青藏高原风火山盆地地层含矿性及矿床成因研究

通过对盆地形成过程的研究,认为风火山盆地经历了基底、古地貌盆地、沉积盆地及构造盆地4个阶段,在晚白垩世沉积形成.地层含矿性特征表明,晚白垩世风火山群砂岩夹灰岩组和砂岩组地层是含矿地层,其中砂岩夹灰岩组是主要含矿地层,与铜矿成矿关系密切.矿床成因分析认为,盆地附近的隆起区作为蚀源区,其晚三叠世地层及其他浅成侵入岩等,为沉积盆地提供了沉积物,也为盆地地层沉积提供了铜质来源.在砂岩夹灰岩组和砂岩组地层中,还原、碱性环境下沉积形成的灰绿色碎屑岩形成了矿源层,经过后期的活化、迁移、富集,形成了沉积一改造型层控铜矿床.     

大庆长垣南端晚白垩世孢粉组合特征及其古气候记录

钻孔ZKMX15位于松辽盆地北部大庆长垣南端,岩性以泥岩夹粉砂岩为主,富含孢粉化石.通过对大庆长垣南端铀矿区钻孔ZKMX15岩芯孢粉分析,可以确定采样段岩心的地质时代为晚白垩世Campanian期;根据沉积特征和孢粉植物群面貌,对古植被和古气候进行了讨论,认为本区晚白垩世嫩江组上部沉积时期植被类型是针叶林、草丛,属于半...     

松辽盆地朝73-87井青山口组缺氧事件层的有机地球化学特征

松辽盆地白垩纪青山口组下部广泛分布一套富含有机碳的黑色泥岩、页岩和油页岩沉积,是全盆地划分泉头组与青山口组的一级标志.朝73-87井青山口组黑色页岩、油页岩的地球化学特征研究表明：它具有干酪根碳同位素正偏和重排甾烷含量低,存在28,30一双降藿烷、伽马蜡烷生物标志化合物等有机地球化学特征,表征为白垩纪温室效应时间窗内古湖泊缺氧事件的产物.结合生物地层研究成果,认为青山口期缺氧事件层大体可与白垩纪古海洋Cenomanian-Turonian界线事件层进行对比,进而提出松辽盆地青山口组的时代归属晚白垩世晚cenomanian-Turonian期的新观点.     

松辽盆地白垩系青山口阶缺氧事件层的有机地球化学特征

松辽盆地白垩系青山口阶下部广泛分布一套富含有机碳的黑色泥岩、页岩沉积,它具有干酪根碳同位素正偏、重排甾烷含量低,普遍存在伽马蜡烷生物标志化合物等有机地球化学特征,代表了白垩纪温室效应时间窗内古湖泊贫氧环境条件下的沉积产物。结合生物地层研究成果,认为青山口阶下部曾发生过古湖泊缺氧事件,其层位大体可与白垩纪古海洋Cenomanian-Turonian界线事件层进行对比,由此提出了松辽盆地青山口阶下部的时代归属于晚白垩世Cenomanian晚期—Turonian早期的新观点。     

松辽盆地晚白垩世青山口组缺氧事件层的地质地球化学特征

松辽盆地白垩系青山口组下部广泛分布一套富含有机碳的黑色泥岩、页岩沉积,是全盆地地层划分对比的一级标志。茂206井是中国白垩纪大陆科学钻探工程井,全井获取了青山口组497.02 m的岩心资料。茂206井青山口组具有相对高的有机碳、干酪根碳同位素正偏、重排甾烷含量低以及普遍存在伽马蜡烷生物标志化合物等有机地球化学特征,表征为白垩纪温室效应时间窗内古湖泊缺氧事件的产物。结合生物地层研究成果,认为青山口期缺氧事件层大体可与白垩纪古海洋Cenomanian-Turonian界线事件层进行对比,进一步证实了青山口组的地质时代属晚白垩世晚Cenomanian-Turonian期的观点。     

松辽盆地东南隆起区深部地层孢粉组合及其时代讨论

松辽盆地东南隆起区深部地层十分发育,含丰富的孢粉化石,所建立的4个孢粉组合,为地层划分对比和时代确定提供了生物地层学依据。火石岭组相当于晚侏罗世,沙河子组为早白垩世凡兰吟期至戈特里夫期,营城组为早白垩世巴列姆期,十屋组为早白垩世阿普第期。     

松辽盆地东南缘晚中生代火山事件的锆石年代学与地球化学制约

松辽盆地东南缘营城组地层中发育大量的晚中生代火山岩。SHRIMP锆石U-Pb测年表明,火山岩主要形成于117~110Ma,可以划分出早、晚两期,时代上属于早白垩世Albian期-Aptian期。岩石学和地球化学研究表明火山活动早期以酸性喷发为主,晚期则以中基性的玄武粗安岩喷发为主,基本上都属高钾钙碱性系列或亚碱系列,两期火山岩具有演化的亲缘性特征。Sr-Nd同位素研究表明,早、晚两期火山岩是同源岩浆演化的产物,来源于亏损型地幔源区,但演化过程又受到地壳物质不同程度的混染。松辽盆地东南缘火山事件的精确厘定对认识覆盖区晚中生代火山活动序列及邻区岩浆事件的对比具有重要的意义。     

山东平邑盆地官庄群有关地层的重新厘定

平邑盆地的官庄群是我国罕见的富含碳酸盐岩和石膏岩的非海相河湖沉积,中生界-新生界界线连续,孢粉和其他微体生物化石丰富,对研究我国华北地区晚白垩世与古新世生物群及其演变、白垩系-古近系界线以及晚白垩世晚期的地质事件等具有十分重要的意义,引起众多地质学者的关注。通过对平邑盆地官庄群岩石地层的详细考察及对其赋存的生物群的研究,对固城组和卞桥组的定义进行了厘定。固城组为下粗上细的红色砂砾岩和砂泥岩,含砾石,其成分基本为火山岩,含晚白垩世孢粉和其他微体化石,时代为晚白垩世晚期;卞桥组为一套富含碳酸盐岩和石膏的地层,富含晚白垩世晚期至古新世孢粉和其他微体化石,可分为3个岩性段,白垩系-古近系界线在卞桥组一段的一、二亚段之间。     

松辽盆地坳陷期湖盆层序地层研究

以横跨松辽盆地北部东西向大剖面为例,综合应用钻井岩芯、测井曲线、古生物和地震资料,进行松辽盆地北部坳陷期(早白垩世晚期—晚白垩世)湖盆层序地层学研究,共识别出2个二级层序界面和13个三级层序界面,划分出2个二级层序和13个三级层序。2个二级层序以姚家组底界不整合面为界,自下而上命名为SSI、SSII。     

中国东北中生代构造体制与区域成矿背景: 来自中生代火山岩组合时空变化的制约

本文系统总结了东北地区中生代火山岩的年代学、岩石组合及其时空分布规律,以便对环太平洋构造体系和蒙古——鄂霍茨克构造体系中生代的演化历史及其东北地区中生代区域成矿背景给出制约。基于火山岩中锆石U——Pb定年结果,东北地区中生代火山作用可划分成六期:晚三叠世(200～228Ma)、早——中侏罗世(173～190Ma)、中——晚侏罗世(158～166Ma)、早白垩世早期(138～145Ma)、早白垩世晚期(106～133Ma)和晚白垩世(88～97Ma)。晚三叠世火山作用主要分布在吉黑东部和小兴安岭——张广才岭地区,前者为A型流纹岩,后者为双峰式火山岩组合,它们共同揭示了古亚洲洋最终闭合后的伸展环境;早——中侏罗世火山岩主要分布在吉黑东部、小兴安岭——张广才岭和额尔古纳地区,吉黑东部和额尔古纳地区早——中侏罗世钙碱性火山岩的存在分别标志着古太平洋板块和蒙古——鄂霍茨克洋板块俯冲作用的发生,而小兴安岭——张广才岭早——中侏罗世火山岩则以双峰式火成岩组合为特征,反映了双向俯冲的弧后伸展环境;中——晚侏罗世和早白垩世早期火山岩主要分布在松辽盆地以西和冀北——辽西地区,前者为碱性——亚碱性的过渡系列,主要由玄武粗安岩、粗安岩和少量粗面岩组成,后者为A型流纹岩或碱性流纹岩组成,这些火山岩形成于加厚陆壳的坍塌或拆沉阶段;早白垩世晚期火山岩广泛分布于东北地区,吉黑东部为钙碱性火山岩组合,而松辽盆地和大兴安岭地区则主要为双峰式火山岩组合,前者标志着古太平洋板块的俯冲,后者与早期加厚陆壳的拆沉和/或类似弧后的伸展环境有关;晚白垩世火山岩主要分布在吉黑东部和陆内,前者为钙碱性火山岩组合,后者为碱性玄武岩,反映了来自东部环太平洋构造体系的俯冲作用。综合上述中生代火山岩的岩石组合及时空分布特征,可以判定:1)环太平洋构造体系对东亚大陆下的俯冲始于早侏罗世,中生代期间存在早侏罗世、早白垩世晚期和晚白垩世三次俯冲事件,其影响的空间范围主要在松辽盆地及其以东地区,陆缘和古俯冲带是寻找斑岩型矿床的有利场所,而陆内的伸展区域主要与浅成低温热液矿床有关;2)蒙古——鄂霍茨克构造体系经历了中生代早期的俯冲事件和中侏罗世及早白垩世早期两次陆内推覆事件,其影响的空间范围主要在松辽盆地以西地区和华北地块北缘,中生代早期的俯冲事件主要与活动陆缘背景下的斑岩型矿床关系密切,而晚侏罗世和早白垩世两次与加厚陆壳拆沉有关的伸展背景有利于多金属矿床的形成。     

Climatic signals in lacustrine deposits of the Upper Yacoraite Formation,Western Argentina: Evidence from clay minerals,analcime, dolomite and fibrous calcite

Authigenic clays are an important control on reservoir quality in lacustrine carbonates but remain challenging to predict. Lacustrine depositional systems respond to climatic variations in rainfall, surface runoff and groundwater input, and evaporation, and result in rapid and frequent changes in lake volume; this is expressed through changing water depth and shoreline position. In the upper portion of the Early Palaeocene Yacoraite Formation of the Salta Basin in Argentina, extensive lacustrine deposits were deposited during the sag phase of rifting. Prior high-resolution stratigraphic studies have suggested that climatic factors control microbial carbonate sequences within a ‘balanced fill’ lake, with variation in the lake level having a major influence on facies association changes. This study characterizes the evolution of facies and mineralogy within the Yacoraite Formation, focusing on the distribution of clay minerals, making a link between the high, medium and low-frequency sequence stratigraphic cycles. The low-frequency transgressive hemicycle of the upper portion of the Yacoraite Formation is comprised of abundant siliciclastic facies, suggesting a wetter period. Microbialites occurring in this interval are coarse-grained and agglutinated. Detrital clay minerals such as illite and chlorite and associated siliciclastic sediments were input to the lake during high-frequency transgressive periods. During high-frequency regressive hemicycles, sedimentation was dominated by carbonate facies with Ca-rich dolomite and the authigenic clays are comprised of chlorite/smectite mixed-layers. By contrast, the low frequency regressive hemicycle records fine-grained agglutinated microbialite with horizons of fibrous calcite, more stoichiometric dolomite, barite and authigenic magnesian smectite. This indicates elevated ion concentrations in the lake under intense evaporation during an arid period. Understanding the conditions that are favourable for formation and preservation of authigenic clays within the lacustrine environment can improve understanding of reservoir quality in comparable economically important deposits.     

广安地区侏罗系凉高山组粘土矿物研究

四川广安地区侏罗系粘土矿物类型主要为绿泥石、高岭石、伊蒙混层和伊利石;同一口井随着深度的增加,伊利石、绿泥石含量增加,伊蒙混层中的蒙脱石混层比降低。粘土矿物特征与储集层物性的相关性分析认为:伊蒙混层含量、伊利石含量均与储集层孔渗性能呈负相关,绿泥石与高岭石含量与储集层孔渗性呈正相关;通过对伊蒙混层中蒙脱石的混层比的计算,大多数为有序混层,说明该区凉高山组处于生油高峰期,这与岩石中TOC(%)介于0.8与1.3,Ro(%)介于0.7与1.2相吻合。     

兰州市取暖期可吸入颗粒物中单颗粒矿物组成特征

为研究兰州市2005年冬季大气可吸入颗粒物(PM10)中单颗粒的矿物组成,用能谱扫描电镜识别和统计了兰州市区(东方红广场)和郊区(榆中县)两个采样点的单矿物颗粒。结果在市区样品中识别出方解石、伊/蒙混层、石英、斜长石、伊利石、石膏、绿泥石、高岭石、浊沸石和钾长石等21种矿物,前7种占统计总量的75%以上;郊区样品中识别出20种矿物,以方解石、石英、伊利石、绿泥石、斜长石和伊/蒙混层为主(占70%以上),与市区相比缺少钾石膏、金红石和水铝酸钙而增加了硫酸镁和磷灰石。总体来看,大气PM10中的矿物颗粒可分为粘土类、长石类、碳酸盐类、硫酸盐类、氧化物类和其他六类,以粘土类和碳酸盐类矿物为主(约占60%);冬季市区颗粒物表面的“硫化”现象较郊区严重;这些矿物颗粒主要来自地表土,人为排放和大气中二次化学反应生成的矿物的贡献较小。     

Clay petrology of the Upper Triassic/Lower Jurassic terrestrial strata of the Newark Supergroup,Connecticut Valley,U.S.A.

The clay mineralogy of the Newark Supergroup (Upper Triassic/Lower Jurassic) in the Connecticut Valley was studied by X-ray diffraction analysis. Clay minerals identified in 126 samples are illite, chlorite, smectite, kaolinite, vermiculite, expandable chlorite, mixed-layer illite/smectite, mixed-layer chlorite/smectite, and mixed-layer chlorite/vermiculite. In general, the rocks are illitic with subordinate amounts of chlorite. However, the various lithofacies in the Newark Supergroup are characterized by distinct clay-mineral assemblages. Red beds of floodplain origin contain clays mainly of detrital nature with 2M illite most abundant. Subordinate amounts of chlorite, smectite, vermiculite, kaolinite and mixed-layer illite/smectite are also present. An interstratified chlorite/vermiculite occurs in red mudstone underlying basalt flows. Lacustrine gray beds are generally characterized by the clay-mineral assemblage 1Md illite + chlorite with minor amounts of smectite ane expandable chlorite. An interstratified chlorite/smectite predominates in gray mudstone associated with perennial lake cycles in the East Berlin Formation. Black shales of deeper lacustrine origin contain the assemblage 1Md ifillite + trioctahedral smectite and traces of chlorite. Illite and smectite also occur as mixed-layer phases.In many respects, the distribution of clay minerals in the Connecticut Valley can be likened to the general scheme proposed for the Permo-Triassic basins of Europe and Africa. These display both vertical and horizontal variations in clay-mineral assemblages that reflect the chemical and spatiotemporal evolution of intrabasin depositional and diagenetic environments. Chemical data indicate that magnesium, especially, was concentrated in the black muds of large perennial lakes that intermittently occupied the Connecticut rift valley. Pore waters derived from these sediments played an important role in the development of Mg-rich 2 : 1 and interstratified clay minerals during early diagenesis.     

Near‐isochemical evolution of clay mineral assemblages in differentially buried volcaniclastic sediments,the Late Miocene Upper Red Formation,Iran

The Upper Red Formation (URF) comprises over 1–5 km of late Miocene siliciclastic sediments in the Central Iran Basin. The formation is dominated by volcaniclastic conglomerates and arenites. The prevailing arid conditions during most of the basin's history resulted in deposition of predominantly organic‐poor, red sediments with gypsum and zeolites. This investigation concentrates on the mineralogy and geochemistry of the URF in the southern and northern margins of the basin where the formation was buried to depths of 2.4 and 6.6 km, respectively. Fine fraction mineral separates from the southern margin consist of nearly pure smectite and zeolites at a depth of 400 m and smectite with minor quartz and calcite at 1800 m. Shallow samples (1350 m) from the northern section are rich in smectite, illite/smectite with some discrete illite and chlorite. This assemblage is progressively replaced by discrete illite and chlorite with increasing burial depth so that only these two minerals are found at depths greater than 4300 m. The initial alteration process involved replacement of glass and volcanic lithics by smectite and zeolites in both margins of the basin. Increased depth of burial in the northern margin resulted in the progressive isochemical alteration of smectite to discrete illite and chlorite. Diagenesis of clay assemblages occurred essentially in a closed system. Solute products of glass hydrolysis reactions were retained in highly alkaline, saline ground waters from which zeolites, carbonates and oxides precipitated as cements. It is unlikely that these sediments were ever significantly leached by meteoric waters or by organic acids generated during burial diagenesis. Copyright © 2010 John Wiley & Sons, Ltd.     

鄂尔多斯盆地东缘C-P煤系致密砂岩储层敏感性分析

鄂尔多斯盆地临兴地区上古生界致密砂岩储集层中矿物组成多样、孔隙结构复杂且黏土矿物含量高,直接影响储层改造和开发效果。文章基于X 衍射、铸体薄片、气测孔渗、压汞和敏感性实验,系统研究了储层敏感性及其影响因素。结果表明研究区砂岩中石英和岩屑含量高,长石含量较低,以岩屑砂岩、岩屑石英砂岩、长石岩屑砂岩和石英砂岩为主。黏土矿物主要为伊利石、高岭石、绿泥石以及伊/蒙混层;储层普遍低孔低渗,孔隙结构较差。速敏以太原组最强,山西组最弱,与伊利石+绿泥石含量正相关,高岭石含量负相关。水敏下石盒子组最强,太原组最弱,与伊/蒙混层含量正相关。盐敏与水敏有类似特点,与伊/蒙混层含量表现出正相关。酸敏山西组最强,下石盒子组最弱,与绿泥石和铁白云石矿物含量正相关。碱敏性山西组最强,太原组最弱,受长石、石英和高岭石含量影响。相关认识有助于指导研究区钻井、压裂等施工工艺选择和排采控制。     

Clay Minerals in an Active Hydrothermal Field at Iheya‐North‐Knoll,Okinawa Trough

Iheya‐North‐Knoll is one of the small knolls covered with thick sediments in the Okinawa Trough back‐arc basin. At the east slope of Iheya‐North‐Knoll, nine hydrothermal vents with sulfide mounds are present. The Integrated Ocean Drilling Program (IODP) Expedition 331 studied Iheya‐North‐Knoll in September 2010. The expedition provided us with the opportunity to study clay minerals in deep sediments in Iheya‐North‐Knoll. To reveal characteristics of clay minerals in the deep sediments, samples from the drilling cores at three sites close to the most active hydrothermal vent were analyzed by X‐ray diffraction, scanning electron microscope and transmission electron microscope. The sediments are classified into Layer 0 (shallow), Layer 1 (deep), Layer 2 (deeper) and Layer 3 (deepest) on the basis of the assemblage of clay minerals. Layer 0 contains no clay minerals. Layer 1 contains smectite, kaolinite and illite/smectite mixed‐layer mineral. Layer 2 contains chlorite, corrensite and chlorite/smectite mixed‐layer mineral. Layer 3 is grouped into three sub‐layers, 3A, 3B and 3C; Sub‐layer 3A contains chlorite and illite/smectite mixed‐layer mineral, sub‐layer 3B contains chlorite/smectite and illite/smectite mixed‐layer minerals, and sub‐layer 3C contains chlorite and illite. Large amounts of di‐octahedral clay minerals such as smectite, kaolinite, illite and illite/smectite mixed‐layer mineral are found in Iheya‐North‐Knoll, which is rarely observed in hydrothermal fields in mid‐ocean ridges. Tri‐octahedral clay minerals such as chlorite, corrensite and chlorite/smectite mixed‐layer mineral in Iheya‐North‐Knoll have low Fe/(Fe + Mg) ratios compared with those in mid‐ocean ridges. In conclusion, the characteristics of clay minerals in Iheya‐North‐Knoll differ from those in mid‐ocean ridges; di‐octahedral clay minerals and Fe‐poor tri‐octahedral clay minerals occur in Iheya‐North‐Knoll but not in mid‐ocean ridges.     

鄂尔多斯盆地白垩系粘土矿物的分布特征及其沉积-成岩环境意义

系统地分析了鄂尔多斯盆地白垩系粘土矿物的特征及其沉积、成岩环境意义。研究结果表明:白垩系砂岩、泥质岩的粘土矿物组合以I+C+I/S型、I+C型为主,具有高伊利石含量,较高绿泥石、伊/蒙混层矿物含量的粘土矿物组成特点;其中泥质岩粘土矿物主要为陆源碎屑成因,次为沉积成岩过程中形成的自生粘土矿物,而砂岩粘土矿物兼有陆源碎屑成因和沉积成岩过程自生成因的特征;白垩系沉积时气候总体特征为干旱—半干旱,但局部时段发生干—湿气候波动而处于短暂的湿热气候环境;白垩系沉积物源富含长石等硅酸盐矿物,沉积物质主要自北、南、西向盆地内部搬运沉积;白垩系沉积和埋藏成岩过程中水介质整体上具有盐度较高,偏碱性,富K+、Fe2+、Mg2+的特点,且总体上盆地南部水介质中的这些指标都高于北部。     

兰州盆地永登剖面晚古新世—早渐新世沉积物中粘土矿物的特征及其古气候指示意义

采用X射线衍射、扫描电镜分析方法,对兰州盆地永登剖面晚古新世—早渐新世沉积物中粘土矿物的相对含量、伊利石结晶度、显微形貌及其古气候意义进行深入研究。结果表明:晚古新世—早渐新世沉积物中粘土矿物主要为伊利石、蒙脱石、绿泥石和少量的坡缕石,其中伊利石的含量最高,而且从晚古新世到早渐新世,沉积物中伊利石的含量呈明显升高的趋势,蒙脱石则呈明显减少的趋势;在大约55 Ma处伊利石含量急剧减小,而蒙脱石含量急剧增大。此外,可见到毛发状的自生坡缕石沿蒙脱石晶片边缘交代生长,而碎屑成因的坡缕石则主要呈破碎的短棒状。粘土矿物分布特征表明,兰州盆地晚古新世—早渐新世的古气候以干旱为主导,并且经历了由相对温暖湿润到半干旱半湿润或干旱炎热的转变,这种气候转型主要受全球气候的影响,即受行星风系的控制;而在大约55 Ma处伊利石、蒙脱石的含量变化则记录了全球性的PETM事件。     

蒙脱石+伊/蒙混层+伊利石等粘土矿物混合物相X射线定量分析方法—模拟定量法

本文提出粘土矿物(特别是含伊/蒙不规则混层粘土矿物)混合物相的X射线定量分析方法——模拟定量法。着重解决在蒙脱石-不规则伊/蒙混层粘土矿物-伊利石组合中,伊/蒙混层粘土矿物的定量分析计算。模拟定量法是对以前的各种粘土矿物X射线定量分析方法的补充。用纯净的蒙脱石、伊利石、高岭石、绿泥石及各种伊/蒙混层比的伊/蒙混层粘土矿物,配制了各种不同组合的粘土矿物混合样品,制成定向薄膜片,进行了X射线分析,讨论了各种组合的粘土矿物混合物相X射线衍射图谱的特征,并在此基础上提出了粘土混合物相定量分析的方法。