 md/Å and K(NiO)=0.861 ～ 0.990 md/Å. The Si-O bond is noticeably weakened at high temperatures, despite the small thermal expantion from 1.657 Å (20 °C) to 1.660 Å (500 °C). These changes of the interatomic force constants of the spinel at high temperatures are in accord with the thermal structure changes observed by X-ray diffraction study. The weakened Si-O bond is consistent with the fact that Si atoms in the spinel lattice can diffuse at significant rates at elevated temperature.     

Long-term variations in outgoing long-wave radiation (OLR), convective available potential energy (CAPE) and temperature in the tropopause region over India

Relationship of outgoing long-wave radiation (OLR) with convective available potential energy (CAPE) and temperature at the 100-hPa pressure level is examined using daily radiosonde data for a period 1980–2006 over Delhi (28.3°N, 77.1°E) and Kolkata (22.3°N, 88.2°E), and during 1989–2005 over Cochin (10°N, 77°E) and Trivandrum (8.5°N, 77.0°E), India. Correlation coefficient (R _xy) between monthly OLR and CAPE shows a significant (~???0.45) anti-correlation at Delhi and Kolkata suggesting low OLR associated with high convective activity during summer (seasonal variation). Though, no significant correlation was found between OLR and CAPE at Cochin and Trivandrum (low latitude region); analysis of OLR and temperature (at 100-hPa) association suggests that low OLR peaks appear corresponding to low temperature at Delhi (R _xy~ 0.30) and Kolkata (R _xy ~ 0.25) during summer. However, R _xy between OLR and temperature becomes opposite as we move towards low latitudes (~8°–10°N) due to strong solar cycle influence. Large scale components mainly ENSO and quasi-biennial oscillaton (QBO) that contributed to the 100-hPa temperature variability were also analyzed, which showed that ENSO variance is larger by a factor of two in comparison to QBO over Indian region. ENSO warm conditions cause warming at 100-hPa over Delhi and Darwin. However, due to strong QBO and solar signals in the equatorial region, ENSO signal seems less effective. QBO, ENSO, and solar cycle contribution in temperature are found location-dependent (latitudinal variability) responding in consonance with shifting in convective activity regime during El Niño, seasonal variability in the tropical easterly jet, and the solar irradiance.     

Fluid-bearing and fluid-absent invariant points in the system CaO-MgO-Al2O3-SiO2-CO2-H2O for a greenschist facies assemblage

An outline for a metamorphic grid involving a greenschist facies assemblage is presented in Watts (1973). This grid is derived from a theoretical determination of all possible P-T dependent (solid-solid) reactions and invariant points as well as those in which a fluid, containing CO₂, H₂O and other unspecified components, takes part. The thermodynamic data in Watts (1973) were accidentally calculated at 425° K and not at 425° C. Since 425° K is an unreasonably low temperature for greenschist facies equilibria, these data have been recalculated at 700° K (427° C) and a new topology of fluid-absent (solid-solid) reactions and invariant points in P-T space results, since the slopes of such reactions change under conditions at the higher temperature. The slopes of the fluid-bearing reactions are independent of P, T and remain unchanged. However, for each different P-T grid of solid-solid reactions, a new set of chemographic arrangements is valid for the fluidbearing invariant points. A set of μ_H2O-μ_CO2 diagrams consistent with, and dependent on the new P-T grid is presented.     

Ionospheric foF2 morphology and response of F2 layer height over Jicamarca during different solar epochs and comparison with IRI-2012 model

Diurnal, seasonal and annual foF2 variability and the response of the F2-layer height over Jicamarca (11.9 °S, 76.8 °W, 1 °N dip) during periods of low (LSA), moderate (MSA) and high (HSA) solar activities was investigated. The relative standard deviation (V _R ) was used for the analysis. The F2-layer critical frequency pre-noon peak increases by a factor of 2 more than the post-noon peak as the solar activity increases. The variability coefficient (V _R ) is lowest during the day (7–16%) for the three solar epochs; increases during nighttime (20–26%, 14–26%, and 10–20%, respectively for the LSA, MSA and HSA years); and attained highest magnitude during sunrise (21–27%, 24–27%, and 19–30%, respectively in similar order). Two major peaks were observed in V _R – the pre-sunrise peak, which is higher, and the post-sunset peak. Generally, the variability increases as the solar activity decreases. Annually, V _R peaks within 23–24%, 19–24% and 15–24% for the LSA, MSA, and HSA periods, respectively. The ionospheric F2-layer height rises to the higher level with increasing solar activity. The foF2 comparison results revealed that Jicamarca is well represented on the IRI-2012 model, with an improvement on the URSI option. The importance of vertical plasma drift and photochemistry in the F2-layer was emphasized.     

Temperature conditions in soils as an ecological factor of ecosystem evolution

Criteria of ecological estimation of temperature conditions for functioning of land ecosystems are examined in this work. It has been shown that soil climate has a key influence on the spatial distribution of phytocenosises of the East European Plain. To characterize the temperature regime of soils, it is proposed, together with active temperatures (>10°C), to use ecologically sufficient (5–10°C) and ecologically optimal (10–22°C) temperatures. Some parameters concerning the different depths of the root layer (20 cm, 40 cm, 80 cm, 160 cm, and 320 cm) are proposed for use as the criteria of ecological estimation of the temperature regime. On the basis of the mentioned criteria, the main regularities of the temperature regime of East European Plain soils have been examined.     

An application of artificial intelligence for investigating the effect of COVID-19 lockdown on three-dimensional temperature variation in equatorial Africa

We present interesting application of artificial intelligence for investigating effect of the COVID-19 lockdown on 3-dimensional temperature variation across Nigeria (2°–15° E, 4°–14° N), in equatorial Africa. Artificial neural networks were trained to learn time-series temperature variation patterns using radio occultation measurements of atmospheric temperature from the Constellation Observing System for Meteorology, Ionosphere, and Climate (COSMIC). Data used for training, validation and testing of the neural networks covered period prior to the lockdown. There was also an investigation into the viability of solar activity indicator (represented by the sunspot number) as an input for the process. The results indicated that including the sunspot number as an input for the training did not improve the network prediction accuracy. The trained network was then used to predict values for the lockdown period. Since the network was trained using pre-lockdown dataset, predictions from the network are regarded as expected temperatures, should there have been no lockdown. By comparing with the actual COSMIC measurements during the lockdown period, effects of the lockdown on atmospheric temperatures were deduced. In overall, the mean altitudinal temperatures rose by about 1.1 °C above expected values during the lockdown. An altitudinal breakdown, at 1 km resolution, reveals that the values were typically below 0.5 °C at most of the altitudes, but exceeded 1 °C at 28 and 29 km altitudes. The temperatures were also observed to drop below expected values at altitudes of 0–2 km, and 17–20 km.     

Chemical and physical studies of type 3 chondrites—IV: Annealing studies of a type 3.4 ordinary chondrite and the metamorphic history of meteorites

Samples of a type 3.4 chondrite have been annealed at 400–1000°C for 1–200 hours, their thermoluminescence properties determined and analyzed for K, Na, Mn, Sc and Ca by instrumental neutron activation analysis. After annealing at ?900°C, the samples showed a 50% decrease in TL sensitivity, while after annealing at 1000°C it fell to 0.1-0.01 times its unannealed value and loss of Na and K occurred. The TL and compositional changes resemble those observed for the equilibrated Kernouve chondrite after similar annealing treatments, except that the sharp TL decrease, and element loss, occurred at ~ 1100°C; this difference is presumably due to petrographic differences in the feldspar of the two meteorites. The temperature and the width of the TL peak showed a discontinuous increase after annealing at 800°C; peak temperature jumped from 130 to 200°C and peak width increased from 90 to 150°C. The activation energies for these TL changes are 7–10 kcal/mole. Similar increases in the TL peak temperature have been reported in TL studies of Amelia, VA, albite, where they were associated with the low to high-temperature transformation. However, the activation energy for the transformation is ~80 kcal/mole. These changes in TL emission characteristics resemble trends observed in type 3 ordinary chondrites and it is suggested that type 3.3–3.5 chondrites have a low-feldspar as TL phosphor and > 3.5 have high-feldspar as the phosphor. Thermoluminescence therefore provides a means of palaeothermometry for type 3 ordinary chondrites.     

New palaeomagnetic data from Central Iran and a Triassic palaeoreconstruction

New pole positions for Triassic and Cretaceous times have been obtained from volcanic and sedimentary sequences in Central Iran. These new results confirm the general trend of the Apparent Polar Wander Path (APWP) of the Central-East-Iran microplate (CEIM) from the Triassic through the Tertiary as published by Soffel and Förster (1983, 1984). Two new palaeopoles for the Triassic of the CEIM have been obtained; limestones and tuffs from the Nakhlak region yield a mean direction of 094.0°/25.0°, N=12, k=4.1,α ₉₅=24.7°, after bedding correction, corresponding to a palaeopole position of 310.8°E; 3.9°S, and volcanic rocks from the Sirjan regions yield a mean direction of 114.5°/35.1°, N=44, k=45.9,α ₉₅=3.2° after bedding correction and a palaeopole position of 295.8°E; 10.3°N. Combining these with the two previously published results yields a new palaeopole position of 317.5°E; 12.7°N, for the Triassic of the CEIM, thus confirming that large counterclockwise rotations of the CEIM have occurred since the Triassic time. New results have also been obtained from Cretaceous limestones from the Saghand region of the CEIM. The mean direction of 340.7°/26.3°, N=33, k=44.3,α ₉₅=3.8°, and the corresponding palaeopole position of 283.1°E; 64.4°N, is in agreement with previously determined Cretaceous palaeopole positions of the CEIM. Furthermore, results have also been obtained from Triassic dolomite, limestone, sandstone and siltstone from the Natanz region, which is located to the west of the CEIM. A total of 161 specimens from 44 cores taken at five sites gave a mean direction of the five sites at 033.3°/25.1°, N=5, k=69.0,α ₉₅=9.3° and a palaeopole position of 167.2°E; 53.7°N. They pass the positive fold test of McElhinny (1964) on the level of 99% confidence. This pole position is in fairly good agreement with the mean Triassic pole position of the Turan Plate (149°E; 49°N). It indicates that the area of Natanz has not undergone the large counterclockwise rotation relative to the Turan plate since the Triassic, which has been shown for the CEIM. A Triassic palaeogeographic reconstruction of Iran, Arabia (Gondwana) and the Turan Plate (Eurasia) is also presented.     

Thermal expansion of fayalite,Fe2SiO4

Thermal expansion of single-crystal fayalite has been measured by a dilatometric method at temperatures between 25 °C and 850 °C. The results show the presence of anomalous expansion in the b axis, which is correlated to the anomalous variation of elastic moduli with temperature. Grüneisen's parameter is 1.10 and the thermal Debye temperature is 565 K, which is close to the acoustic Debye temperature of 511 K.     

Altitudinal and latitudinal migration of Cryptomeria japonica for the past 20,000 years in Japan

Biostatistical analysis of modern pollen assemblages in 152 Japanese surface samples shows that Cryptomeria japonica can normally grow in areas with a mean January temperature of approximately −7° to 7°C, a mean August temperature of 19° to 27°C, and an effective precipitation (total precipitation during the growing season) of over 1000 mm. The full-glacial distribution of the species on both the Sea of Japan and the Pacific coasts (35–36°N lat) indicates that in these areas the maximum possible reduction of temperature was 8.7–10.2°C in January and 6.0–7.3°C in August, and that the effective precipitation was low, being 1000–1350 mm, or 40–55% below the modern level, provided that the species has not changed its physiological characteristics. Populations of C. japonica expanded northward and upslope from their full-glacial areas of distribution immediately after late-glacial climatic amelioration. This expansion appears to have been regulated mainly by the availability of effective precipitation which became high in northeastern Honshu about 4000 yr ago. After about 2500 yr B.P., C. japonica was planted extensively by humans in moist, temperate climatic regions (excluding Hokkaido), and now has its widest distribution since at least the last full-glacial interval.     

The radio brightness distribution along the solar limb observed on the Siberian Solar Radio Telescope

The radio brightness distribution at 5.2 cm has been obtained along the entire solar limb down to a level of 0.01 of brightness temperature at the disk center T ₀ ^c during the solar minimum. The measurements are based on strip scans from the Siberian Solar Radio Telescope. Data reduction included model fitting of an actual solar scan for each position angle. The maximum limb brightness, 1.37 T ₀ ^c , in the derived distribution is at equatorial direction, where the radio radius exceeds the photosphere radius by 7%. Toward the poles, the brightness peak and radio radius gradually decrease to 1.01 T ₀ ^c and 1.005 R₀. The derived two-dimensional brightness distribution was used to calculate radio radius as a function of position angle for several wavelengths from 4 to 31.6 cm. These dependences are consistent with RATAN-600 observations at position angles 0° and 25°.     

Isotopic variability of organic carbon in a phytoplankton-based,temperate estuary

An isotopic survey was made of organic carbon in phytoplankton, sediments, Zooplankton, larval fish, and benthic fauna from Narragansett Bay and the Marine Ecosystems Research Laboratory, Rhode Island; the results quantify the extent of variability in a phytoplankton-based ecosystem and elucidate some of its causes. Carbon from primary producers (phytoplankton) varied with taxon and size, ranging from ?20.3 ± 0.6%. (mean ± 1 s.d.) for diatoms (primarily Skeletonema costatum) to ?22.2 ± 0.6%. for nanoplankton (primarily microflagellates and non-motile ultraplankton). Planktonic isotope ratios varied little with either water temperature (0 to 20°C) or degree of preservation (up to 2-year aerobic diagenesis in sea water). Isotopically, sediments from East and West Passages of the bay were homogeneous with location and depth, with a mean (?21.8 ± 0.6%.) similar to a mixture of carbon from diatoms and nanoplankton. Providence River sediments reflected terrigenous and anthropogenic carbon (sewage) in their isotopic ratios (?24.2 ± 0.7%.). Ratios of macrozooplankton (> 150 μm) were statistically separable from those of concurrently collected phytoplankton, being, on average, 0.5 to 0.6%. more positive. Secondary consumers in the water column (shrimp and larval fish) were 2.4%. heavier than diatoms. Thirty-four taxa of benthic fauna had relatively positive isotope ratios (?18.1 ± 1.5%.) which may indicate preferential use of carbon originally from diatoms rather than nanoplankton. The wide range of benthic ratios (?22.7 to ?14.9%.) resulted from both intraspecific variability (mean range = 3%.) and the variety of trophic positions occupied. Some of the intraspecific variability could be related to size. Among species, the isotope ratios increased from meiofauna (?19.5 ± 0.4%.) to macrofaunal non-carnivores (?18.6 ± 1.3%.) and carnivores (?16.6 ± 0.8%.).     

Metamorphic Evolution of Charnockites and Felsic Gneisses from the Schirmacher Region,East Antarctica

The structural and petrographic studies of the metamorphic rocks of the Schirmacher region, East Antarctica, indicate polyphase metamorphism, dominantly of an early granulite and later amphibolite facies metamorphism. In order to understand the metamorphic evolution of the region, the temperature and pressure of metamorphism has been estimated for felsic gneisses and charnockites using conventional models of geothermometry and geobarometry. The studies showed that, the early granulite facies metamorphism and charnockitization took place around 827±29°C at 7.3±0.3 kbar, while the later amphibolite facies metamorphism and granitization took place around 654±27°C at 5.4±0.4 kbar. The pressure and temperature recorded in these rocks suggest that metamorphism was initiated at 20 to 27 km depth, with a geothermal gradient of around 32°C/km. The P-T conditions reflect isobaric cooling path, with a gentle dP/dT slope (∼10±1 bar/°C). The isobaric cooling path owes its origin to the underplating of crust by mantle derived magmas.     

Observations on the crystal structures of lueshite

Laboratory powder XRD patterns of the perovskite-group mineral lueshite from the type locality (Lueshe, Kivu, DRC) and pure NaNbO₃ demonstrate that lueshite does not adopt the same space group (Pbma; #57) as the synthetic compound. The crystal structures of lueshite (2 samples) from Lueshe, Mont Saint-Hilaire (Quebec, Canada) and Sallanlatvi (Kola, Russia) have been determined by single-crystal CCD X-ray diffraction. These room temperature X-ray data for all single-crystal samples can be satisfactorily refined in the orthorhombic space group Pbnm (#62). Cell dimensions, atomic coordinates of the atoms, bond lengths and octahedron tilt angles are given for four crystals. Conventional neutron diffraction patterns for Lueshe lueshite recorded over the temperature range 11–1,000 K confirm that lueshite does not adopt space group Pbma within these temperatures. Neutron diffraction indicates no phase changes on cooling from room temperature to 11 K. None of these neutron diffraction data give satisfactorily refinements but suggest that this is the space group Pbnm. Time-of-flight neutron diffraction patterns for Lueshe lueshite recorded from room temperature to 700 °C demonstrate phase transitions above 550 °C from Cmcm through P4/mbm to \(Pm\overline{3} m\) above 650 °C. Cell dimensions and atomic coordinates of the atoms are given for the three high-temperature phases. The room temperature to 400 °C structures cannot be satisfactorily resolved, and it is suggested that the lueshite at room temperature consists of domains of pinned metastable phases with orthorhombic and/or monoclinic structures. However, the sequence of high-temperature phase transitions observed is similar to those determined for synthetic NaTaO₃, suggesting that the equilibrated room temperature structure of lueshite is orthorhombic Pbnm.     

High-temperature condensates in chondrites and the environment in which they formed

Chemical compositions of melilitee and titaniferous pyroxenes in calcium- and aluminum-rich inclusions in carbonaceous chondrites are consistent with their origin as hightemperature condensates from a gas of solar composition. Thermodynamic calculations indicate that the highest temperature minerals equilibrated with the gas at temperatures in excess of 1400°K. The lack of evidence for direct condensation of gas to liquid enables us to set an upper limit to the pressure when the inclusions formed which may be as low as 2.2 × 10^?3atm. Glasses, which are commonly found in chondrules, are interpreted as quench products of liquids formed by secondary reheating of primary solid condensates. The high-temperature inclusions constitute evidence that accretion of grains to cm-sized objects occurred at a very early stage in the evolution of the solar nebula.     

Interannual variability in the structure of the Kuroshio front along the western boundary of the North Pacific Ocean associated with the 1982 ENSO event

The vertically averaged temperature (T_av) over the upper 200 m of ocean in the W boundary of the N Pacific is used to detect changes in the strenght and path of the Kuroshio Front along the W boundary from Luzon (18° N) to Honshu (34° N) during the period, 1979–1982. During this time period the Kuroshio Front experienced significant interannual changes associated, both with the disappearance of the Kuroshio Meander in late 1980 and with the development of the 1982 ENSO event in early 1982. When the Kuroshio Meander S of Honshu disappeared in the fall of 1980, lasting until the summer of 1981, the intensity of the Kuroshio Front increased, associated with warmer than normal temperatures all along the W boundary of the N Pacific from Luzon to Honshu. The amplitude of the Kuroshio Meander was also correlated with fluctuations in the path of the Kuroshio Front at the Tokara Strait (30° N) and the Bashi Strait (20° N), and with the amplitude of the East China Sea Meander. The East China Sea Meander occurs W of the Ryukyu Islands at 25° N, formed when the Kuroshio Current enters the East China Sea from the Philippine Sea NE of Taiwan Island. It had large amplitude in winter and smaller amplitude in spring and early summer, similar to that in the Kuroshio Meander when it was present during this period. It also had related interannual variability; i.e., when the Kuroshio Meander disappeared in fall of 1980, the East China Sea Meander was weak. These results and earlier ones dealing with the Kuroshio Front E of Japan (e.g., White and He) indicate that fluctuations in the amplitude of the Kuroshio Meander S of Honshu were associated with similar changes in the meandering character over the entire Kuroshio Current System during this four year period. During the 1982 ENSO event, the temperature in the region of the Kuroshio Front in the W boundary became colder than normal, while the Kuroshio Meander S of Honshu and the East China Sea Meander NE of Taiwan Island developed larger amplitudes. This is consistent with the results of White and He, who found during this same time period that the mesoscale meander pattern in the Kuroshio Extension intensifying during the 1982 ENSO period. During this time, the magnitude of the Kuroshio Front all along the W boundary and in the Kuroshio Extension region was weaker in comparison with the three years prior to the 1982 ENSO event.     

The crystal structure and thermal expansion tensor of MgSO<Subscript>4</Subscript>–11D<Subscript>2</Subscript>O(meridianiite) determined by neutron powder diffraction

We have collected high-resolution neutron powder diffraction patterns from MgSO₄·11D₂O over the temperature range 4.2–250 K. The crystal is triclinic, space-group \( \text{P} \bar{1} \) (Z = 2) with a = 6.72746(6) Å, b = 6.78141(6) Å, c = 17.31803(13) Å, α = 88.2062(6)°, β = 89.4473(8)°, γ = 62.6075(5)°, and V = 701.140(6) ų at 4.2 K, and a = 6.75081(3) Å, b = 6.81463(3) Å, c = 17.29241(6) Å, α = 88.1183(3)°, β = 89.4808(3)°, γ = 62.6891(3)°, and V = 706.450(3) ų at 250 K. Structures were refined to wRp = 3.99 and 2.84% at 4.2 and 250 K, respectively. The temperature dependence of the lattice parameters over the intervening range have been fitted with a modified Einstein oscillator model which was used to obtain the coefficients of the thermal expansion tensor. The volume thermal expansion, α_V, is considerably smaller than ice Ih at all temperatures, and smaller even than MgSO₄·7D₂O (although ?α_V/?T is very similar for both sulfates); MgSO₄·11D₂O exhibits negative α_V below 55 K (compared to 70 K in D₂O ice Ih and 20 K in MgSO₄·7D₂O) The relationship between the magnitude and orientation of the principal axes of the expansion tensor and the main structural elements are discussed.     

Oxygen isotope study of metamorphic rocks from the Ouégoa district,New Caledonia

48 minerals from 18 in situ metamorphic rocks (mostly metasediments) from the Ouégoa district have been studied. Particular emphasis was placed on obtaining isotopic data for quartz, calcite and muscovite but some pyroxenes and amphiboles were also examined. Data for Ouégoa rocks show they have tended to be isotopically homogenized by metamorphism and that the effect of increasing metamorphism is to progressively deplete the rocks of heavy C and O isotopes. These results indicate that during metamorphism the rocks isotopically exchanged through the medium of a widespread oxygen-carrying fluid phase. Tentatively assigned temperatures obtained from isotopic data for quartz-calcite and quartz-muscovite pairs, using the calibration curves of Epstein and Taylor (1967), indicate lawsonite in the Ouégoa schists to be stable over a temperature range of 250 to 400° C and epidote from ca. 380° to at least 550° C. Temperatures for metamorphic zones in Ouégoa blueschists closely parallel those obtained for Type III and IV glaucophane-bearing rocks from Ward Creek, California (Taylor and Coleman, 1968). The measured tectonic thickness of lawsonite-bearing schists has been used to calculate a lithostatic pressure increment of 2 Kb and geothermal gradient of 20° C per km for the lawsonite zone. Comparison of lithostatic pressure increment with total pressure increment estimated from the stability relations of lawsonite over the temperature range 250–400° C (3.5 Kb Nitsch, 1972) suggest P _total ≠ P _lithostatic and that that the pressure of the fluid phase may have exceeded lithostatic pressure.