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1.
Avcılar is the suburb of Istanbul that was most heavily damaged during the August 17, 1999 Mw 7.4 Izmit earthquake. Strong ground motion caused fatalities and damage in Avcılar despite being 90 km from the epicenter. We deployed five portable seismograph stations equipped with Reftek 24-bit recorders and L4C-3D seismometers for 2 months, in order to understand why the local site response was different from elsewhere in Istanbul. A reference station was placed on a hard rock site, and the remaining four stations were placed on other geological units, in areas that had experienced varying levels of damage. We calculated frequency-dependent ground amplification curves by taking the ratios of the spectra at soft and hard rock sites. We obtained similar site response curves for most earthquakes at each site in the frequency range of 0.3–1.6 Hz, and observed no significant site amplification beyond 2.0 Hz at any site. The overall characteristics of the recorded S-waveforms and our modeling of the calculated site amplification curves are consistent with amplification as a result of trapping of seismic energy within a 100–150 m thick, low-velocity subsurface layer. We also review the applicability of microtremor measurements to estimate local site effects at Avcılar. For these data, we used ratios of spectra of horizontal to vertical components to obtain each site response. These results are compared with standard spectral ratios. These microtremor measurements provide consistent estimates of the amplification at most sites at the higher end of the frequency band, namely above 1 Hz. The results from both methods indeed agree well in this part of the frequency band. However, the microtremor method fails to detect amplification at lower frequencies, namely <1.0 Hz.  相似文献   

2.
Site response measurements provide information on the amplification of ground motions generated by local conditions. Recent studies of large destructive earthquakes have shown that damage during the earthquakes are often caused by the amplification of seismic waves in near-surface sedimentary layers. The estimation of site response is therefore critical, in order to evaluate the true seismic hazard potential of a given area. We investigated local site amplifications in the South Iceland Seismic Zone (SISZ). Nine digital seismographs were deployed, temporarily, in an area of approximately 400 km2, in the westernmost part of the SISZ. Among the 90 events recorded, 15 were used in this study, including a magnitude 3.1 (ML) event and selected aftershocks, which occurred in the northern outskirts of the village Hveragerdi. Single Station Spectral Ratios (SSSR) of the recorded earthquakes revealed some of the effects of local site conditions. Spectral amplification factors of 2–5 on average, can be expected in the SIL area, depending on the sediment type and thickness. Higher site amplifications occur in the southern part of the study region, where the thickest sedimentary cover is found. Spectral amplification, related to topographical effects, is observed at the bedrock reference station, Bjarnastadir. Standard Spectral Ratios (SSR), with respect to the bedrock reference station, Bjarnastadir, were also calculated for some stations, in order to compare the two spectral ratio results. The two methods show a good correlation at some stations, whereas at others they vary considerably. The comparison between the earthquake and ambient noise data, on the other hand, gave better correlation when the SSSR method is used.  相似文献   

3.
In this paper, we present a seismic hazard scenario for the Garhwal region of the north-western Himalayan range, in terms of the horizontal Peak Ground Acceleration. The scenario earthquake of moment magnitude M w 8.5 has a 10% exceedance probability over the next 50 years. These estimates, the first for the region, were calculated through a stepwise process based on:
  • An estimation of the Maximum Credible Earthquake from the seismicity of the region and Global Seismic Hazard Assessment Program considerations, and
  • four seismotectonic parameters abstracted from near field weak-motion data recorded at five stations installed in Chamoli District of the Garhwal region in the aftermath of the 1999 Chamoli earthquake. The latter include
  • The frequency dependent power law for the shear wave quality factor, Q S
  • the site amplification at each station using horizontal-to-vertical-spectral ratio and generalized inversion technique
  • source parameters of various events recorded by the array and application of the resulting relations between the scalar seismic moment M 0 (dyne-cm) and moment magnitude M w and the corner frequency, ? c (Hz) and moment magnitude M w to simulate spectral acceleration due to higher magnitude events corresponding to the estimated Maximum Credible Earthquake, and
  • regional and site specific local spectral attenuation relations at different geometrically central frequencies in the low, moderate and high frequency bands.
  相似文献   

4.
An earthquake of magnitude 6.9 (M w) occurred in the Sikkim region of India on September 18, 2011. This earthquake is recorded on strong-motion network in Uttarakhand Himalaya located about 900 km away from the epicenter of this earthquake. In this paper acceleration record from six far-field stations has been used to compute the source parameters of this earthquake. The acceleration spectra of ground motion at these far-field stations are strongly affected by both local site effects and near-site anelastic attenuation. In the present work the spectrum of S-phase recorded at these far-field stations has been corrected for anelastic attenuation at both source and site and the site amplification terms. Site amplifications at different stations and near-site shear wave attenuation factor have been computed by the technique of inversion of acceleration spectra given by Joshi et al. (Pure Appl Geophys 169:1821–1845, 2012a). For estimation of site amplification and shear wave quality factor [Q β (f)] at the recording sites, ten local events recorded at various stations between July 2011 and December 2011 have been used. The obtained source spectrum from acceleration records is compared with the theoretical source spectrum defined by Brune (J Geophys Res 76:5002, 1970) at each station for both horizontal components of the records. Iterative forward modeling of theoretical source spectrum gives the average estimate of seismic moment (M o), source radius (r o) and stress drop (Δσ) as (3.2 ± 0.8) × 1026 dyne cm, 13.3 ± 0.8 km and 59.2 ± 8.8 bars, respectively, for the Sikkim earthquake of September 18, 2011.  相似文献   

5.
This paper presents a major extension of seismic vulnerability research project on the site of Trako??an Castle based on the initial horizontal-to-vertical-spectral-ratio (HVSR) results from Stanko et al. (2016). The estimated HVSR site frequencies and HV amplification at Trako??an Castle can only be used as an indication of the initial soil site frequency and amplification, so-called natural soil model, corresponding to the subsoil profile without the influence of an earthquake. The equivalent-linear (EQL) site response analysis has been carried out for different earthquake scenarios for a maximum input rock peak ground acceleration (PGAROCK) that corresponds to return periods of 95 (0.08 g), 475 (0.18 g) and 1000 years (0.31 g). The aim of the research is to evaluate structural seismic design responses and to determine type and degree of damage caused by local site effect, which is the result of an alluvial basin and topographic influences. The main objective of this research is the formation of local microseismic zones based on an EQL analysis: surface spectral acceleration and amplification maps at the predominant frequency. Based on the HVSR frequency response of the core structure of Trako??an Castle and the Tower itself (fundamental and higher frequency modes), maps of surface spectral acceleration and soil amplification at different frequencies (3, 5 and 10 Hz) are developed for different input PGAROCK levels (0.08, 0.18 and 0.31 g) to evaluate seismic response of the Castle. Observed amplifications are correlated with ground motion polarization and directionality of the ground motion from the alluvial basin to the hilltop. Shortening of predominant frequencies (lengthening of the period), particularly in the alluvial basin, has been observed with higher input PGAROCK in the EQL analysis. This effect is not manifested in the Trako??an hill, and predominant frequencies match HVSR frequencies. The use of certain geophysical survey methods at historical sites is a big problem, because terrain features (e.g. steep hills, mountains, ridges, slopes, cliffs) create lack of space and make it impossible to carry out geophysical investigation. Microtremor measurements at historical sites can overcome this limitation and provide local seismic response and vulnerability behaviour of historical monuments without destroying their authenticity. Also, computational modelling can greatly improve the results. The EQL site response analysis on the site of Trako??an Castle has confirmed and improved the results of seismic response and vulnerability based on HVSR method.  相似文献   

6.
We present a preliminary study of strong ground motion during the largest aftershock (Mw 5.8) of the 1999 Izmit earthquake (Mw 7.4), Turkey, at 11:55 on 13 September 1999. The peak ground acceleration observed near the epicentre of this aftershock was in agreement with that predicted by standard empirical prediction equations. Its spectral source parameters of the largest aftershock are also typical for a Mw 5.8 earthquake. At greater epicentral distances, there is an order-of-magnitude in scatter in peak ground acceleration values for this aftershock, which is attributed to site effects. The presence of thick layers of low-velocity sediments caused significant amplification of S-waves in the Avcılar district of Istanbul, at frequencies of 1 Hz, explaining the observed concentration of damage there as a result of the Izmit mainshock.  相似文献   

7.
A first order seismic microzonation map of Delhi is prepared using five thematic layers viz., Peak Ground Acceleration (PGA) contour, different soil types at 6 m depth, geology, groundwater fluctuation and bedrock depth, integrated on GIS platform. The integration is performed following a pair-wise comparison of Analytical Hierarchy Process (AHP), wherein each thematic map is assigned weight in the 5-1 scale: depending on its contribution towards the seismic hazard. Following the AHP, the weightage assigned to each theme are: PGA (0.333), soil (0.266), geology (0.20), groundwater (0.133) and bedrock depth (0.066). The thematic vector layers are overlaid and integrated using GIS. On the microzonation theme, the Delhi region has been classified into four broad zones of vulnerability to the seismic hazard. They are very high (> 52%), high (38–52%), moderate (23–38%) and less ( < 23%) zones of seismic hazard. The “very high” seismic hazard zone is observed where the maximum PGA varies from 140 to 210 gal for a finite source model of Mw 8.5 in the central seismic gap. A site amplification study from local and regional earthquakes for Delhi region using Delhi Telemetry Network data shows a steeper site response gradient in the eastern side of the Yamuna fluvial deposits at 1.5 Hz. The ‘high’ seismic hazard zone occupies most of the study area where the PGA value ranges from 90 to 140 gal. The ‘moderate’ seismic hazard zone occurs on either side of the Delhi ridge with PGA value varying from 60 to 90 gal. The ‘less’ seismic hazard zone occurs in small patches distributed along the study area with the PGA value less than 60 gal. Site response studies, PGA distribution and destruction pattern of the Chamoli earthquake greatly corroborate the seismic hazard zones estimated through microzonation on GIS platform and also establishes the methodology incorporated in this study.  相似文献   

8.
Creepex, defined as the systematic deviation of the magnitude of a single earthquake from the linear orthogonal regression between local magnitude ML and coda duration magnitude Md, calculated for the whole region, is used as a measure of the frequency content of the seismic sources in the Italian region. Predominantly high-frequency events are found in the two areas of Quaternary tectonic shortening in North-Central Italy and in the Calabrian Arc. This result, confirmed by two independent statistical tests, is in agreement with the global pattern obtained from the study of the regression between body-wave magnitude, mb, and surface-wave magnitude Ms: systematic shift to high frequencies in the energy release of seismic sources located in subduction zones and to low frequencies in zones of spreading. The analysis of the correlation between the patterns of heat flow and of seismic source spectral properties indicates that these source properties, in general, do not reflect thermal conditions in the lithosphere, but rather represent the result of tectonic processes.  相似文献   

9.
Propagation of seismic waves through soil layers would drastically change the frequency content and amplitude-based features of ground motions at the surface. These alterations are known as seismic site effects. Computation of site effects of high-populated areas such as large cities is of great importance (e.g., it is used in development of seismic microzonation of a region). Shiraz is one of the most populous cities of Iran and is located in a high seismic hazardous region. A representative clay site in this city is selected to assess local site effects. The time series and random vibration theory procedure in the frequency domain are implemented to analyze the aforementioned site. Furthermore, the nonlinear dynamic soil behavior is simulated by the equivalent linear method and the nonlinear method via DEEPSOIL program. Three types of soil column uncertainties such as shear wave velocity, modulus reduction, and damping ratio of soil layers as well as depth of underlying rock half-space (D bed) are considered herein. The mean amplification and standard deviation of natural logarithm of amplification factors are computed for a variety of analysis types. The results of the current study show that the computed mean and standard deviation of amplification factor in ln units by considering only V S uncertainty are in good agreement with the corresponding ones by considering V S and modulus reduction and damping ratio variabilities simultaneously for the studied site. Furthermore, it seems that the effect of bedrock depth in definition of spectral shapes of the Iranian seismic building code should be taken into account.  相似文献   

10.
The Surat City, which is the second most populated city in the state of Gujarat in western India, warrants site-specific seismic hazard assessment due to its rapid urbanization and proximity to major seismogenic zones. This study reports results of microtremor investigations at 72 single stations and 4 arrays in an area of 325 km2 spanning the city. The resonant frequencies, associated peak amplification values and liquefaction vulnerability indices were deduced from the horizontal to vertical spectral ratios. Ground amplification (AHVSR) in the range of 3.0–5.0 was observed in the 2.0–4.0-Hz frequency band at most of the sites. A secondary AHVSR between 2.0 and 3.0 is also observed in the 6.0–7.0-Hz frequency band at a few sites. Locales that are most susceptible to liquefaction are identified based on their vulnerability index (K g) exceeding the value of 10. The shear wave velocities (V s) ≥ 500 m/s inferred from array measurements occur at 38 m depth in the western part and ~16 m depth in the eastern part of city. The response spectra estimated from strong motion data recorded at an accelerograph site in Surat from three earthquakes of M w ≥ 3.2 that occurred in Kachchh, Saurashtra and Narmada regions are in accordance with our inferences of characteristic site frequencies and amplification. Our results, in agreement with the damage scenario during the 2001 Bhuj earthquake, provide valuable inputs for site-specific seismic hazard evaluation of the Surat City.  相似文献   

11.

The paper highlights the importance of using site-specific shear modulus reduction (G/Gmax versus shear strain, γ) curves and damping ratio (D versus shear strain, γ) curves for ground response analysis. In order to develop comprehensive G/Gmax–γ and Dγ curves (i.e. over a wide range of strain level), two types of apparatus, viz. resonant column and cyclic simple shear, have been used. The case study considered the geological deposits from the river beds of Yamuna River originating from the Himalayan seismic zone of North India. The tests results have been analysed to develop G/Gmaxγ and Dγ curves and compared with standard curves. It has been observed that upper and lower boundaries for the standard curves are remarkably different for the geological deposit under consideration. In order to assess the impact of using standard curves rather than site-specific curves, ground response analysis has been carried out at five sites along the Yamuna River using two types of curves (standard and site-specific developed in this study). The study showed that the amplification of shear waves at these sites based on the experimentally derived curves is much higher as compared to the standard curves. The proposed curves better represent dynamic behaviour of the soil deposits of the region and will provide a realistic response as far as practically possible, for the structures constructed in the states of Haryana and Delhi and nearby areas. It is anticipated that the data presented in this paper will have wide application and usage.

  相似文献   

12.

The definition of the Richter Ml magnitude scale is in terms of seismic wave horizontal components recorded on Wood‐Anderson seismographs. However, at many seismograph sites only the vertical component is available, and at sedimentary sites horizontal components are usually significantly amplified, causing complications in the assignment of a magnitude to an earthquake. Because each earthquake can be recorded at a different subset of sites, each subset having a different combination of site amplifications, the assignment of a magnitude is dependent upon the seismograph site combination that records a particular earthquake. Although there is some amplification of the vertical component at sedimentary foundation sites, it is shown that a reduced spread of values of Ml magnitude, consistent with low amplification (bedrock) site magnitudes, can be achieved using the vertical component to compute the magnitude and adding 0.2 to adjust to the Ml magnitude scale (defined in terms of the horizontal components). This presupposes that the sites used by Richter were on bedrock; however, even if this is incorrect, it appears to be a necessary precondition for the world‐wide unification of the Richter scale along with defining the true gain of Wood‐Anderson seismographs rather than accepting the design gain of 2800. Site corrections would be smaller than those established using the horizontal components. Taking into account the use of only the vertical component in the calculation of Ml and including the 0.2 adjustment to the equivalent horizontal component derived magnitude, the expression for the calculation of magnitudes in the Victoria region becomes:

Ml = logAz ‐ logSz + 0.9 + logR + 0.0056Re‐0.0013R

where Az is the equivalent Wood‐Anderson seismograph displacement amplitude, Sz is the site amplification (vertical component) and R is the hypocentral distance.  相似文献   

13.
Morphostructural zoning (MSZ) scheme of the Himalayan arc region as obtained from a joint study of topographic, geological and tectonic maps as well as satellite imagery is analysed. Three types of morphostructures have been determined: territorial units (blocks of different ranks), linear zones limiting these blocks (lineaments) and intersections of the lineaments (knots). Comparison of MSZ scheme with the know seismicity indicates epicenters of strong earthquakes (M≥6·5) clustered around some of these knots. Pattern recognition method is used to determine seismically potential areas for the occurrence of recognition method is used to determine seismically potential, for the occurrence of strong earthquakes of magnitude ≥M 0. We have carried out two such studies for the Himalayan arc region, one forM 0=6·5 and the other forM 0=7·0. Out of a total number of 97 knots, 48 knots are found to be seismically potential for the occurrence of earthquake ofM≥6·5. The results of the study forM 0=6·5 were presented in the symposium on “Earthquake Prediction” held in Strasbourg, France, March 1991 (Gorshkovet al 1991). The epicenter of Uttarkashi earthquake of magnitude,M b=6·6 that occurred in the late hours of 19th October 1991 (UTC) lies in the vicinity of one such knot. The second study carried out subsequently shows that only 36, knots are potential for the occurrence of earthquakes ofM≥7·0, which include the knot, associated with theUttarkashi earthquake.  相似文献   

14.
Site response in the Gujarat region is studied using local earthquake data recorded at 32 sites spread all over Gujarat region, India. Out of these 32 sites, 15 sites are located in Kachchh region, 8 in Saurashtra and 9 in mainland Gujarat region. These sites are underlain by different types of rocks/sediments of different ages. Out of 32 stations, 7 stations are on Quaternary deposits, 6 on Tertiary, 11 on Deccan, 3 on Jurassic, 3 on Cretaceous and 2 on Proterozoic rocks. The predominant frequencies at these sites depend strongly on the local geology. The average predominant frequencies of the sites on Quaternary sediments are 2.4?Hz, 5.3?Hz on Tertiary, 7.5?Hz on Jurassic, 7.2?Hz on Deccan, 4.6?Hz on Cretaceous and 7.5?Hz on Proterozoic formations. The average site amplification values at predominant frequencies are 3.7 for the sites of Quaternary deposits, 3.3 for Tertiary, 3.3 for Cretaceous rock, 4.2 for Deccan trap, 4.1 for Jurassic sites and 4.6 for Proterozoic. The damage to the houses during 2001 Bhuj earthquake is compared with the amplification at predominant frequencies at those sites. The spatial variation of predominant frequencies and the site amplifications at different frequencies corresponding to the natural frequencies of different storey buildings are studied, which will be useful in the evaluation of seismic hazard in the region.  相似文献   

15.
High-resolution seismic-reflection/refraction data were acquired on the ground surface at six locations to compare with near-surface seismic-velocity downhole measurements. Measurement sites were in Seattle, WA, the San Francisco Bay Area, CA, and the San Fernando Valley, CA. We quantitatively compared the data in terms of the average shear-wave velocity to 30-m depth (Vs30), and by the ratio of the relative site amplification produced by the velocity profiles of each data type over a specified set of quarter-wavelength frequencies. In terms of Vs30, similar values were determined from the two methods. There is <15% difference at four of the six sites. The Vs30 values at the other two sites differ by 21% and 48%. The relative site amplification factors differ generally by less than 10% for both P- and S-wave velocities. We also found that S-wave reflections and first-arrival phase delays are essential for identifying velocity inversions. The results suggest that seismic reflection/refraction data are a fast, non-invasive, and less expensive alternative to downhole data for determining Vs30. In addition, we emphasize that some P- and S-wave reflection travel times can directly indicate the frequencies of potentially damaging earthquake site resonances. A strong correlation between the simple S-wave first-arrival travel time/apparent velocity on the ground surface at 100 m offset from the seismic source and the Vs30 value for that site is an additional unique feature of the reflection/refraction data that could greatly simplify Vs30 determinations.  相似文献   

16.
We analyze the strong motion accelerograms recorded for the large (MS=7.7, MW=7.3, mb=6.4) Rudbar earthquake of June 20, 1990. The earthquake had a complex source process. We have identified the imprints of rupture of three localized asperities on the major causative fault on the accelerograms. These asperities are interpreted to correspond to (i) the main shock that initiated the rupture process and was located in the domino block between the Kabateh and Zard Goli faults, (ii) a foreshock that occurred about 10 s earlier in the Kabateh fault and (iii) a later shock, on the western end of the Baklor fault, which terminated the bilateral rupture process at the western end. We estimate the strike, dip and slip of these causative sub-event rupture planes using the SH spectral amplitudes, based on a point source representation of sub-events and a non-linear least square formulation for inversion of the amplitude data. The results of our inversion of the near field data are comparable to other studies based on teleseismic data.  相似文献   

17.
In this study, soil response was carried out for the Greater Delhi region. A folded Proterozoic formation was identified as Delhi ridge, passes through its central part along SSW–NNE direction, and appears to be a main geomorphic feature for the study area. The Delhi ridge is an exposed quartzite rock of about 10–100 m wide and ~25 km long with gentler dipping both toward east and west. We have considered the exposed part as an outcrop side near the ridge axis and the dipping area as rigid base away from the ridge axis for ground motion study during the occurrence of the 25 November 2007 earthquake with magnitude M L 4.3 (Richter scale) that occurred at Delhi–Haryana State boundary. The degree of shaking was very strong and reported major cracks in the buildings near the epicenter area. We have studied the soil response parameters at the surface level, considering horizontally stratified soil layers above rigid base. The equivalent linear method was used for soil response analysis at 25 sites in Greater Delhi area. The peak amplification factors vary from 3.2 to 5.9 and peak resonance frequency varies from 1.2 to 5.3 Hz. The correlation among the peak amplification factor (A) and frequency (f) was empirically established as A = 0.36f + 3.60. Increasing peak amplification factor was found at sites with increasingly thicker alluvium deposit with lower frequency contains ground motion and vice versa. Seismic zoning map was also reconstructed for peak amplification factors and predominant periods for the study area for the mitigation purposes of earthquake damage. The average shear wave velocity up to 30 m soil depth is also obtained for site classification. The average velocity to 30 m [ $ \overline{{V_{\text{s}} }} (30) $ ] is a widely used parameter for classifying sites for predicting their potentiality to amplify seismic shaking. A lower value [ $ \overline{{V_{\text{s}} }} (30) $ ] thus yields a more conservative estimate of ground motion, which generally increases as $ \overline{{V_{\text{s}} }} (30) $ decreases. Present estimate of $ \overline{{V_{\text{s}} }} (30) $ varies from 315 to 419 m/s. In this study, we have identified two site classes C and D, as per National Earthquake Hazard Reduction Program. The city planner or engineers can directly use these data for site-specific assessment during retrofitting of the existing structure, demolition of the old buildings and design a new structure to avoid major destruction of the buildings due to future earthquake.  相似文献   

18.
Site classification studies play a vital role in earthquake hazard assessment since in situ ground conditions substantially affect the characteristics of incoming seismic waves during earthquakes. Flat areas along the coast and rivers generally consist of thick layers of soft clay and sand. Such deposits amplify certain frequencies of ground motion, thereby attributing to an increase in the damage due to an earthquake. Hence, site classification studies have been carried out using shear-wave velocity, ground response, and corresponding amplification at 83 locations in Pondicherry, a coastal city in India. The present study is aimed at estimating the shear-wave velocity through multichannel analysis of surface waves and to compute the average shear-wave velocity (V S 30 ), stiffness, and N values using empirical relations. Further, site-response studies (horizontal-to-vertical spectral ratio) were conducted to estimate the ground-response frequencies and corresponding amplifications through Nakamura technique. From the results, the study area was classified into three types, i.e., C-class: with V S 30 in the range of 360–760 m/s, D-class: with V S 30 in the range of 180–360 m/s, and E-class: with V S 30  < 180 m/s following the National Earthquake Hazard Reduction Programme norms (BSSC in NEHRP recommended provisions for seismic regulations for new buildings and other structures (FEMA 450), part 1: provisions. Building Seismic Safety Council for the Federal Emergency Management Agency, Washington, 2003). Finally, a site classification map for Pondicherry region has been prepared, which can be used in urban planning and strengthening of existing structures against future earthquakes.  相似文献   

19.
OH in zoned amphiboles of eclogite from the western Tianshan,NW-China   总被引:1,自引:0,他引:1  
Chemically-zoned amphibole porphyroblast grains in an eclogite (sample ws24-7) from the western Tianshan (NW-China) have been analyzed by electron microprobe (EMP), micro Fourier-transform infrared (micro-FTIR) and micro-Raman spectroscopy in the OH-stretching region. The EMP data reveal zoned amphibole compositions clustering around two predominant compositions: a glaucophane end-member ( B Na2 C M2+ 3 M3+ 2 T Si8(OH)2) in the cores, whereas the mantle to rim of the samples has an intermediate amphibole composition ( A 0.5 B Ca1.5Na0.5 C M 2+ 4.5 M 0.53+ T Si7.5Al0.5(OH)2) (A = Na and/or K; M 2+ = Mg and Fe2+; M 3+ = Fe3+ and/or Al) between winchite (and ferro-winchite) and katophorite (and Mg-katophorite). Furthermore, we observed complicated FTIR and Raman spectra with OH-stretching absorption bands varying systematically from core to rim. The FTIR/Raman spectra of the core amphibole show three lower-frequency components (at 3,633, 3,649–3,651 and 3,660–3,663 cm−1) which can be attributed to a local O(3)-H dipole surrounded by M(1) M(3)Mg3, M(1) M(3)Mg2Fe2+ and M(1) M(3) Fe2+ 3, respectively, an empty A site and T Si8 environments. On the other hand, bands at higher frequencies (3,672–3,673, 3,691–3,697 and 3,708 cm−1) are observable in the rims of the amphiboles, and they indicate the presence of an occupied A site. The FTIR and Raman data from the OH-stretching region allow us to calculate the site occupancy of the A, M(1)–M(3), T sites with confidence when combined with EPM data. By contrast M(2)- and M(4) site occupancies are more difficult to evaluate. We use these samples to highlight on the opportunities and limitations of FTIR OH-stretching spectroscopy applied to natural high pressure amphibole phases. The much more detailed cation site occupancy of the zoned amphibole from the western Tianshan have been obtained by comparing data from micro-chemical and FTIR and/or Raman in the OH-stretching data. We find the following characteristic substitutions Si(T-site) (Mg, Fe)[M(1)–M(3)-site] → Al(T-site) Al[M(1)–M(3)-site] (tschermakite), Ca(M4-site)□ (A-site) → Na(M4-site) Na + K(A-site) (richterite), and Ca(M4-site) (Mg, Fe) [M(1)–M(3)-site] → Na(M4-site) Al[M(1)–M(3)-site] (glaucophane) from the configurations observed during metamorphism.  相似文献   

20.
The Attock Basin is situated close to the northwest of Pakistan. Recent seismic event of October 2015 (7.5Mw) near the Pakistan Afghanistan border has proved that the area of interest is seismically active and triggered a series of aftershocks of magnitude even greater than 6.5Mw. This seismic activity has posed danger to the future of the people and infrastructure especially to the northwestern part of the country. Therefore, site response analysis is essential for estimating local site conditions in response to seismic events. Ambient noise recordings were made at 50 sites within urban and semi-urban settlements in the Attock Basin to analyze the site response of the small but densely populated basin. At each of these sites, the fundamental frequency of the soft sediments (f 0), the amplitude (A 0) of corresponding H/V spectral ratios, the thickness of soft sediment (H) lying over competent lithology, and the soil vulnerability index (K g) were studied. Results were correlated with sparsely available borehole data to enhance the credibility of the study conducted for microzonation and predicting the site response to earthquake seismicity in the Attock Basin. The soil vulnerability index was found to range from moderate to high. Results clearly showed that the study area exhibits low to moderate fundamental frequency with greater soft sediment thicknesses distributed throughout the study area. Moreover, higher impedance contrasts were found at most of the sites within the central part of the Attock Basin, thus reflecting a moderate to high susceptibility of damage in those regions in response to seismic events.  相似文献   

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