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1.
Denitrification of groundwater was studied using a laboratory-scale reactor packed with biodegradable snack ware served as both carbon source and biofilm support for microorganisms. The complete removal of 50 mg/L of nitrate-nitrogen was achieved in a 23-day-old reactor with 2.1 h of hydraulic retention time without inoculating with any external microorganisms, which indicates that indigenous microorganisms in groundwater proliferate readily and result in stable biofilm formation onto biodegradable snack ware. Accumulation of nitrite and nitrate residue was detected when hydraulic retention time was lower than 2.1 h. The breakthrough of nitrate-nitrogen up to over 10 mg/L in the effluent water was observed with nitrate removal efficiency reducing to about 75 % when hydraulic retention time was lowered to 1.4 h. The highest rate of denitrification was observed with 1.5 h of hydraulic retention time. Dissolved organic carbon concentration in the effluent water ranged between 10 and 20 mg/L during the stable operation of the reactor, and nitrite-nitrogen concentration was never higher than 0.09 mg/L. Considering its relatively low price and high denitrification rate, biodegradable snack ware can become a good alternative for denitrification process.  相似文献   

2.
Influence of water quality change in Fu River on Wetland Baiyangdian   总被引:1,自引:0,他引:1  
Fu River is the only river that has perennial flow into Wetland Baiyangdian and is mainly composed of living sewage and industrial wastewater from Baoding city. Pollutant concentrations were monitored at three sections in the upstream, midstream, and downstream of Fu River and water quality in Wetland Baiyangdian was monitored at seven monitoring sites from 2001 to 2005. Results show that pollutant concentrations in Fu River and pollution load entering Wetland Baiyangdian generally increased during 2001–2005. On average, the concentrations of CODMn and BOD5 increased by 46.5% and 50% from 2001 to 2005 in Fu River and CODMn increased by 17% in Wetland Baiyangdian. The total amount of CODMn and BOD5 entering Wetland Baiyangdian increased from 1630 and 997 t/a to 2243 and 1583 t/a from 2001 to 2005, respectively. Total amount of water within the wetland and non-point source pollution input from surrounding areas also influenced the water quality in the wetland.  相似文献   

3.
Treated wastewater is a valuable resource, particularly in countries facing water shortage such as Jordan. Nevertheless, excess nutrients, especially phosphorus, may have detrimental impacts on receiving waterbodies. Treated wastewater in Jordan often exceeds the recommended levels set by the Jordanian Standards for wastewater reuse and discharge. Therefore, it is important to reduce phosphorus loads to acceptable levels before discharge. Biofiltration is a low-cost technology that has shown good potential for wastewater treatment. The performance of biofilters largely depends on the media used. In this study, local sand and sand augmented with biochar prepared from the olive oil processing waste (SBC) were used as filter media for phosphorus removal from clarified secondary treated wastewater. The two media types were tested under different hydraulic and phosphorus loading conditions to simulate shock, flooding, and inundation conditions. The results showed that sand media was more effective in removing phosphorus (90.8 ± 2.6%) than sand amended with biochar (83.3 ± 3.2%). Both media showed resilience under extreme loading conditions. Although phosphorus removal efficiency was negatively affected following the extreme loading events, the observed effects were temporary. The simulated inundation event further showed that the media was able to retain the adsorbed phosphorus. Furthermore, the phosphorus concentration in the effluent remained within the prescribed discharge guidelines at all times.  相似文献   

4.
Nanoscale zero-valent iron flakes for groundwater treatment   总被引:1,自引:0,他引:1  
Even today the remediation of organic contaminant source zones poses significant technical and economic challenges. Nanoscale zero-valent iron (NZVI) injections have proved to be a promising approach especially for source zone treatment. We present the development and the characterization of a new kind of NZVI with several advantages on the basis of laboratory experiments, model simulations and a field test. The developed NZVI particles are manufactured by milling, consist of 85 % Fe(0) and exhibit a flake-like shape with a thickness of <100 nm. The mass normalized perchloroethylene (PCE) dechlorination rate constant was 4.1 × 10?3 L/g h compared to 4.0 × 10?4 L/g h for a commercially available reference product. A transport distance of at least 190 cm in quartz sand with a grain size of 0.2–0.8 mm and Fe(0) concentrations between 6 and 160 g/kg (sand) were achieved without significant indications of clogging. The particles showed only a low acute toxicity and had no longterm inhibitory effects on dechlorinating microorganisms. During a field test 280 kg of the iron flakes was injected to a depth of 10–12 m into quaternary sand layers with hydraulic conductivities ranging between 10?4 and 10?5 m/s. Fe(0) concentrations of 1 g/kg (sand) or more [up to 100 g/kg (sand)] were achieved in 80 % of the targeted area. The iron flakes have so far remained reactive for more than 1 year and caused a PCE concentration decrease from 20.000–30.000 to 100–200 µg/L. Integration of particle transport processes into the OpenGeoSys model code proved suitable for site-specific 3D prediction and optimization of iron flake injections.  相似文献   

5.
Modeling and simulation using GPS-X software for a packed bed up-flow anaerobic sludge blanket followed by a biological aerated filter were studied. Both treatment units were packed with a non-woven polyester fabric as a bio-bed. The system was operated at a hydraulic and organic loading rate of 9.65 m3/m2/d and 2.64 kg BOD5/m3/day. Verification of the experimental results and calibration of the model were carried out prior simulation and modeling. Variables under consideration were HLR, OLR, and surface area of the packing material. HLR and OLR are increased incrementally until the break through point has been achieved. The results obtained from modeling indicated that the treatment system has great potential to be used as an ideal and efficient option for high hydraulic and organic loading rates up to 19.29 m3/m2/d and 4.48 kg BOD5/m3/day. The model indicated that increasing the input HLR and OLR loads to the treatment system up to 50 % of the original values achieved removal efficiencies 98 % for TSS, 88 % for BOD5, and 85 % for COD. Moreover, increasing the HLR to four times the original value (38.59 m3/m2/d) reduced the efficiency of the treatment system to 50 % for COD and BOD5. However, the removal rates of TSS, TKN, and TP were not affected. Also, the modeling results indicated that increasing the surface area of the packing material increased the overall efficiency of the treatment system.  相似文献   

6.
In the present study the removal of nitrates from wastewater using Pseudomonas stutzeri microorganism in a Gas–Liquid–Solid bioreactor at the concentration of 200 ppm was studied for a period of 12 h. The response surface methodology with the help of central composite design and genetic algorithm were employed to optimize the process parameters such as airflow rate, biofilm carrier, carbon source, temperature and pH which are responsible for the removal of nitrates. The optimized values of parameters found from RSM are airflow rate 2.41 lpm, biofilm carrier 15.15 g/L, carbon source 85.0 mg/L, temperature 29.74 °C, pH 7.47 and nitrate removal 193.16. The optimized parameters obtained from genetic algorithm are airflow rate 2.42 lpm, biofilm carrier 15.25 g/L, carbon source 84.98 mg/L, temperature 29.61 °C, pH 7.51 and nitrate removal is 194.14. The value of R2 > 0.9831 obtained for the present mathematical model indicates the high correlation between observed and predicted values. The optimal values for nitrate removal at 200 ppm are suggested according to genetic algorithm and at these optimized parameters more than 96 % of nitrate removal was estimated, which meets the standards for drinking water.  相似文献   

7.
The hydraulic conductivity represents an important indicator parameter in the generation and redistribution of excess pore pressure of sand–silt mixture soil deposits during earthquakes. This paper aims to determine the relationship between the undrained shear strength (liquefaction resistance) and the saturated hydraulic conductivity of the sand–silt mixtures and how much they are affected by the percentage of low plastic fines (finer than 0.074 mm) and void ratio of the soil. The results of flexible wall permeameter and undrained monotonic triaxial tests carried out on samples reconstituted from Chlef river sand with 0, 10, 20, 30, 40, and 50 % non-plastic silt at an effective confining pressure of 100 kPa and two initial relative densities (D r = 20, 91 %) are presented and discussed. It was found that the undrained shear strength (liquefaction resistance) can be correlated to the fines content, intergranular void ratio and saturated hydraulic conductivity. The results obtained from this study reveal that the saturated hydraulic conductivity (k sat) of the sand mixed with 50 % low plastic fines can be, in average, four orders of magnitude smaller than that of the clean sand. The results show also that the global void ratio could not be used as a pertinent parameter to explain the undrained shear strength and saturated hydraulic conductivity response of the sand–silt mixtures.  相似文献   

8.
The wastewater discharged by poultry slaughterhouse industries are characterized mainly by high biochemical oxygen demand, high suspended solids and complex mixture of fats, proteins and fibers requiring systematic treatment prior to disposal. In this study, the performance of an upflow anaerobic filter reactor for treating Indian poultry slaughterhouse wastewater under low upflow velocity of 1.38 m/day at mesophilic temperature (29-35 °C) was investigated. The reactor was inoculated with anaerobic non-granular sludge from an anaerobic reactor treating the poultry slaughterhouse wastewater. The reactor took 147 days for complete start-up with removal efficiencies of total chemical oxygen demand and soluble chemical oxygen demand of 70 and 79 % respectively. The maximum total chemical oxygen demand removal efficiency of 78 % was achieved at an organic loading rate of 10.05 kg/m3/day and at an hydraulic retention time of 12 h. The average methane content varied between 46 and 56 % and methane yield at maximum removal efficiency was 0.24 m3 CH4/kg CODremoved·day. Sludge granules of 1–2 mm were observed in between the packing media. Scanning electron microscope analysis revealed that sludge granules are composed of clumps of Methanosarcina clustered with less intertwined Methanosaeta fibre of granules. The lower velocity used in this study has achieved better performance of the reactor by creating active microbial formation with stable pH upto an organic loading rate of 14.3 kg/m3/day. This has proved that the poultry slaughterhouse wastewater can be treated using anaerobic filter reactor under low upflow velocity.  相似文献   

9.
A transparent aqueous-saturated sand surrogate for use in physical modeling   总被引:3,自引:0,他引:3  
This paper presents the geotechnical properties of a new family of synthetic transparent soils made of fused quartz, saturated with a matched refractive index water-based sucrose solution, suitable for modeling the behavior of sand in small-scale model tests. The dry density ranged between 1,134 and 1,358 kg/m3. The peak angle of friction was found to range from 46° to 57°. The average hydraulic conductivity was 1.7 × 10?5 cm/s. The compressibility index (C c) ranged from 0.34 to 0.57. The main advantage of fused quartz over available sand surrogates made of silica gel is that its solid structure better models the behavior of natural sand. The matching pore fluids are inert and non-toxic, which facilitates their use in educational settings. The availability of a safe and easy-to-use transparent sand permits measurement of three-dimensional deformation patterns and flow characteristics in controlled research experiments. The introduction of an aqueous solution permits the use of two immiscible pore fluids, one made of mineral oil and the other made of a sucrose solution, for modeling multiphase flow problems, as well as coupled flow-deformation problems.  相似文献   

10.
Biofiltration has shown to be a promising technique for handling malodours arising from process industries. The present investigation pertains to the removal of hydrogen sulphide in a lab scale biofilter packed with biomedia, encapsulated by sodium alginate and poly vinyl alcohol. The experimental data obtained under both steady state and shock loaded conditions were modelled using the basic principles of artificial neural networks. Artificial neural networks are powerful data driven modelling tools which has the potential to approximate and interpret complex input/output relationships based on the given sets of data matrix. A predictive computerised approach has been proposed to predict the performance parameters namely, removal efficiency and elimination capacity using inlet concentration, loading rate, flow rate and pressure drop as the input parameters to the artificial neural network model. Earlier, experiments from continuous operation in the biofilter showed removal efficiencies from 50 to 100 % at inlet loading rates varying up to 13 g H2S/m3h. The internal network parameter of the artificial neural network model during simulation was selected using the 2k factorial design and the best network topology for the model was thus estimated. The results showed that a multilayer network (4-4-2) with a back propagation algorithm was able to predict biofilter performance effectively with R2 values of 0.9157 and 0.9965 for removal efficiency and elimination capacity in the test data. The proposed artificial neural network model for biofilter operation could be used as a potential alternative for knowledge based models through proper training and testing of the state variables.  相似文献   

11.
The groundwater abstracted at a well field near the Yamuna River in Central Delhi, India, has elevated ammonium (NH4 +) concentrations up to 35 mg/L and arsenic (As) concentrations up to 0.146 mg/L, constituting a problem with the provision of safe drinking and irrigation water. Infiltrating sewage-contaminated river water is the primary source of the NH4 + contamination in the aquifer, leading to reducing conditions which probably trigger the release of geogenic As. These conclusions are based on the evaluation of six 8–27-m deep drillings, and 13 surface-water and 69 groundwater samples collected during seven field campaigns (2012–2013). Results indicate that losing stream conditions prevail and the river water infiltrates into the shallow floodplain aquifer (up to 16 m thickness), which consists of a 1–2-m thick layer of calcareous nodules (locally known as kankar) overlain by medium sand. Because of its higher hydraulic conductivity (3.7 × 10?3 m/s, as opposed to 3.5 × 10?4 m/s in the sand), the kankar layer serves as the main pathway for the infiltrating water. However, the NH4 + plume front advances more rapidly in the sand layer because of its significantly lower cation exchange capacity. Elevated As concentrations were only observed within the NH4 + plume indicating a causal connection with the infiltrating reducing river water.  相似文献   

12.
13.
A three stage and a one-stage bench-scale biofilter with effective heights of 129 cm filled with same type of packing material were operated at different influent concentrations of ammonia in order to investigate their performance in treating waste gas streams. The columns contained a mixture of municipal compost inoculated with thickened municipal activated sludge as a base material and shredded hard plastic as a bulking agent in a 3:2 v/v ratio; the porosity, density and pH were 52 %, 0.65 and 7.2 respectively. Microbial acclimation to ammonia was achieved by exposing the three stage biofilter to an average inlet loading rate of 2.15g-NH3/m3h and the one-stage to an average inlet loading rate of 1.32 g NH3/m3h and an empty bed residence time of 60 s, for 10 days and 17 days respectively. Under steady-state condition, maximum elimination capacity (EC) was 9.85 g-NH3/m3h at a loading rate of 9.86 g-NH3/m3h for three-stage biofilter and 8.08 g NH3/m3h at a loading rate of 8.13 g-NH3/m3h for one-stage biofilter. The average pressure drop across biofilters bed was determined 33.76 Pa/m1 in three-stage biofilter and 180.7 Pa/m1 in one-stage biofilter. The three stage biofilter showed superior performance and gained more elimination capacity, shorter acclimation time, longer operation in steady-state condition and less pressure drop than one-stage biofilter.  相似文献   

14.
Antibiotic contamination of aqueous environment due to pharmaceutical sewage may lead to development of antibiotic-resistant bacteria strain. In this research, elimination of antibiotics from synthetic wastewater was investigated. For this purpose, sulfamethoxazole and trimethoprim were treated by a pilot scale of net-like rotating biological contactor with three compartments, 48 plastic discs with total volume of 78.75 L. This system was continuously operated for about one year at various organic loading rates with different antibiotic dosages. The obtained results indicated that by increasing hydraulic retention time, the chemical oxygen demand (COD) removal was gradually increased. The optimal hydraulic retention time for desired rate of COD removal was 36 h. In addition, the effect of hydraulic retention time, organic load rate and sulfamethoxazole concentration in the removal of sulfamethoxazole and organic matter was assessed. Moreover, the results demonstrated that with increasing in organic load rate, sulfamethoxazole elimination was enhanced. In the next step, simultaneous removal of both antibiotics for constant inlet COD concentration of 8000 mg/L at optimum hydraulic retention time was analysed. The results showed that trimethoprim removal efficiency was approximately 100%, even at high concentration of trimethoprim (50 mg/L). For observation of dominant microorganism, samples of the developed biofilm on rotating biological contactor discs were scanned by scanning electron microscopy. In the first compartment where biomass was exposed to highest concentration of antibiotics, fungus strains were the dominant organism. In the second and third compartment antibiotic-resistant bacteria were the dominant attached living organisms.  相似文献   

15.
This study was carried out to determine the flux of nutrients and heavy metals from the Melai sub-catchment into Lake Chini through the process of erosion. Melai River is one of the seven feeder rivers that contributed to the present water level of Lake Chini. Three properties of soils, such as particle size, organic matter content, and soil hydraulic conductivity and three chemical soil properties, such as available nutrients, dissolved nutrients, and heavy metals, were analyzed and interpreted. Potential soil loss was estimated using the revised universal soil loss equation model. The results show that the soil textures in the study area consist of clay, silty clay, clay loam, and sandy silt loam. The organic matter content ranges from 3.40 to 9.92 %, while the hydraulic conductivity ranges from 5.2 to 25.3 cm/h. Mean values of available P, K, and Mg amount was 8.5 ± 3.7 μg/g, 24.5 ± 3.4 μg/g, and 20.7 ± 18.6 μg/g, respectively. The highest concentration of soluble nutrients was SO 4 ?2 (815.8 ± 624.1 μg/g), followed by NO3 ?-N (295.5 ± 372.7 μg/g), NH4 +-N (24.5 ± 22.1 μg/g) and PO4 3? (2.0 ± 0.8 μg/g). The rainfall erosivity value was 1658.7 MJ mm/ha/h/year. The soil erodibility and slope factor ranges from 0.06 to 0.26 ton h/MJ/mm and 7.63 to 18.33, respectively. The rate of soil loss from the Melai sub-catchment in the present condition is very low (0.0028 ton/ha/year) to low (18.93 ton/ha/year), and low level flow of nutrients and heavy metals, indicating that the Melai River was not the contaminant source of sediments, nutrients, and heavy metals to the lake.  相似文献   

16.
Wastewater treatment using moving bed membrane bioreactor technology was tested with real urban wastewater at a pilot plant, combining moving bed treatment as a biological process with hybrid biomass (suspended and fixed) and the advantages of a membrane separation system. The evolution of the kinetic constants of the hybrid biomass and organic matter removal were studied in a pilot plant under different operational conditions, by varying hydraulic retention time (HRT), mixed liquor suspended solids (MLSS) and temperature, and considering the attached biomass of the carrier and the dispersed biomass of the flocs to reproduce real treatment conditions. The rates of organic matter removal were 97.73 ± 0.81 % of biochemical oxygen demand (BOD5), 93.44 ± 2.13 % of chemical oxygen demand (COD), 94.41 ± 2.26 % of BOD5 and 87.62 ± 2.47 % of COD using 24.00 ± 0.39 and 10.00 ± 0.07 h of HRT, respectively. The influence of the environmental variables and operational conditions on kinetic constants was studied; it was determined that the most influential variable for the decay coefficient for heterotrophic biomass was HRT (0.34 ± 0.14 and 0.31 ± 0.10 days?1 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively), while for heterotrophic biomass yield, this was temperature (0.61 ± 0.04 and 0.52 ± 0.06 with 10.00 ± 0.07 and 24.00 ± 0.39 h of HRT, respectively). The results show that introducing carriers in an MBR system provides similar results for organic matter removal, but with a lower concentration of MLSS.  相似文献   

17.
Petrographical and geochemical studies of Silurian Niur sandstones, Derenjal Mountains, Central Iran, were carried out to infer their provenance and tectonic setting. Modal analysis data of 37 medium sand size and well-sorted samples revealed that most quartz is composed of monocrystalline grains with straight to slightly undulos extinction and about 3 % polycrystalline quartz has inclusions, such as rutile needles. The sandstones are classified as quartzarenite, sublitharenite, and subarkose types based on framework composition and geochemistry. Petrographic studies reveal that these sandstones contain quartz, feldspars, and fragments of sedimentary rocks. The detrital modes of these sandstones indicate that they were derived from recycled orogen and stable cratonic source. Major and trace element contents of them are generally depleted (except SiO2) relative to upper continental crust which is mainly due to the presence of quartz and absence of Al-bearing minerals. Modal composition (e.g., quartz, feldspar, and lithic fragments) and discrimination diagrams based on major elements, trace elements (Ti, La, Th, Sc, and Zr), and also such ratios as La/Sc, Th/Sc, La/Co, and Th/Co, in sandstones suggest a felsic igneous source rock and quartzose polycyclic sedimentary provenance in a passive continental margin setting. Furthermore, high Zr/Sc values in these sandstones are considered as a sign of recycling. We indicated paleo-weathering conditions by modal compositions, the CIA index and Al2O3?+?K2O?+?Na2O% vs. SiO2% bivariate for these sandstones. Based on these results, although recycling is important to increase the maturity of the Niur sandstones, humid climate conditions in the source area have played a decisive role.  相似文献   

18.
Compacted soil–bentonite liners, consisting of a sandy soil mixed with bentonite as backfill, are used extensively as engineered barriers for contaminant containment. This paper studies the valorization of local materials containing calcareous sand, tuff obtained from Laghouat region (in the South Algeria), to associate with bentonite in order to improve their hydraulic characteristics for use as landfill liner material. Firstly, a geotechnical characterization of mixtures chooses from a fixed percentage to 10% bentonite and different percentages of calcareous sand and tuff so that they are complementary to 90% by not 10%. Thereafter, the determination of saturated hydraulic conductivity at falling-head permeability (Kv) and oedometer (Kid, indirect Measure) tests of all compacted mixtures at Optimum Normal Proctor have been carried out using both permeates by tap water and a landfill leachate in order to simulate long-term conditions. The results showed that the saturated hydraulic conductivity of tap water is relatively lower than the one saturated by leachate in the falling-head test, unlike the oedometer test. The B10CS20T70 mixture has satisfied the hydraulic conductivity criterion of bottom barriers (i.e. water permeated: kv20° = 1.97 × 10?9 and kid from 7 × 10?9 to 1.83 × 10?10 < 10?9m/s; leachate permeated: kv20° = 2.91 × 10?9 and kid from 7 × 10?9 at 1.44 × 10?10 < 10?9 m/s). Finally, a comparison between direct measurements of the saturated hydraulic conductivity by triaxial (Kd) test and oedometer test (Kid) in the range of effective stress applied 100–800 kPa led to propose equations of correlations between these two methods. In conclusion, adopted formulation B10CS20T70 perfectly meets the regulatory requirements in force and constitutes an economic product based on available local materials for engineers barriers.  相似文献   

19.
In this study, the performance of moving-bed biofilm sequencing batch reactor in operating the anaerobic/anoxic/oxic (A2O) process for treatment of wastewaters containing nitrogen and phosphorous was evaluated. For this purpose, a pilot system with two bench-scale sequencing batch reactors with a total volume of 30 L and functional volume of 10 L was used. The installation was elaborated using plexiglass, in which 60% of the functional volume consisted of PVC suspended carriers (Kaldnes K3) with a specific surface area of 560 m2/m3. The independent variables used in this study were hydraulic retention time (HRT) (1.5, 2, 2.5, 3, and 3.5 h) and the initial organic load (300, 500, 800, 1000 mg O2/L). The results showed impressive performance in the case of an initial organic load of 300 mg O2/L and HRT of 3 h with maximum removal of COD and TN, respectively, by 95.1 and 89.8%. In the case of an initial organic load of 1000 mg O2/L and HRT of 3.5 h, the maximum total phosphorus removal was 72.3%. Therefore, according to the analysis of data obtained by different HRTs, it was revealed that the system of A2O has greater efficiency in removing organic matter from wastewater in the shortest possible time.  相似文献   

20.
This literature review surveys the previous and current researches on the co-digestion of anaerobic processes and examines the synergies effect of co-digestion with cattle manure. Furthermore, this review also pays attention to different operational conditions like operating temperature, organic loading rate (OLR), hydraulic retention time (HRT), chemical oxygen demand (COD) and volatile solid (VS) removal efficiency and biogas or methane production. This review shows that anaerobic mono-digestion of cattle manure usually causing poor performance and stability. Anaerobic studies were generally performed under mesophilic conditions maintained between 35 and 37 °C. Organic waste loading rate generally ranges from 1 to 6 g VS–COD L?1 day?1 stable condition in anaerobic digester. Generally, studies show that HRT for co-digestion of fruit–vegetables waste and industrial organic waste appears to exceed 20 days. However, the anaerobic co-digestion process is generally operated at HRT of between 10 and 20 days. VS and COD removal efficiency usually reaches up to 90 % due to co-digestion with different type organic waste. Methane–biogas production is generally obtained between 0.1 and 0.65 L CH4–biogas g?1 VS.  相似文献   

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