Spatio-temporal trends of heavy metals and source apportionment in Tolo Harbour,Hong Kong

This study provided a picture of the spatial and temporal distributions of Cr, Co, Ni Cu, Zn, As, Cd and Pb in bottom sediments of Tolo Harbour. The concentrations of the eight heavy metals differed significantly between sites due to the poor tidal flushing in Tolo Harbour. The levels of Cu, Zn, Cd and Pb were generally enriched in sediments from inner Tolo Harbour, while sediments from outer Tolo Harbour (Tolo Channel) had higher levels of Cr, Co and Ni. The redox sensitive element arsenic showed no distinct spatial pattern in Tolo Harbour. The decreasing levels of Cu, Zn, Pb and Cd in sediments with increasing distance from land demonstrated a typical diffusion pattern from land to the direction of sea. Two hot spots of Cu, Zn, Pb and Cd in sediments were located near Tai Po and Sha Tin new town, indicating that Cu, Zn, Pb and Zn were from land-derived sources. The sites with relatively high levels of Cr, Co and Ni in sediments were located in areas close to waste spoil in sea floor. The natural and anthropogenic inputs from Sha Tin and Tai Po to Tolo Harbour were mostly responsible for Cu, Zn, Cd and Pb enrichment in sediments from inner Tolo Harbour. The waste spoil in sea floor was believed to contribute to the Cr, Co and Ni in outer Tolo Harbour. The results of correlation coefficient between the eight heavy metals showed that Cu, Zn, Cd and Pb were strongly positively correlated, and Cr, Co and Ni were also significantly correlated with each other. The best explanation of strong correlation was their similar source. As, however, is not well correlated with the other seven heavy metals. The average concentrations of Cu and Zn displayed general increasing trends from 1978 to 2006 in Tolo Harbour, while the mean levels of Cr and Pb displayed a substantial decrease from 1978 to 1987, then a slight increase after 1987. No distinct temporal trends of the concentrations of Ni and As were observed from 1978 due to the inconsecutive data. On the other hand, the increasing trends of Cr, Cu, Zn, Cd and Pb were observed since 1996.     

Ecosystem Engineering Effects of <Emphasis Type="Italic">Aster tripolium</Emphasis> and <Emphasis Type="Italic">Salicornia procumbens</Emphasis> Salt Marsh on Macrofaunal Community Structure

This paper examines how perennial Aster tripolium and annual Salicornia procumbens salt marshes alter the biomass, density, taxon diversity, and community structure of benthic macrofauna, and also examines the role of elevation, sediment grain size, plant cover, and marsh age. Core samples were collected on a fixed grid on an intertidal flat in the Westerschelde estuary (51.4° N, 4.1° E) over 5 years (2004–2008) of salt marsh development. In unvegetated areas, macrobenthic biomass, density, and taxon diversity were highest when elevation was highest, benthic diatoms were most abundant, and sediment median grain size was smallest. In contrast, in salt marsh areas, macrobenthic biomass and taxon diversity increased with median grain size, while the effects of elevation and diatom abundance on macrobenthic biomass, density, and diversity were not significant. In fine sediments, macrofaunal community structure in the salt marsh was particularly affected; common polychaetes such as Nereis diversicolor, Heteromastus filiformis, and Pygospio elegans had low abundance and oligochaetes had high abundance. Marsh age had a negative influence on the density of macrofauna, and A. tripolium stands had lower macrofaunal densities than the younger S. procumbens stands. There were no significant effects of marsh age, plant cover, and vegetation type on macrobenthic biomass, taxon diversity, and community structure. The results highlight that ecosystem engineering effects of salt marsh plants on macrofauna are conditional. Organic enrichment of the sediment and mechanical hindering of macrofaunal activity by plant roots are proposed as plausible mechanisms for the influence of the salt marsh plants on macrofauna.     

Effects of sediment contaminants and environmental gradients on macrobenthic community trophic structure in Gulf of Mexico estuaries

Macrobenthic communities from estuaries throughout the northern Gulf of Mexico were studied to assess the influence of sediment contaminants and natural environmental factors on macrobenthic community trophic structure. Community trophic data were also used to evaluate whether results from laboratory sediment toxicity tests were effective indicators of site-specific differences in benthic trophic structure. A multiple regression model consisting of five composite factors (principal components) was used to distinguish the effects of sediment contaminants and environmental variables on benthic community trophic structure. This model explained 33.5% of the variation in macrobenthic trophic diversity (p<0.001), a variable derived from the distribution of taxas among nine original trophic categories. A significant negative relatinship was found between principal components reflecting concentrations of sediment contaminants and macrobenthic trophic diversity. Detritivores including surface deposit-feeders (SDF), subsurface deposit-feeders (SSDF), and filter feeders (FF) were numerically dominant at 201 random sites, each group accounting for 25–30% of total macrobenthic abundance. The relative abundance of SDFs was considerably lower (12.1±2.9% to 17.1±4.4%) at sites where sediment contaminant concentrations exceeded minimum biological effects thresholds (ER-L values from Long and Morgan 1990 than at sites sampled at random (29.3±5.7%). SSDFs were proportionally more abundant at contaminated sites (42.0±7.7% to 63.6±10.3%) versus random sites (27.5±5.7%), and the relative abundance of SSDFs was positively correlated with concentrations of particular contaminants. Benthic trophic structure was also found to be a function of salinity, where the proportion of SSDFs was negatively correlated with salinity (p=0.035, r=−0.223, n=326). Silt-clay content loaded fairly strongly on the first principal component, but trophic structure parameters were not significantly correlated with sediment grain size or dissolved oxygen (perhaps due, in part, to covariation). Results from laboratory sediment toxicity tests with mysids were predictive of differences in macrobenthic trophic structure in situ (i.e., mysid survival was negatively correlated with %SSDF; p<0.001, r=−0.292, n=326). Results from laboratory sediment toxicity tests with ampeliscid amphipods were not indicative of site-specific differences in benthic trophic structure.     

围海造地工程对香港维多利亚港现代沉积作用的影响

对采自香港维多利亚港的 4个 6m长的沉积柱状样作了2 10 Pb及Pb、Zn、Cu含量分析。结果表明,维多利亚港开阔区域现代沉积速率在 0.3～ 2cm/a之间变化,西部大于东部。在九龙海峡主航道上,基本上处于冲淤平衡状态。由于近百年来围海造地、海岸工程建设,使维多利亚港的岸线发生了较大的变化,在台风避风塘等潮流作用较弱的区域及靠近城市排污口的地方沉积速率可达 3～ 5cm/a,这表明围海造地、海岸工程等造成的岸线变化是影响维多利亚港堆积侵蚀的主要因素。Pb、Zn、Cu等重金属在沉积柱状样中的分布表明,在沉积速率较快的区域,重金属的污染也较为严重。     

A benthic index of environmental condition of Gulf of Mexico estuaries

An index was developed for estuarine macrobenthos in the Gulf of Mexico that discriminated between areas with degraded environmental conditions and areas with undegraded or reference conditions. Test sites were identified as degraded or reference based on criteria for dissolved oxygen levels, sediment toxicity tests, and sediment contamination. Discriminant analysis was used to identify a suite of measures of benthic community composition and diversity that would most successfully distinguish degraded from undegraded sites. The resultant benthic index was composed of a linear combination of three factors: the Shannon-Wiener diversity index, the proportion of total benthic abundance as tubificid oligochaetes, and the proportion of total benthic abundance as bivalve molluscs. This index was used to evaluate the spatial patterns of degraded benthic resources in the Gulf of Mexico.     

Effects of low dissolved oxygen events on the macrobenthos of the lower Chesapeake Bay

The effects of low dissolved oxygen or hypoxia (<2 mg l^?1) on macrobenthic infaunal community structure and composition in the lower Chesapeake Bay and its major tributaries, the Rappahannock, York, and James rivers are reported. Macrobenthic communities at hypoxia-affected stations were characterized by lower species diversity, lower biomass, a lower proportion of deep-dwelling biomass (deeper than 5 cm in the sediment), and changes in community composition. Higher dominance in density and biomass of opportunistic species (e.g., euryhaline annelids) and lower dominance of equilibrium species (e.g., long-lived bivalves and maldanid polychaetes) were observed at hypoxia-affected stations. Hypoxia-affected macrobenthic communities were found in the polyhaline deep western channel of the bay mainstem north of the Rappahannock River and in the mesohaline region of the lower Rappahannock River. No hypoxic effects on the infaunal macrobenthos were found in the York River, James River, or other deep-water channels of the lower Chesapeake Bay.     

Relationship between Hypoxia and Macrobenthic Production in Chesapeake Bay

Human development has degraded Chesapeake Bay's health, resulting in an increase in the extent and severity of hypoxia (≤2 mg O₂ l^-1). The Bay's hypoxic zones have an adverse effect on both community structure and secondary production of macrobenthos. From 1996 to 2004, the effect of hypoxia on macrobenthic production was assessed in Chesapeake Bay and its three main tributaries (Potomac, Rappahannock, and York Rivers). Each year, in the summer (late July???early September), 25 random samples of the benthic macrofauna were collected from each system, and macrobenthic production in the polyhaline and mesohaline regions was estimated using Edgar's allometric equation. Fluctuations in macrobenthic production were significantly correlated with dissolved oxygen. Macrobenthic production was 90 % lower during hypoxia relative to normoxia. As a result, there was a biomass loss of ~7,320–13,200 metric tons C over an area of 7,720 km², which is estimated to equate to a 20 % to 35 % displacement of the Bay's macrobenthic productivity during the summer. While higher consumers may benefit from easy access to stressed prey in some areas, the large spatial and temporal extent of seasonal hypoxia limits higher trophic level transfer, via the inhibition of macrobenthic production. Such a massive loss of macrobenthic production would be detrimental to the overall health of the Bay, as it comes at a time when epibenthic and demersal predators have high-energy demands.     

Impacts of human activities and natural inputs on heavy metal contents of many coral reef environments along the Egyptian Red Sea coast

In order to monitor the heavy metals effect coming from both human activities and natural inputs on coral reef environments of the Egyptian Red Sea coast, metal concentrations in thirty- eight coral reef species and nearby sediment samples collected from seven studied sites were analyzed. Four sites represent impacted areas; included from south to north Hamrawein, Safaga and Hurghada Harbours and Ras El-Behar Area. Wadi El-Gemal represents natural input area while Qola'an and Kalawye Reefs are the control areas. Heavy metal contents were measured in both coral skeletons and nearby marine sediments. Both impact areas as well as natural inputs area recorded the highest values of metals compared with the control ones. However, heavy metal contents recorded high values in sediments of Hamrawein Harbour, while coral species recorded high values in Wadi El-Gemal area. Generally, metal variations in coral reef species reflect natural conditions and human activity. On the other hand, there are no clear relationships between concentrations of heavy metals in coral reef species and those in sediments.     

Composition of macrobenthos from the Central Indian Ocean Basin

The deep sea is well known for its high faunal diversity. But the current interest in its abundant polymetallic nodules, poses a threat to the little known benthic organisms surviving in this unique environment. The present study is the first attempt to document the Indian Ocean abyssal benthic diversity of macroinvertebrates and to investigate its relation to the surface primary production (chl-a), sediment labile organic matter, organic carbon and texture. The present study is based on 87 individuals. Altogether 39 macroinvertebrate genera were obtained from water depths of 4500–5500 m from 23 box cores. Reduction in macrobenthic density was seen towards the southern latitudes. The area was dominated by deposit feeding macrobenthos. Vertically, the fauna was distributed down to 30 cm depth, with the highest faunal density in the top 2–5 cm sediment section. The values for population density were strongly correlated with surface water chl-a and sediment protein, indicating supply of fresh organic matter as a critical factor for maintaining the deep sea benthic diversity and abundance.     

Impact of ‘Chitra’ Oil Spill on Tidal Pool Macrobenthic Communities of a Tropical Rocky Shore (Mumbai,India)

A collision between the ships MSC Chitra and MV Khalijia 3 in the mouth region of Mumbai Harbour led to a leakage of around 800 t of fuel oil in August 2010, affecting the rocky intertidal region of Colaba. To evaluate the impact of this catastrophic event on the resident biota, a 15-month-long sampling programme was initiated in the oil-affected area immediately after the spill. Petroleum hydrocarbons in water and sediment organic carbon values were high just after the oil spill but subsequently decreased in the following months. In total, 70 macrobenthic taxa were identified. Univariate diversity indices indicated that while the ecological status of the site, albeit briefly, was affected during August 2010, a healthy environment prevailed subsequently. Cluster and multi-dimensional scale (MDS) analyses distinctly segregated the oil impacted monsoon months from the other sampling months. BIOENV analyses indicated that petroleum hydrocarbons and organic carbon were the anthropogenic parameters influencing macrobenthic community structure. Benthic Opportunistic Polychaetes Amphipods (BOPA) index was used to evaluate the ecological quality of the study area as the index is sensitive to oil pollution. Low BOPA values throughout the study period indicated that the environment was good with few opportunistic species. Comparison with past data revealed that the oil spill did not have long-term deleterious effects on the macrobenthic species diversity of this rocky beach, and reasons thereof are discussed.     

Recolonization of Intertidal Infauna in Relation to Organic Deposition at an Oyster Farm in Atlantic Canada—A Field Experiment

A field experiment was carried out to investigate the patterns of macrobenthic recolonization and to determine the effects of biodeposition on benthic communities at an intertidal oyster culture site in New Brunswick, Canada. Total organic deposition in azoic organic-free sediment trays was generally higher within the farm compared to reference sites. Two weeks after deployment of trays, total organic content had reached 1.1%. The abundance, species number, and diversity of the macrobenthic community were positively correlated with the total organic content in the experimental trays, but the correlations between community parameters and organic content were negative in the ambient sediment. The results suggest that organic matter in sediment may have positive effects on macrobenthic infauna at low levels as an additional food source but may be harmful to benthic animals at high levels. This study also indicates that location in the intertidal zone is a major parameter affecting the community structure of macrobenthic colonization.     

Long-term variation in mesohaline Chesapeake Bay macrobenthos: Spatial and temporal patterns

Macrobenthos, sediments, and environmental conditions were sampled in the mesohaline region of western Chesapeake Bay (1971–1984) and the Potomac River (1980–1984). The survey data were used to quantify variation in macrobenthos and the physicochemical environment due to seasonal dynamics, spatial pattern (regional and local), and annual as well as long-term trends. Field experiments were conducted to test hypotheses suggested by the analysis of the survey data. Long-term and regional changes in the physiochemical environment, particularly salinity and dissolved oxygen concentration, had major influences on regional and long-term abundance patterns of macrobenthos. Two major species groups were identified along the mesohaline salinity gradient: those characteristic of high and low mesohaline salinities. Salinity increased and dissolved oxygen concentration below the pycnocline declined over the 14 yr. Estuarine endemic and euryhaline marine species concomitantly decreased in abundance. Opportunist species responded to increasing salinity and declining oxygen levels with increases in abundance. Predation on macrobenthos by fish and crabs affected the amplitude of annual recruitment pulses. Food availability apparently determined the magnitude of summer macrobenthic mortality. Spring was a critical period for the establishment of distributional patterns. The macrobenthos of the upper Chesapeake Bay was relatively stable over the study period mainly due to the stability and predictability of physicochemical processes controlling recruitment patterns.     

Trophic structure of macrobenthic communities in the Calcasieu estuary,Louisiana

Trophic groups were used to investigate broad patterns and predict species interactions of macrobenthic assemblages in Calcasieu Estuary, Louisiana. Macrobenthic assemblages of the estuary were numerically dominated by deposit-feeding species. Surface-deposit feeders were the most abundant macrobenthos of the upper estuary, subsurface-deposit feeders dominated the lower estuary, and a trophically well-mixed assemblage inhabited the middle estuary. There were periodic shifts in species dominance within each region, but the shifts were without temporal pattern and seldom led to changes in trophic structure of the region. The macrobenthic assemblages of the upper estuary were dominated by several early-colonizing species which switched feeding modes with changes in water flow, suggesting that disturbances in the upper estuary had a direct effect on macrobenthic communities. Disturbances also may have eliminated macrobenthic species before they could establish a well-mixed community. The presence of trophically mixed communities in the middle estuary probably was indicative of fewer disturbances there. The dominance by subsurface-deposit feeders in the lower estuary probably indicates that sedimentary food in Calcasieu Lake was seldom utilized at the sediment-water interface. Rather, most food became buried and was available only to subsurface-deposit feeders.     

Heavy metals in the Ventspils Harbour: normalization based on a multi-parameter dataset

Heavy metals were investigated in the sediments of the Ventspils Harbour located in north-west Latvia (eastern Baltic Sea). Sediment samples were analysed for major and trace metals by ICP-AES, supplemented by inorganic and organic carbon as well as grain-size distributions. Principal component analysis of the data resulted in two main parameter clusters associated with Ca- and Al-rich material and indicated differing behaviour of Pb, Cu, Zn, N and P. Normalization with respect to Ca and Al by least absolute values regression removed the spatial pattern of sediment metal content in the harbour. High residual concentrations at individual sites were associated with local contaminations, whereas the overall concentration pattern was governed by the transport of riverine fine material. Dilution with coarser, quartz-rich marine sediments led to a pronounced heavy metal concentration drop towards the harbour gates. High mixing was an important feature of sediment dynamics in the Ventspils Harbour, hampering contaminant source identification and sediment monitoring.     

Spatial distribution of heavy metals in surficial sediments from Guanabara Bay: Rio de Janeiro, Brazil

Ninety-two surface sediment samples were collected in Guanabara Bay, one of the most prominent urban bays in SE Brazil, to investigate the spatial distribution of anthropogenic pollutants. The concentrations of heavy metals, organic carbon and particle size were examined in all samples. Large spatial variations of heavy metals and particle size were observed. The highest concentrations of heavy metals were found in the muddy sediments from the north western region of the bay near the main outlets of the most polluted rivers, municipal waste drainage systems and one of the major oil refineries. Another anomalous concentration of metals was found adjacent to Rio de Janeiro Harbour. The heavy metal concentrations decrease to the northeast, due to intact rivers and the mangrove systems in this area, and to the south where the sand fraction and open-marine processes dominate. The geochemical normalization of metal data to Li or Al has also demonstrated that the anthropogenic input of heavy metals have altered the natural sediment heavy metal distribution.     

Changes in benthos following the clean-up of a severely metalpolluted cove in the Hudson River estuary: Environmental restoration or ecological disturbance?

We studied changes in macrobenthic communities following the environmental clean-up of metal-polluted (cadmium, nickel, and cobalt) sediments in Foundry Cove, a small inlet within the Hudson River estuary of New York. We used a BACI-style experiment to test the hypotheses that high levels of cadmium in sediments change macrobenthic assemblages relative to unpolluted areas, and removal of metals (especially cadmium) by dredging will restore the benthos, such that benthic fauna in Foundry Cove are not different from unpolluted areas. In 1984, prior to the restoration work, there were no significant differneces between macrobenthic assemblages in polluted and unpolluted locations, indicating that cadmium had little effect on community structure. The lack of an observed toxicity effect may have been caused by the compensatory evolution of resistance to cadmium in dominant organisms. Six years after the restoration work and despite a substantial reduction in metal pollution, there were lower abundances of oligochaetes, nematodes, and chironomids and a higher abundance of polychaetes at Foundry Cove relative to reference locations. Correlative analyses identified greater sediment compaction caused by dredging at Foundry, Cove as a possible cause of faunal differences. The results demonstrate that it is difficult to accurately predict, the effects of anthropogenic disturbances and restorations in complex natural systems and that unforeseen side effects are inevitable. Documenting these unpredicted effects and experimentally understanding their causes in past restorations will greatly improve the success and cost-effectiveness of future projects of a similar type.     

Heavy metal distribution between parent soil and pepper in an unpolluted area,Hainan Island,China

Consuming edible plants contaminated by heavy metals transferred from soil is an important pathway for human exposure to environmental contaminants. In the past several decades, heavy metal accumulation in contaminated soil has been widely studied; however, few researches investigated the background levels of metals in plants and evaluated the difference in plants grown in soils produced from different parent rocks. In this study, a systemic survey of heavy metal distribution and accumulation in the soil–pepper system was investigated in an unpolluted area, Hainan Island, China. Levels of Cu, Pb, Zn and Cd were measured in soils and pepper fruits from five representative pepper-growing areas with different soil parent rocks (i.e. basalt, granite, sedimentary rock, metamorphic rock and alluvial deposits). Average concentrations of Cu, Pb, Zn and Cd in pepper fruits were 11.52, 0.84, 8.77 and 0.05 mg/kg, respectively. The concentrations of heavy metals in soils are controlled by the parent materials and varied greatly from in different areas. Heavy metal contents in all pepper samples were lower than the Chinese maximum contaminant levels. The relationship between heavy metals in soils and biological absorption coefficient (BAC) of pepper fruits suggests that the uptake ability of pepper for soil metals depends mainly on the physiological mechanism, while in some cases, the soil types and supergene environment are also important.     

Is geomorphic zonation a useful predictor of patterns of benthic infauna in intermittent estuaries in New South Wales, Australia?

Geomorphic classifications of estuaries are used to guide management. One classification recognizes four geomorphic zones within estuaries: marine tidal delta, central mud basin, fluvial delta, and riverine channel. It is assumed that the biota is controlled primarily by salinity and characteristics of sediments. By ignoring small-scale variability, the number of species and diversity are predicted to be homogeneous within each zone, but to decrease with increasing distance from the sea. Data from surveys of macrobenthos and meiobenthos in four intermittently closed coastal lakes in New South Wales, Australia, were used to test these predictions. Assemblages of macrobenthos and meiobenthos in different localities within marine tidal deltas were different and also differed from those in fluvial deltas. Several families of polychaetes, in addition to nematodes and oligochaetes, distinguished between macrobenthic assemblages. Assemblages of meiobenthos were distinguished mainly by nematodes, turbellarians, and copepods. Numbers of macrobenthic species decreased by more than 50% between localities near the mouth and those further upstream, even though they were located within the same geomorphic zone, before increasing to a maximum in fluvial deltas. For meiobenthos, similar trends were evident, but differences were smaller. Half of the macrobenthic taxa and all but one among the meiobenthos exhibited the predicted decrease in density with increasing distance from the sea. There were no consistent correlations with physical factors (median grain size, percent clay, organic content, or salinity) at the level of assemblages or of individual taxa. Physical classifications fail to predict patterns in benthos, possibly because they do not incorporate linkages between physical and ecological processes at appropriate spatial and temporal scales.     

Heavy metal pollution of coastal river sediments, north-eastern New South Wales, Australia: lead isotope and chemical evidence

 Heavy metal and metalloid concentrations within stream-estuary sediments (<180-μm size fraction) in north-eastern New South Wales largely represent natural background values. However, element concentrations (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn) of Hunter River sediments within the heavily industrialized and urbanized Newcastle region exceed upstream background values by up to one order of magnitude. High element concentrations have been found within sediments of the Newcastle Harbour and Throsby Creek which drains into urbanized and light industry areas. Observed Pb enrichments and low ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁶Pb/²⁰⁴Pb ratios are likely caused by atmospheric deposition of Pb additives from petrol and subsequent Pb transport by road run-off waters into the local drainage system. Sediments of the Richmond River and lower Manning, Macleay, Clarence, Brunswick and Tweed River generally display no evidence for anthropogenic heavy metal and metalloid contamination (Ag, As, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Zn). However, the rivers and their tributaries possess localized sedimentary traps with elevated heavy metal concentrations (Cu, Pb, Zn). Lead isotope data indicate that anthropogenic Pb provides a detectable contribution to investigated sediments. Such contributions are evident at sample sites close to sewage outlets and in the vicinity of the Pacific Highway. In addition, As concentrations of Richmond River sediments gradually increase downstream. This geochemical trend may be the result of As mobilization from numerous cattle-dip sites within the region into the drainage system and subsequent accumulation of As in downstream river and estuary sediments. Received: 5 September 1997 · Accepted: 4 November 1997     

Quantitative identification and source apportionment of anthropogenic heavy metals in marine sediment of Hong Kong

Based on ten heavy metals collected twice annually at 59 sites from 1998 to 2004, enrichment factors (EFs), principal component analysis (PCA) and multivariate linear regression of absolute principal component scores (MLR-APCS) were used in identification and source apportionment of the anthropogenic heavy metals in marine sediment. EFs with Fe as a normalizer and local background as reference values was properly tested and suitable in Hong Kong, and Zn, Ni, Pb, Cu, Cd, Hg and Cr mainly originated from anthropogenic sources, while Al, Mn and Fe were derived from rocks weathering. Rotated PCA and GIS mapping further identified two types of anthropogenic sources and their impacted regions: (1) electronic industrial pollution, riparian runoff and vehicle exhaust impacted the entire Victoria Harbour, inner Tolo Harbour, Eastern Buffer, inner Deep Bay and Cheung Chau; and (2) discharges from textile factories and paint, influenced Tsuen Wan Bay and Kwun Tong typhoon shelter and Rambler Channel. In addition, MLR-APCS was successfully introduced to quantitatively determine the source contributions with uncertainties almost less than 8%: the first anthropogenic sources were responsible for 50.0, 45.1, 86.6, 78.9 and 87.5% of the Zn, Pb, Cu, Cd and Hg, respectively, whereas 49.9% of the Ni and 58.4% of the Cr came from the second anthropogenic sources.