Stability of CRMs: Significance to the User

The stability of geochemical reference materials is subject to breakdown due to mineralic component or particle size fraction segregation or to ambient oxidation. A statistical design is presented to the analyst for detecting such a breakdown as soon as possible to avoid the resultant degradation in his output. The application of this design to a base metal certified reference material, MP-1a, is illustrated.     

Neoproterozoic to Early Ordovician Evolution of the Paleo-Asian Ocean: Implications to the Break-up of Rodinia

The paper reviews and integrates the recent geological and geochronological data, which allow us to recognize three stages of the evolution of the Paleo-Asian Ocean.The opening of the Paleo-Asian Ocean at 970-850 Ma is dated by the Nersin Complex in the Aldan shield, plagiogranites of the Sunuekit massif, enderbites of the Sludinsk Lake area, and passive margin sediments of the Patoma or Baikal series. The initial subduction (850-700 Ma) is marked by volcanic rocks, trondjemite and gabbro of the Sarkhoy island arc series. Collisions of microcontinents with Siberia at 660 to 620 Ma are evidenced by the exhumation of Muya eclogites (650 Ma), formation of migmatites and amphibolites of the Njurundukan belt (635 and 590 Ma), metamorphic units of the Near-Yenisei belt (640-600 Ma), and orogenic molasse (640-620 Ma). The Paleo-Asian Ocean maximally opened at 620-550 Ma, because at that time a long island arc composed of boninite volcanic rocks was formed. Primitive island arcs of that age have been reconstructed in Kazakhstan, Gorny Altai, West and East Sayan, and North Mongolia. HP and UHP rocks formed in two stages at 550-520 and 520-490 Ma. At 550-490 Ma oceanic islands and Gondwana-derived microcontinents (Kokchetav, Tuva-Mongolian, Central Mongolian and others) collided with the Cambrian-early Ordovician island arc of the Siberian continent. As a result, the island-arc system was extensively modified. Collision occurred twice at 550-520 and 520-490 Ma during which many HP and UHP rocks formed. At that time, the new oceans - the Junggar, Kazakhstan and Uralian - with an Ordovician island arc were formed.     

古地磁:从地球到火星

古地磁学是一门典型的交叉学科,通过综合地质学、地球物理学、环境科学等学科相关方法,分析天然样品中记录的磁学信息,深入研究地磁场演化、地球动力学过程、古环境与古气候演化等.自20世纪中叶以来,古地磁学在各研究领域得到快速发展,通过进一步与其他学科交叉,衍生出诸多新兴方向.首先回顾了古地磁学的发展历史与基础研究领域.在此基础上,重点介绍了高精度卫星磁测与相关研究新领域、月球与火星磁学研究的新进展.同时,对古地磁学与高精度磁测等方法集成在地磁场演化、板块构造、深部结构、月球磁场演化、火星磁场及环境演化等方面的综合应用进行了讨论.最后,对古地磁学未来的潜在研究方向进行了展望.      

Fougerite: From field experiment to the homologation of the mineral

Fougerite has been approved as a new mineral by the International Mineralogical Association in February 2004. Its characteristic blue-green colour is used as a universal criterion to identify the gley soils. By oxidation, it transforms into lepidocrocite. The discovery of fougerite in 1996 was the result of 10 years of a study of in situ seasonal dynamics of the system soil–solution, which led to the confirmation of the ancient assumption of the existence of a mixed hydroxide of the group of green rusts (GRs) in gleys. Synthetic GRs consist of a brucitic layer of Fe(II)–Fe(III), whose excess positive charge, due to Fe³⁺, is compensated in the interlayer by different anions, such as sulphate, chloride, oxalate, carbonate, etc. Physical, chemical, and mineralogical characterizations have been performed as a complement, and have confirmed the first results. In fougerite from Fougères, Mg is present in the layer in addition to Fe; the nature of the interlayer anion, which can vary depending on the environment, remains an open question. To cite this article: F. Trolard, C. R. Geoscience 338 (2006).     

An extension to the DRASTIC model to assess groundwater vulnerability to pollution: application to the Haouz aquifer of Marrakech (Morocco)

An extension to the DRASTIC model is proposed in order to assess aquifer vulnerability to pollution. In contrast to the DRASTIC model, which considers the unsaturated and saturated zones together and computes a global intrinsic vulnerability index, the suggested approach discriminates between the aquifer vertical vulnerability (a concept related to the pollutant percolation) and the groundwater susceptibility (a concept that depends on the behaviour and uses of the groundwater). This approach is applied to the Haouz aquifer (Morocco) that supplies water to the Marrakech area. This aquifer is widely overexploited and there is evidence that the groundwater quality is threatened by various sources of pollution. Evaluation of the vertical vulnerability indicates that the aquifer mainly presents a moderate-to-weak vertical vulnerability. The zones potentially most favourable to pollutant percolation are mainly located in Central Haouz, along or near the surface wadis. The aquifer susceptibility is high in places located near the N’Fis, Baaja and Issil wadis. Everywhere else, low-to-moderate susceptibility is observed. This new approach therefore enables areas of vertical vulnerability and areas of susceptibility to be delineated separately. As a result, it constitutes a valuable decision-making tool for optimising the management of aquifer water resources and land-use planning.     

A geoarchaeological approach to the evolution of the town and port of Dover: Prehistoric to Saxon periods

Dover is located at the mouth of a narrow valley that forms the only significant break in almost 20 km of chalk cliffs along the Kentish Channel coast. This, together with the close proximity of the Continent, has ensured the site's standing as a port since pre-Roman times. However, little is known of the sequence of events associated with the transformation of the area since the later prehistoric period, and in particular the evolution of the harbour which has had at least four different locations. Work to regenerate central Dover has however provided opportunities to address these issues and we report here on geological evidence for harbour development and coastal change from the middle Holocene period to the present day.Foraminifera and ostracods recovered from boreholes and excavations in the town centre allow patterns of sedimentation to be identified and linked to archaeological finds such as the Dover Bronze Age Boat and Roman harbour installations. Radiocarbon dating, and archaeological spot-dating provides a chronological framework for these changes. In particular the later Prehistoric environments and their transformation to estuarine environments by the time of Roman activity in the area are examined (including the role of sea level change and coastal erosion). The history of sedimentation within the Roman harbour and the role played by human activity in accelerating sedimentation in the old valley mouth is also considered. Finally dune formation across former estuarine habitats is documented in the Anglo-Saxon period creating the topographic template on which the modern town is based.     

A global approach to reactive transport: application to the MoMas benchmark

Water resource management involves numerical simulations in order to study contamination of groundwater by chemical species. Not only do the aqueous components move due to physical advection and dispersion processes, but they also react together and with fixed components. Therefore, the mass balance couples transport and chemistry, and reactive transport models are partial differential equations coupled with nonlinear algebraic equations. In this paper, we present a global method based on the method of lines and differential algebraic system (DAE) solvers. At each time step, nonlinear systems are solved by a Newton-LU method. We use this method to carry out numerical simulations for the reactive transport benchmark proposed by the MoMas research group. Although we study only 1D computations with a specific geochemical system, several difficulties arise. Numerical experiments show that our method can solve quite difficult problems, get accurate results and capture sharp fronts.     

Climate: Is the past the key to the future?

 The climate of the Holocene is not well suited to be the baseline for the climate of the planet. It is an interglacial, a state typical of only 10% of the past few million years. It is a time of relative sea-level stability after a rapid 130-m rise from the lowstand during the last glacial maximum. Physical geologic processes are operating at unusual rates and much of the geochemical system is not in a steady state. During most of the Phanerozoic there have been no continental ice sheets on the earth, and the planet’s meridional temperature gradient has been much less than it is presently. Major factors influencing climate are insolation, greenhouse gases, paleogeography, and vegetation; the first two are discussed in this paper. Changes in the earth’s orbital parameters affect the amount of radiation received from the sun at different latitudes over the course of the year. During the last climate cycle, the waxing and waning of the northern hemisphere continental ice sheets closely followed the changes in summer insolation at the latitude of the northern hemisphere polar circle. The overall intensity of insolation in the northern hemisphere is governed by the precession of the earth’s axis of rotation, and the precession and ellipticity of the earth’s orbit. At the polar circle a meridional minimum of summer insolation becomes alternately more and less pronounced as the obliquity of the earth’s axis of rotation changes. Feedback processes amplify the insolation signal. Greenhouse gases (H₂O, CO₂, CH₄, CFCs) modulate the insolation-driven climate. The atmospheric content of CO₂ during the last glacial maximum was approximately 30% less than during the present interglacial. A variety of possible causes for this change have been postulated. The present burning of fossil fuels, deforestation, and cement manufacture since the beginning of the industrial revolution have added CO₂ to the atmosphere when its content due to glacial-interglacial variation was already at a maximum. Anthropogenic activity has increased the CO₂ content of the atmosphere to 130% of its previous Holocene level, probably higher than at any time during the past few million years. During the Late Cretaceous the atmospheric CO₂ content was probably about four times that of the present, the level to which it may rise at the end of the next century. The results of a Campanian (80 Ma) climate simulation suggest that the positive feedback between CO₂ and another important greenhouse gas, H₂O, raised the earth’s temperature to a level where latent heat transport became much more significant than it is presently, and operated efficiently at all latitudes. Atmospheric high- and low-pressure systems were as much the result of variations in the vapor content of the air as of temperature differences. In our present state of knowledge, future climate change is unpredictable because by adding CO₂ to the atmosphere we are forcing the climate toward a “greenhouse” mode when it is accustomed to moving between the glacial–interglacial “icehouse” states that reflect the waxing and waning of ice sheets. At the same time we are replacing freely transpiring C3 plants with water-conserving C4 plants, producing a global vegetation complex that has no past analog. The past climates of the earth cannot be used as a direct guide to what may occur in the future. To understand what may happen in the future we must learn about the first principles of physics and chemistry related to the earth’s system. The fundamental mechanisms of the climate system are best explored in simulations of the earth’s ancient extreme climates. Received: 7 November 1996/Accepted: 23 January 1997     

Porphyroblast inclusion trails: the key to orogenesis

Detailed microstructural analysis of inclusion trails in hundreds of garnet porphyroblasts from rocks where spiral-shaped inclusion trails are common indicates that spiral-shaped trails did not form by rotation of the growing porphyroblasts relative to geographic coordinates. They formed instead by progressive growth by porphyroblasts over several sets of near-orthogonal foliations that successively overprint one another. The orientations of these near-orthogonal foliations are alternately near-vertical and near-horizontal in all porphyroblasts examined. This provides very strong evidence for lack of porphyroblast rotation.
The deformation path recorded by these porphyroblasts indicates that the process of orogenesis involves a multiply repeated two-stage cycle of: (1) crustal shortening and thickening, with the development of a near-vertical foliation with a steep stretching lineation; followed by (2) gravitational instability and collapse of this uplifted pile with the development of a near-horizontal foliation, gravitational spreading, near-coaxial vertical shortening and consequent thrusting on the orogen margins. Correlation of inclusion trail overprinting relationships and asymmetry in porphyroblasts with foliation overprinting relationships observed in the field allows determination of where the rocks studied lie and have moved within an orogen. This information, combined with information about chemical zoning in porphyroblasts, provides details about the structural/metamorphic ( P-T-t ) paths the rocks have followed.
The ductile deformation environment in which a porphyroblast can rotate relative to geographic coordinates during orogenesis is spatially restricted in continental crust to vertical, ductile tear/transcurrent faults across which there is no component of bulk shortening or transpression.     

Radiative transfer code: Application to the calculation of PAR

The production of carbon in the ocean, the so-called primary production, depends on various physicobiological parameters: the biomass and nutrient amounts in oceans, the salinity and temperature of the water and the light available in the water column. We focus on the visible spectrum of the solar radiation defined as the Photosynthetically Active Radiation (PAR). We developed a model (Chamiet al. 1997) to simulate the behavior of the solar beam in the atmosphere and the ocean. We first describe the theoretical basis of the code and the method we used to solve the radiative transfer equation (RTE): the successive orders of scattering (SO). The second part deals with a sensitivity study of the PAR just above and below the sea surface for various atmospheric conditions. In a cloudy sky, we computed a ratio between vector fluxes just above the sea surface and spherical fluxes just beneath the sea surface. When the optical thickness of the cloud increases this ratio remains constant and around 1.29. This parameter is convenient to convert vector flux at the sea surface as retrieved from satellite to PAR. Subsequently, we show how solar radiation as vector flux rather than P A R leads to an underestimate of the primary production up to 40% for extreme cases.     

构造地貌－认识高原历史的钥匙

简要评述了构造地貌的研究,并以青藏高原西北缘克里雅河流域地貌演化说明了构造变形与青藏高原的形成历史.以西域砾岩顶部的玄武岩作为区域构造地貌的标志,获得的高质量Ar-Ar年龄的加权平均值为1.09Ma±O.13Ma.该年龄不仅代表了西域砾岩沉积结束的时间,并制约了区域风沙堆积时代的下限,是一个重要的气候环境变化的转折点.更重要的是.该年龄标志了克里雅河演化的开始,即目前可观察的克里雅河的历史不过1.1Ma.另外获得的系统、丰富、翔实的沉积学、构造地质学、低温热年代数据和克里雅河流域地貌的测量结果还揭示了上新世晚期以来区域强烈的变形与构造地貌的演化.获得的重要结论还包括:能够分析恢复的前克里雅河的历史不超过西域砾岩沉积期,能够推测的青藏高原西北缘河流体系演化的最老历史不超过上新世阿图什组沉积期.在中新世乌恰组沉积时,基本观察不到青藏高原现今地貌体系产生的沉积作用的记录,而是更老的前青藏高原构造地貌格架对沉积体系产生的影响.青藏高原的主体可能在中更新世早期前后才抬升进入冰冻圈.现今的克里雅河地貌主要是在区域构造抬升中由冰川融水侵蚀形成的.克里雅河源头可能残留了青藏高原演化的关键记录.     

Voices and silences: the problem of access to embeddedness

The economic geography literature invokes a broad range of socio-cultural factors in explaining the performance of economic actors. The Polanyian–Granovetterian notion of embeddedness is among those often used in this context. This paper discusses epistemological problems involved in doing empirical research on the embeddedness of business firms in the local context. The obvious group of actors addressed in such studies are corporate managers. They can be depicted as agents who derive their power from the corporate resources that they control as well as from the social capital that they gain through their connectedness to a range of social relations.Interviews between academic researchers and corporate managers are viewed as Bakhtinian dialogues. They are analysed in terms of voice and silence, multivoicedness, social language and speech genre. Voices represent managerial elites in their different roles as well as the social relationships in which they are involved. They are resonated in managers’ utterances in interview dialogues. What is not expressed at all or is expressed unclearly or inadequately is captured by the metaphor of silence. Managers’ embeddedness in multiple sets of social relations results in multivoicedness, which leads to the need for the researcher to try to identify the different voices and their social origins.The paper elaborates on the complexities involved in carrying out empirical research on embeddedness. It can also be read as a warning against pursuing such an endeavour without careful conceptual elaboration on the very notion of embeddedness.     

Kinetics of the Coesite-Quartz Transition: Application to the Exhumation of Ultrahigh-Pressure Rocks

The kinetics of the quartz–coesite phase transition hasbeen studied in situ by X-ray diffraction in the 2·1–3·2GPa, 500–1010°C pressure–temperature range.Analysis of the data within Cahn's model of nucleation and growthat grain boundaries reveals that the prograde and retrogradereactions have different kinetics. The quartz