The first tephra evidence for a Late Glacial explosive volcanic eruption in the Arxan-Chaihe volcanic field (ACVF), northeast China

A 5 mm thick tephra layer has been identified in the lacustrine sediments of Moon Lake in the Arxan-Chaihe volcanic field (ACVF) in Greater Khingan Mountains (NE China). The visible tephra layer is clearly revealed as a distinct peak in magnetic susceptibility measurements. The tephra layer consists mainly of brown vesicular glass shards and minor amounts of plagioclase, olivine and clinopyroxene. Major and minor element analysis has been carried out on the glass shards and plagioclase minerals. Glass shards show low concentrations of K₂O, similar to the eruptive products derived from post-Miocene volcanoes of the ACVF. The plagioclase phenocrysts in both lava and tephra from ACVF, and in the tephra recorded in Moon Lake are labradorites. During the Late Pleistocene to Holocene, there were also extensive explosive eruptions in the nearby Nuominhe volcanic field (NVF). Volcanic rocks from the ACVF are easily distinguished from those derived from the NVF, having distinctly different K₂O concentrations. This compositional variation is likely the result of different magmatic processes operating in the ACVF and NVF. Radiocarbon dating on organic materials from the lacustrine sediments dates the tephra layer to ca. 14,200 cal yrs BP, which implies that it was generated by a previously unknown Late Pleistocene explosive eruption in the ACVF. These results, for the first time, give a direct tephra record in this area, and suggest that identification of further tephra and/or cryptotephra in local sedimentary basins such as crater lakes of scoria cones and maars will be significant for dating the Late Pleistocene to Holocene volcanic eruptions and will help to establish a detailed record of the volcanic activity in the ACVF. The newly discovered tephra layer also provides a dated tephrochronological marker layer, which will in future studies provide a means to synchronise local sedimentary records of the climatically variable Late Glacial.     

Explosive silicic volcanism in Iceland and the Jan Mayen area during the last 6 Ma: sources and timing of major eruptions

Fifty-three major explosive eruptions on Iceland and Jan Mayen island were identified in 0–6-Ma-old sediments of the North Atlantic and Arctic oceans by the age and the chemical composition of silicic tephra. The depositional age of the tephra was estimated using the continuous record in sediment of paleomagnetic reversals for the last 6 Ma and paleoclimatic proxies (δ¹⁸O, ice-rafted debris) for the last 1 Ma. Major element and normative compositions of glasses were used to assign the sources of the tephra to the rift and off-rift volcanic zones in Iceland, and to the Jan Mayen volcanic system. The tholeiitic central volcanoes along the Iceland rift zones were steadily active with the longest interruption in activity recorded between 4 and 4.9 Ma. They were the source of at least 26 eruptions of dominant rhyolitic magma composition, including the late Pleistocene explosive eruption of Krafla volcano of the Eastern Rift Zone at about 201 ka. The central volcanoes along the off-rift volcanic zones in Iceland were the source of at least 19 eruptions of dominant alkali rhyolitic composition, with three distinct episodes recorded at 4.6–5.3, 3.5–3.6, and 0–1.8 Ma. The longest and last episode recorded 11 Pleistocene major events including the two explosive eruptions of Tindfjallajökull volcano (Thórsmörk, ca. 54.5 ka) and Katla volcano (Sólheimar, ca. 11.9 ka) of the Southeastern Transgressive Zone. Eight major explosive eruptions from the Jan Mayen volcanic system are recorded in terms of the distinctive grain-size, mineralogy and chemistry of the tephra. The tephra contain K-rich glasses (K₂O/SiO₂>0.06) ranging from trachytic to alkali rhyolitic composition. Their normative trends (Ab–Q–Or) and their depleted concentrations of Ba, Eu and heavy-REE reflect fractional crystallisation of K-feldspar, biotite and hornblende. In contrast, their enrichment in highly incompatible and water-mobile trace elements such as Rb, Th, Nb and Ta most likely reflect crustal contamination. One late Pleistocene tephra from Jan Mayen was recorded in the marine sequence. Its age, estimated between 617 and 620 ka, and its composition support a common source with the Borga pumice formation at Sør Jan in the south of the island.     

Laser-ablation ICP-MS zircon U-Pb ages for key Pliocene-Pleistocene tephra beds in unglaciated Yukon and Alaska

Tephrochronology is one of the most effective ways to correlate and date Quaternary deposits across large distances. However, it can be challenging to obtain direct ages on tephra beds when they are beyond the limit of radiocarbon dating, do not contain mineral phases suitable for ⁴⁰K-⁴⁰Ar (or ⁴⁰Ar/³⁹Ar) dating, or suitable glass shards for fission-track dating are not available. Zircon U-Pb dating by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) is an emerging technique for dating young (<1 Ma) tephra. Here, we demonstrate that LA-ICP-MS zircon U-Pb dating can produce reliable ages for key tephra beds found in Yukon and Alaska. We assessed five different techniques for calculating tephra maximum depositional ages from zircon U-Pb ages for eight tephra beds. Our preferred zircon U-Pb ages (reported with 2σ uncertainties), based on a Bayesian model for calculating maximum depositional ages, are broadly consistent with previously established chronology constructed from stratigraphy, paleomagnetism, and/or glass fission track and ⁴⁰Ar/³⁹Ar ages: Biederman tephra (178 ± 17 ka), HP tephra (680 ± 47 ka), Gold Run tephra (688 ± 44 ka), Flat Creek tephra (708 ± 43 ka), PA tephra (1.92 ± 0.06 Ma), Quartz Creek tephra (2.62 ± 0.08 Ma), Lost Chicken tephra (3.14 ± 0.07 Ma), and GI tephra (542 ± 64 ka). We also present newly revised glass fission-track and ⁴⁰Ar/³⁹Ar ages recalculated from previous determinations using updated ages for the Moldavite tektite and Fish Canyon Tuff standards, and updated K decay constants. For Pleistocene age zircon crystals, corrections for ²³⁰Th disequilibrium and common-Pb are significant and must be treated with caution. Similarly, apparent tephra ages are sensitive to the choice of method used to calculate a maximum depositional age from the assemblage of individual crystallization ages. This study demonstrates that LA-ICP-MS zircon U-Pb dating can be successfully applied to numerous Pliocene-Pleistocene Alaskan-Yukon tephra, providing confidence in applying this method to other stratigraphically important tephra in the region.     

A 90,000–200,000 yrs marine tephra record of Italian volcanic activity in the Central Mediterranean Sea

A detailed tephrochronological study was undertaken in three deep-sea cores collected in the Tyrrhenian and Ionian Seas. The age and the origin of the marine tephra were inferred from oxygen isotope records of foraminifera and from major element compositions of glass-shards. Seventy-one eruptions were detected in the time interval 90,000–200,000 yrs during which the volcanoes of the Roman and Campanian regions and of the southern Italy were in activity. This is attested by the consistency of the geochemical compositions of both marine and terrestrial deposits. Most of the marine tephra consisted in trachytes and phonolites characterizing a Roman and Campanian origin. Several tephra were proposed as key-horizons for proximal and distal sediments. Among them, one tephra originating from Mount Etna (149,300 yrs) and five tephra from Pantelleria island (130,000 yrs, 163,600 yrs, 192,500 yrs, 197,400 yrs and 198,400 yrs) were northerly dispersed. Several other key horizons originated from the Campanian or Roman provinces were detected as far as 1000 km from the vents.     

Structural,stratigraphic, and petrologic aspects of the Arenal-Chato volcanic system,Costa Rica: Evolution of a young stratovolcanic complex

Geologic mapping on a scale of 1:10000 and detailed stratigraphic studies of lava flows and tephra deposits of the Arenal-Chato volcanic system reveal a complex and cyclic volcanic history. This cyclicity provides insight into the evolution of magma batches during the growth of the andesitic volcanic system. The Arenal and Chato volcanoes have a central zone comprised of a lava armor and a distal zone comprised of a tephra apron. During Arenal's last two eruptive periods major craters formed near intersections of regional fractures at the lava armortephra apron transition. We suggest that such intersections are potential sites for future major explosions. The earliest rocks, i.e., the Chato lava flows, range in composition from basaltic andesite to andesite. These rocks, except for the andesitic domes of Chatito and La Espina, appear to have evolved from a common parental magma. The last active period of Chato volcano occurred 3550 B. P. The earliest known activity of Arenal volcano is 2900 B. P. Arenal lava flows have 54–56 wt% SiO₂ and may be subdivided into a high-alumina group (HAG, Al₂O₃ = 20 wt%) and a low-alumina group (LAG, Al₂O₃ = 19 wt%). Compared to the HAG, the LAG also has smaller amounts of incompatible elements and higher amounts of FeO and MgO. Arenal tephra deposits were emplaced by Plinian-Sub-Plinian explosions occurring at 300±150-yr intervals. These deposits are compositionally zoned and alternate between dacite and basalt. The stratigraphy reveals an apparent magmatic cycle consisting of (a) dacitic-andesitic tephra, (b) HAG lava flows, (c) LAG lava flows, and (d) andesitic-basaltic tephra. This magmatic cycle is repeated four times during Arenal's history and is interpreted to have developed by the crystal fractionation and crystal redistribution of a single magma batch. The period of this cycle, and consequently the life of a magma batch, is about 800 years. If the cyclic pattern continues, a basaltic explosive phase may occur in the next 250 years.     

Geochemical evidence for sundering of the West Mariana arc in miocene ash from the Parece Vela Basin

Glass and mineral fragments from discrete volcanic ash layers were sampled from DSDP/IPOD Site 450 in the Parece Vela Basin, Philippine Sea and analyzed by electron microprobe. The ashes are interpreted as eruptive products of the adjacent West Mariana arc system between 25 and 14 Ma B.P., and have compositions between basaltic andesite and rhyolite, and rarely, boninite. ‘Continuous’ chemical trends appear to reflect mixing of mafic and silicic magmas. ‘Discontinuous’ trends between these end-members are relatively few, and are consistent with ‘liquid lines’ produced by fractional crystallization. Andesitic tephra become progressively richer in MgO and CaO through the middle Miocene, while boninite appears towards the end of the sequence, between 14 and 15 Ma B.P. Coeval rhyolitic glasses become richer in K₂O and Na₂O, with maximum concentrations at about 15 Ma B.P. Chronologic changes in fractionation type and composition of parent magmas are interpreted to reflect the subaerial volcanic evolution of the West Mariana arc. The appearance of boninite is believed to signal early stages of arc sundering, and corresponds temporally with regional uplift of the sea floor above the carbonate compensation depth, precursor to a new pulse of back-arc spreading.     

Temporal evolution of the Roccamonfina volcanic complex (Pleistocene), Central Italy

The Roccamonfina volcanic complex (RVC), in southern Italy, is an Early to Middle Pleistocene stratovolcano sharing temporal and morphological characteristics with the Somma–Vesuvius and the Alban Hills; both being associated with high volcanic hazard for the cities of Naples and Rome, respectively. The RVC is important for the understanding of volcanic evolution in the Roman and Campanian volcanic provinces. We report a comprehensive study of its evolution based on morphological, geochemical and K–Ar geochronological data.     

Volcanic risk ranking for Auckland, New Zealand. I: Methodology and hazard investigation

Volcanic eruptions typically produce a number of hazards, and many regions are at risk from more than one volcano or volcanic field. So that detailed risk assessments can be carried out, it is necessary to rank potential volcanic hazards and events in terms of risk. As it is often difficult to make accurate predictions regarding the characteristics of future eruptions, a method for ranking hazards and events has been developed that does not rely on precise values. Risk is calculated individually for each hazard from each source as the product of likelihood, extent and effect, based on the parameters order of magnitude. So that multiple events and outcomes can be considered, risk is further multiplied by the relative probability of the event occurring (probability_e) and the relative importance of the outcome (importance_o). By adding the values obtained, total risk is calculated and a ranking can be carried out.This method was used to rank volcanic hazards and events that may impact the Auckland Region, New Zealand. Auckland is at risk from the Auckland volcanic field, Okataina volcanic centre, Taupo volcano, Tuhua volcano, Tongariro volcanic centre, and Mt. Taranaki volcano. Relative probabilities were determined for each event, with the highest given to Mt. Taranaki. Hazards considered were, for local events: tephra fall, scoria fall and ballistic impacts, lava flow, base surge and associated shock waves, tsunami, volcanic gases and acid rain, earthquakes and ground deformation, mudflows and mudfills, lightning and flooding; and for distal events: tephra fall, pyroclastic flows, poisonous gases and acid rain, mudflows and mudfills, climate variations and earthquakes. Hazards from each source were assigned values for likelihood, with the largest for tephra fall from all sources, earthquakes and ground deformation, lava flows, scoria fall and base surge for an Auckland eruption on land, and earthquakes and ground deformation from an Auckland eruption in the ocean. The largest values for extent were for tephra fall and climate variation from each of the distal centres. However, these parameters do not give a true indication of risk. In a companion paper the effect of each hazard is fully investigated and the risk ranking completed.     

Records of Toba eruptions in the South China Sea

Three layers of volcanic tephra, sampled from ODP 1143 Site in the South China Sea, were observed at the mcd depth of 5.55 m, 42.66 m, and 48.25 m, and named, in this paper, layers of A, B, and C, respectively. All of these tephra layers have an average thickness of ca. 2 cm. They were constrained in age of ca. 0.070 Ma, ca. 0.80 Ma, and ca. 1.00 Ma, respectively, by the microbiostratigraphy data. These tephra layers were predominated by volcanic glass shards with a median grain size of 70–75 μm in diameter. Major chemical compositions analyzed by EMPA and comparison with the previous data from other scatter areas suggest that these three layers of tephra can correspond to the three layers of Toba tephra, YTT, OTT, and HDT, respectively, erupting during the Quaternary. The occurrence of these tephra layers in the South China Sea implies that the Toba eruptions often occurred in the summer monsoon seasons of the South China Sea during the Quaternary, and that the strength of eruptions was probably stronger than that previously estimated.     

Distribution, age and chemical composition of tephra layers in deep-sea sediments off western Indonesia

Tephra layers occur in deep-sea sediments of the northeastern Indian Ocean, adjacent to western Indonesian are. The layers range in age from Recent to Late Miocene. Relative abundance of light and heavy mineral species in all tephra layers have been determined, and pure glass shards from representative samples have been analyzed chemically for major oxides. On the basis of the chemical data, three distinct provinces can be recognized: (1) an extensive province of rhyolitic tephra layers, ranging in age back to Late Miocene, is found adjacent to Sumatra; (2) a more restricted province of dacitic layers, adjacent to Sunda Strait and western Java; and (3) a province of andesitic layers, found adjacent to eastern Java and the Lesser Sunda Islands. Chemical composition of tephra layers in each province remains constant with time. As an example, tephra layers from the rhyolitic province are characterized by a high and restricted range of SiO₂ (75–77%) when expressed on an H₂O-free basis.Tephra layers recovered from the study area were examined for chemical evidence of secondary alteration. The analyses revealed that H₂O is the only major oxide in the glass shards which increases progressively with the age of the tephra layers regardless of the bulk composition. H₂O, however, reaches a “saturation point” of 4–5% in the layers 250–400 thousands of years old and remains constant to the oldest recovered tephra layer (7.5 m.y. old).The decrease in silica content in deep-sea tephra layers eastward along the Indonesian volcanic arc coincides with a similar eastward decrease in average silica content in Indonesian lavas. A relatively high silica content in lavas from Sumatra, with associated ignimbrites and their deep-sea ash-fall equivalents is closely linked to thick pre-Cenozoic crust. In the portion of the arc to the east of Sumatra, the crust is Cenozoic and thin. Difference in silica content of both the lavas and deep-sea tephras along the Indonesian arc is considered in regard to the hypothesis of “magma filtering” which is based on the contrasting density gradients of ascending magma and the upper crust.     

A simple method for the collection and analysis of volcanic gas samples

Investigations into the chemistry of volcanic gases depend on the availability of complete and accurate analyses of volcanic exhalations. The wide variety of sampling and analysis methods hitherto used, often supplying only partial analyses of low precision, made intercomparison, and thus a systematic study of volcanic gases, difficult. With the method proposed here, complete volcanic gas samples are obtained permitting the accurate determination of all major species by standard analytical methods without the need for highly specialised ancillary equipment. The samples are collected in evacuated 300 ml pyrex flasks through titanium tubes deeply inserted into the gas vent. Two types of flask are used, a single compartment flask allowing the easy determination of the major constituents and containing 50 ml 4 N NaOH, and a double compartment flask for the separate analysis of the sulfur species and containing 25 ml 0.1 N As₂O₃ in 1 N HClO₄ in the first, and 50 ml 4 N NaOH in the second compartment. Non-absorbed gases are determined by gas chromatography, the rest by standard analytical procedures. The determination of H₂O, CO₂, SO₂, SO₂, S₂, H₂S, HCl, HF, H₂, N₂, O₂, CH₄, CO and NH₂ is described.     

Late Quaternary tephrostratigraphy and pollen stratigraphy of Uwa Formation,Shikoku Island,SW Japan: Reconsidering the MIS 11 super-interglacial horizon

We investigated a late Quaternary terrestrial sedimentary sequence (Uwa Formation) in core IC2, from a site adjacent to that of the reported core IC on NW Shikoku Island, SW Japan, and developed its tephra and pollen stratigraphy to refine the age model of the formation. First, we identified 19 horizons with high glass shard concentrations in the IC2 core sediments as possible tephras or cryptotephras, and correlated them with reported tephras on the basis of the major- and trace-element compositions of their glass shards. All correlated widespread tephras and cryptotephras were products of volcanoes in the Kyushu volcanic zone (Aso, Kakuto, Aira, Ata, and Kikai calderas). Second, we confirmed the presence in core IC2 of two pollen zones dominated by Quercus subgen. Cyclobalanopsis, which is an indicator of very warm interglacial vegetation. In the Japanese Islands, these two vegetation zones have usually been considered to characterize marine isotopic stages (MISs) 1 and 11. A previous study of the Uwa Formation correlated the upper pollen zone to MIS 1, but the lower zone was not correlated to MIS 11; rather, it was inferred to be older than MIS 12 because it was stratigraphically below the “Oda” tephra (equivalent to a distal Kasamori 5 [Ks5] tephra [MIS 12]). In this study, however, noting that the Naruohama-IV tephra (Nh-IV; MIS 10d) and Ks5 cannot be distinguished by their shard chemistries, we inferred that the suggested “Oda” tephra actually correlates to Nh-IV, rather than to the Ks5 tephra. By re-assigning the “Oda” tephra to Nh-IV, we could correlate the underlying Quercus subgen. Cyclobalanopsis-abundant zone to MIS 11 and, consequently, a pair of pollen zones indicating cool and warm conditions below the MIS 11 pollen zone to MISs 12 and 13, respectively. The resulting age model whereby tephra and pollen constraints are integrated showed a roughly constant sedimentation rate from MIS 13, without any long-term gaps; further, our MIS 13 horizon in core IC2 corresponds to the reported 1 Ma tephra horizon in core IC. Therefore, these findings represent a dramatic change in the Uwa Formation age model and validate the Uwa Formation as one of the most useful terrestrial archives of Quaternary tephrostratigraphy and paleoclimatic fluctuation in SW Japan.     

Chronology of Pliocene and Quaternary bioevents and climatic events from fission-track ages on tephra beds, Wairarapa, New Zealand

High-resolution Pliocene and Pleistocene sequences exposed on land in New Zealand are some of the few detailed records of widepread marine bioevents and paleoclimatic changes in the Southern Hemisphere. Marine biostratigraphy calibrated in deep-sea cores by paleomagnetic reversals has been the primary basis for the chronology of these sequences. We have determined ages for several tephra beds which now provide an independent numerical age calibration for a well-studied marine and terrestrial section in Wairarapa. By using the isothermal plateau fission track (ITPFT) method on volcanic glass we have overcome the problems of partial track fading and detrital mineral contamination, which hindered earlier studies, to reveal a new chronology extending back to nearly 5 Ma.

Our ages for the Hikawera Tuff (4.91 ± 0.25 Ma) and Spooner Tuff (3.44 ± 0.13 Ma) are consistent with the appearance and disappearance of many early Pliocene foraminiferial species, validating their age calibration in New Zealand. However, some fossil occurrences, including coccoliths, differ temporally by as much as 0.55 Ma, perhaps due to local tectonic-induced recycling.

Four Pleistocene tephra beds (Potaka tephra (1.00 ± 0.03 Ma), Kaukatea tephra (0.87 ± 0.05 Ma), Rangitawa tephra (ca. 0.35 Ma) and Kawakawa tephra (ca. 0.22 Ma)) are now recognised in the Wairarapa sequence via stratigraphic and new geochemical and age data. These beds allow direct correlation to other marine and terrestrial basins, as well as volcanic regions in New Zealand, and will ultimately aid in a regional paleoenvironmental reconstruction where bioevents are absent. The tephra ages indicate that the marine sediment accumulation rates varied from 90 to 250 m/Ma between different sections of the Pliocene and reached ca. 350 m/Ma in the last 2.4 Ma, when the sequence displays pronounced glacioeustatic cyclic deposition. In the terrestrial realm, the oldest loess in New Zealand is now constrained to between 1.00 and 0.87 Ma.     

Determination of pre-eruptive H2O,F and Cl contents of silicic magmas using melt inclusions: Examples from Taupo volcanic center,New Zealand

Water, F, and Cl contents of melt inclusions in phenocrysts from the 2-ka-old Taupo and Hatepe plinian tephras, and the 22-ka-old Okaia tephra from the Taupo volcanic center, New Zealand, were measured by electron and ion microprobe. Major and trace element chemistry of the inclusions is similar to that of bulk rock, supporting our assumption that volatile contents of inclusions are representative of the magma in which the crystals grew. Inclusions in the 2-ka Taupo plinian tephra contain a mean of 4.3 wt% H₂O, 450 ppm F, and 1700 ppm Cl; from the Hatepe plinian tephra 4.3 wt% H₂O, 430 ppm F, and 1700 ppm Cl; and from the Okaia tephra 5.9 wt% H₂O, 470 ppm F, and 2100 ppm Cl. Sulfur was below the detection limit of 200 ppm. The constant H₂O, F and Cl from a number of stratigraphic horizons in the tephra deposits suggest that the Taupo and Hatepe plinian tephras (>8.2 km³ magma volume) were derived from a magma body that did not contain a strong volatile gradient. By inference, there is no pre-eruptive volatile difference between these plinian eruptions and a phrea-toplinian eruption which occurred between the two. Virtually no major element zonation is seen in this eruptive sequence. Although the Okaia tephra was also erupted from the Taupo volcanic center, probably from a similar vent area, its higher volatile contents and distinct composition as compared to the Taupo tephras show that it was derived from a different, and possibly deeper, magma body.     

Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations

The Yixian Formation at Sihetun in western Liao- ning Province has attracted considerable attention over the last two decades due to discovery of a wide range of well-preserved ‘feathered’ dinosaurs and primitive bird fossils[1―4]. This formation is dominated by vol- canic rocks, with fossil-bearing lacustrine sedimentary rocks at the upper part of the section[4]. The sedimen- tary rocks contain thin layers of tuff. According to previous studies[4], the total thickness of the Yixian Form…     

Records of Toba eruptions in the South China Sea -Chemical characteristics of the glass shards from ODP 1143A

Three layers of volcanic tephra, sampled from ODP 1143 Site in the South China Sea,were observed at the mcd depth of 5.55 m, 42.66 m, and 48.25 m, and named, in this paper, lay ers of A, B, and C, respectively. All of these tephra layers have an average thickness of ca. 2 cm.They were constrained in age of ca. 0.070 Ma, ca. 0.80 Ma, and ca. 1.00 Ma, respectively, by the microbiostratigraphy data. These tephra layers were predominated by volcanic glass shards with a median grain size of 70-75 μm in diameter. Major chemical compositions analyzed by EMPA and comparison with the previous data from other scatter areas suggest that these three layers of tephra can correspond to the three layers of Toba tephra, YTT, OTT, and HDT, respectively, erupt ing during the Quaternary. The occurrence of these tephra layers in the South China Sea implies that the Toba eruptions often occurred in the summer monsoon seasons of the South China Sea during the Quaternary, and that the strength of eruptions was probably stronger than that previously estimated.     

Geochemistry of the Submarine Gaseous Emissions of Panarea (Aeolian Islands, Southern Italy): Magmatic vs. Hydrothermal Origin and Implications for Volcanic Surveillance

The marine sector surrounding Panarea Island (Aeolian Islands, South Italy) is affected by widespread submarine emissions of CO₂ -rich gases and thermal water discharges which have been known since the Roman Age. On November 3^rd, 2002 an anomalous degassing event affected the area, probably in response to a submarine explosion. The concentrations of minor reactive gases (CO, CH₄ and H₂) of samples collected in November and December, 2002 show drastic compositional changes when compared to previous samples collected from the same area in the 1980s. In particular the samples collected after the November 3^rd phenomenon display relative increases in H₂ and CO and a strong decrease in the CH₄ contents, while other gas species show no significant change. The interaction of the original gas with seawater explains the variable contents of CO₂, H₂S, N₂, Ar and He which characterize the different samples, but cannot explain the large variations of CO, CH₄ and H₂ which are instead compatible with changes in the redox, temperature and pressure conditions of the system. Two models, both implying an increasing input of magmatic fluids are compatible with the observed variations of minor reactive species. In the first one, the input of magmatic fluids drives the hydrothermal system towards atypical (more oxidizing) redox conditions, slowly pressurizing the system up to a critical state. In the second one, the hydrothermal system is flashed by the rising high-T volcanic fluid, suddenly released by a magmatic body at depth. The two models have different implications for volcanic surveillance and risk assessment: In the first case, the November 3^rd event may represent both the culmination of a relatively slow process which caused the overpressurization of the hydrothermal system and the beginning of a new phase of quiescence. The possible evolution of the second model is unforeseeable because it is mainly related to the thermal, baric and compositional state of the deep magmatic system that is poorly known.     

Correlation of rhyolitic pyroclastic eruptive units from the Taupo volcanic zone by Fe–Ti oxide compositional data

Grain-specific analyses of Fe–Ti oxides and estimates of eruption temperature (T) and oxygen fugacity (fO₂) have been used to fingerprint rhyolitic fall and flow deposits that are important for tephrostratigraphic studies in and around the Taupo volcanic zone of North Island, New Zealand. The analysed Fe–Ti oxides commonly occur in the rims of orthopyroxene crystals and appear to reflect equilibrium immediately prior to eruption because of geochemical correlation with the co-existing glass phase. The composition of the spinel phase is particularly diagnostic of eruptive centre for post-65 ka events and can be used to distinguish many tephra beds from the same volcano. The 29 different units examined were erupted over a wide range in T (690–990°C) and Δ log fO₂ (–0.1 to 2.0). These parameters are closely related to the mafic mineral assemblage, with hydrous mineral-bearing units displaying higher fO₂. Such trends are superimposed on larger differences in fO₂ that are related to eruptive centre. At any given temperature, all post-65 ka Okataina centre tephra have higher fO₂ values than post-65 ka Taupo centre tephra. This provides a useful criterion for identifying the volcanic source. There are no temporal T and fO₂ trends in the tephra record; over intervals >20 ka, however, tephra sequences from Taupo centre form characteristic T-fO₂ buffer trends mirroring the glass chemistry. Individual eruptive events display uniform spinel and rhombohedral phase compositions and thus narrow ranges in T (± <20°C) and log fO₂ (± <0.5), allowing these features to identify individual magma batches. These criteria can help distinguish tephra deposits of similar bulk or glass composition that originated from the same volcano. Distal fall deposits record the same T-fO₂ conditions as the proximal ignimbrite and enable distal–proximal correlation. Lateral and vertical compositional and T-fO₂ variability displayed in large volume (>100 km³) ignimbrites, such as the Oruanui, Rotoiti and Ongatiti, is similar to that found in a single pumice clast and thus mainly reflects analytical error; however, thermal gradients of ca. 50°C may occur in some units. Received: 6 April 1998 / Accepted: 16 June 1998     

Protolith natures and U-Pb sensitive high mass-resolution ion microprobe (SHRIMP) zircon ages of the metabasites in Hainan Island, South China: Implications for geodynamic evolution since the late Precambrian

Abstract Metabasites within the Paleozoic volcanic‐clastic sedimentary sequences in Hainan Island, South China, show large differences not only in the nature of protoliths, but also in zircon U‐Pb sensitive high mass‐resolution ion microprobe (SHRIMP) ages. The protoliths for the Tunchang area metabasites have intraoceanic arc geochemical affinities. In the east‐central island gabbroic to diabasic rocks and pillow lavas are also present, while the Bangxi area metabasites with back‐arc geochemical affinities in the northwest island consist of basaltic, gabbroic and/or picritic rocks. Three types of zircon domains/crystals in the Tunchang area metabasites are defined. Type 1 is comagmatic and yields concordant to approximately concordant 206 Pb/238 U ages ranging from 442.1 ± 13.7 Ma to 514.3 ± 30.2 Ma with a weighted U‐Pb mean age of 445 ± 10 Ma. Type 2 is inherited and yields a weighted 207 Pb/206 Pb mean age of 2488.1 ± 8.3 Ma. Type 3 is magmatic with a 207 Pb/206 Pb age of ca 1450 Ma. Magmatic zircons in the Bangxi area metabasites yield a weighted U‐Pb mean age of 269 ± 4 Ma. We suggest 450 Ma is the minimum age for crystallization of protoliths of the Tunchang area metabasites, because the age range of ca 440–514 Ma probably corresponds to both the time of igneous crystallization and the high‐temperature overprint. The presence of abundant inherited zircons strongly favors derivation of these rocks from a NMORB‐like mantle proximal to continental crust. A protolith age of ca 270 Ma for the Bangxi area metabasites probably records expansion of an epircontinental back‐arc basin and subsequent generation of a small oceanic basin. The presence of ophiolitic rocks with an age of ca 450 Ma, not only in Hainan Island, but also in the Yangtze block, highlights the fact that the South China Caledonian Orogeny was not intracontinental in nature, but characterized by an ocean‐related event.     

Subduction-related episodes of K-alkaline magmatism (15–0.1 Ma) and geodynamic implications in the north Tyrrhenian — central Italy region: a review

In the north Tyrrhenian region and adjoining shores of Alpine Corsica and central Italy, four magmatic phases (15–14; 8–6; 5–2; and 1.3–0.1 Ma) are present which consist prevailingly of either old acidic and lamproitic rocks or young (1.3–0.1 Ma) basic volcanics with potassic–ultrapotassic affinity (the rocks of the K and HK series of the Roman province, and the kamafugitic rocks). Composition, age and location of the igneous phases reveal a geochemical polarity oriented from west to east. The episodes of magmatic activity reflect the evolution of the geodynamic environment (ensialic plate convergence): backarc stretching and attenuation of an Alpine orogenic wedge were accompanied by the eastward roll-back and progressive steepening of the descending Adria plate. The latter process led to enhanced metasomatic modifications of the mantle wedge composition and to eruption of the large volumes of KS and HKS volcanic rocks in central Italy (0.6–0.1 Ma).