库车前陆盆地流体化学,成因与流动

库车前陆盆地寒武系－第三系流体分析显示：寒武系－奥陶系和侏罗系油田水与白垩系－第三系有所差异,前者总矿化度相对较低,为９０ｇ／Ｌ～１１０ｇ／Ｌ;相对富Ｃａ＾２＋和ＨＣＯ３＾－;后者总矿化度介于７３ｇ／Ｌ～３１０ｇ／Ｌ,主要为１３０ｇ／Ｌ～２９０ｇ／Ｌ,相对富Ｋ＾＋Ｎａ＾＋和Ｃｌ＾－;而大宛齐第三系油田水则相对富Ｃａ。影响水化学演化的因素包括：膏盐类、沸石类矿物溶解以及白云化作用和富镁绿泥石形成等。     

塔中古生界油田水的成因和混合的证据

塔中地区奥陶纱、志留系和石炭系油田水的主元素、微量元素、＾８７Ｓｒ／＾８６Ｓｒ、δＤ、δ＾１８Ｏ及全岩的＾８７Ｓｒ／＾８６Ｓｒ测试结果表明,油田水相对于海水蒸发曲线,富Ｓｒ＾２＋、Ｃａ＾２＋、ＣＦ而贫Ｋ＾＋、Ｍｇ＾２＋,系水－岩反应改造的产物。远高于海水的＾８７Ｓｒ／＾８６Ｓｒ值表明油田水具有钾长石等矿物溶解的影响。油田水＾８７Ｓｒ／＾８６Ｓｒ－１／Ｓｒ的关系显示具有两种混合趋势,一种是奥陶系油田     

塔里木盆地油田水的成因与演化

塔里木盆地油田水具有高矿化度，相对贫镁，富钙，富锶等特点，在含油层中铝浓度高，铝可能以有机络合物形成存在。氢氧同位素测量值表明；侏罗系，三叠系及寒武系－奥陶系内幕油田水为成岩改造原生水；白垩系，第三系为同生沉积水蒸发五余；侏罗系与石炭系，三叠系与石炭系的不整合面附近及奥陶系顶部，塔中地区石炭系是淡水与成岩改造或蒸发残余原生水混合成因。     

荧光光度法测定地热水中的镁

研究了－羟基喹啉－５－磺酸与镁的荧光反应,在增效试剂溴化十六烷基三甲铵存在下,提高了反应的灵敏度,０￣０．３６ｍｇ／Ｌ范围内Ｍｇ＾２＋量与ΔＦ值呈良好的线性关系,检出限为２．６μｇ／Ｌ,其相对标准偏差为２．３％。本法用于地热水中镁的测定,取得了良好的效果。     

三溴偶氮胂—锇—溴酸钾催化光度法测定微量锇

在酸性介质中Ｏｓ（Ⅳ）对ＫＢｒＯ３氧化三溴偶氮胂的褪色反应有明显的催化作用，借此反应可在水相中直接测定微量锇。方法灵敏度高，锇的质量浓度为１０～２００μｇ／Ｌ时符合比尔定律，表观摩尔吸光系数为９１８×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。方法已用于贵金属精矿中锇的测定     

苏州地区I-A型花岗岩特征与成因的对比研究

应用岩石学、矿物学、地球化学及岩浆物理学等的理论和方法，对苏州地区Ｉ型和Ａ型花岗岩的特征及成因进行了对比研究，得出以下主要结论：Ｉ型花岗岩为晚侏罗世火山弧压性环境产物，侵位较深；而Ａ型者为Ａ２型花岗岩，为早白垩世造山后张性环境产物，侵位较浅，具晶洞构造．Ａ型比Ｉ型花岗岩以酸度、碱度、Ａｌ，Ｆ含量高而Ｈ２Ｏ＋含量低，以ＲＥＥ及不相容元素丰度高，负Ｅｕ异常强，而ｗ（ＬＲＥＥ）／ｗ（ＨＲＥＥ）低为特色．Ａ型者矿物结晶顺序先浅色后暗色，暗色矿物以富铁贫镁、ＲＥＥ分配系数高及负Ｅｕ异常明显及长石富碱贫钙，而与Ｉ型花岗岩不同．Ａ型者副矿物４０余种，属锆石－褐帘石－萤石型，锆石结晶温度高，（１１０），（１１１）晶面发育；而Ｉ型者仅１０余种，属榍石－锆石－磷灰石型，锆石结晶温度低，（１００），（３１１）晶面发育．Ｉ型花岗岩为幔源岩浆与下地壳部分熔融岩浆混合及ＡＦＣ作用产物，而Ａ型花岗岩为残余下地壳（麻粒岩相）熔融后分离结晶产物，二者并非同源岩浆演化关系．Ａ型比Ｉ型岩浆来源浅，酸度大，含水少；故岩浆密度小，粘度大，上升慢，冷凝长．受密度筛影响，Ａ型花岗岩岩浆房及侵位深度小于Ｉ型     

预富集柱—离子色谱法测定高纯水中痕量氟和氯

在国产离子色谱仪上加装填充有季铵型阴离子交换剂的预富集柱，所设计的流路和方法可将测定Ｆ－和Ｃｌ－的检出限分别降至０１７μｇ／Ｌ和０２７μｇ／Ｌ。测定精密度好，ＲＳＤ＜５％，方法满足反应堆堆芯冷却水中痕量Ｆ－和Ｃｌ－的检测要求。     

痕量银与meso－四（对－磺酸基苯基）卟啉显色反应的研究

研究了Ａｇ（Ｉ）与ｍｅｓｏ－四（对－磺酸基苯基）叶琳的光催化显色反应。在ｐＨｌ０的缓冲溶液中形成稳定的Ａｇ（Ｉ）－ＴＰＰＳ＿４－ＣＴＭＡＢ三元配合物，其最大吸收波长为４２６ｎｍ，组成为Ａｇ（１）ＴＰＰＳ＿４：ＣＴＭＡＢ＝１：１：２。表观摩尔吸光系数为２．７９×ｌ０￣５Ｌ·ｍｏｌ￣－１·ｃｍ￣－１，Ａｇ（１）的浓度在０～０．２μｇ／ｍｌ内符合比尔定律。基于此建立的测Ａｇ（Ｉ）方法灵敏度高，结合巯基棉分离干扰，可用于矿物中Ａｇ（Ｉ）的测定。     

河北平原东部地下碘水资源形成机理及其开发意义

河北平原东部平原第四系含水系统广泛赋存着地下碘水，碘含量一般２００－８００μｇ／Ｌ，最高可达１２５０μｇ／Ｌ，本文通过对地下碘水含水介质沉积环境及其地球化学特征、地下水中碘的水文地球化学特征等综合研究，认为本区地下碘水资源的民第 以来所发生的６次海侵密切相关。     

河北省赤城县小张家口超基性岩体主要特征和时代

小张家口超基性岩体是华北板块北缘超基性岩带的一个典型岩体，岩相分带明显，由透辉岩、闪辉岩、二辉岩和纯橄岩组成，主要矿物组成包括透辉石、贵橄榄石、角闪石等。化学成分上富ＦｅＯ、ＣａＯ而贫ＭｇＯ，ｍ／ｆ平均２．２１，属铁质或富铁质超基性岩。稀土分布形式为轻稀土富集型，具不显著的负铕异常，微量元素以富含不相容元素Ｒｂ、Ｔｉ、Ｓｒ、Ｖ等而贫Ｃｒ、Ｃｏ、Ｎｉ等相容元素为特征。Ｓｍ－Ｎｄ等时年龄１８３７Ｍａ，Ｎｄ（ｔ）为十１０．７２。该岩体由亏损型地幔部分熔融所产生的岩浆经结晶分异作用而形成。     

The terrestrial fauna of the Late Triassic Pant-y-ffynnon Quarry fissures,South Wales,UK and a new species of Clevosaurus (Lepidosauria: Rhynchocephalia)

Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.     

The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts

The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H₂O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H₂O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.     

Quaternary stresses revealed by calcite twinning inversion: insights from observations in the Savonnières underground quarry (eastern France)

Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ₁ roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).     

HYDROGEOLOGY

正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level     

METAMORPHIC PETROLOGY

正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),     

SERIALS

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GEOPHYSICAL EXPLORATION

正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-     

QUATERNARY GEOLOGY & GEOMORPHOLOGY

正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-     

PETROLEUM GEOLOGY

正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)     

GEOCHEMISTRY

正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861