长江中下游贵池矿集区燕山期岩浆作用及其地质意义:年代学、地球化学及Sr-Nd-Hf同位素证据

长江中下游贵池地区燕山期侵入岩发育,与成矿关系密切.本文对该区侵入岩开展了详细的锆石U-Pb年代学、地球化学及Sr-Nd-Hf同位素研究.结果表明,马头花岗闪长斑岩形成于147±2Ma,而花园巩石英二长岩形成于127±1Ma,比花岗闪长斑岩晚约20Ma.早期的花岗闪长斑岩(147 ～ 145Ma)为高钾钙碱性系列,具有高Al2O3、Sr含量和Sr/Y、La/Yb比值,以及低的Y、Yb含量,与埃达克质岩的地球化学特征一致;而晚期石英二长岩(127Ma)和石英正长岩为钾玄岩系列,具有高的(Na2O+ K2O)、Zr、Nb、Y含量和Y/Nb、Yb/Ta比值,与造山带A2型花岗岩地球化学特征相似;碱长花岗岩(125～124Ma)同样具有A型花岗岩的地球化学特征,但与石英二长岩、石英正长岩相比,碱长花岗岩的Y/Nb、Yb/Ta比值相对较低,具板内环境A1型花岗岩的地球化学特征.因此,贵池地区岩浆岩从早期的埃达克质岩变为晚期的A型花岗岩,反应了晚中生代时期长江中下游地区的构造环境由大陆边缘环境向伸展环境的转变.     

长江中下游成矿带钨矿床

长江中下游成矿带是我国重要的铜-铁-金多金属成矿带,近年来在长江中下游成矿带内发现多处白钨矿床和矿化点,为该成矿带的成矿学研究提供了新的研究课题。相比成矿带铜铁金多金属矿床研究程度,钨矿床成矿作用研究明显薄弱,尚未进行系统的成矿作用和成矿规律总结。成矿带内发育的钨矿床主要为北亚带的东顾山矿床、主带(中亚带)的阮家湾矿床和南亚带的桂林郑矿床和高家塝矿床。本文对这四个钨矿床及几个含钨矿床的地质和地球化学特征、成岩成矿时代、成矿岩体地球化学特征等方面的研究资料和成果进行了总结,讨论和试图阐明长江中下游成矿带钨矿床的成矿作用。研究显示,长江中下游成矿带存在三期钨成矿作用,分别为146～143Ma、127Ma和97Ma,在成矿带的铜主成矿期前和铁成矿期均有钨成矿作业发生。钨矿床中白钨矿的Sr-Nd同位素组成分别落入董岭式基底或江南式基底范围,表明长江中下游成矿带的董岭式和江南式基底是形成原始含矿岩浆的物质基础。长江中下游成矿带的钨矿床成矿岩体为中酸性岩,ε_(Hf)(t)值很低,且Zr/Hf、K/Rb比值小,表明成钨岩浆岩为古老地壳物质重熔并经历了较充分的分异演化,对比成矿带中成铜、成铁岩体,源区性质可能是导致长江中下游成矿带金属成矿差异的根本原因。燕山期的陆内俯冲是造成长江中下游成矿带钨矿床成矿的主导机制。     

长江下游宁镇地区晚中生代侵入岩：同位素年龄、地球化学特征与成因探讨

发育于长江中下游构造-岩浆-成矿带最东端宁镇地区的晚中生代中酸性-酸性侵入岩以富钠、高Sr和Ba、富集轻稀土元素,强烈亏损重稀土元素为特征,高场强元素Ti、Nb、Ta等表现出显著的负异常,岩石地球化学的总体特征类似于高Sr/Y的埃达克岩。但与长江中下游其他地区的高Sr/Y岩浆岩相比,宁镇地区的这些侵入岩体还表现出低的放射性成因Pb、更低的重稀土元素含量、相对高的MgO、Cr和Ni含量及Mg#值等特征,推测它们的形成过程是由(再)富集的上地幔物质部分熔融形成的岩浆与古老的大陆下地壳物质部分熔融形成的埃达克质岩浆混合,混合岩浆在演化过程中还经历过较强的矿物分离结晶作用以及一定程度的上地壳物质混染。该再富集事件的发生可能与俯冲的古太平洋板块部分熔融所析出的熔体(或流体)交代上覆的地幔楔有关,导致原已富集的陆下岩石圈地幔更进一步富集挥发分以及不相容元素,古老的富集地幔中所累积的放射性成因Sr、Nd同位素被"中和",该作用在长江中下游地区可能仅影响到最东段的宁镇地区,并没有波及到更靠内陆的其他地区。宁镇地区的这些埃达克岩侵位于100~108Ma的早白垩世末期,晚于长江中下游其他地区高Sr/Y岩体长达30Ma左右,其间存在着较长时间的岩浆活动静止期,意味着它们可能形成于不同的动力学背景。后者的形成可能与区内印支期—早燕山期陆内挤压造山后的应力松池,加厚的大陆下地壳及其富集的岩石圈地幔发生拆沉和部分熔融有关,这种发生在长江中下游广大地区的岩石圈减薄事件可能并没有波及到最东段的宁镇地区。而前者可能与早白垩世末期—晚白垩世初期,太平洋板块相对亚洲大陆板块运动方向发生了改变,中国东部大陆边缘进入拉张-裂解的构造环境有关,但其效应在长江中下游地区可能主要影响到了最东段的宁镇地区,其他地区对这次构造变动并没有产生明显的岩浆活动。     

长江中下游成矿带成矿规律和成矿模式

长江中下游成矿带作为中国东部重要的成矿带之一,成矿地质条件、成矿规律和成矿模式的相关研究已经十分深入,形成了一系列公认的理论研究成果,本文重点论述了成矿带成矿地质条件和成矿规律方面研究的新进展,并在此基础上构筑了成矿带的成矿模式。本文主要开展了以下总结工作:(1)将成矿带的构造要素突破以往按构造单元分解的做法,确立跨构造单元的"复合构造系统",结合成矿带成岩成矿作用特点,重新确定了长江中下游成矿带的范围,并对成矿亚带进行了重新划分;(2)收集汇总了长江中下游成矿带近年来国内外学者最新的成岩成矿年龄数据,总结了矿床时空分布规律;(3)从地质,地球物理和地球化学等方面,总结归纳了沿基底结合带复活的网状断裂系统,阐明了成矿带的控矿构造格架,分析了长江中下游成矿带的成因规律;(4)补充和完善了断隆区和断凹区的成矿模式,并初步构筑了长江中下游成矿带综合成矿模式。提出长江中下游成矿带内主体成岩成矿作用总体上分为走滑挤压阶段(146~135Ma)、走滑引张阶段(135~126Ma)和拉张伸展阶段(126~123Ma)等三个阶段,古太平洋板块作用导致的壳幔过程,引发含元古代弧岩浆岩源区活化和中生代的构造活化("双活化")是长江中下游成矿带形成的主要机制。     

Late Mesozoic magmatism of the Jiurui mineralization district in the Middle–Lower Yangtze River Metallogenic Belt, Eastern China: Precise U–Pb ages and geodynamic implications

The Middle–Lower Yangtze River metallogenic belt (MLYRMB), extending from Daye in Hubei Province in the west to Zhenjiang in Jiangsu Province in the east, hosts a number of large polymetallic (Cu–Au–Mo, Fe, Zn, Pb, and Ag) deposits and constitutes one of the most important metallogenic belts in China. The Cu–Au–Mo deposits in the Jiurui district are an important component of the MLYRMB. In this study we carried out precise and detailed zircon U–Pb dating for all types of magmatic rocks from the Wushan ore deposit in the Jiurui district. Three samples of Cu–Au–Mo-related porphyries from different ore belts at Wushan were analyzed and yielded zircon U–Pb ages of 148.0 ± 1.0 Ma, 145.4 ± 0.9 Ma and 147.3 ± 0.9 Ma, respectively. A series of dykes were emplaced immediately following the Cu–Au–Mo-related porphyries at Wushan. A dark-colored basic dyke which intruded into the granodiorite porphyry at Wujia gold deposit near Wushan was dated at 144.5 ± 1.2 Ma. Two lamprophyre dykes taken from the north ore belt at Wushan underground mining stops were dated at 143.6 ± 0.9 Ma and 144.3 ± 0.9 Ma, respectively. A late-stage dyke which was also taken from the Wushan north ore belt yielded an age of 142.6 ± 1.0 Ma and might represent the end of magmatism in the Wushan ore deposit. These new geochronological data demonstrate that the time range of magmatism in the Wushan ore deposit is approximately between 148 Ma and 143 Ma, showing that the magmatic activity at Wushan was rapid and intensive. The ages of Cu–Au–Mo-related porphyries from other areas in the Jiurui district, such as the Dongleiwan, Yangjishan and Chengmenba ore deposits, were also measured and yielded zircon U–Pb ages of 141.5 ± 1.7 Ma, 143.4 ± 1.4 Ma and 146.6 ± 1.0 Ma, respectively. Combined with those previously reported zircon U–Pb age results from the Jiurui district, the present age data set demonstrates that extensive magmatism in the Jiurui district was coeval and intensive, marked by a magmatic activity in the age range of 148 to 138 Ma and peaked between 148 Ma and 142 Ma. According to the statistics of all those precise zircon U–Pb ages, the Cu–Au–Mo-related porphyries in the Edong and Tongling districts in the MLYRMB show similar ages, and they have a slightly younger peak age and a longer duration than that of the Jiurui district. The geographic shape of the MLYRMB in the Cretaceous shows an arcuate structure, the Jiurui district is located at the transitional point of the arcuate structure and the Edong and Tongling districts are situated on both sides of the arcuate structure. Considering that the Jiurui district has a slightly older peak age and a shorter duration of magmatic activity than that in the Edong and Tongling districts, it seems that the arcuate structure of the MLYRMB played an important role in the formation of these Cu–Au–Mo-related porphyries. Consequently, we suggest that the genesis of the Late Mesozoic magmatic rocks along the MLYRMB may have been due to a tectonic activity developed from southeast to northwest, which probably has a close relationship with the subduction of the paleo-Pacific plate beneath the Eurasian plate in Mesozoic times.     

Geological and Geochemical Constraints on the Newly Discovered Yangchongli Gold Deposit in Tongling Region, Lower Yangtze Metallogenic Belt

The newly discovered Yangchongli gold deposit is a unique independent gold deposit in the Tongling ore-cluster region controlled by the tectonic alteration firstly discovered in the Lower Yangtze Metallogenic Belt(LYMB). The host magmatic rocks mainly consist of monzodiorite and K-feldspar granite. The LA-ICP-MS U-Pb zircons dating yielded weighted mean ~(206)Pb/~(238)U ages of 140.7 ± 1.8 Ma and 126.4 ± 1.2 Ma for the monzodiorite and K-feldspar granite, respectively. Monzodiorites are enriched in Sr, Ba, Rb, and depleted in Y, Yb with high Sr/Y and La/Yb ratios, similar to the geochemical features of adakite, considered as products of differentiation of mafic magmas originating from lithospheric mantle melt/fluids caused by metasomatism during paleo-Pacific Plate subduction in the Mesozic. In contrast, the compositions of K-feldspar granites are A-type granites, indicating an extensional tectonic background. Gold ores hosted in the fracture zone occurred as quartz vein within cataclastic rock. Sulfur and lead isotopes from pyrites show crust-mantle mixing characteristics. Metal components from strata also took part in the gold mineralization, and resulted from two episodes of magmatism that were probably related to tectonic transition from a compressive to an extensional setting between 140–126 Ma, which led to the Mesozoic large-scale polymetallic mineralization events in eastern China.     

长江中下游成矿带陆内斑岩型矿床的成岩成矿作用

陆内环境斑岩型矿床的发现对斑岩成矿理论的完善具有重要意义。长江中下游成矿带作为中国东部重要的陆内成矿带之一,成矿带内发育多个重要的斑岩型矿床,如铜山口Cu-Mo矿床、鸡冠嘴Cu-Au矿床、白云山Cu矿、城门山Cu-Mo矿床、武山Cu-Mo矿床、丰山洞Cu-Au矿床、丁家山Cu矿、洋鸡山Au矿、沙溪Cu-Au矿床、冬瓜山Cu-Au矿床、舒家店Cu矿床和安基山Cu矿床等。本文选取成矿带内典型的、具有代表性的斑岩型矿床,对其地质特征(地层、构造、含矿斑岩、脉体特征和围岩蚀变)、成岩成矿年代、成矿岩体的岩石化学和成岩成矿地球化学等方面的研究资料和成果进行了系统总结,讨论和试图阐明长江中下游成矿带陆内斑岩型矿床的成岩成矿作用与成矿模式。研究显示,长江中下游成矿带形成于燕山期陆内造山过程,成矿斑岩岩浆活动和成矿作用主要发生于149~105Ma之间,进一步可以分为早、中、晚三阶段:149~135Ma、133~125Ma和123~105Ma,三阶段岩浆活动和成矿作用主要发生于成矿带中的断隆区,早阶段(149~135Ma)和晚阶段(123~105Ma)多为斑岩-矽卡岩型矿化,中阶段(133~125Ma)矿化为典型的斑岩型矿化。长江中下游成矿带内斑岩型矿床的含矿斑岩为高钾钙碱性-钙碱性系列岩石,大部分具有埃达克岩的地球化学特征,可能为源自富集地幔的岩浆和加厚下地壳部分熔融的岩浆混合的产物,源自富集地幔的基性岩浆对成矿具有至关重要的作用,它的混入使得混合岩浆富水、硫和金属(Cu、Au)等。进一步通过与岩浆弧环境的斑岩型矿床对比研究发现,长江中下游成矿带斑岩型矿床一般不发育高级泥化岩帽(advanced argillic liithocaps)以及浅部的高-中硫矿化蚀变系统,含矿岩浆源区性质和成矿物质来源等与岩浆弧环境的斑岩型矿床明显不同。     

贵池岩体的锆石定年和地球化学:岩石成因和深部过程

贵池地区的贵池岩体和茅坦岩体是下扬子地区两个重要的A型花岗岩岩体.野外岩相学观察将贵池岩体分为中心相和边缘相.在前人工作的基础上,对其进行了锆石U-Pb定年以及元素、同位素地球化学研究.两个岩体的SiO2和K2O含量高,MgO、Al2O3、CaO、P2O5、MnO、TiO2含量低;K2O/Na2O比值、FeOT/MgO比值高,碱铝比(NK/A)在0.88 ～0.93之间,铝过饱和度(A/CNK)在1.02 ～1.10之间.同时,这些岩体稀土含量较高,轻稀土富集,具有明显的Eu负异常,大离子亲石元素Ba、Sr明显负异常以及很低的Cr、Ni含量.初始87Sr/86Sr (t)比值介于0.7065 ～0.7111之间,εNd(t)较为集中,为-6.7 ～-7.3.其中,贵池岩体边缘相和茅坦岩体SiO2含量相对较高,全碱含量相对较低,稀土含量相对较低,TAS图上位于亚碱性系列,U -Pb定年结果分别为124.6±2.0Ma和127.7±1.8Ma;贵池岩体中心相SiO2含量相对较低,全碱含量相对较高,TAS图上位于碱性系列,U-Pb定年结果显示了两期岩浆活动,分别为145.4±3.2Ma和123.0±3.7Ma.综合分析表明,贵池岩体边缘相和茅坦岩体源于中上地壳的部分熔融;贵池岩体中心相是两期岩浆混合的产物,分别是早期来自富集岩石圈地幔结晶分异的中酸性碱性岩浆和晚期形成贵池岩体边缘相的A型花岗岩浆.结合长江中下游地区高碱钙碱性侵入岩和火山岩的研究成果,表明127 ～123Ma是长江中下游地区地壳伸展最强烈的阶段.     

Three-dimensional P-wave Velocity Structure Modelling of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt: Crustal Architecture and Metallogenic Implications

In this study, we compiled and analyzed 69310 P-wave travel-time data from 6639 earthquake events. These events (M ≥ 2.0) occurred from 1980s to June 2019 and were recorded at 319 seismic stations (Chinese Earthquake Networks Center) in the study area. We adopted the double-difference seismic tomographic method (tomoDD) to invert the 3-D P-wave velocity structure and constrain the crust-upper mantle architecture of the Middle and Lower Reaches of the Yangtze River Metallogenic Belt (MLYB). A 1-D initial model extracted from wide-angle seismic profiles was used in the seismic tomography, which greatly reduced the inversion residual. Our results indicate that reliable velocity structure of the uppermost mantle can be obtained when Pn is involved in the tomography. Our results show that: (1) the pattern of the uppermost mantle velocity structure corresponds well with the geological partitioning: a nearly E–W-trending low-velocity zone is present beneath the Dabie Orogen, in contrast to the mainly NE-trending low-velocity anomalies beneath the Jiangnan Orogen. They suggest the presence of thickened lower crust beneath the orogens in the study area. In contrast, the Yangtze and Cathaysia blocks are characterized by relatively high-velocity anomalies; (2) both the ultra-high-pressure (UHP) metamorphic rocks in the Dabie Orogen and the low-pressure metamorphic rocks in the Zhangbaling dome are characterized by high-velocity anomalies. The upper crust in the Dabie Orogen is characterized by a low-velocity belt, sandwiched between two high velocity zones in a horizontal?direction, with discontinuous low-velocity layers in the middle crust. The keel of the Dabie Orogen is mainly preserved beneath its northern section. We infer that the lower crustal delamination may have mainly occurred in the southern Dabie Orogen, which caused the mantle upwelling responsible for the formation of the granitic magmas emplaced in the middle crust as the low-velocity layers observed there. Continuous deep-level compression likely squeezed the granitic magma upward to intrude the upper crustal UHP metamorphic rocks, forming the ‘sandwich’ velocity structure there; (3) high-velocity updoming is widespread in the crust-mantle transition zone beneath the MLYB. From the Anqing-Guichi ore field northeastward to the Luzong, Tongling, Ningwu and Ningzhen orefields, high-velocity anomalies in the crust-mantle transition zone increase rapidly in size and are widely distributed. The updoming also exists in the crust-mantle transition zone beneath the Jiurui and Edongnan orefields, but the high-velocity anomalies are mainly stellate distributed. The updoming high-velocity zone beneath the MLYB generally extends from the crust-mantle transition zone to the middle crust, different from the velocity structure in the upper crust. The upper crust beneath the Early Cretaceous extension-related Luzong and Ningwu volcanic basins is characterized by high velocity zones, in contrast to the low velocity anomalies beneath the Late Jurassic to Early Cretaceous compression-related Tongling ore field. The MLYB may have undergone a compressive-to-extensional transition during the Yanshanian (Jurassic–Cretaceous) period, during which extensive magmatism occurred. The near mantle–crustal boundary updoming was likely caused by asthenospheric underplating at the base of the lower crust. The magmas may have ascended through major crustal faults, undergoing AFC (assimilation and fractional crystallization) processes, became emplaced in the fault-bounded basins or Paleozoic sequences, eventually forming the many Cu-Fe polymetallic deposits there.     

长江中下游成矿带铁-铜成矿系统结构的地球物理探测: 综合分析

成矿系统是在深部过程驱动下形成的、具有自组织的能量及物质迁移-汇聚系统。系统在形成和演化过程中,在岩石圈不同尺度上留下“痕迹”,这种“痕迹”可以通过地球物理、地球化学和遥感等方法进行探测或观测。文章尝试在成矿系统理论框架下,对近10多年来在长江中下游成矿带进行的多尺度地球物理、地球化学探测结果进行分析,识别典型陆内成矿系统“源区”“通道”“场所”的地球物理、地球化学“痕迹”,尝试构建陆内成矿系统的空间结构模型。主要结论有:(1)长江中下游晚中生代的大规模铁、铜多金属成矿作用是一个完整的成矿系统。该系统包括3个子系统,分别为与高钾钙碱性岩浆岩有关的夕卡岩-斑岩成矿子系统、与橄榄安粗岩有关的陆相火山岩铁(硫)成矿子系统和与碱性岩有关的铜-金(铀)成矿子系统。(2)成矿系统的“源区”来自富集地幔的熔融、底侵,并在壳/幔边界与下地壳物质的混合,具有多级分布特点。幔源岩浆与地壳物质混合的比例决定了成矿金属的类型。(3)成矿带发育的“鳄鱼嘴”构造是铁铜成矿系统的主干“通道”。成矿系统“末端”矿质沉淀的“场所”主要受近地表褶皱、断裂、层间滑脱断层,以及由它们形成的断裂(裂隙)网络控制。(4)区域磁异常、放射性和地球化学异常是成矿系统残留“痕迹”的响应和“标识”。通过分析不同尺度的“标识”特征,可以深入认识成矿系统的空间结构,并可用于深部成矿预测。     

Genesis of Early Cretaceous porphyrite-type iron deposits and related sub-volcanic rocks in the Ningwu Volcanic Basin,Middle-Lower Yangtze Metallogenic Belt,Southeast China

ABSTRACT

The Ningwu Volcanic Basin (NVB), located in the Lower Yangtze Metallogenic Belt, is characterized by the widespread occurrence of porphyritic iron-ore deposits. These deposits are clustered in three areas within the basin: the northern, central, and southern districts. Our study shows that the differences are existed in geochemistry of the rocks and the mineralization of the deposits among these three districts. Though results of Sr–Nd isotopes indicate that the parental magma of the sub-volcanic rocks in NVB were derived from EMI and EMII, however, the sub-volcanic rocks from the northern and southern districts have higher ε_Nd(t) values (t = 130 Ma) and lower initial ⁸⁷Sr/⁸⁶Sr ratios (t = 130 Ma) than those from middle district. The rocks from northern and southern districts are similar to EMI in geochemistry; in contrast, rocks from the middle district are close to EMII. Meanwhile, the deposits from different districts show some differences in mineralization. The magnetites from the northern ore deposits are rich in Cu, Mo, Zn, and Mg and poor in Ca, Al, and Ti, which probably indicates that the magnetites from the northern ore deposits closer to hydrothermal genesis than to magmatic genesis, but the magnetites from the centre are closer to both magmatic and hydrothermal geneses. Based on the fact that a part of the sub-volcanic rocks is closer to EMI and another part to EMII in geochemistry, we suggested that the incorporation of the lower and upper crustal materials into the source regions of the sub-volcanic rocks has taken place by different manner and processes. Integrated with analysis of the tectonic evolution of NVB, we come to the conclusion that the sub-volcanic rocks have recorded the geochemical imprints of the subduction of Yangtze block towards North China block during Indosinian Period and the delamination of the lower crust of Yangtze block during Yanshanian Period.     

长江中下游—大别造山带中生代火山岩特征及成因

中国中东部长江中下游地区和大别造山带广泛发生了中生代岩浆作用,火山岩均集中在中间阶段,时代分别为135~127 Ma和133~125 Ma。长江中下游地区多个中生代火山盆地发育高钾钙碱性系列双峰式火山岩和中基性橄榄安粗岩系列火山岩。这些岩石富集大离子亲石元素,亏损高场强元素,弱富集Sr-Nd-Hf同位素,具有高放射成因Pb同位素组成,指示地幔源区地壳组分的加入。其中,中基性火山岩起源于富集的岩石圈地幔,受到俯冲大洋板片析出的含水熔体交代,晚阶段的超碱质火山岩起源于类似交代介质交代的软流圈地幔,指示岩浆源区的加深。大别造山带中生代火山岩包括高钾钙碱性系列和超钾质系列,均富集大离子亲石元素,亏损高场强元素,高度富集Sr-Nd-Hf同位素,具有低放射成因Pb同位素组成,与长江中下游地区差异显著。其中,高钾钙碱性系列火山岩起源于交代富集的岩石圈地幔,交代介质为印支期深俯冲的华南陆壳析出熔体,而晚阶段的超钾质火山岩起源更深,是深俯冲的华南陆壳在高压下,多硅白云母分解产生熔体交代的地幔源区。长江中下游地区幔源火山岩记录了俯冲的古太平洋板块的直接物质贡献,而大别造山带地幔源区记录了印支期俯冲陆壳的信息。两个构造单元火山岩早、晚阶段均表现出岩浆源区的加深,长江中下游地区对应了古太平洋板块的低角度俯冲及俯冲板片的回卷(约130 Ma),而大别造山带在古太平洋板块俯冲回卷的动力学机制下,发生造山带的垮塌和岩石圈的拆沉。     

Mineralization,Geochemistry and Zircon U‐Pb Ages of the Paodaoling Porphyry Gold Deposit in the Guichi Region,Lower Yangtze Metallogenic Belt,Eastern China

The newly discovered Paodaoling porphyry Au deposit from the Guichi region, Lower Yangtze River Metallogenic Belt(LYRB), contains 35 tons of Au at an average grade of ~1.7 g/t. It is a porphyry ‘Au-only' deposit, as revealed by current exploration in the depths, mostly above-400 m, which is quite uncommon among coeval porphyry mineralization along the LYRB. Additionally, there are also Cu-Au bearing porphyries and barren alkaline granitoids in the Paodaoling district. Zircon LA-ICP-MS U-Pb dating of the Cu-Au-bearing porphyries yield an age of 141–140 Ma, falling within the main magmatic stage of the LYRB, whereas the barren granites give an age of 125–120 Ma, coeval with the regional Atype granites. The Cu-Au-bearing porphyries are LILE-, LREE-enriched and HFSE-depleted, typical of arc magmatic affinities. The barren granites are HFSE-enriched, with lower LREE/HREE ratios and pronounced negative Eu anomalies. The Cu-Au-bearing porphyries in the Paodaoling district have high oxygen fugacities and high water content. Pyrite sulfur isotopes of the Paodaoling gold deposit indicate a magmatic-sedimentary mixed source for the ore-forming fluids. Based on the alteration and poly-metal zonation of the deepest exploration drill hole from the Paodaoling Au deposit, we propose that Cu ore bodies could lie at depth beneath the current Au ore bodies. The magmatism and associated Cu-Au mineralization of the Paodaoling district are likely to have formed in a subduction setting, during slab rollback of the paleo-Pacific plate.     

长江中下游转换构造结与区域成矿背景分析

中国东部中生代以来的地壳运动频繁,构造演化复杂,岩浆活动剧烈,成矿作用多样,是不同体制构造转换的重要地区.长江中下游地区是中生代特提斯构造体制与太平洋构造体制转换的经典地区,是两大构造体制交汇和转换的焦点部位,具有岩石圈物质重组、结构重建的时-空演化关系.长江中下游转换构造结由是中国东部中生代特提斯构造体制与太平洋构造...     

长江中下游地区怀宁盆地侵入岩的锆石U-Pb年代学和Hf同位素研究

怀宁盆地是长江中下游地区晚中生代发育的一系列断陷型火山岩盆地中的一个,盆地内以发育橄榄安粗质的火山岩为特色。本次主要选取该盆地内研究程度相对薄弱且具代表性的宋家和史家岩体首次开展了系统的锆石U-Pb年龄和Lu-Hf同位素测定。测年结果显示,宋家和史家岩体分别形成于128.5±1.6 Ma和126.8±1.2 Ma,与该盆地内火山岩系(122~132 Ma)几乎同期,都为早白垩世岩浆活动的产物,对应于中国东部岩石圈伸展减薄的高峰期,表明怀宁盆地内火山-侵入岩即形成于该地球动力学背景下。相关的锆石εHf(t)值分别介于–12.6~–6.0和–12.4~–4.7,二阶段模式年龄分别介于1576~1979 Ma和1475~1961 Ma,这与长江中下游地区橄榄安粗质中基性岩石的锆石Hf同位素组成基本一致。结合区域资料,我们认为怀宁盆地内宋家和史家岩体形成可能与富集幔源岩浆与下地壳物质(类似董岭群)的混合作用有关。     

庐枞矿集区与钨矿床有关的花岗岩的年代学及地球化学特征:岩石成因及其对长江中下游晚白垩世成矿的启示

长江中下游是中国东部一个重要的与中生代岩浆作用有关的Cu-Au-Mo-Fe矿成矿带。近期勘查工作在庐枞矿集区东顾山地区深部首次发现了与隐伏花岗岩密切相关的钨钼多金属矿化。岩石学和岩石地球化学研究结果表明,隐伏花岗岩具有高硅富碱高钾、贫铁贫镁及铝弱饱和的特征,属于高钾钙碱性系列岩石;具有富集Rb、Th、U等强不相容元素和轻稀土元素,亏损Nb、P、Ti、Y等高场强元素,低ε_(Nd)(t)(-18.2~-17.1)和相对高的((~(87)Sr/~(86)Sr)_i)(0.70596~0.70631)的特征,推测其岩浆来源于扬子下地壳的部分熔融,岩浆在就位之前经历了一定程度的分异结晶作用。利用LA-ICP MS锆石U-Pb定年获得96.7±1.3Ma的锆石年龄,表明其属于晚白垩世早期岩浆活动的产物。结合区域成岩成矿时空格架,认为东顾山地区隐伏花岗岩及与之有关的钨钼多金属矿化可能代表了长江中下游成矿带的新一期成岩成矿事件。     

长江中下游成矿带矽卡岩型矿床矿物包裹体激光拉曼分析结果及其地质-地球化学意义

矽卡岩矿床各种硅酸盐矿物中熔融包裹体和流体-熔融包裹体的显微测温资料和相成分让我们提出过大量矽卡岩是岩浆成因的建议。在本文中,我们提供沿长江中下游成矿带的许多矽卡岩矿床包含在石榴子石和辉石里的熔融包裹体和流体-熔融包裹体的激光拉曼分析结果,目的是证明所研究的并与Cu-Fe-Au矿床共生的矽卡岩系岩浆成因。我们的研究结果显示,熔融包裹体只含固体相和微量气相。流体-熔融包裹体除了含大量固相外,还含微量流体和气相以及没有被仪器检测到的气体。固体相与包裹体寄主矿物相同或类似。流体相主要为水或盐水溶液和包括C6H6、C3H6、C3H8、CH4、CO2和O2的气体。我们提出,熔融包裹体和流体-熔融包裹体是原始岩浆的最好代表。这就证明,矽卡岩组合是由一个原生岩浆直接结晶而成。此外,我们还讨论了岩浆矽卡岩形成的温度、分布范围和规模、形成机制和与Cu-Fe-Au矿化作用的联系。     

Cathodoluminescence and Trace Element Composition of Scheelite from the Middle-Lower Yangtze River Metallogenic Belt (MLYB): Implications for Mineralization and Exploration

The Middle–Lower Yangtze River Metallogenic Belt (MLYB) is known to contain abundant copper and iron porphyry-skarn deposits, with an increasing number of tungsten deposits and scheelite in Fe–Cu deposits being discovered in the MLYB during recent decades. The ore genesis of the newly-discovered tungsten mineralization in the MLYB is poorly understood. We investigate four sets of scheelite samples from tungsten, iron and copper deposits, using CL imaging and LA–ICP–MS techniques to reveal internal zonation patterns and trace element compositions. The REE distribution patterns of four studied deposits show varying degrees of LREE enrichment with negative Eu anomalies. The oxygen fugacity of ore-forming fluid increased in Donggushan, while the oxygen fugacity of ore-forming fluid decreased in Ruanjiawan, Guilinzheng and Gaojiabang. The scheelites from the Donggushan, Ruanjiawan, Guilinzheng and Gaojiabang deposits show enrichment in LREEs and HFSE, with Nb/La ratios ranging from 1.217 to 52.455, indicating that the four tungsten deposits are enriched in the volatile fluorine. A plot of (La/Lu)N versus Mo/δEu can be used to distinguish quartz vein type, porphyry and skarn tungsten deposits. This study demonstrates that scheelite grains can be used to infer tungsten mineralization and are effective in identifying magmatic types of tungsten deposits in prospective mining sites.     

长江中下游地区繁昌盆地火山岩成因:锆石Hf-O同位素制约

繁昌盆地是长江中下游地区沿江火山盆地之一,目前针对该盆地火山岩的研究相对薄弱,因此本文选择该盆地中分村组流纹岩、赤沙组粗安岩、蝌蚪山组流纹岩为研究对象,结合本课题组前期发表的研究成果,开展锆石原位Hf-O同位素和U-Pb年代学研究,以期深入探讨繁昌盆地火山岩的岩石成因。中分村组流纹岩、赤沙组粗安岩、蝌蚪山组流纹岩的LA-ICPMS锆石U-Pb定年结果分别为132.1±1.5Ma、129.1±1.8Ma和129.5±3.3Ma。三组火山岩的εHf(t)值分别为-8.2~-5.8、-6.0~-3.4、-7.4~-2.2,δ18O值分别为6.3‰~7.9‰、7.0‰~7.8‰、6.6‰~8.2‰,从中分村组到赤沙组再到蝌蚪山组εHf(t)、δ18O值逐渐升高。综合分析表明:中分村组、赤沙组、蝌蚪山组火山岩的源区相似,它们是新元古新生地壳熔融形成的岩浆和少量的富集岩石圈地幔部分熔融形成的岩浆混合后经结晶分异形成。从148~133Ma至132~126Ma,本地区经历了俯冲带构造环境至拉张环境的转换,古太平洋板片的俯冲及后撤的转换时间在132Ma左右。