Preferred orientation in experimentally deformed limestone

Over sixty syntectonic deformation experiments in uniaxial compression have been done on fine-grained limestones in the stability fields of calcite I, calcite II and aragonite. X-ray techniques and spherical harmonic analysis of the data were used to determine preferred orientation quantitatively, and inverse pole-figures were derived for these axially symmetric specimens. They display in most cases strong preferred orientation which varies as a function of the experimental conditions, mainly temperature and pressure. At temperatures below 350° C recrystallization is lacking and flattened grains indicate that translation, twin gliding and kinking have been the dominant deformation mechanisms. The inverse pole-figure shows a maximum at c with a shoulder towards or a second maximum at e. This is in agreement with preferred orientation observed in experimentally deformed Yule marble and can be explained as the product of dominant twin gliding on e and translation gliding on r (Turner et al., 1956). At high temperatures (900–1000° C) strong grain growth (from 4 to 50 microns) indicates that the fabric recrystallized. Grains are equidimensional and clear with a marble-like texture. The inverse pole-figure shows a single maximum at r, and c-axes are oriented in a small circle around the axis of compression, ₁. Such a pattern of preferred orientation would be expected on thermodynamic grounds assuming that recrystallized grains will be oriented in such a way that the strain energy is a maximum (e.g. MacDonald, 1960). Decrease in confining pressure caused a decrease of the maximum at c and the formation of a secondary maximum at highangle positive rhombs in the inverse pole-figure. This can be interpreted as r translation dominating over e twinning. In all deformation experiments an equilibrium in preferred orientation was reached after 20 percent shortening. The strength of preferred orientation decreased with increasing temperature. Aragonite was produced within its hydrostatic stability field at temperatures above 500° C. Close to the phase boundary, coarse-grained textures showed preferred orientation with poles to (010) parallel to ₁. At higher pressures the fabric is fine-grained and [001] is aligned parallel to ₁. Evidence is given that the phase change from calcite to aragonite in these deformation experiments is a diffusive and not a martensitic transformation.Publication No. 1043, Institute of Geophysics and Planetary Physics, University of California, Los Angeles, California.     

Dynamic recrystallization near the brittle-plastic transition in naturally and experimentally deformed quartz aggregates

The electron backscattering diffraction technique (EBSD) was used to analyze bulging recrystallization microstructures from naturally and experimentally deformed quartz aggregates, both of which are characterized by porphyroclasts with finely serrated grain boundaries and grain boundary bulges set in a matrix of very fine recrystallized grains. For the Tonale mylonites we investigated, a temperature range of 300–380 °C, 0.25 GPa confining pressure, a flow stress range of ~ 0.1–0.2 GPa, and a strain rate of ~ 10^− 13 s^− 1 were estimated. Experimental samples of Black Hills quartzite were analyzed, which had been deformed in axial compression at 700 °C, 1.2–1.5 GPa confining pressure, a flow stress of ~ 0.3–0.4 GPa, a strain rate of ~ 10^− 6 s^− 1, and to 44% to 73% axial shortening. Using orientation imaging we investigated the dynamic recrystallization microstructures and discuss which processes may contribute to their development. Our results suggest that several deformation processes are important for the dismantling of the porphyroclasts and the formation of recrystallized grains. Grain boundary bulges are not only formed by local grain boundary migration, but they also display a lattice misorientation indicative of subgrain rotation. Dynamic recrystallization affects especially the rims of host porphyroclasts with a hard orientation, i.e. with an orientation unsuitable for easy basal slip. In addition, Dauphiné twins within porphyroclasts are preferred sites for recrystallization. We interpret large misorientation angles in the experimental samples, which increase with increasing strain, as formed by the activity of fluid-assisted grain boundary sliding.     

Microstructural development of fine-grained quartz aggregates by syntectonic recrystallization

Experimental study of syntectonic recrystallization of fine-grained quartz aggregates was carried out in order to simulate the development of some natural microstructures of quartz tectonites and to understand their formation condition. Agate was axially compressed with a constant-strain-rate apparatus. Experiments were conducted at 4 kbar solid confining pressure, 700–1000°C and 10⁻⁴-10⁻⁶ sec⁻¹ to 10%–45% strain. In all runs, deformation has proceeded under wet condition caused by dehydration of pyrophyllite used as pressure medium.Two different types of microstructure were distinguished in the deformed specimens. One is P-type which is characterized by equant, equidimensional, and polygonal grains. The other is S-type which is characterized by the highly oblate grains with the largest dimension perpendicular to the compression axis. The P-type microstructure is developed at higher temperatures and slower strain rates, while the S-type developed at lower temperatures and faster strain rates. The transition between the S- and P-types is found to be very sharp.     

Dynamic recrystallization and fabric development during the simple shear deformation of ice

In situ observations of polycrystalline ice deformed in simple shear between −10 and −1°C are presented. This study illustrates the processes responsible for the deformation, the development of a preferred crystallographic orientation and the formation of a preferred dimensional orientation. Intracrystalline glide on the basal plane, accompanying grain rotations and dynamic recrystallization, helps to accommodate the large intragranular strains. These are the most important mechanisms for crystallographic reorientation and produce a stable fabric that favours glide on the basal plane. Localized kinks, developed in grains unfavourably oriented for easy glide, are unstable and are overprinted by dynamic recrystallization. Dynamic recrystallization is a strain softening process with nucleation occurring in the form of equiaxed grains that grow subparallel to pre-existing grain anisotropies and become elongate during deformation. Plots of grain axial ratio against orientation ( ) indicate a weak shape fabric which does not correspond to the theoretical foliation and elongation for the appropriate increment of shear strain. We argue that estimates of the strain magnitude made from orientation of elongate grains are unreliable in high temperature shear zones. These results are applicable to both geological and glacial shear environments.     

Development of crystallographic preferred orientations by nucleation and growth of new grains in experimentally deformed quartz single crystals

Deformation experiments have been carried out to investigate the effect of dynamic recrystallisation on crystallographic preferred orientation (CPO) development. Cylindrical samples of natural single crystals of quartz were axially deformed together with 1 vol.% of added water and 20 mg of Mn₂O₃ powder in a Griggs solid medium deformation apparatus in different crystallographic orientations with compression direction: (i) parallel to <c>, (ii) at 45° to <c> and 45° to <a> and (iii) parallel to <a>. The experiments were performed at a temperature of 800 °C, a confining pressure of 1.2 GPa, a strain rate of  10^− 6 s^− 1, to bulk finite strains of  14–36%. The deformed samples were analysed in detail using optical microscopy, electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). Two different microstructural domains were distinguished in the deformed samples: (i) domains with undulatory extinction and deformation lamellae, and (ii) domains with new recrystallised grains. Within the domains of undulatory extinction, crystal-plastic deformation caused gradual rotations of the crystal lattice up to  30° away from the host orientation. New recrystallised grains show a strong CPO with c-axis maxima at  45° to the compression direction. This is the case in all experiments, irrespective of the initial crystallographic orientation. The results show that c-axes are not continuously rotated towards the new maxima. The new grains thus developed through a mechanism different from subgrain rotation recrystallisation. New grains have a subeuhedral shape and numerous microcavities, voids, fluid channels and fluid inclusions at their grain boundaries. No host control is recorded in misorientation axes across their large angle grain boundaries. New grains might have been created by nucleation from solution in the μm-scale voids and microfractures. The CPO most likely developed due to preferred growth of the freshly precipitated grains with orientations suitable for intracrystalline deformation at the imposed experimental conditions.     

Fabrication of synthetic calcite–muscovite rocks with variable texture — An analogue to cataclasite fabrics?

A series of large diameter calcite–muscovite aggregates has been prepared from calcite and muscovite powders, in order to gain a better understanding of how texture develops in impure carbonate rocks. The development of the microstructure and the crystallographic preferred orientation (CPO, texture) during the preparation process is described. The synthetic rocks have been fabricated from powders of calcite and muscovite by uniaxial cold-pressing at loads up to 400 MPa and subsequent hot isostatic pressing (HIPping) at pressures of 150 to 170 MPa and a temperature of 670 °C. The resulting textures and microstructures are homogeneous throughout the samples. The calcite CPO is generated by rigid body rotation and twinning during cold-pressing and is not significantly altered by recrystallization during HIPping. Grain growth during HIPping is observed in pure calcite samples, but is inhibited through high porosity and the presence of muscovite in the mixed aggregates. The preferred orientation of the calcite c-axes is found to increase with increasing uniaxial cold pressure, and to be independent of the muscovite content. The magnetic bulk susceptibility of the starting material has been changed by the formation of ferromagnetic impurities during fabrication. Comparison of the samples to natural calcite fabrics from fault zones show the potential of the experiments and fabric analyses presented to analyze and to better understand the deformation mechanisms of fault zones.     

Schlieren formation in diatexite migmatite: examples from the St Malo migmatite terrane, France

Schlieren are trains of platy or blocky minerals, typically the ferromagnesian minerals and accessory phases, that occur in granites and melt‐rich migmatites, such as diatexites. They have been considered as: (1) unmelted residue from xenoliths or the source region; (2) mineral accumulations formed during magma flow; (3) compositional layering; and (4) sites of melt loss. In order to help identify schlieren‐forming processes in the diatexites at St Malo, differences in the size, shape, orientation, distribution and composition of the biotite from schlieren and from their hosts have been investigated. Small biotite grains are much less abundant in the schlieren than in their hosts. Schlieren biotite grains are generally larger, have greater aspect ratios and have, except in hosts with low (< 10%) biotite contents, a much stronger shape preferred orientation than host biotite. The compositional ranges of host and schlieren biotite are similar, but schlieren biotite defines tighter, sharper peaks on composition‐frequency plots. Hosts show magmatic textures such as imbricated (tiled), unstrained plagioclase. Some schlieren show only magmatic textures (tiled biotite, no crystal‐plastic strain features), but many have textures indicating submagmatic and subsolidus deformation (e.g. kinked grains) and these schlieren show the most extensive evidence for recrystallization. Magmas at St Malo initially contained a significant fraction of residual biotite and plagioclase crystals; smaller biotite grains were separated from the larger plagioclase crystals during magma flow. Since plagioclase was also the major, early crystallizing phase, the plagioclase‐rich domains developed rapidly and reached the rigid percolation threshold first, forcing further magma flow to be concentrated into narrowing melt‐rich zones where the biotite had accumulated, hence increasing shear strain and the degree of shape preferred orientation in these domains. Schlieren formed in these domains as a result of grain contacts and tiling in the grain inertia‐regime. Final amalgamation of the biotite aggregates into schlieren involved volume loss as melt trapped between grains was expelled after the rigid percolation threshold was reached in the biotite‐rich layers.     

Static recrystallization and preferred orientation of phyllosilicates: Michigamme Formation,northern Michigan,USA

The Michigamme Formation of the Marquette District in Michigan's Upper Peninsula comprises a sequence of cleaved rocks of increasing metamorphic grade. Because metamorphism in the area occurred after cleavage formation, the rocks provide an opportunity to study preferred orientation development of phyllosilicates under conditions of static recrystallization.X-ray texture goniometry on samples from the greenschist-facies zone that were collected at varying distances from the bounding biotite-in and garnet-in isograds, shows that: (1) the preferred orientation of phyllosilicates is always parallel to the mesoscopic cleavage, and (2) the degree of preferred orientation of phyllosilicates improves as a function of increasing metamorphic grade (from <4 to >9 m.r.d.). Scanning electron microscopy on these samples shows that: (1) the length/width ratio increases with increasing grade, and (2) grain shapes are better defined with increasing grade.Previous work on slates showed mechanical processes dominate at very low-grade metamorphism, whereas chemical processes are favored at higher grades. The Michigamme samples show that improvement of preferred orientation occurrred by grain dissolution and crystallization. Noncleavage-parallel phyllosilicate grains were preferentially dissolved, probably facilitated by internal strain energy from mineral defects, aided by chemical energy, whereas cleavage-parallel phyllosilicates were hosts for new growth along their basal planes. These results show that significant fabric strengthening can be achieved by grain dissolution and crystallization in the absence of tectonic stress.     

Development of texture and microstructure in extruded ionic polycrystalline aggregates

The crystallographic preferred orientation (here referred to as texture) developed in extruded ionic polycrystalline aggregates with the NaCl-structure is studied as a function of extrusion temperature and ionicity of the material. In pure alkali halides and silver chloride a 100111 double fibre texture is found for all extrusion temperatures investigated. In extruded natural rock salt the 100 fibre is replaced by 115 at or below room temperature. The temperature dependence of the intensity of preferred orientation together with microstructural investigations suggest the 100 and 115 components to be primarily due to dynamic recrystallization. The 111 deformation texture agrees with model calculations based on simultaneous slip on both the {110}110 and {100}110 slip systems, generally observed as primary and secondary slip systems in NaCl-type ionic crystals, respectively. Possible applications to the study of the diapirism of salt domes are discussed.     

Oxygen isotope exchange and disequilibrium between calcite and tremolite in the absence and presence of an experimental C–O–H fluid

Oxygen isotope exchange between minerals during metamorphism can occur in either the presence or the absence of aqueous fluids. Oxygen isotope partitioning among minerals and fluid is governed by both chemical and isotopic equilibria during these processes, which progress by intragranular and intergranular diffusion as well as by surface reactions. We have carried out isotope exchange experiments in two- and three-phase systems, respectively, between calcite and tremolite at high temperatures and pressures. The two-phase system experiments were conducted without fluid either at 1 GPa and 680 °C for 7 days or at 500 MPa and 560 °C for 20 days. Extrapolated equilibrium fractionations between calcite and tremolite are significantly lower than existing empirical estimates and experimental determinations in the presence of small amounts of fluid, but closely match calculated fractionations by means of the increment method for framework oxygen in tremolite. The small fractionations measured in the direct calcite–tremolite exchange experiments are interpreted by different rates of oxygen isotope exchange between hydroxyl oxygen, framework oxygen and calcite during the solid–solid reactions where significant recrystallization occurs. The three-phase system experiments were accomplished in the presence of a large amount of fluid (CO₂+H₂O) at 500 MPa and 560 °C under conditions of phase equilibrium for 5, 10, 20, 40, 80, 120, 160, and 200 days. The results show that oxygen isotope exchange between minerals and fluid proceeds in two stages: first, through a mechanism of dissolution-recrystallization and very rapidly; second, through a mechanism of diffusion and very slowly. Synthetic calcite shows a greater rate of isotopic exchange with fluid than natural calcite in the first stage. The rate of oxygen diffusion in calcite is approximately equal to or slightly greater than that in tremolite in the second stage. A calculation using available diffusion coefficients for calcite suggests that grain boundary diffusion, rather than volume diffusion, has been the dominant mechanism of oxygen transport between the fluid and the mineral grains in the later stage.Editorial responsibility: T.L. Grove     

The effect of high temperature and high confining pressure on compressional wave velocities in quartz-bearing and quartz-free igneous and metamorphic rocks

Compressional wave velocities have been measured in granite, granulite, amphibolite and peridotite specimens under conditions of high temperature up to 700°C and confining pressures up to 6 kbar. In general, velocity increases with pressure and decreases with temperature.Quartz-bearing rocks show an anomalous behavior of their compressional wave velocities. The velocity—temperature relations exhibit a velocity-“deep” due to the high—low inversion of the constituent quartz crystals. The intrinsic effect of temperature on velocities is hard to determine due to thermal expansion and consequent loosening of the structure. The opening of new cracks and the widening of old cracks causes a large decrease in compressional wave velocities. The minimum pressure to prevent damage at a given temperature should, therefore, be about 1 kbar/100°C.The values obtained at these conditions are considered to be most nearly correct as intrinsic properties of the compact aggregates. Velocity anisotropies at high confining pressures and high temperatures correlate with preferred lattice orientation of the constituent minerals. The effect of dimensional orientation and microcracks on seismic anisotropy seems to be of minor importance in dry rocks. It is the more eliminated the higher the confining pressure. The data do not support the concept of a velocity maximum in depth of 10–20 km.     

Albite crystallographic preferred orientation and grain misorientation distribution in a low-grade mylonite: implications for granular flow

Crystallographic orientation data from pure albite domains in a low-grade sheared metagabbro from the Combin Zone of the western Italian Alps were measured by electron backscatter diffraction. Crystallographic preferred orientations (CPOs) in four high-strain domains are non-random and have a triclinic symmetry. The clusters of [100], [010] and [001] show an angular relationship that corresponds to that of the albite crystal lattice. However, the orientations of axis clusters to the kinematic axes vary from domain to domain. CPOs from a low-strain domain also show clustered axes with triclinic symmetry, but with more intense clustering than those in the high-strain domains. Grain misorientation distributions are presented both for the low-strain domain and one of the high-strain domains. In the high-strain domain, the distribution of misorientation angles between neighbouring grains displays a peak at about 70°. The equivalent distribution in the low-strain domain has a peak at 30°. For both domains, the misorientation axis distributions, between neighbouring and non-neighbouring grains, are random, except for some of axes with 160–180° misorientation that exhibit a slight concentration around [010]. The diversity of CPOs among the domains suggests that these CPOs could not be produced by dislocation creep. They are likely to have been inherited from plagioclase parents, as a result of host control on the nucleation of the new albite grains. These CPOs do not contain any direct information about the deformation kinematics. We interpret that deformation of these domains occurred by granular flow. Crystallographic axis dispersion due to grain boundary sliding (GBS) caused weakening of CPOs, modification of misorientation angle distributions and randomisation of misorientation axis distributions. The fact that a CPO can survive GBS even after a high strain indicates that CPO is not always a sensitive indicator of deformation mechanisms. Misorientation distribution may provide a complementary, and possibly a more sensitive indicator of deformation mechanisms.     

Dynamic recrystallization of wet synthetic polycrystalline halite: dependence of grain size distribution on flow stress, temperature and strain

It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10⁻⁷ s⁻¹ and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10⁻⁷–1×10⁻⁴ s⁻¹ and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.     

Marble mylonites in the Bancroft shear zone, Ontario, Canada: microstructures and deformation mechanisms

Mylonitization of medium-grade marbles in the Bancroft shear zone, Ontario, Canada, is characterized by decreasing grain-size of both calcite and graphite, and a variety of textures. Calcite grain-sizes vary from several millimeters in the protolith, to 50–200 μm in mylonite, to <30 μm in ultramylonite. Corresponding calcite grain shapes are equant in the protolith, elongate in protomylonite (first-developed dimensional preferred orientation), equant in coarse mylonite, elongate in fine mylonite (second-developed dimensional preferred orientation) and generally equant in ultramylonite, which suggests that external energy (applied stress) that tends to elongate grains competed with internal energy sources (e.g. distortional strain) that favor equant shapes. Graphite grain-size changes from several millimeters to centimeters in the protolith to submicroscopic in ultramylonite. In the mylonitic stages, graphite is present as dark bands, while in the ultramylonitic stage it is preserved as a fine coating on calcite grains.Based on textural evidence, twinning (exponential creep; regime I), dynamic recrystallization (power law creep; regime II) and possibly grain boundary sliding superplasticity (regime III) are considered the dominant deformation mechanisms with increasing intensity of mylonitization; their activity is largely controlled by calcite grain-size. Calcite grain-size reduction occurred predominantly by the process of rotation recrystallization during the early stages of mylonitization, as indicated by the occurrence of core and mantle or mortar structures, and by the grain-size of subgrains and recrystallized grains. Grain elongation in S-C structures indicates the activity of migration recrystallization; these structures are not the result of flattening of originally equant grains. Differential stress estimates in coarse mylonites and ultramylonites, based on recrystallized grain-size, are 2–5 and 14–38 MPa, respectively. Initial grain-size reduction of graphite occurred by progressive separation along basal planes, analogous to mica fish formation in quartzo-feldspathic mylonites.Calcite-graphite thermometry on mylonitic and ultramylonitic samples shows that the metamorphic conditions during mylonitization were 475 ± 50°C, which, combined with a differential stress value of 26 MPa, gives a strain rate of 1.2 x 10⁻¹⁰s⁻¹ based on constitutive equations; corresponding displacement rates are <38 mmyr⁻¹.     

Compositional changes of minerals associated with dynamic recrystallizatin

The rate of compositional and isotopic exchange between minerals may be enhanced significantly if the rock is deformed simultaneously. The enhanced exchange rate may result from a reduction in grain size (shorter distance for volume diffusion), dissolution and growth of grains by diffusion creep (pressure solution), or the movement of high-angle grain boundaries through strained grains during recrystallization in the dislocation creep regime. The migration of high-angle grain boundaries provides high diffusivity paths for the rapid exchange of components during recrystallization. The operation of the latter process has been demonstrated by deforming aggregates consisting of two plagioclases (An₁ and An₇₉) at 900°C, 1 GPa confining pressure, and a strain rate of ∼2x10^-6s^-1. The polygonal, recrystallized grains were analyzed using an analytical transmission electron microscope and have a variable but often intermediate composition. At the conditions of these experiments, the volume interdiffusion rate of NaSi/CaAl is too slow to produce any observable chemical change, and microstructural-chemical relations indicate that the contribution from diffusion creep was insignificant except for initially fine-grained (2–10 μm) aggregates. These results indicate that strain-induced recrystallization can be an effective mechanism for enhancing the kinetics of metamorphic reactions and for resetting the isotope systematics of minerals such as feldspars, pyroxenes, and amphiboles.     

The eastern Tonale fault zone: a ‘natural laboratory’ for crystal plastic deformation of quartz over a temperature range from 250 to 700 °C

Near the eastern end of the Tonale fault zone, a segment of the Periadriatic fault system in the Italian Alps, the Adamello intrusion produced a syn-kinematic contact aureole. A temperature gradient from 250 to 700 °C was determined across the Tonale fault zone using critical syn-kinematic mineral assemblages from the metasedimentary host rocks surrounding deformed quartz veins. Deformed quartz veins sampled along this temperature gradient display a transition from cataclasites to mylonites (frictional–viscous transition) at 280±30 °C. Within the mylonites, zones characterized by different dynamic recrystallization mechanisms were defined: Bulging recrystallization (BLG) was dominant between 280 and 400 °C, subgrain rotation recrystallization (SGR) in the 400–500 °C interval, and the transition to dominant grain boundary migration recrystallization (GBM) occurred at 500 °C. The microstructures associated with the three recrystallization mechanisms and the transitions between them can be correlated with experimentally derived dislocation creep regimes. Bulk texture X-ray goniometry and computer-automated analysis of preferred [c]-axis orientations of porphyroclasts and recrystallized grains are used to quantify textural differences that correspond to the observed microstructural changes. Within the BLG- and SGR zones, porphyroclasts show predominantly single [c]-axis maxima. At the transition from the SGR- to the GBM zone, the texture of recrystallized grains indicates a change from [c]-axis girdles, diagnostic of multiple slip systems, to a single maximum in Y. Within the GBM zone, above 630±30 °C, the textures also include submaxima, which are indicative of combined basal a- and prism [c] slip.     

Dynamic recrystallization and chemical evolution of clinoamphibole from Senja,Norway

Clinoamphibole from a mylonitic amphibolite exhibits microstructures characteristic of dynamic recrystallization, including porphyroclasts in a finer grained matrix of needle-shaped amphibole. The matrix amphibole defines an LS fabric and porphyroclasts have core and mantle structures with a core containing undulose to patchy extinction and (100) deformation twinning surrounded by a mantle of recrystallized grains. In addition intragranular grains also occur within the cores. TEM analyses of the porphyroclasts reveal that they contain a wide variety of lattice defects including high densities (5 × 10⁸cm^–2) of free dislocations and dislocation arrays, dissociated dislocations, stacking faults, and (100) micro-twins. TEM also shows that matrix grains and intragranular grains have relatively low defect densities, and that the intragranular new grains occur at localities in the porphyroclasts characterized by high densities of dislocations. These observations along with the chemical and orientation relationships between the recrystallized grains and porphyroclasts indicate that the new grains may have formed by heterogeneous nucleation and that further growth probably occurred by both strain assisted and chemically induced grain boundary migration or liquid film migration. This recrystallization event is interpreted to be synkinematic based on the fact that no recrystallization textures are present in the matrix grains and that the matrix grains define an LS fabric. However, the low defect densities in the matrix grains and the lack of intracrystalline strain in other phases indicate that post-kinematic recovery processes were active.     

A scanning electron microscope study of the effects of dynamic recrystallization on lattice preferred orientation in olivine

Effects of dynamic recrystallization on lattice preferred orientation (LPO) in olivine were investigated through the combination of two SEM-based techniques, electron backscattered diffraction (EBSD) technique for crystallographic orientation measurement and backscattered electron imaging (BEI) for dislocation observation. Samples are experimentally deformed olivine aggregates in simple shear geometry. In the sample deformed at T=1473 K and high stresses (480 MPa), only incipient dynamic recrystallization is observed along grain-boundaries. Orientations of these small recrystallized grains are more random than that of relict grains, suggesting an important role of grain-boundary sliding at this stage of recrystallization. In the sample deformed at T=1573 K and low stress (160 MPa), dynamic recrystallization is nearly complete and the LPO is characterized by two [100] peaks. One peak is located at the orientation subparallel to the shear direction and is dominated by grains with high Schmid factor. The other occurs at high angles to the shear direction and is due to the contribution from grains with low Schmid factor. Grains with high Schmid factor tend to have higher dislocation densities than those with low Schmid factor. Based on these observations, we identify two mechanisms by which dynamic recrystallization affects LPO: (1) enhancement of grain-boundary sliding due to grain-size reduction, leading to the modification of LPO caused by the relaxation of constraint for deformation; (2) grain-boundary migration by which grains with lower dislocation densities grow at the expense of grains with higher dislocation densities. Based on the deformation mechanism maps and stress versus recrystallized grain-size relation, we suggest that the first mechanism always plays an important role whereas the second mechanism has an important effect only under limited conditions.     

High-temperature deformation in the Neoproterozoic transpressional Ribeira belt, southeast Brazil

The Neoproterozoic Ribeira belt is subdivided in two domains with contrasting tectonic characteristics. The northern domain is dominated by shallowly dipping foliations and orogen-normal thrust tectonics. The southern domain is characterized by a 1000-km-long network of anastomosing transcurrent shear zones parallel to the belt. This contrast is interpreted as reflecting continent–continent convergence that is almost orthogonal to the margins in the northern domain and significantly oblique in the southern domain. The central, transitional, domain of the Ribeira belt displays the northern termination of the transcurrent shear zone network: the Além Paraíba–Pádua shear zone system (APPSS). The 250-km-long Além Paraíba–Pádua system involves granulites facies mylonites deformed through transpression.A detailed study of the microstructure and lattice preferred orientation (LPO) of the rock-forming minerals in these granulite mylonites allow a better understanding of deformation mechanisms active at high temperature in the crust. Plagioclase crystals are plastically deformed; they display curved twins and cleavages, mechanical twins, and evidence of dynamic recrystallization. LPO of plagioclase is consistent with activation of the (010) [100] and (010) [001] slip systems. LPO of orthopyroxene and amphibole indicates that these minerals have been deformed through dislocation creep with the activation of the (100) [001] slip system. Quartz in granulite mylonite displays evidence of extensive growth through grain boundary migration. The LPO of quartz is therefore the result of a static transformation of an initial, syn-kinematic LPO, and cannot be straightforwardly interpreted in terms of deformation mechanisms active during mylonitization.     

Multi-stage evolution of the picritic Mælifell rocks,SW Iceland: constraints from mineralogy and inclusions of glass and fluid in olivine

The picritic Mælifell pillow lava series contains olivine macrocrysts (Fo 83.0–91.7) and microphenocrysts (Fo 86.8–88.5), resorbed Cr–Al endiopside, ± plagioclase, and microphenocrysts of Cr-spinel. The most primitive olivine cores (Fo 90–91.7) are probably derived from a peridotitic mantle. Gabbroic adcumulus xenoliths in the lavas contain plagioclase, Cr–Al endiopside and olivine (Fo 85.5–87.5) which overlap compositionally with lava minerals, ± Cr-spinel. This suggests that all pyroxene and much of the olivine ± feldspar in the lavas are xenocrysts. Olivines from the pillow lavas and from the gabbroic xenoliths contain inclusions of Cr-spinel, silicate glass and pure or nearly pure CO₂. Early (type 1) silicate melt inclusions which occur in lava-olivine only, have crystalized 0.1 to 4 vol.% daughter spinel and unknown amounts of olivine during pre-eruptive cooling. Later (type 2) glass inclusions in olivine from the lavas do not contain daughter minerals; similar type 2 inclusions also occur in the xenoliths. High-temperature microthermometry at buffered oxygen fugacity (f _{O 2}) gives a plagioclaseout temperature of about 1230°C for both types of silicate melt inclusions; this was interpreted as the liquidus temperature for type 2 inclusions. Molar volumes of undisturbed CO₂ inclusions in olivine from both lavas and xenoliths correspond to a depth of trapping of 7–10 km (2.2–3.0 kbar) at 1230°C. This is interpreted as a minimum depth to a partially molten layer near the crust/mantle boundary in the rift zone. The xenoliths are thus probably derived from a layered olivine-gabbro complex similar to those occurring in ophiolite complexes.