Geology and Geochemistry of the Buerkesidai and Kuoerzhenkuola Gold Deposits in the Sawuershan Region, Xinjiang Uigur Autonomous Region, Northwest China

The Sawuershan region, one of the important gold metallogenic belts of Xinjiang, is located in the western part of the Kalatongke island arc zone of north Xinjiang, NW China. There are two gold deposits in mining, namely the Kuoerzhenkuola and the Buerkesidai deposits. Gold ores at the Kuoerzhenkuola deposit occur within Carboniferous andesite and volcanic breccias in the form of gold‐bearing quartz–pyrite veins and veinlet groups containing native gold, electrum, pyrite, pyrrhotite and chalcopyrite. Gold ores at the Buerkesidai deposit occur within Carboniferous tuffaceous siltstones in the form of gold‐bearing quartz veinlet groups and altered rocks, with electrum, pyrite and arsenopyrite as major metallic minerals. Both gold deposits are hosted by structurally controlled faults associated with intense hydrothermal alteration. The typical alteration assemblage is sericite + chlorite + calcite + quartz, with an inner pyrite–sericite zone and an outer chlorite–calcite–epidote zone between orebodies and wall rocks. δ³⁴S values (0.3–1.3‰) of pyrite of ores from Kuoerzhenkuola deposit are similar to those (0.4–2.9‰) of pyrite of ores from Buerkesidai deposit. δ³⁴S values (1.1–2.8‰) of pyrite from altered rocks are similar to δ³⁴S values of magmatic or igneous sulfide sulfur, but higher than those from ores. ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb data of sulfide from ores range within 17.72–18.56, 15.34–15.61, and 37.21–38.28, respectively. These sulfur and lead isotope compositions imply that ore‐forming materials might originate from multiple, mainly deep sources. He and Ar isotope study on fluid inclusions of pyrites from ores of Kuoerzhenkuola and Buerkesidai gold deposits produces ⁴⁰Ar/³⁶Ar and ³He/⁴He ratios in the range of 282–525 and 0.6–9.4 R/Ra, respectively, indicating a mixed source of deep‐seated magmatic water (mantle fluid) and shallower meteoric water. In terms of tectonic setting, the gold deposits in the Sawuershan region can be interpreted as epithermal. These formations resulted from a combination of protracted volcanic activity, hydrothermal fluid mixing, and a structural setting favoring gold deposition. Fluid mixing was possibly the key factor resulting in Au deposition in the gold deposits in Sawuershan region.     

Fenitized Wall Rock Geochemistry of the First Carbonatite Dyke at Bayan Obo,Inner Mongolia,China

The first carbonatite dyke at Bayan Obo is well exposed on the surface for a length and width of approximately 60 m and 1.1–1.5 m, respectively. Along its strike, the fenitized H1(Qs) and H2(Cs) quartzite is replaced by Na-amphiboles, aegirines, and alkali-feldspars, intermittently stretching as far away as 800 m in length. Based on petrographical characteristics, the dyke's fenitized wall rocks are divisible into different zones:(1) outer,(2) middle, and(3) inner. The outer zone is 5–17 m from the NW margin of the dyke. The middle zone is located at 3.5–5 m from the NW margin of the dyke. The inner contact zone is located between direct contact with the dyke and 3.5 m from the dyke. In the outer zone, upon visual examination, no evidence of outcrop fenitization was found and the major elemental rock composition is nearly identical to the unaltered H1 and H2 lithologies. In the thin sections, however, small amounts of Na-amphibole and phlogopite are present. Despite relatively poor development throughout the 5 m of fenitization, the wall rocks have retained at least a small geochemical signature comparable to the original sedimentary protolith. The fenites occurring in the inner zone exhibit distinct variations, not only for the sharp contact at the outcrop scale, but also for variations in major, rare earth elements(REE), and trace elements and Sm-Nd isotope composition. The wall rocks within 3.5 m have undergone strong fenitization, inheriting the geochemical signature derived from the carbonatite dyke. Fenitization in the middle zone was not as strong, at least compared to the inner zone, but was stronger than the outer zone. Compared to some trace elements and REEs, the major elements are relatively immobile during fenitization. The Sm-Nd isotope data for the carbonatite dyke and the adjacent fenitized wall rocks, where the Sm and Nd originate solely from the dyke, plots as a six-point isochron with an age of 1308±56 Ma. This age is identical to that of ore-bearing dolomite carbonatite and the related ore-forming events, indicating that there may be a petrogenetic link between the two. Based on Sr and Nd isotope compositional data, the first carbonatite dyke may be derived from an enriched mantle.     

Geology and Geochemistry of the Bianbianshan Au‐Ag‐Cu‐Pb‐Zn Deposit,Southern Da Hinggan Mountains,Northeastern China

The Bianbianshan deposit, the unique gold-polymetal (Au-Ag-Cu-Pb-Zn) veined deposit of the polymetal metallogenic belt of the southern segment of Da Hinggan Mountains mineral province, is located at the southern part of the Hercynian fold belt of the south segment of Da Hinggan Mountains mineral province, NE China. Ores at the Bianbianshan deposit occur within Cretaceous andesite and rhyolite in the form of gold-bearing quartz veins and veinlet groups containing native gold, electrum, pyrite, chalcopyrite, galena and sphalerite. The deposit is hosted by structurally controlled faults associated with intense hydrothermal alteration. The typical alteration assemblage is sericite + chlorite + calcite + quartz, with an inner pyrite - sericite - quartz zone and an outer seicite - chlorite - calcite - epidote zone between orebodies and wall rocks. δ34 S values of 17 sulfides from ores changing from –1.67 to +0.49‰ with average of –0.49‰, are similar to δ34 S values of magmatic or igneous sulfide sulfur. 206Pb/204Pb, 207Pb/204Pb and 208Pb/ 204Pb data of sulfide from ores range within 17.66–17.75, 15.50–15.60, and 37.64–38.00, respectively. These sulfur and lead isotope compositions imply that ore-forming materials might mainly originate from deep sources. H and O isotope study of quartz from ore-bearing veins indicate a mixed source of deep-seated magmatic water and shallower meteoric water. The ore formations resulted from a combination of hydrothermal fluid mixing and a structural setting favoring gold-polymetal deposition. Fluid mixing was possibly the key factor resulting in Au-Ag-Cu-Pb-Zn deposition in the deposit. The metallogenesis of the Bianbianshan deposit may have a relationship with the Cretaceous volcanic-subvolcanic magmatic activity, and formed during the late stage of the crust thinning of North China.     

Neotectonic and volcanic characteristics of the Karasu fault zone (Anatolia,Turkey): The transition zone between the Dead Sea transform and the East Anatolian fault zone

The Karasu Rift (Antakya province, SE Turkey) has developed between east-dipping, NNE-striking faults of the Karasu fault zone, which define the western margin of the rift and west-dipping, N–S to N20°–30°E-striking faults of Dead Sea Transform fault zone (DST) in the central part and eastern margin of the rift. The strand of the Karasu fault zone that bounds the basin from west forms a linkage zone between the DST and the East Anatolian fault zone (EAFZ). The greater vertical offset on the western margin faults relative to the eastern ones indicates asymmetrical evolution of the rift as implied by the higher escarpments and accumulation of extensive, thick alluvial fans on the western margins of the rift. The thickness of the Quaternary sedimentary fill is more than 465 m, with clastic sediments intercalated with basaltic lavas. The Quaternary alkali basaltic volcanism accompanied fluvial to lacustrine sedimentation between 1.57 ± 0.08 and 0.05 ± 0.03 Ma. The faults are left-lateral oblique-slip faults as indicated by left-stepping faulting patterns, slip-lineation data and left-laterally offset lava flows and stream channels along the Karasu fault zone. At Hacılar village, an offset lava flow, dated to 0.08 ± 0.06 Ma, indicates a rate of left-lateral oblique slip of approximately 4.1 mm·year^–1. Overall, the Karasu Rift is an asymmetrical transtensional basin, which has developed between seismically active splays of the left-lateral DST and the left-lateral oblique-slip Karasu fault zone during the neotectonic period.     

Gold Abundance and Stable Isotopes (H, O, S) in Hydrothermal Alteration Zones of Gasa Island (Gasado), Korea

Geology of the Gasa Island (Gasado), Korea, consists mainly of tuffaceous rocks, rhyolite and andesitic rocks related to Cretaceous volcanic activity. These rocks are hydrothermally altered, and are classified into the following four alteration zones based on the alteration mineral assemblages: advanced argillic alteration (alunite‐pyrophyllite‐kaolinite‐pyrite); sericitic alteration (sericite‐kaolinite‐quartz); propylitic alteration (quartz‐chlorite‐carbonate‐pyrite); and silicified zones. Alunite in the advanced argillic zone occurred in two types; a massive or disseminated type and a vein type. Most of the massive or disseminated alunites are ≥50 μm in size, whereas the size of vein alunites is <20–30 μm. Alunite grain size is greater in the central part of disseminated or massive alunite, while it is smaller toward the margins. The gold content of each alteration zone is 21–2900 ppb, 15–88 ppb, 57–1730 ppb, and 2–231 ppb, respectively. The gold content of quartz veins developed in the alteration zones is 39–715 ppb. Gold is enriched in the minerals and rocks around faults and fissures, and is strongly concentrated in the advanced argillic alteration zone around faults. Hydrothermal solutions traveling along the fracture systems might be responsible for the comparatively high gold content in the study area. δ³⁴S of alunites occurring in the advanced argillic alteration zone range from +16.5 to +3.9‰, although most are in a comparatively narrow range from +8.6 to +5.2‰. There is no difference between disseminated or massive and vein alunites. The δ³⁴S of pyrites in the advanced argillic alteration zone are from +4.8 to ?2.9‰. Oxygen and hydrogen isotope values of alunites are from +8.5 to 0‰ and from ?59.6 to ?97.3‰, respectively. With an assumed temperature of 200°C, δD and δ¹⁸O of hydrothermal solutions calculated for alunites are from ?53.6 to ?91.3‰, and from ?2.4 to ?8.1 for massive or disseminated alunites and from ?6.6 to ?10.9‰ for vein alunites, respectively. These data suggest that meteoric water dominated during the alunite formation. Isotopic data, geological setting, mineralogy, size of alunite and pure alunite composition (K end member) indicate that alunites of the study area were formed in the steam‐heated environment of acid sulfate alteration.     

Endeavour 42 deposit,Lake Cowal,New South Wales: A structurally controlled gold deposit

Endeavour 42 is a structurally controlled Au deposit with similarities to adularia‐sericite deposits. It is the largest of four gold prospects discovered in the Late Ordovician Lake Cowal volcanic complex, adjacent to the Gilmore Fault Zone, in central New South Wales, Australia. The Lake Cowal volcanic complex consists of calc‐alkaline to shoshonitic volcanic rocks and related sedimentary rocks that were deposited in a relatively deep‐water environment. The volcanic and sedimentary rocks of the Lake Cowal volcanic complex were intruded by diorite and granodiorite. Low‐grade porphyry Cu (0.2–0.35% Cu) mineralisation is developed in parts of the granodiorite intrusion. The gold deposits are developed north of the porphyry Cu mineralisation and occur within a north‐south corridor adjacent to a north‐south‐oriented body of diorite. The Endeavour 42 deposit is hosted by three volcanic units and a diorite. The stratigraphic units at Endeavour 42, consistently strike 215° and dip 50°NW, and comprise an upper unit dominated by redeposited pyroclastic debris and a lower conglomerate unit with clasts of reworked volcanic rocks. Separating these units is a sequence of trachyandesite lava and hyaloclastite breccias. Laminated mudstone and siltstone throughout the sequence are indicative of a relatively deep‐water, below wave‐base, environment. Porphyritic dykes, which are typically associated with zones of faulting, cross‐cut both the volcano‐sedimentary sequence and the diorite. The major fault orientations are 290° and 340°, forming subparallel conjugate fault sets. Both sets of faults are mineralised, contain deformed porphyritic dykes and are associated with sericitic alteration. Endeavour 42 is a sulfide‐poor gold deposit with free native Au and Au associated with pyrite and sphalerite. Minor galena, pyrrhotite and chalcopyrite are also observed. Irregular pyrite veinlets and carbonate‐sulfide veinlets occur in the upper unit of re‐deposited pyroclastic debris. Auriferous veins are parallel‐sided dilatant veins with quartz‐sulfide‐carbonate‐adularia. These veins display a consistent strike of 305° and a dip of 35°SW. Alteration and mineralisation were influenced by host‐rock composition and rheology. A pervasive alteration assemblage of chlorite‐carbonate‐hematite‐epidote is developed throughout the Lake Cowal volcanic complex. This is overprinted by sericite‐silica‐carbonate alteration around fault zones and dykes, with patchy and pervasive alteration of this type developed in the lava sequence and upper volcani‐clastic unit, reflecting permeability and probable alteration zoning. In the lower clastic unit, the diorite and, in parts of the lava sequence, a chlorite‐carbonate‐pyrite assemblage partially overprints sericite‐silica alteration, suggesting an evolving fluid composition, changing physico‐chemical conditions or a different alteration fluid. Age dating of the intrusive phases and sericitic alteration associated with mineralisation at Endeavour 42 yields ages of 465.76 ± 1 and 438.6 ± 0.5 Ma, respectively, suggesting that mineralisation post‐dates the Lake Cowal intrusive event and is related to intrusion of magma during the 440 Ma mineralising event, an important period in the eastern Lachlan Fold Belt.     

Ordovician Macquarie Arc and turbidite fan relationships,Lachlan Orogen,southeastern Australia: stratigraphic and tectonic problems

Ordovician rocks of the Lachlan Orogen consist of two major associations, mafic to intermediate volcanic and volcaniclastic rocks (Macquarie Arc), which aerially comprise several north–south-trending belts, and the quartz-rich turbidite succession. Relationships between these associations are integral to resolving their tectonic settings and opinions range between contacts being major thrusts, combinations of various types of faults, and stratigraphic contacts with structural complications. Stratigraphic contacts between these associations are found with volcaniclastic-dominant units overlying quartz-turbidite units along the eastern boundary of the eastern volcanic belt and along the southern boundary of the central volcanic belt. Mixing between these major associations is limited and reflects waning quartzose turbidite deposition along a gently sloping sea floor not penetrating steeper volcaniclastic aprons that were developing around the growing volcanic centres formed during late Middle Ordovician to early Silurian Macquarie Arc igneous activity. An island arc setting has been most widely supported for the Macquarie Arc, but the identification and polarity of the associated subduction zone remain a contentious issue particularly for the Early Ordovician phase of igneous activity. The Macquarie Arc initiated within a Cambrian backarc formed by sea-floor spreading behind a boninitic island arc and presumably reflects a renewed response to regional convergence as subduction ceased along the Ross–Delamerian convergent boundary at the East Gondwana continental margin. An extensional episode accompanied initiation of the late Middle Ordovician expansion in island arc development. A SSE-dipping subduction zone is considered to have formed the Macquarie Arc and underwent anticlockwise rotation about an Euler pole at the western termination of the island arc. This resulted in widespread deformation west of the Macquarie Arc in the Benambran Orogeny and development of subduction along the eastern margin of the orogenic belt.     

The Arinem Te‐Bearing Gold‐Silver‐Base Metal Deposit,West Java,Indonesia

The vein system in the Arinem area is a gold‐silver‐base metal deposit of Late Miocene (8.8–9.4 Ma) age located in the southwestern part of Java Island, Indonesia. The mineralization in the area is represented by the Arinem vein with a total length of about 5900 m, with a vertical extent up to 575 m, with other associated veins such as Bantarhuni and Halimun. The Arinem vein is hosted by andesitic tuff, breccia, and lava of the Oligocene–Middle Miocene Jampang Formation (23–11.6 Ma) and overlain unconformably by Pliocene–Pleistocene volcanic rocks composed of andesitic‐basaltic tuff, tuff breccia and lavas. The inferred reserve is approximately 2 million tons at 5.7 g t^?1 gold and 41.5 g t^?1 silver at a cut‐off of 4 g t^?1 Au, which equates to approximately 12.5t of Au and 91.4t of Ag. The ore mineral assemblage of the Arinem vein consists of sphalerite, galena, chalcopyrite, pyrite, marcasite, and arsenopyrite with small amounts of pyrrhotite, argentite, electrum, bornite, hessite, tetradymite, altaite, petzite, stutzite, hematite, enargite, tennantite, chalcocite, and covellite. These ore minerals occur in quartz with colloform, crustiform, comb, vuggy, massive, brecciated, bladed and calcedonic textures and sulfide veins. A pervasive quartz–illite–pyrite alteration zone encloses the quartz and sulfide veins and is associated with veinlets of quartz–calcite–pyrite. This alteration zone is enveloped by smectite–illite–kaolinite–quartz–pyrite alteration, which grades into a chlorite–smectite–kaolinite–calcite–pyrite zone. Early stage mineralization (stage I) of vuggy–massive–banded crystalline quartz‐sulfide was followed by middle stage (stage II) of banded–brecciated–massive sulfide‐quartz and then by last stage (stage III) of massive‐crystalline barren quartz. The temperature of the mineralization, estimated from fluid inclusion microthermometry in quartz ranges from 157 to 325°C, whereas the temperatures indicated by fluid inclusions from sphalerite and calcite range from 153 to 218 and 140 to 217°C, respectively. The mineralizing fluid is dilute, with a salinity <4.3 wt% NaCl equiv. The ore‐mineral assemblage and paragenesis of the Arinem vein is characteristically of a low sulfidation epithermal system with indication of high sulfidation overprinted at stage II. Boiling is probably the main control for the gold solubility and precipitation of gold occurred during cooling in stage I mineralization.     

Dyke magnetization, magnetostratigraphy and upper-crustal structure in the Reydarfjordur area of eastern Iceland

A dyke swarm approximately 12 m.y. old and comprising 103 basaltic dykes was sampled during a palaeomagnetic investigation of the Reydarfjördur area, eastern Iceland. Of 100 dykes yielding statistically significant palaeomagnetic directions 36 are normal, 43 reversed and 21 are intermediate; 5% of the dykes are olivine-phyric. The magnetic stratigraphy of the lava pile in this area is partially known from earlier palaeomagnetic studies, and six additional sections measured by field magnetometer and a palaeomagnetic section of 40 flows (20 reversed, 16 normal, and 4 intermediate) are reported here. These sections can be correlated by means of petrologic horizons (silicic tuffs, olivine basalts and porphyritic units) and exhibit stratigraphic thickening towards the centre of the Reydarfjördur dyke swarm. The portion of the basalt pile cut by the dyke swarm can be related both petrologically and palaeomagnetically to the dykes, and the number of exposed dykes is found to be of the same order, but smaller than, the number of lava flows in that comparable portion of the lava pile. This implies that in general the exposed dyke swarm is related to the exposed lava pile which is unlikely to extend much further downdip than the known extension updip. The lava pile in Iceland evolves as large lenticular units formed at eruptive axes, and distributed en échelon along the length of the axial zone with spacings comparable to the thickness of the lithosphere.     

Localization control for chlorite breccia deformation beneath Catalina detachment fault,Rincon Mountains,Tucson, Arizona

The structural location of an approximately 3-km stretch of the Catalina detachment fault zone appears to have been controlled by an ultramylonite shear zone within mylonites of the Catalina–Rincon metamorphic core complex. The Catalina detachment fault zone consists of the detachment fault surface, a 3–5 m interval of cataclasite and ultracataclasite, up to ∼50 m of chlorite breccia, and a discrete subdetachment fault. Beneath the subdetachment fault is a km-scale thickness of mylonites. Progressive ductile-to-brittle shear-zone evolution of the fault-rock stratigraphy started with mylonitization, was followed by overprinting of mylonites by chlorite brecciation, and culminated in the formation of the Catalina detachment fault and associated ultracataclasites. The detachment fault is cospatial with and subparallel to the zone of chlorite breccia. The subdetachment fault is subparallel to the interval of chlorite brecciation and to the detachment fault. The ‘plane’ of projection of the approximately 30-m thick ultramylonite shear zone within the mountain of mylonite, when followed downdip, coincides with the base of the ‘chlorite breccia’ brittle shear zone. Ultramylonite is preserved in places in the immediate lower plate of the subdetachment fault. The position and orientation of the subdetachment fault appears to have been controlled by an ultramylonite shear zone within the lower-plate mylonites. The rheological properties and orientation of this ultramylonite shear zone favored its reactivation as the brittle sole fault of the zone of chloritic brecciation.     

Chemical and Isotopic Characteristics of the Kuroko‐Forming Volcanism

The Miocene northeast Honshu magmatic arc, Japan, formed at a terrestrial continental margin via a stage of spreading in a back‐arc basin (23–17 Ma) followed by multiple stages of submarine rifting (19–13 Ma). The Kuroko deposits formed during this period, with most forming during the youngest rifting stage. The mode of magma eruption changed from submarine basalt lava flows during back‐arc basin spreading to submarine bimodal basalt lava flows and abundant rhyolitic effusive rocks during the rifting stage. The basalts produced during the stage of back‐arc basin spreading are geochemically similar to mid‐ocean ridge basalt, with a depleted Sr–Nd mantle source, whereas those produced during the rifting stage possess arc signatures with an enriched mantle source. The Nb/Zr ratios of the volcanic rocks show an increase over time, indicating a temporal increase in the fertility of the source. The Nb/Zr ratios are similar in basalts and rhyolites from a given rift zone, whereas the Nd isotopic compositions of the rhyolites are less radiogenic than those of the basalts. These data suggest that the rhyolites were derived from a basaltic magma via crystal fractionation and crustal assimilation. The rhyolites associated with the Kuroko deposits are aphyric and have higher concentrations of incompatible elements than do post‐Kuroko quartz‐phyric rhyolites. These observations suggest that the aphyric rhyolite magma was derived from a relatively deep magma chamber with strong fractional crystallization. Almost all of the Kuroko deposits formed in close temporal relation to the aphyric rhyolite indicating a genetic link between the Kuroko deposits and highly differentiated rhyolitic magma.     

The role of dextral transpressional faulting in the evolution of an early Carboniferous mafic–felsic plutonic and volcanic complex: Cobequid Highlands, Nova Scotia, Canada

The Wentworth plutonic complex, consisting of gabbro and granite, was emplaced in the earliest Carboniferous in the Cobequid shear zone of the northern Appalachians. The plutonic complex is coeval with a 5-km-thick pile of volcanic rocks. Early alkalic A-type granite correlates with thick felsic pyroclastics and minor basalt, which are overlain by 1.5-km-thick basalts that correlate with a large gabbro pluton that is intruded, in turn, by late granites. The basalt and gabbro are Fe-rich tholeiites. The geochemistry of the late granites suggests that they formed by differentiation of a granodioritic magma resulting from assimilation of early granite by the gabbroic magma. The Wentworth plutonic complex lies on the north side of the dextral Rockland Brook fault, near the western tip of wedge-shaped basement block of the Avalon terrane. Field observations of mesoscopic structures and map contacts show that the plutonic bodies at all structural levels are related to transpressive strike–slip faults. Dykes parallel to the mylonitic foliation in the Rockland Brook fault zone and at the contacts between igneous phases suggest that the plutons developed largely through dyke to pluton construction. The plutonism was initiated by dyking related to major faults under transpression that was partitioned into shear zone-bounded blocks, while the sinking of those blocks finally provided the space for mafic magma emplacement. Dyking was active over at least a 10-Ma time period. The overall location of plutonism in the Cobequid shear zone appears related to its position at the intersection of the shear zone bounding the southwestern margin of the Magdalen basin and the E–W transpressional contact of the Avalon and Meguma terranes. Magmatism enabled thermomechanical softening of the crust and the vertical and lateral extrusion of the wedge-shaped basement blocks, whose movement controlled the localisation of the voluminous magmatic activity.     

Geology and Alteration-Mineralization Characteristics of the Cibaliung Epithermal Gold Deposit, Banten, Indonesia

Abstract. The Cibaliung gold project is located at the central portion of the Neogene Sunda‐Banda magmatic arc. Gold‐silver mineralization in the area is hosted in a thick sequence of sub‐aqueous basaltic andesite volcanics with intercalated sediments intruded by sub‐volcanic andesite to diorite plugs and dykes, and subsequently cut by a cluster of diatreme breccias. These host rocks are unconformably overlain by dacitic tuffs, younger sediments and basalt flows. The gold prospects in Cibaliung occur within a NW‐trending structural corridor that is 3.5 km wide by at least 6 km long. It is fault‐bounded and is considered to be a graben. Two aligned NNW‐trending sub‐vertical shoots, Cikoneng and Cibitung, host the currently defined resource within the steeply dipping vein system with a minimum strike length of 1,300 m. As of July 2001, exploration has defined an inferred + indicated mineral resource of approximately 1.3 million tonnes at 10.42 g/t gold and 60.7 g/t silver at a 3 g/t Au cut‐off. This equates to approximately 435,000 ounces of gold and 2.54 million ounces of silver. Gold‐silver mineralization occurs as quartz veins characteristic of the low‐sulphidation epithermal adularia‐sericite type. Progressive dilation with a general increase in gold grade has produced multi‐stage veining and brecciation that grades from early to late stages as: pre‐mineral fluidized breccia, quartz vein stockwork, massive vein, crustiform vein, colloform‐crustiform vein with progressive increase in chloritic clay bands, clay‐quartz milled matrix breccias with a progressive increase in clay content, and synto post‐mineral fault gouge with vein clasts. Wall rock alteration is characterized by pro‐grade chlorite+adularia flooding that is locally overprinted by a low temperature argillic alteration (smectite, illite and mixed layered clays). Generally, the argillic alteration becomes weak with depth. The major mineral constituents of the veins are quartz, adularia and clay. In the early gold‐poor hydrothermal stages, quartz and adularia dominate with minor calcite and clay (smectite, poorly crystalline chlorite, interlayered chlorite‐smectite and illite‐smectite). In the later gold‐rich hydrothermal stages, clay with variable amounts of carbonate increases whereas the abundance of quartz and adularia decreases. Gold occurs mainly as electrum while silver occurs as argentite‐aguilarite‐naumannite and electrum, and rarely as native silver, sulphosalts and tellurides. Sulphides generally comprise <1 vol % of the vein, with pyrite as the most common species. Together with pyrite, traces of very fine‐grained base metal sulphides dominated by chalcopyrite, sphalerite and galena are in most cases intimately associated with electrum and silver minerals. Partial supergene oxidation generally extends down to about 200 m below the surface at Cikoneng and further down to more than 300 m at Cibitung. The hydrothermal system responsible for the gold‐silver mineralization in the area may be related to rhyolitic magmatism focused on a volcanic intrusive center during back arc rifting that formed a graben or pull‐apart basin. The dominant mechanism for the higher grade gold deposition is fluid mixing of up welling metal‐bearing hydrothermal solutions with relatively near surface cool, oxygenated condensate and/or steam‐heated meteoric fluids, as opposed to retrograde boiling. The strongly focused dilational structural environment is thought to have been the mechanism for focusing fluid flows, both up welling and descending, forming pipe‐like mineralized bodies in the rhomboidal dilation zones. It is interpreted that mineralization took place under low temperature conditions (<150–220d?C) at a minimum depth of around 200–250 m below the palaeo‐water table.     

河南省洛宁县三官庙金矿床构造控矿特征

三官庙金矿位于太华群与熊耳群接触带附近的似斑状花岗岩体南侧,矿床明显受断裂构造控制。矿区内拆离断裂带和层间滑脱断裂蚀变带发育,含金蚀变破碎带中的构造岩石为含矿主岩。矿体形态以较稳定的似层状为主,金矿物为银金矿等;金的载体矿物为黄铁矿、石英和方铅矿。围岩蚀变为硅化、黄铁矿化、方铅矿化、绿泥石化和绢云母化等,矿化类型属蚀变岩型金矿。在多期次强烈构造-岩浆活动、区域变质和混合岩化作用过程中,Au元素得以沿层间滑脱断裂蚀变带富集成矿。     

Magmatic source and metamorphic grade of metavolcanic rocks from the Granjeno Schist: was northeastern Mexico a part of Pangaea?

The geochemistry of the metavolcanic rocks from the Granjeno Schist in northeastern Mexico indicates an origin in different tectonic environments: mid‐ocean ridge and ocean island. High ratios of Hf/Th and Th/Nb (4.4–14 and 0.08–0.15), low ratios of LaN/YbN and LaN/SmN (0.74–1.7 and 0.60–1.4) and depleted LREE patterns in metabasalt display mid‐ocean ridge characteristics. In contrast, the pattern of trace‐element ratios and REEs in metabasalt and metapillow lava 60 km to the west indicates a magma source with ocean‐island basalt characteristics. Both areas were metamorphosed during the Late Carboniferous (300 ± 4 Ma). Estimated metamorphic conditions deduced from white mica and chlorite compositions, distinguish greenschist facies (350 °C and 4 kbar) for the mid‐ocean ridge basalt, and prehnite–pumpellyite facies (250 °C and 2.5 kbar) for the ocean‐island‐type basalt. This metamorphism took place at an active continental margin during Pennsylvanian time. Our new tectonic model, which differs from earlier models, suggests that the origin of the Granjeno Schist is related to a subduction zone located at the western margin of Pangaea, active after Laurentia–Gondwana collision. Copyright © 2015 John Wiley & Sons, Ltd.     

Co‐seismic Faults and Geological Hazards and Incidence of Active Fault of Wenchuan Ms 8.0 Earthquake,Sichuan, China

Abstract: There are two co-seismic faults which developed when the Wenchuan earthquake happened. One occurred along the active fault zone in the central Longmen Mts. and the other in the front of Longmen Mts. The length of which is more than 270 km and about 80 km respectively. The co-seismic fault shows a reverse flexure belt with strike of N45°–60°E in the ground, which caused uplift at its northwest side and subsidence at the southeast. The fault face dips to the northwest with a dip angle ranging from 50° to 60°. The vertical offset of the co-seismic fault ranges 2.5–3.0 m along the Yingxiu-Beichuan co-seismic fault, and 1.5–1.1 m along the Doujiangyan-Hanwang fault. Movement of the co-seismic fault presents obvious segmented features along the active fault zone in central Longmen Mts. For instance, in the section from Yingxiu to Leigu town, thrust without evident slip occurred; while from Beichuan to Qingchuan, thrust and dextral strike-slip take place. Main movement along the front Longmen Mts. shows thrust without slip and segmented features. The area of earthquake intensity more than IX degree and the distribution of secondary geological hazards occurred along the hanging wall of co-seismic faults, and were consistent with the area of aftershock, and its width is less than 40km from co-seismic faults in the hanging wall. The secondary geological hazards, collapses, landslides, debris flows et al., concentrated in the hanging wall of co-seismic fault within 0–20 km from co-seismic fault.     

陕西省铧厂沟金矿围岩蚀变和元素迁移特征

陕西省铧厂沟金矿床位于勉略缝合带以南,矿体受控于近东西向逆冲断层和韧脆性剪切带。本文以细碧岩矿带为例,系统研究了围岩蚀变分带及蚀变矿物组合,总结了矿床的蚀变分带模式。围岩蚀变以穿切细碧岩透镜体的剪切带为中心向外依次可划分为黄铁绢英岩化带、绢云碳酸盐化带和绿泥赤铁矿化带。蚀变矿物组合分别为黄铁矿＋铁白云石＋铬云母＋绢云母＋钠长石＋石英＋方解石、铁白云石＋绢云母＋钠长石＋石英±黄铁矿、（铁）绿泥石＋钠长石＋铁白云石＋赤铁矿＋钛铁氧化物＋石英±绿帘石。蚀变岩石组分迁移分析表明,在围岩蚀变过程中, SiO2、Na2O、Fe2O3T、MgO与Y等组分发生不同程度的迁出, K2O、CaO、Ba、Rb、Sr、Cr、Cu、Pb和挥发组分等迁入,并以黄铁绢英岩化带最为显著。金在成矿流体中以Au（HS）–2络合物迁移,成矿流体与富铁细碧岩之间的反应是金沉淀重要机制。     

One dimensional diffusion of radiogenic 87Sr and fluid transport of volatile elements across the margin of a metamorphosed Archaean basic dyke from Saglek,Labrador

An example of diffusion in a natural solid rock is described using ⁸⁷Sr as a tracer. The distribution of excess radiogenic ⁸⁷Sr across the contact of a metamorphosed basic dyke in a granodioritic gneiss is shown to fit closely to a mathematically modelled theoretical diffusion curve. It is suggested that the excess radiogenic Sr was generated by the breakdown of older Rb-rich biotite in the country rock to form chlorite during a late-stage greenschist facies metamorphism, and then taken up into a fluid phase migrating along the country rock — dyke interface. This fluid introduced silica, alkalies, light REE, H₂O, CO₂, N and Cl into the marginal zone of the dyke, probably during fluid migration along grain boundaries. The present irregular distribution of the volatile constituents across the contact and in the dyke excludes a diffusion controlled distribution. The distribution of volatiles probably reflects the influence of the existing mineralogy on the geochemical anomaly actually recorded from a post magmatic process. Evidence is presented that the diffusivity of radiogenic Sr was enhanced by the presence of a volatile phase.     

Sulphide mineralization and wall-rock alteration in ophiolites and modern oceanic spreading centres

Massive and stockwork Fe-Cu-Zn (Cyprus type) sulphide deposits in the upper parts of ophiolite complexes represent hydrothermal mineralization at ancient accretionary plate boundaries. These deposits are probable metallogenic analogues of the polymetallic sulphide deposits recently discovered along modern oceanic spreading centres. Genetic models for these deposits suggest that mineralization results from large-scale circulation of sea-water through basaltic basement along the tectonically active axis of spreading, a zone of high heat flow. The high geothermal gradient above 1 to 2 km deep magma chambers emplaced below the ridge axis drives the convective circulation cell. Cold oxidizing sea-water penetrating the crust on the ridge flanks becomes heated and evolves into a highly reduced somewhat acidic hydrothermal solvent during interaction with basaltic wall-rock. Depending on the temperature and water/rock ratio, this fluid is capable of leaching and transporting iron, manganese, and base metals; dissolved sea-water sulphate is reduced to sulphide. At the ridge axis, the buoyant hydrothermal fluid rises through permeable wall-rocks, and fluid flow may be focussed along deep-seated fractures related to extensional tectonic processes. Metal sulphides are precipitated along channelways as the ascending fluid undergoes adiabatic expansion and then further cooling during mixing with ambient sub-sea-floor water. Vigorous fluid flow results in venting of reduced fluid at the sea-floor/sea-water interface and deposition of massive sulphide. A comparison of sulphide mineralization and wall-rock alteration in ancient and modern spreading centre environments supports this genetic concept.Massive sulphide deposits in ophiolites generally occur in clusters of closely spaced (< 1–5 km) deposits. Individual deposits are a composite of syngenetic massive sulphide and underlying epigenetic stockwork-vein mineralization. The massive sulphide occurs as concordant tabular, lenticular, or saucer-shaped bodies in pillow lavas and pillow-lava breccia; massive lava flows, hyalcoclastite, tuff, and bedded radolarian chert are less commonly associated rock types. These massive sulphide zones are as much as 700 m long, 200 m wide, and 50 m thick. The pipe-, funnel-, or keel-shaped stockwork zone may extend to a dehpth of 1 km in the sheeted-dike complex. Several deposits in Cyprus are confined to grabens or the hanging wall of premineralization normal faults.Polymetallic massive sulphide deposits and active hydrothermal vents at medium- to fast-rate spreading centres (the East Pacific Rise at lat. 21°N, the Galapagos Spreading Centre at long. 86°W, the Juan de Fuca Ridge at lat. 45°N., and the Southern Trough of Guaymas Basin, Gulf of California) have interdeposit spacings on a scale of tens or hundreds of metres, and are spatially associated with structural ridges or grabens within the narrow (< 5 km) axial valleys of the rift zones. Although the most common substrate for massive sulphide accumulations is stacked sequences of pillow basalt and sheet flows, the sea-floor underlying numerous deposits in Guaymas Basin consists of diatomaceous ooze and terrigenous clastic sediment that is intruded by diabase sills. Mound-like massive sulphide deposits, as much as 30 m wide and 5m high, occur over actively discharging vents on the East Pacific Rise, and many of these deposits serve as the base for narrow chimneys and spires of equal or greater height. Sulphides on the Juan de Fuca Ridge appear to form more widespread blanket deposits in the shallow axial-valley depression. The largest deposit found to date, along the axial ridge of the Galapagos Spreading Centre, has a tabular form and a length of 1000 m, a width of 200 m, and a height of 30 m.The sulphide assemblage in both massive and vein mineralization in Cyprus type deposits is characteristically simple: abundant pyrite or, less commonly, pyrrhotite accompanied by minor marcasite, chalcopyrite, and sphalerite. With few exceptions, the composition of massive sulphide ranges from 0.3 to 5 wt. % Cu, from 0.1 to 3 wt. % Zn, from 0.5 to 30 ppm Au, and from 1 to 50 ppm Ag. The only common gangue minerals — quartz, chlorite, calcite, and gypsum generally make up less than 10 percent of the massive zone.Sulphide assemblages in massive sulphide samples recovered from the Juan de Fuca Ridge (abundant sphalerite, wurtzite, and pyrite; minor marcasite, chalcopyrite, and galena), East Pacific Rise (abundant sphalerite, pyrite, and chalcopyrite; minor wurtzite, marcasite, and pyrrhotite), and Guaymas Basin (abundant pyrrhotite and sphalerite; minor chalcopyrite) contrast with ophiolitic deposits. Bulk analyses of two zinc-rich sulphide samples from the Juan de Fuca Ridge yield the following average values: Zn, 56.6 wt. %; Cu, 0.2 wt. %; Pb, 0.15 wt. %; Fe, 4.9 wt. %; Ag, 260 ppm; and Cd, 775 ppm. Other minerals precipitated with sulphides at hydrothermal-vent sites include anhydrite, barite, gypsum, Mg-hydroxysulphate-hydrate, talc, sulphur, and amorphous silica.Massive sulphide lenses in some Cyprus-type deposits are underlain by a silica-rich zone consisting of massive quartz, opaline silica, red jasper, or chert mixed with disseminated and veinlet Fe-Cu-Zn sulphides. Some deposits are overlain by ochre, a gossanous Mn-poor Fe-rich bedded deposit composed of goethite, maghemite, quartz, and finely disseminated sulphide. In the Solomon Islands, ochre is overlain by siliceous sinter containing anhydrite, barite, and sulphide; the sinter contains anomalous Ag, Au, Cu, Zn, and Hg, and grades upward into Fe-rich chert and manganiferous wad. Amorphous Fe-Mn deposits (umber) and Mn-bearing chert enriched in Ba, Co, Cu, Ni, Cr, Pb, and Zn are common features near the top of ophiolite sequences. Although their genetic relation to sulphide mineralization is uncertian, they probably formed during off-axis hydrothermal discharge.At modern, medium-rate spreading centres, thin blankets of unconsolidated hydrothermal sediment have been observed near hydrothermal sulphide deposits. Basalt fragments recovered with massive sulphide from the Juan de Fuca Ridge have surfaces coated with smectite, magnetite, hematite, opaline silica, and Fe---Mn-oxyhydroxides. Sediment mounds composed largely of nontronitic clay and hydrated Fe and Mn oxides, and more distal metalliferous (Fe, Mn, Cu, Ni, Pb, Zn) sediment on the flanks of ceanridges, are also products of off-axis hydrothermal processes.Pillow lavas, diabase dikes, and gabbro in ophiolite sequences, and deeper, layer 2 basalt and diabase recovered from oceanic ridges, are altered to greenschist-facies assemblages (albite + chlorite + actinolite ± sphene ± quartz ± pyrite) during high-temperature sub-sea-floor hydro-thermal metamorphism near the axis of spreading. Chemical changes in the wall-rock during this large-scale sea-water/rock interactive episode depend on the water/rock ratio and temperature but generally include gains in Mg, Na and H₂O and losses of Ca. Subsequent low temperature sea-water/rock interaction away from the axis of spreading results in fracture-controlled zeolitefacies alteration, characterized by smectite, caledonite, zeolite, calcite, prehnite, hematite, marcasite, and pyrite. This retrograde alteration involves increases in total Fe, K, and H₂O and decreases in Mg and Si in the wallrock; Ca may be lost or gained.Wall-rock alteration in Cyprus type stockwork zones is more striking, in that the basalt and diabase between veins of Fe---Cu-Zn sulphides, quartz, and chlorite have undergone partial to complete conversion to fine-grained aggregates of quartz + chlorite + illite + pyrite; kaolinite and palygorskite may be present in minor amounts. Calcium and Na are strongly depleted; K, Al, Ti, Mn, and Ni are leached to a lesser extent; and Fe, S, Cu, Zn, and Co are strongly enriched in the wall-rock underlying massive sulphide. Mafic rocks at depth in the volcanic pile may be enriched in K, Rb, and Li, and depleted in Cu, Co, and Zn. Lavas lateral to and overlying massive sulphide mineralization may have low concentrations of Cu and high concentrations of Zn and Co relative to background levels.Mutual consideration of hydrothermal sulphide deposits and associated wall-rock alteration in ophiolites and at modern oceanic spreading centres can provide useful criteria for the development of regional exploration models for ophiolitic terrains.     

宁芜马山式黄铁矿床的地质特征和成因探讨

马山式黄铁矿是玢岩铁硫矿床早期成矿阶段的产物。矿石矿物成分简单,品位低,规模大,埋藏浅,伴生组分Co、Ni、Ga、Se、Te 等可综合利用。矿体产于宁芜早白垩世大王山组火山隆起构造的爆破角砾岩简附近,分上、中、下3个矿带,分别对应一套特征的蚀变岩蒂。从黄铁矿标型特征、测温数据、硫同位素及Co/Ni 比值等判断,矿床属火山喷气热液成因。形成于宁芜玢岩铁矿主体之前,找矿潜力很大。