A magnetic investigation of a Late Quaternary loess/palaeosol record in Siberia

A Late Quaternary loess/palaeosol sequence at Kurtak in the Yenisey River valley, southern Siberia, has been studied magnetically. The 34  m section (340 samples) exhibits variations in magnetic susceptibility which can be correlated with oxygen isotope stages 1–7. A detailed sampling of stage 5 (a further 209 samples) permits the identification of substages 5a–e. The susceptibility variations themselves are in the opposite sense to that found in the classic sections of the Chinese Loess Plateau, but are in agreement with the 'wind-intensity' model which has been put forward to explain similar findings in loess sequences in Alaska. Published results for the susceptibility of magnetite imply volume fractions of ≈0.2 per cent in glacial stages 2 and 4, dropping to ≈0.05 per cent in stages 1, 3 and 5. These fluctuations match the aeolian flux variations observed in core V21–146 from the north Pacific. Even though the warmer intervals are characterized by lower susceptibilities, the observed frequency dependence of susceptibility indicates that new magnetic material is produced as a result of pedogenesis during interglacial and interstadial times.     

Palaeoclimatic record from a loess–soil profile in northeastern Bulgaria—II. Correlation with global climatic events during the Pleistocene

Magnetic susceptibility ( χ ) variations and the behaviour of the ratio of susceptibility to saturation magnetization ( χ/J _s ) along the loess/palaeosol section at Koriten (NE Bulgaria) are used to deduce climatic changes during the Pleistocene in southeastern Europe. A good correlation of susceptibility variations with the astronomically tuned oxygen isotope record from ODP site 677 enables us to propose a more precise dating of the upper part of the Bulgarian loess complex. Close correspondence between susceptibility and δ ^{1 8} O records demonstrates the global significance of the palaeoclimatic signal recorded, although differences in relative amplitudes of χ and χ/J _s and δ ^{1 8} O create difficulties in making quantitative estimates of the climatic humidity in the past. The role of local factors affecting the palaeoclimatic mineral magnetic record deduced from the profile studied in Bulgaria is discussed.     

Rock magnetic properties of recent soils from northeastern Bulgaria

In this paper, basic rock magnetic studies of Holocene loess-soil samples from northeastern Bulgaria are reported. The sites are related to the Danube river and located at different distances southwards, thus representing various pedogenic conditions. The study is primarily aimed at determining the main magnetic carrier(s) and their physical characteristics (grain-size distribution, magnetic enhancement, etc.). Oxyhydroxides, maghemite and titanomagnetites of various oxidation degrees are assumed to be the main ferromagnetic minerals present. Our results suggest that the uppermost part of recent soil profiles is rich in stable, near-single-domain (SD) particles, while the illuvial horizons are characterized by a gradual decrease in grain sizes, from highly viscous to a true superparamagnetic (SP) domain state. The properties of samples from carbonate-rich horizons of recent soils are basically controlled by detrital minerals, while those from sites with more intensive pedogenesis and especially grey forest soils are influenced by strongly magnetic minerals formed ' in situ '.     

Palaeoclimatic record from a loess–soil profile in northeastern Bulgaria—I. Rock magnetic properties

A detailed record of mineral magnetic properties of a loess–palaeosol profile comprising seven loess horizons, six interbedded palaeosols and recent soil at the top in NE Bulgaria is analysed. A strong contrast between the soil and loess susceptibilities as well as other concentration-dependent hysteresis parameters is present, similar to the well-documented magnetic characteristics of the Chinese loess ( Hus & Han 1992 ; Maher & Thompson 1992 ; Heller & Evans 1995 ; Hunt et al. 1995 ). The magnetic enhancement of the palaeosol units is caused by very fine-grained pedogenic magnetite with superparamagnetic behaviour. Thermomagnetic analyses on bulk material suggest magnetite and maghemite as the main ferrimagnetic carriers in both soil and loess horizons. Their relative proportions are shown to reflect different palaeoclimatic conditions. Chernozem soils, which include recent soil S₀ and first and second palaeosols S₁ and S₂ developed under steppe vegetation, show a high degree of low-temperature oxidation of the pedogenic magnetite to maghemite. This material is characterized by coercive force H _c showing even higher values than those of the parent loess material. The older palaeosols (S₄ to S₆ ) were formed during more humid climatic conditions and therefore probably developed as forest types. Rock magnetic data suggest the existence here of only partly oxidized magnetite grains. The behaviour of the thermomagnetic curves, characterized by a kink at 200 °C, may be due to either a release of internal stress (built up as a result of partial low-temperature oxidation) or interactions between two phases.     

Review of the low-temperature magnetic properties of magnetite from a rock magnetic perspective

The low-temperature magnetic properties of magnetite are reviewed, and implications for rock magnetism considered. The behaviour of fundamental properties of magnetite at low temperatures near the Verwey transition ( T _v ) are documented, and attention is given to various Verwey transition theories. The low-temperature behaviour of the magnetic energies that control domain structure is reviewed in detail. For the first time in rock magnetic literature, the low-temperature anomaly in spontaneous magnetization ( M _s ) is documented and the differences between the saturation magnetization and M _s near the Verwey transition are discussed. It is argued that the low-temperature behaviour of the magnetocrystalline anisotropy, and in particular the anomaly at T _v , is most likely to affect multidomain remanence during low-temperature cycling. For multidomain crystals it is calculated that the large increase in magnetocrystalline anisotropy intensity and reduction in symmetry on cooling through T _v is likely to reduce the stability of closure domains.     

The rock magnetic signal of climate change in the maar lake sequence of Lac St Front (France)

Rock magnetic properties of the maar lake sediments of Lac St Front (Massif Central, France) reflect environmental changes during the last climatic cycle. High magnetic concentrations are measured in the sediments deposited under glacial climatic conditions, while lower concentrations correspond with more temperate climatic periods. Low- and high-temperature measurements indicate that the remanence is carried by (titanium-poor) magnetite. However, some maghemite and haematite is present in sediments deposited under temperate conditions.
Normalized intensities and coercivities of the anhysteretic remanent magnetization (ARM) are clearly higher for the sediments deposited during the temperate climatic periods of the Eemian, St Germain I, II and Mid-glacial than for glacial sediments, but other magnetic parameters hardly differ between these groups. Due to slight differences in magnetic composition and possible effects of grain interactions, it is not straightforward to relate this different ARM behaviour to magnetic grain-size variations. For the Holocene sediments, rock magnetic parameters indicate a larger grain size. This trend is also suggested by granulometric experiments with an optical laser granulometer. Dissolution of smaller grains is the most likely explanation for this larger grain size.
Changes in magnetic composition and grain size are extremely limited for the glacial sediments, but magnetic concentration varies considerably. Magnetic concentration maxima in the glacial sediments of Lac St Front correlate with those of the nearby Lac du Bouchet (Thouveny et al. 1994). Correlating the susceptibility records of these sequences with the δ¹⁸O record of the GRIP ice cores (Thouveny et al. 1994) suggests that magnetic concentration maxima may correspond with short cold climatic episodes, associated with Heinrich events.     

Nature and origin of magnetic minerals within the Middle Jurassic shallow-water carbonate rocks of the Paris Basin, France: implications for magnetostratigraphic dating

The Middle and Upper Jurassic Bathonian-Oxfordian shallow-water carbonate rocks from the Paris Basin, France, consist mainly of oolitic and bioclastic limestones that are hydrocarbon reservoirs in the subsurface. Despite a preliminary positive study, these deposits have been considered to be largely remagnetized (Rochette, private communication), and hence not amenable to palaeomagnetic dating. To establish their magnetic mineralogy and test this remagnetization hypothesis, we have used an integrated investigation combining petrographic, geochemical, rock-magnetic and palaeomagnetic measurements on samples extracted from five cores from the Paris Basin and from outcrops in Burgundy. Magnetic minerals in the Bathonian-Oxfordian carbonates include: (1) primary biogenic single-domain magnetite and detrital multi-domain Ti-magnetite and their oxidized form, maghemite; (2) authigenic spheres of magnetite probably related to hydrocarbons; and (3) goethite, either restricted to ferruginous ooid layers or resulting from surficial alteration, notably replacement of pyrite framboids. Rock-magnetic experiments carried out on 68 samples reveal H _cr/ H _c and M _rs/ M _s ratios ranging from 1.88 to 5.58 and 0.017 to 0.314, respectively. These values are clearly distinct from diagnostic values for a chemical remagnetization. Pyrrhotite was not identified within these sediments. Moreover, the average H _cr/ H _c ratio of 3.14 is significantly different from the value of 1.333 for natural pyrrhotite (Dekkers 1988). These results have a direct implication for the preservation of the primary magnetization; consequently, these deposits are selectively amenable for magnetostratigraphic dating and possible regional correlations.     

Separation of pedogenic and lithogenic components of magnetic susceptibility in the Chinese loess/palaeosol sequence as determined by the CBD procedure and a mixing analysis

Magnetic susceptibility variations in the Chinese loess/palaeosol sequences have been used extensively for palaeoclimatic interpretations. The magnetic signal of these sequences must be divided into lithogenic and pedogenic components because the palaeoclimatic record is primarily reflected in the pedogenic component. In this paper we compare two methods for separating the pedogenic and lithogenic components of the magnetic susceptibility signal: the citrate-bicarbonate-dithionite (CBD) extraction procedure, and a mixing analysis. Both methods yield good estimates of the pedogenic component, especially for the palaeosols. The CBD procedure underestimates the lithogenic component and overestimates the pedogenic component. The magnitude of this effect is moderately high in loess layers but almost negligible in palaeosols. The mixing model overestimates the lithogenic component and underestimates the pedogenic component. Both methods can be adjusted to yield better estimates of both components. The lithogenic susceptibility, as determined by either method, suggests that palaeoclimatic interpretations based only on total susceptibility will be in error and that a single estimate of the average lithogenic susceptibility is not an accurate basis for adjusting the total susceptibility. A long-term decline in lithogenic susceptibility with depth in the section suggests more intense or prolonged periods of weathering associated with the formation of the older palaeosols.
The CBD procedure provides the most comprehensive information on the magnitude of the components and magnetic mineralogy of loess and palaeosols. However, the mixing analysis provides a sensitive, rapid, and easily applied alternative to the CBD procedure. A combination of the two approaches provides the most powerful and perhaps the most accurate way of separating the magnetic susceptibility components.     

The detection of single-domain greigite (Fe3S4) using rotational remanent magnetization (RRM) and the effective gyro field (Bg): mineral magnetic and palaeomagnetic applications

The intensity of rotational remanent magnetization (RRM) acquired by single-domain greigite at a rotation frequency of 5 rps was combined with measurements of anhysteretic remanent magnetization (ARM) to calculate the effective biasing field ( Bg ) that produced the RRM. Samples of single-domain greigite had Bg values between -137 and -84 μT, and a MDF_RRM of c. 80 mT. By contrast, a suite of natural and synthetic ferrimagnetic iron oxide samples, including single-domain magnetite and y Fe₃O₄ tape particles, acquired Bg values between -3 and -14 μT, and MDF_RRM ranged between 43 and 68 mT (when RRM was acquired). Multidomain magnetite did not acquire a RRM. Bg values at 5 rps were calculated from previously published data for magnetite particles of different grain sizes, which revealed a minimum Bg value of -24 μT and a MDF_RRM of 57 mT for the finest fraction (0.2-0.8 μm in diameter). In a geological example, measurements of Bg and MDF_RRM were used to detect the presence of greigite in a 4 m long Late Weichselian sediment core. Variations in inclination, declination and the intensity of the natural remanent magnetization (NRM) correlate with changes in magnetic mineralogy.     

Environmental magnetic record of Antarctic palaeoclimate from Eocene/Oligocene glaciomarine sediments, Victoria Land Basin

The onset of continent-wide glaciation in Antarctica is still poorly understood, despite being one of the most important palaeoclimatic events in the Cenozoic. The Eocene/Oligocene boundary interval has recently been recognized as a critical time for Antarctic climatic evolution, and it may mark the preglacial–glacial transition. Magnetic susceptibility, intensity of natural and artificial remanences, hysteresis parameters and magnetic anisotropy of the lower half (late Eocene/early Oligocene) of the CIROS-1 core (from McMurdo Sound, Antarctica) reveal alternating intervals of high and low magnetic mineral concentrations that do not correspond to lithostratigraphic units in the core. Pseudo-single-domain magnetite is the main magnetic mineral throughout the sequence, and sharp changes in magnetite concentration match changes in clay mineralogy beneath and at the Eocene/Oligocene boundary. The detrital magnetite originated from weathering of the Ferrar Group (which comprises basic extrusive and intrusive igneous rocks). Weathering processes and input of magnetite to the Victoria Land Basin were intense during periods when the Antarctic climate was warmer than today, but during intervals when the climate was relatively cool, chemical weathering of the Ferrar Group was suppressed and input of detrital magnetite to the Victoria Land Basin decreased. Our results also indicate that a cold and dry climate was not established in Antarctica until the Eocene/Oligocene boundary, with major ice sheet growth occurring at the early/late Oligocene boundary. Some earlier cold intervals are identified, which indicate that climate had begun to deteriorate by the middle/late Eocene boundary.