天然麻粒岩高温流变实验研究

本实验在气体介质三轴高温流变仪上,采用怀安瓦窑口麻粒岩,在温度900～1200℃、围压300 MPa、应变速率10~(-4)～10~(-6)/s条件下,开展高温流变实验.实验样品麻粒岩由斜长石(52%)、单斜辉石和斜方辉石(40%)、石英(3%)、磁铁矿和钛铁矿(5%)组成,矿物平均粒度为:斜长石294μm、单斜辉石和斜方辉石282μm、石英97μm、磁铁矿和钛铁矿109μm.利用傅里叶变换红外光谱仪分析获得变形后样品的水含量约为0.17±0.05wt%.实验样品的强度随温度升高而降低,随应变速率降低而降低.基于力学数据,采用稳态流变方程,获得实验样品在900～1000℃时的应力指数为8.1～12.9,在1050～1150℃时的应力指数为4.8～5.8,平均值5.2.应力指数随着温度升高而降低.显微结构和成分分析表明,在900℃时麻粒岩出现矿物压扁与定向拉长特征,样品以位错滑移和微破裂变形为主;在950～1000℃时,麻粒岩样品中颗粒边界变得圆滑,表现出位错攀移特征,辉石和磁铁矿边缘出现微量熔体;在1050～1200℃时麻粒岩出现部分熔融,而且随着温度和实验时间(应变)增加,熔体含量增加,熔体结晶出微粒斜长石、辉石和橄榄石,部分辉石通过固体反应生成橄榄石.颗粒边界熔体和矿物反应促进了扩散作用,导致位错攀移和熔体引起的扩散蠕变共同控制了麻粒岩的高温流变.     

Time domain spectral induced polarization of disseminated electronic conductors: Laboratory data analysis through the Debye decomposition approach

We measured Spectral Induced Polarization responses of 22 models of disseminated ore with a time domain (TD) technique. The models were mixtures of calibrated sand (0.2–0.3 mm) with calibrated ore grains (average radii: 0.045, 0.055, 0.13, 0.20, 0.38 and 0.55 mm). The grains represent a mixture of pyrrhotite (30%), pyrite (30%), magnetite (30%) and chalcopyrite (10%) coming from a natural ore. In the models, the grain concentration (by volume) varied between 0.6 and 30%.We obtained IP decays with a conventional field TD measuring technique and a lab low-current transmitter in the time range from 0.3 ms to 64 s. The IP decays measured with various current wavelength forms were inverted to relaxation time distributions (RTD) on the basis of the Debye decomposition approach.RTD parameters were found to be closely related to the ore volumetric content and the ore grain size. The total chargeability is independent of the grain size, but is determined by the grain volume fraction. In contrast, the mean IP relaxation time is related to the grain size. These facts make RTD attractive to use in ore prospecting and studying reactive permeable barriers.Moreover, for low salinity pore water used in this study, the relaxation times of disseminated ores are three to four decades smaller than that of the insulating grains of the same size typical of common soils and sediments. This allows recover the relaxation times on the basis of relatively fast IP measurements with short time pulses (in TD) or high frequency values in the frequency domain; however attention should be paid to inductive and capacitive couplings.     

Flocculation settling characteristics of mud: sand mixtures

When natural muds become mixed with sandy sediments in estuaries, it has a direct effect on the flocculation process and resultant sediment transport regime. Much research has been completed on the erosion and consolidation of mud/sand mixtures, but very little is known quantitatively about how mixed sediments interact whilst in suspension, particularly in terms of flocculation. This paper presents the settling velocity findings from a recent laboratory study which examined the flocculation dynamics for three different mud/sand mixtures at different concentrations (0.2–5 g.l^?1) and turbulent shear stresses (0.06–0.9 Pa) in a mini-annular flume. The low intrusive video-based Laboratory Spectral Flocculation Characteristics instrument was used to determine floc/aggregate properties (e.g., size, settling velocity, density and mass) for each population. Settling data was assessed in terms of macrofloc (>160 μm) and microfloc (<160 μm) settling parameters: Ws_macro and Ws_micro, respectively. For pure muds, the macroflocs are regarded as the most dominant contributors to the total depositional flux. The parameterised settling data indicates that by adding more sand to a mud/sand mixture, the fall velocity of the macrofloc fraction slows and the settling velocity of microflocs quickens. Generally, a mainly sandy suspension comprising 25% mud and 75% sand (25M:75S), will produce resultant Ws_macro which are slower than Ws_micro. The quickest Ws_micro appears to consistently occur at a higher level of turbulent shear stress (τ?～?0.6 Pa) than both the macrofloc and microfloc fractions from suspensions of pure natural muds. Flocculation within a more cohesively dominant muddy-sand suspension (i.e., 75M:25S) produced macroflocs which fell at similar speeds (±10%) to pure mud suspensions at both low (200 mg l^?1) and intermediate (1 g?l^?1) concentrations at all shear stress increments. Also, low sand content suspensions produced Ws_macro values that were faster than the Ws_micro rates. In summary, the experimental results of the macrofloc and microfloc settling velocities have demonstrated that flocculation is an extremely important factor with regards to the depositional behaviour of mud/sand mixtures, and these factors must be considered when modelling mixed sediment transport in the estuarine or marine environment.     

Assessment of magnetite as a magnetic tracer for sediments in the study of ephemeral gully erosion: Conditioning factors of magnetic susceptibility

In gully erosion, the detached soil can be transported over long distances along the landscape. The eroded material can be redistributed and/or deposited on the soil surface along the landscape and then eventually be buried by newly eroded and deposited sediment. There can be significant variability of the soil conditions (e.g., texture and moisture content) over which the eroded material travels. The eroded material can be detected through the use of magnetic tracers attached to or mixed with the eroded soil. In this study we evaluated the degree to which the magnetic signal of the magnetite is conditioned by (i) burial depth of tracer, (ii) condition of soil covering the tracer and (iii) tracer concentration. In the laboratory containers were filled with a specific soil. In the filling process, a 0.5-cm layer of a soil–magnetite mixture was interspersed in the soil profile at a certain depth. Experiments encompassed three different soil–tracer concentrations (1000:1, 200:1, 100:1), four burial depths of tracer (0 cm, 3 cm, 5 cm and 10 cm from soil surface), and two different soils. In each case, the magnetic susceptibility was measured with a susceptometer. Experiments were repeated with different soil moisture contents. If the tracer is located under the soil surface, a minimum soil–tracer concentration of 200:1 is required for its correct detection. The intensity of the magnetic signal decreases dramatically with the vertical distance of the tracer from the soil surface. The maximum detection depth for the tracer's magnetic signal is strongly dependent on the natural magnetic susceptibility of the soil, which masks the tracer's signal. Variation in soil moisture content does not significantly affect the magnetic signal. For extensive field studies, the soil–tracer volume to be handled would be very high and therefore, it is necessary to explore new tracer application techniques.     

Effect of salt types on salt precipitation and water transport in saline sandy soil

Salt precipitation on the surface of porous media significantly affects water transport processes. Most studies on salt precipitation mainly focused on single salts, but in nature, salt precipitation usually occurs as mixtures. Consequently, information on the crystallization of salt mixtures and its effect on water transport remains scarce. This study investigated the precipitation of mixtures (the mass ratios of NaCl:Na₂SO₄ were 3:7, 5:5, and 7:3, respectively) of NaCl (typical efflorescence) and Na₂SO₄ (typical subflorescence) in the initially saturated sandy soil columns and its effect on evaporation and compared it with the cases of the two salts individually. The results showed that salt mixtures exhibited a mixed pattern of crystals including both efflorescence and subflorescence, and the efflorescence showed granular aggregation, unlike the mono-salts. The crystallization coverage of the salt mixtures was smaller than that of NaCl mono-salt; high (7:3) and low (5:5 and 3:7) proportions of NaCl led to larger and smaller crystallization coverage than that of Na₂SO₄ mono-salt, respectively. While the salt mixtures had less crystallization coverage than the mono-salts, they showed lower evaporation because the salt mixtures formed a denser crystallization structure of efflorescence-subflorescence-soil layer, this crystallization structure exhibited greater inhibition of water vapour diffusion, thus reducing evaporation. In addition, the crystallization of the salt mixtures with higher NaCl proportion afforded greater resistance of evaporation. The mixed crystallization pattern formed by the salt mixtures significantly enhances the crystallization resistance to evaporation.     

The identification of magnetite in limestones using the low-temperature transition

The low-temperature (K₁) transition has been measured in prepared samples with a low concentration of magnetite to test the validity of the technique for identifying magnetite in weakly magnetized rocks. Using an astatic magnetometer, magnetite concentrations as low as 1 part in 100,000 can be satisfactorily detected.Measurements on natural samples show the presence of magnetite in a variety of limestones which are known to have a stable natural remanent magnetization.     

Improved Interpretation of Nuclear Magnetic Resonance T1 and T2 Distributions for Permeability Prediction: Simulation of Diffusion Coupling for a Fractal Cluster of Pores

NMR relaxometry is a powerful tool for inferring porosity and permeability data. In practice, measured magnetization decay curves are inverted for relaxation time distributions. Subsequently, one presumes a linear relationship between the pore radius distribution and the T ₁ and T ₂ distribution, for longitudinal and transverse magnetization, respectively. The fundamental equations used are based on a pore model, in which pores are assumed to be isolated from each other with respect to the NMR process and have smooth walls. The present study is based on a geometrical pore space model with connected pores and structured pore walls. The physical processes of surface relaxation, irreversible dephasing of magnetic spins and diffusive proton exchange between pores, are described by a system of differential equations. The solution yields a set of exponential functions representing the relaxation time distribution. We describe the difference between the distributions obtained for diffusion coupling and for isolated pores. With diffusion coupling on, the spectral width of the T ₁ distribution is strongly reduced, which indicates that the influence of large and small radii according to the T ₁-pore radius relationship is mixed to some extent. For a fractal pore space structure, where large pores are surrounded by adjacent minor pores, the T ₁ distribution does not resolve these substructures. Nevertheless, permeability values calculated from the logarithmic mean relaxation time T _1,LM are quite the same for diffusion coupling and for isolated pores. The T ₂ distribution for diffusion coupling is little constricted and gives a better resolution of the pore wall structures than the corresponding T ₁ distribution. The permeability values from T ₂ distributions agree with the values from longitudinal magnetization, provided that we use a corrected relaxation time T _2,corr, accounting for the dependence of the surface relaxivity ρ ₂ on pore radius. The study shows that radius distributions calculated from a T ₁ and from a T ₂ distribution differ from one another and both present an altered image of the true pore radius distribution. In practice, this has no serious influence on estimating permeability of medium- to high-permeability sandstones with the currently applied methods. The presented methodology of calculating the NMR response of pore space models with diffusion coupling may facilitate understanding porosity-permeability relationships of different rock types such as carbonate rocks with micro-porosity.     

Thermomagnetic analysis of meteorites, 1. C1 chondrites

Samples of all five of the known C1 chondrites have been analyzed thermomagnetically. The only magnetic phase found in four of the chondrites (Alais, Ivuna, Orgueil, Tonk) was magnetite containing less than 6% nickel. The Revelstoke C1 chondrite contains essentially Ni-free Fe₃O₄ as the predominant phase; however, a small amount of a thermally unstable iron compound (presumably FeS) is additionally present. Estimates of the weight percentage of magnetite, based on saturation moments, are: Alais, 5.3 ± 0.4%; Ivuna, 12.2 ± 0.9%; Orgueil, 11.9 ± 0.8%; Revelstoke, 7.2 ± 0.5%; and Tonk, 9.4 ± 0.6%. The first three estimates are based on multiple analyses and are considered to be grossly representative of the meteorites as a whole. The last two estimates are based on single-sample measurements and should be considered only in that context. The magnetite of the Alais sample appears to be somewhat unusual inasmuch as it is inhomogeneously distributed, and its content is only about half that of the average C1 chondrite.     

基于SVD和BRD的二维核磁共振测井正则化反演算法研究

二维核磁共振能从"弛豫-扩散"两个维度上展现流体性质,在识别稠油储层方面具有理论优势,是当前核磁共振测井技术的研究热点.本文深入研究二维核磁共振测井原理,系统分析CPMG-DE脉冲序列测量扩散系数与弛豫时间的方法,结合核磁共振二维谱数理模型,提出一种基于SVD和BRD的正则化反演算法.该算法通过SVD压缩数据,采用带非负约束的Tikhonov正则化方法求解流体"弛豫-扩散"分布,并基于BRD算法迭代确定最佳正则化因子.模拟实验与数值分析表明,该算法无需先验信息、运算效率高、相对误差小,在原始数据信噪比低至50时,仍可有效获取流体(T₂,D)二维分布.在二维核磁共振测井数据实时解释应用中,该方法较传统反演算法(如TSVD)具有较大优势.同时,在自主研发的核磁共振测井仪测量CuSO₄溶液(T₂,D)分布的实验显示,本文设计算法对弛豫时间和扩散系数的反演误差分别仅为2%和4%,较TSVD算法有较大改善.     

Erosion rate of sand and mud mixtures

Erosion of mixed cohesive and noncohesive sediments is studied using the erosion test instrument SEDFlume. The sediment mixtures are composed of well-sorted quartz sand (0.25–0.5 mm) and one of the three used muds: kaolinite, kaolinite-bentonite and Mississippi River muds. The mud contents cover from 0 to 100%. The measured data of erosion rate and bed shear stress are used to examine the segmented linear, nonlinear, and exponential erosion models. The parameters of each erosion model are related to the physical properties of sediment mixtures, including clay fraction, mud fraction, mixture dry density, and mud dry density. It is found that the three models can fit well with the data, and their parameters have strong relations with the mud fraction and mud dry density, to a less extent with the clay fraction, but not with the mixture dry density.     

北京密云水库表层沉积物磁性矿物的鉴别

本文对密云水库表层沉积物中的磁性矿物进行了岩石磁学和透射电子显微学的综合研究.本实验建立的磁选方法实现将70%~85%左右的磁性矿物从沉积物中分离出来.岩石磁学研究表明,密云水库沉积物中的磁性矿物以多畴和单畴磁铁矿为主,还含有少量高矫顽力弱磁性载磁矿物(可能为赤铁矿).对磁选矿物的透射电镜观测表明,样品中部分单畴磁铁矿具有纳米尺寸和化学纯度高等特点,为拉长的立方-八面体磁铁矿,是趋磁细菌产生的化石磁小体;多畴磁铁矿多数具有微米尺寸,形状不规则,为碎屑成因;超顺磁磁铁矿粒径约为5~20nm,且含硅、铝等元素,可能为自生成因.研究结果表明,岩石磁学和透射电子显微学的综合应用可以更全面、准确地分析沉积物中磁性矿物的成分、含量、粒径和化学成分等信息,为环境磁学、生物地磁学和古地磁学研究提供依据.     

Hydraulic Conductivity Calibration of Logging NMR in a Granite Aquifer,Laramie Range,Wyoming

In granite aquifers, fractures can provide both storage volume and conduits for groundwater. Characterization of fracture hydraulic conductivity (K) in such aquifers is important for predicting flow rate and calibrating models. Nuclear magnetic resonance (NMR) well logging is a method to quickly obtain near-borehole hydraulic conductivity (i.e., K_NMR) at high-vertical resolution. On the other hand, FLUTe flexible liner technology can produce a K profile at comparable resolution but requires a fluid driving force between borehole and formation. For three boreholes completed in a fractured granite, we jointly interpreted logging NMR data and FLUTe K estimates to calibrate an empirical equation for translating borehole NMR data to K estimates. For over 90% of the depth intervals investigated from these boreholes, the estimated K_NMR are within one order of magnitude of K_FLUTe. The empirical parameters obtained from calibrating the NMR data suggest that “intermediate diffusion” and/or “slow diffusion” during the NMR relaxation time may occur in the flowing fractures when hydraulic aperture are sufficiently large. For each borehole, “intermediate diffusion” dominates the relaxation time, therefore assuming “fast diffusion” in the interpretation of NMR data from fractured rock may lead to inaccurate K_NMR estimates. We also compare calibrations using inexpensive slug tests that suggest reliable K_NMR estimates for fractured rock may be achieved using limited calibration against borehole hydraulic measurements.     

砂岩核磁共振响应模拟及受限扩散

本文运用随机游走方法模拟了砂岩储层中流体的核磁共振(NMR)响应及其受限扩散现象.通过改变数字岩心的分辨率模拟生成不同孔隙尺寸的砂岩,研究了不同孔隙尺寸砂岩饱含水时流体扩散系数随扩散时间的变化关系,同时模拟了砂岩饱和单相流体和两相流体的NMR响应;研究了流体的受限扩散系数与横向弛豫时间T2的关系,分析了表面弛豫率和胶结指数对润湿相流体受限扩散系数线位置的影响,并将其用于解释砂岩储层的D-T2分布.结果表明:孔隙流体的扩散系数会随扩散时间的增加而逐渐减小并趋于定值.随着岩石孔隙尺寸的减小,受限扩散现象越明显,受限扩散对岩石NMR响应的影响也越大.润湿相流体受限扩散系数线的位置受岩石胶结指数和表面弛豫率的影响较大.由于润湿相流体扩散系数减小,导致D-T2分布中润湿相流体信号偏离其自由扩散系数线,需要利用流体的受限扩散系数线准确识别D-T2分布中的润湿相流体.     

Distribution of clay minerals in marine sediments off Chennai,Bay of Bengal,India： Indicators of sediment sources and transport processes

Clay mineralogy, texture size and statistical analyses were carried out on surface sediments from the continental shelf of Chennai, Bay of Bengal, India. The purpose of this study is to characterize the clay mineral distribution and its relation to the hydrodynamics off Chennai to identify the sources and transport pathways of the marine sediments. Characterization of clay minerals in coastal sediments by Fourier Transform Infrared （FTIR） spectroscopy has provided the association of quartz, feldspar, kaolinite, chlorite, illite and iron oxides （magnetite and hematite） derived from river catchments and coastal erosion. Kaolinite, chlorite, illite, iron oxides, and organic matter are the dominant minerals in Cooum, and Adayar region. High quartz and feldspar zones were identified in Marina, which are being confined the sand zone and paralleling the coast. The strong relationships among the wave energy density, sand, quartz and carbonate revealed that wave induced littoral drift system play a dominant role in transportation and deposition of sediments in the Chennai coast. The sediment texture and minerals data are in agreement well with the previous results of hydrodynamics and littoral drift models in this region. Multivariate statistical analyses （correlation, cluster and factor analyses） were carried out and obtained results suggested that clay minerals and organic matter are trapped in silt and clay particles, whereas quartz, feldspar and carbonate are associated with sand particles. Results of sediment sources and transport processes from this study will be useful to predict the fate of the pollutants released from land or the potential change in sediment delivery to coastal areas.     

Dissolution rates of calcium carbonate in the deep ocean; an in-situ experiment in the North Atlantic Ocean

An in-situ water circulator (ISWAC) was developed to allow accurate measurement of dissolution rates of various carbonate particles with minimal stagnation and mechanical weight loss. Three ISWAC packages were deployed at 3600, 4800 and 5518 m for 79 days in the Sargasso Sea (Northwest Atlantic). Weight losses for different particles during 79 days at 5518 m were as follows: pteropods and synthetic aragonite, 72.8%; reagent calcite, 57.5%; foraminifera, 23–36%; coccoliths, 11.3–24%, and diatoms, 12%. These weight losses are 2.5–7.5 times higher than those reported in earlier in-situ experiments. Normalization of weight losses with respect to BET specific surface area for different calcite particles yielded specific dissolution rates that differed by more than 2 orders of magnitude. Bleached biogenic particles dissolve significantly faster than non-bleached although their surface area is identical. We suggest that the BET surface area does not represent the reactive surface area available for dissolution, especially in biogenic calcite particles. Coatings, probably of organic matter, may reduce the reactive surface area and thus retard dissolution rates.The existence of a chemical lysocline in the Northwest Atlantic was confirmed. However, it seems that different kinds of particles have different lysoclines. The origin of the lysocline cannot be attributed to water flow or to the thermodynamic transition from supersaturation to undersaturation (Ω = 1). It seems to be a kinetic phenomenon.A simple model comparing the complete dissolution time and the residence time of a particle on the sediment-water interface suggests that coccoliths can be preserved in the sediments of the deep Northwest Atlantic below the CCD, in good agreement with SEM observations.     

Minerals produced during cooling and hydrothermal alteration of ash flow tuff from Yellowstone drill hole Y-5

A rhyolitic ash-flow tuff in a hydrothermally active area within the Yellowstone caldera was drilled in 1967, and cores were studied to determine the nature and distribution of primary and secondary mineral phases. The rocks have undergone a complex history of crystallization and hydrothermal alteration since their emplacement 600,000 years ago. During cooling from magmatic temperatures, the glassy groundmass underwent either devitrification to alkali feldspar + α-cristobalite ± tridymite or granophyric crystallization to alkali feldspar + quartz. Associated with the zones of granophyric crystallization are prismatic quartz crystals in cavities similar to those termed miarolitic in plutonic rocks. Vapor-phase alkali feldspar, tridymite, magnetite, and sporadic α-cristobalite were deposited in cavities and in void spaces of pumice fragments. Subsequently, some of the vapor-phase alkali feldspar crystals were replaced by microcrystalline quartz, and the vapor-phase minerals were frosted by a coating of saccharoidal quartz.Hydrothermal minerals occur primarily as linings and fillings of cavities and fractures and as altered mafic phenocrysts. Chalcedony is the dominant mineral related to the present hydrothermal regime and occurs as microcrystalline material mixed with various amounts of hematite and goethite. The chalcedony displays intricate layering and was apparently deposited as opal from silica-rich water. Hematite and goethite also replace both mafic phenocrysts and vapor-phase magnetite. Other conspicuous hydrothermal minerals include montmorillonite, pyrite, mordenite, calcite, and fluorite. Clinoptilolite, erionite, illite, kaolinite, and manganese oxides are sporadic. The hydrothermal minerals show little correlation with temperature, but bladed calcite is restricted to a zone of boiling in the tuff and clearly was deposited when CO₂ was lost during boiling.Fractures and breccias filled with chalcedony are common throughout Y-5 and may have been produced by rapid disruption of rock caused by sudden decrease of fluid pressure in fractures, most likely a result of fracturing during resurgent doming in this part of the Yellowstone caldera. The chalcedony probably was deposited as opal or β-cristobalite from a pre-existing silica floc that moved rapidly into the fractures and breccias immediately after the sudden pressure drop.     

Strain localisation in bimineralic rocks: Experimental deformation of synthetic calcite–anhydrite aggregates

Deformation of synthetic calcite–anhydrite aggregates to large shear strains (up to γ = 12.4 at 600 °C, 300 MPa confining pressure and a constant angular displacement rate corresponding to a shear strain rate of 10^− 3 s^− 1) resulted in the first experimental observation of strain localisation from initially homogeneous rocks. In contrast to experiments on pure calcite and anhydrite, which deformed homogeneously to large strains (γ ≥ 5), all experiments on calcite–anhydrite mixtures resulted in heterogeneous deformation at γ > 1 and the formation of narrow localised bands in the microstructures at γ > 4. In these bands, the amount of strain is at least twice as large as in the rest of the sample and individual grains of the same phase cluster and align, thereby forming microstructural layering similar to planar fabrics in natural mylonites. A switch in deformation mechanism in anhydrite from dislocation creep to diffusion creep and/or grain boundary sliding occurs simultaneously with strain localisation. It is concluded that deformation-induced heterogeneous phase distributions cause local strength differences initiating strain localisation in the calcite–anhydrite mixtures. The study suggests that the presence of two phases in combination with a change in deformation mechanism may be responsible for strain localisation in natural poly-mineralic mylonites.     

Visualizations and Optimization of Iron–Sand Mixtures for Permeable Reactive Barriers

Diluting granular iron with sand is a common practice performed to minimize clogging and to reduce the cost of permeable reactive barrier (PRB) installations. This study used a pore‐scale image analysis technique and a reanalysis of previously published data to test the hypothesis of Bi et al. (2009) that the mixing of 15% by weight sand with a commercial, platy‐grained iron medium opens the pore space between grains, exposes more reactive grain surface to flowing water, and leads to a more reactive medium (i.e., promoting faster transformation rates per unit volume of medium) than 100% by weight granular iron. Four mixing ratios (100, 85, 75 and 50% iron by weight) were compared on the basis of two morphological parameters measured in section: (1) total grain area, which correlates with the total amount of iron present, and (2) grain perimeter, which is governed by both the mobile solution‐available surface and the total amount of iron present. As expected, grain areas exposed in section were highest for 100% iron packings and decreased with increasing sand content. The estimated iron grain effective perimeters (i.e., accessible to mobile water) for 85% iron‐by weight mixtures were similar to 100% iron and decreased in 75 and 50% iron mixtures. The section confirmed that the presence of 15% sand by weight opened up the pore structure, likely improving the mobile‐water to iron contact. The analysis of kinetic column experimental data indicated that the same trend was present in the sorption capacity term in the Kinetic Iron Model (KIM) equation, providing corroborating evidence that the iron surface availability was higher in the 85% iron medium than the 100% iron medium on a per gram of iron basis.     

太湖梅梁湾水体及沉积物中微囊藻毒素含量垂向分布特征

为探究太湖梅梁湾水体及沉积物中微囊藻毒素（MC-LR、MC-RR、MC-YR）含量的垂向分布特征,于2018年5月采集梅梁湾6个点位表层水、上覆水、混合水、间隙水以及柱状沉积物样品,并采用超高效液相色谱-串联质谱法分析样品中微囊藻毒素的含量.分析结果表明：水体中（表层水、上覆水、混合水以及间隙水）MC-LR、MC-RR、MC-YR的浓度范围分别为11.80~1297.14、2.50~818.40、1.80~176.00 ng/L,表层水、上覆水以及混合水中MC-LR的浓度高于MC-RR和MC-YR,MC-RR和MC-YR之间差别较小,而间隙水中MCs三种异构体浓度大小顺序为：MC-LR > MC-RR > MC-YR;垂向分布上,间隙水中MCs异构体（MC-LR、MC-RR、MC-YR）浓度均远高于表层水、上覆水以及混合水,表层水MCs异构体浓度略高于上覆水,混合水MCs异构体浓度介于表层水和上覆水之间.对沉积物的研究发现,1~10 cm表层沉积物中MC-LR、MC-RR、MC-YR含量范围分别为0.60~26.95、0~0.90、0~8.10 ng/g,且1~10 cm层中MCs三种异构体平均含量大小顺序为：MC-LR > MC-YR > MC-RR,其中MC-LR、MC-RR、MC-YR的检出率分别为100%、70%、92%;垂向分布上,MC-RR含量较低且变化不大,而MC-YR和MC-LR含量均随沉积物深度的增加先升高后降低.相关性分析结果表明,表层水和混合水中MCs与总磷浓度呈显著正相关,而与总氮浓度无显著相关性;上覆水、间隙水以及沉积物中MCs与总氮、总磷浓度均呈显著正相关.