Pb-Pb age of sedimentary phosphorite reworking in Lower Riphean carbonate sediments,the Satka Formation of Southern Urals

The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The ⁸⁷Sr/⁸⁶Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (²³⁸U/²⁰⁴Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex.     

Rb-Sr and U-Pb systematics of metasedimentary carbonate rocks: The Paleoproterozoic Kuetsjarvi Formation of the Pechenga Greenstone Belt, Kola Peninsula

The Rb-Sr and U-Pb systematics have been studied in the metasedimentary carbonate rocks from the Paleoproterozoic Kuetsjarvi Formation. Samples were taken from the borehole drilled in the northern zone of the Pechenga Greenstone Belt in the northwestern Kola Peninsula. The carbonate section of the formation is made up of three units (from the bottom to top): (I) dolomite (68 m), (II) calcareous-dolomite (9 m), and (III) clayey calcareous (1 m) ones. Dolomites (Mg/Ca = 0.55–0.61) from the lowermost unit I contain 70.3–111 ppm Sr. Initial ⁸⁷Sr/⁸⁶Sr ratio in them varies within 0.70560–0.70623 and characterizes the primary continental-lacustrine carbonate sediments. Calcareous dolomites (Mg/Ca = 0.39–0.59) and dolomitic limestones of units II and III (Mg/Ca = 0.02–0.36) are enriched in Sr (285–745 and 550–1750 ppm, respectively). Initial ⁸⁷Sr/⁸⁶Sr ratios in these rocks (0.70406–0.70486 and 0.70407–0.70431, respectively) fall within the range typical of the Jatulian seawater, which indicates that the carbonate sediments of two upper units were formed in an open marine basin. Study of dolomites from unit I showed that the Svecofennian metamorphism more significantly affected the U-Pb systems of carbonate rocks as compared to their Rb-Sr systems. In the ²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb diagram, most data points corresponding to the carbonate constituent of dolomites define isochron with an age of 1900 ± 25 Ma (MSWD = 0.5). The same samples define a positive correlation in the ²⁰⁸Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb plot. Since sedimentary carbonates usually do not contain Th, this correlation points to secondary enrichment of the studied dolomites in Th or thorogenic ²⁰⁸Pb. Hence, the obtained Pb-Pb dating can be regarded as the age of the Svecofennian metamorphic event. Three samples from dolomites of unit I lack any disturbance of the initial U-Th-Pb systematics, but their trend in the ²⁰⁷Pb/²⁰⁴Pb-²⁰⁶Pb/²⁰⁴Pb diagram deviates from the 1900 Ma isochron. Based on these samples, the model U-Pb premetamorphic age of the Kuetsjarvi carbonate sediments is 2075–2100 Ma. This interval is consistent with the age range of the Lomagundi-Jatulian event, which was responsible for the formation of carbonate sediments with high positive δ¹³C values.     

The Sr isotopic characterization and Pb-Pb age of carbonate rocks from the Satka formation,the Lower Riphean Burzyan Group of the southern Urals

The Rb-Sr and U-Pb systematics are studied in carbonate deposits of the Satka and Suran formations corresponding to middle horizons of the Lower Riphean Burzyan Group in the Taratash and Yamantau anticlinoria, respectively, the southern Urals. The least altered rock samples retaining the ⁸⁷Sr/⁸⁶Sr ratio of sedimentation basin have been selected for analysis using the original method of leaching the secondary carbonate phases and based on strict geochemical criteria of the retentivity (Mn/Sr < 0.2, Fe/Sr < 5 and Mg/Ca < 0.024). The stepwise dissolution in 0.5 N HBr has been used to enrich samples in the primary carbonate phase before the Pb-Pb dating. Three (L-4 to L-6) of seven consecutive carbonate fractions obtained by the step-wise leaching are most enriched in the primary carbonate (in terms of the U-Pb systematics). In the ²⁰⁶Pb/²⁰⁴Pb-²⁰⁷Pb/²⁰⁴Pb diagram, data points of these fractions plot along an isochron determining age of 1550 ± 30 Ma (MSWD = 0.7) for the upper member of the Satka Formation. The initial ⁸⁷Sr/⁸⁶Sr ratio in the least altered limestones of this formation is within the range of 0.70460–0.70480. Generalization of the Sr isotopic data published for the Riphean carbonates from different continents showed that 1650–1350 Ma ago the ⁸⁷Sr/⁸⁶Sr ratio in the world ocean was low, slightly ranging from 0.70456 to 0.70494 and suggesting the prevalent impact of mantle flux.     

Pb-Sr-O-C isotope compositions of metacarbonate rocks of the Derbina Formation (East Sayan): Chemostratigraphic and geochronological significance

The Pb-Sr-O-C isotope compositions of calcite marbles of the Derbina Formation, exposed in the northwestern part of the Derbina block of the East Sayan, were studied. Rocks of the Derbina Formation were metamorphosed under high-temperature amphibolite facies conditions. The carbonate constituent of marbles contains (ppm) 15–130 Mn, 130–160 Fe, 0.008–0.039 Rb, 645–2190 Sr, 0.565–0.894 U, and 0.288–1.42 Pb. These concentrations are similar to those in modern carbonate sediments. The values of δ¹³C in marbles of the Derbina Formation range from–0.6 to +1.4‰ PDB; the values of δ¹⁸O range from 21.5 to 28.6‰ SMOW. The ⁸⁷Sr/⁸⁶Sr ratio values in the two least altered rocks, which meet geochemical criteria of the Rb-Sr system preservation in high-grade carbonate rocks, are 0.70804 and 0.70829. The protolith ages of marbles determined using Sr and C chemostratigraphy lie within the interval of 560–530 Ma, which is regarded as the period of carbonate sedimentation. The slope of the straight line on the ²⁰⁶Pb/²⁰⁴Pb–²⁰⁷Pb/²⁰⁴Pb diagram (n = 9, MSWD = 19) constructed on the basis of the data points of bulk carbonate constituents of all samples studied and those representing leachate steps of one of them in 0.5N HBr yields Late Vendian age (556 ± 31 (2σ) Ma. Taking into account the data on Sr and C isotope systematics of Derbina marbles, this age is regarded as the age of early diagenesis of carbonate sediments close to the age of sedimentation. Thus, metacarbonate rocks of the Derbina Formation preserved the pre-metamorphic chemostratigraphic and isotope-geochronological information. The age obtained testifies that formation of the carbonate cover of the Derbina block occurred in the Late Vendian. At the end of the Cambrian, carbonate deposits were metamorphosed during the Early Caledonian tectonic event in the southeastern part of the Central Asian Fold Belt.     

Sr isotopic composition of Paleoproterozoic C-rich carbonate rocks: The Tulomozero Formation,SE Fennoscandian Shield

Rb–Sr systematics has been studied in ¹³C-rich carbonate rocks of the Paleoproterozoic (2.09 ± 0.07 Ga) Tulomozero Formation in the northern Onega Lake area, the SE Fennoscandian Shield. The formation is divided into eight members (A–F) consisting of greenschist-facies-grade, variegated sandstones, siltstones, mudstones, stromatolitic dolostones and subordinate crystalline limestones. Samples of carbonate rocks were obtained from two overlapping drillholes intersecting the entire thickness of the Tulomozero Formation. Prior to isotope analysis, the rocks powders were treated with 1N ammonium acetate for partial removal of the late epigenetic carbonate phases. Major resetting of the Rb–Sr systems in the Tulomozero carbonate rocks appears to take place during the Svecofennian regional metamorphic event, and it was screened by using Mn/Sr, Fe/Sr, Mg/Ca, and ¹⁸O/¹⁶O ratios. High Sr content (up to 2080 μg/g in limestones, and 530 μg/g in dolostones) coupled with low Fe/Mn (<0.40) ratios in the Tulomozero carbonate rocks of Members A, B (the lower part), D, F, and E are consistent with accumulation of original carbonate sediments in evaporitic lacustrine, playa, and sabkha environments. A decrease in the Sr content with concurrent increase in the Fe/Mn ratio (>0.40) in dolostones of the upper part of Member B, and of Members G and H is indicative of seawater influxes (sea transgression) into the Tulomozero basin. The ⁸⁷Sr/⁸⁶Sr values in the least altered (Mn/Sr < 2.0) marine dolostones are 0.70418–0.70442 and 0.70343–0.70409 for the earlier and late phases of the marine transgression, respectively. The decrease in the ⁸⁷Sr/⁸⁶Sr ratio in ca. 2.1 Ga seawater is attributable to an increase in hydrothermal flux Sr into the Palaeoproterozoic ocean.     

湘西北上震旦统碳酸盐层序地层

碳酸盐层序地层应考虑碳酸盐＂加工厂＂、气候条件、构造背景、沉降速率、与陆地连接情况和底质类型等多种因素。碳酸盐层序地层模式在大多数情况下有别于Ｖａｉｌ的碎屑岩层序地层模式，并且气候条件是一个值得多加考虑的因素。通过不同相区碳酸盐层序地层的划分，笔者建立了研究区上震旦统碳酸盐层序地层模式，即陵山沱期为缓坡背景碳酸盐层序地层模式，灯影期为碳酸盐台地（初始）背景层序地层模式。在高水位体系域中识别出早期高水位体系域和晚期高水位体系域。已识别出浅潮下和环潮坪两种不同类型的副层序旋回。通过层序地层分析，笔者认为陡山沱底部的白云岩属于低水位楔。     

渤海湾盆地饶阳凹陷大王庄地区古近系沙三上亚段混积模式研究

利用岩芯、薄片、测录井以及测试分析等资料,结合区域地质,研究了渤海湾盆地饶阳凹陷大王庄地区古近系沙三上亚段（Es₃上）I油组发育的混积岩特征,分析了其沉积环境,探讨了其沉积模式。研究结果表明:大王庄地区古近系沙三上亚段I油组混积岩分为（含）陆源碎屑质—碳酸盐岩和（含）碳酸盐质—陆源碎屑岩两大类,以灰（云）质砂岩、砂质泥晶云岩为主,（含）陆源碎屑质—碳酸盐岩主要分布于工区中部和北部,（含）碳酸盐质—陆源碎屑岩分布于西部和南部;混积成因类型以原地混合和相源混合为主,相源混合出现于Es₃上I油组早中期,原地混合出现于Es₃上I油组早期;少量母源混合出现于Es₃上I油组晚期。饶阳凹陷大王庄地区古近系沙三上亚段I油组沉积环境主要位于滨浅湖,可划分为砂质混积滩坝沉积、碳酸盐岩混积滩坝沉积以及滨浅湖泥混积3种沉积微相类型。综合分析湖平面变化、构造演化、古地貌等对混合沉积的控制作用,建立了湖平面先稳定上升后下降的混积岩沉积模式:随着湖平面的缓慢上升,混合沉积呈增多趋势,以相源混合和原地混合为主;当湖平面到达一定高度时,纯碳酸盐岩增多,混合沉积减少,以相源混合为主;后期,湖平面下降,可能形成母源混合沉积。     

Cause of elevated as concentrations in the Baltic Sea and Vistula Lagoon

As is less toxic than Hg, Cd, Pb, Se, Zn, and Cu. The As clarke for clays and shales is 10 ppm. Our samples of bottom sediments from Kurshskii Bay were determined to contain from 15 to 26 ppm As and up to 34 ppm As in the vicinity of the Neman River mouth. Elevated As concentrations (50–114 ppm) were detected in four columns of subsurface bottom sediments (at depths of 10–65 cm) from the Vistula Lagoon. Elevated As concentrations (50–180 ppm) were also found in a few surface samples of sand from the Gdansk Deep near oil platform D-6. These sediments are either partly contaminated with anthropogenic As or contain Fe sulfides and glauconite, which can concentrate As and contain its elevated concentrations. The As concentration in columns of bottom sediments from the Gulf of Finland were at the natural background level (throughout the columns) typical of the area (9–34 ppm). We repeatedly detected very high As concentrations (up to 227 ppm As) in pelitic ooze from Bornholm Deep, in the vicinity of the sunken vessel with chemical weapons. The sources of elevated As concentrations in the Baltic Sea are the following: (1) chemical weapon (CW) material buried in the floor of the Baltic Sea; (2) As-bearing pesticides, agricultural mineral fertilizers, and burned coal and other fuels; (3) kerogen-bearing Ordovician rocks exposed on the bottom; and (4) As-rich Fe sulfides brought to the area together with construction sand and gravel. This mixture was used in paper production and for the construction of hydraulic engineering facilities in the Vistula Lagoon in the early 20th century and later caused the so-called lagoon disease.     

Strontium isotope composition of the lower proterozoic carbonate concretions: The Zaonega Formation,Southeast Karelia

The middle part of the volcanosedimentary Zaonega Formation of the Ludikovian Suprahorizon (approximately 2.0 Ga) includes large carbonates concretions and lenses in shungite layers. Carbonate lenses and concretions are primarily elongated and flattened, and their thickness varies from tens of centimeters to a few meters. Some lenses retain relicts of lamination. Concretions are composed of calcite or dolomite. They contain abundant organic matter, as well as mica, talc, chlorite, quartz, and pyrite crystals. The calcite concretions contain some dolomite admixture (Mg/Ca = 0.011?0.045) and differ from sedimentary limestones by a low Fe/Mn value (0.3–2.1). The Sr content is as much as 385–505 μg/g in most samples and is low (86 μg/g) only in one sample. The Rb-Sr systematics of carbonate concretions was studied with the stepwise dissolution procedure, which included processing with the ammonium acetate solution (AMA fraction) to partially remove the secondary carbonate material, with dissolution of the residue in acetic acid (ACA fraction). In individual calcite samples, discrepancy between the measured ⁸⁷Sr/⁸⁶Sr values in the AMA and ACA calcite fractions shows a variation range of 0.0008–0.0033. The initial ⁸⁷Sr/⁸⁶Sr ratio in the ACA fractions of the studied samples varies from 0.7053 to 0.7162. The ratio shows a positive correlation with Mg/Ca and the proportion of siliciclastic admixture and negative correlation with the Mn content. The concretions were formed when the sediments subsided, probably, during the transition from a zone with “mild” reductive conditions to zones with active sulfate reduction and methanogenesis. In the sulfate reduction zone, where most pyrite-bearing concretions were formed, the sediment was not geochemically exchaged with the bottom water and was evolved into a closed or semiclosed system. Processes of diagenesis in this zone promoted the release of the radiogenic ⁸⁷Sr from the associated siliciclastic minerals, resulting in growth of the initial ⁸⁷Sr/⁸⁶Sr in concretions up to 0.7108–0.7162. Some calcite concretions, which lacked pyrite (or contained its minimal amount) were likely formed in a thin surficial sediment layer located above the sulfate reduction zone. Therefore, they precipitated Sr in isotope equilibrium with Sr of the bottom water. However, large concretions and carbonate lenses with an insignificant siliciclastic admixture could retain the signature of early diagenesis or even sedimentation. The initial ⁸⁷Sr/⁸⁶Sr ratio in one of such samples with the siliciclastic admixture of 6.2% makes it possible to estimate the maximal value of this ratio (0.7053) in the Ludikovian paleobasin.     

Evaluating the provenance of Archean sedimentary rocks of the Diemals Formation (central Yilgarn Craton) using whole-rock chemistry and precise U – Pb zircon chronology

Whole-rock chemistry and precise U – Pb zircon chronology have been used to determine the provenance of Archean greenschist-facies siliciclastic sedimentary rocks of the Diemals Formation in the Marda – Diemals area of the central Yilgarn Craton, Western Australia. Field evidence shows that these siliciclastic rocks are, at least in part, derived from uplift and erosion of underlying greenstones, and this is borne out by the similar La/Sc, Cr/Th and REE chemistry of Diemals Formation siltstones and some sandstones to mafic volcanic rocks of the underlying greenstones. The higher Cr/V and lower Y/Ni of some siltstones is consistent with input from ultramafic and mafic rocks. Diemals Formation sandstones and siltstones cannot be separated in terms of ratios such as Zr/La, and siliciclastic rock chemistry reflects provenance rather than the effects of transport and depositional processes, such as sorting. Chemistry does not support input to Diemals Formation sedimentary rocks from the Marda volcanic complex despite both units being close to each other, and having overlapping maximum depositional and crystallisation ages, respectively. Instead, it is likely that detritus for the two units was deposited in adjacent, physically discrete basins. Some Diemals Formation sandstones are geochemically similar to felsic rocks intruding the underlying greenstone succession, with higher La/Sc and lower Cr/Th, and LREE-enriched patterns with negative Eu anomalies. Support for a genetic relationship is shown by the overlap in the maximum depositional age of these sandstones with the crystallisation age of the geochemically identical Pigeon Rocks Monzogranite. Combined whole-rock chemistry and precise U – Pb zircon chronology indicates that Diemals Formation sedimentary rocks were in large part derived from the underlying mafic volcanic rocks, with progressive unroofing of this succession leading to erosion of felsic intrusive rocks, now represented by sandstones found at various levels in the Diemals Formation.     

Source rocks and provenances of the Ladoga Group siliciclastic metasediments (Svecofennian Foldbelt, Baltic Shield): Results of geochemical and Sm-Nd isotopic study

Siliciclastic metasediments of the Ladoga Group that is the Kalevian stratotype in Karelia correlative with the Kalevian siliciclastic succession in Finland are studied in terms of geochemistry and Sm-Nd isotopic systematics. The results obtained show that rocks in the Ladoga Group lower part are enriched, as compared to rocks of the upper part, in TiO₂, Fe₂O₃, MgO, Cr, Co, Ni, and Sc, being comparatively depleted in Al₂O₃ and Th that is a result of compositional changes in provenances. The Sm-Nd isotopic data evidence that siliciclastic sediments of the Ladoga Group have accumulated during the erosion of rocks, which originated at the time of the Archean and Early Proterozoic crust-forming processes. Siliciclastic material with the Archean and Early Proterozoic T_Nd(DM) values, which are characteristic of metasediments in the group lower part, was derived respectively from granite gneisses of the Archean basement in the Karelian megablock of the Baltic Shield and from volcanic rocks of the Sortavala Group. Volcanic rocks of island-arc terranes of the Svecofennian foldbelt represented main source of siliciclastic material that accumulated in upper part of the succession.     

白云鄂博陆缘裂谷系沉积物源与超大型稀土矿床含矿白云岩的成因探讨

白云鄂博群尖山组H4岩性段石英砂岩中的碎屑锆石年龄纪录了华北克拉通北缘两期重要的构造岩浆事件,一组年龄集中在新太古代—古元古代初期(2379～2596Ma),另一组年龄集中在古元古代晚期(1761～1946Ma),该结果与白云鄂博地区基底岩石的锆石年龄相吻合。白云鄂博群沉积碳酸盐岩的全岩207Pb-206Pb等时线年龄1649±45Ma,代表了白云鄂博群的沉积时代。白云鄂博地区沉积灰岩、白云岩与含矿白云岩的Pb同位素组成存在非常大的差异,在Pb同位素组成和构造图解中,含矿白云岩都集中在地幔演化线附近,靠近亏损地幔端元[(206Pb/204Pb)i=15.04～16.49,(207Pb/204Pb)i=15.17～15.28,(208Pb/204Pb)i=31.20～36.40],而白云鄂博群中的灰岩、白云岩则位于造山带演化线附近,靠近深海沉积物端元[(206Pb/204Pb)i=17.28～19.35,(207Pb/204Pb)i=15.47～15.69,(208Pb/204Pb)i=36.62～37.12]。     

Analcime in lake and lake-margin sediments of the Carboniferous Rocky Brook Formation, Western Newfoundland, Canada

In the Deer Lake Basin of western Newfoundland, Canada, analcime has been found within fine-grained, siliciclastic and carbonate, lake and lake-margin sediments of the Carboniferous Rocky Brook Formation. Analcime is the only zeolite observed in these unmetamorphosed and non-volcanogenic rocks. Microscopic analcime occurs as vug-filling, limpid, isotropic to anisotropic crystals. Microprobe analyses show this type of analcime to be lower in silica than most analcime in sedimentary rocks. A second textural type of finer-grained submicroscopic analcime can be detected from X-ray diffraction spectra of Rocky Brook Formation mudstones, where it is associated with phyllosilicates (illite, interstratified chlorite/smectite, smectite, chlorite), other silicates (quartz, feldspar) and carbonates (dolomite, calcite). Results of this study suggest that the analcime in the Rocky Brook Formation formed either by direct lakewater/porewater precipitation or by reaction of these waters with one or more clay mineral types or plagioclase.     

U-Th-Pb systematics in hydrothermally altered granites from the Granite Mountains,Wyoming

U-Th-Pb systematics were investigated in 15 samples representing two types of deuterically altered Archean granite (albitized and silicified-epidotized granite) from the Granite Mountains, Wyoming. The loss of K-feldspar during both types of deuteric alteration was accompanied by an extreme reduction of Pb content from roughly 40 ppm to less than 12 ppm in the most altered samples. Nine of the 15 samples yield anomalously young whole-rock Pb-Pb and Th-Pb ages compared to concordia ages for zircons and to whole-rock Pb-Pb and Th-Pb ages for samples of unaltered granite. The young ages are interpreted to be the result of radiogenic Pb loss during a middle Proterozoic metamorphism that disturbed several isotopic systems in the unaltered granite. The loss of radiogenic Pb from the whole-rock systems of the deuterically altered granites is most likely due to the absence of microcline. In many granitic rocks, potassium feldspar tends to act as a receptor for Pb that has been mobilized, and this effect may account for the closed-system behavior of Pb in whole-rock samples of the unaltered granite. It may also account for the apparent gain of radiogenic Pb during the Proterozoic by one sample which was collected at the edge of an alteration zone. The deuterically altered granites may have also lost U during the Proterozoic, but, except for two samples, the dominant U loss occurred relatively recently, probably during Tertiary uplift and erosion.The low common-Pb contents and rather high U and Th contents of the hydrothermally altered granites might seem to indicate that these rocks are well suited for geochronologic studies in the U-Th-Pb system because such rocks should have a high percentage of radiogenic Pb. Unfortunately, open-system behavior in response to post-crystallization metamorphism shows that apparent ages for these types of rocks must be interpreted with caution.     

U-Pb Geochronologic, Nd Isotopic, and Geochemical Evidence for the Correlation of the Chopawamsic and Milton Terranes, Piedmont Zone, Southern Appalachian Orogen

We report U-Pb crystallization ages from four metavolcanic rocks and two granitic gneiss samples as well as whole-rock chemical analyses and Sm-Nd isotopic ratios from 25 metaigneous and metasedimentary rocks from the Chopawamsic and Milton terranes, southern Appalachian Orogen. A metarhyolite sample from the Chopawamsic Formation and a metabasalt sample from the Ta River Formation in the Chopawamsic terrane have indistinguishable U-Pb crystallization ages of 471.4+/-1.3 Ma and 470.0+1.3/-1.5 Ma, respectively. A sample from the Prospect granite that intruded metavolcanic rocks of the Ta River Formation yields a younger U-Pb date of 458.0+/-1 Ma. Metarhyolite and granitic gneiss samples from the northern part of the Milton terrane yield U-Pb dates of 458.5+3.8/-1.0 Ma and 450+/-1.8 Ma, respectively. Metavolcanic and metaplutonic rocks from both terranes span a range in major element composition from basalt to rhyolite. Trace element concentrations in these samples show enrichment in large-ion lithophile elements K, Ba, and Rb and depletion in high field strength elements Ti and Nb, similar to those from island arc volcanic rocks. Initial epsilon(Nd) values and T(DM) ages of the metaigneous and metasedimentary samples range from 0.2 to -7.2 and from 1200 to 1700 Ma for the Chopawamsic terrane and from 3.7 to -7.2 and from 850 to 1650 Ma for the Milton terrane. The crystallization ages for the metavolcanic and metaplutonic samples from both terranes indicate that Ordovician magmatism occurred in both. Similar epsilon(Nd) values from representative samples from both terranes suggest that both were generated from an isotopically similar source. Xenocrystic zircons from metavolcanic rocks in the Chopawamsic terrane have predominately Mesoproterozoic (207)Pb/(206)Pb ages (600-1300 Ma), but a single Archean (2.56 Ga) core was also present. The xenocrystic zircons and the generally negative epsilon(Nd) values indicate that both terranes are composed of isotopically evolved continental crust.     

Storm-influenced siliciclastic and carbonate ramp deposits, the Lower Ordovician Dumugol Formation, South Korea

The Dumugol Formation (Lower Ordovician) in the southern part of the Baegunsan syncline, South Korea, contains mixed siliciclastic and carbonate ramp deposits. The ramp sediments were frequently influenced by storm events resulting in tempestites of sandstone-mudstone couplets, bioclastic grainstones to packstones, flat-pebble conglomerates, a skeletal lag layer and laminated calcisiltites. All tempestites are characterized by an erosive to sharp base, poor grading and a transitional upper boundary. The difference in lithology of tempestites appears to have been controlled by the nature of substrates and by proximality. For example, laminated calcisiltites have developed on the shallow carbonate ramp, flat-pebble conglomerates are closely associated with nodular limestones on shallow and deep ramps, and thin skeletal lag layers from fossiliferous argillaceous sediments formed in a basinal setting. The stratigraphic succession of the Dumugol Formation represents an initial transgression followed by a regression. The vertical facies change records the transition from a shallow siliciclastic ramp to a deep carbonate ramp, to a basin, shallowing to a deep carbonate ramp, and to a shallow carbonate ramp. Storm effects are mostly well preserved in shallow to deep ramp deposits.     

石臼坨凸起西南陡坡带扇三角洲锆石定年与源汇示踪

为了示踪渤海湾盆地石臼坨凸起西南陡坡带扇三角洲源汇体系,对其东三段层序（Ed₃）的6个砂岩样品进行碎屑锆石U-Pb定年分析.西部扇体（C6-4-4井）富含白垩纪（K）锆石并具有110 Ma峰值,母岩以白垩系义县组火成岩为主;中部（C6-4-3、C6-4-6D井）、东部扇体（C6-4-5D）富含侏罗纪（J）锆石并具有152 Ma或168 Ma峰值,母岩以侏罗系蓝旗组火成岩为主,古生代（Pz）锆石则来自中生界碎屑岩.所有样品都含有太古代（Ar）、元古代（Pt）锆石,母岩为花岗岩基底.研究表明,除古生界碳酸盐岩外,源区的母岩地层均可通过碎屑锆石U-Pb年龄示踪,各扇体物源的差异性是由母岩地层倾向控制的,由于中生界向西北倾斜,白垩系主控西部扇体沉积,侏罗系则是中部、东部扇体的主要物源区.      

U–Pb detrital zircon geochronology and its implications: The early Late Triassic Yanchang Formation,south Ordos Basin,China

U–Pb detrital zircon geochronology has been used to identify provenance and document sediment delivery systems during the deposition of the early Late Triassic Yanchang Formation in the south Ordos Basin. Two outcrop samples of the Yanchang Formation were collected from the southern and southwestern basin margin respectively. U–Pb detrital zircon geochronology of 158 single grains (out of 258 analyzed grains) shows that there are six distinct age populations, 250–300 Ma, 320–380 Ma, 380–420 Ma, 420–500 Ma, 1.7–2.1 Ga, and 2.3–2.6 Ga. The majority of grains with the two oldest age populations are interpreted as recycled from previous sediments. Multiple sources match the Paleozoic age populations of 380–420 and 420–500 Ma, including the Qilian–Qaidam terranes and the North Qilian orogenic belt to the west, and the Qinling orogenic belt to the south. However, the fact that both samples do not have the Neoproterozoic age populations, which are ubiquitous in these above source areas, suggests that the Late Triassic Yanchang Formation in the south Ordos Basin was not derived from the Qilian–Qaidam terranes, the North Qilian orogenic belt, and the Qinling orogenic belt. Very similar age distribution between the Proterozoic to Paleozoic sedimentary rocks and the early Late Triassic Yanchang Formation in the south Ordos Basin suggests that it was most likely recycled from previous sedimentary rocks from the North China block instead of sediments directly from two basin marginal deformation belts.     

Carbonate platform growth and cyclicity at a terminal Proterozoic passive margin, Infra Krol Formation and Krol Group, Lesser Himalaya, India

Abstract The Infra Krol Formation and overlying Krol Group constitute a thick (< 2 km), carbonate-rich succession of terminal Proterozoic age that crops out in a series of doubly plunging synclines in the Lesser Himalaya of northern India. The rocks include 18 carbonate and siliciclastic facies, which are grouped into eight facies associations: (1) deep subtidal; (2) shallow subtidal; (3) sand shoal; (4) peritidal carbonate complex; (5) lagoonal; (6) peritidal siliciclastic–carbonate; (7) incised valley fill; and (8) karstic fill. The stromatolite-rich, peritidal complex appears to have occupied a location seaward of a broad lagoon, an arrangement reminiscent of many Phanerozoic and Proterozoic platforms. Growth of this complex was accretionary to progradational, in response to changes in siliciclastic influx from the south-eastern side of the lagoon. Metre-scale cycles tend to be laterally discontinuous, and are interpreted as mainly autogenic. Variations in the number of both sets of cycles and component metre-scale cycles across the platform may result from differential subsidence of the interpreted passive margin. Apparently non-cyclic intervals with shallow-water features may indicate facies migration that was limited compared with the dimensions of facies belts. Correlation of these facies associations in a sequence stratigraphic framework suggests that the Infra Krol Formation and Krol Group represent a north- to north-west-facing platform with a morphology that evolved from a siliciclastic ramp, to carbonate ramp, to peritidal rimmed shelf and, finally, to open shelf. This interpretation differs significantly from the published scheme of a basin centred on the Lesser Himalaya, with virtually the entire Infra Krol–Krol succession representing sedimentation in a persistent tidal-flat environment. This study provides a detailed Neoproterozoic depositional history of northern India from rift basin to passive margin, and predicts that genetically related Neoproterozoic deposits, if they are present in the High Himalaya, are composed mainly of slope/basinal facies characterized by fine-grained siliciclastic and detrital carbonate rocks, lithologically different from those of the Lesser Himalaya.     

黔西南水银洞超大型金矿龙潭组赋矿层岩相特征及对金成矿的控制

黔西南地区水银洞超大型金矿床产于上二叠统龙潭组,金异常富集的高品位层状-似层状矿体受特定的不纯碳酸盐岩和有利岩性组合控制。对龙潭组赋矿层及围岩开展系统岩石学对比分析,总结制约龙潭组沉积作用及岩石类型的控制因素,分析龙潭组中高品位金矿体产出特征及其对岩性岩相的选择性规律。结果表明,龙潭组整体为一套浅水三角洲泥炭沼泽与滨岸潮坪泻湖相沉积,以富含有机质为特征,灰岩夹层可能代表不同时期的海侵事件;峨眉山玄武岩浆的喷溢改变吴家坪期沉积古地理格局和龙潭组中陆源碎屑岩的成分,发育与火山活动有关的沉积,矿石中铁白云石可能是火山碎屑物质热蚀变产物;富有机质和玄武质火山碎屑的不纯生物碎屑灰岩是金异常富集形成高品位矿体的重要控制因素。在黔西南地区找寻该类型矿床时应重点评价特定的岩石类型及组合特征。