Chemical weathering of granite under acid rainfall environment, Korea

Chemical weathering was investigated by collecting samples from five selected weathering profiles in a high elevation granitic environment located in Seoul, Korea. The overall changes of chemistry and mineralogical textures were examined reflecting weathering degrees of the samples, using polarization microscopy, X-ray diffraction (XRD), electron probe micro analysis (EPMA), X-ray fluorescence spectroscopy (XRF), and inductively coupled plasma–mass spectroscopy (ICP–MS). The chemical distribution in the weathering profiles shows that few trace elements are slightly immobile, whereas most major (particularly Ca and Na) and trace elements are mobile from the beginning of the granite weathering. On the other hand, there were mineralogical changes initiated from a plagioclase breakdown, which shows a characteristic circular dissolved pattern caused by a preferential leaching of Ca cation along grain boundaries and zoning. The biotite in that region is also supposed to be sensitive to exterior environmental condition and may be easily dissolved by acidic percolated water. As a result, it seems that some rock-forming minerals in the granitic rock located in Seoul are significantly unstable due to the environmental condition of acidic rainfall and steep slopes, where they are susceptible to be dissolved incongruently leading some elements to be highly depleted.     

Fluvial Geochemistry through a Short-Duration, Tropical-Cyclone Induced Discharge event in the Burdekin River and Hann Creek, North Queensland, Australia

The chemical composition of river water integrates a number of factors such as weathering, land use, climate, vegetation cover and human activity that individually affect its chemistry. Short term variations may also be significant. The Burdekin River, NE Australia, is an example of a class of tropical streams which experiences two to four orders of magnitude variation in discharge in response to seasonal but erratic monsoonal and cyclonic rainfall. In these systems individual discharge events last for days to weeks. Given the inherent difficulty sampling these events published data on water chemistry (and thus calculated fluxes and global budgets) may tend to be biased to low flow conditions. One such discharge event in February 1996 has been investigated for its impact on the chemistry of the water. Major cations (Na, Mg, K, Ca) all decreased in concentration as the water level rose, as did the minor elements Sr, Ba and U. Some other trace elements, notably Rb, Cr, Pb and REE were enriched in the peak flow waters. The flux of all measured elements increased substantially during the seven days of the discharge event. Such short term but significant events will have a major impact on the annual fluxes of elements delivered to the oceans from the land and global discharge budgets may need to take them into account when refining databases in the future.     

Geochronology of weathering and landscape evolution, Dugald River valley, NW Queensland, Australia

⁴⁰Ar/³⁹Ar laser incremental heating analyses of individual grains of supergene jarosite, alunite, and cryptomelane from weathering profiles in the Dugald River area, Queensland, Australia, show a strong positive correlation between a sample’s age and its elevation. We analyzed 125 grains extracted from 35 hand specimens collected from weathering profiles at 11 sites located at 3 distinct elevations. The highest elevation profile hosts the oldest supergene minerals, whereas progressively younger samples occur at lower positions in the landscape. The highest elevation sampling sites (three sites), located on top of an elongated mesa (255 to 275 m elevation), yield ages in the 16 to 12 Ma range. Samples from an intermediate elevation site (225 to 230 m elevation) yield ages in the 6 to 4 Ma range. Samples collected at the lowest elevation sites (200 to 220 m elevation) yield ages in the 2.2 to 0.8 Ma interval.Grains of supergene alunite, jarosite, and cryptomelane analyzed from individual single hand specimens yield reproducible results, confirming the suitability of these minerals to ⁴⁰Ar/³⁹Ar geochronology. Multiple samples collected from the same site also yield reproducible results, indicating that the ages measured are true precipitation ages for the samples analyzed. Different sites, up to 3 km apart, sampled from weathering profiles at the same elevation again yield reproducible results. The consistency of results confirms that ⁴⁰Ar/³⁹Ar geochronology of supergene jarosite, alunite, and cryptomelane yields ages of formation of weathering profiles, providing a reliable numerical basis for differentiating and correlating these profiles.The age versus elevation relationship obtained suggest that the stepped landscapes in the Dugald River area record a progressive downward migration of a relatively flat weathering front. The steps in the landscape result from differential erosion of previously weathered bedrock displaying different susceptibility to weathering and contrasting resistance to erosion. Combined, the age versus elevation relationships measured yield a weathering rate of 3.8 m. Myr⁻¹ (for the past 15 Ma) if a descending subhorizontal weathering front is assumed. The results also permit the calculation of the erosion rate of the more easily weathered and eroded lithologies, assuming an initially flat landscape as proposed in models of episodic landscape development. The average erosion rate for the past 15 Ma is 3.3 m. Myr⁻¹, consistent with erosion rates obtained by cosmogenic isotope studies in the region.     

Supply limited sediment transport in a high-discharge event of the tropical Burdekin River, North Queensland, Australia

Interactions between catchment variables and sediment transport processes in rivers are complex, and sediment transport behaviour during high‐flow events is not well documented. This paper presents an investigation into sediment transport processes in a short‐duration, high‐discharge event in the Burdekin River, a large sand‐ and gravel‐bed river in the monsoon‐ and cyclone‐influenced, semi‐arid tropics of north Queensland. The Burdekin's discharge is highly variable and strongly seasonal, with a recorded maximum of 40 400 m³ s^?1. Sediment was sampled systematically across an 800 m wide, 12 m deep and straight reach using Helley‐Smith bedload and US P‐61 suspended sediment samplers over 16 days of a 29‐day discharge event in February and March 2000 (peak 11 155 m³ s^?1). About 3·7 × 10⁶ tonnes of suspended sediment and 3 × 10⁵ tonnes of bedload are estimated to have been transported past the sample site during the flow event. The sediment load was predominantly supply limited. Wash load included clay, silt and very fine sand. The concentration of suspended bed material (including very coarse sand) varied with bedload transport rate, discharge and height above the bed. Bedload transport rate and changes in channel shape were greatest several days after peak discharge. Comparison between these data and sparse published data from other events on this river shows that the control on sediment load varies between supply limited and hydraulically limited transport, and that antecedent weather is an important control on suspended sediment concentration. Neither the empirical relationships widely used to estimate suspended sediment concentrations and bedload (e.g. Ackers & White, 1973) nor observations of sediment transport characteristics in ephemeral streams (e.g. Reid & Frostick, 1987) are directly applicable to this river.     

An experimental and numerical study of a landslide triggered by an extreme rainfall event in northern Australia

In February/March 2007, an extreme rainfall event occurred in the Jabiru region of the Northern Territory of Australia. Rainfall of 784 mm fell in a 72-h period. This rainfall event resulted in 49 separate landslides occurring in the adjacent, but remote and inaccessible region of Arnhem Land. The landslides were extensively mapped and characterised. A common feature of the landslides was their relatively surficial nature. This paper reports on laboratory and field tests to characterise the material properties of the slide material and the underlying, more competent material. One particular, large and relatively accessible landslide was chosen for detailed investigation. The experimental data are used to carry out seepage and slope stability analyses, taking account of changes in the degree of saturation (and thus the negative pore water pressure or suction) in the slope material during the rainfall event in question. Using a parametric study in which various material parameters were varied around the measured mean values, it is shown that the failure of this particular slope could have been predicted using relatively straightforward seepage and limit equilibrium slope stability analyses, coupled with the relevant rainfall data, as long as the contribution of matric suction to the engineering characteristics of the slope material was accounted for. The work also highlights the importance of in situ conditions at the time a particular rainfall event (particularly an extreme event such as that considered in this paper) occurs. If the slope has a relatively high degree of saturation, manifested as a low initial in situ suction, it is more susceptible to rainfall triggering a slope failure. Although this observation is not novel, the investigation described in this paper confirms the importance of ambient in situ conditions and provides an indication of how the likelihood of landslide occurrence at this particular site may in the future be quantified, i.e. by focussing on antecedent rainfall history.     

Thrust kinematics and transposition fabrics from a basal detachment zone, eastern Australia

Emplacement of an upper crustal, leading imbricate-fan thrust belt in the Lachlan Fold Belt of eastern Australia was accomplished along a 0.5–1 km thick zone of heterogeneously deformed, low grade phyllonite in pelitic rock. Continuous recrystallization and neocrystallization of mica in a zone of transposition layering has provided a weak zone at the base of a 100 km wide × 150 km exposed length × 10 km thick thrust system. The basal deformation zone is characterized by a low-moderately dipping, strong-intense transposition foliation enclosing elongate fault-bounded slices (up to 20 km long × 5 km wide in map view) of disrupted Cambrian metavolcanics and Upper Ordovician black shales and slates. These are derived from a structurally lower zone of duplexing or from the overturned limbs of anticlinorial structures. The detachment zone is a 10–15 km wide zone of intense deformation showing a transition from open, upright folds with weak cleavage to inclined, tightisoclinal folds with strong axial surface cleavage. The intensity of minor faults also increases into the zone. Leading imbricate fan thrust belts show maximum deformation effects along the basal detachment which forms the frontal or leading fault. The leading imbricate geometry is due to emplacement of the basal detachment zone up the lowest and last formed imbricate thrust. Movement is along a relatively ductile, low viscosity ‘layer’ at the base where strain softening occurs with development of transposition layering. This enables confined ‘flow’ along the basal zone with transport and emplacement of the fold system and duplex zone to higher structural levels. Reaction-enhanced ductility and grain boundary sliding may be important deformation mechanisms responsible for this flow. Localized polydeformation, marked by mesofolds and crenulation cleavage, reflects the interaction between thrust sheets and the movement on faults.     

Sedimentology of the continental end‐Permian extinction event in the Sydney Basin,eastern Australia

Upper Permian to Lower Triassic coastal plain successions of the Sydney Basin in eastern Australia have been investigated in outcrop and continuous drillcores. The purpose of the investigation is to provide an assessment of palaeoenvironmental change at high southern palaeolatitudes in a continental margin context for the late Permian (Lopingian), across the end‐Permian Extinction interval, and into the Early Triassic. These basins were affected by explosive volcanic eruptions during the late Permian and, to a much lesser extent, during the Early Triassic, allowing high‐resolution age determination on the numerous tuff horizons. Palaeobotanical and radiogenic isotope data indicate that the end‐Permian Extinction occurs at the top of the uppermost coal bed, and the Permo‐Triassic boundary either within an immediately overlying mudrock succession or within a succeeding channel sandstone body, depending on locality due to lateral variation. Late Permian depositional environments were initially (during the Wuchiapingian) shallow marine and deltaic, but coastal plain fluvial environments with extensive coal‐forming mires became progressively established during the early late Permian, reflected in numerous preserved coal seams. The fluvial style of coastal plain channel deposits varies geographically. However, apart from the loss of peat‐forming mires, no significant long‐term change in depositional style (grain size, sediment‐body architecture, or sediment dispersal direction) was noted across the end‐Permian Extinction (pinpointed by turnover of the palaeoflora). There is no evidence for immediate aridification across the boundary despite a loss of coal from these successions. Rather, the end‐Permian Extinction marks the base of a long‐term, progressive trend towards better‐drained alluvial conditions into the Early Triassic. Indeed, the floral turnover was immediately followed by a flooding event in basinal depocentres, following which fluvial systems similar to those active prior to the end‐Permian Extinction were re‐established. The age of the floral extinction is constrained to 252.54 ± 0.08 to 252.10 ± 0.06 Ma by a suite of new Chemical Abrasion Isotope Dilution Thermal Ionization Mass Spectrometry U‐Pb ages on zircon grains. Another new age indicates that the return to fluvial sedimentation similar to that before the end‐Permian Extinction occurred in the basal Triassic (prior to 251.51 ± 0.14 Ma). The character of the surface separating coal‐bearing pre‐end‐Permian Extinction from coal‐barren post‐end‐Permian Extinction strata varies across the basins. In basin‐central locations, the contact varies from disconformable, where a fluvial channel body has cut down to the level of the top coal, to conformable where the top coal is overlain by mudrocks and interbedded sandstone–siltstone facies. In basin‐marginal locations, however, the contact is a pronounced erosional disconformity with coarse‐grained alluvial facies overlying older Permian rocks. There is no evidence that the contact is everywhere a disconformity or unconformity.     

Determination of chemical weathering rates from U series nuclides in soils and weathering profiles: Principles,applications and limitations

The development of U-series nuclides for investigating weathering processes has been significantly stimulated by the analytical improvement made over the last decades in measuring the ²³⁸U series with intermediate half-lives (i.e., ²³⁴U–²³⁰Th–²²⁶Ra). It is proposed in this paper to present principles and methods that are now being developed to determine weathering rates from the study of U-series nuclides in soils and weathering profiles. Mathematical approaches, developed to calculate such rates, are based on some implicit assumptions that are also presented and must be kept in mind if one wants to correctly interpret the obtained ages.     

Response of a loess landslide to rainfall: observations from a field artificial rainfall experiment in Bailong River Basin,China

Rainfall-induced landslides are a significant hazard in many areas of loess-covered terrain in Northwest China. To investigate the response of a loess landslide to rainfall, a series of artificial rainfall experiments were conducted on a natural loess slope, located in the Bailong River Basin, in southern Gansu Province. The slope was instrumented to measure surface runoff, pore water pressure, soil water content, earth pressure, displacement, and rainfall. The hydrological response was also characterized by time-lapse electrical resistivity tomography. The results show that most of the rainfall infiltrated into the loess landslide, and that the pore water pressure and water content responded rapidly to simulated rainfall events. This indicates that rainfall infiltration on the loess landslide was significantly affected by preferential flow through fissures and macropores. Different patterns of pore water pressure and water content variations were determined by the antecedent soil moisture conditions, and by the balance between water recharge and drainage in the corresponding sections. We observed three stages of changing pore water pressure and displacement within the loess landslide during the artificial rainfall events: Increases in pore water pressure initiated movement on the slope, acceleration in movement resulting in a rapid decrease in pore water pressure, and attainment of a steady state. We infer that a negative pore water pressure feedback process may have occurred in response to shear-induced dilation of material as the slope movement accelerated. The process of shear dilatant strengthening may explain the phenomenon of semi-continuous movement of the loess landslide. Shear dilatant strengthening, caused by intermittent or continuous rainfall over long periods, can occur without triggering rapid slope failure.     

用稀盐酸浸取方法探讨玄武岩风化产物中REE与Al、P、Fe和Mn的依存关系

用2 mol/L HCl对海南新生代玄武岩风化剖面上的风化产物进行了浸取实验,通过浸取出来的稀土元素(REE)比例及其REE与Al、P、Fe和Mn的关系探讨风化产物中REE的赋存状态.结果显示,大部分REE、Al和Mn(＞50%)、相当一部分P(20%～40%)和Fe(-20%)被稀盐酸浸出.这些盐酸提取出来的REE(不包括Ce)根据含量不同与其他元素有不同的对应关系,较高的REE含量(＞250μg/g)与Al显示出良好的正相关关系,而与Fe、P和Mn相关性不明显;较低的REE含量(＜150μg/g)与Fe和P显示很好的正相关关系,与Mn正相关性不明显,与Al存在负相关关系;Ce与Mn存在较好的正相关关系,与Al、P和Fe没有明显的相关性.结合风化产物全样的相应元素分布特征可以判断,这些风化产物中高含量的REE(不包含Ce)是以比较松散的形式存在,并容易被流体淋滤出去,而正常含量的REE主要赋存于Fe氧化物/氢氧化物和次生磷酸盐矿物中,Ce的赋存则与Mn氧化物/氢氧化物有密切关系.同时也做了原岩的淋洗实验,发现Al、P及REE等元素被大量析出,因此不支持用2 mol/L以上的酸对岩石样品进行淋洗前处理.     

Chemical weathering in soils from the glacial Lake Agassiz region of Manitoba, Canada

 Recently, there has been considerable interest in categorizing the availability of plant essential nutrients and selected transition metals in the soil environment so as to predict their effects on ecosystem health and the efficacy of potential management practices. Researchers desire to isolate important soil properties, determinant biotic activities and fundamental pedogenic processes that control biogeochemical cycling and are potentially modifiable for the goal of ecosystem sustainability. In a relative sense, a significant portion of this scientific effort has been directed towards temperate and tropical forest ecosystems, with relatively less attention given towards understanding the boreal forest ecosystem. Consequently, an investigation was undertaken near Thompson, Manitoba, to: (1) determine the extent of weathering of the principal soils, (2) employ a selective-sequential chemical extraction method to categorize the soil-chemical fractions responsible for nutrient availability, and (3) infer the importance of selected soil forming processes responsible for soil genesis and nutrient availability. Preliminary findings suggest that nutrient availability is related to the nutrient concentration in the cation exchange fraction and/or to nutrients sequestered by the organic fraction. The metals in the manganese, noncrystalline and crystalline iron oxide fractions may be bound so tightly to these oxides that they are largely unavailable to plants; however, they are largely responsible for buffering the more labile pools against gradually changing vegetational and climatic conditions. Received: 31 October 1996 · Accepted: 21 May 1997     

Distribution and speciation of metals,phosphorus, sulfate and organic material in brackish estuary water affected by acid sulfate soils

Dissolved (<1 kDa) and colloidal (1 kDa-0.45 μm) size fractions of sulfate, organic carbon (OC), phosphate and 17 metals/metalloids were investigated in the acidic Vörå River and its estuary in Western Finland. In addition, geochemical modelling was used to predict the formation of free ions and complexes in these waters. The sampling was carried out during high-water flow in autumn and in spring when the abundantly occurring acid sulfate (AS) soils in the catchment area are extensively flushed. Based on the high concentrations of sulfate, acidity and several metals, it is clear that the Vörå River and its estuary is strongly affected by AS soils. The high dissolved form of metals limits also the existence of fish and other organisms in this estuary, and certainly also in other similar shallow brackish estuaries elsewhere in the Gulf of Bothnia. However, generally already <20% saline sea water reduces the concentration for OC and several elements (Al, Cu, Cr, Fe, Pb, PO₄ and U) by half and c. 20–30% saline sea water is needed to halve concentrations of Cd, Co, Mn, Ni and Zn. Consequently, these elements as well as organic matters were rapidly precipitated in the estuary, even after mixing with fairly small amounts of the alkaline brackish sea water. Aluminium, Cu, Fe and U most likely precipitate together with organic matter closest to the river mouth. Manganese is relatively persistent in solution and, thus, precipitates further down the estuary as Mn oxides, which concomitantly capture Ba, Cd, Co, Cu, Ni and Zn. In the inner estuary, the high contents of Al is as important than Fe in removing PO₄ and, thus, also reducing the risk of algae blooms in near coastal areas influenced by AS soils in the Gulf of Bothnia. Moreover, the dispersion of metals far out in the estuary is dependent on hydrological conditions, i.e. with high flows the plume of metal-rich water will spread further out in the estuary. Furthermore, the extensive drainage of the catchment and subsequent artificial enlargement of the river channel during recent decades has not only enabled oxidation of sulfidic sediments, but strongly increased flow peaks that reach further out in the estuary.     

Characterization of acid sulfate soils and assessing their impact on a humic boreal lake

Due to acidity and metals from acid sulfate soils (a.s. soils), many watercourses in midwestern Finland have since 1960s regularly experienced short but intensive periods of poor water quality during high water flow. This has led to occasional massive fish kills and a significant decline in fish populations.     

Function of a deltaic silt deposit as a repository and long-term source of sulfate and related weathering products in a glaciofluvial aquifer derived from organic-rich shale (North Dakota,USA)

A shallow unconfined glaciofluvial aquifer in North Dakota (USA) has largest groundwater sulfate concentrations near the bottom boundary. A deltaic silt layer underlying the aquifer, at >16 m, is the modern proximate sulfate source for the aquifer. The original sulfate source was pyrite in the organic-rich shale component of the aquifer and silt grain matrix. An oxidizing event occurred during which grain-matrix pyrite sulfur was oxidized to sulfate. Thereafter the silt served as a “conserving” layer, slowly feeding sulfate into the lower part of the aquifer and the underlying till. A method was developed for estimating the approximate initial sulfate concentration in the source layer and the redistribution time since the oxidizing event, using a semi-generic convection–dispersion model. The convection–dispersion model and a model for the evolution of modern sulfate δ ³⁴S in silt-layer pore water from the initial grain-matrix pyrite δ ³⁴S, both estimated that the oxidizing event occurred several thousand years ago, and was likely related to the dry conditions of the Hypsithermal Interval. The silt layer also serves as an arsenic source. Results indicate that deltaic silts derived from organic-rich shale parent materials in a glacial environment can provide long-term sources for sulfate and arsenic and possibly other related oxidative weathering products.     

Changes in the composition of organic matter from prodeltaic sediments after a large flood event (Po River, Italy)

The Po River (Italy) experienced a 100-year flood in October 2000. Surface sediments (0-1 cm) from cross-shelf transects were collected in the Po prodelta area (Adriatic Sea) in December 2000, in order to describe the distribution of organic matter (OM) along the main sediment dispersal system immediately after the flood event. Stations were subsequently reoccupied in October 2001 and April 2002. This sampling program provided a special opportunity to characterize the initial surficial flood deposit and the evolution of its associated OM over the course of 2 years. CuO oxidation, elemental, δ¹³C, Δ¹⁴C, and grain-size analyses were carried out to characterize the source, age, and spatial variability of sedimentary OM. Statistical analysis (PERMANOVA) was then applied to investigate temporal changes in different portions of the Po prodelta area. Isotopic and biomarker data suggest that the sedimentary OM in the flood deposit was initially dominated by aged (Δ¹⁴C_Dec-00 = −298.7 ± 56.3‰), lignin-poor OM (Λ_Dec-00 = 1.96 ± 0.33 mg/100 mg OC), adsorbed on the fine material (clay_Dec-00 = 72.1 ± 4.8%) delivered by the flood. In the 2 years following the flood, post-depositional processes significantly increased the content of lignin (Λ_Oct-01 = 2.19 ± 0.51 mg/100 mg OC; Λ_Apr-02 = 2.61 ± 0.63 mg/100 mg OC); and coarse material (silt and sand), while decreasing the contributions from aged OC (Δ¹⁴C_Oct-01 = −255.7 ± 32.8‰; Δ¹⁴C_Apr-02 = −213.2 ± 30.4‰) and fine fraction (clay_Oct-01 = 54.8 ± 9.5%; clay_Apr-02 = 44.6 ± 13.3%). The major changes were observed in the northern and central portions of the prodelta.     

Flushing of dense, hypoxic water from a cavity of the Swan River estuary, Western Australia

Flushing of dense water from cavities of the upper reaches of the Swan River estuary in Western Australia was investigated using measured salinity and dissolved oxygen profiles and a two-dimensional, laterally averaged hydrodynamic model (TISAT). Seasonal flushing of dense, hypoxic bottom waters from a relatively deep site took place over ∼3 days at the onset of winter in 1994. Model simulations of the purging of this dense water did not correspond closely with changes in the densimetric Froude number. Purging, expressed as depth of the halocline as a fraction of the total cavity depth, occurred when the simulated mean horizontal velocity at 2 m depth (top of cavity) changed from negative to strongly positive, indicating arrest of upstream flow and continuous downstream flow. This corresponded to freshwater discharge of about 50 m³ s⁻¹. Oxygen depletion of bottom waters was closely related to stratification. Oxygen dynamics at the onset of winter river flow was analysed using an exponential decay model, assuning that there was no net inflow or outflow across the halocline and thus no vertical transport of oxygen during a period of strong stratification. The rate constant for oxygen decay at Ron Courtney Island (RCI) was estimated to be 0.232 d⁻¹ for this period. Bottom waters at RCI declined to less than 1 mg 1⁻¹ prior to complete flushing through increased river flows. This study provided in sights to how freshwater flows may be allocated to maintain suitable oxygen levels in the bottom waters of estuarine cavities.     

Caesium as a possible discriminant between felsic rocks of different origins from eastern Australia

The use of Cs to discriminate between igneous rocks derived from an igneous’ protolith (I‐type) and those derived from a metasedimentary protolith (5‐type) is evaluated for selected eastern Australian granitic and felsic volcanic rocks. For this investigation a ‘flame emission’ technique has been developed and tested for the rapid determination of Cs in rock samples. In the Berridale Batholith, where the I‐type, 5‐type subdivision was first recognized, the Cs content of the granites clearly distinguished the two granite types. In the New England Batholith the leucocratic 5‐types have higher Cs abundances, in most cases, than the similar I‐type granites, but the Cs values of the more mafic 5‐type granites overlap those of the I‐type. Problems in assigning origins for volcanics are complicated by alteration, but Cs may be useful in distinguishing reworked tuffs from volcanic rocks in volcanic sequences. Caesium may also find application in distinguishing volcanics and sediments in Precambrian terrains.     

Impact of variational assimilation technique on simulation of a heavy rainfall event over Pune,India

Prediction of heavy rainfall events due to severe convective storms in terms of their spatial and temporal scales is a challenging task for an operational forecaster. The present study is about a record-breaking heavy rainfall event observed in Pune (18°31′N, 73°55′E) on October 4, 2010. The day witnessed highest 24-h accumulated precipitation of 181.3 mm and caused flash floods in the city. The WRF model-based real-time weather system, operating daily at Centre for Development of Advanced Computing using PARAM Yuva supercomputer showed the signature of this convective event 4-h before, but failed to capture the actual peak rainfall and its location with reference to the city’s observational network. To investigate further, five numerical experiments were conducted to check the impact of assimilation of observations in the WRF model forecast. First, a control experiment was conducted with initialization using National Centre for Environmental Prediction (NCEP)’s Global Forecast System 0.5° data, while surface observational data from NCEP Prepbufr system were assimilated in the second experiment (VARSFC). In the third experiment (VARAMV), NCEP Prepbufr atmospheric motion vectors were assimilated. Fourth experiment (VARPRO) was assimilated with conventional soundings data, and all the available NCEP Prepbufr observations were assimilated in the fifth experiment (VARALL). Model runs were compared with observations from automated weather stations (AWS), synoptic charts of Indian Meteorological Department (IMD). Comparison of 24-h accumulated rainfall with IMD AWS 24-h gridded data showed that the fifth experiment (VARALL) produced better picture of heavy rainfall, maximum up to 251 mm/day toward the southern side, 31 km away from Pune’s IMD observatory. It was noticed that the effect of soundings observations experiment (VARPRO) caused heavy precipitation of 210 mm toward the southern side 49 km away from Pune. The wind analysis at 850 and 200 hPa indicated that the surface and atmospheric motion vector observations (VARAMV) helped in shifting its peak rainfall toward Pune, IMD observatory by 18 km, though VARALL over-predicted rainfall by 60 mm than the observed.     

Fluid flow characteristics of Bandanna Coal Formation: a case study from the Fairview Field,eastern Australia

Fluid flow characteristics of cleat systems in coalbed methane reservoirs are crucial in reservoir management and field development plans. This paper aims to evaluate the cleat system properties including cleat porosity, permeability, and aperture as well as the impact of permeability growth on production performance in the Bandanna Coal Formation of the Fairview Field, eastern Queensland. Owing to the presence of bad hole conditions and poor core recovery of the coal intervals, the petrophysical well logs and laboratory measurements cannot be used as a source of information for this purpose. Hence, a new approach is employed that utilises early water production data to measure water in place and absolute permeability of the coal. In addition, micro-computed tomography (CT) scan method is used to investigate the cleat system that is preserved in a core sample and results are compared with the ones obtained by analysis of production data. Cleat system evaluation by analysis of production data and micro-CT scan technique provides a comprehensive approach that brings confidence in measurements and helps to obtain cleat properties at the sufficient scale for reservoir engineering purposes. The necessary information including production data and core samples are collected from a dewatering well and the nearby observation well in the study area. Analysis of early water production data (single-phase flow) indicates that coal permeability is 189 mD and the average cleat porosity is approximately 5%. High cleat porosity describes the large volume of water produced over the life of the study well. The 3D model of the fossilised cleat system constructed by the micro-CT scan method reveals that coal is well-cleated and cleat spacing and mean cleat aperture are 4 and 0.136 mm, respectively. The average cleat porosity that is measured by the micro-CT scan method is 5.7%, which is fairly close to the cleat porosity measured by analysis of production data. Production data analysis indicates that effective permeability to gas starts to grow at the midlife of the well and it strongly controls the shape of the production profile. The results of this study help in future field development and infill drilling programs in the Fairview Field and provide important insights into cleat system of Bandanna Coal Formation.     

Chemical dynamics and weathering rates of a carbonate basin Bow River,southern Alberta

Discharge is the dominant control on the TDS load of the Bow River; TDS varies inversely with discharge. Although discharge is the dominant control on concentration, the sources of ions in the river are atmospheric deposition and water/rock interaction. Atmospheric loading can be a significant source of some ions in the pristine headwaters of the river (e.g., 50% of K, 17% of SO₄, 16% of Cl). In terms of water/rock interaction, the input of ions to the river is largely controlled by dissolution of carbonate and evaporite minerals.The chemical denudation rate for the Bow River at Banff is 678 kg/ha/a, or 1.50×10⁸ kg of rock that is removed as dissolved load each year, in the low range for an alpine carbonate basin. An additional 11 kg/ha/a are removed as suspended load. A rock volume of 5.45×10⁴ m³ is carried by the Bow River from Banff National Park each year.