Anomalous mixing of the w2Po3/2 and x6Po3/2 levels in Fe ii

The neighbouring lines a ⁶D_5/2– x ⁶P^o_3/2 (1272.617 Å) and a ⁶D_5/2– w ²P^o_3/2 (1272.657 Å) have been observed in the UV spectrum of χ Lupi to be of comparable intensity. The latter, Δ S  = 2, transition would be expected to be very weak. The two upper states should display negligible mixing. We give a detailed, quantitative discussion of how the two upper states are in fact strongly mixed through their mixing with 3d⁶(³D)4p ⁴P^o_3/2, and hence we explain the relative strengths of the two UV lines.     

Changes in the frequency distribution of f0Es and fbEs over two solar cycles

The dependence of the occurrence probabilities of ionosonde sporadic-E parameters f₀E_s and f_bE_s on probing frequency is analyzed for wintertime for day and night for two Southern Hemisphere stations. The ionosonde data indicate that significant changes have taken place over the period 1958–1983 suggesting that E_s has become increasingly dense and also less patchy.     

A global study of O2(1Δg) airglow: Day and twilight

Aircraft measurements of $\text{O}{}_2\text{(}{}^1\text{Δ}{}_{\mathrm{g}}\text{)}$ emission made over a 10-yr period provide information on the variation of ozone with latitude and season in the altitude region 50–90 km. Between 50 and 70 km there appears to be little variation (< ± 25%) whereas the abundance between 80 and 90 km exhibits a large seasonal change north of 30°N and much less at lower latitude. At mid and high latitude the column abundance above ～ 80 km changes from ? 1 × 10¹⁴ cm^?2 in summer to about 3 × 10¹⁴ cm^?2 in winter. There are occasional enhancements in both the day and twilight airglow which almost always occur in association with auroral activity or, at least, where such activity is statistically most likely. These enhancements appear to reflect a corresponding increase in the ozone mixing ratio in the upper stratosphere. While the gradient in ozone mixing ratio with latitude is generally small at altitudes between 50 and 90km there are occasions when a temporary latitude structure can be seen, particularly above 80 km.     

Class II maser candidates in substituted methanol: CH3OD, 13CH3OH, CH318OH and CH3SH

We investigate the possibility of interstellar masers in transitions of the methanol isotopomers CH₃OD, ¹³CH₃OH and CH₃¹⁸OH, and of CH₃SH. The model used, in which masers are pumped through the first and second torsionally excited states by IR radiation, has accounted successfully for the Class II masers in main species methanol, ¹²CH₃¹⁶OH. Several potential maser candidates are identified for CH₃OD, their detectability depending on the enrichment of this species in star-forming regions. In ¹³CH₃OH and CH₃¹⁸OH the best maser candidates are direct counterparts of the well-known 6.7- and 12.2-GHz methanol masers, but the lower interstellar abundance of these substituted species means that the expected brightness is greatly reduced. The maser candidates in CH₃SH are also weak. By comparing these species we find that the large b -component of the dipole moment in methanol plays a significant role in its propensity to form masers, as does the strong torsion–rotation interaction due to the light hydroxyl frame. Thus the exceptional brightness of interstellar methanol masers is due to a favourable combination of molecular properties as well as high interstellar abundance.     

Estimated conductivity ratio ∑H∑P in the auroral electrojets in connection with electrojet width and field-aligned currents

By using ground based magnetic observations and by assuming a three-dimensional current system model the conductivity ratio $\text{∑}{}_{\mathrm{<mtext>H</mtext>}}\text{∑}{}_{\mathrm{<mtext>P</mtext>}}$ is calculated for several substorms. It is shown that this ratio decreases when the field aligned current intensity is enhanced. The enhancement is connected with a broadening of the electrojet region.     

A discussion of the energy transfer from N2(A3Σu+) to O(1S) in pulsating aurora

In a recent paper, Brekke and Pettersen (1972) have introduced a method for estimating any indirect process in the production of the $\text{O}\text{(}{}^1\text{S}$) atoms in pulsating aurora; for 38 per cent of their data they found that the decay time for the indirect mechanism was shorter than the effective lifetime of the ${}^1\text{S}$ state. These data are related to the energy transfer from the N₂(A³Σ) molecules to the $\text{O}\text{(}{}^1\text{S)}$ state, and evidence is found for this process to contribute in the altitude range below 125 km.     

On determining magnetohydrodynamic shock parameters θBn and MA

In a collisionless plasma, the magnetohydrodynamic shock structure, the associated waves and turbulence depend strongly on the shock parameters θ_Bn and M_A, where θ_Bn is the angle between the upstream magnetic field and the shock normal and M_A is the upstream Alfvén Mach-number. A method is given to determine θ_Bn and M_A and their estimated errors for all types of shocks without knowing the shock normals. The only measured quantities needed to determine θ_Bn and M_A are the plasma density and magnetic field on both sides of the shock. The estimated error of θ_Bn using our method can be obtained in a straightforward manner and is more reliable than that based on the calculated shock normal and the upstream magnetic field. Its simplicity and ability to handle parallel shocks as well as perpendicular and oblique shocks are illustrated by examples. This method should be useful for characterizing the types of shocks from analyzing the copious amount of data on magnetohydrodynamic (MHD) shocks found in space.     

Ground-based observations of O2 (b1Σ+g−X3Σ−g) atmospheric bands in high latitude auroras

Analysis of observed spectrograms is based on comparison with synthetic spectra. The O₂(b¹Σ⁺_g?X³Σ^?_g Atm. (1,1) band in high latitude auroras observed from the ground is found to be the strongest in the Δv = 0 sequence. It is enhanced with altitude relative to the N₂ 1P(2, 0)and N⁺₂ M(2,0) bands, but the O₂ Atm. (2, 2) band has an unexpected low intensity. The range of rotational temperatures of the O₂ Atm. bands varies from approx. 200 to above 500 K which indicates that the altitude of the centroid of the emission region varies from about 100 km to the F-region. The highest temperature is found in the midday aurora associated with the magnetospheric cusp. Conspicuous relative variations between the intensities of N₂ and O₂ spectra are documented, but a satisfactory explanation of the variety is not given. Deviations of the observed O₂ Atm. band intensities from the vibrational intensity distribution predicted by Franck-Condor factors indicate that the excitation of the O₂ Atm. bands in aurora is not mainly due to particle impact on O₂, and the contribution due to energy transfer from hot O(¹D) atoms has to be found in future research.     

The semiannual variation in the magnetic activity indices Aa and Ap

The technique of Complex Demodulation is used to examine the long-term modulation of the semiannual variation in planetary magnetic activity as characterised by the A_a index for 1868–1980 and the A_p index for 1932–1980. From the phase results, strong support is found for an “equinoctial” mechanism for the semiannual variation. The amplitude shows a quasi 11 -year modulation for most of the period of analysis and a pronounced increase over the years 1938–1966 approximately. Comparison of the long-term modulation of the semiannual variation in activity, with that of the occurrence of stormy days suggests that the semiannual modulation is energy dependent, being more effective with increasing energy.     

Is Te equal to Tnm at the heights of 100 to 120 km?

Low and mid-latitude lower E-region electron temperature profiles which were obtained by means of an insitu probe were collected. Profiles which are discussed here cover the heights of 90–120 km and measurement reliability at these heights is discussed mainly in terms of electrode contamination and aerodynamical heating.Although measurement errors might exist in some of the electron temperature profiles, it is conclusively described that daytime electron temperature is very often much higher than the possible neutral temperature and T_e ≈ T_n is rarely seen.     

A possible current system associated with the Sqp variation

It is suggested that the quiet day daily magnetic variation in the polar cap region, S_q^p, results partly from the short-circuit effect of the magnetotail current by the polar ionosphere. This implies that there is an inward field-aligned current from the dawnside magnetopause to the forenoon sector of the auroral oval (positively charged) and an outward field-aligned current to the duskside magnetopause from the afternoon sector of the oval (negatively charged), together with the ionospheric (Pedersen and Hall) currents. The distribution of the magnetic field vectors of both combined current systems agrees with the observed S_q^pvector distribution. The space charges provide an electric field distribution which is similar to that which has been observed by polar orbiting satellites.     

Auroral N2(c′4Σu → aΠg emission

Inspection of recent spectra presented by Sivjee (1983) show evidence of the 0–4 and 0–5 bands of the N₂(c′₄¹Σ_u⁺ → a¹Π_g) Gaydon-Herman system. In conjunction with earlier spectra, it is now possible that this band system is a significant auroral component, with an intensity approx. 7% that of the N2 2P system. The absence in aurorae of the potentially far stronger N₂(c′₄¹Σ_u⁺ → X¹Π_g) system is discussed. It is that the O₂(A³Σ_u⁺ → X³Σ_g⁻) band system is indiscernible in Sivjee's auroral spectra, under conditio the foreground nightglow is expected to be clearly visible. On the other hand, at least one relatively strong O₂(A′³Δ_u → a¹Δ_g) band appears to be present in these spectra.     

The excitation of atomic oxygen to the O(1S) level by energy transfer from N2(A3∑u+) molecules in aurora

The part that the energy transfer reaction $\text{N}{}_2\text{(A}{}^3\text{∑}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{) + O(}{}^3\text{P) → N}{}_2\text{(X}{}^1\text{∑}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{) + O(}{}^1\text{S)}$ plays in the excitation of the auroral green line has been investigated. The contribution is estimated to be 40 per cent in this case, containing pulsating aurora in class IBC 1. Due to greater quenching of the A³∑_u⁺ state, the centroid of the VK emission is displaced 10 km upwards of the green line height, which is centred at 110 km.     

Carbon abundances and 12C/13C from globular cluster giants

The behaviour of the  Δν= 2 CO  bands around 2.3 μm was examined by comparing observed and synthetic spectra in stars in globular clusters of different metallicity. Changes in the ¹²C/¹³C isotopic ratio and the carbon abundances were investigated in stars from 3500–4900 K in the galactic globular clusters M71, M5, M3 and M13, covering the metallicity range from −0.7 to −1.6. We found relatively low carbon abundances that are not affected by the value of oxygen abundance. For most giants, the ¹²C/¹³C ratios determined are consistent with the equilibrium value for the CN cycle. This suggests complete mixing on the ascent of the red giant branch, in contrast to the substantially higher values predicted across this range of parameters by the current generation of models. We found some evidence for a larger dispersion of ¹²C/¹³C in giants of M71 of metallicity  [μ]=[M/H]=−0.7  in comparison with the giants of M3, M5 and M13, which are more metal deficient. Finally, we show evidence for lower ¹²C/¹³C in giants of globular clusters with lower metallicities, as predicted by theory.     

CH4/N2/H2 spark hydrophilic tholins: A systematic approach to the characterization of tholins

Tholins are complex organic materials produced by irradiation of several carbon and nitrogen rich atmospheres. They could have played a key role in the origin of life on Earth because their ability to release important bioorganics, which are nowadays present in proteins, nucleic-acid bases and other important biostructures. Usually, the yield of these compounds is higher after acid hydrolysis, however little is known about the structure and chemical composition of the tholins. In this work, we propose the use of different spectroscopic and separation techniques, which are not usually applied in this field, in order to obtain complete information about the tholin structure and behavior. Two different simulation experiments of prebiotic synthesis were carried out in CH₄/N₂/H₂ atmosphere out from spark discharge activation of aqueous aerosols and liquid water, respectively. In both cases, a hydrophilic tholin and a hydrophobic tholin were obtained. Herein, we report the application of this methodology to our hydrophilic tholins and we review, briefly, some astrobiological aspects related to these complex substances.     

H3+ in diffuse interstellar gas

A model is constructed of the material in front of the star Cygnus OB2 no. 12 in which dense cores are embedded in diffuse clumps of gas. The model reproduces the measured abundances of C₂ and CO, and predicts a column density of 910¹⁰ cm² for HCO⁺.     

Non-thermal O(1D) produced by dissociative recombination of O2+: A theoretical model and observational results

Thermal and non-thermal $\text{O}\text{(}{}^1\text{D}\text{)}$ number density profiles are calculated. The two populations are assumed to be coupled by a thermalization cross-section which determines the loss and production in the non-thermal and thermal populations, respectively. The sources, sinks and transport of the two populations are used to model volume emission rate profiles at 6300 Å. The 6300 Å brightness measured by the Visible Airglow Experiment is then used to establish the presence of the non-thermal population and to determine the thermalization cross-section.     

A new interpretation of the 1304 Å triplet airglow intensity ratio with the fine structure levels O3Pj) in local thermodynamic equilibrium

The intensity ratios of the 1304 Å triplet airglow of atomic oxygen observed by Fastie and Crosswhite (1964) are interpreted on the basis of the radiative transfer formulation for a model with complete frequency redistribution in a Voigt line profile. A model for the fine structure levels $\text{O(}{}^3\text{P}{}_{\mathrm{j}}\text{)}$ in local thermodynamic equilibrium is favorable to the observed intensity ratios, as far as a Voigt profile is applicable. In view of large cross sections as calculated theoretically by Allison and Burke (1969), the mutual relaxation among the ³P_j levels should occur rapidly enough to allow the population in the ³P_j levels to be in thermodynamic equilibrium with the ambient neutral gases.     

The excitation of O2(b1Σg+) in the nightglow

It is proposed that the available measurements of the O₂(b¹Σ_g⁺ ?X³Σ_g^?) atmospheric bands both in the nightglow and in the laboratory indicate that the excitation mechanism is a two-step process rather than the direct three body recombination of atomic oxygen. It is shown that such a two-step mechanism can explain observations of the atmospheric bands both in altitude and intensity.