陕西潼关金矿区农田土壤Hg污染的环境效应

以潼关金矿区农田土壤Hg污染区的小麦、蔬菜、水果中的Hg含量为重点研究对象,与尚未污染的农田土壤区进行对比,研究土壤Hg污染的农作物效应.评价区小麦样本Hg的超标率为78.57%,小麦Hg超标与土壤Hg污染的关系明显.评价区萝卜样本超标率为40%,叶菜、西红柿、苹果、红薯中样本超标率均为100%,对照区果蔬类也全部超标,但明显低于评价区.评价区农作物Hg超标倍数从大到小依次为:青菜＞油麦菜＞萝卜叶＞西红柿＞苹果＞红薯＞小麦＞萝卜.土壤Hg污染的环境效应极为严重,矿区环境污染防治刻不容缓.     

Concentration,distribution and bioaccumulation of mercury in the Xunyang mercury mining area,Shaanxi Province,China

Samples of surface water, soil, sediment and plants from the Xunyang Hg mining area in Shaanxi Province, China, were analyzed to assess the effects of the Hg mining activities on the environment. The results show that: (1) the mining activities are sources of Hg to the environment surrounding the mine; (2) the environment, especially riverbeds in the Xunyang area, is contaminated with Hg and (3) Hg accumulation in cabbage leaves, the main vegetable for the local residents, is high, reaching concentrations that are 6–540 times higher than the maximum Hg concentration recommended for edible plants in China. Action should be taken to remediate contaminated sites, manage waste discharges and reduce the exposure of Hg to local residents by issuing advisories against consuming agricultural products grown in the area, which are contaminated with Hg.     

3D Positional and Quantitative Prediction of the Xiaoqinling Gold Ore Belt in Tongguan,Shaanxi, China

Quantitative prediction of deep orebody based on 3D visualization technology is of great significance in mineral exploration. Based on the 2D traditional quantitative predicting method, the geoanomaly theory and the mineral exploration model idea, we constructed 3D models of the topography, strata, structure, magmatite and prospecting engineering of the study area using the commercial 3D modeling software Micromine, delineated eight prospective areas and estimated the gold resources amount with methods of Abundance Estimation and Volume Estimation. Then, we compared and counted the known ore blocks and the predicted blocks, which quantitatively explains this prediction’s validity. The results show that Xiaoqinling gold belt in Tongguan has convincing potential for gold development and utilization and the prediction method based on 3D visualization technology proves to be effective.     

陕西略阳铧厂沟金矿床金的赋存状态研究

陕西略阳县铧厂沟金矿床为一正在开采的小型金矿床。利用野外观察、显微镜观察、电子探针扫描等综合分析技术对金矿石中金的赋存状态进行了研究。结果表明,金主要以独立矿物相存在,金的载体矿物主要为黄铁矿,其次为石英、白云石、黄铜矿、砷黝铜矿。金矿物均为自然金(成色为945～982),未发现含银自然金及银金矿等矿物。金的嵌布类型有包裹金、裂隙金、粒间金和连生金4种。矿石中自然金的粒度主要以显微微粒金(0.010～0.005 mm)为主(约占44%),其次是显微细粒金(0.020～0.010 mm)(约占22%)和显微极微粒金(0.005～0.001 mm)(约占19%)。显微中粒金—巨粒金数量较少(约占14%),但其面积含量较高(约占57%),对于矿石品位和储量来说非常重要。还讨论了铧厂沟金矿床自然金嵌布特征的地质意义以及金成色较高的成因。     

Mercury emission from the indigenous mercury smelting in Wuchuan mercury mining areas, Guizhou Province, China

Mercury smelting is one of the important anthropogenic atmospheric mercury emission sources. Small-scale mercury smelting activities with indigenous method which is considered illegal and forbidden by local government always extensively existed in the Wuchuan area, northeastern Guizhou Province, China. Because of the simple processes without any environmental protection, a large amount of mercury vapor released to the ambient air during the processing of cinnabar roasting. By determining mercury concentrations in mercury ore and smelting slag samples, a mass balance method was used to calculate mercury emission factors and annual mercury emission from indigenous mercury smelting in Wuchuan mercury mining areas, Guizhou Province, China. The mercury emission factors ranged from 6.9% to 32.1% with the recovery from 78.4% to 93.6% and the annual mercury emission was up to 3.7-9.6 metric tons. The results highlighted that the indigenous mercury smelting was one of the most important anthropogenic atmospheric mercury emission sources in this region.     

Migration and speciation transformation mechanisms of mercury in undercurrent zones of the Tongguan gold mining area,Shaanxi Loess Plateau and impact on the environment

In order to study the migration and transformation mechanism of Hg content and occurrence form in subsurface flow zone of gold mining area in Loess Plateau and its influence on water environment, the field in-situ infiltration test and laboratory test were carried out in three typical sections of river-side loess, alluvial and proluvial strata in Tongguan gold mining area of Shaanxi Province, and the following results were obtained: (1) The source of Hg in subsurface flow zone is mainly caused by mineral processing activities; (2) the subsurface flow zone in the study area is in alkaline environment, and the residual state, iron and manganese oxidation state, strong organic state and humic acid state of mercury in loess are equally divided in dry and oxidizing environment; mercury in river alluvial or diluvial strata is mainly concentrated in silt, tailings and clayey silt soil layer, and mercury has certain stability, and the form of mercury in loess is easier to transform than the other two media; (3) under the flooding condition, most of mercury is trapped in the silt layer in the undercurrent zone where the sand and silt layers alternate with each other and the river water and groundwater are disjointed, and the migration capacity of mercury is far less than that of loess layer and alluvial layer with close hydraulic connection; (4) infiltration at the flood level accelerates the migration of pollutants to the ground; (5) the soil in the undercurrent zone is overloaded and has seriously exceeded the standard. Although the groundwater monitoring results are safe this time, relevant enterprises or departments should continue to pay attention to improving the gold extraction process, especially vigorously rectify the small workshops for illegal gold extraction and the substandard discharge of the three wastes, and intensify efforts to solve the geological environmental problems of mines left over from history. At present, the occurrence form of mercury in the undercurrent zone is relatively stable, but the water and soil layers have been polluted. The risk of disjointed groundwater pollution can not be ignored while giving priority to the treatment of loess and river alluvial landform areas with close hydraulic links. The research results will provide a scientific basis for water conservancy departments to groundwater prevention and control in water-deficient areas of the Loess Plateau.     

陕西镇安丘岭卡林型金矿金的赋存状态和富集机理

丘岭金矿床是西秦岭地区重要的卡林型金矿之一, 金矿化赋存于上泥盆统南阳山组和下石炭统袁家沟组地层中, 容矿岩石的岩性为钙质粉砂岩、粉砂质页岩和泥质灰岩.金矿石中主要金属矿物为黄铁矿和毒砂, 非金属矿物则以石英、方解石和绢云母为主.通过对矿石矿物黄铁矿和毒砂的扫描电镜-能谱分析、电子探针分析和激光剥蚀电感耦合等离子体质谱分析, 对丘岭金矿床金的赋存形式和富集机理进行了较为详细的研究.结果表明, 丘岭金矿床中金主要以次显微不可见金的形式存在, 其次为显微可见金.次显微金包括: (1)固溶体金(Au+), 主要存在于环带状细粒黄铁矿的含砷增生边区域和毒砂中, 少量存在于环带状黄铁矿的核部不含砷区域; (2)纳米级自然金颗粒(Au0), 存在于粗晶黄铁矿中.环带状细粒黄铁矿核部的次显微金可能主要以胶体吸附的形式存在, 暗示容矿岩石在沉积成岩过程中有金的初步富集, 而环带状黄铁矿幔部和毒砂中的Au则主要来源于成矿流体, 以S和As的络合物形式搬运.显微可见金主要分布在细粒黄铁矿的晶体边缘和热液蚀变绢云母、石英及方解石中, 粒径通常小于3~5 μm, 其形成可能与成矿流体中金的局部过饱和及成矿流体对细粒黄铁矿和毒砂中次显微金的活化和再次富集有关.      

陕西潼关县金矿矿区周边农田土壤重金属生态健康风险评价

为了解潼关金矿矿区早期粗放式的矿业活动对矿区周边农田土壤的重金属污染状况的影响以及对暴露人群的不良健康效应的评价,采用地质调查工程选取了矿区附近6块农田土壤为研究对象,通过X射线荧光光谱分析法测定了68个土壤样本中Cd、Hg、As、Pb、Cr、Cu、Ni、Zn等8种土壤重金属含量,采用地累积指数法、潜在生态危害指数法和...     

石泉县羊坪湾金矿床成矿模式及其找矿模型

对羊坪湾金矿床的地质地球化学特征研究表明,该金矿床为陕南黑色岩系中发现的沉积-改造型金矿床。它的成矿作用经历了沉积-成岩、构造-变质和改造-就位三个主要阶段;其找矿模型为在志留系梅子垭组含碳二云母石英片岩这一层位,韧性剪切带、紧闭褶皱等地质构造发育地段,出现黄铁矿化、硅化等热液蚀变和石英细脉、钠长岩脉等脉体,具有Au、As等元素化探异常与弱的激电异常,表现出断续的线性遥感影像。     

A Discussion on the Two-stage Mineralization of the Baguamiao-Shuangwang Gold Orefield, Shaanxi Province, China

The gold orefield studied is located on the south border of the underthrust-collision zone of the Qinling microplate and the North China microplate in the Indosinian epoch. The main ore deposits localized in the area where the WNW-trending compression-shear type fault of the Indosinian epoch intersected the NE-trending tenso-shear type fault of the Yanshanian epoch. The orebody appeared in a chambered or wedged form. The mineral composition is relatively complex. On the southeastern border of the orefield there have developed intermediate-acid anatectic magmatites of the Mesozoic Era. Three-phase inclusions (Lco2, Vco2 and LNaCl-H2O) comprise over 50%, associated with vapor phase consisting of H2O, CO2, CO, CH4, N2 and H2. The ore-forming fluids can be divided into 2 stages (the early and the late). The samples are projected in the area of mixture of initial magmatic and meteoric water on the δD-δ18O diagram, suggesting two types of mineralization, i.e. the re-equilibrated magmatic-hydrothermal type an     

陕西潼关金矿区泥石流潜势度评价

陕西潼关金矿区位于小秦岭北坡，区内发生的泥石流灾害，其物源90％是采矿弃渣。本文选择采矿弃渣量、纵坡降比、渣堆补给长度与沟长比、沟岸山坡坡度、河流弯曲程度、河流堵塞情况、渣堆稳定性、流域面积、历史上有无泥石流灾害发生等9个泥石流发生的因子，在给定因子权重排序的基础上，采用因子权值与因子赋值相乘后相加的方法，求得18条沟谷泥石流潜势度指数及其排序。在降雨量相同的条件下，潜势度指数可似比风险度指数。     

Mercury pollution from artisanal mercury mining in Tongren, Guizhou, China

Concentrations of total Hg (T-Hg) were measured in mine waste, stream water, soil and moss samples collected from the Tongren area, Guizhou, China to identify potential Hg contamination to local environments, which has resulted from artisanal Hg mining. Mine waste contained high T-Hg concentrations, ranging from 1.8 to 900 mg/kg. High concentrations of Hg were also found in the leachates of mine waste, confirming that mine waste contains significant water-soluble Hg compounds. Total Hg distribution patterns in soil profiles showed that top soil is contaminated with Hg, which has been derived from atmospheric deposition. Data suggest that organic matter plays an important role in the binding and transport of Hg in soil. Elevated T-Hg concentrations (5.9–44 mg/kg) in moss samples suggest that atmospheric deposition is the dominant source of Hg to local terrestrial ecosystems. Concentrations of T-Hg were highly elevated in stream water samples, varying from 92 to 2300 ng/L. Particulate Hg in water constituted a large proportion of the T-Hg and played a major role in Hg transport. Methyl–Hg (Me–Hg) concentrations in the water samples was as high as 7.9 ng/L. Data indicate that Hg contamination is dominantly from artisanal Hg mining in the study area, but the extent of Hg contamination is dependent on the mining history and the scale of artisanal Hg mining.     

陕西八卦庙金矿钠长石的成因

陕西八卦庙金矿产于凤太矿田北部，含矿地层为上泥盆统星红铺组下段中上部。赋矿围岩中含有较多的钠长石。钠长石呈层状顺层产出，镜下观察为砂屑状、次棱角状，与石英及铁白云石呈镶嵌粒状关系，而无交代结构；钠长石成分计算其形成温度超过800℃和400℃，表明其形成与喷流作用有关，并受到后期变质改造；锯钠长石X射线衍射分析，其有序度为0．38，形成温度为620－667℃，说明它不是一般意义上的热水沉积岩产物。上述研究表明：八卦庙金矿中的钠长石是火山喷发沉积－变质重结晶的产物，火山沉积作用参与该地区成矿是形成巨型金矿的最有利条件。含钠长石硅质岩、千枚岩、灰岩组合是找矿评价的重要标志。     

Tourism in the northwestern part of Sichuan Province,PR China

In the paper, unique karst lakes in high mountains, snow-covered mountains, glaciers, rare animals and plants are discussed. These landscape resources of nature and man in the NW part of Sichuan are superior for tourism. In addition, distribution of tourist regions and their characteristics are reviewed. The authors also evaluate landscape resources, and put forward some proposals about exploitation and conservation of scenic resources in the NW part of Sichuan province.     

Ore-forming and Exploration Models of the Baguamiao Gold Deposit, Shaanxi Province

The Baguamiao superlarge gold deposit in Shaanxi Province is one of the typical cases in China that are hosted by sedimentary rocks. Explorers and researchers have discussed the gold mineralization enrichment conditions by studying sulphur, oxygen, carbon, silicon stable isotopes and mineralizing fluid features of the Baguamiao gold deposit and proposed a hydrothermal sedimentation-magmatic reconstructing gold mineralization model featuring multi-sources of ore-forming materials and multistage mineralizations. In addition, prospecting for "Baguamiao-type" gold deposits was started in the Fengtai Basin and a great number of important prospecting targets such as Tonglinggou, Simaoling, Guoansi and Dachaigou were discovered.     

甘肃阳山金矿带构造岩浆演化与金矿成矿

甘肃阳山金矿带位于西秦岭南部,结合同位素测年资料发现阳山金矿区在侏罗纪早期、白垩纪早期及第三纪早期曾发生3期岩浆活动;稳定同位素分析结果显示,矿石中石英的流体包裹体δD值为-75‰～-56‰,δ¹⁸O_H2O为3.7‰～12.2‰,矿脉中黄铁矿及辉锑矿的δ³⁴S为-2.2‰～-0.7‰,表明阳山金矿成矿热液及成矿物质主要来自于岩浆作用;构造变形分析显示该区在三叠纪曾发生韧性变形,在侏罗纪早期产生韧-脆性变形;侏罗纪晚期以后区内构造转为脆性,早期以逆冲推覆构造为主,晚期主要为脆性伸展活动。结合该区地质构造演化史认为本区的3期岩浆活动与区域伸展作用有关,而与岩浆侵入有关的多期岩浆热液活动是促成阳山金矿床形成的主要因素。     

陕西省泾惠渠灌区地下水污染与人体健康风险评价

通常井内的地下水流速是由单井示踪试验或Aqua Vision流速流向仪测定得来,用以计算含水层中的地下水流速。由于表皮结构的影响,导致井筒附近的地下水流场发生变化,引起井筒内的流速与含水层中的流速存在偏差。为了探究表皮效应对井筒内地下水流速的影响,利用COMSOL Multiphysics软件,建立考虑表皮效应的地下水流数值模型,系统分析表皮厚度以及渗透系数对井筒中地下水流速的影响机制,根据模拟结果进一步评估利用井筒内地下水流速换算含水层地下水达西流速已有经验公式的可靠性。结果表明：(1)井筒附近表皮区域渗透系数越大,井筒内的地下水流速越大,且利用经验公式计算的地下水达西流速相对误差均小于0.23%,具有较高可靠性;(2)表皮区域渗透系数小于含水层渗透系数时,随着表皮厚度增大,井筒内地下水流速越小,经验公式计算结果的相对误差呈现增大趋势;(3)表皮区域渗透系数大于含水层渗透系数时,随着表皮厚度增大,井筒内地下水流速增大,计算结果相对误差总体上呈现减小的趋势,但其误差波动性较大,表明在该条件下经验公式计算的稳定性较差。结果显示表皮结构对井筒内地下水流速影响较大,在实际应用中要关注表皮结构的影响。

     

Baolun Gold Deposit, An Orogenic Gold Deposit in Hainan Province,South China

Please refer to the attachment(s) for more details.     

陕西双王金矿床矿化富集规律对成矿构造的指示意义

双王金矿床是秦岭地区大型的危机矿山之一,找矿工作是当务之急,但其成因类型特殊,人们对其成矿构造的演化过程和控矿机制尚存在争议.以该矿床KT5矿体为例,研究了角砾岩体、断裂裂隙和金品位的空间分布关系,并结合趋势面分析,探讨了金矿化富集规律及其对成矿构造的指示意义.矿床地质特征及对矿区内基性岩墙的测年结果表明其成矿时代为印支期.在印支期秦岭造山过程中的NS向主压应力背景下,成矿断裂早期右行斜向剪切作用奠定了角砾岩带的雏形;断裂中期活动引发的地震及伴生液压致裂作用,使矿区内形成了角砾岩主体和断裂裂隙系统,主成矿阶段角砾岩化作用减弱,断裂裂隙持续发育,并作为流体运移和成矿的主要通道和有利部位,使金的矿化富集呈面状展布,断裂裂隙带的产状变化是金沉淀的重要影响因素;晚期构造应力转换为近EW向拉伸,近NS向基性岩墙群侵位并受到成矿流体的改造.      

陕西山阳夏家店金矿床地质与流体地球化学

夏家店金矿是在东秦岭震旦系与寒武系界面新发现和勘查的金矿床,主要为含金角砾岩型。研究认为夏家店金矿的硅化与区内的断裂构造期次关系紧密。矿石矿物中石英流体包裹体的成分富含Cl-和SO24-;成矿流体体系属CO2-H2O-XCl-XSO4(X代表阳离子)型。成矿温度有两个峰值,其一为240～360oC,集中于240～280oC;其二为120～240oC,集中于180～220oC,两期蚀变特征相协调。氢氧同位素组成反映了成矿流体主体是来自于富δ18OHO的变质水。