柴北缘鱼卡河榴辉岩的变质演化——石榴石成分环带及矿物反应结构的证据

柴北缘鱼卡河榴辉岩的典型矿物组合为石榴石-绿辉石-多硅白云母-金红石。其中粗粒石榴石变斑晶普遍保存进变质生长环带,从核部到边部石榴石的化学成分、包体矿物的种类和粒度皆呈现出规律的分带性。岩相学和矿物化学研究进一步表明,该榴辉岩经历了前榴辉岩相、榴辉岩相及后榴辉岩相三个主要变质演化阶段。前榴辉岩相以石榴石核部成分及核部包体矿物组合石榴石(GrtⅠ) 角闪石(AmpⅠ) 斜长石(PⅡ) 石英(Qtz)为特征,P-T 估算结果为450～500℃和0.6～0.7GPa。榴辉岩相变质阶段又可细分为早期、峰期榴辉岩和退变角闪榴辉岩三个亚相。早期榴辉岩亚相以石榴石幔部成分和幔部包体矿物组合石榴石(GrtⅡA) 绿辉石(OmpⅡA) 多硅白云母(PheⅡA)±黝帘石(Zoi) 金红石(Ru)为代表,估算的温压条件为580～640℃和2.4～2.5GPa;峰期榴辉岩相以石榴石的边部(GrtⅡB)及基质中绿辉石(OmpⅡB)和多硅白云母(PheⅡB)的核部为代表,矿物组合为 GrtⅡB OmpⅡB PheⅡB Ru,估算的 P-T 条件为620～680℃和3.0～3.4GPa;退变角闪榴辉岩相以共生的石榴石的最边部(GrtⅡC)、基质绿辉石(OmpⅡC)和多硅白云母(PheⅡC)的边部及镁红闪石(AmpⅡ)组合为代表,矿物组合为 GrtⅡC OmpⅡC AmpⅡ PheⅡC,估算的 P-T 条件为700～720℃和2.3～2.4GPa。后榴辉岩阶段主要为麻粒岩-高角闪岩相,以绿辉石分解形成透辉石 钠长石冠状体以及进一步分解形成韭闪石 斜长石,铁红闪石分解形成浅闪石 斜长石为代表,P-T 估算结果为550～600℃和0.6～1GPa。温压估算结果表明,鱼卡河榴辉岩经历了升温升压—升温降压—降温降压的一个顺时针 P-T 演化轨迹,它记录了从俯冲-超高压变质-抬升的连续的演化过程。峰期变质条件为630～680℃和3.0～3.4GPa,已达超高压变质范畴。榴辉岩中进变质矿物组合和生长环带的保存说明榴辉岩的形成经历了相对快速的俯冲和折返的动力学过程。     

新疆西南天山哈布腾苏河高压-超高压变质带中榴辉岩和蓝片岩的岩石学及变质演化

对西南天山哈布腾苏河一带出露的典型榴辉岩和蓝片岩进行了详细的岩相学、矿物化学和温压条件综合研究。榴辉岩可分为蓝闪石榴辉岩、钠云母榴辉岩、绿帘石榴辉岩和蓝闪石榴角闪岩(退变榴辉岩)4类,蓝片岩可分为含蓝闪石石榴白云母钠长片岩、石榴白云母蓝闪片岩和石榴白云母蓝闪石英片岩3类。新鲜榴辉岩主要矿物组合为石榴石+绿辉石+钠云母+绿帘石,退变榴辉岩则为石榴石+蓝闪石+角闪石;蓝片岩主要矿物组合为石榴石+蓝闪石+多硅白云母+钠云母+钠长石+石英。榴辉岩和蓝片岩中石榴石变斑晶均保存进变质生长环带,从核部到边部XMn和XFe降低,XMg和XCa升高,指示了升温进变质的演化过程。根据榴辉岩矿物共生组合、石榴石内部包体组合分布特征及传统地质温压计估算结果,确定榴辉岩经历了4阶段的变质演化:早期硬柱石蓝片岩相进变质阶段、峰期榴辉岩相变质阶段(t=543～579℃,p=1.5～1.6 GPa)、峰后绿帘蓝片岩相退变质阶段(t=～450℃,p1.0GPa)和晚期蓝闪绿片岩相退变质阶段(t400℃,p0.5 GPa)。利用p-T视剖面图计算的榴辉岩、蓝片岩峰期变质温压条件与传统地质温压计估算结果十分相近,其中榴辉岩的峰期变质条件t=520～550℃,p=1.7～1.9 GPa;蓝片岩峰期变质条件t=520～620℃,p=1.7～2.3 GPa。本文估算的榴辉岩峰期变质压力条件与前人根据柯石英的发现而认为研究区部分榴辉岩及其围岩曾经历超高压变质作用的认识明显相悖,原因可能如下:①后期退变质作用引起研究区榴辉岩全岩成分、矿物化学成分的调整,在采用Grt-Cpx-Phe温压计和以全岩成分为基础的相平衡模拟方法估算峰期温压条件时受到影响,从而使估算峰期压力条件普遍偏低;②西南天山的榴辉岩可能并非全都经历了超高压变质作用,高压、超高压榴辉岩可能分别代表了不同变基性岩块在不同俯冲深度变质的产物。     

大别超高压变质带的进变质、超高压和退变质时代的准确限定:以双河大理岩中榴辉岩锆石SHRIMP U-Pb定年为例

在大别超高压变质带的双河地区存在一种特殊类型的榴辉岩,该类榴辉岩主要以似层状、条带状以及不规则透镜体赋存于大理岩中。矿物组成主要为石榴石、绿辉石以及少量的金红石、白云石、菱镁矿等。沿石榴石和绿辉石边缘常退变为角闪石+斜长石等,有的岩石完全退变为斜长角闪岩。激光拉曼和阴极发光综合分析表明,该类榴辉岩中的锆石可划分为两种类型:继承性碎屑锆石和变质锆石。继承性碎屑锆石十分少见,阴极发光图象具有明显的双层结构,即强发光的核和弱发光的边,核部和边部的包体矿物分别为Pl+Ap和Qtz+Pl。SHRIMP U-Pb定年结果表明。继承性碎屑锆石核部记录的207Pb／206Pb年龄为2701±15Ma,Th/U比值明显偏高为1．05,稀土元素配分模式显示重稀土明显富集,具有典型岩浆结晶锆石的特点;边部记录的207Pb／206Pb年龄为1801±12Ma-1753±22Ma,Th／U比值则明显偏低,为0．19-0．22之间,稀土元素配分模式显示重稀土相对平坦,具有典型变质锆石的特点。上述特征表明该类继承性碎屑锆石可能来源于太古代的基底,并经历了早元古代变质热事件的改造。新生的变质锆石无论是矿物包体还是阴极发光图象均与继承性碎屑锆石存在明显差异。有的变质增生锆石具有弱发光的核(阴极发光图象呈灰色)和强发光的边(阴极发光图象呈白色)。核部包体矿物组合为Qtz +Grt+Omp+Phe+Dol+Ap,具有典型石英榴辉岩相矿物组合特征,而边部则保存含柯石英的超高压包体矿物组合Coe+Grt +Omp+Mgs+Arg+Ap,表明该类锆石的核部和边部分别形成于俯冲进变质阶段和超高压变质阶段。另一部分变质增生锆石具有强发光的核(阴极发光图象呈白色)和弱发光的边(阴极发光图象呈黑色)。核部保存的标志性超高压包体矿物组合为Coe+Grt+Omp+Mgs+Arg+Ap,边部则保存Qtz+Cal等退变矿物组合,有的则缺乏矿物包体,表明该类锆石自超高压变质阶段开始生长,并经历了后期退变质作用的改造。从不同微区矿物包体组合的性质及其转变特征可以明显看出,自石英榴辉岩相进变质阶段到超高压峰期变质阶段存在下列转变反应:Qtz→Coe和Dol→Mgs+Arg;而自超高压峰期变质阶段到后期退变质阶段则存在下列退变反应:Coe→Qtz和Arg→Cal。SHRIMP U-Pb定年结果表明,含石英榴辉岩相矿物包体的锆石微区记录的206Pb／238U年龄为249-241Ma,加权平均值为244±4Ma,代表了深俯冲石英榴辉岩相进变质阶段的变质年龄;含柯石英等超高压矿物包体的锆石微区记录的206Pb／238U年龄为239-231Ma,加权平均值为234±3Ma,代表超高压阶段的峰期变质年龄;而含石英和方解石的退变边记录的206Pb／238U年龄为219-211Ma,加权平均值为216±6Ma,应代表后期折返阶段的角闪岩相退变质年龄。上述两类变质增生锆石微区的Th／U比值和稀土元素配分模式十分相似,Th／U比值变化于0．02- 0．18之间,稀土元素配分模式显示重稀土相对平坦,稀土元素总量明显低于继承性碎屑锆石,具有典型变质锆石的特点。根据锆石微区矿物包体的化学成分,采用Grt-Omp和Grt-Omp-Phe温压计,结合前人的变质反应实验资料的综合分析,确定榴辉岩的原岩在深俯冲过程的石英榴辉岩相进变质阶段的变质温压条件为T=588-668℃,P=1．7-1．8GPa;超高压峰期阶段的温压条件为T=784-849℃,P>5．5GPa;而构造折返过程中角闪岩相退变质阶段的温压条件为T=550-720℃,P=0．8～1．4GPa。由此可见,大别超高压变质岩的原岩——元古代(部分可能为太古代)的陆壳物质在早三叠纪发生俯冲至55- 60km深处,并经历了石英榴辉岩相变质作用。随后这些变质岩石继续深俯冲至165～175km的地幔深处,于中三叠纪发生了超高压变质作用,石英榴辉岩相矿物组合转变为超高压榴辉岩相矿物组合。最后这些超高压变质岩石发生构造折返,至晚三叠纪抬升到约30km的中下地壳深度,并经历了角闪岩相退变质作用的改造,超高压榴辉岩相矿物组合退变为角闪岩相矿物组合。由此推断,大别超高压变质带俯冲和折返速率分别为11-12km Myr-1和7．5-8．1km Myr-1。该项成果不仅确定了大别超高压变质地体的石英榴辉岩相进变质-超高压榴辉岩相峰期变质-角闪岩相退变质的年代谱系,而且对于重塑大别超高压变质地体的快速俯冲-折返的动力学模式有着重要的科学意义。     

柴北缘鱼卡榴辉岩的pT演化历史

鱼卡榴辉岩位于柴北缘HP/UHP变质带的西段,榴辉岩呈透镜状或似层状分布在变质泥质岩、花岗质片麻岩及少量大理岩中,主要由石榴石和绿辉石组成,具有含量不等的多硅白云母、角闪石、黝帘石(斜黝帘石或绿帘石)、金红石和石英等。岩相学和矿物化学研究显示榴辉岩经历了3期与俯冲和折返作用有关的变质演化阶段:(1)前榴辉岩相进变质阶段,榴辉岩矿物组合为石榴石(核) 绿帘石 斜长石 角闪石,以包体的形式保存于具有生长环带的石榴石核部,形成的温压条件为p=1.06～1.11GPa,t=560～577℃;(2)榴辉岩相变质阶段,以绿辉石、多硅白云母等矿物围绕石榴石定向分布为特征,其矿物组合为石榴石(边) 绿辉石 多硅白云母±黝帘石,温压估算获得榴辉岩相的变质条件为p=2.35～2.52GPa,t=610～680℃;(3)后榴辉岩相变质阶段,矿物组合为石榴石 角闪石 斜长石,主要存在于围绕榴辉岩透镜体分布的退变榴辉岩(角闪石化榴辉岩)中,形成的温压条件为p=1.09±0.12GPa,t=635±44℃。研究结果显示榴辉岩的pT轨迹具有“发卡”型特点,表明鱼卡榴辉岩经历了快速俯冲和折返的演化历史。     

中国大陆科学钻探主孔0~2000 m榴辉岩的退变质过程

中国大陆科学钻探主孔位于大别-苏鲁这条典型的超高压变质带上，孔内0-2000m的岩心中，各种榴辉岩占到50％以上。榴辉岩大多经历了不同程度的退变质。依据榴辉岩中主要矿物绿辉石和石榴石的退变质程度，0-2000m榴辉岩的退变质过程可分为2个大阶段，4个亚阶段：第一大阶段(又分为轻微退变质、部分退变质)、第二大阶段(又分为退变质和强退变质)。总的退变质趋势是：石榴石逐渐被韭角闪石或黑云母 绿帘石替代；绿辉石逐渐被角闪石 钠长石后成合晶替代，硬玉(1d)含量逐渐减少，并部分转化为霓辉石。榴辉岩在退变质过程中所经历的温压条件为：峰期变质温度为697-831℃，压力3．0Gpa左右；部分退变质阶段温度为629-776℃，压力1．2-1．6Gpa；退变质阶段温度为550-650℃，压力O．5-0．7Gpa；强退变质阶段温度为300-400℃，压力0．30-0．35Gpa。综合岩石、矿物及形成温压条件等特征，推断榴辉岩的折返过程经历了两个大阶段：第一大阶段是近等温降压的快速折返(榴辉岩在此期间经历了第一大阶段的退变质)，第二大阶段是降温降压的缓慢抬升(榴辉岩继而经历了第二大阶段的退变质)。绿辉石的完全退变质，既是划分榴辉岩两大退变质阶段的标志，同时也是区分两大折返阶段的标志。     

滇西勐库退变质榴辉岩的P-T-t轨迹及地质意义

滇西双江县勐库地区的退变质榴辉岩经历了多期退变质作用的改造,早期的平衡共生矿物组合难觅踪迹。应用传统的石榴石-单斜辉石(GC)温度计、石榴石-单斜辉石-多硅白云母(GCP)压力计进行变质作用的PT条件估算存在许多不确定性。本文应用魏春景等(2009)依据MORB成分计算的PT视剖面图上多硅白云母、石榴石、绿辉石的成分随体系中PT条件的变化情况,估算了进变质的P=2.00~2.30GPa,T=420~460℃,相当于硬柱石蓝片岩相—硬柱石-蓝闪石榴辉岩相;峰期变质的P=3.35~4.46GPa,T=530~610℃,相当于硬柱石榴辉岩相;早期退变质的P=2.00~2.50GPa,T=470~540℃,相当于硬柱石-蓝闪石榴辉岩相;中期退变质的P=0.95~1.43GPa,T=700~750℃,相当于角闪石榴辉岩相-高压麻粒岩相。晚期退变质作用以出现大量的闪石类矿物为特征,可划分为3个阶段,并显示了持续的降温、降压过程。结合区域地壳演化进程,本文详细讨论了上述P-T-t轨迹的地质意义。     

大别山西段含蓝闪石-蓝晶石榴辉岩的相平衡研究

目前对于大别山西段超高压榴辉岩仍存在一些不清楚的问题和模糊的认识,如蓝闪石和蓝晶石组合的稳定范围,峰期温压条件和矿物组合,以及早期退变质过程的矿物演化和流体作用。本文对取自大别山西段新县高压-超高压榴辉岩单元内不同地点的超高压榴辉岩样品进行了详细的岩石学和矿物学研究,在此基础上使用相平衡定量分析方法的 PT 视剖面图对它们进行了正演模拟计算,结果表明:含蓝闪石和蓝晶石榴辉岩处于相对低温或低压的蓝闪石榴辉岩和相对高温高压的蓝晶石榴辉岩的过渡区,其稳定的温压范围大致为温度590～700℃,压力1.7～3.3GPa,而且压力大于2.5GPa 时温度范围很窄,为600～640℃。由石榴石边缘成分和 PT 视剖面图确定的榴辉岩峰期温压条件为压力2.85～2.95GPa 和温度625～630℃,峰期矿物组合为石榴石 绿辉石 蓝闪石 蓝晶石 硬柱石 柯石英±多硅白云母。峰期之后,榴辉岩经历了快速近等温降压(ITD)的早期高压退变质作用,这是一个非平衡过程,所发生的主要变化如下:柯石英→石英,硬柱石→黝帘石 蓝晶石,在相对富镁岩石中出现滑石,当水含量较高时可以出现钠云母,蓝闪石在原来基础上有一定量的生长,并且绿辉石和多硅白云母很可能只部分地发生了成分变化,而石榴石几乎未发生改变。这样形成了目前观察到的矿物组成为石榴石 绿辉石 蓝闪石 蓝晶石 黝帘石/绿帘石 石英±多硅白云母±钠云母±滑石,它代表了 UHP 榴辉岩在早期高压退变质阶段结束时所具有的矿物组成,这一阶段结束时的温压条件大致为2.0～2.2GPa 和600～630℃;早期高压退变质阶段是脱水过程,流体是内部缓冲的。     

中祁连地块北缘退变榴辉岩的发现及其地质意义

1∶5万区域地质调查首次在中祁连地块北缘发现的退变榴辉岩,呈构造岩块分布于大羊陇一带的变质基底中。岩相学和矿物学研究显示,石榴石的矿物包体和化学成分具有进变质环带的特征,属于C类榴辉岩。石榴石核部成分以及残留于核部的黑云母、斜长石等矿物包体代表了进变质阶段(M1)矿物组合,计算得到其温压条件为568～580 ℃和0.80～0.82 GPa。大致估算得峰期榴辉岩相阶段(M2)温压条件为(669±5) ℃和(2.1±0.2) GPa。石榴石“白眼圈”结构指示了等温减压退变质作用,利用局部的平衡矿物获得高角闪岩相退变质阶段(M3)的温压条件为681～705 ℃和0.68～0.71 GPa。进一步的退变质作用发生在低角闪岩相条件下,以基质中出现粗粒的角闪石和斜长石为特征,估算得到这一阶段(M4)温压分别为500～545 ℃和0.38～0.43 GPa。上述变质过程形成一个顺时针的p-T演化轨迹,暗示板片经历过快速俯冲和折返。榴辉岩的锆石CL图像显示锆石大部分发光度低,为无分带、弱分带或海绵状分带,边部发育宽约5 μm的强阴极发光带,主体表现为变质增生锆石的特征。LA-ICP-MS锆石U-Pb定年获得峰期榴辉岩相变质的上限年龄为(485±22) Ma。根据岩石地球化学特征和构造环境判别,大羊陇榴辉岩的原岩为MORB,推测属于北祁连洋壳的组成部分。结合中祁连地块北缘广泛发育弧岩浆岩,确定了晚寒武世-中奥陶世北祁连洋壳存在向南的俯冲作用,其俯冲极性为南北双向俯冲。     

鲁东南岚山头榴辉岩的变质作用演化PTt轨迹及地质意义

岚山头含柯石英榴辉岩呈透镜状块体产于晚元古代含霓石花岗质片麻岩中.榴辉岩的典型矿物平衡共生可划分为四个阶段:(1)前柯石英榴辉岩相阶段(M1);(2)柯石英榴辉岩相阶段(M2);(3)第一退变质阶段(M3);(4)第二退变质阶段(M4).M2阶段典型的矿物共生组合为石榴石+绿辉石+柯石英±蓝晶石.其石榴石中Pyr组分17.9%～31.7%, 绿辉石中Jd组分29.1%～52.8%.各阶段的变质温压条件是:M1阶段P≤1.56GPa,T=700℃;M2阶段P>2.74～2.95GPa,T=722℃～981℃;M3阶段P=1.34～1.54GPa,T=568℃～589℃;M4阶段P=0.61～1.04GPa,T=469℃.M2变质阶段单颗粒锆石207Pb-206Pb年龄为613.3Ma±30.4Ma,M4阶段的多硅白云母的 40Ar-39Ar坪年龄为313.49Ma.据上述资料可重塑一个较完整的顺时针PTt轨迹的变质作用演化.退变质作用的两个阶段反映榴辉岩折返可分为两个阶段.     

中大别腹地榴辉岩锆石U-Pb年龄及其类型归属

根据对黄岗-牛凸岭地区榴辉岩样品JS249和JS250的岩相学研究表明,该地区榴辉岩具有明显的高压变质特征,石榴石中包含大量的早期矿物,成分环带显著,其峰期矿物组合主要为Grt+ Omp+ Phn+ Rt+ Qtz+ Ep+ Ky,角闪岩相退变矿物主要为Di+ Mg-Hbl+ Ab+ Prg+ Bt.对样品JS249和JS250温压条件进行计算,样品JS249为T=594±61℃,P=2.58±0.27GPa;样品JS250为T=616±56℃,P=2.14±0.14GPa.同时利用LA-ICPMS以及激光拉曼对这两个样品进行锆石U-Pb年代学研究和锆石包裹体分析,结果显示样品JS249锆石包体主要为角闪石、长石等退变矿物,其加权平均年龄为217.3±3.5Ma,该组年龄代表了角闪岩相退变质年龄;样品JS250锆石包含了石榴石、金红石、绿辉石等峰期矿物包体,其加权平均年龄为235.2±4.2Ma,该年龄应为峰期变质年龄.综合榴辉岩的岩石学、热力学和年代学的研究表明,黄岗-牛凸岭地区应属于低温高压单元,与南大别变质块体类似.     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。