Hydrocarbon Vapor Diffusion in Intact Core Sleeves

The diffusion of 2,2,4-trimethylpentane (TMP) and 2,2,5-trimethylhexane (TMH) vapors put of residually contaminated sandy soil from the U.S. Environmental Protection Agency (EPA) field research site at Traverse City, Michigan, was measured and modeled. The headspace of an intact core sleeve sample was swept with nitrogen gas to simulate the diffusive release of hydrocarbon vapors from residual aviation gasoline in and immediately above the capillary fringe to a soil-venting air flow in the unsaturated zone. The resulting steady-state profile was modeled using existing diffusivity and air porosity estimates in a balance of diffusive flux and a first order source term. The source strength, which was calibrated with the observed flux of 2,2,4-TMP leaving the sleeve, varied with the residual gasoline remaining in the core, but was independent of the headspace sweep flow rate. This finding suggested that lower soil-venting air flow rates were in principle as effective as higher air flow rates in venting LNAPL vapors from contaminated soils. The saturated vapor concentration ratio of 2,2,4-TMP to 2,2,5-TMH decreased from 6.6 to 3.5 over the duration of the experiments in an expression of distillation effects. The vertical profile model was tested against sample port data in four separate experiments for both species, yielding mean errors ranging from 0 to—24 percent in magnitude.     

Sensitivity of Mesoscale Surface Dynamics to Surface Soil and Vegetation Contrasts over the Carolina Sandhills

A region of contrasting soils exists over the Carolinas region of the southeastern United States. Previous research has shown an increase in mesoscale summertime precipitation over this region. Numerical simulations are analyzed to investigate the relationships between mesoscale surface dynamics and the transition from clay to sandy soils over this region. Numerical modeling experiments using four different soil and vegetation patterns suggest that the presence of the clay-to-sand transition zone produces a surface heat flux gradient and enhanced convergence. The soil contrasts appear to dominate over vegetation contrasts in affecting local surface heating and convergence in the model atmosphere.     

PREDICTION OF THE GRAIN SIZE OF SUSPENDED SEDIMENT： IMPLICATIONS FOR CALCULATING SUSPENDED SEDIMENT CONCENTRATIONS USING SINGLE FREQUENCY ACOUSTIC BACKSCATTER

Collection of samples of suspended sediment transported by streams and rivers is difficult and expensive. Emerging technologies, such as acoustic backscatter, have promise to decrease costs and allow more thorough sampling of transported sediment in streams and rivers. Acoustic backscatter information may be used to calculate the concentration of suspended sand-sized sediment given the vertical distribution of sediment size. Therefore, procedures to accurately compute suspended sediment size distributions from easily obtained river data are badly needed. In this study, techniques to predict the size of suspended sand are examined and their application to measuring concentrations using acoustic backscatter data are explored. Three methods to predict the size of sediment in suspension using bed sediment, flow criteria, and a modified form of the Rouse equation yielded mean suspended sediment sizes that differed from means of measured data by 7 to 50 percent. When one sample near the bed was used as a reference, mean error was reduced to about 5 percent. These errors in size determination translate into errors of 7 to 156 percent in the prediction of sediment concentration using backscatter data from 1 MHz single frequency acoustics.     

The Effects of Hydrophilic Polymer and Soil Salinity on Corn Growth in Sandy and Loamy Soils

The interaction effects of different applied ratios of a hydrophilic polymer (Superab A200) (0, 0.2, 0.6% w/w) under various soil salinity levels (initial salinity, 4 and 8 ms/cm) were evaluated on available water content (AWC), biomass, and water use efficiency for corn grown in loamy sand and sandy clay loam soils. The results showed that the highest AWC was measured at the lowest soil salinity. The application of 0.6% w/w of the polymer at the lowest salinity level increased the AWC by 2.2 and 1.2 times greater than those of control in the loamy sand and sandy clay loam soils, respectively. The analysis of variance of data showed that the effect of salinity was significant on biomass and water use efficiency of corn in the loamy sand and sandy clay loam soils. The highest amounts of these traits were measured in soils with the lowest salinity level. Application of polymer at the rate of 0.6% in the loamy sand soil and at the rate of 0.2% in the sandy clay loam soil resulted in the highest aerial and root biomass and water use efficiency for corn. At these polymer rates the amounts of water use efficiency for corn were 2.6 and 1.7 times greater than those of control in the loamy sand and sandy clay loam soils, respectively. Thus, the use of hydrophilic polymer in soils especially in the sandy soils increases soil water holding capacity, yield, and water use efficiency of plant. On the other hand, decreases the negative effect of soil salinity on plant and helps for irrigation projects to succeed in arid and semi‐arid areas.     

A fractal analysis of the water retention curve

The dependence of the soil water content ? upon the matric potential ψ is studied within a fractal approach that regards the water retention curve as a sequence of well defined fractal regimes. Each of such regimes accounts for a given functional dependence ?≡?(ψ), which in turn is characterized by a fractal dimension. The difference between the double fractal (observed into sandy soils) and multifractal (observed into clay soils) regime is explained by recalling that, for a sandy soil, the transition from saturated to dry conditions is driven by a steep reduction of ψ. To the contrary, for a clay (where the change from the highest water contents to the smallest ones is characterized by a large range of the matric potential), the multifractal behaviour is observed. These results are also confirmed by the analysis of experimental data. In particular, we show that the intermediate regime, generally accounting for the fractal multimodality, is due to the sandy nature of the soil at stake, practically immaterial. Finally, we demonstrate that our model can be also regarded as the straightforward generalization of that of Millán and González‐Posada ( 2005 ).     

Fracture control of ground water flow and water chemistry in a rock aquitard

There are few studies on the hydrogeology of sedimentary rock aquitards although they are important controls in regional ground water flow systems. We formulate and test a three-dimensional (3D) conceptual model of ground water flow and hydrochemistry in a fractured sedimentary rock aquitard to show that flow dynamics within the aquitard are more complex than previously believed. Similar conceptual models, based on regional observations and recently emerging principles of mechanical stratigraphy in heterogeneous sedimentary rocks, have previously been applied only to aquifers, but we show that they are potentially applicable to aquitards. The major elements of this conceptual model, which is based on detailed information from two sites in the Maquoketa Formation in southeastern Wisconsin, include orders of magnitude contrast between hydraulic diffusivity (K/S(s)) of fractured zones and relatively intact aquitard rock matrix, laterally extensive bedding-plane fracture zones extending over distances of over 10 km, very low vertical hydraulic conductivity of thick shale-rich intervals of the aquitard, and a vertical hydraulic head profile controlled by a lateral boundary at the aquitard subcrop, where numerous surface water bodies dominate the shallow aquifer system. Results from a 3D numerical flow model based on this conceptual model are consistent with field observations, which did not fit the typical conceptual model of strictly vertical flow through an aquitard. The 3D flow through an aquitard has implications for predicting ground water flow and for planning and protecting water supplies.     

Optical dating of young deltaic deposits on a decadal time scale

Modern Mississippi Delta sediments were analyzed to investigate quartz OSL signal resetting in large river deltas and test the accuracy of OSL dating on a decadal time scale with the early background subtraction and a recently proposed burial dose estimation procedure. Both fine silt-sized and sand-sized quartz were measured with a modified single-aliquot regenerative dose (SAR) protocol and equivalent dose (D_e) was calculated using different background subtraction methods. Evidence of insufficient bleaching was observed, but the residual signal is equivalent to ∼100 a on average for both sandy quartz and fine silt-sized quartz. It is shown that dose distributions of sandy quartz are affected by the background subtraction. The proportion of aliquots that have D_e in agreement with expectation is significantly larger when an early background is subtracted compared to the late background subtraction. This is, in contrast, not observed for fine silt-sized quartz. Accurate OSL ages were obtained by employing the unlogged minimum age model to D_es of sandy quartz obtained with the early background subtraction method.     

Pedotransfer functions estimating soil hydraulic properties using different soil parameters

Estimates of soil hydraulic properties using pedotransfer functions (PTF) are useful in many studies such as hydrochemical modelling and soil mapping. The objective of this study was to calibrate and test parametric PTFs that predict soil water retention and unsaturated hydraulic conductivity parameters. The PTFs are based on neural networks and the Bootstrap method using different sets of predictors and predict the van Genuchten/Mualem parameters. A Danish soil data set (152 horizons) dominated by sandy and sandy loamy soils was used in the development of PTFs to predict the Mualem hydraulic conductivity parameters. A larger data set (1618 horizons) with a broader textural range was used in the development of PTFs to predict the van Genuchten parameters. The PTFs using either three or seven textural classes combined with soil organic mater and bulk density gave the most reliable predictions of the hydraulic properties of the studied soils. We found that introducing measured water content as a predictor generally gave lower errors for water retention predictions and higher errors for conductivity predictions. The best of the developed PTFs for predicting hydraulic conductivity was tested against PTFs from the literature using a subdata set of the data used in the calibration. The test showed that the developed PTFs gave better predictions (lower errors) than the PTFs from the literature. This is not surprising since the developed PTFs are based mainly on hydraulic conductivity data near saturation and sandier soils than the PTFs from the literature. Copyright © 2007 John Wiley & Sons, Ltd.     

Soil redistribution and pedologic transformations in coastal plain croplands

In agricultural basins of the southeastern coastal plain there are typically large disparities between upland soil erosion and sediment delivered to streams. This suggests that colluvial storage and redistribution of eroded soil within croplands is occurring, and/or that processes other than fluvial erosion are at work. This study used soil morphology and stratigraphy as an indicator of erosion and deposition processes in a watershed at Littlefield, North Carolina. Soil stratigraphy and morphology reflect the ways in which mass fluxes associated with cultivation transform the local soils. Fluvial, aeolian and tillage processes were all found to be active in the redistribution of soil. The soil transformations are of five general types. First, erosion and compaction in the cultivated area as a whole result in the thinning of Arenic and Grossarenic Paleudults and Paleaquults to form Arenic, Typic and Aquic Paleudults and Paleaquults. Second, redistribution of surficial material within the fields results in transitions between Arenic and Typic or Aquic subgroups as loamy sand A and E horizons are truncated or accreted. Third, aeolian deposition at forested field boundaries leads to the formation of compound soils with podzolized features. Fourth, sandy rill fan deposits at slope bases create cumulic soils distinct from the loamy sands of the source area or the darker, finer terrace soils buried by the fan deposits. Finally, tillage and fluvial deposition in upland depressions results in the gradual burial of Rains (poorly drained Typic Paleaquults) soils. Results confirm the importance of upland sediment storage and redistribution, and the role of tillage and aeolian processes as well as fluvial processes in the region. Copyright © 1999 John Wiley & Sons, Ltd.     

Soil organic carbon enrichment of dust emissions: magnitude,mechanisms and its implications for the carbon cycle

Soil erosion is an important component of the global carbon cycle. However, little attention has been given to the role of aeolian processes in influencing soil organic carbon (SOC) flux and the release of greenhouse gasses, such as carbon dioxide (CO₂), to the atmosphere. Understanding the magnitude and mechanisms of SOC enrichment in dust emissions is necessary to evaluate the impact of wind erosion on the carbon cycle. This research examines the SOC content and enrichment of dust emissions measured using Big Spring Number Eight (BSNE) wind‐vane samplers across five land types in the rangelands of western Queensland, Australia. Our results show that sandy soils and finer particulate quartz‐rich soils are more efficient at SOC emission and have larger SOC dust enrichment than clay‐rich aggregated soils. The SOC enrichment ratios of dusts originating from sites with sand‐rich soil ranged from 2·1–41·9, while the mean enrichment ratio for dusts originating from the clay soil was 2·1. We hypothesize that stronger inter‐particle bonds and the low grain density of the aggregated clay soil explain its reduced capacity to release SOC during saltation, relative to the particulate sandy soils. We also show that size‐selective sorting of SOC during transport may lead to further enrichment of SOC dust emissions. Two dust samples from regional transport events were found to contain 15–20% SOC. These preliminary results provide impetus for additional research into dust SOC enrichment processes to elucidate the impact of wind erosion on SOC flux and reduce uncertainty about the role of soil erosion in the global carbon cycle. Copyright © 2013 John Wiley & Sons, Ltd.     

Rainfall,runoff and erosion on bare arable soils in east Shropshire,England

The magnitude, frequency, and duration of erosive rainfall on bare arable soils is investigated within an area of sandy soils in east Shropshire. Rainfall parameters are compared with runoff and erosion from ten 25 m² runoff plots, maintained in a bare condition on slopes of varying steepness. On rain-drop compacted (capped) soils measured erosion rates of ≦ 42.7t ha^?1 occur during individual storms. Erosion rates increase markedly with slope and on slopes > ? 13° are largely attributable to rill erosion. Prolonged duration, low intensity events cause relatively little erosion; most is accomplished by short duration, high intensity (> 10 mm h^?1) convective rainstorms. Comparison of measured erosion-producing events and long-term rainfall records indicate that potentially erosive storms are quite frequent, and are most likely to cause erosion in late spring/early summer.     

Comparison of infiltration models

Fourteen popular, representative infiltration models, some physically based, some semi‐empirical and some empirical, were selected for a comparative evaluation. Using the Nash and Sutcliffe efficiency criterion, the models were evaluated and compared for 243 sets of infiltration data collected from field and laboratory tests conducted in India and the USA on soils ranging from coarse sand to fine clay. Based on a relative grading scale, the semi‐empirical Singh–Yu general model, Holtan model and Horton model were graded respectively as 6·52, 5·57 and 5·48 out of 10. The empirical Huggins and Monke model, modified Kostiakov and Kostiakov model were graded as 5·57, 5·30 and 5·22, respectively. The physically based non‐linear and linear models of Smith–Parlange were graded as 5·48 and 5·22, respectively. Other models were ranked lower than these models. All the models generally performed poorly in field tests on Georgia's sandy soils, except the Robertsdale loamy sand. Copyright © 2003 John Wiley & Sons, Ltd.     

Establishment of Baseline Reference Geochemical Values in Tropical Soils of Western Ghats: Assessment of Periyar Basin with Special Reference to Contaminant Geochemistry

Based on the detailed geochemical studies of 184 soil samples from Periyar River Basin (PRB), a tropical monsoon dominated river basin (5398 km²) in the southern western Ghats (WGs) of India, a baseline reference data is established. The soils are mildly acidic with sandy loam and silt loam facies in non-monsoon to sandy loam and sandy clay loam in monsoon. The mean metal concentrations follow the upper continental crust and world shale values. The Geoaccumulation index (Igeo) shows unpolluted to moderately polluted category, except for Cu, Zn, and Ba, while Enrichment Factor (EF) indicates no to minor enrichment for all elements. Contamination factor (Cf) indicates low to considerable contamination for V, Rb, Sr, Ni, and low to very high contamination for Cu, Zn, and Ba. Three significant components are extracted by Principal Component Analysis (PCA), explaining 78.09% and 74.10% of the total variance for monsoon and non-monsoon seasons. Ti, Al, Fe, Ca, Na, K, V, Cr, Ni, Sr, and Ba exhibited common source of origin while anthropogenic origin is identified for Zn and Cu. The study will provide valuable information into the pedological characteristics of WGs river basins.     

Representation and Analysis of the Earthquake Size Distribution: A Historical Review and Some New Approaches

—The size distribution of earthquakes has been investigated since the early 20th century. In 1932 Wadati assumed a power-law distribution n(E) = kE ^?w for earthquake energy E and estimated the w value to be 1.7 ～ 2.1. Since the introduction of the magnitude-frequency relation by Gutenberg and Richter in 1944 in the form of log n(M) = a?bM, the spatial or temporal variation (or stability) of b value has been a frequently discussed subject in seismicity studies. The log n(M) versus M plots for some data sets exhibit considerable deviation from a straight line. Many modifications of the G-R relation have been proposed to represent such character. The modified equations include the truncated G-R equation, two-range G-R equation, equations with various additional terms to the original G-R equation. The gamma distribution of seismic moments is equivalent to one of these equations.¶In this paper we examine which equation is the most suitable to magnitude data from Japan and the world using AIC. In some cases, the original G-R equation is the most suitable, however in some cases other equations fit far better. The AIC is also a powerful tool to test the significance of the difference in parameter values between two sets of magnitude data under the assumption that the magnitudes are distributed according to a specified equation. Even if there is no significant difference in b value between two data sets (the G-R relation is assumed), we may find a significant difference between the same data sets under the assumption of another relation. To represent a character of the size distribution, there are indexes other than parameters in the magnitude-frequency distribution. The η value is one of such numbers. Although it is certain that these indexes vary among different data sets and are usable to represent a certain feature of seismicity, the usefulness of these indexes in some practical problems such as foreshock discrimination has not yet been established.     

关于砂土液化判别的若干意见

简要回顾了我国抗震规范中液化判别方法的发展历史,并对我国若干规范中的液化初步判别的条文进行了比较,提出了修改意见;对我国有代表性的几种液化判别方法及基于Seed简化方法修正的美国NCEER法进行了评述和综合对比,指出了我国现行若干规范中有关液化判别规定方面的错误;此外,还将GB50011－2001《建筑抗震设计规范》液化判别公式转变为类似于NCEER法的表达式,拓宽了该规范方法的应用范围。最后,结合某长江大桥工程的地基液化判别工作,探讨了深层土液化判别的可能性,结果表明,本文建议的方法是可行的。     

A Method for Predicting Chloride Concentrations in Leachate at Natural Attenuation Landfills in the Precambrian Shield Regions of Ontario, Canada

Natural attenuation landfill sites continue to be the preferred method of domestic waste disposal in the Precambrian Shield regions of Ontario due to economic factors. The main challenge in siting these landfills is ensuring that there will be no adverse impact on off-site water resources. Impact risk assessments are generally based on estimated volumes and strengths of chloride in the leachate. While volumes can be estimated using simple water balances, peak chloride concentration predictions are based on judgment and are quite variable. Since design chloride strengths dictate the size of the required attenuation zone, overestimating concentrations will typically make it impossible to find a suitable site, while underestimating concentrations increases the potential for adverse off-site impacts occurring.
Hydrogeological data from active and closed landfills in the Precambrian Shield region were collected to help develop a reliable method of predicting peak chloride concentrations in leachate. This study focused on 21 sites located on relatively permeable sandy soils since landfills underlain by low permeability clayey soils retain leachate similar to lined facilities.
Linear regression analyses were conducted to determine if source chloride concentrations at the "sand" sites are significantly influenced by waste thickness, fill area, waste volume, waste deposition rate, hydraulic conductivity, upgradient flow length, depth to the water table, and moisture surplus.
A strong relationship (R = 0.957) was found to exist between source chloride concentrations and waste volume. This empirical volume versus chloride regression equation can be used as the basis for establishing design chloride concentrations at new natural attenuation landfills developed over sandy soils in the Precambrian Shield regions of Ontario. An alternative risk assessment approach is required for sites developed over clay soils.     

C) W.M.O.—E.C.A.F.E.

Abstract

The authors give data of water infiltrations in horizontal and vertical columns, and in a two dimensional model. The soils are two mixtures of sand and loam, and a natural sandy loam. The characteristics of these soils are given in the article.

As a conclusion, the two dimensional problem can be approached by a linear combination of data in horizontal and vertical columns.     

Steady, annual, and monthly recharge implied by deep unconfined aquifer flow

We consider the response of a deep unconfined horizontal aquifer to steady, annual, and monthly recharge. A groundwater divide and a zero head reservoir constrain the aquifer, so that sinusoidal monthly and aperiodic annual recharge fluctuations create transient specific discharge near the reservoir and an unsteady water table elevation inland. One existing and two new long-term data sets from the Plymouth-Carver Aquifer in southeastern Massachusetts calibrate and confirm hydraulic properties in a set of analytical models. [Geohydrology and simulated groundwater flow, 1992] data and a new power law for tritiugenic helium to tritium ratios calibrate the steady recharge that drives the classical parabolic model of steady hydraulics [Applied Hydrogeology, 2001]. Observed water table and gradient fluctuations calibrate the transient recharge models. In the latter regard, monitoring wells within 1 km of Buttermilk Bay exhibit appreciable specific discharge and reduced water table fluctuations. We apply [Trans Am Geophys Union 32(1951)238] periodic model to the monthly hydraulics and a recharge convolution integral [J Hydrol 126(1991)315] to annual flow. An infiltration fraction of 0.79 and a consumptive use coefficient of 1.08×10⁻⁸ m/s °C relate recharge to precipitation and daylight weighted temperature across all three time scales. Errors associated with this recharge relation decrease with increasing time scale.     

Particle size characteristics of suspended sediment in hillslope runoff and stream flow

This study examines the particle size characteristics of hillslope soils and fluvial suspended sediments in an agricultural catchment. Samples of surface runoff and stream flow were collected periodically and analysed for the size distributions of the effective (undispersed) sediment. This sediment was subsequently dispersed and the ultimate size distributions determined. The median effective particle size of stream suspended sediment was considerably coarser than the median ultimate particle size, indicating that most of the load included a substantial proportion of aggregates. Moreover, the proportion of fine material (i.e. silt and clay) increased, and the proportion of sand-sized material decreased, with increasing discharge. This decrease in sediment size with increased flow, which is contrary to the traditional assumption of a positive discharge/particle size relationship, is thought to reflect: (i) the influx of silt and clay, predominantly the former, originating on the catchment slopes and brought to the stream by overland flow along vehicle wheelings, roads and tracks; and (ii) erosion of fine material from the channel bed and banks. During large storms, however, the proportion of sand-sized sediment increased during the rising limb of the hydrograph, as a result of the entrainment of coarser source material from the valley floor during overbank flooding. The stream suspended sediment was finer than the catchment soils and considerably finer than material eroding from the catchment slopes during storms. The degree of clay and silt enrichment in the suspended sediments was largely the result of preferential deposition of the coarser fraction during the transport and delivery of sediment from its source to basin outlet. The data from this study confirm that a significant mode of sediment transport in fluvial systems is in the form of aggregates, and that the dispersed sediment size distribution is inappropriate for determining the transportability of sediment by flow. © 1997 by John Wiley & Sons, Ltd.