Microtextures, geochemistry and geochronology of authigenic xenotime: constraining the cementation history of a Palaeoproterozoic metasedimentary sequence

An ≈ 26 m thick unit of phosphatic sandstone and black shale (the Phosphatic Unit) in the Palaeoproterozoic Mount Barren Group of south-western Australia contains abundant authigenic xenotime crystals showing well-preserved diagenetic textures. Despite extensive regional deformation and thermal metamorphism, the peak of which occurred at ≈ 1205 Ma, the Phosphatic Unit was preserved as a low-strain envelope because of its pre-compaction carbonate and phosphate cementation. In situ U–Pb geochronology of xenotime reveals four discrete age populations at 1693 ± 4, 1645 ± 3, 1578 ± 10 and 1481 ± 21 Ma. When integrated with petrography, the age data place a timeframe on: (i) sediment deposition; (ii) phosphogenesis; (iii) diagenetic cement infilling; (iv) diagenetic pyrite formation; (v) secondary porosity generation; (vi) hydrocarbon migration; (vii) burial compaction; and (viii) hydrothermal alteration, up until peak thermal metamorphism. Xenotime growth at ≈ 1693 Ma occurred prior to compaction, whereas xenotime growth at ≈ 1645 Ma occurred during burial. Xenotime growth at ≈ 1580 Ma and at ≈ 1480 Ma appears to be the far-field record of thermotectonic events associated with intracontinental extension and magmatism recorded elsewhere in Australia. Geochemical analysis, integrated with geochronology, shows a systematic increase in MREE/HREE in xenotime crystals with decreasing age and with increasing stratigraphic depth. Coupled with a decrease in xenotime abundance and age with depth, it suggests that: (i) the main focus of porosity infilling was at the top of the Phosphatic Unit and progressed downwards over the > 200 Myr period of porosity infilling, and (ii) the changes in xenotime REE chemistry may be due to an influx of MREE from increasing amounts of dissolved apatite or changes, with respect to REE solubility, in the physiochemical nature of the fluids with burial depth.     

Uraniferous Black Shale and Related Uranium Mineralization Features in South China

: Black shales are marine sediments with argillaceous, silty and siliceous compositions and high contents of organic materials, disseminated pyrite and uranium. Uraniferous black shale has uranium content of more than 20 ppm.Black shales are widely distributed in 17 provinces or autonomous regions in northwestern and southern-central China. Their sedimentary ages are from the Sinian to the Tertiary and uraniferous black shales are mainly exposed in Yunnan, Guizhou, Sichuan, Hunan, Hubei, Jiangxi, and Zhejiang provinces and Guangxi Zhuang Autonomous Region and the economically significant uranium deposits associated with black shale occur in Hunan and Jiangxi provinces and Guangxi Zhuang Autonomous Region.Uranium mineralization associated with black shale has the following main features: (1) forming stratabound deposits; (2) controlled by structures such as interlayer and intersected faults and fractures; (3) associated with different ore-forming processes such as leaching and hydrothermal reworking; (4)     

Age constraints on felsic intrusions, metamorphism and gold mineralisation in the Palaeoproterozoic Rio Itapicuru greenstone belt, NE Bahia State, Brazil

U–Pb sensitive high resolution ion microprobe mass spectrometer (SHRIMP) ages of zircon, monazite and xenotime crystals from felsic intrusive rocks from the Rio Itapicuru greenstone belt show two development stages between 2,152 and 2,130 Ma, and between 2,130 and 2,080 Ma. The older intrusions yielded ages of 2,152±6 Ma in monazite crystals and 2,155±9 Ma in zircon crystals derived from the Trilhado granodiorite, and ages of 2,130±7 Ma and 2,128±8 Ma in zircon crystals derived from the Teofilândia tonalite. The emplacement age of the syntectonic Ambrósio dome as indicated by a 2,080±2-Ma xenotime age for a granite dyke probably marks the end of the felsic magmatism. This age shows good agreement with the Ar–Ar plateau age of 2,080±5 Ma obtained in hornblendes from an amphibolite and with a U–Pb SHRIMP age of 2,076±10 Ma in detrital zircon crystals from a quartzite, interpreted as the age of the peak of the metamorphism. The predominance of inherited zircons in the syntectonic Ambrósio dome suggests that the basement of the supracrustal rocks was composed of Archaean continental crust with components of 2,937±16, 3,111±13 and 3,162±13 Ma. Ar–Ar plateau ages of 2,050±4 Ma and 2,054±2 Ma on hydrothermal muscovite samples from the Fazenda Brasileiro gold deposit are interpreted as minimum ages for gold mineralisation and close to the true age of gold deposition. The Ar–Ar data indicate that the mineralisation must have occurred less than 30 million years after the peak of the metamorphism, or episodically between 2,080 Ma and 2,050 Ma, during uplift and exhumation of the orogen.Electronic supplementary material Supplementary material is available for this article at     

Grenvillian-aged orogenesis in the Palaeoproterozoic Gascoyne Complex, Western Australia: 1030–950 Ma reworking of the Proterozoic Capricorn Orogen

In situ SHRIMP U–Pb geochronology of monazite and xenotime in pelitic schists from the central Gascoyne Complex, Western Australia, shows that greenschist to amphibolite facies metamorphism occurred between c. 1030 and c. 990 Ma. Monazite from an undeformed rare‐element pegmatite from the same belt gives a ²⁰⁷Pb/²⁰⁶Pb age of c. 950 Ma, suggesting that peak metamorphism and deformation was followed by pegmatite intrusion and coeval granite magmatism. Metamorphism in the central Gascoyne Complex was previously interpreted as Barrovian, largely based on the identification of kyanite in peak metamorphic assemblages, and has been attributed to intense crustal shortening and substantial tectonic thickening during Palaeoproterozoic continent–continent collision. However, the stable Al₂SiO₅ polymorph has been identified in this study as andalusite rather than kyanite, and the prograde assemblages of staurolite–garnet–andalusite–biotite–muscovite–quartz indicate temperatures of 500–550 °C and pressures of 3–4 kbar. These data show that the Palaeoproterozoic Gascoyne Complex underwent an episode of Grenvillian‐aged intracontinental reworking concentrated in a NW–SE striking corridor, during the Edmundian Orogeny. Until now, the Edmundian Orogeny was thought to have involved only reactivation of structures in the Gascoyne Complex, along with deformation and very low‐ to low‐grade metamorphism of Mesoproterozoic cover rocks some time between 1070 and 755 Ma. However, we suggest that it involved regional amphibolite facies metamorphism and deformation, granite magmatism and pegmatite intrusion between c. 1030 and c. 950 Ma. Therefore, the Capricorn Orogen experienced a major phase of tectonic reworking c. 600 Myr later than previously recognized. Our results emphasize the importance of in situ geochronology integrated with petrological studies in order to link the metamorphic history of a terrane with causally related tectonic events.     

Late-orogenic Sveconorwegian massif anorthosite in the Jotun Nappe Complex,SW Norway,and causes of repeated AMCG magmatism along the Baltoscandian margin

The age and tectonometamorphic history of massif anorthosite in the Jotun Nappe Complex, SW Norway, were investigated by zircon and titanite U–Pb ID-TIMS. The anorthosite contains sparse zircons showing complex U–Pb systematics reflecting events dated at 965 ± 4 and 913 ± 2 Ma, and a pronounced Caledonian metamorphic overprint. The oldest age is interpreted as the protolith age of the massif anorthosite. We propose that the Jotun anorthosite is related to 970–960 Ma magmatism in the Western Gneiss Region and coeval, orogen-perpendicular extension. Conversely, a 930 Ma high-grade metamorphic event in the Jotun Nappe Complex and the related Lindås Nappe is likely related to formation of the autochthonous ca. 930 Ma Rogaland anorthosite complex. We suggest that the two late- to post-orogenic AMCG events reflect two instances of lithospheric foundering below the orogen separated by ca. 20–30 my. The 913 ± 2 Ma metamorphic episode appears to date a heating event restricted to the outermost edge of the Western Gneiss Region. Leucosome formation in high-grade gneisses geographically close to the Jotun anorthosite is dated at 892 ± 4 Ma and suggested to reflect CO₂-rich (?) fluid flux along shear zones.     

Thermochemistry of monazite-(La) and dissakisite-(La): implications for monazite and allanite stability in metapelites

Thermochemical properties have been either measured or estimated for synthetic monazite, LaPO₄, and dissakisite, CaLaMgAl₂(SiO₄)₃OH, the Mg-equivalent of allanite. A dissakisite formation enthalpy of ?6,976.5 ± 10.0 kJ mol^?1 was derived from high-temperature drop-solution measurements in lead borate at 975 K. A third-law entropy value of 104.9 ± 1.6 J mol^?1 K^?1 was retrieved from low-temperature heat capacity (C _p) measured on synthetic LaPO₄ with an adiabatic calorimeter in the 30–300 K range. The C _p values of lanthanum phases were measured in the 143–723 K range by differential scanning calorimetry. In this study, La(OH)₃ appeared as suitable for drop solution in lead borate and represents an attractive alternative to La₂O₃. Pseudo-sections were calculated with the THERIAK-DOMINO software using the thermochemical data retrieved here for a simplified metapelitic composition (La = ∑REE + Y) and considering monazite and Fe-free epidotes along the dissakisite-clinozoïsite join, as the only REE-bearing minerals. Calculation shows a stability window for dissakisite-clinozoïsite epidotes (T between 250 and 550°C and P between 1 and 16 kbar), included in a wide monazite field. The P–T extension of this stability window depends on the bulk-rock Ca-content. Assuming that synthetic LaPO₄ and dissakisite-(La) are good analogues of natural monazite and allanite, these results are consistent with the REE-mineralogy sequence observed in metapelites, where (1) monazite is found to be stable below 250°C, (2) around 250–450°C, depending on the pressure, allanite forms at the expense of monazite and (3) towards amphibolite conditions, monazite reappears at the expense of allanite.     

丹凤地区北部加里东期岩浆岩特征及其与铀矿化关系

丹凤地区北部加里东期岩浆岩的形成经历了挤压-过渡-拉伸3个阶段,分别形成了花岗岩体、花岗岩株和花岗伟晶岩脉,三者矿物组成、结构和构造差异性明显。岩浆运动方向是由北向南、由东向西斜向抬升,岩浆运移与结晶分异、成岩及成矿过程大致同步,铀矿化最终富集于拉伸阶段形成的黑云母花岗伟晶岩脉中,较好解释了目前落实的矿床、矿点和矿化点主要分布于花岗岩体南部花岗岩株接触带黑云母花岗伟晶岩脉中的现象,为今后该区铀矿找矿选区提供了依据。     

Conventional and in situ geochronology of the Teplá Crystalline unit, Bohemian Massif: implications for the processes involving monazite formation

The Teplá Crystalline unit (TCU), western Bohemian Massif, proves highly suitable for studying the effects of differential metamorphic reworking on the U–Th–Pb systematics in monazite, as the overprint of Variscan regional metamorphism onto high-grade Cadomian paragneisses intensifies progressively towards the northwest. Although variably hampered by scarcity, small size, and low uranium contents of monazite, isotope dilution–thermal ionisation mass spectrometry of monazite from paragneisses from the garnet, staurolite, and kyanite zones of the TCU gives a narrow ²⁰⁶Pb/²³⁸U age range from 387 to 382 Ma for Variscan peak metamorphism. These data are supported by 382–373 Ma monazite ages derived from electron microprobe analyses. Inheritance of older components in grains from the central TCU imply major “resetting” of pre-Variscan monazite around 380 Ma, possibly due to widespread garnet growth during Variscan metamorphism, which led to the consumption of pre-Variscan high-Y monazite and subsequent growth of new low-Y monazite. Concordant 498–494 Ma monazite ages in a migmatitic paragneiss close to the adjacent Mariánské Lázně Complex (MLC) grew in response to metagabbro emplacement in the MLC from 503 to 496 Ma and not during either Cadomian or Variscan regional metamorphism. Backscatter imaging and electron microprobe analyses reveal that discordant monazite of the migmatite comprises a mix of various age domains that range from ca. 540 to 380 Ma. Combined evidence presented here suggests that instead of Pb loss by volume diffusion, the apparent resetting of the U–Th–Pb systematics in monazite rather involves new crystal growth or regrowth by recrystallisation and dissolution/reprecipitation.     

查干诺尔盆地构造演化与铀成矿作用关系

本文着重从盆地构造演化这一角度出发，论述了盆地构造演化对盆地结构、沉积充填序列、水文条件、铀活化迁移等与盆地铀矿化作用关系密切的因素的控制作用，认为盆地构造为查干诺尔盆地铀矿化作用创造了有利的条件，控制了查干诺尔盆地铀矿化的成因类型、分布范围及矿化程度。受盆地构造演化特征的影响，盆地内铀矿化存在两种类型，即潜水氧化带型和局部性层间氧化带型。     

U–Pb zircon dating of post-obduction volcanic-arc granitoids and a granulite-facies xenolith from New Caledonia. Inference on Southwest Pacific geodynamic models

In New Caledonia, the occurrence of one of the World’s largest and best-exposed subduction/obduction complex is a key point for the understanding of the geodynamic evolution of the whole Southwest Pacific region. Within the ophiolite, pre-and post-obduction granitoids intrude the ultramafic allochthon and provide new time constraints for the understanding of obduction processes. At 27.4 Ma, a new East-dipping subduction generated the active margin magmatism along the western coast of the island (Saint-Louis massif). At 24.3 Ma, the eastward shift of the magma activity and slightly different geochemical features (Koum-Borindi massif) was either related to the older slab break-off; or alternatively, due to the eastward migration of the mantle wedge following the collision of the eastern margin of the Low Howe rise. Finally, the occurrence of a granulite-facies xenolith in the Koum-Borindi massif with comparable 24.5 Ma U–Pb zircon age and isotopic features (initial ε_Nd = 5.1) suggests that these evolved magmas were generated within the lithospheric mantle beneath a continental crust of normal thickness. Geochronological evidence for continuous convergence during the Oligocene infers an East-dipping Eocene-Oligocene subduction/obduction system to have existed in the Southwest Pacific from the d’Entrecasteaux zone to the North Island of New Zealand.     

990 and 1100 Ma Grenvillian tectonothermal events in the northern Oaxacan Complex, southern Mexico: roots of an orogen

Inliers of 1.0–1.3 Ga rocks occur throughout Mexico and form the basement of the Oaxaquia microcontinent. In the northern part of the largest inlier in southern Mexico, rocks of the Oaxacan Complex consist of the following structural sequence of units (from bottom to top), which protolith ages are: (1) Huitzo unit: a 1012±12 Ma anorthosite–mangerite–charnockite–granite (AMCG) suite; (2) El Catrı́n unit: ≥1350 Ma orthogneiss migmatized at 1106±6 Ma; and (3) El Marquez unit: ≥1140 Ma para- and orthogneisses. These rocks were affected by two major tectonothermal events that are dated using U–Pb isotopic analyses of zircon: (a) the 1106±6 Ma Olmecan event produced a migmatitic or metamorphic differentiation banding folded by isoclinal folds; and (b) the 1004–978±3 Ma Zapotecan event produced at least two sets of structures: (Z1) recumbent, isoclinal, Class 1C/3 folds with gently NW-plunging fold axes that are parallel to mineral and stretched quartz lineations under granulite facies metamorphism; and (Z2) tight, upright, subhorizontal WNW- to NNE-trending folds accompanied by development of brown hornblende at upper amphibolite facies metamorphic conditions. Cooling through 500 °C at 977±12 Ma is documented by ⁴⁰Ar/³⁹Ar analyses of hornblende. Fold mechanisms operating in the northern Oaxacan Complex under Zapotecan granulite facies metamorphism include flexural and tangential–longitudinal strain accompanied by intense flattening and stretching parallel to the fold axes. Subsequent Phanerozoic deformation includes thrusting and upright folding under lower-grade metamorphic conditions. The Zapotecan event is widespread throughout Oaxaquia, and took crustal rocks to a depth of 25–30 km by orogenic crustal thickening, and is here designated as Zapotecan Orogeny. Modern analogues for Zapotecan granulite facies metamorphism and deformation occur in middle to lower crustal portion of subduction and collisional orogens. Contemporaneous tectonothermal events took place throughout Oaxaquia, and in various parts of the Genvillian orogen in Laurentia and Amazonia.     

Origin and U–Pb dating of zircon-bearing nepheline syenite xenoliths preserved in basaltic tephra (Massif Central, France)

Zircon-bearing xenoliths in continental basalts are often interpreted as witnesses of the continental basement uplifted during volcanic eruptions. Nevertheless, their origin is still debated. The Devès basaltic plateau belongs to the alkaline volcanic province of the French Massif Central. In few outcrops, zircon-bearing nepheline syenite xenoliths were preserved. U–Pb dating of the zircon crystals define an age of 956 ± 11 kyr constraining the crystallisation time of the zircons and consequently of the host xenoliths. This age, together with mineral chemistry arguments lead us to conclude that these minerals do not derive from a continental protolith. Rather, they likely result from the crystallisation of a liquid characterised by a nepheline–felspar composition and produced by the differentiation of a basaltic magma or, alternatively, by the low degree partial melting of a metasomatised lithospheric mantle. Such alkaline sialic rock and xenoliths may occur in large volumes at depth and generate the large amounts of zircon megacrysts discovered worldwide in secondary deposits within continental basaltic provinces.     

松辽盆地钱家店铀矿床含矿层位的岩相特征及其与铀成矿的关系

松辽盆地钱家店铀矿床含矿主岩为姚家组中的厚层砂岩。该砂岩上、下隔水层发育，局部夹较多不连续的泥岩透镜体，为辫状河流相沉积成因。平面上辫状河道周围为泛滥平原，以泥质沉积为主，在河道中间局部夹有河道间的沉积，其泥岩夹层多、厚度大，非均质性较强。通过与氧化带、铀矿化的对比分析，发现姚家组的岩相特征和砂体的非均质性对氧化带和铀矿化的分布、形态有明显的控制作用。河道间沉积及砂体中的泥质夹层可以阻碍含铀含氧水的流动，在其附近形成氧化-还原过渡带和铀的富集。砂体均质性较强的部位有利于氧化带的发育，而非均质性较强的部位则有利于铀成矿。     

中国北方砂岩型铀矿中铀的储集空间类型探讨

在中国北方的大多数沉积盆地里均发现有砂岩型铀矿床或铀矿化现象。通过样品薄片电子探针背散射图像分析,结合前人对各盆地砂岩型铀矿中铀矿物的赋存状态及近年来铀储层的研究成果,认为中国北方砂岩型铀矿中铀矿物的主要储集空间类型可分为原生孔隙（主要是炭屑）、缩小（残留）粒间孔隙、次生溶蚀孔隙、晶间孔隙及微裂缝。通过对铀储层孔隙类型的分析讨论,有利于进一步从微观了解砂岩铀储层内部结构的不均一性及铀矿物的成因。     

160 Ma of magmatic/hydrothermal and metamorphic activity in the Gällivare area: Re–Os dating of molybdenite and U–Pb dating of titanite from the Aitik Cu–Au–Ag deposit, northern Sweden

Host rocks to the Aitik Cu–Au–Ag deposit in northern Sweden are strongly altered and deformed Early Proterozoic mica(-amphibole) schists and gneisses. The deposit is characterised by numerous mineralisation styles, vein and alteration types. Four samples were selected for Re–Os molybdenite dating and 12 samples for U–Pb titanite dating in order to elucidate the magmatic/hydrothermal and metamorphic history following primary ore deposition in the Aitik Cu–Au–Ag deposit. Samples represent dyke, vein and alteration assemblages from the ore zone, hanging wall and footwall to the deposit. Re–Os dating of molybdenite from deformed barite and quartz veins yielded ages of 1,876±10 Ma and 1,848±8 Ma, respectively. A deformed pegmatite dyke yielded a Re–Os age of 1,848±6 Ma, and an undeformed pegmatite dyke an age of 1,728±7 Ma. U–Pb dating of titanite from a diversity of alteration mineral associations defines a range in ages between 1,750 and 1,805 Ma with a peak at ca. 1,780 Ma. The ages obtained, together with previous data, bracket a 160-Ma (1,890–1,730 Ma) time span encompassing several generations of magmatism, prograde to peak metamorphism, and post-peak cooling; events resulting in the redistribution and addition of metals to the deposit. This multi-stage evolution of the Aitik ore body suggests that the deposit was affected by several thermal events that ultimately produced a complex ore body. The Re–Os and U–Pb ages correlate well with published regional Re–Os and U–Pb age clusters, which have been tied to major magmatic, hydrothermal, and metamorphic events. Primary ore deposition at ca. 1,890 Ma in connection with intrusion of Haparanda granitoids was followed by at least four subsequent episodes of metamorphism and magmatism. Early metamorphism at 1,888–1,872 Ma overlapping with Haparanda (1,890–1,880 Ma) and Perthite-monzonite (1,880–1,870 Ma) magmatism clearly affected the Aitik area, as well as late metamorphism and Lina magmatism at 1,810–1,774 Ma and TIB1 magmatism at 1,800 Ma. The 1,848 Ma Re–Os ages obtained from molybdenite in a quartz vein and pegmatite dyke suggests that the 1,850 Ma magmatism recorded in parts of northern Norrbotten also affected the Aitik area.     

Recurrent mesoproterozoic continental magmatism in South-Central Norway

We report U–Pb dates and Lu–Hf isotope data, obtained by LAM-ICPMS, for zircons from metamorphic rocks of the Setesdalen valley, situated in the Telemark block south of the classic Telemark region of southern Norway. The samples include infracrustal rocks from the metamorphic basement, metaigneous rocks and metasediments from the Byglandsfjorden supracrustal cover sequence, and metaigneous rocks which intruded the whole succession. The main crustal evolution took place from 1,550–1,020 Ma, beginning with the emplacement of juvenile tonalitic melts; the contribution of older crustal material increased with time. Around 1,320 Ma, further addition of juvenile material occurred, involving both mafic and felsic melts, metamorphism and deformation. Acid magmas with high FeO*/MgO were intruded at 1,215 Ma, coinciding with underplating elsewhere in South Norway. The period starting at 1,215 Ma is represented by supracrustal rocks, principally metarhyolites with minor mafic material and immature sediments of the Byglandsfjorden Group. The crust generation processes ended with the intrusion of diorites and granodiorites at 1,030 Ma, late in the Sveconorwegian orogeny. Regional processes of metamorphism and deformation (around 1,290 and 1,000 Ma) can be related to the assembly of Rodinia. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

SHRIMP U–Pb dating of the Antucoya porphyry copper deposit: new evidence for an Early Cretaceous porphyry-related metallogenic epoch in the Coastal Cordillera of northern Chile

The Antucoya porphyry copper deposit (300 Mt at 0.45% total Cu) is one of the largest deposits of a poorly known Early Cretaceous porphyry belt in the Coastal Cordillera of northern Chile. It is related to a succession of granodioritic and tonalitic porphyritic stocks and dikes that were emplaced within Jurassic andesitic rocks of the La Negra Formation immediately west of the N–S trending sinistral strike-slip Atacama Fault Zone. New zircon SHRIMP U–Pb data indicate that the porphyries of Antucoya crystallized within the time span from 142.7 ± 1.6 to 140.6 ± 1.5 Ma (±2 σ), and late, unmineralized, NW–SE trending dacite dikes with potassic alteration and internal deformation crystallized at 141.9 ± 1.4 Ma. The Antucoya porphyry copper system appears to be formed after a change of stress conditions along the magmatic arc from extensional in the Late Jurassic to transpressive during the Early Cretaceous and provides support for an Early Cretaceous metallogenic episode of porphyry-type mineralization along the Coastal Cordillera of northern Chile.     

Lower Carboniferous post-orogenic granites in central-eastern Sierra de Velasco,Sierras Pampeanas,Argentina: U–Pb monazite geochronology,geochemistry and Sr–Nd isotopes

The central-eastern part of the Sierra de Velasco (Sierras Pampeanas, NW Argentina) is formed by the large Huaco (40 × 30 km) and Sanagasta (25 × 15 km) granite massifs and the small La Chinchilla stock (2 × 2 km). The larger granites intrude into Ordovician metagranitoids and crosscut Devonian (?) mylonitic shear zones, whereas the small stock sharply intrudes into the Huaco granite. The two voluminous granites are biotitic-muscovitic and biotitic porphyritic syeno- to monzogranites. They contain small and rounded tonalitic and quartz-dioritic mafic microgranular enclaves. The small stock is an equigranular, zinnwaldite- and fluorite-bearing monzogranite. The studied granites are silica-rich (SiO₂ >70%), potassium-rich (K₂O >4%), ferroan, alkali-calcic to slightly calk-alkalic, and moderately to weakly peraluminous (A/CNK: 1.06–1.18 Huaco granite, 1.01–1.09 Sanagasta granite, 1.05–1.06 La Chinchilla stock). They have moderate to strong enrichments in several LIL (Li, Rb, Cs) and HFS (Nb, Ta, Y, Th, U) elements, and low Sr, Ba and Eu contents. U–Pb monazite age determinations indicate Lower Carboniferous crystallization ages: 350–358 Ma for the Huaco granite, 352.7 ± 1.4 Ma for the Sanagasta granite and 344.5 ± 1.4 Ma for the La Chinchilla stock. The larger granites have similar ?Nd values between ?2.1 and ?4.3, whereas the younger stock has higher ?Nd of ?0.6 to ?1.4, roughly comparable to the values obtained for the Carboniferous San Blas granite (?1.4 to ?1.7), located in the north of the sierra. The Huaco and Sanagasta granites have a mainly crustal source, but with some participation of a more primitive, possibly mantle-derived, component. The main crustal component can be attributed to Ordovician peraluminous metagranitoids. The La Chinchilla stock derives from a more primitive source, suggesting an increase with time in the participation of the primitive component during magma genesis. The studied granites were generated during a post-orogenic period in a within-plate setting, possibly as a response to the collapse of the previous Famatinian orogen, extension of the crust and mantle upwelling. They are part of the group of Middle Devonian–Lower Carboniferous granites of the Sierras Pampeanas. The distribution and U–Pb ages of these granites suggests a northward arc-parallel migration of this mainly post-orogenic magmatism with time.     

竹山下铀矿床碱交代岩特征与铀成矿关系

围岩与热液所发生的的置换作用称为交代作用,顾名思义碱交代作用就是钾、钠碱金属性化学物质参与交代作用。碱金属(钾、钠)带进热液蚀变岩称为碱交代岩。所以碱交代作用主要是以热液作用为主体,对金属元素成矿物质的迁移和富集成矿起到了很重要的作用。诠释了热液作用是成矿物质富集的驱动力。碱交代岩是竹山下铀矿床主要的蚀变类型之一。通过对竹山下碱交代型铀矿床的钻孔20-1碱交代岩进行野外踏勘采集样品、室内岩相学分析和电子探针成分分析研究,确定了竹山下地区碱交代作用对铀矿床的实质为钾交代作用,碱交代作用使得富铀岩石中的惰性铀成为活性铀,从而被活化迁移,富集成矿。     

钾交代的热力学计算及其与铀成矿关系讨论

结合薄片镜下鉴定特征,探讨不同温度及埋深条件下斜长石钾长石化、黑云母绿泥石化以及[UO2（CO3）3]4-还原成沥青铀矿的ΔrG变化及其相互关系。结果表明：钾长石交代斜长石在无深部热流体作用的情况下不能进行;黑云母绿泥石化具有最低的ΔrG,且随埋深的加大ΔrG表现出先降低后增加直至为正值,表明该反应在相对低温条件下更容易进行;[UO2（CO3）3]4-在碱性环境下被磁铁矿还原时的ΔrG始终为负值,说明其可以在任何温度压力条件下进行;在无外来钾源流体作用下,黑云母绿泥石化可以为钾交代提供稳定的钾源,当两者反应交集温度越宽,则该深度越有利于钾交代的进行,并且钾交代主要发生在埋深2500 m以上;在钾交代区域内出现代表酸性流体的特征矿物,则表明沥青铀矿富集程度愈高。