Biogeochemical processes in the water column of the Caspian Sea in November 2008

Doklady Earth Sciences -     

Deep basins of the Black Sea and Caspian Sea as remnants of Mesozoic back-arc basins

We review the geological and geophysical structural framework of the deep Black Sea and Caspian Sea basins. Based on seismic evidence and subsidence history, we conclude that the deep basins have an oceanic crust formed in a marginal sea environment. We propose that the present deep basins are remnants of a much greater marginal sea formed during three separate episodes during the Mesozoic: in the Middle Jurassic, Upper Jurassic and Late Cretaceous. A tentative sketch of the geologic evolution of the area is presented. The marginal sea reached its greatest extent in the Early Tertiary when it was about 900 km wide and 3000 km long. The central part of the marginal sea has since disappeared during the collision between the Arabian promontory and the Eurasian margin.     

Occurrence of hydrogen sulfide in the ground water of Kuwait

Hydrogen sulfide occurs in high concentration (10–200 mg/l) in different parts of Kuwait City and its suburbs at relatively shallow depths (15–40 m from the surface). This was revealed by drilling through the aquifer system underlying the city and sampling and analyzing the ground water at the drilled locations. The near-absence of coliform bacteria in the sulfide-rich zones, the presence of sulfur-reducing bacteria in the deep (>80 m) Dammam Formation aquifer and a linear positive relation between the concentration of hydrogen sulfide and the total dissolved solids content suggested non-anthropogenic origin of the sulfide in the ground water of Kuwait. The upward movement of sulfide-rich water from depth and its differential flushing by surface recharge through outcrops of the aquifers appear to have given rise to the present distribution of hydrogen sulfide in the aquifers underlying the Kuwait City.     

The driving forces behind the Caspian Sea mean water level oscillations

Closed basins such as the Caspian Sea rapidly respond to variations in atmospheric and geological events. This study has been conducted to deduce the role of natural and anthropogenic influences on the Caspian Sea mean water level fluctuations for the period of 1998–2005. It is recognized that climate is the primary mechanism of the Caspian Sea mean water level variations based on the relatively small differences of the Caspian Sea hydrologic budget residuals and the Caspian Sea mean water level fluctuations. This is further supported by the similarity in water-level variations of the Caspian Sea with those of Lake Van and Lake Urmia. On the other hand, the Caspian Sea needed to lose some of its water to attain water balance equilibrium in 2000 and 2001. The year 2000 showed anomalous seismic activity particularly in the southwestern part of the Caspian Sea. Two significant earthquakes with magnitudes of 6.8 and 6.5 M_w occurred on November 25, 2000. The focal mechanisms of these earthquakes and numerous aftershocks indicated normal faulting and, therefore, caused the Caspian Sea lake level to decline in 2000. The contribution of submarine mud volcano eruptions to the Caspian Sea lake level could be insignificant based on the comparison of water budget residuals and the mean water level variations. Neither crustal deformation (based on the GPS measurements) nor the offshore oil and natural gas production activities in the Caspian Sea are responsible for noticeable changes to the level of the Caspian Sea.     

Distribution of hydrocarbons in water and bottom sediments of the Northern and Middle Caspian Sea

A study of two classes of hydrocarbons (HCs)—aliphatic and polycyclic aromatic—in suspended matter of the surface waters and bottom sediments of the Northern and Middle Caspian Sea (R/V Nikifor Shurekov, October 2015) is described. It has been determined that oil pollution transported by river runoff and fluid streams flowing from sedimentary formations in the northeastern part are the main sources of hydrocarbons in the river–sea boundaries of the Volga, Terek, and Sulak rivers.     

Flocculation of heavy metals during mixing of freshwater with Caspian Sea water

Flocculation of colloidal size fraction for Cu, Zn, Pb, Ni and Mn was investigated on a series of mixtures with water salinities ranging from 1.5 to 9.5‰ during mixing of Haraz River with the Caspian Sea water. The flocculation trend of Zn (85.5%) > Mn (55.2%) > Cu (39.6%) > Pb (33.7%) > Ni (11.3%) indicates that Cu, Zn, Pb and Mn have non-conservative behavior and Ni has relatively conservative behavior during estuarine mixing. Highest flocculation of heavy metals occurs between salinities of 1.5 and 4.5‰. Statistical analysis indicates that the flocculation of Cu, Zn and Ni is governed by pH and total nitrogen.     

Environmental management of coastal regions in the Caspian Sea

Considering rapid population growth and migration, higher accumulation of communities is noticed in coastal areas. This is especially true with the coastal areas of the Caspian Sea. In the present investigation coastal areas between Jouybar to Behshahr region is selected for their special geographical and ecological locations. Further, adverse impacts of human, agriculture and industrial activities was examined along side the above mentioned coasts. It should be pointed out that protected Miankaleh Wildlife zone which is an internationally recognized wetland, falls within area of study. In the present study strengths, weaknesses, opportunities and threats method is used for the evaluation of environmental management status. In this regard, internal and external factors gained 2.28 and 2.58 scores. This is indicative of the abundance of weaknesses over strengths and it also shows that opportunities are more than threats. Subsequently 27 strategies were developed and quantitative strategic planning matrix method was also used to score each strategies. The results of quantitative strategic planning matrix method analysis was programmed in strategic position and action evaluation matrix. The present situation falls within “competitive” classification. This is indicative of weakness in coordinating development and environmental strategic plans. The result of present investigation strongly emphasis on compilation of strategic environmental plans for the control of population, pollution emission and land use planning changes. The most important strategies include development of environmental regulations and better supervision on enforcement of laws.     

Atmospheric circulation and storm events in the Black Sea and Caspian Sea

Extreme sea storms are dangerous and a potential source of damage. In this study, we examine storm events in the Black Sea and Caspian Sea, the atmosphere circulation patterns associated with the sea storm events, and their changes in the present (1961–2000) and future (2046–2065) climates. A calendar of storms for the present climate is derived from results of wave model SWAN (Simulating WAves Nearshore) experiments. On the basis of this calendar, a catalog of atmospheric sea level pressure (SLP) fields was prepared from the NCEP/NCAR reanalysis dataset for 1961–2000. The SLP fields were subjected to a pattern recognition algorithm which employed empirical orthogonal decomposition followed by cluster analysis. The NCEP/NCAR reanalysis data is used to evaluate the occurring circulation types (CTs) within the ECHAM5-MPI/OM Atmosphere and Ocean Global Circulation Model (AOGCM) for the period 1961–2000. Our analysis shows that the ECHAM5-MPI/OM model is capable of reproducing circulation patterns for the storm events. The occurrence of present and future ECHAM5-MPI/OM CTs is investigated. It is shown that storm CTs are expected to occur noticeably less frequently in the middle of the 21^st century.     

The recent tectonics of the Caspian Sea region

Recent uplifts and depressions complicated by lineaments, many of which are faults, were found within the Caspian depression using complex structural and geomorphological studies, which included visual interpretation of different-scale topographic maps, as well as an analysis and computer processing of radar satellite images. In many respects, the latest dislocations correlate with the structures and sedimentary cover of the basement and are also determined by salt tectonics. Their formation is substantially influenced by the Ural Orogen and the Scythian plate is involved in the entire uplift at the latest stage.     

Aerosols in the Near-Water Surface Layer of the Caspian Sea

The first data on the concentrations, fluxes, and mineral and chemical compositions of aerosols from the near-water surface layer of the Caspian Sea are presented. It is shown that the aerosol fluxes onto the sea surface are comparable to the fluxes of a lithogenic substance in a water column. The mineral and chemical compositions of aerosols depend on the carrying air masses that pass through different regions. The coefficients of enrichment of aerosols with chemical elements relative to the upper lithosphere and their correlation relationships are studied.

     

Peculiarities of the centennial salinity regime of the Caspian Sea

Based on primary information from the Caspian Sea oceanographic database, the centennial salinity regime was analyzed. The regularities of the salinity spatial dynamics and vertical distribution were found for the characteristic periods of the sea level changes. Significant changes in the hydrological regime and the structure of the water mass for the centennial period were shown.     

Gas seeps in the North Caspian water area

Seismoacoustic profiling and sonar survey of the North Caspian water area revealed in some areas signs of intense release of methane from the sedimentary sequence. This fact was also supported by submarine videorecording data. Such sites are characterized by hummocky and ridgy morphologies, which accommodate local cone-shaped bodies (up to 1.3–1.5 m high) overgrown with algae, Balanus, and shelly material. Based on dredging data, these rises are composed of hard sandstones and shells. They can cover the seafloor or make up separate interlayers in the bottom sediments down to a depth of 2.7 m. Mineralogical studies demonstrated that the coarse-grained sediments are cemented with Mg-calcite, with δ¹³C reaching ?32.6‰. They also include microcrystalline barite and globular iron sulfides. The results of investigation suggest that the local activation of authigenic mineral formation is related to gas discharge sources.     

Dissolved and particulate trace metal geochemistry during mixing of Karganrud River with Caspian Sea water

Arabian Journal of Geosciences - Estuaries are both chemically and physically dynamic ecosystems that, due to their location at the river-sea interface, act as buffer zones between the continent...     

Global hydrogen reservoirs in basement and basins

Background

Hydrogen is known to occur in the groundwaters of some ancient cratons. Where associated gases have been dated, their age extends up to a billion years, and the hydrogen is assumed also to be very old. These observations are interpreted to represent the radiolysis of water and hydration reactions and migration of hydrogen into fracture systems. A hitherto untested implication is that the overwhelming bulk of the ancient low-permeability basement, which is not adjacent to cross-cutting fractures, constitutes a reservoir for hydrogen.

Results

New data obtained from cold crushing to liberate volatiles from fluid inclusions confirm that granites and gneiss of Archean and Palaeoproterozoic (>1600 Ma) age typically contain an order of magnitude greater hydrogen in their entrained fluid than very young (<200 Ma) granites. Sedimentary rocks containing clasts of old basement also include a greater proportion of hydrogen than the young granites.

Conclusions

The data support the case for a global reservoir of hydrogen in both the ancient basement and in the extensive derived sediments. These reservoirs are susceptible to the release of hydrogen through a variety of mechanisms, including deformation, attrition to reduce grain size and diagenetic alteration, thereby contributing to the hydrogen required by chemolithoautotrophs in the deep biosphere.

     

Modern diversity of the macroalgae of the Sea of Azov,the Black Sea,and the Caspian Sea

Currently, the species list of the macroalgae (excluding Charales) inhabiting the southern seas of Russia includes 388 species, specifically, 362 species in the Black Sea, 46 species in the Sea of Azov, and 70 species in the Caspian Sea. The species list has been increased by approximately 30% (96 species, most of them are registered in the Black Sea), compared to the data obtained 30 years ago. The green and red macroalgae of warm-water Mediterranean and tropical origin (Ceramium, Polysiphonia, Laurencia, Ulva, and Chaetomorpha) and brown algae (Sargassum and Cytoseira) were the key invaders. Nowadays the maximal species diversity is found on the Crimean coast and the Turkish coast of the Black Sea; and the species list of the Turkish coast differs significantly from all the other studied sites of the Black Sea. The number of the algae of the warm-water complex increased the most in 1990s–2000s in the Black Sea; species of boreal-tropical and subtropical origin dominate. However, such a tendency was not observed in the Sea of Azov and in the Caspian Sea, but expansion of the habitats of the brackish green algae has been registered.     

The Equation of State for Caspian Sea Waters

The density ρ of Caspian Sea waters was measured as a function of temperature (273.15–343.15) K at conductivity salinities of 7.8 and 11.3 using the Anton-Paar Densitometer. Measurements were also made on one of the samples (S = 11.38) diluted with water as a function of temperature (T = 273.15–338.15 K) and salinity (2.5–11.3). These latter results have been used to develop an equation of state for the Caspian Sea (σ = ±0.007 kg m⁻³)

Holocene deposits in the Mangyshlak Peninsula,North Caspian Sea region

Comprehensive analysis of the data of high-precision seismoacoustic profiling, drilling and sampling of deposits using seabed corers, biostratigraphic studies, and radiocarbon age data was performed for the first time for Mangyshlak sediments in several bottom sites of the North Caspian. It was found that the Mangyshlak sediments comprise numerous linearly stretched depressions of 5–10 m in depth (morphologically similar to modern substeppe ilmen areas in the Volga River delta), which are covered by the Novocaspian sedimentary cover, and river incisions (among them the largest Volga River valley). In addition, the Mangyshlak sediments comprise the deltaic alluvial fans of different sizes along the shelf zone of the North Caspian. Analysis of mollusks and biogenic remains indicates that accumulation of the Mangyshlak sediments occurred in freshwater and slightly salty water environments under various hydrodynamic and hydrochemical conditions. According to radiocarbon dating of organic matter, the Mangyshlak sediments formed during sea regression in the range of 10-8 ka (isotopic age) or 11.5-8.5 ka (calendar age). Several types of sediments are distinguished: clayey-carbonate sediments, enriched with organic matter up to the formation of sapropel and peat, accumulated at the lowest sea level; weakly calcareous silty-clayey silts, formed during the subsequent intense filling of paleodepressions with terrigenous material. The features of the mineral composition of sediments are as follows: polymineral composition of clayey material with a high proportion of hydromica and disordered mixed-layered formations, a high content of minerals of the epidote group, amphiboles, and other accessory minerals. All of this indicates a genetic relationship between the Mangyshlak sediments and the Volga terrigenous material.