The metamorphic paragenesis of cordierite in pelitic rocks

A petrogenetic grid is constructed for mineral assemblages occurring in metapelitic rocks, particularly those involved in the paragenesis of cordierite. The most useful assemblages for estimating pressures and temperatures are staurolite-cordierite, cordierite-biotite-Al₂SiO₅ and cordierite-hypersthene. Cordierite is stable with kyanite, sillimanite or andalusite. At high pressures cordierite is Mg-rich so that pelitic rocks typically do not contain the phase. Cordierite is stable at temperatures less than 500° C but does not commonly appear in metapelitic rocks until the garnet-chlorite, chlorite-staurolite or chlorite-Al₂SiO₅ tie-lines are broken. At high metamorphic grades, the assemblage garnet-hypersthene-cordierite indicates relatively low pressures, and the assemblage hypersthene-cordierite-sillimanite relatively high pressures. It is clear however, that the absence of cordierite is of little use in characterizing a metamorphic facies unless an alternate mineral assemblage can be shown to be more stable.     

Textural relations,P-T path,polymetamorphism and also geodynamic significance of metamorphic rocks of the Aligudarz-Khonsar region,Sanandaj-Sirjan zone,Iran

The metamorphic rocks of the Aligudarz-Khonsar region can be divided into nine groups: slate, phyllite, sericite schist, biotite-muscovite schist, garnet schist, garnet-staurolite schist, staurolite schist, mylonitic granite, and marble. In this metamorphic region, four phases of metamorphism can be identified (dynamothermal, thermal, dynamic and retrograde metamorphism) and there are three deformation phases (D1, D2 and D3). Paleozoic pelagic shales experienced prograde metamorphism and polymetamorphism from the greenschist to amphibolite facies along the kyanite geotherm. The metapelites show prograde dynamothermal metamorphism from the greenschist to amphibolite facies. Maximum degree of dynamothermal metamorphism is seen in the Nughan bridge area. Also development of the mylonitic granites in the Nughan bridge area shows that dynamic metamorphism in this area was more intense than in other parts of the AligudarzKhonsar metapelitic zone. The chemical zoning of garnets shows three stages of growth and syn-tectonic formation. With ongoing metamorphism, staurolite appeared, and the rocks reached amphibolite facies, but the degree of metamorphism did not increase past the kyanite zone. Thus, metamorphism of the pelitic sediments occurred at the greenschist to amphibolite facies (kyanite zone). Thermodynamic studies of these rocks indicate that the metapelites in the Aligudarz-Khonsar region formed at 490–550°C and 0.47–5.6 kbar.     

Bulk chemical control on metamorphic monazite growth in pelitic schists and implications for U–Pb age data

Several petrographic studies have linked accessory monazite growth in pelitic schist to metamorphic reactions involving major rock‐forming minerals, but little attention has been paid to the control that bulk composition might have on these reactions. In this study we use chemographic projections and pseudosections to argue that discrepant monazite ages from the Mount Barren Group of the Albany–Fraser Orogen, Western Australia, reflect differing bulk compositions. A new Sensitive High‐mass Resolution Ion Microprobe (SHRIMP) U–Pb monazite age of 1027 ± 8 Ma for pelitic schist from the Mount Barren Group contrasts markedly with previously published SHRIMP U–Pb monazite and xenotime ages of c. 1200 Ma for the same area. All dated samples experienced identical metamorphic conditions, but preserve different mineral assemblages due to variable bulk composition. Monazite grains dated at c. 1200 Ma are from relatively magnesian rocks dominated by biotite, kyanite and/or staurolite, whilst c. 1027 Ma grains are from a ferroan rock dominated by garnet and staurolite. The latter monazite population is likely to have grown when staurolite was produced at the expense of garnet and chlorite, but this reaction was not intersected by more magnesian compositions, which are instead dominated by monazite that grew during an earlier, greenschist facies metamorphic event. These results imply that monazite ages from pelitic schist can vary depending on the bulk composition of the host rock. Samples containing both garnet and staurolite are the most likely to yield monazite ages that approximate the timing of peak metamorphism in amphibolite facies terranes. Samples too magnesian to ever grow garnet, or too iron‐rich to undergo garnet breakdown, are likely to yield older monazite, and the age difference can be significant in terranes with a polymetamorphic history.     

Petrology of ultrahigh-pressure rocks from the southern Su-Lu region, eastern China

Abstract In the Su-Lu ultrahigh- P terrane, eastern China, many coesite-bearing eclogite pods and layers within biotite gneiss occur together with interlayered metasediments now represented by garnet-quartz-jadeite rock and kyanite quartzite. In addition to garnet + omphacite + rutile + coesite, other peak-stage minerals in some eclogites include kyanite, phengite, epidote, zoisite, talc, nyböite and high-Al titanite. The garnet-quartz-jadeite rock and kyanite quartzite contain jadeite + quartz + garnet + rutile ± zoisite ± apatite and quartz + kyanite + garnet + epidote + phengite + rutile ± omphacite assemblages, respectively. Coesite and quartz pseudomorphs after coesite occur as inclusions in garnet, omphacite, jadeite, kyanite and epidote from both eclogites and metasediments. Study of major elements indicates that the protolith of the garnet-quartz jadeite rock and the kyanite quartzite was supracrustal sediments. Most eclogites have basaltic composition; some have experienced variable 'crustal'contamination or metasomatism, and others may have had a basaltic tuff or pyroclastic rock protolith.
The Su-Lu ultrahigh- P rocks have been subjected to multi-stage recrystallization and exhibit a clockwise P-T path. Inclusion assemblages within garnet record a pre-eclogite epidote amphibolite facies metamorphic event. Ultrahigh- P peak metamorphism took place at 700–890° C and P >28 kbar at c . 210–230 Ma. The symplectitic assemblage plagioclase + hornblende ± epidote ± biotite + titanite implies amphibolite facies retrogressive metamorphism during exhumation at c . 180–200 Ma. Metasedimentary and metamafic lithologies have similar P-T paths. Several lines of evidence indicate that the supracrustal rocks were subducted to mantle depths and experienced in-situ ultrahigh- P metamorphism during the Triassic collision between the Sino-Korean and Yangtze cratons.     

Polymetamorphism, zircon growth and retention of early assemblages through the dynamic evolution of a continental arc in Fiordland, New Zealand

The Marguerite Amphibolite and associated rocks in northern Fiordland, New Zealand, contain evidence for retention of Carboniferous metamorphic assemblages through Cretaceous collision of an arc, emplacement of large volumes of mafic magma, high‐P metamorphism and then extensional exhumation. The amphibolite occurs as five dismembered aluminous meta‐gabbroic xenoliths up to 2 km wide that are enclosed within meta‐leucotonalite of the Lake Hankinson Complex. A first metamorphic event (M1) is manifest in the amphibolite as a pervasively lineated pargasite–anorthite–kyanite or corundum ± rutile assemblage, and as diffusion‐zoned garnet in pelitic schist xenoliths within the amphibolite. Thin zones of metasomatically Al‐enriched leucotonalite directly at the margins of each amphibolite xenolith indicate element redistribution during M1 and equilibration at 6.6 ± 0.8 kbar and 618 ± 25 °C. A second phase of recrystallization (M2) formed patchy and static margarite ± kyanite–staurolite–chlorite–plagioclase–epidote assemblages in the amphibolite, pseudomorphs of coronas in gabbronorite, and thin high‐grossular garnet rims in the pelitic schists. Conditions of M2, 8.8 ± 0.6 kbar and 643 ± 27 °C, are recorded from the rims of garnet in the pelitic schists. Cathodoluminescence imaging and simultaneous acquisition of U‐Th‐Pb isotopes and trace elements by depth‐profiling zircon grains from one pelitic schist reveals four stages of growth, two of which are metamorphic. The first metamorphic stage, dated as 340.2 ± 2.2 Ma, is correlated with M1 on the basis that the unusual zircon trace element compositions indicate growth from a metasomatic fluid derived from the surrounding amphibolite during penetrative deformation. A second phase of zircon overgrowth coupled with crosscutting relationships date M2 to between 119 and 117 Ma. The Early Carboniferous event has not previously been recognized in northern Fiordland, whereas the latter event, which has been identified in Early Cretaceous batholiths, their xenoliths, and rocks directly at batholith margins, is here shown to have also affected the country rock. However, the effects of M2 are fragmentary due to limited element mobility, lack of deformation, distance from a heat source and short residence time in the lower crust during peak P and T. It is possible that many parts of the Fiordland continental arc achieved high‐P conditions in the Early Cretaceous but retain earlier metamorphic or igneous assemblages.     

苏鲁地体超高压矿物的三维空间分布

采用激光拉曼技术,配备电子探针和阴极发光测试,确认苏鲁地体大多数花岗质片麻岩,所有类型片麻岩、斜长角闪岩、蓝晶石英岩和大理岩的锆石中均隐藏以柯石英为代表的超高压包体矿物组合。其中花岗质片麻岩典型超高压包体矿物为柯石英±多硅白云母;副片麻岩为柯石英+石榴子石+绿辉石、柯石英±石榴子石+硬玉+多硅白云母+磷灰石、柯石英+多硅白云母±磷灰石;斜长角闪岩为柯石英+石榴子石+绿辉石±金红石;蓝晶石英岩为柯石英+蓝晶石+金红石+磷灰石、柯石英+蓝晶石+多硅白云母+金红石;大理岩为柯石英+透辉石、柯石英+橄榄石。表明苏鲁地体由榴辉岩及其围岩所组成的巨量陆壳物质曾普遍发生深俯冲,并经历了超高压变质作用。锆石的矿物包体分布特征及相应的阴极发光图像研究表明,在同一样品中,锆石的成因特征存在明显差异。有的锆石显示继承性(碎屑)锆石的核(core)、超高压变质的幔(mantle)和退变质的边(rim);有的锆石则具有超高压的核、幔和退变质的边;而有的锆石却记录了深俯冲的核、超高压的幔和退变质的边。标志着苏鲁超高压变质带各类岩石副矿物锆石均具有十分复杂的结晶生长演化历史。因此,在充分研究锆石中矿物包体性质、分布特征以及相应阴极发光图像的基础上,采用SHRIMP离子探针技术,在锆石晶体的不同     

Cretaceous high-temperature rapid loading and unloading in the Abukuma metamorphic terrane, Japan

The Cretaceous Abukuma metamorphic terrane consists of the oceanic Gosaisyo Series overthrust onto the terrigenous Takanuki Series. Although the dominant mineralogy defines one of the classic areas of andalusite–sillimanite type progressive metamorphism, there are several lines of evidence suggesting an earlier higher-pressure (up to c . 12  kbar) history of the Takanuki Series and the nearby Gosaisyo Series. These are: (1) the occurrence of rare although widespread relic kyanite in sillimanite+K-feldspar zone-grade pelitic rocks; (2) the high grossular content of garnet interiors (up to c . 30  mol %) overgrown by Ca-poor rims ( c . 2  mol % grossular) in pelitic rocks containing Al₂SiO₅ minerals (sillimanite±relic kyanite±retrograde andalusite), plagioclase and quartz; (3) the occurrence of rutile as inclusions in garnet in pelitic rocks; and (4) the occurrence of relic corundum+almandine association in silica-poor and Al–Fe-rich rocks. Garnet in the Takanuki Series pelitic rocks commonly shows textural sector zoning and preserves growth zoning despite the high metamorphic grade, suggesting rapid changes in P–T  conditions and a relatively short duration of high-temperature conditions. Combined with radiometric dating, these observations suggest that the Abukuma sillimanite+K-feldspar zone-grade rocks underwent a clockwise P–T  path with very fast (>4  mm  y⁻¹) average burial and exhumation rates.     

Prograde destruction and formation of monazite and allanite during contact and regional metamorphism of pelites: petrology and geochronology

The conditions at which monazite and allanite were produced and destroyed during prograde metamorphism of pelitic rocks were determined in a Buchan and a Barrovian regional terrain and in a contact aureole, all from northern New England, USA. Pelites from the chlorite zone of each area contain monazite that has an inclusion-free core surrounded by a highly irregular, inclusion-rich rim. Textures and ²⁰⁸Pb/²³²Th dates of these monazites in the Buchan terrain, obtained by ion microprobe, suggest that they are composite grains with detrital cores and very low-grade metamorphic overgrowths. At exactly the biotite isograd in the regional terrains, composite monazite disappears from most rocks and is replaced by euhedral metamorphic allanite. At precisely the andalusite or kyanite isograd in all three areas, allanite, in turn, disappears from most rocks and is replaced by subhedral, chemically unzoned monazite neoblasts. Allanite failed to develop at the biotite isograd in pelites with lower than normal Ca and/or Al contents, and composite monazite survived at higher grades in these rocks with modified texture, chemical composition, and Th-Pb age. Pelites with elevated Ca and/or Al contents retained allanite in the andalusite or kyanite zone. The best estimate of the time of peak metamorphism at the andalusite or kyanite isograd is the mean Th-Pb age of metamorphic monazite neoblasts that have not been affected by retrograde metamorphism: 364.3Dž.5 Ma in the Buchan terrain, 352.9NJ.9 Ma in the Barrovian terrain, and 403.4LJ.9 Ma in the contact aureole. Some metamorphic monazites from the Buchan terrain have ages partially to completely reset during an episode of retrograde metamorphism at 343.1Nj.1 Ma. Interpretation of Th-Pb ages of individual composite monazite grains is complicated by the occurrence of subgrain domains of detrital material intergrown with domains of material formed or recrystallized during prograde and retrograde metamorphism.     

西昆仑布伦阔勒岩群中泥质高压麻粒岩的岩石学、年代学及其地质意义

西昆仑的深变质岩类主要发育于布伦阔勒岩群之中,其中的高压麻粒岩是西昆仑造山带中目前已知的变质程度最高的岩石.本文以其中的泥质高压麻粒岩为研究对象,结合岩相学、相平衡模拟以及锆石年代学分析等方法进行研究.结果 显示其峰期变质矿物组合蓝晶石+石榴石+钾长石,是典型的泥质高压麻粒岩岩石组合.根据相平衡模拟估算,高压麻粒岩相峰...     

Mode of occurrence and significance of jadeite in the Kamuikotan metamorphic rocks, Hokkaido, Japan

Abstract In the Kamuikotan zone, jadeite occurs in pelitic rocks, in metaplagiogranites, in veins in amphibolites and mafic sedimentary rocks, and in jadeite-albite rocks. In the first and second types, jadeite is associated with quartz, and is often in direct contact with it. However, such rock-types never occur as part of the coherent metamorphic sequence, but are found only as exotic blocks enclosed in serpentinite. Thus, jadeite + quartz-bearing assemblages are not regarded as representative of the Kamuikotan metamorphism. Lawsonite and aragonite, however, commonly do occur in the Kamuikotan metamorphic rocks, and this metamorphism belongs to a subfacies of the lawsonite-albite facies, in which aragonite is stable. The serpentinite matrix which carried jadeite + quartz-bearing pelites and metaplagiogranites into the metamorphic sequence is interpreted as a tectonic rather than a sedimentary melange.     

Eclogite facies relics and a multistage breakdown in metabasites of the KTB pilot hole,NE Bavaria: implications for the Variscan tectonometamorphic evolution of the NW Bohemian Massif

Complex reaction textures in coronitic metagabbros and retrograded eclogites of the KTB pilot and an adjacent drilling provide evidence for a multistage metamorphic history in the Variscan basement of the NW Bohemian Massif. The eclogites show complete metamorphic recrystallization leaving no textural or mineral relics of their igneous precursors. In contrast, textural relics of the igneous protolith are still preserved in the metagabbros where the metamorphic overprint under high pressure conditions achieved only partial replacement of the initial assemblage plagioclase + augite + amphibole (+olivine or orthopyroxene?) + ilmenite to form the eclogite facies assemblage garnet + omphacite + kyanite + zoisite + quartz+rutile. The garnets in the metagabbros occur in the typical ‘necklace’ fashion at the borders between the original plagioclase and mafic phase domains. In the same rocks, omphacite formed by a topotactic reaction mechanism replacing igneous augite as well as in smaller grains at the margins of the texturally igneous clinopyroxene where it occurs without fixed orientation with respect to the relict phase. Both eclogites and metagabbros show a partial breakdown under high pressure granulite (transitional to high pressure amphibolite) facies conditions during which omphacite broke down to vermicular symplectites of diopside + plagioclase. A later pervasive medium pressure metamorphism under amphibolite facies conditions led to the development of assemblages dominated by hornblende + plagioclase+titanite: phases prevailing in the overwhelming majority of the surrounding metabasites. Subsequent vein-associated retrogression produced minerals typical of the greenschist to zeolite facies. All metamorphic stages may be represented in a single thin section but although the overall reaction sequence is apparent, the obvious disequilibrium in the rocks makes the use of conventional geothermobarometry difficult. However, calculations made by assuming an approach to domainal equilibrium show that both the eclogite facies and early breakdown occurred above 10 kb. As the metamorphic unit hosting these particular metabasites is generally characterized by pressures below 10 kb these results have important implications for understanding the tectonometamorphic evolution of the region. The relationship between the studied rocks and other units in the NW Bohemian Massif exhibiting a multistage metamorphic evolution is discussed and possible tectonic models evaluated.     

胶北地体多期变质事件的P-T-t轨迹及其对胶-辽-吉带形成与演化的制约

胶北地体位于华北克拉通东部陆块胶-辽-吉带南端,主要由闪长质-TTG-花岗质片麻岩、变质表壳岩系和变质镁铁-超镁铁质岩所组成。本文通过对胶北早前寒武纪变质岩系的岩石学、矿物化学、变质反应结构和序列、变质温度和压力估算与同位素年代学资料的综合研究和总结,得出以下重要结论:(1)与华北克拉通东部陆块其它地区太古宙变质基底类似,本区也存在~2500Ma区域性新太古代变质事件,且与本区2550~2500Ma岩浆作用在时间上非常接近,其变质作用发生的时间比岩浆作用要晚10~50Myr,指示本区~2500Ma区域性变质事件可能与大规模的幔源岩浆底侵作用存在密切的成因关系。(2)胶北还存在1950~1850Ma区域性古元古代变质事件,并导致了大量高压基性和泥质麻粒岩的形成,高压基性麻粒岩主要以不规则透镜体、变形岩墙群或岩脉群的形式赋存于闪长质-TTG-花岗质片麻岩之中,并集中分布在安丘-平度-莱西-莱阳-栖霞一带,大致沿北东-南西向断续带状分布,构成了一条长约300km的古元古代高压麻粒岩相变质带。(3)本区古元古代高压麻粒岩以记录近等温减压(ITD)及随后近等压降温(IBC)的顺时针P-T-t轨迹为特征,指示本区变质杂岩在古元古代晚期曾强烈地卷入了与俯冲-拼贴-碰撞造山有关的构造过程,并可能经历了如下复杂的构造演化:(I)在古元古代晚期2000~1950Ma,随着有限大洋地壳的持续俯冲作用,本区各类变质岩的原岩开始经历一次构造增厚事件,并导致了它们的原岩经历了早期绿片岩相-角闪岩相进变质作用;(II)1950~1870Ma,大洋地壳俯冲作用结束,本区开始发生弧-陆拼贴和陆-陆碰撞作用,大陆地壳持续缩短和加厚,在加厚下地壳或岛弧根部带约50km的深度,发生了区域性高压麻粒岩相变质作用,并导致了本区变基性岩和变泥质岩分别形成了石榴石+单斜辉石+斜长石±角闪石±石英±铁-钛氧化物和石榴石+蓝晶石+钾长石+斜长石+黑云母+石英+铁-钛氧化物+熔体的高压麻粒岩相矿物组合。(III)1870~1800Ma,在同碰撞峰期变质结束之后,本区造山作用进入了后碰撞构造折返-伸展演化阶段,先后经历了早期快速构造折返和晚期缓慢冷却降温两个构造热演化阶段。其中,在早期快速构造折返阶段,高压麻粒岩经历了峰后近等温或略微增温减压退变质作用的叠加,高压基性麻粒岩表现为沿石榴石边部形成了含斜方辉石的后成合晶。与此同时,早期快速构造折返阶段还伴随着热松弛和伸展作用,出现一系列的幔源基性岩浆活动,不仅导致了本区大量未经历高压麻粒岩相变质的变基性岩群的形成,同时也诱发了区内大规模的地壳深熔作用的发生。自温度高峰期之后,本区地壳岩石还经历了一个近等压冷却降温过程,并发生了区域性角闪岩相退变质作用,高压基性麻粒岩表现为石榴石和斜方辉石边部常出现含角闪石的退变边或后成合晶。最终,在1800Ma左右,本区含电气石花岗伟晶质岩脉的大量出现,则标志着胶北地体古元古代晚期(2000~1800Ma)俯冲-拼贴-碰撞造山作用的最终结束。     

Decompressed eclogites in the Sveconorwegian (–Grenvillian) orogen of SW Sweden: petrology and tectonic implications

Relict eclogites and associated high-pressure rocks are present in the Eastern Segment of the SW Swedish gneiss region (the tectonic counterpart of the Parautochthonous Belt of the Canadian Grenville). These rocks give evidence of Sveconorwegian eclogite facies metamorphism and subsequent pervasive reworking and deformation at granulite and amphibolite facies conditions. The best-preserved eclogite relics suggest a clockwise P–T –t history, beginning in the amphibolite facies, progressing through the eclogite facies, decompressing and partially reequilibrating through the high- and medium-pressure granulite facies, before cooling through the amphibolite facies. Textures demonstrate the former coexistence of the plagioclase-free assemblages garnet+clinopyroxene+quartz+rutile+ilmenite, garnet+clinopyroxene+ kyanite+rutile, and garnet+kyanite+quartz+rutile. The former existence of omphacite is evidenced by up to 45 vol.% plagioclase expelled as small grains within large clinopyroxene. Matrix plagioclase is secondary and occurs expelled from clinopyroxene or in fine-grained, granulite facies reaction domains formed during resorption of garnet and kyanite. Garnet shows preserved prograde growth zoning with rimward increasing pyrope content, decreasing spessartine content and decreasing Fe/(Fe+Mg) ratio, but is partly resorbed and reequilibrated at the rims. P–T estimates from microdomains with clinopyroxene+plagioclase+quartz+garnet indicate pressures of 9.5–12 kbar and temperatures of 705–795 °C for a stage of the granulite facies decompression. The preservation of the prograde zoning suggests that the rocks did not reside at these high temperatures for more than a few million years, and chemical disequilibrium and ‘frozen’ reaction textures indicate heterogeneous reaction progress and overstepping of reactions during the decompression through the granulite facies. Together these features suggest a rapid tectonic exhumation. The eclogite relics occur within a high-grade deformation zone with WNW–ESE stretching and associated oblique normal-sense, top-to-the-east (sensu lato) displacement, suggesting that extension was a main cause for the decompression and exhumation. Probable tectonic scenarios for this deformation are Sveconorwegian late-orogenic gravitational collapse or overall WNW–ESE extension.     

Alpine metamorphism of pelitic schists in the Nufenen Pass area, Lepontine Alps

Abstract The effects of Tertiary Alpine metamorphism on pelitic Mesozoic cover rocks have been studied along a cross-section in the central Lepontine Alps in the Nufenen Pass area, Switzerland. Greenschist facies to amphibolite facies conditions are indicated by the formation of the index minerals chloritoid, garnet, staurolite and kyanite in pelitic rocks. Regional metamorphism reached maximum conditions during the interkinematic period between a main Alpine penetrative (D2) and a late Alpine (D3) crenulation type deformation phase or synchronous with the late Alpine deformation. Based on AFM phase relationships four different metamorphic zones can be distinguished: (1) chloritoid zone; (2) staurolite + chlorite zone; (3) staurolite + biotite zone; and, (4) kyanite zone. The isograds that separate these zones can be modelled by univariant reactions in the KFMASH system. The conditions of metamorphism calculated from geological ther-mobarometers for the maximum post-D2 por-phyroblast stage are from North to South: 500° C at 5-6 kbar and 600° C at 7-8 kbar. Detailed thermobarometry of garnet por-phyroblasts with complex textures suggests that maximum temperature was reached later than maximum pressure. Early garnet growth occurred along a prograde P-T-path, post-D2 rims grew with increasing temperature but decreasing pressure, and finally post-D3 garnet formed along a retrograde P-T-path. It may be concluded from the calculated pressure and temperature difference over a short distance (3 km) across the mapped area that the isogradic surfaces of the post-D2 metamorphism are steeply oriented. The data also suggest that isobaric and isothermal surfaces are parallel. Much of the observed metamorphic pattern can be explained as the result of a significant post-D2 differential uplift of the hot Pennine area relative to the Helvetic area along a tectonic contact zone. The closely spaced isograds (isotherms) in the North may then be interpreted as a thermal effect owing to the emplacement of the hot Pennine rocks against the Got-thard massif with its cover. Whereas, in the Pennine metasediments, post-D2 porphyroblast formation can be related to the decompression path which was steep enough for dehydration reactions to proceed. It is also remarkable that late kyanite porphyroblasts probably formed with decreasing pressure. The interpretation given here for the Nufenen Pass area may also apply to the Luk-manier Pass area where similar metamorphic patterns have been reported by Fox (1975). The formation of the ‘Northern Steep Belt’;, as denned by Milnes (1974b), and the associated late Alpine fold zones may, therefore, have significantly modified the metamorphic pattern of the Helvetic-Penninic contact zone.     

Chloritoid and barroisite-bearing pelitic schists from the eclogite unit in the Besshi district, Sanbagawa metamorphic belt

The Sanbagawa metamorphic rocks in the Besshi district, central Shikoku, are grouped into eclogite and noneclogite units. Chloritoid and barroisite-bearing pelitic schists occur as interlayers within basic schist in an eclogite unit of the Seba area in the Sanbagawa metamorphic belt, central Shikoku, Japan. Major matrix phases of the schists are garnet, chlorite, barroisite, paragonite, phengite, and quartz. Eclogite facies phases including chloritoid and talc are preserved only as inclusions in garnet. P–T conditions for the eclogite facies stage estimated using equilibria among chloritoid, barroisite, chlorite, interlayered chlorite–talc, paragonite, and garnet are 1.8 GPa/520–550 °C. Zonal structures of garnet and matrix amphibole show discontinuous growth of minerals between their core and mantle parts, implying the following metamorphic stages: prograde eclogite facies stage→hydration reaction stage→prograde epidote–amphibolite stage. This metamorphic history suggests that the Seba eclogite lithologies were (1) juxtaposed with subducting noneclogite lithologies during exhumation and then (2) progressively recrystallized under the epidote–amphibolite facies together with the surrounding noneclogite lithologies.

The pelitic schists in the Seba eclogite unit contain paragonite of two generations: prograde phase of the eclogite facies included in garnet and matrix phase produced by local reequilibration of sodic pyroxene-bearing eclogite facies assemblages during exhumation. Paragonite is absent in the common Sanbagawa basic and pelitic schists, and is, however, reported from restricted schists from several localities near the proposed eclogite unit in the Besshi district. These paragonite-bearing schists could be lower-pressure equivalents of the former eclogite facies rocks and are also members of the eclogite unit. This idea implies that the eclogite unit is more widely distributed in the Besshi district than previously thought.     

Trace element systematics in granulite facies rutile: implications for Zr geothermometry and provenance studies

Metamorphic rutile from granulite facies metapelitic rocks of the Archean Pikwitonei Granulite Domain (PGD; Manitoba, Canada) provides constraints on the systematics of trace elements in rutile during high‐temperature conditions and subsequent slow cooling. Compositional profiles and maps of the Zr concentrations in rutile grains (120–600 μm) from three metapelitic gneisses were acquired by electron probe micro‐analysis, using a spatial resolution of down to 2 μm. Simultaneously, profiles were analysed for Nb, Cr and V, which have significantly different diffusion characteristics in rutile. The profiles of all elements show relatively homogeneous concentrations within most grains, but significant inter‐grain differences even within a single thin section. Some rutile grains display a slight concentration decrease from a neighbouring garnet towards the matrix for all measured elements. The lack of diffusion profiles for all analysed elements shows that these are highly immobile in rutile and that distributions of these elements are primary and preserve prograde information. The Nb and Cr concentrations overlap with ranges that are ascribed to different provenances indicating that source discrimination based on these elements is not possible in all cases. High retentiveness for Zr implies that the Zr‐in‐rutile geothermometer is highly robust to diffusive re‐equilibration, even during very slow cooling (<2 °C Ma^?1) from granulite facies conditions. Most grains have high Zr contents (3000–4600 ppm). Differences between high Zr contents suggest that during growth under vapour‐absent conditions there may not be saturation of Zr in rutile, even if zircon is present. Therefore, several rutile grains need to be analysed in a sample to obtain a useful minimum peak temperature. The highest Zr concentrations correspond to ～900 °C. This is significantly higher than previous peak temperature estimates of 820 °C based on two‐feldspar thermometry. On a regional scale this implies that part of the PGD was affected by ultra‐high temperature (UHT) metamorphism. It also implies that rutile is able to preserve primary compositions even to UHT conditions. This study shows that, if combined with textural information, Zr‐in‐rutile has the potential to be a very useful tool for estimating rutile crystallization temperatures and peak metamorphic conditions. For granulite facies rocks, Zr‐in‐rutile yields more reliable peak metamorphic temperatures than most other exchange geothermometers, which tend to partially re‐equilibrate by diffusion during cooling.     

High‐pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu‐Hf and U‐Pb geochronology

As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.     

Formation of eclogite, and reaction during exhumation to mid-crustal levels, Snowbird tectonic zone, western Canadian Shield

A re‐evaluation of the P–T history of eclogite within the East Athabasca granulite terrane of the Snowbird tectonic zone, northern Saskatchewan, Canada was undertaken. Using calculated pseudosections in combination with new garnet–clinopyroxene and zircon and rutile trace element thermometry, peak metamorphic conditions are constrained to ～16 kbar and 750 °C, followed by near‐isothermal decompression to ～10 kbar. Associated with the eclogite are two types of occurrences of sapphirine‐bearing rocks preserving a rich variety of reaction textures that allow examination of the retrograde history below 10 kbar. The first occurs as a 1–2 m zone adjacent to the eclogite body with a peak assemblage of garnet–kyanite–quartz interpreted to have formed during the eclogite facies metamorphism. Rims of orthopyroxene and plagioclase developed around garnet, and sapphirine–plagioclase and spinel–plagioclase symplectites developed around kyanite. The second variety of sapphirine‐bearing rocks occurs in kyanite veins within the eclogite. The veins involve orthopyroxene, garnet and plagioclase layers spatially organized around a central kyanite layer that are interpreted to have formed following the eclogite facies metamorphism. The layering has itself been modified, with, in particular, kyanite being replaced by sapphirine–plagioclase, spinel–plagioclase and corundum–plagioclase symplectites, as well as the kyanite being replaced by sillimanite. Petrological modelling in the CFMAS system examining chemical potential gradients between kyanite and surrounding quartz indicates that these vein textures probably formed during further essentially isothermal decompression, ultimately reaching ～7 kbar and 750 °C. These results indicate that the final reaction in these rocks occurred at mid‐crustal levels at upper amphibolite facies conditions. Previous geochronological and thermochronological constraints bracket the time interval of decompression to <5–10 Myr, indicating that ～25 km of exhumation took place during this interval. This corresponds to minimum unroofing rates of ～2–5 mm year^?1 following eclogite facies metamorphism, after which the rocks resided at mid‐crustal levels for 80–100 Myr.     

中国大陆科学钻探主孔0～4500米变质岩石锆石中保存的超高压矿物包体

中国大陆科学钻探主孔0-4500米的岩心主要由榴辉岩、斜长角闪岩、副片麻岩、正片麻岩以及少量的超基性岩所组成。岩相学研究结果表明,榴辉岩的围岩普遍经历了强烈角闪岩相退变质作用的改造,峰期超高压变质的矿物组合已完全被后期退变质过程中角闪岩相矿物组合所替代。采用激光拉曼技术,配备电子探针和阴极发光测试,发现主孔224件岩心中有121件(包括榴辉岩、斜长角闪岩、副片麻岩和正片麻岩)样品的锆石中普遍隐藏以柯石英为代表的超高压矿物包体,且不同岩石类型锆石中所保存的超高压矿物包体组合存在明显差异。(含多硅白云母)金红石石英榴辉岩锆石中保存的典型超高压包体矿物组合为柯石英 石榴石、柯石英 石榴石 绿辉石 金红石和柯石英 多硅白云母 磷灰石。黑云绿帘斜长角闪岩锆石中保存的超高压矿物组合为柯石英 石榴石 绿辉石、柯石英 石榴石 多硅白云母和柯石英 绿辉石 金红石,与榴辉岩所保存的超高压矿物组合十分相似,表明该类斜长角闪岩是由超高压榴辉岩在构造折返过程中退变质而成。在副片麻岩类岩石,如石榴绿帘黑云二长片麻岩锆石中,代表性的超高压包体矿物组合为柯石英 多硅白云母和柯石英 石榴石等;而在石榴黑云角闪钠长片麻岩锆石中,则保存柯石英 硬玉 石榴石 磷灰石、柯石英 硬玉 多硅白云母 磷灰石和柯石英 石榴石 磷灰石等超高压矿物包体。在正片麻岩锆石中,标志性的超高压矿物包体为柯石英、柯石英 多硅白云母、柯石英 蓝晶石 磷灰石和柯石英 蓝晶石 榍石等。此外,在南苏鲁东海至临沭一带的地表露头以及一系列卫星孔岩心的锆石中,也普遍发现以柯石英为代表的标志性超高压矿物包体,表明在南苏鲁地区由榴辉岩及其围岩的原岩所组成的巨量陆壳物质(方圆>5000km2,厚度超过4.5km)曾整体发生深俯冲,并经历了超高压变质作用。该项研究对于重塑苏鲁-大别超高压变质带俯冲-折返的动力学模式有着重要的科学意义。     

Ultra-high temperature overprinting of high pressure pelitic granulites in the Huai'an complex,North China Craton: Evidence from thermodynamic modeling and isotope geochronology

Paleoproterozoic granulite facies rocks are widely distributed in the North China Craton (NCC). The Huai'an terrane, located within the northern segment of the Trans-North China Orogen (TNCO), a major Paleoproterozoic collisional belt in the central NCC expose mafic and pelitic granulites as well as TTG (tonalite-trondhjemite-granodiorite) gneisses. Here we investigate the pelitic granulites from this complex and identify four distinct mineral assemblages corresponding to different metamorphic stages. The prograde metamorphism (M1) is recorded by relict biotite and the compositional profile of X_ca (grt) isopleths. The P_max (M2) is distinguished by the X_ca (grt) isopleths, which corresponds to the kyanite stable area with an inclusion mineral assemblage of Grt-c–(Ky)-Qz-Rt-Kfs-liq suggesting that the pressures were higher than 12 kbar with a temperature below 900 °C. However, kyanite is absent in thin sections suggesting its consumption during later stages. The T_max metamorphism (M3) is characterized by the assemblage: Grt-m-Qz-Pl-Rt-Kfs-Sil-liq in the garnet mantle and also reflected in the compositional profile. Two-feldspar geothermometry yields a P-T range of 940 °C–950 °C and 9.5–10.5 kbar, indicating ultra-high temperature (UHT) metamorphic overprinting. The subsequent retrograde metamorphic stage (M4) is characterized by Grt-r-Bt-Sil-Kfs-Pl-Qz ± Rt ± Ilm with symplectites of Bt-Sil-Qz in the garnet rim suggesting garnet breakdown with P-T conditions estimated as 770 °C–840 °C and 6.5–8 kbar. The pelitic granulites show a clockwise path, with P-T estimates higher than those in estimated in previous studies using conventional techniques.LA-ICP-MS U–Pb analysis of metamorphic zircon grains yield two groups of ages at 1972.9 ± 8.1 Ma and 1873.3 ± 9.9 Ma. We suggest that the protoliths of the Manjinggou HP-UHT granulites were deep subducted where they experienced HP metamorphism associated with the collision of the Ordos and Yinshan blocks at ca. 1.97 Ga. Subsequently, the UHT metamorphic overprint occurred during the assembly of the unified Western and Eastern Blocks of the NCC along the TNCO at ca. 1.87 Ga.