Orthopyroxene–sillimanite–sapphirine granulites from the Bamble granulite terrane, southern Norway

Silica-deficient sapphirine-bearing rocks occur as an enclave within granulite facies Proterozoic gneisses and migmatites near Grimstad in the Bamble sector of south-east Norway (Hasleholmen locality). The rocks contain peraluminous sapphirine, orthopyroxene, gedrite, anthophyllite, sillimanite, sapphirine, corundum, cordierite, spinel, quartz and biotite in a variety of assemblages. Feldspar is absent.
Fe²⁺/(Fe²⁺+ Mg) in the analysed minerals varies in the order: spinel > gedrite ≥ anthophyllite ≥ biotite > sapphirine>orthopyroxene > cordierite.
Characteristic pseudomorph textures indicate coexistence of orthopyroxene and sillimanite during early stages of the reaction history. Assemblages containing orthopyroxene-sillimanite-sapphirine-cordierite-corundum developed during a high-pressure phase of metamorphism and are consistent with equilibration pressures of about 9 kbar at temperatures of 750–800°C. Decompression towards medium-pressure granulite facies generated various sapphirine-bearing assemblages. The diagnostic assemblage of this stage is sapphirine-cordierite. Sapphirine occurs in characteristic symplectite textures. The major mineralogical changes can be described by the discontinuous FMAS reaction: orthopyroxene + sillimanite → sapphirine + cordierite + corundum.
The disequilibrium textures found in the Hasleholmen rocks are characteristic for reactions which have been in progress but then ceased before they run to completion. Textures such as reaction rims, symplectites, partial replacement, corrosion and dissolution of earlier minerals are characteristic of granulite facies rocks. They indicate that, despite relatively high temperatures (700–800° C), equilibrium domains were small and chemical communication and transport was hampered as a result of dry or H₂O-poor conditions.     

A corundum–quartz assemblage from the Eastern Ghats Granulite Belt,India: evidence for high P–T metamorphism?

Corundum+quartz-bearing assemblages occur in small lenses in granulite facies metapelites in Rayagada, north-central part of the Eastern Ghats Granulite Belt, India. Corundum porphyroblasts and quartz coexist with porphyroblastic almandine-rich garnet, hercynite spinel, ilmenite and magnetite. Corundum and quartz are separated by sillimanite or a composite corona consisting of sillimanite and garnet, whereas corundum shows sharp grain boundaries with spinel, ilmenite and magnetite. Porphyroblastic corundum contains prismatic sillimanite inclusions in which irregularly shaped quartz is enclosed. Two distinct reactions are inferred from the textural features: corundum+quartz=sillimanite and spinel+quartz=garnet+sillimanite. From the petrographical features, we infer that corundum–quartz–garnet–spinel was the peak metamorphic assemblage. Although large uncertainties exist regarding the positions of the respective reactions in P–T  space, from several published experimental results and theoretical calculations a peak metamorphic condition of 12  kbar and 1100  °C is estimated as the lower stability limit of the corundum–quartz assemblage. Decompression from the peak P–T  condition to c .  9  kbar, 950  °C is inferred.     

高喜马拉雅变质岩“夕线石带”的地质意义

通过对聂拉木高喜马拉雅结晶岩系石榴子石带-十字石带-蓝晶石带-夕线石带倒转变质的研究,认为除夕线石带以外的其它变质带主要由固相变质反应形成。夕线石的出现并非蓝晶石或十字石带递增变质所致。"倒转变质"不应包括所谓的夕线石带。实际上,夕线石化与深熔作用之后的溶液（或熔体）活动更为密切。时间顺序上应是递增变质作用及分带→深熔作用→夕线石化,夕线石的出现不是深熔作用的开始,而是深熔作用的结束。夕线石的形成主要与变形作用过程中黑云母和／或钾长石的分解及碱（土）金属组分的迁移有关,关键在于溶液（或熔体）组分沿裂隙迁移过程中发生的组分逐步沉淀,最早沉凝的Al、Si组分形成夕线石和石英,之后陆续有其它的组分的结晶;细夕线石粗粒化即进一步转化形成柱状夕线石的同时形成蠕英结构和斜长石生长边。夕线石化可能与深熔花岗（片麻）岩的上升过程有关。     

Silica-undersaturated sapphirine, spinel and kornerupine granulite facies rocks, NE Strangways Range, Central Australia

Small pods of silica-undersaturated Al-rich and Mg-rich granulite facies rocks containing sapphirine, pleonastic spinel, kornerupine, cordierite, orthopyroxene, corundum, sillimanite and gedrite are scattered throughout the NE Strangways Range, Central Australia. These are divided into four distinct rock types, namely orthopyroxene-rich aluminous granofels and metapelitic gneisses containing sapphirine, spinel or kornerupine. Two granulite facies metamorphic events are recognized, of which only the first (M1) is considered in this paper. Peak metamorphic mineral parageneses indicate that the M1 thermal maximum occurred at approximately 900–950 °C and 8–9 kbar. All samples are characterized by profuse and diverse coronitic and symplectic reaction textures. These are interpreted as evidence for the sequential crossing of the following reactions in the system FMAS: cordierite + spinel + corundum = sapphirine + sillimanite, cordierite + spinel = orthopyroxene + sapphirine + sillimanite, sapphirine + spinel + sillimanite = orthopyroxene + corundum, sapphirine + sillimanite = cordierite + orthopyroxene + corundum. Phase stability relationships in FMAS and MASH indicate an anticlockwise P–T path terminated by isobaric cooling. Such a path is exemplified by early low-P mineral parageneses containing spinel, corundum and gedrite and the occurrence of both prograde and retrograde corundum. Reaction textures preserve evidence for an increase in aH₂O and aB₂O₃ with progressive isobaric cooling. This hydrous retrogression resulted from crystallization of intimately associated M1 partial melt segregations. There is no evidence for voluminous magmatic accretion giving rise to the high M1 thermal gradient. The M1 P–T path may be the result of either lithospheric thinning after both crustal thickening and burial of the supracrustal terrane, or concomitant crustal thickening and mantle lithosphere thinning.     

Corundum–quartz-bearing assemblage in the Ihouhaouene area (In Ouzzal, Algeria)

Granulite facies quartzites from the Ihouhaouene region, in the northern part of In Ouzzal, contain the assemblage corundum+quartz+magnetite together with hercynitic spinel+quartz+magnetite, sillimanite+quartz+magnetite and almandine-rich garnet+quartz+magnetite. Two types of corundum have been recognized: the first is primary and is found with quartz and magnetite only; the second type is found together with magnetite and chlorite rimming spinel as a fine-grained corona. The textures show that spinel-rich magnetite probably exsolved primary corundum, sillimanite, spinel and garnet during the cooling history. The secondary corundum formed later from the spinel already exsolved from magnetite. The secondary corundum is certainly metastable with respect to quartz. This may also apply for the primary corundum. However, given the high-temperature setting of this rock, it cannot be excluded that the stable contacts observed between primary corundum and quartz indicate equilibrium between the two phases. Taking into account the uncertainties in the thermodynamic data, the stability of this assemblage would imply that this part of In Ouzzal has recorded very high P–T conditions, above 1100°C at 12 kbar.     

Ultra high temperature-metamorphism and its significance in the Central Indian Tectonic Zone

In the present study from the southern margin of the Central Indian Tectonic Zone, it is demonstrated how the metamorphic P–T path of ultrahigh-temperature granulite terranes can be reconstructed using the metamorphic transition in corundum granulites from early biotite melting to later FMAS solid–solid reaction. The extreme metamorphism in these rocks caused two-stage biotite melting, resulting in initial porphyroblastic garnet₁ and later sapphirine–spinel₁ incongruent solid mineral assemblages. During this process, the leucocratic and melanocratic layers in the corundum granulites evolved from an initial silica-oversaturated to a later silica-undersaturated domain. In the melanocratic layer, this allowed localized concentration of sapphirine-spinel₁ and residual sillimanite₁, producing an extremely restitic assemblage, at the culmination of peak metamorphism, BM₁. BM₁ is constrained at  1000 °C at relatively deep crustal levels (P  9 kbar) from the stability of ferroaugite in a co-metamorphosed Iron Formation granulite. During subsequent metamorphism (BM₂), the reaction path and history in the corundum granulites shifted to the restitic domain allowing reacting sapphirine, spinel₁ and sillimanite to produce coronal garnet₂–corundum assemblage via a FMAS univariant reaction. In the final stages of reaction history, biotite₂–sillimanite₂–spinel₂ assemblage was produced after garnet₂–corundum due to localized melt–crystal interaction. The metamorphic sequence, when interpreted with the help of a newly constructed, qualitative KFMASH petrogenetic grid, reveals successive stages of heating, increasing pressure and cooling around the KFMASH invariant point, [Opx,Crd], which is consistent with a counterclockwise metamorphic P–T path. The near isobaric nature of post-peak cooling (ΔT  250–300 °C) is also evident from multistage pyroxene exsolution and by the appearance of lamellar and coronal garnets in the Iron Formation granulites. This study provides the first tight constraint for ultrahigh-T metamorphism along a counter clockwise P–T trajectory in the Central Indian Tectonic zone, and has important bearing for terrane correlations in this part of East Gondwanaland. In addition, the new KFMASH grid allows evaluation of metamorphic phase relations in ultrahigh-T, corundum-bearing and corundum-absent aluminous granulites.     

Chloritoid and staurolite stability: implications for metamorphism in the Archaean Yilgarn Block, Western Australia

Abstract The stability of quartz-chloritoid-staurolite-almandine-cordierite and aluminium silicates is used to constrain both metamorphic conditions and pressure-temperature trajectories for two localities within the 2700 Ma Archaean Yilgarn Block in Western Australia. Available experimental data are used to calculate thermodynamic data for a self-consistent set of equilibria between these minerals. A lower amphibolite facies locality from the margin of a lower strain area contains assemblages including quartz-chloritoid-staurolite-garnet-biotite with altered cordierite replacing chloritoid, quartz-staurolite-andalusite, and quartz-cordierite-andalusite-biotite. This locality was heated to 530–560°C in the andalusite field, at 4.2 kbar. A sample from a mid- to upper-amphibolite facies, highly strained locality contains relict staurolite enclosed by andalusite, in turn replaced by cordierite and muscovite with biotite and sillimanite in the matrix. The assemblage was heated isobarically from conditions near the maximum experienced by the lower grade locality of 560°C at 4.2 kbar to temperatures in excess of the andalusite-sillimanite transition but within the quartz plus muscovite stability field (600–650°C). The higher grade locality is close to a granitoid dome and sections based on gravity profiles reveal that this locality is underlain by granitoid at shallow depths. The higher grade metamorphism apparently reflects superposition of the thermal aureole on regional metamorphic conditions similar to those in the lower grade areas.     

Towards a Better Understanding of the Fibrolite Problem: the Effect of Reaction Overstepping and Surface Energy Anisotropy

Trachytes from the Euganean Hills District (Italy) contain metapeliticxenoliths that have been pyrometamorphosed during incorporationin the melt. In xenoliths containing sillimanite crystallizedduring a previous regional HT/LP metamorphism, fibrolite systematicallynucleates at the grain boundaries of sillimanite prisms andwithin plagioclase crystals. Ternary feldspar thermometry showsthat plagioclase in contact with sillimanite plots along the750°C solvus that reflects near-equilibrium conditions ofregional metamorphism. Plagioclase containing fibrolite plotscloser towards the 950°C solvus, reflecting the tendencyof plagioclase to re-equilibrate at high temperature duringpyrometamorphism by a fibrolite-forming reaction:     

Metastable growth of corundum adjacent to quartz in a spinel-bearing quartzite from the Archaean Napier Complex, Antarctica

In a granulite-facies spinel-bearing quartzite, corundum, orthopyroxene and sapphirine (and rarely cordierite and sillimanite) form partial rims separating spinel from quartz. Textures indicate the reactions:
spinel + quartz = orthopyroxene + corundum, and
spinel + quartz = orthopyroxene + sapphirine.
Thus, corundum and sapphirine are produced by reactions involving quartz. The low Al-content of the orthopyroxene (0.5–2.8 wt %) and low values for Mg–Fe distribution coefficient for spinel–sapphirine and spinel–orthopyroxene reflect low-temperature conditions during formation of the reaction products. Absence of zoning in spinel and a constant Mg–Fe distribution coefficient for spinel–sapphirine and spinel–orthopyroxene, over a compositional range, indicate Mg–Fe equilibration. It is suggested that stable reactions such as spinel + quartz = cordierite or spinel + quartz = garnet + sillimanite were over-stepped and that metastable reactions give rise to the anomalous juxtaposition of corundum + quartz.     

Kyanite-bearing rocks from the Hackett River area,N.W.T.: Implications for Archean geothermal gradients

The increase in metamorphic grade toward the Hackett River gneiss dome indicates that the structural dome is also a metamorphic culmination. In pelitic rocks east of the dome, the prograde sequence is chlorite, biotite, staurolite-cordierite, sillimanite. To the southwest the sequence is andalusite-staurolite-cordierite, sillimanite. In quartzofeldspathic gneisses which are closer to the dome than the sillimanite isograd, kyanite occurs as corroded relics, cross-cut by sillimanite and rimmed by cordierite and plagioclase.The pelites were metamorphosed under regional low-pressure conditions at the same time the quartzo-feldspathic rocks underwent higher-pressure metamorphism. A lateral variation in geothermal gradient during metamorphism is postulated to account for the change in facies-series. High heat flow beneath oceanic crust produced the low-pressure assemblages in the pelites; higher-pressure assemblages formed in a region of suppressed isotherms around a relatively cool, proto-continental trondhjemitic body. Low-pressure conditions were imposed on the kyanite-bearing gneisses during continuing metamorphism and diapiric uplift.Spatial association of late Archean kyanite-bearing rocks with early Archean sodic proto-cratons has also been noted in the Churchill and Superior Provinces of Canada as well as the Rhodesian Craton.     

Phosphate and sulfate-phosphate mineralization in sillimanite-bearing rocks at the Kyakhta deposit,western Transbaikal region

The phosphate and sulfate-phosphate minerals in the sillimanite-bearing rocks of the Kyakhta deposit are considered. The mineral assemblages of the high-Al rocks were formed during prograde and retrograde stages of metamorphism. The first stage is characterized by the formation of sillimanite, corundum, muscovite, quartz, rutile, titanohematite, magnetite, feldspar, biotite, lazulite, and wagnerite. The muscovite composition showed that sillimanite paragenesis was formed at temperatures above 510–600°C. According to oxygen isotope thermometry, the minimum metamorphic temperature for quartz and titanohematite is 690°C. Andalusite, diaspore, quartz, pyrophyllite, muscovite, and a wide range of phosphates and sulfate-phosphates crystallized during the retrograde stage. The decrease in temperature and increase in the water content led to the following sequence of mineral formation: Mg-Fe-Al-Ca-REE-rich phosphates (lazulite, scorzalite, augelite, apatite, and monazite) → Ca-Sr sulfate-phosphates (woodhouseite and svanbergite) → sulfate (barite) → Sr-Ca-Ba aluminophosphates (goyazite, crandallite, and gorceixite). The chemical compositions of phosphates and sulfate-phosphates minerals and their formation conditions are discussed.     

Cretaceous high-temperature rapid loading and unloading in the Abukuma metamorphic terrane, Japan

The Cretaceous Abukuma metamorphic terrane consists of the oceanic Gosaisyo Series overthrust onto the terrigenous Takanuki Series. Although the dominant mineralogy defines one of the classic areas of andalusite–sillimanite type progressive metamorphism, there are several lines of evidence suggesting an earlier higher-pressure (up to c . 12  kbar) history of the Takanuki Series and the nearby Gosaisyo Series. These are: (1) the occurrence of rare although widespread relic kyanite in sillimanite+K-feldspar zone-grade pelitic rocks; (2) the high grossular content of garnet interiors (up to c . 30  mol %) overgrown by Ca-poor rims ( c . 2  mol % grossular) in pelitic rocks containing Al₂SiO₅ minerals (sillimanite±relic kyanite±retrograde andalusite), plagioclase and quartz; (3) the occurrence of rutile as inclusions in garnet in pelitic rocks; and (4) the occurrence of relic corundum+almandine association in silica-poor and Al–Fe-rich rocks. Garnet in the Takanuki Series pelitic rocks commonly shows textural sector zoning and preserves growth zoning despite the high metamorphic grade, suggesting rapid changes in P–T  conditions and a relatively short duration of high-temperature conditions. Combined with radiometric dating, these observations suggest that the Abukuma sillimanite+K-feldspar zone-grade rocks underwent a clockwise P–T  path with very fast (>4  mm  y⁻¹) average burial and exhumation rates.     

http://www.sciencedirect.com/science/article/pii/S1674987112000060

The Khondalite Belt within the Inner Mongolia Suture Zone（IMSZ） in the North China Craton is a classic example for Paleoproterozoic ultrahigh-temperature（UHT） metamorphism.Here we report new spinel-bearing metapelitic granulites from a new locality at Xumayao within the southern domain of the IMSZ.Petrological studies and thermodynamic modeling of the spinel+quartz-bearing assemblage shows that these rocks experienced extreme metamorphism at UHT conditions.Spinel occurs in two textural settings:（1） high X_Zn（Zn/（Mg+Fe^Ⅱ+Zn）=0.071-0.232） spinel with perthitic K-feld-spar. sillimanite and quartz in the rock matrix;and（2） low X_Zn（0.045—0.070） spinel as inclusions within garnet porphyroblasts in association with quartz and sillimanite. Our phase equilibria modeling indicates two main stages during the metamorphic evolution of these rocks:（1） near-isobaric cooling from 975℃to 875℃around 8 kbar.represented by the formation of garnet porphyroblasts from spinel and quartz;and（2）cooling and decompression from 850℃.8 kbar to below 750℃.6.5 kbar,represented by the break-down of garnet.The spinel+quartz assemblage is considered to have been stable at peak metamorphisni.formed through the break-down of cordierite.indicating a near isothermal compression process.Our study confirms the regional extent of UHT metamorphisni within the IMSZ associated with the Paleoproterozoic subduction-collision process.     

Epitaxial quartz inclusions in corundum from a sapphirine–garnet boudin,Bamble Sector,SE Norway: SiO2–Al2O3 miscibility at high P–T dry granulite facies conditions

An Al‐rich, SiO₂‐deficient sapphirine–garnet‐bearing rock occurs as a metapelitic boudin within granulite facies Proterozoic charnockitic gneisses and migmatites on the island of Hisøy, Bamble Sector, SE Norway. The boudin is made up of peraluminous sapphirine, garnet, corundum, spinel, orthopyroxene, sillimanite, cordierite, staurolite and biotite in a variety of assemblages. Thermobarometric calculations based on coexisting sapphirine–spinel, garnet–corundum–spinel–sillimanite, sapphirine–orthopyroxene, and garnet–orthopyroxene indicate peak‐metamorphic conditions near to 930 °C at 10 kbar. Corundum occurs as single 200 to 3000 micron sized skeletal crystal intergrowths in cores of optically continuous pristine garnet porphyroblasts. Quartz occurs as 5–60 micron‐sized euhedral to lobate inclusions in the corundum where it is in direct contact with the corundum with no evidence of a reaction texture. Some crystal inclusions exhibit growth zoning, which indicates that textural equilibrium was achieved. Electron Back‐Scatter Diffraction (EBSD) studies reveal that the quartz inclusions share a common c‐axis with the host corundum crystal. The origin of the quartz inclusions in corundum is enigmatic as recent experimental studies have confirmed the instability of quartz–corundum over geologically realistic P–T ranges. The combined EBSD and textural observations suggest the presence of a former silica‐bearing proto‐corundum, which underwent exsolution during post‐peak‐metamorphic uplift and cooling. Exsolution of quartz in corundum is probably confined to fluid‐absent conditions where phase transitions by coupled dissolution–precipitation mechanisms are prevented.     

FT-IR Spectroscopic Investigation of Hydrous Components in Sillimanite from Eastern Ghat Granulite Belt, India

FT-IR spectra of sillimanite samples from high grade regionally metamorphosed rocks belonging to the granulite terrain (amphibolite to pyroxene granulite facies) deciphers prominent OH features. Heating experiments indicate growth of prominent band at 3161cm⁻¹. Heating above 1000°C all OH features disappear in intensity into broad features with slight shift of bands towards lower energies. Complete dehydration requires temperatures above 1000°C. Coexistence of boron and OH features are also observed in all sillimanite samples. The high temperature behaviour of sillimanite from the granulite terrain discerns that the hydrous species in sillimanite were incorporated much below 700°C, however, secondary hydration due to pegmatite activity, retrograde metamorphism and migmatisation is not ruled out. Thus a near anhydrous condition were probably not achieved during the granulite facies metamorphism in Eastern ghat granulite terrain.     

Preservation of Permo–Triassic low-pressure assemblages in the Cretaceous high-pressure metamorphic Saualpe crystalline basement (Eastern Alps, Austria)

Metapelites and intercalated metapegmatites of the Saualpe crystalline basement, which forms part of the Austroalpine nappe complex in the Eastern Alps, display a polyphase tectonometamorphic history. Here, we focus on the evolution that these rocks underwent prior to Cretaceous (eo‐Alpine) high‐pressure metamorphism and related penetrative deformation. Geothermobarometry on coarse‐grained porphyroclastic parageneses (garnet–biotite–muscovite–plagioclase–sillimanite–quartz), which occur as relics in kyanite–garnet, two‐mica gneiss, yielded 600 °C/0.4 GPa. Results from a corundum‐bearing lithology suggest that higher temperatures may have been reached in very restricted areas. The matrix of these rocks displays intense recrystallization during a pressure‐dominated metamorphic overprint. Microstructures and mineral chemistry indicate that this low‐pressure metamorphism was the first significant metamorphic imprint in these rocks. Mineral relics in all metapelitic rock types reflect low‐pressure conditions for this interkinematic crystallization phase. The distribution, macroscopic and microscopic observations and the mineralogical composition of intercalated metapegmatites point to regionally elevated temperature conditions during their emplacement. Therefore, pegmatite formation is correlated with mineral formation in metapelites. Sm–Nd‐dating of magmatic garnet from the pegmatite gneiss yielded 249 ± 3 Ma, which is interpreted to represent the age of pegmatite‐emplacement and low‐pressure metamorphism in the metapelites. Since the pegmatites are overprinted by mylonitisation and high‐pressure metamorphism, this Permo–Triassic age also sets an upper age‐limit to the eclogite facies metamorphic event, which affected considerable parts of the Saualpe crystalline basement.     

Corundum + quartz and Mg-staurolite bearing granulite from the Limpopo Belt, southern Africa: Implications for a P–T path

A new occurrence of the rare corundum + quartz assemblage and magnesian staurolite has been found in a gedrite–garnet rock from the Central Zone of the Neoarchean Limpopo Belt in Zimbabwe. Poikiloblastic garnet in the sample contains numerous inclusions of corundum + quartz ± sillimanite, magnesian staurolite + sapphirine ± orthopyroxene, and sapphirine + sillimanite assemblages, as well as monophase inclusions. Corundum, often containing subhedral to rounded quartz, occurs as subhedral to euhedral inclusions in the garnet. Quartz and corundum occur in direct grain contact with no evidence of a reaction texture. The textures and Fe–Mg ratios of staurolite inclusions and the host garnet suggest a prograde dehydration reaction of St → Grt + Crn + Qtz + H₂O to give the corundum + quartz assemblage. Peak conditions of 890–930 °C at 9–10 kbar are obtained from orthopyroxene + sapphirine and garnet + staurolite assemblages. A clockwise P–T path is inferred, with peak conditions being followed by retrograde conditions of 4–6 kbar and 500–570 °C. The presence of unusually magnesian staurolite (Mg / [Fe + Mg] = 0.47–0.53) and corundum + garnet assemblages provides evidence for early high-pressure metamorphism in the Central Zone, possibly close to eclogite facies. The prograde high-pressure event followed by high- to ultrahigh-temperature metamorphism and rapid uplifting of the Limpopo Belt could have occurred as a result of Neoarchean collisional orogeny involving the Zimbabwe and Kaapvaal Cratons.     

Three-stage metamorphic history of a whiteschist from Sar e Sang,Afghanistan, as part of a former evaporite deposit

Small volumes (in the cm³ range) of a talc-kyanite schist exhibit mosaic equilibria characterized by mineral assemblages conventionally attributed to vastly different pressure temperature conditions of metamorphism. On the basis of petrographic and microprobe studies these assemblages are attributed to three consecutive stages of metamorphism of a chemically exceptional rock composition falling largely into the model system MgO-Al₂O₃-SiO₂-H₂O. Stage 1 typified by Mg chlorite-quartz-talc and some paragonite was followed during stage 2 by talc-kyanite, Mg gedrite-quartz, and the growth of large dravites. In stage 3 pure Mg cordierite formed with or without corundum and/or talc, and kyanite was partly converted into sillimanite. Pressures and temperature during this final stage of metamorphism were probably near 5–6 kb, 640 ° C. The preservation of this succession of mineral assemblages related to each other through isochemical reactions suggests that the main factors governing the metamorphic history of this whitheschist were compositional changes of the coexisting fluids with time, whereas pressure temperature variations may be subordinate. In the Sar e Sang area such chemical variations of the metamorphic fluids are probably caused by progressive metamorphism and mobilization of a former evaporite deposit. Microprobe analyses of the phases gedrite and talc indicate variable degrees of sodium incorporation into these phases according to the substitution NaAl→Si.     

Petrology of corundum-spinel-sapphirine-anorthite rocks (sakenites) from the type locality in southern Madagascar

‘Sakenites’ constitute a unique association of corundum‐, spinel‐ and sapphirine‐bearing anorthitic to phlogopitic rocks, first described in rocks from an exposure along the beds of the Sakena river to the NW of Ihosy, south Madagascar. The exposure has been revisited and subjected to a detailed petrological and geochemical study. The aluminous anorthitic rocks occur as boudinaged bands and lenses, closely associated with corundum‐, spinel‐ and sapphirine‐bearing phlogopitites, diverse calcsilicate rocks and marbles within a series of biotite‐sillimanite‐cordierite gneisses of the Ihosy granulite unit in the NW of the Pan‐African Bongolava‐Ranotsara shear zone. Bimineralic anorthite + corundum domains preserve the earliest record of a polyphasic evolutionary history that includes two distinct metasomatic episodes. Probable protoliths of these bimineralic rocks were kaolinite‐rich sediments or calcareous bauxites that were altered by Ca or Si infiltration‐metasomatism prior to or coeval with the development of the anorthite‐corundum assemblage. P–T pseudosection modelling of metapelitic gneisses suggests peak‐conditions around 800 °C and 6–7 kbar for the regional high‐grade metamorphism and deformation in the NW part of the Bongolava‐Ranotsara shear zone. The well‐annealed granoblastic‐polygonal textures indicate complete chemical and textural re‐equilibration of the foliated bimineralic rocks during this event. Subsequently, at somewhat lower P–T conditions (750–700 °C, 6 kbar), the influx of Mg‐, Si‐ and K‐bearing fluids into the anorthite‐corundum rocks caused significant metasomatic changes. In zones infiltrated by ‘primary’ potassic fluids, the bimineralic assemblage was completely replaced by phlogopite and Mg‐Al minerals, thereby producing corundum‐, spinel‐ and sapphirine‐bearing phlogopitites. Further advance of the resulting ‘residual’ Mg‐ and Si‐bearing fluids into anorthite‐corundum domains led to partial to complete replacement of corundum porphyroblasts by spinel, spinel + sapphirine or sapphirine, depending on the activities of the solutes. The static textures developed during this second metasomatic episode suggest fluid influx subsequent to intense ductile deformation in the Bongolava‐Ranotsara ductile shear zone c. 530–500 Ma ago.     

大陆碰撞过程中的巴罗式变质作用及原地深熔作用:以南阿尔金为例

南阿尔金吐拉地区所出露的变质泥质岩和变质基性岩普遍经历了中压麻粒岩相变质作用,其中变泥质岩以出现石榴子石+夕线石+长石+黑云母+石英为特征,而基性麻粒岩则以石榴子石+单斜辉石+紫苏辉石+斜长石+石英为特征,具有典型中压相系的麻粒岩相变质作用矿物组合,即显示"巴罗式"变质作用特征。野外宏观特征显示这套变泥质岩普遍经历了原地深熔作用,并局部发生混合岩化作用。岩相学观察结果显示泥质片麻岩保留了关键的深熔作用显微结构证据:(1)石榴子石内部发育有钾长石、石英和斜长石组成的矿物集合体,可能代表了早期熔体的假象;(2)黑云母颗粒边界发育尖锐的、不规则的微斜长石,而且黑云母边界溶蚀明显,形成锯齿状不规则的边界,指示深熔作用可能与黑云母的分解密切相关,即黑云母可能为深熔作用的主要反应相;(3)石英、斜长石或石榴子石颗粒边界发育圆珠状不规则的钾长石,而且颗粒边界或三联点中尖锐状钾长石与周围矿物的形成较小的二面角,有些甚至相互连通呈网络状,这也与它们继承了熔体结构特征一致;(4)不规则钾长石(或微斜长石)分布在石榴子石和夕线石附近,指示石榴子石和夕线石可能为深熔作用的残留相。锆石U-Pb定年结果显示麻粒岩相变质作用和相关深熔作用时代基本一致,主要发生在~450Ma。因此,吐拉地区的中压麻粒岩相变质作用和深熔作用明显要晚于南阿尔金地区榴辉岩和高压麻粒岩的峰期变质时代40~50Myr,而是与榴辉岩折返过程中麻粒岩相叠加变质作用的时代较为接近。但南阿尔金~450Ma的变质作用、深熔作用和岩浆作用是否为独立的构造热事件抑或深俯冲板片折返阶段的产物,这还需要今后进一步的工作验证。