An excursion to the Bayuda volcanic field of Northern Sudan

A cluster of well-preserved recent volcanoes in the northern Bayuda Desert make up a more or less continuous field some 520 km² in area surrounded by a number of isolated centres of eruption. The volcanoes are numerous but small; up to 400 m in height and 0.35 km² in volume. Most of them are simple composite volcanoes with a pyroclastic cone skirted by a small lava field erupted from the same vent after explosive eruptions had ceased. In a few instances, however, the cone was eviscerated by more violent eruptions, leaving a deep explosion crater. The lavas are all nepheline-normative alkali basalts and contain a variety of xenocrysts and xenoliths from at least three different sources. The distribution of the recent volcanoes was partly controlled by large granitic ring-intrusions of the Basement Complex country rocks. These intrusions belong to the Younger Granite association of late Precambrian or Lower Palaeozoic age and represent a volcanic-intrusive episode widespread in northern Africa. The complexes are composed of cale-alkaline and peralkaline granites and syenites and a related plexus of dyke swarms.     

The Nevados de Payachata volcanic region (18°S/69°W,N. Chile)

Subduction-related volcanism in the Nevados de Payachata region of the Central Andes at 18°S comprises two temporally and geochemically distinct phases. An older period of magmatism is represented by glaciated stratocones and ignimbrite sheets of late Miocene age. The Pleistocene to Recent phase (0.3 Ma) includes the twin stratovolcanoes Volcan Pomerape and Volcan Parinacota (the Nevados de Payachata volcanic group) and two small centers to the west (i. e., Caquena and Vilacollo). Both stratovolcanoes consist of an older dome-and-flow series capped by an andesitic cone. The younger cone, i. e., V. Parinacota, suffered a postglacial cone collapse producing a widespread debris-avalanche deposit. Subsequently, the cone reformed during a brief, second volcanic episode. A number of small, relatively mafic, satellitic cinder cones and associated flows were produced during the most recent activity at V. Parinacota. At the older cone, i. e., V. Pomerape, an early dome sequence with an overlying isolated mafic spatter cone and the cone-forming andesitic-dacitic phase (mostly flows) have been recognized. The two Nevados de Payachata stratovolcanoes display continuous major- and trace-element trends from high-K₂O basaltic andesites through rhyolites (53%–76% SiO₂) that are well defined and distinct from those of the older volcanic centers. Petrography, chemical composition, and eruptive styles at V. Parinacota differ between pre- and post-debris-avalanche lavas. Precollapse flows have abundant amphibole (at SiO₂ > 59 wt%) and lower Mg numbers than postcollapse lavas, which are generally less silicic and more restricted in composition. Compositional variations indicate that the magmas of the Nevados de Payachata volcanic group evolved through a combination of fractional crystallization, crustal assimilation, and intratrend magma mixing. Isotope compositions exhibit only minor variations. Pb-isotope ratios are relatively low (²⁰⁶Pb/²⁰⁴Pb = 17.95–18.20 and²⁰⁸Pb/²⁰⁴Pb = 38.2–38.5);⁸⁷Sr/⁸⁶Sr ratios range 0.70612–0.70707,¹⁴³Nd/¹⁴⁴Nd ratios range 0.51238–0.51230, and ¹⁸O_SMOW values range from + 6.8%_o to + 7.6%_o SMOW. A comparison with other Central Volcanic Zone centers shows that the Nevados de Payachata magmas are unusually rich in Ba (up to 1800 ppm) and Sr (up to 1700 ppm) and thus represent an unusual chemical signature in the Andean arc. These chemical and isotope variations suggest a complex petrogenetic evolution involving at least three distinct components. Primary mantle-derived melts, which are similar to those generated by subduction processes throughout the Andean arc, are modified by deep crustal interactions to produce magmas that are parental to those erupted at the surface. These magmas subsequently evolve at shallower levels through assimilation-crystallization processes involving upper crust and intratrend magma mixing which in both cases were restricted to end members of low isotopic contrast.     

Physical-chemical conditions of the Teide volcanic system (Tenerife, Canary Islands)

The Teide volcano (3717 m) is the central structure of the island of Tenerife and at present its morphology is that of a stratovolcano which has grown on a large caldera with a collapse 17 km in diameter, which was generated some 0.6 million years ago.The different studies that have been carried out seem to indicate that, in a oversimplified model, there is an intermediate magma chamber with an approximate volume of 30 km³ and located 2–3 km below the actual base of the caldera, i.e., almost at sea level, with a temperature of 430 ± 50°C, and a pressure of 400 ± 100 bar.The summit fumarole emissions are 85°C and are formed mainly of CO₂ with small amounts of sulphur species, H₂, CH₄ and He. The water vapor (68–82%) emitted with the gases comes from the vaporization of a perched aquifer in the upper cone, as shown by the isotopic analyses.     

Surface exposure dating of Holocene basalt flows and cinder cones in the Kula volcanic field (Western Turkey) using cosmogenic 3He and 10Be

The Kula volcanic field in Western Turkey comprises about 80 cinder cones and associated basaltic lava flows of Quaternary age. Based on geomorphological criteria and K-Ar dating, three eruption phases, β2–β4, were distinguished in previous studies. Human footprints in ash deposits document that the early inhabitants of Anatolia were affected by the volcanic eruptions, but the age of the footprints has been poorly constrained. Here we use ³He and ¹⁰Be exposure dating of olivine phenocrysts and quartz-bearing xenoliths to determine the age of the youngest lava flows and cinder cones. In the western part of the volcanic field, two basalt samples from a 15-km-long block lava flow yielded ³He ages of 1.5 ± 0.3 ka and 2.5 ± 0.4 ka, respectively, with the latter being in good agreement with a ¹⁰Be age of 2.4 ± 0.3 ka for an augen gneiss xenolith from the same flow. A few kilometers farther north, a metasedimentary xenolith from the top of the cinder cone Çakallar Tepe gave a ¹⁰Be age of 11.2 ± 1.1 ka, which dates the last eruption of this cone and also the human footprints in the related ash deposits. In the center of the volcanic field, a basalt sample and a metasedimentary xenolith from another cinder cone gave consistent ³He and ¹⁰Be ages of 2.6 ± 0.4 ka and 2.6 ± 0.3 ka, respectively. Two β4 lava flows in the central and eastern part of the volcanic province yielded ³He ages of 3.3 ± 0.4 ka and 0.9 ± 0.2 ka, respectively. Finally, a relatively well-preserved β3 flow gave a ³He age of ∼13 ka. Taken together, our results demonstrate that the penultimate eruption phase β3 in the Kula volcanic field continued until ∼11 ka, whereas the youngest phase β4 started less than four thousand years ago and may continue in the future.     

The volcanic and magmatic evolution of Volcán Ollagüe, a high-K, late quaternary stratovolcano in the Andean Central Volcanic Zone

Volcán Ollagüe is a high-K, calc-alkaline composite volcano constructed upon extremely thick crust in the Andean Central Volcanic Zone. Volcanic activity commenced with the construction of an andesitic to dacitic composite cone composed of numerous lava flows and pyroclastic deposits of the Vinta Loma series and an overlying coalescing dome and coulée sequence of the Chasca Orkho series. Following cone construction, the upper western flank of Ollagüe collapsed toward the west leaving a collapse-amphitheater about 3.5 km in diameter and a debris avalanche deposit on the lower western flank of the volcano. The deposit is similar to the debris avalanche deposit produced during the May 18, 1980 eruption of Mount St. Helens, U.S.A., and was probably formed in a similar manner. It presently covers an area of 100 km² and extends 16 km from the summit. Subsequent to the collapse event, the upper western flank was reformed via eruption of several small andesitic lava flows from vents located near the western summit and growth of an andesitic dome within the collapse-amphitheater. Additional post-collapse activity included construction of a dacitic dome and coulée of the La Celosa series on the northwest flank. Field relations indicate that vents for the Vinta Loma and post-collapse series were located at or near the summit of the cone. The Vinta Loma series is characterized by an anhydrous, two-pyroxene assemblage. Vents for the La Celosa and Chasca Orkho series are located on the flanks and strike N55 W, radial to the volcano. The pattern of flank eruptions coincides with the distribution in the abundance of amphibole and biotite as the main mafic phenocryst phases in the rocks. A possible explanation for this coincidence is that an unexposed fracture or fault beneath the volcano served as a conduit for both magma ascent and groundwater circulation. In addition to the lava flows at Ollagüe, magmas are also present as blobs of vesiculated basaltic andesite and mafic andesite that occur as inclusions in nearly all of the lavas. All eruptive activity at Ollagüe predates the last glacial episode ( 11.000 a B.P.), because post-collapse lava flows are overlain by moraine and are incised by glacial valleys. Present activity is restricted to emission of a persistent, 100-m-high fumarolic steam plume from a vent located within the summit andesite dome.Sr and Nd isotope ratios for the basaltic andesite and mafic andesite inclusions and lavas suggest that they have assimilated large amounts of crust during crystal fractionation. In contrast, narrow ranges in ¹⁴³Nd/¹⁴⁴Nd and ⁸⁷Sr/⁸⁶Sr in the andesitic and dacitic lavas are enigmatic with respect to crustal contamination.     

Caldera formation at Volcán Colima, Mexico, by a large large holocene volcanic debris avalanche

About 4,300 years ago, 10 km³ of the upper cone of ancestral Volcán Colima collapsed to the southwest leaving a horseshoe-shaped caldera 4 km in diameter. The collapse produced a massive volcanic debris avalanche deposit covering over 1550 km² on the southern flanks of the volcano and extending at least 70 km from the former summit. The avalanche followed a steep topographic gradient unobstructed by barriers, resulting in an unusually high area/volume ratio for the Colima deposit. The apparent coefficient of friction (fall height/distance traveled) for the Colima avalanche is 0.06, a low value similar to those of other large-volume deposits. The debris avalanche deposit contains 40–75% angular volcanic clasts from the ancestral cone, a small proportion of vesicular blocks that may be juvenile, and in distal exposures, rare carbonate clasts plucked from the underlying surface by the moving avalanche. Clasts range in size to over 20 m in diameter and are brecciated to different degrees, pulverized, and surrounded by a rock-flour matrix. The upper surface of the deposit shows prominent hummocky topography with closed depressions and surface boulders. A thick, coarse-grained, compositionally zoned scoria-fall layer on the upper northeastern slope of the volcano may have erupted at the time of collapse. A fine-grained surge layer is present beneath the avalanche deposit at one locality, apparently representing an initial blast event. Most of the missing volume of the ancestral volcano has since been restored at an average rate of 0.002 km³/yr through repeated eruptions from the post-caldera cone. As a result, the southern slope of Volcán Colima may again be susceptible to collapse. Over 200,000 people are now living on primary or secondary deposits of the debris avalanche, and a repetition of this event would constitute a volcanic disaster of great magnitude.Ancestral Volcán Colima grew on the southern, trenchward flank of the earlier and larger volcano Nevado de Colima. Trenchward collapse was favored by the buttressing effect of Nevado, the rapid elevation drop to the south, and the intrusion of magma into the southern flank of the ancestral volcano. Other such trenchward-younging, paired volcanoes are known from Mexico, Guatemala, El Salvador, Chile, and Japan. The trenchward slopes of the younger cones are common sites for cone collapse to form avalanche deposits, as occurred at Colima and Popocatepetl in Mexico and at San Pedro Volcano in Chile.     

A methodology for the evaluation of long-term volcanic risk from pyroclastic flows in Campi Flegrei (Italy)

The volcanological history of Campi Flegrei suggests that the most frequent eruptions are characterized by the emplacement of pyroclastic flow and surge deposits erupted from different vents scattered over a 150-km² caldera. The evaluation of volcanic risk in volcanic fields is complex because of the lack of a central vent. To approach this problem, we subdivided the entire area of Campi Flegrei into a regular grid and evaluated the relative spatial probability of opening of vents based on geological, geophysical and geochemical data. We evaluated the volcanic risk caused by pyroclastic flows based on the formula proposed by UNESCO (1972), R=H×V×Va, where H is the hazard, V is the vulnerability and Va is the value of the elements at risk. The product H×V was obtained by performing simulations of type eruptions centered in each cell of the grid. The simulation is based on the energy cone scheme proposed by Sheridan and Malin [J. Volcanol. Geotherm. Res. 17 (1983) 187–202], hypothesizing a column collapse height of 100 m for eruptions of VEI=3 and 300 m for eruptions of VEI=4 with a slope angle of 6°. Each simulation has been given the relative probability value associated with the corresponding cell. We made use of the GIS software ArcView 3.2 to evaluate the intersection between the energy cone and the topography. The superposition of the areas invaded by pyroclastic flows (124 simulations for VEI=3 and 37 for VEI=4) was used to obtain the relative hazard map of the area. The relative volcanic risk map is obtained by superimposing the urbanization maps.     

Chemical evolution and volcanic activity of the active crater lake of Poás volcano, Costa Rica, 1993–1997

Concentrations of chloride and sulfate and pH in the hot crater lake (Laguna Caliente) at Poás volcano and in acid rain varied over the period 1993–1997. These parameters are related to changes in lake volume and temperature, and changes in summit seismicity and fumarole activity beneath the active crater. During this period, lake level increased from near zero to its highest level since 1953, lake temperature declined from a maximum value of 70°C to a minimum value of 25°C, and pH of the lake water increased from near zero to 1.8. In May 1993 when the lake was nearly dry, chloride and sulfate concentrations in the lake water reached 85,400 and 91,000 mg l⁻¹, respectively. Minimum concentrations of chloride and sulfate after the lake refilled to its maximum volume were 2630 and 4060 mg l⁻¹, respectively. Between January 1993 and May 1995, most fumarolic activity was focused through the bottom of the lake. After May 1995, fumarolic discharge through the bottom of the lake declined and reappeared outside the lake within the main crater area. The appearance of new fumaroles on the composite pyroclastic cone coincided with a dramatic decrease in type B seismicity after January 1996. Between May 1995 and December 1997, enhanced periods of type A seismicity and episodes of harmonic tremor were associated with an increase in the number of fumaroles and the intensity of degassing on the composite pyroclastic cone adjacent to the crater lake. Increases in summit seismic activity (type A, B and harmonic tremor) and in the height of eruption plumes through the lake bottom are associated with a period of enhanced volcanic activity during April–September 1994. At this time, visual observations and remote fumarole temperature measurements suggest an increase in the flux of heat and gases discharged through the bottom of the crater lake, possibly related to renewed magma ascent beneath the active crater. A similar period of enhanced seismic activity that occurred between August 1995 and January 1996, apparently caused fracturing of sealed fumarole conduits beneath the composite pyroclastic cone allowing the focus of fumarolic degassing to migrate from beneath the lake back to the 1953–1955 cone. Changes in the chemistry of summit acid rain are correlated changes in volcanic activity regardless of whether fumaroles are discharging into the lake or are discharging directly into the atmosphere.     

Recent geophysical investigation at Somma-Vesuvio volcanic complex

Activity at Somma-Vesuvio volcanic area in southern Italy is monitored by seismic stations and periodic geodetic and gravity surveys. The seismic network, which consists at present of four vertical stations and one three-component station, recorded an increase in earthquake activity in 1978 and between November 1988 and March 1989. During the later activity, earthquakes were located in a cluster about 3 km beneath the summit of the volcano. Two tide gauges, two tiltmeters and a recording gravimeter are also operating at Somma-Vesuvio. Yearly levelling surveys are conducted along several closed routes that extend from as much as 6 km from the base of the volcano to the summit area. Survey results reveal no significant ground movement since 1959, except for a slight subsidence around the rim of the summit crater. Gravity changes have been larger than the expected 10 μGal uncertainty of the measurements. The lack of contemporary elevation changes implies that the observed gravity changes are the result of a slight change in density structure. The cone of Somma-Vesuvio has been very stable for the last few decades, showing no indications of a buildup to activity. The lack of surface movement should rule out a magma-supply rate to this volcano at the historic eruptive rate of 0.002 km³/yr.     

Jom-Bolok Holocene volcanic field in the East Sayan Mts., Siberia,Russia: structure,style of eruptions,magma compositions,and radiocarbon dating

Jom-Bolok volcanic field is located in the East Sayan Mts. of Siberia (Russia), a portion of the Asian convergent zone. It is located at the boundary of the Riphean Tuva-Mongolia massif, which was probably reactivated because of the interplay between far-field tectonic stress derived from the India–Asia collision zone and extension in the south-western Baikal rift system. The volcanic field comprises a number of hawaiitic lava flows, of various lengths, which flowed down paleorivers. Flows were fed by fissure eruptions and the largest lava flow field was dated as 7,130?±?140 cal ¹⁴C years BP using a buried organic sample found inside the associated cinder cone. This lava flow field is about 70 km long, ～100 km² in area, and 7.9 km³ in volume. The area and volume of this flow field ranks this eruption highly in the global record of fissure-fed effusive eruptions. This lava flow field makes up 97% of the entire Jom-Bolok volcanic field, a fact which raises a puzzling question: why and/or how did a relatively small-volume volcanic field produce such a large-volume individual eruption? A working hypothesis is that a pond of sublithospheric melt accumulated over a relatively prolonged period. This was then rapidly drained in response of tectonic changes triggered by unloading of ice in the Early Holocene.     

New radiometric and petrological constraints on the evolution of the Pichincha volcanic complex (Ecuador)

Fieldwork, radiometric (⁴⁰Ar/³⁹Ar and ¹⁴C) ages and whole-rock geochemistry allow a reconstruction of eruptive stages at the active, mainly dacitic, Pichincha Volcanic Complex (PVC), whose eruptions have repeatedly threatened Quito, most recently from 1999 to 2001. After the emplacement of basal lavas dated at ∼1100 to 900 ka, the eruptive activity of the old Rucu Pichincha volcano lasted from ∼850 ka to ∼150 ka before present (BP) and resulted in a 15 × 20 km-wide edifice, which comprises three main building stages: (1) A lower stratocone (Lower Rucu, ∼160 km³ in volume) developed from ∼850 to 600 ka; (2) This edifice was capped by a steeper-sided and less voluminous cone (the Upper Rucu, 40–50 km³), the history of which started 450–430 ka ago and ended around 250 ka with a sector collapse; (3) A smaller (8–10 km³) but more explosive edifice grew in the avalanche amphitheatre and ended Rucu Pichincha's history about 150 ka ago. The Guagua Pichincha volcano (GGP) was developed from 60 ka on the western flank of Rucu with four growth stages separated by major catastrophic events. (1) From ∼60 to 47 ka, a basal effusive stratocone developed, terminating with a large ash-and-pumice flow event. (2) This basal volcano was followed by a long-lasting dome building stage and related explosive episodes, the latter occurring between 28–30 and 22–23 ka. These first two stages formed the main GGP (∼30 km³), a large part of which was removed by a major collapse 11 ka BP. (3) Sustained explosive activity and viscous lava extrusions gave rise to a new edifice, Toaza (4–5 km³ in volume), which in turn collapsed around 4 ka BP. (4) The ensuing amphitheatre was partly filled by the ∼1-km³ Cristal dome, which is the historically active centre of the Pichincha complex. The average output rate for the whole PVC is 0.29 km³/ka. Nevertheless, the chronostratigraphic resolution we obtained for Lower Rucu Pichincha and for the two main edifices of Guagua Pichincha (main GGP and Toaza), leads to eruptive rates of 0.60–0.65 km³/ka during these construction stages. These output rates are compared to those of other mainly dacitic volcanoes from continental arcs. Our study also supports an overall SiO₂ and large-ion lithophile elements enrichment as the PVC develops. In particular, distinctive geochemical signatures indicate the involvement of a new magma batch at the transition between Rucu and Guagua. At the GGP, the same phenomenon occurs at each major collapse event marking the onset of the ensuing magmatic stage. Since the 11-ka-BP collapse event, this magmatic behaviour has led to increasingly explosive activity. Four explosive cycles of between 100 and 200 years long have taken place at the Cristal dome in the past 3.7 ka, and repose intervals between these cycles have tended to decrease with time. As a consequence, we suggest that the 1999–2001 eruptive period may have initiated a new eruptive cycle that might pose a future hazard to Quito (∼2 million inhabitants).     

The origin ofBe in island-arc volcanic rocks

The presence of cosmogenic¹⁰Be (t_1/2 = 1.5 × 10⁶ y) in island-arc volcanic rocks has been interpreted as indicating that sediments are subducted to the depths of island-arc magma genesis [1,2]. We have measured¹⁰Be and⁹Be (the stable common isotope) in phenocryst and groundmass fractions separated from four Aleutian volcanic rocks.¹⁰Be and⁹Be covary linearly in three of the rocks proving that the¹⁰Be was incorporated prior to the formation of phenocrysts. In the other rock¹⁰Be and⁹Be do not covary; the lack of covariation indicates either that the rock incorporated¹⁰Be during weathering or that⁹Be-rich xenocrysts were incorporated by mechanical mixing. Our results strongly support the hypothesis of Brown et al. [1] and Tera et al. [2] that sediments containing¹⁰Be are an integral part of island-arc magmatic systems. As we cannot identify the depth at which the¹⁰Be was incorporated we still cannot completely rule out the possibility of assimilation of sediments or altered crust near the Earth's surface as a source of¹⁰Be.     

The exceptional activity and growth of the Southeast Crater, Mount Etna (Italy), between 1996 and 2001

Between 1971 and 2001, the Southeast Crater was the most productive of the four summit craters of Mount Etna, with activity that can be compared, on a global scale, to the opening phases of the Pu‘u ‘Ō‘ō-Kūpaianaha eruption of Kīlauea volcano, Hawai‘i. The period of highest eruptive rate was between 1996 and 2001, when near-continuous activity occurred in five phases. These were characterized by a wide range of eruptive styles and intensities from quiet, non-explosive lava emission to brief, violent lava-fountaining episodes. Much of the cone growth occurred during these fountaining episodes, totaling 105 events. Many showed complex dynamics such as different eruptive styles at multiple vents, and resulted in the growth of minor edifices on the flanks of the Southeast Crater cone. Small pyroclastic flows were produced during some of the eruptive episodes, when oblique tephra jets showered the steep flanks of the cone with hot bombs and scoriae. Fluctuations in the eruptive style and eruption rates were controlled by a complex interplay between changes in the conduit geometry (including the growth of a shallow magma reservoir under the Southeast Crater), magma supply rates, and flank instability. During this period, volume calculations were made with the aid of GIS and image analysis of video footage obtained by a monitoring telecamera. Between 1996 and 2001, the bulk volume of the cone increased by ~36×10⁶ m³, giving a total (1971–2001) volume of ~72×10⁶ m³. At the same time, the cone gained ~105 m in height, reaching an elevation of about 3,300 m. The total DRE volume of the 1996–2001 products was ~90×10⁶m³. This mostly comprised lava flows (72×10⁶ m³) erupted at the summit and onto the flanks of the cone. These values indicate that the productivity of the Southeast Crater increased fourfold during 1996–2001 with respect to the previous 25 years, coinciding with a general increase in the eruptive output rates and eruption intensity at Etna. This phase of intense summit activity has been followed, since the summer of 2001, by a period of increased structural instability of the volcano, marked by a series of important flank eruptions.     

Diffuse volcanic degassing and thermal energy release from Hengill volcanic system, Iceland

We report the first detailed study of spatial variations on the diffuse emission of carbon dioxide (CO₂) and hydrogen sulfide (H₂S) from Hengill volcanic system, Iceland. Soil CO₂ and H₂S efflux measurements were performed at 752 sampling sites and ranged from nondetectable to 17,666 and 722?g?m^?2?day^?1, respectively. The soil temperature was measured at each sampling site and used to evaluate the heat flow. The chemical composition of soil gases sampled at selected sampling sites during this study shows they result from a mixing process between deep volcanic/hydrothermal component and air. Most of the diffuse CO₂ degassing is observed close to areas where active thermal manifestations occur, northeast flank of the Hengill central volcano close to the Nesjavellir power plant, suggesting a diffuse degassing structure with a SSW?CNNE trend, overlapping main fissure zone and indicating a structural control of the degassing process. On the other hand, H₂S efflux values are in general very low or negligible along the study area, except those observed at the northeast flank of the Hengill central volcano, where anomalously high CO₂ efflux and soil temperatures were also measured. The total diffuse CO₂ emission estimated for this volcanic system was about 1,526?±?160?t?day^?1 of which 453?t?day^?1 (29.7?%) are of volcanic/hydrothermal origin. To calculate the steam discharge associated with the volcanic/hydrothermal CO₂ output, we used the average H₂O/CO₂ mass ratio from 12 fumarole samples equal to 88.6 (range, 9.4?C240.2) as a representative value of the H₂O/CO₂ mass ratios for Hengill fumarole steam. The resulting estimate of the steam flow associated with the gas flux is equal to 40,154?t?day^?1. The condensation of this steam results in thermal energy release for Helgill volcanic system of 1.07?×?10¹⁴?J?day^?1 or to a total heat flow of 1,237?MW_t.     

Fractionation of metals in volcanic emissions

The enrichment of some metals (Al, Mg, Na, K, Cu, Zn, Cd) in volcanic gases is measured by an emanation coefficient ε_x relating the amount of the element x in lavas and in aerosols.ε_x is determined in the volcanic emissions of Mount Etna (Sicily), with regard to that of²¹⁰Pb. The accuracy of the results is limited by the geochemical behavior of common lead compared to that of²¹⁰Pb. Concerning the most volatile species, it appears that practically all the volcanic aerosols are produced by evaporation followed by gas-to-particle conversion and the spattered fraction appears to be negligible.     

A 14?500 year record of the accumulation of atmospheric mercury in peat: volcanic signals, anthropogenic influences and a correlation to bromine accumulation

A 14?500 calendar year record of mercury accumulation rates has been obtained from an ombrotrophic peat bog in the Swiss Jura mountains. The range of natural (pre-industrial) mercury accumulation rates varied from 0.3 to 8.0 μg m⁻² yr⁻¹. During the Late Glacial and Holocene, climatic and volcanic signals were evident in the mercury record. Mercury accumulation rates increased by a factor of ca 5 during the Younger Dryas cold period. Short-term spikes in mercury accumulation rates, which correspond in time to known volcanic eruptions, occur during the late Boreal and Older Atlantic periods, when volcanic influences on mercury deposition appear to have been intensified due to increased atmospheric humidity. A correlation of mercury to bromine accumulation is observed throughout the pre-anthropogenic period. During the Holocene, mercury accumulation only exceeded the range of this correlation for a few short periods of elevated mercury deposition which correspond to known volcanic eruptions during the Older Atlantic. During historical times, mercury accumulation rates have exceeded the range of the correlation of mercury to bromine continuously since ca 1330 AD. This excess in mercury accumulation is interpreted as an indication of pollution. During the industrial period, mercury accumulation rates reached 107.6 μg m⁻² yr⁻¹, of which 84% was mercury that exceeded the correlation range. Mercury accumulation rates peaked again during the 1970s, with 78.8 μg m⁻² yr⁻¹. Early 20th century pollution appears to have been dominated by non-Swiss emissions from coal burning, whereas Swiss mercury emissions appear to have been the dominant pollution source during the mid and late 20th century. Current mercury accumulation rates at the site are similar to those ca 10 years ago, with modern deposition rates being ca 15 times their prehistorical average. Anthropogenic emissions of reactive brominated compounds could be contributing to increased atmospheric deposition rates of mercury.     

Radon anomalies and volcanic eruptions

A well-documented case of ²²²Rn anomaly preceding the eruptive activity of Karymsky volcano (Kamchatka) was recently reported in the literature. Stimulated by this example, we have attempted to utilize the available data on radon emanation from rocks, its solubility, and its circulation in waters to discuss how a ²²²Rn anomaly can be produced by magma approaching the surface. It is shown that the most likely process of radon release is the flushing of gases through pore fluids. Heating of extensive fracture surfaces by high-temperature gases may also be important. In order to survive in detectable amounts after moving distances greater than a few meters, radon must be transported by fast-moving fluids, such as those rising toward the surface through a fracture or in the ascending limbs of fluids convecting in very porous rocks under high temperature gradients. The pattern observed at Karymsky volcano is interpreted on the basis of these relations.     

Cone-building block-and-ash flows: the Senyama volcanic products of O’e Takayama volcano,SW Japan

The Senyama volcanic products of the late Pliocene to early Pleistocene O’e Takayama volcano overlie a 100-m-thick, late Pliocene coastal quartz-sandstone and are intruded by an early Pleistocene dacite dome. The Senyama volcanic products are the remains of a cone that retains a basal part 1.5 km across and 150–250 m high from the substrate. The cone comprises dacite block-and-ash flow deposits and minor base-surge deposits occur at the base. Single beds of the block-and-ash flow deposits are 1–16 m thick and dip inward 20–40° at the base of the cone and inward or outward 10–20° at the summit. Juvenile fragments in the block-and-ash flow deposits are non- to poorly vesicular and commonly have curviplanar surfaces and prismatic joints extending inward from the surfaces, which imply quenching and brittle fracturing of dacite lava. They are variably hydrothermally altered. Nevertheless, juvenile blocks appear to retain a uniform direction of the magnetization vector residual during thermal demagnetization between 280°C and 625°C. At the time of the eruption, the well-sorted sand of the substrate was at the coast and a good aquifer that facilitated explosive interaction of water and the ascending dacite lava. The mechanism of the explosion perhaps involved thermal contraction cracking of the dacite lava, water-inflow into the interior of the lava, and explosive expansion of the water. Initial phreatomagmatic explosions opened the vent. Succeeding phreatomagmatic or phreatomagmatic–vulcanian explosions produced block-and-ash flow deposits around the vent. Hydrothermal silver-ore deposits and manganese-oxide deposits occur in the Senyama volcanic products and the underlying sandstone, respectively. They could represent post-eruptive activity of the hydrothermal system developed in and around the cone.     

Studies of volcanic ash from two recent Central American eruptions

The 1971 eruptions of Cerro Negro volcano in Nicaragua and Fuego volcano in Guatemala produced ash blankets with minimum volumes of 7 × 10⁷ m³ and 6 × 10⁷ m³, respectively. Seven new chemical analyses show that ash produced by both eruptions was basaltic and similar to previously — erupted lavas of both volcanoes. Both ash blankets were sampled areally and stratigraphically before they were affected by rain. Chemical analyses of soluble materials leached from these ashes show that near the end of both eruptions the concentrations of soluble materials increased by about an order of magnitude. These changes are believed to reflect changes in the composition of eruptive gases.     

Holocene volcanic activity at Koniuji Island,Aleutians

Reconnaissance mapping and ⁴⁰Ar/³⁹Ar age determinations establish an eruptive chronology for Koniuji Island in the central Aleutian island arc. Koniuji is a tiny 0.95 km² island that rises only 896 ft above the Bering Sea. Previous accounts describe Koniuji as a mostly submerged, deeply eroded, dormant stratovolcano. However, new ⁴⁰Ar/³⁹Ar ages constrain the duration of subaerial eruptive activity from 15.2 to 3.1 ka. Furnace incremental heating experiments on replicate groundmass separates from two samples of a 30–50 m thick basaltic andesite flow at the southernmost point of the island gave a weighted mean ⁴⁰Ar/³⁹Ar age of 15.2 ± 5.0 (2σ). The next phase of eruptive activity includes a series of 5.8–4.6 ka basaltic andesitic to andesitic lava flows preserved along the western shoreline. The basal lavas contain numerous mafic enclaves and dioritic cumulates suggesting a major disturbance in the plumbing system during the initial stages of emplacement. The 5.8–4.6 ka lavas are truncated by an andesitic dome complex that includes hornblende-bearing domes, flows and pyroclastics which extruded into the center of the island and comprise the majority of the subaerial eruptive volume. An angular block from within the dome complex yielded ⁴⁰Ar/³⁹Ar age of 3.1 ± 1.9 ka, thereby making it one of the youngest island arc volcanics to be dated using the ⁴⁰Ar/³⁹Ar method. Overall, the ⁴⁰Ar/³⁹Ar data indicate that Koniuji is a nascent stratovolcano that has only recently emerged above sea level, not a glacially-eroded, long-lived volcanic complex like those found on many other central Aleutian Islands.