有效全岩成分的计算方法及其在变质相平衡模拟中的应用

变质相平衡模拟是变质岩领域近几十年最重要的进展之一，它已经成为确定变质作用P-T-t轨迹和探索变质演化过程的有力工具。变质岩的矿物组合不但与其形成的温度（T）和压力（P）条件有关，而且受控于岩石的全岩成分（X）。但是变质岩通常是不均匀的并且往往保留两期以上的矿物组合，因此计算不同成分域或不同变质演化期次的有效全岩成分是模拟P-T视剖面图的核心问题之一。在中-低温变质岩中，石榴石变斑晶的生长会不断地将其核部成分"冻结"而不参与后续变质反应，这导致根据实测全岩成分计算的P-T视剖面图无法有效地模拟石榴石幔部或边部生长阶段的变质演化过程。"瑞利分馏法"和"球体积法"利用电子探针实测的石榴石成分环带可以模拟计算石榴石各个生长阶段所对应的有效全岩成分，本文推荐使用这两个方法来处理石榴石变斑晶的分馏效应问题。相比较而言，石榴石在高温变质岩中通常无法保留生长阶段的成分环带特征，这是因为石榴石成分在高温条件下会发生扩散再平衡，并同时与多数基质矿物达到热力学平衡，这时一般不需要考虑石榴石的分馏效应。但是高温变质岩通常会发生部分熔融并伴随熔体的迁移，进而改变岩石的有效全岩成分。因此，通过P-T视剖面图模拟熔体迁移前后的变质演化过程需要使用"相平衡法"计算迁移的熔体成分以及熔体迁移前后岩石的有效全岩成分。此外，后成合晶与反应边是变质岩中最常见的退变质反应结构，但是后成合晶或反应边中的矿物之间并未达到热力学平衡。这种情况需要结合岩相学观察和矿物成分，利用最小二乘法确定后成合晶或反应边中发生的平衡反应方程式，进而获取变质反应发生时的有效全岩成分并通过计算P-T视剖面图来估算退变质的温压条件。除此之外，岩石体系中三价铁（Fe₂O₃）和H₂O含量的估算一直以来都是相平衡模拟研究中的难点，本文推荐使用P/T-X（Fe³⁺/Fe^tot，MH₂O）视剖面图来确定这两个组分的含量，这是因为P/T-X图可以估算各个变质演化阶段或特定矿物组合的Fe₂O₃或H₂O含量。     

Quantitative determination of metamorphic reaction history: mass balance relations between groundmass and mineral inclusion assemblages in metamorphic rocks

Qualitative and quantitative information about metamorphic reaction history and PT paths may be obtained from mineral inclusions in garnet by comparing the mineralogy, distribution, and compositions of paragenetically-related inclusions with minerals in the groundmass assemblage. Using the algebraic technique of singular value decomposition (SVD), we document mass balance relations between inclusion and groundmass assemblages in metapelitic rocks from two metamorphic terranes that experienced different peak metamorphic conditions, and whose transition from inclusion to groundmass assemblage records different PT path segments relative to peak conditions. We calculate mass balances relating an inclusion assemblage consisting in part of armored relics of chloritoid to groundmass mineral assemblages in a kyanite-staurolite mica schist from the Solitude Range, British Columbia, and an inclusion assemblage of kyanite, staurolite, and rutile to groundmass minerals in a sillimanite-cordierite gneiss from the Skagit Gneiss, North Cascade Range, Washington. Mass balances for each rock are consistent with reaction histories inferred from petrographic observations. In the Solitude Range schist, the results of mass balance calculations are consistent with the growth of staurolite and garnet at the expense of chloritoid during prograde metamorphism and suggest that chlorite, although not preserved as an inclusion, was involved in initial staurolite growth. In the Skagit sillimanite gneiss, mass balance relations exist between the inclusion suite, which formed during high pressure metamorphism, and the associated groundmass assemblage, which equilibrated at high temperature but much lower pressure. Mass balance does not exist between the groundmass of the Skagit sillimanite gneiss and the groundmass of a nearby kyanite-staurolite schist that has been proposed as a possible lower-grade equivalent of the sillimanite-bearing rocks. These results indicate that, although compositional modification and selective preservation of minerals must be taken into account, mineral inclusion suites may nevertheless preserve enough compositional information to allow reconstruction of complete or nearly complete pre-existing assemblages. This information may not be retrievable from any other source if no lower-grade equivalents of the rocks of interest are exposed.     

A general model for the intrusion and evolution of 'mantle' garnet peridotites in high-pressure and ultra-high-pressure metamorphic terranes

Garnet‐bearing peridotite lenses are minor but significant components of most metamorphic terranes characterized by high‐temperature eclogite facies assemblages. Most peridotite intrudes when slabs of continental crust are subducted deeply (60–120 km) into the mantle, usually by following oceanic lithosphere down an established subduction zone. Peridotite is transferred from the resulting mantle wedge into the crustal footwall through brittle and/or ductile mechanisms. These ‘mantle’ peridotites vary petrographically, chemically, isotopically, chronologically and thermobarometrically from orogen to orogen, within orogens and even within individual terranes. The variations reflect: (1) derivation from different mantle sources (oceanic or continental lithosphere, asthenosphere); (2) perturbations while the mantle wedges were above subducting oceanic lithosphere; and (3) changes within the host crustal slabs during intrusion, subduction and exhumation. Peridotite caught within mantle wedges above oceanic subduction zones will tend to recrystallize and be contaminated by fluids derived from the subducting oceanic crust. These ‘subduction zone peridotites’ intrude during the subsequent subduction of continental crust. Low‐pressure protoliths introduced at shallow (serpentinite, plagioclase peridotite) and intermediate (spinel peridotite) mantle depths (20–50 km) may be carried to deeper levels within the host slab and undergo high‐pressure metamorphism along with the enclosing rocks. If subducted deeply enough, the peridotites will develop garnet‐bearing assemblages that are isofacial with, and give the same recrystallization ages as, the eclogite facies country rocks. Peridotites introduced at deeper levels (50–120 km) may already contain garnet when they intrude and will not necessarily be isofacial or isochronous with the enclosing crustal rocks. Some garnet peridotites recrystallize from spinel peridotite precursors at very high temperatures (c. 1200 °C) and may derive ultimately from the asthenosphere. Other peridotites are from old (>1 Ga), cold (c. 850 °C), subcontinental mantle (‘relict peridotites’) and seem to require the development of major intra‐cratonic faults to effect their intrusion.     

Two-dimensional numerical modeling of tectonic and metamorphic histories at active continental margins

The evolution of an active continental margin is simulated in two dimensions, using a finite difference thermomechanical code with half-staggered grid and marker-in-cell technique. The effect of mechanical properties, changing as a function of P and T, assigned to different crustal layers and mantle materials in the simple starting structure is discussed for a set of numerical models. For each model, representative P–T paths are displayed for selected markers. Both the intensity of subduction erosion and the size of the frontal accretionary wedge are strongly dependent on the rheology chosen for the overriding continental crust. Tectonically eroded upper and lower continental crust is carried down to form a broad orogenic wedge, intermingling with detached oceanic crust and sediments from the subducted plate and hydrated mantle material from the overriding plate. A small portion of the continental crust and trench sediments is carried further down into a narrow subduction channel, intermingling with oceanic crust and hydrated mantle material, and to some extent extruded to the rear of the orogenic wedge underplating the overriding continental crust. The exhumation rates for (ultra)high pressure rocks can exceed subduction and burial rates by a factor of 1.5–3, when forced return flow in the hanging wall portion of the self-organizing subduction channel is focused. The simulations suggest that a minimum rate of subduction is required for the formation of a subduction channel, because buoyancy forces may outweigh drag forces for slow subduction. For a weak upper continental crust, simulated by a high pore pressure coefficient in the brittle regime, the orogenic wedge and megascale melange reach a mid- to upper-crustal position within 10–20 Myr (after 400–600 km of subduction). For a strong upper crust, a continental lid persists over the entire time span covered by the simulation. The structural pattern is similar in all cases, with four zones from trench toward arc: (a) an accretionary complex of low-grade metamorphic sedimentary material; (b) a wedge of mainly continental crust, with medium-grade HP metamorphic overprint, wound up and stretched in a marble cake fashion to appear as nappes with alternating upper and lower crustal provenance, and minor oceanic or hydrated mantle interleaved material; (c) a megascale melange composed of high-pressure and ultrahigh-pressure metamorphic oceanic and continental crust, and hydrated mantle, all extruded from the subduction channel; (d) zone represents the upward tilted frontal part of the remaining upper plate lid in the case of a weak upper crust. The shape of the P–T paths and the time scales correspond to those typically recorded in orogenic belts. Comparison of the numerical results with the European Alps reveals some similarities in their gross structural and metamorphic pattern exposed after collision. A similar structure may be developed at depth beneath the forearc of the Andes, where the importance of subduction erosion is well documented, and where a strong upper crust forms a stable lid.     

Petrogenesis of UHP metamorphic rocks from Qinglongshan, southern Sulu, east-central China

Five kinds of UHP metamorphic rocks, including eclogite, orthogneiss, paragneiss, schist and quartzite are exposed in the Qinglongshan roadcut, southern Sulu orogenic belt of eastern central China. They comprise metamorphic supracrustal rocks with bimodal volcanic characteristics and continental affinity, and granitic intrusive associations. The preservation of coesite inclusions and/or its pseudomorphs in eclogite and other rocks indicate that they have been subjected to in-situ UHP metamorphism. Four stages of metamorphism were recognized by combining petrographic observations and compositions of minerals from various UHP rocks. Prograde epidote-amphibolite facies, UHP coesite–eclogite facies, post UHP quartz–eclogite facies, and retrograde amphibolite facies assemblages delineate an inferred P–T path with a clockwise trajectory and a retrograde event characterized by the coupling of decompression with a temperature decrease. Garnet porphyroblasts in UHP eclogites display a complex growth zoning and mineral distribution, and record a crucial segment of the prograde and retrograde metamorphic evolution. The preservation of growth zoning in eclogitic and gneissic garnets suggests that the UHP rocks had a short residence time before retrograde metamorphism and a very high uplift rate in order to preserve the prograde growth zoning.     

青藏高原羌塘中部高压变质带的研究进展及存在问题

羌塘中部高压变质带是目前青藏高原内部延伸规模最大的高压变质带,是理解特提斯演化的关键地质记录。高压变质带主要沿龙木措-双湖-澜沧江缝合带一线出露,主要由榴辉岩、蓝片岩、石榴子石多硅白云母片岩及少量高压麻粒岩组成。其中,榴辉岩主要出露于戈木、果干加年山、冈玛错、巴青及滇西的勐库地区,主要呈透镜状产于石榴子石多硅白云母片岩中。除巴青地区的榴辉岩外,其余地区榴辉岩的峰期变质温度较低且含有硬柱石及其假象,峰期变质条件位于硬柱石榴辉岩相稳定区域,是洋壳冷俯冲的产物。虽然对于戈木地区榴辉岩锆石成因仍有争议,但已有资料显示,羌塘中部高压变质带主体变质时代集中在晚三叠世,其相关高压变质岩石的折返可能与洋盆的闭合及随后的陆-陆碰撞相关。近期研究表明,羌塘中部可能存在二叠纪低温高压变质岩,折返于大洋俯冲阶段,可能与洋岛或海山的俯冲及引发的俯冲侵蚀作用相关。此外,羌塘香桃湖地区出露早古生代的基性高压麻粒岩,是冈瓦纳大陆北缘陆块拼贴的记录。因此,对羌塘中部高压变质带进行进一步系统的研究工作,对于深入理解冈瓦纳北缘构造演化及古特提斯的俯冲与闭合过程具有重要的意义。     

Paired and unpaired metamorphic belts

Paired metamorphic belts occur in many parts of the circum-Pacific regions. A pair is composed of two contrasting belts running parallel: a high-pressure metamorphic belt which probably formed beneath a trench zone, and a low-pressure metamorphic belt which probably formed beneath a volcanic chain in the adjacent island arc or continental margin. The former and the latter belt are accompanied by basic-ultrabasic rocks and by granitic-andesitic-rhyolitic rocks, respectively.The rapid descent of a thick, cold oceanic plate along a convergent plate juncture should create an unusually low geothermal gradient to cause high-pressure metamorphism. If the rate of plate descent is relatively slow, or if the descending oceanic lithosphere is too thin or too hot, the resultant geothermal gradient will not be low enough to cause high-pressure, but may cause medium-pressure metamorphism. In this case, the contrast between the two associated metamorphic belts will be obscure. The heat transfer by the rise of magmas and mantle materials appears to be a necessary condition for the formation of low-pressure metamorphic belts.Presumably, paired and unpaired (single) metamorphic belts form by the same mechanism, and an unpaired belt represents paired belts in which the contrast between the two belts is obscure, or in which one of the two belts is undeveloped or lost.Progress in experimental petrology enables us to estimate the pressure and temperature during metamorphism, and to know the relations between the conditions of partial melting and the composition of the resultant magmas. This sets limits to our ideas about the relevant tectonic processes in plate junctures.     

Geochronology of the Duguer range metamorphic rocks,Central Tibet: implications for the changing tectonic setting of the South Qiangtang subterrane

The Duguer area represents one of the few occurrences of high-grade metamorphic rocks in the ‘Central Uplift’ zone of the Qiangtang terrane, central Tibet. The metamorphic rocks consist mainly of orthogneiss, paragneiss, and schist. To better understand the formation of these rocks, seven samples of gneiss and schist from the Duguer area were selected for in situ zircon U–Pb analysis and Ar–Ar dating of metamorphic minerals. The results suggest two distinct metamorphic stages, during the Late Triassic (229–227 Ma) and Late Jurassic (150–149 Ma). These stages correspond to the closure of the Palaeo-Tethys Ocean and northward subduction of the Bangong–Nujiang Neo-Tethys oceanic crust, respectively. We suggest that the Late Triassic metamorphic rocks of the Duguer area in the central South Qiangtang subterrane provide evidence of continental collision between the North and South Qiangtang subterranes, following the subduction of oceanic crust. It is likely that deep subduction of oceanic crust occurred along the Longmu Co–Shuanghu–Lancangjiang suture zone (LSLSZ), which would have hindered exhumation owing to the high density of oceanic crust. Subsequent break-off and delamination of the subducted oceanic slab at ~220 Ma may have resulted in exhumation of high-pressure and high-grade metamorphic rocks in the South Qiangtang subterrane. The Late Jurassic ages of metamorphism and deformation obtained in this study indicate the occurrence of an Andean-type orogenic event within the South Qiangtang subterrane. This hypothesis is further supported by an apparent age gap in magmatic activity (150–130 Ma) along the magmatic arc, and the absence of Late Jurassic sediments.     

阿尔泰造山带喀纳斯群变质碎屑岩地球化学特征及年代学研究

喀纳斯群为一套巨厚的中低压型浅变质碎屑岩系,主要由片岩、片麻岩、变质砂岩等组成,其形成时代未有统一的认识,致使阿尔泰构造带的构造演化过程争议较大。对喀纳斯群变质岩进行原岩恢复,认为该套变质岩为副变质岩,考虑到变质碎屑岩的成岩物质继承母岩特征和变质程度的影响,利用碎屑岩研究方法对元素地球化学特征进行探讨,显示出喀纳斯群变质碎屑岩原岩形成环境以大陆岛弧为主,兼有活动大陆边缘的特征,CIA、ICV指数反应出原岩经历了相对温暖、湿润的风化作用,成熟度较低。锆石U-Pb定年结果表明,最年轻的锆石年龄集中在(500±3.0)Ma,代表喀纳斯群的上限年龄,认为该套地层形成于晚寒武世晚期之前,为一套形成于大陆岛弧或活动大陆边缘的复理石建造。新元古代青白口纪初期基底裂解事件,暗示着阿尔泰构造带存在前寒武纪大陆地壳基底。     

Triple-junction migration during Paleozoic plate convergence: the Aracena metamorphic belt, Hercynian massif, Spain

New data on the petrology and structure of the Aracena metamorphic belt shows that this is a subduction-related, low-pressure/high-temperature complex developed by plate convergence at the north margin of Gondwana during the Paleozoic. The low-pressure, inverted metamorphic gradient in MORB-derived amphibolites resulted from heating from the continental hanging wall during subduction. This implies that the previous heating of the continental rocks was related to subduction of an oceanic ridge and the creation of a slab window beneath the continental margin. This slab window brought the asthenosphere in contact with the continental margin inducing a shallow thermal anomaly and partial melting of the lithospheric mantle resulting in boninite magmatism.     

超高压变质矿物中的多相固体包裹体研究进展

大陆碰撞过程中熔/流体的组成和演化是研究大陆深俯冲动力学的重要内容,而超高压岩石记录了大陆俯冲和折返过程中的熔/流体-岩石相互作用,因而是研究大陆碰撞过程中熔/流体组成和演化的天然实验室。大陆俯冲带高压/超高压变质矿物中多相固体包裹体作为熔/流体活动的直接记录,为我们提供了揭示超高压变质过程中熔/流体演化的重要制约。近年来,围绕超高压岩石中多相固体包裹体的形成时间、演化过程及其所反映的俯冲带超高压变质熔/流体的组成和性质,进行了大量的研究工作。超高压岩石中多相固体包裹体的发现,为理解峰期超高压变质流体的组成和演化提供了重要制约,同时也为研究俯冲板片-地幔楔界面的熔/流体交代作用提供了新的途径。本文从多相固体包裹体形成机制、结构形态特征、矿物化学成分及其地质地球化学意义等方面,对于超高压变质岩中多相固体包裹体的研究现状和存在的问题进行系统地总结和探讨,以期促进多相固体包裹体的岩石学和地球化学研究。     

High-pressure micro-inclusions and development of an inverted metamorphic gradient in the Santiago Schists (Ordenes Complex, NW Iberian Massif, Spain): evidence of subduction and syncollisional decompression

Abstract The Santiago Schists are located in the Basal Unit of the Ordenes Complex, one of the allochthonous complexes outcropping in the inner part of the Hercynian Belt in the north-west of the Iberian Peninsula. Their tectonothermal evolution is characterized by the development of an eo-Hercynian metamorphic episode (c. 374 Ma) of high-P, low- to intermediate-T. The mineral assemblage of the high-P episode is preserved as a very thin Si= S1 foliation included in albite porphyroblasts, being composed of: albite + garnet-I + white mica-1 + chlorite-1 + epidote + quartz + rutile ± ilmenite. The equilibrium conditions for this mineral assemblage have been estimated by means of different thermobarometers at 495 ± 10 °C and 14.7 ± 0.7 kbar (probably minimum pressure). The later evolution (syn-D2) of the schists defines a decompressive and slightly prograde P-T path which reached its thermal peak at c. 525 ± 10 °C and 7 kbar. Decompression of the unit occurred contemporaneously with an inversion of the metamorphic gradient, so that the zones of garnet-II, biotite (with an upper subzone with chloritoid) and staurolite developed from bottom to top of the formation. The estimated P-T path for the Santiago Schists suggests that the Basal Unit, probably a fragment of the Gondwana continental margin, was uplifted immediately after its subduction at the beginning of the Hercynian Orogeny. It also suggests that the greater part of the unroofing history of the unit took place in a context of ductile extension, probably related to the continued subduction of the Gondwana continental margin and the contemporaneous development of compensatory extension above it. The inverted metamorphic gradient seems related to conductive heat transferred from a zone of the mantle wedge above the subducted continental margin, when it came into contact with the upper parts of the schists along a detachment, probably of extensional character. The general metamorphic evolution of the Santiago Schists, with the development of high-P assemblages with garnet prior to decompressive and prograde parageneses with biotite, is unusual in the context of the European Hercynian Belt, and shows a close similarity to the tectonothermal evolution of several high-P, low- to intermediate-T circum-Pacific belts.     

P-T paths from high temperature shear zones beneath ophiolites

Abstract Mctamorphic rocks of the St Anthony Complex of north-western Newfoundland are best interpreted in terms of a high-temperature shear zone formed between down-going continental margin rocks and overriding oceanic lithosphere in a subduction zone. High-grade rocks, immediately beneath the oceanic lithosphere peridotite, display retrograde meta-morphism in high-strain zones, whereas lower grade rocks, near the base of the metamorphic complex, display prograde metamorphism in high-strain zones. Mylonite zones in meta-basitcs at all levels in the complex contain the assemblage epidote-hornblende-albite-sodic oligoclase. These observations suggest that the 'inverted metamorphic gradient'within the St Anthony Complex results from the fortuitous preservation of residual metamorphic assemblages from different crustal levels within an epidote amphibolite facies shear zone. The degree of re-equilibration is strongly dependent on the degree of strain, and is best achieved in synmetamorphic mylonite zones. This interpretation of the St Anthony Complex can be extended to other sub-ophiolite metamorphic sheets, which show very similar relationships. It is proposed that most metamorphic sheets beneath ophiolites are high temperature shear zones, the P-T paths of which preserve records of burial and exhumation in subduction zones.     

辽北开原地区新太古代变质深成岩LA-ICP-MS 锆石U-Pb 年龄及地球化学特征

辽北开原地区新太古代变质深成岩位于华北板块北缘陆缘活动带东段,主要岩性为二长花岗质片麻岩、花岗闪长质片麻岩和英云闪长质片麻岩,其中英云闪长质片麻岩LA-ICP-MS锆石207Pb/206Pb年龄加权平均值为2489.6±9.1 Ma,为新太古代。新太古代变质深成岩属高钾钙碱性-钾玄岩,准铝-过铝质岩石系列,轻稀土元素较富集,重稀土元素相对亏损,具有下地壳或太古宙沉积岩部分熔融形成的特征。通过岩石学、岩石地球化学和构造环境及就位机制分析,结合邻区构造演化研究,认为辽北开原地区变质深成岩岩浆来自较浅的基性古陆壳局部熔融。大地构造位置可能处在洋壳与陆壳的接触带,说明新太古代清河断裂附近可能出现陆壳碰撞增生活动。闪长质-石英闪长质-花岗闪长质-二长花岗质片麻岩体现了陆壳经历长时间的增生、造陆活动,已由早期的基性陆壳向现今的硅铝质陆壳转变。     

Geodynamic settings and formation conditions of crystalline complexes in the south Altai and south Gobi metamorphic belts

The Hercynian mobile belts in Central Asia comprise the Hercynian proper and the Late Hercynian (Indosinian) belts separated by the South Gobi microcontinent, the origin of which is related to the evolution of the South Mongolian and Inner Mongolian basins with the oceanic crust. Crystalline complexes within these belts occur as tectonic sheets of a variety of sizes. At the early stages, the metamorphic grade of these complexes reached conditions of high-temperature subfacies of amphibolite and locally developed granulite facies. In tectonic terms, the Hercynian belt of metamorphic rocks is situated at the margin of the North Asian Caledonian continent and extends from the southeast to the northwest along the southern slope of the Gobi, Mongolian, and Chinese Altai to East Kazakhstan, where metamorphic rocks are localized in the Irtysh Shear Zone. All these rocks are combined into the South Altai metamorphic belt of more than 1500 km in extent. Another belt of isolated outcrops of crystalline rocks conventionally combined into the Indosinian South Gobi metamorphic belt is traced along the junction of the Hercynides with the South Gobi microcontinent. The high-grade metamorphic rocks within both belts are not fragments of an ensialic Caledonian or older basement. These rocks were formed 390–360 and 230–220 Ma ago as a result of the closure of the Tethian South Mongolian and Inner Mongolian oceanic basins (Paleotethys I and Paleotethys II). The spatial position of the South Altai and South Gobi metamorphic belts is caused by the asymmetric structure of the Tethian basins, where active continental margins are expressed most distinctly along their northern parts, while passive margins extend along the southern parts (in present-day coordinates).     

Integration of natural data within a numerical model of ablative subduction: a possible interpretation for the Alpine dynamics of the Austroalpine crust

A numerical modelling approach is used to validate the physical and geological reliability of the ablative subduction mechanism during Alpine convergence in order to interpret the tectonic and metamorphic evolution of an inner portion of the Alpine belt: the Austroalpine Domain. The model predictions and the natural data for the Austroalpine of the Western Alps agree very well in terms of P–T peak conditions, relative chronology of peak and exhumation events, P–T–t paths, thermal gradients and the tectonic evolution of the continental rocks. These findings suggest that a pre‐collisional evolution of this domain, with the burial of the continental rocks (induced by ablative subduction of the overriding Adria plate) and their exhumation (driven by an upwelling flow generated in a hydrated mantle wedge) could be a valid mechanism that reproduces the actual tectono‐metamorphic configuration of this part of the Alps. There is less agreement between the model predictions and the natural data for the Austroalpine of the Central‐Eastern Alps. Based on the natural data available in the literature, a critical discussion of the other proposed mechanisms is presented, and additional geological factors that should be considered within the numerical model are suggested to improve the fitting to the numerical results; these factors include variations in the continental and/or oceanic thickness, variation of the subduction rate and/or slab dip, the initial thermal state of the passive margin, the occurrence of continental collision and an oblique convergence.     

The nature of the Palaeozoic oceanic basin at the southwestern margin of Gondwana and implications for the origin of the Chilenia terrane (Pichilemu region,central Chile)

The Coastal Accretionary Complex of central Chile constitutes the product of early Carboniferous to Late Triassic subduction at the rear of Chilenia, a continental terrane likely derived from Laurentia and accreted to southwestern margin of Gondwana during the Mid to Late Devonian. The complex contains basaltic metavolcanic sequences of the subducted oceanic lithosphere accreted to the active margin. In this paper, we address the tectonic setting of these rocks by means of a geochemical study in the coastal area of Pichilemu region, central Chile. The accreted fragments of oceanic crust occupy different structural levels, exhibit variable metamorphic grade, and have geochemical fingerprints that reveal a compositional heterogeneity of the subducted oceanic crust. The amphibolites have N to E-MORB compositions. Greenschist units include N-MORB and E-MORB transitional to OIB, and blueschists and greenschists interleaved within a single metavolcanosedimentary sequence have OIB signatures. Neodymium isotopic systematics indicate depleted and enriched mantle sources, whereas strontium isotopic systematics indicate seawater/rock interaction. The variety of rocks suggests formation in an oceanic setting characterized by shallow and deep mantle sources, such as plume-influenced ridge. Based on the geological, petrological, geochemical, and isotopic characteristics, we propose that the metavolcanic protoliths of the Pichilemu region formed relatively close to the western margin of the Chilenia terrane during the initial stage (late Cambrian–Early Devonian) of seafloor development and drifting of this continental block. Geochemical similarities with oceanic units accreted to the active margin south of the Pichilemu region indicate a regional pattern of the oceanic crust subducted under the Palaeozoic Chilean margin between, at least, 34°S and 39°S latitude, strongly supporting the activity of a mantle plume. This, in turn, can be correlated with the location of the Pacific plume generation zone in early Palaeozoic era, corroborating a Laurentian origin for the Chilenia terrane.     

Prograde pressure–temperature paths in the pelitic schists of the Sambagawa metamorphic belt, SW Japan

Prograde P–T paths recorded by the chemistry of minerals of subduction‐related metamorphic rocks allow inference of tectonic processes at convergent margins. This paper elucidates the changing P–T conditions during garnet growth in pelitic schists of the Sambagawa metamorphic belt, which is a subduction related metamorphic belt in the south‐western part of Japan. Three types of chemical zoning patterns were observed in garnet: Ca‐rich normal zoning, Ca‐poor normal zoning and intrasectoral zoning. Petrological studies indicate that normally‐zoned garnet grains grew keeping surface chemical equilibrium with the matrix, in the stable mineral assemblage of garnet + muscovite + chlorite + plagioclase + paragonite + epidote + quartz ± biotite. Pressure and temperature histories were inversely calculated from the normally‐zoned garnet in this assemblage, applying the differential thermodynamic method (Gibbs' method) with the latest available thermodynamic data set for minerals. The deduced P–T paths indicate slight increase of temperature with increasing pressure throughout garnet growth, having an average dP/dT of 0.4–0.5 GPa/100 °C. Garnet started growing at around 470 °C and 0.6 GPa to achieve the thermal and baric peak condition near the rim (520 °C, 0.9 GPa). The high‐temperature condition at relatively low pressure (for subduction related metamorphism) suggests that heating occurred before or simultaneously with subduction.     

Cretaceous high-temperature rapid loading and unloading in the Abukuma metamorphic terrane, Japan

The Cretaceous Abukuma metamorphic terrane consists of the oceanic Gosaisyo Series overthrust onto the terrigenous Takanuki Series. Although the dominant mineralogy defines one of the classic areas of andalusite–sillimanite type progressive metamorphism, there are several lines of evidence suggesting an earlier higher-pressure (up to c . 12  kbar) history of the Takanuki Series and the nearby Gosaisyo Series. These are: (1) the occurrence of rare although widespread relic kyanite in sillimanite+K-feldspar zone-grade pelitic rocks; (2) the high grossular content of garnet interiors (up to c . 30  mol %) overgrown by Ca-poor rims ( c . 2  mol % grossular) in pelitic rocks containing Al₂SiO₅ minerals (sillimanite±relic kyanite±retrograde andalusite), plagioclase and quartz; (3) the occurrence of rutile as inclusions in garnet in pelitic rocks; and (4) the occurrence of relic corundum+almandine association in silica-poor and Al–Fe-rich rocks. Garnet in the Takanuki Series pelitic rocks commonly shows textural sector zoning and preserves growth zoning despite the high metamorphic grade, suggesting rapid changes in P–T  conditions and a relatively short duration of high-temperature conditions. Combined with radiometric dating, these observations suggest that the Abukuma sillimanite+K-feldspar zone-grade rocks underwent a clockwise P–T  path with very fast (>4  mm  y⁻¹) average burial and exhumation rates.     

Tectono-metamorphic evolution of the Neyriz metamorphic complex, Quri-Kor-e-Sefid area (Sanandaj-Sirjan Zone, SW Iran)

The Neyriz region includes outcrops of metamorphic rocks that are thrust over the Neotethyan ophiolites. These rocks are affected by a major deformational event, the result of which includes a shearing polyphase foliation present in gneissic core domes, overprinted by a crenulation cleavage. These fundamental structures developed contemporaneously with a medium-pressure metamorphism which is characterized by the syn-kinematic crystallization of kyanite and the beginning of anatexis, followed by the development of retrometamorphic mineral parageneses. The major deformation phase in the area occurred during the Early-Cimmerian orogeny in the Late Triassic. Following the orogeny, the gneiss domes started to rise into the upper levels of the crust. From the geodynamic point of view, after the Mid-Permian the studied area was situated at southern passive margin of the Iranian plate; the central Iranian microcontinent at that time was separated by the Neotethys ocean from the Gondwanian supercontinent. After the Late Triassic the region became an active margin associated with an accretionary prism. The margin was finally involved in an orogenic wedge after the closure of the Neotethyan oceanic basin in the Late Mesozoic. Closure of the basin resulted in a major thrusting of the metamorphic rocks of the southern Iranian margin over the Neotethyan ophiolites.